DE69710617T2 - Verfahren zur entgiftung von nitril- und/oder amid-verbindungen - Google Patents
Verfahren zur entgiftung von nitril- und/oder amid-verbindungenInfo
- Publication number
- DE69710617T2 DE69710617T2 DE69710617T DE69710617T DE69710617T2 DE 69710617 T2 DE69710617 T2 DE 69710617T2 DE 69710617 T DE69710617 T DE 69710617T DE 69710617 T DE69710617 T DE 69710617T DE 69710617 T2 DE69710617 T2 DE 69710617T2
- Authority
- DE
- Germany
- Prior art keywords
- mixture
- nitrile
- compounds
- amide
- ppm
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- 150000002825 nitriles Chemical class 0.000 title claims abstract description 289
- 238000000034 method Methods 0.000 title claims abstract description 181
- 150000001875 compounds Chemical class 0.000 title claims abstract description 75
- -1 nitrile compounds Chemical class 0.000 claims abstract description 420
- 239000000203 mixture Substances 0.000 claims abstract description 403
- 244000005700 microbiome Species 0.000 claims abstract description 289
- 150000001408 amides Chemical class 0.000 claims abstract description 151
- 239000002253 acid Chemical class 0.000 claims abstract description 85
- HRPVXLWXLXDGHG-UHFFFAOYSA-N Acrylamide Chemical compound NC(=O)C=C HRPVXLWXLXDGHG-UHFFFAOYSA-N 0.000 claims abstract description 66
- DLFVBJFMPXGRIB-UHFFFAOYSA-N Acetamide Chemical compound CC(N)=O DLFVBJFMPXGRIB-UHFFFAOYSA-N 0.000 claims abstract description 56
- 238000004519 manufacturing process Methods 0.000 claims abstract description 51
- 239000002699 waste material Substances 0.000 claims abstract description 39
- 238000002360 preparation method Methods 0.000 claims abstract description 35
- WEVYAHXRMPXWCK-UHFFFAOYSA-N Acetonitrile Chemical compound CC#N WEVYAHXRMPXWCK-UHFFFAOYSA-N 0.000 claims description 276
- NLHHRLWOUZZQLW-UHFFFAOYSA-N Acrylonitrile Chemical compound C=CC#N NLHHRLWOUZZQLW-UHFFFAOYSA-N 0.000 claims description 125
- 239000002609 medium Substances 0.000 claims description 69
- 230000000694 effects Effects 0.000 claims description 62
- IAHFWCOBPZCAEA-UHFFFAOYSA-N succinonitrile Chemical compound N#CCCC#N IAHFWCOBPZCAEA-UHFFFAOYSA-N 0.000 claims description 58
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims description 47
- 230000008569 process Effects 0.000 claims description 45
- HGINCPLSRVDWNT-UHFFFAOYSA-N Acrolein Chemical compound C=CC=O HGINCPLSRVDWNT-UHFFFAOYSA-N 0.000 claims description 40
- 239000001963 growth medium Substances 0.000 claims description 36
- 238000012360 testing method Methods 0.000 claims description 32
- KYPOHTVBFVELTG-OWOJBTEDSA-N (e)-but-2-enedinitrile Chemical compound N#C\C=C\C#N KYPOHTVBFVELTG-OWOJBTEDSA-N 0.000 claims description 30
- 235000015097 nutrients Nutrition 0.000 claims description 30
- 238000012258 culturing Methods 0.000 claims description 28
- 239000000284 extract Substances 0.000 claims description 27
- 230000008034 disappearance Effects 0.000 claims description 24
- 239000007787 solid Substances 0.000 claims description 21
