DE69933403T2 - Verfahren zur autothermen Dampfreformierung einer Kohlenwasserstoffeinspeisung - Google Patents

Verfahren zur autothermen Dampfreformierung einer Kohlenwasserstoffeinspeisung Download PDF

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Publication number
DE69933403T2
DE69933403T2 DE69933403T DE69933403T DE69933403T2 DE 69933403 T2 DE69933403 T2 DE 69933403T2 DE 69933403 T DE69933403 T DE 69933403T DE 69933403 T DE69933403 T DE 69933403T DE 69933403 T2 DE69933403 T2 DE 69933403T2
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DE
Germany
Prior art keywords
steam
soot
carbon ratio
reactor
atr
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Fee Related
Application number
DE69933403T
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German (de)
English (en)
Other versions
DE69933403D1 (de
Inventor
Peter Seier Christensen
Thomas Sandahl Christensen
Ivar Ivarsen Primdahl
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Topsoe AS
Original Assignee
Haldor Topsoe AS
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
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Publication date
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Priority claimed from DK199800216A external-priority patent/DK21698A/da
Application filed by Haldor Topsoe AS filed Critical Haldor Topsoe AS
Application granted granted Critical
Publication of DE69933403D1 publication Critical patent/DE69933403D1/de
Publication of DE69933403T2 publication Critical patent/DE69933403T2/de
Anticipated expiration legal-status Critical
Expired - Fee Related legal-status Critical Current

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Classifications

    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G5/00—Recovery of liquid hydrocarbon mixtures from gases, e.g. natural gas
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B3/00—Hydrogen; Gaseous mixtures containing hydrogen; Separation of hydrogen from mixtures containing it; Purification of hydrogen; Reversible storage of hydrogen
    • C01B3/02—Production of hydrogen; Production of gaseous mixtures containing hydrogen
    • C01B3/32—Production of hydrogen; Production of gaseous mixtures containing hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide or air
    • C01B3/34—Production of hydrogen; Production of gaseous mixtures containing hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide or air by reaction of hydrocarbons with gasifying agents
    • C01B3/38—Production of hydrogen; Production of gaseous mixtures containing hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide or air by reaction of hydrocarbons with gasifying agents using catalysts
    • C01B3/382—Processes with two or more reaction steps, of which at least one is catalytic, e.g. steam reforming and partial oxidation
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B3/00—Hydrogen; Gaseous mixtures containing hydrogen; Separation of hydrogen from mixtures containing it; Purification of hydrogen; Reversible storage of hydrogen
    • C01B3/02—Production of hydrogen; Production of gaseous mixtures containing hydrogen
    • C01B3/32—Production of hydrogen; Production of gaseous mixtures containing hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide or air
    • C01B3/34—Production of hydrogen; Production of gaseous mixtures containing hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide or air by reaction of hydrocarbons with gasifying agents
    • C01B3/48—Production of hydrogen; Production of gaseous mixtures containing hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide or air by reaction of hydrocarbons with gasifying agents followed by reaction of water vapour with carbon monoxide
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/02—Processes for making hydrogen or synthesis gas
    • C01B2203/0205—Processes for making hydrogen or synthesis gas containing a reforming step
    • C01B2203/0227—Processes for making hydrogen or synthesis gas containing a reforming step containing a catalytic reforming step
    • C01B2203/0244—Processes for making hydrogen or synthesis gas containing a reforming step containing a catalytic reforming step the reforming step being an autothermal reforming step, e.g. secondary reforming processes
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/02—Processes for making hydrogen or synthesis gas
    • C01B2203/0283—Processes for making hydrogen or synthesis gas containing a CO-shift step, i.e. a water gas shift step
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/04—Integrated processes for the production of hydrogen or synthesis gas containing a purification step for the hydrogen or the synthesis gas
    • C01B2203/0465—Composition of the impurity
    • C01B2203/0495—Composition of the impurity the impurity being water
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/08—Methods of heating or cooling
    • C01B2203/0805—Methods of heating the process for making hydrogen or synthesis gas
    • C01B2203/0838—Methods of heating the process for making hydrogen or synthesis gas by heat exchange with exothermic reactions, other than by combustion of fuel
    • C01B2203/0844—Methods of heating the process for making hydrogen or synthesis gas by heat exchange with exothermic reactions, other than by combustion of fuel the non-combustive exothermic reaction being another reforming reaction as defined in groups C01B2203/02 - C01B2203/0294
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/12—Feeding the process for making hydrogen or synthesis gas
    • C01B2203/1205—Composition of the feed
    • C01B2203/1211—Organic compounds or organic mixtures used in the process for making hydrogen or synthesis gas
    • C01B2203/1235—Hydrocarbons
    • C01B2203/1241—Natural gas or methane
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/12—Feeding the process for making hydrogen or synthesis gas
    • C01B2203/1258—Pre-treatment of the feed
    • C01B2203/1264—Catalytic pre-treatment of the feed
    • C01B2203/127—Catalytic desulfurisation
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/14—Details of the flowsheet
    • C01B2203/142—At least two reforming, decomposition or partial oxidation steps in series
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/16—Controlling the process
    • C01B2203/1628—Controlling the pressure
    • C01B2203/1638—Adjusting the pressure
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/16—Controlling the process
    • C01B2203/1642—Controlling the product
    • C01B2203/1647—Controlling the amount of the product
    • C01B2203/1652—Measuring the amount of product
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/16—Controlling the process
    • C01B2203/1642—Controlling the product
    • C01B2203/1671—Controlling the composition of the product
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/16—Controlling the process
    • C01B2203/169—Controlling the feed
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/80—Aspect of integrated processes for the production of hydrogen or synthesis gas not covered by groups C01B2203/02 - C01B2203/1695
    • C01B2203/82—Several process steps of C01B2203/02 - C01B2203/08 integrated into a single apparatus