- FHVDTGUDJYJELY-UHFFFAOYSA-N 6-{[2-carboxy-4,5-dihydroxy-6-(phosphanyloxy)oxan-3-yl]oxy}-4,5-dihydroxy-3-phosphanyloxane-2-carboxylic acid Chemical compound O1C(C(O)=O)C(P)C(O)C(O)C1OC1C(C(O)=O)OC(OP)C(O)C1O FHVDTGUDJYJELY-UHFFFAOYSA-N 0.000 claims description 17
- 229940072056 alginate Drugs 0.000 claims description 17
- 235000010443 alginic acid Nutrition 0.000 claims description 17
- 229920000615 alginic acid Polymers 0.000 claims description 17
- 108700023418 Amidases Proteins 0.000 claims description 14
- 102000005922 amidase Human genes 0.000 claims description 14
- MNWBNISUBARLIT-UHFFFAOYSA-N sodium cyanide Chemical compound [Na+].N#[C-] MNWBNISUBARLIT-UHFFFAOYSA-N 0.000 claims description 12
- UQSXHKLRYXJYBZ-UHFFFAOYSA-N Iron oxide Chemical compound [Fe]=O UQSXHKLRYXJYBZ-UHFFFAOYSA-N 0.000 claims description 8
- 230000001939 inductive effect Effects 0.000 claims description 8
- 238000003786 synthesis reaction Methods 0.000 claims description 8
- 239000000126 substance Substances 0.000 claims description 7
- 238000012544 monitoring process Methods 0.000 claims description 6
- 239000002023 wood Substances 0.000 claims description 6
- KJTLSVCANCCWHF-UHFFFAOYSA-N Ruthenium Chemical compound [Ru] KJTLSVCANCCWHF-UHFFFAOYSA-N 0.000 claims description 4
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 claims description 4
- 239000000919 ceramic Substances 0.000 claims description 4
- 229910052707 ruthenium Inorganic materials 0.000 claims description 4
- 239000000679 carrageenan Substances 0.000 claims description 3
- 229920001525 carrageenan Polymers 0.000 claims description 3
- 229940113118 carrageenan Drugs 0.000 claims description 3
- 230000002349 favourable effect Effects 0.000 claims description 3
- 238000012216 screening Methods 0.000 claims description 3
- 230000031018 biological processes and functions Effects 0.000 claims description 2
- 238000010438 heat treatment Methods 0.000 claims description 2
- 230000006872 improvement Effects 0.000 claims description 2
- 238000001784 detoxification Methods 0.000 abstract description 102
- 238000006243 chemical reaction Methods 0.000 abstract description 27
- 239000002028 Biomass Substances 0.000 abstract description 11
- 231100000419 toxicity Toxicity 0.000 abstract description 5
- 230000001988 toxicity Effects 0.000 abstract description 5
- 150000002826 nitrites Chemical class 0.000 abstract 1
- 210000004027 cell Anatomy 0.000 description 51
- 230000000875 corresponding effect Effects 0.000 description 43
- 229910052799 carbon Inorganic materials 0.000 description 40
- JFDZBHWFFUWGJE-UHFFFAOYSA-N benzonitrile Chemical compound N#CC1=CC=CC=C1 JFDZBHWFFUWGJE-UHFFFAOYSA-N 0.000 description 39
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 description 36
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 36
- 230000006698 induction Effects 0.000 description 26
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 24
- 239000001301 oxygen Substances 0.000 description 24
- 229910052760 oxygen Inorganic materials 0.000 description 24
- BFNBIHQBYMNNAN-UHFFFAOYSA-N ammonium sulfate Chemical compound N.N.OS(O)(=O)=O BFNBIHQBYMNNAN-UHFFFAOYSA-N 0.000 description 22