Landscapes

  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Inorganic Chemistry (AREA)
  • Combustion & Propulsion (AREA)
  • General Health & Medical Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • General Chemical & Material Sciences (AREA)
  • Hydrogen, Water And Hydrids (AREA)
  • Pigments, Carbon Blacks, Or Wood Stains (AREA)
  • Physical Or Chemical Processes And Apparatus (AREA)
  • Production Of Liquid Hydrocarbon Mixture For Refining Petroleum (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
DE69933403T 1998-02-17 1999-02-08 Verfahren zur autothermen Dampfreformierung einer Kohlenwasserstoffeinspeisung Expired - Fee Related DE69933403T2 (de)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
DK199800216A DK21698A (da) 1997-12-18 1998-02-17 Fremgangsmåde til automatisk reforming af carbonhydrid fødemateriale
DK21698 1998-02-17

Publications (2)

Publication Number Publication Date
DE69933403D1 DE69933403D1 (de) 2006-11-16
DE69933403T2 true DE69933403T2 (de) 2007-01-11

Family

ID=8091049

Family Applications (1)

Application Number Title Priority Date Filing Date
DE69933403T Expired - Fee Related DE69933403T2 (de) 1998-02-17 1999-02-08 Verfahren zur autothermen Dampfreformierung einer Kohlenwasserstoffeinspeisung

Country Status (10)

Country Link
US (1) US6143202A (https=)
EP (1) EP0936183B1 (https=)
JP (1) JPH11314901A (https=)
KR (1) KR100314453B1 (https=)
CN (1) CN1183227C (https=)
AT (1) ATE341524T1 (https=)
CA (1) CA2262070A1 (https=)
DE (1) DE69933403T2 (https=)
EA (1) EA001722B1 (https=)
ES (1) ES2273450T3 (https=)

Families Citing this family (17)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE19953924A1 (de) * 1999-11-10 2001-06-07 Bundesdruckerei Gmbh Zinksulfidische Elektroluminophore sowie Verfahren zu ihrer Herstellung
JP4742405B2 (ja) 2000-06-28 2011-08-10 トヨタ自動車株式会社 燃料改質装置
EP1188713A3 (en) 2000-09-18 2003-06-25 Haldor Topsoe A/S Production of hydrogen and carbon monoxide containing synthesis gas by partial oxidation
US6818198B2 (en) * 2002-09-23 2004-11-16 Kellogg Brown & Root, Inc. Hydrogen enrichment scheme for autothermal reforming
CA2410927A1 (fr) * 2002-11-05 2004-05-05 Michel Petitclerc Reacteur a chauffage electrique pour le reformage en phase gazeuse
FR2846958B1 (fr) * 2002-11-13 2005-08-26 N Ghy Valorisation de l'oxygene pour la production d'hydrogene a partir d'hydrocarbures avec sequestration de co2
US6872753B2 (en) * 2002-11-25 2005-03-29 Conocophillips Company Managing hydrogen and carbon monoxide in a gas to liquid plant to control the H2/CO ratio in the Fischer-Tropsch reactor feed
US6946493B2 (en) * 2003-03-15 2005-09-20 Conocophillips Company Managing hydrogen in a gas to liquid plant
US6958363B2 (en) * 2003-03-15 2005-10-25 Conocophillips Company Hydrogen use in a GTL plant
US7427388B2 (en) 2004-03-19 2008-09-23 Air Products And Chemicals, Inc. Process for improving prereforming and reforming of natural gas containing higher hydrocarbons along with methane
GB0502608D0 (en) * 2005-02-09 2005-03-16 Rolls Royce Plc A fuel processor
US20080260631A1 (en) 2007-04-18 2008-10-23 H2Gen Innovations, Inc. Hydrogen production process
JP2010189217A (ja) * 2009-02-17 2010-09-02 Keio Gijuku 改質器および改質方法
DE102011101077A1 (de) * 2011-05-10 2012-11-15 L'Air Liquide, Société Anonyme pour l'Etude et l'Exploitation des Procédés Georges Claude Verfahren und Reaktor zur autothermen Reformierung von Brennstoffen
US9933408B2 (en) 2014-11-10 2018-04-03 Air Products And Chemicals, Inc. Method for characterizing the hydrocarbon content of a reformate stream
US9409773B2 (en) 2014-11-10 2016-08-09 Air Products And Chemicals, Inc. Steam-hydrocarbon reforming process
DE102015210803A1 (de) 2015-06-12 2016-12-15 Thyssenkrupp Ag Festlegung von Druck, Temperatur und S/C-Verhältnis für einen rußfreien ATR-Betrieb

Family Cites Families (10)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4473543A (en) * 1982-04-26 1984-09-25 United Technologies Corporation Autothermal reforming catalyst and process
US4666680A (en) * 1984-01-30 1987-05-19 Fluor Corporation Autothermal production of synthesis gas
JPH01261201A (ja) * 1988-04-12 1989-10-18 Mitsubishi Gas Chem Co Inc 炭化水素改質反応器
JPH0218303A (ja) * 1988-07-07 1990-01-22 Mitsubishi Gas Chem Co Inc 炭化水素の改質反応器および改質方法
US5112527A (en) * 1991-04-02 1992-05-12 Amoco Corporation Process for converting natural gas to synthesis gas
FR2679217B1 (fr) * 1991-07-18 1994-04-01 Institut Francais Petrole Procede et dispositif pour la fabrication de gaz de synthese et application.
DK168460B1 (da) * 1991-12-06 1994-03-28 Topsoe Haldor As Hvirvelbrænder
JPH06206702A (ja) * 1993-01-12 1994-07-26 Mitsubishi Gas Chem Co Inc 炭化水素反応器
CN1065510C (zh) * 1994-07-07 2001-05-09 国际壳牌研究有限公司 含有氢气和一氧化碳的混合物的制备方法
JPH10273678A (ja) * 1997-03-28 1998-10-13 Sekiyu Sangyo Kasseika Center 熱交換型改質反応器

Also Published As

Publication number Publication date
ES2273450T3 (es) 2007-05-01
JPH11314901A (ja) 1999-11-16
ATE341524T1 (de) 2006-10-15
EP0936183B1 (en) 2006-10-04
CN1183227C (zh) 2005-01-05
EA199900125A2 (ru) 1999-08-26
EA199900125A3 (ru) 1999-12-29
EA001722B1 (ru) 2001-08-27
CA2262070A1 (en) 1999-08-17
DE69933403D1 (de) 2006-11-16
CN1229122A (zh) 1999-09-22
KR19990072685A (ko) 1999-09-27
EP0936183A3 (en) 2000-02-23
US6143202A (en) 2000-11-07
EP0936183A2 (en) 1999-08-18
KR100314453B1 (ko) 2001-11-22

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8363 Opposition against the patent
8339 Ceased/non-payment of the annual fee