- 229910052921 ammonium sulfate Inorganic materials 0.000 description 22
- 235000011130 ammonium sulphate Nutrition 0.000 description 22
- 241000187562 Rhodococcus sp. Species 0.000 description 21
- XSQUKJJJFZCRTK-UHFFFAOYSA-N Urea Chemical compound NC(N)=O XSQUKJJJFZCRTK-UHFFFAOYSA-N 0.000 description 20
- NNFCIKHAZHQZJG-UHFFFAOYSA-N potassium cyanide Chemical compound [K+].N#[C-] NNFCIKHAZHQZJG-UHFFFAOYSA-N 0.000 description 20
- 229910052757 nitrogen Inorganic materials 0.000 description 18
- 229910021529 ammonia Inorganic materials 0.000 description 17
- 150000007513 acids Chemical class 0.000 description 16
- 239000000243 solution Substances 0.000 description 16
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Chemical compound O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 16
- 108010024026 Nitrile hydratase Proteins 0.000 description 15
- NPDACUSDTOMAMK-UHFFFAOYSA-N 4-Chlorotoluene Chemical compound CC1=CC=C(Cl)C=C1 NPDACUSDTOMAMK-UHFFFAOYSA-N 0.000 description 14
- MVPPADPHJFYWMZ-UHFFFAOYSA-N chlorobenzene Chemical compound ClC1=CC=CC=C1 MVPPADPHJFYWMZ-UHFFFAOYSA-N 0.000 description 14
- GPSDUZXPYCFOSQ-UHFFFAOYSA-N m-toluic acid Chemical compound CC1=CC=CC(C(O)=O)=C1 GPSDUZXPYCFOSQ-UHFFFAOYSA-N 0.000 description 14
- 241000187693 Rhodococcus rhodochrous Species 0.000 description 13
- 239000011324 bead Substances 0.000 description 13
- 239000010941 cobalt Substances 0.000 description 13
- 229910017052 cobalt Inorganic materials 0.000 description 13
- GUTLYIVDDKVIGB-UHFFFAOYSA-N cobalt atom Chemical compound [Co] GUTLYIVDDKVIGB-UHFFFAOYSA-N 0.000 description 13
- XMGQYMWWDOXHJM-UHFFFAOYSA-N limonene Chemical compound CC(=C)C1CCC(C)=CC1 XMGQYMWWDOXHJM-UHFFFAOYSA-N 0.000 description 12
- 239000002351 wastewater Substances 0.000 description 12
- 229920001817 Agar Polymers 0.000 description 11
- QQONPFPTGQHPMA-UHFFFAOYSA-N Propene Chemical compound CC=C QQONPFPTGQHPMA-UHFFFAOYSA-N 0.000 description 11
- 239000007788 liquid Substances 0.000 description 11
- 229920002401 polyacrylamide Polymers 0.000 description 11
- XFXPMWWXUTWYJX-UHFFFAOYSA-N Cyanide Chemical compound N#[C-] XFXPMWWXUTWYJX-UHFFFAOYSA-N 0.000 description 10
- 239000004202 carbamide Substances 0.000 description 10
- 239000000047 product Substances 0.000 description 10
- 241000894006 Bacteria Species 0.000 description 9
- 108010033272 Nitrilase Proteins 0.000 description 9
- 239000007864 aqueous solution Substances 0.000 description 9
- 238000007792 addition Methods 0.000 description 8
- 239000008272 agar Substances 0.000 description 8
- YCIMNLLNPGFGHC-UHFFFAOYSA-N catechol Chemical compound OC1=CC=CC=C1O YCIMNLLNPGFGHC-UHFFFAOYSA-N 0.000 description 8
- GVEPBJHOBDJJJI-UHFFFAOYSA-N fluoranthrene Natural products C1=CC(C2=CC=CC=C22)=C3C2=CC=CC3=C1 GVEPBJHOBDJJJI-UHFFFAOYSA-N 0.000 description 8
- IBSQPLPBRSHTTG-UHFFFAOYSA-N 1-chloro-2-methylbenzene Chemical compound CC1=CC=CC=C1Cl IBSQPLPBRSHTTG-UHFFFAOYSA-N 0.000 description 7
- OSOUNOBYRMOXQQ-UHFFFAOYSA-N 1-chloro-3-methylbenzene Chemical compound CC1=CC=CC(Cl)=C1 OSOUNOBYRMOXQQ-UHFFFAOYSA-N 0.000 description 7
- WQZGKKKJIJFFOK-GASJEMHNSA-N Glucose Natural products OC[C@H]1OC(O)[C@H](O)[C@@H](O)[C@@H]1O WQZGKKKJIJFFOK-GASJEMHNSA-N 0.000 description 7
- 239000002518 antifoaming agent Substances 0.000 description 7
- WQZGKKKJIJFFOK-VFUOTHLCSA-N beta-D-glucose Chemical compound OC[C@H]1O[C@@H](O)[C@H](O)[C@@H](O)[C@@H]1O WQZGKKKJIJFFOK-VFUOTHLCSA-N 0.000 description 7
- 230000015556 catabolic process Effects 0.000 description 7
- 239000000287 crude extract Substances 0.000 description 7
- 238000006731 degradation reaction Methods 0.000 description 7
- 238000002955 isolation Methods 0.000 description 7
- 230000007246 mechanism Effects 0.000 description 7
- AUHZEENZYGFFBQ-UHFFFAOYSA-N mesitylene Substances CC1=CC(C)=CC(C)=C1 AUHZEENZYGFFBQ-UHFFFAOYSA-N 0.000 description 7
- 125000001827 mesitylenyl group Chemical group [H]C1=C(C(*)=C(C([H])=C1C([H])([H])[H])C([H])([H])[H])C([H])([H])[H] 0.000 description 7
- ZPQOPVIELGIULI-UHFFFAOYSA-N 1,3-dichlorobenzene Chemical compound ClC1=CC=CC(Cl)=C1 ZPQOPVIELGIULI-UHFFFAOYSA-N 0.000 description 6
- SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Chemical compound COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 description 6
- NIXOWILDQLNWCW-UHFFFAOYSA-N 2-Propenoic acid Natural products OC(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 description 6
- IKCLCGXPQILATA-IDEBNGHGSA-N 2-chlorobenzoic acid Chemical compound OC(=O)[13C]1=[13CH][13CH]=[13CH][13CH]=[13C]1Cl IKCLCGXPQILATA-IDEBNGHGSA-N 0.000 description 6
- LULAYUGMBFYYEX-UHFFFAOYSA-N 3-chlorobenzoic acid Chemical compound OC(=O)C1=CC=CC(Cl)=C1 LULAYUGMBFYYEX-UHFFFAOYSA-N 0.000 description 6
- XRHGYUZYPHTUJZ-UHFFFAOYSA-N 4-chlorobenzoic acid Chemical compound OC(=O)C1=CC=C(Cl)C=C1 XRHGYUZYPHTUJZ-UHFFFAOYSA-N 0.000 description 6
- CSCPPACGZOOCGX-UHFFFAOYSA-N Acetone Chemical compound CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 description 6
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical group [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 6
- JVTAAEKCZFNVCJ-UHFFFAOYSA-M Lactate Chemical compound CC(O)C([O-])=O JVTAAEKCZFNVCJ-UHFFFAOYSA-M 0.000 description 6
- CSNNHWWHGAXBCP-UHFFFAOYSA-L Magnesium sulfate Chemical compound [Mg+2].[O-][S+2]([O-])([O-])[O-] CSNNHWWHGAXBCP-UHFFFAOYSA-L 0.000 description 6
- 239000004952 Polyamide Substances 0.000 description 6
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 description 6
- 235000010419 agar Nutrition 0.000 description 6
- 230000001580 bacterial effect Effects 0.000 description 6
- KVNRLNFWIYMESJ-UHFFFAOYSA-N butyronitrile Chemical compound CCCC#N KVNRLNFWIYMESJ-UHFFFAOYSA-N 0.000 description 6
- 230000000593 degrading effect Effects 0.000 description 6
- 229940087305 limonene Drugs 0.000 description 6
- 235000001510 limonene Nutrition 0.000 description 6
- 239000008188 pellet Substances 0.000 description 6
- 150000002978 peroxides Chemical class 0.000 description 6
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- 239000011541 reaction mixture Substances 0.000 description 6
- 239000010802 sludge Substances 0.000 description 6
- DAEPDZWVDSPTHF-UHFFFAOYSA-M sodium pyruvate Chemical compound [Na+].CC(=O)C([O-])=O DAEPDZWVDSPTHF-UHFFFAOYSA-M 0.000 description 6
- 241000316848 Rhodococcus <scale insect> Species 0.000 description 5
- HXGDTGSAIMULJN-UHFFFAOYSA-N acetnaphthylene Natural products C1=CC(C=C2)=C3C2=CC=CC3=C1 HXGDTGSAIMULJN-UHFFFAOYSA-N 0.000 description 5
- 238000004458 analytical method Methods 0.000 description 5
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- LOKCTEFSRHRXRJ-UHFFFAOYSA-I dipotassium trisodium dihydrogen phosphate hydrogen phosphate dichloride Chemical compound P(=O)(O)(O)[O-].[K+].P(=O)(O)([O-])[O-].[Na+].[Na+].[Cl-].[K+].[Cl-].[Na+] LOKCTEFSRHRXRJ-UHFFFAOYSA-I 0.000 description 5
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- 238000004128 high performance liquid chromatography Methods 0.000 description 5
- 239000000178 monomer Substances 0.000 description 5
- LQNUZADURLCDLV-UHFFFAOYSA-N nitrobenzene Chemical compound [O-][N+](=O)C1=CC=CC=C1 LQNUZADURLCDLV-UHFFFAOYSA-N 0.000 description 5
- 239000002953 phosphate buffered saline Substances 0.000 description 5
- 230000002829 reductive effect Effects 0.000 description 5
- 239000000758 substrate Substances 0.000 description 5
- KDYFGRWQOYBRFD-UHFFFAOYSA-L succinate(2-) Chemical compound [O-]C(=O)CCC([O-])=O KDYFGRWQOYBRFD-UHFFFAOYSA-L 0.000 description 5
- 239000003039 volatile agent Substances 0.000 description 5
- 239000012138 yeast extract Substances 0.000 description 5
- SDOFMBGMRVAJNF-KVTDHHQDSA-N (2r,3r,4r,5r)-6-aminohexane-1,2,3,4,5-pentol Chemical compound NC[C@@H](O)[C@@H](O)[C@H](O)[C@H](O)CO SDOFMBGMRVAJNF-KVTDHHQDSA-N 0.000 description 4
- CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 description 4
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- ZIUHHBKFKCYYJD-UHFFFAOYSA-N n,n'-methylenebisacrylamide Chemical compound C=CC(=O)NCNC(=O)C=C ZIUHHBKFKCYYJD-UHFFFAOYSA-N 0.000 description 1
- 125000002560 nitrile group Chemical group 0.000 description 1
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- USHAGKDGDHPEEY-UHFFFAOYSA-L potassium persulfate Chemical compound [K+].[K+].[O-]S(=O)(=O)OOS([O-])(=O)=O USHAGKDGDHPEEY-UHFFFAOYSA-L 0.000 description 1
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Classifications
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- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F3/00—Biological treatment of water, waste water, or sewage
- C02F3/02—Aerobic processes
- C02F3/12—Activated sludge processes
- C02F3/1205—Particular type of activated sludge processes
- C02F3/1231—Treatments of toxic sewage
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F3/00—Biological treatment of water, waste water, or sewage
- C02F3/34—Biological treatment of water, waste water, or sewage characterised by the microorganisms used
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02W—CLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO WASTEWATER TREATMENT OR WASTE MANAGEMENT
- Y02W10/00—Technologies for wastewater treatment
- Y02W10/10—Biological treatment of water, waste water, or sewage
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10S435/00—Chemistry: molecular biology and microbiology
- Y10S435/81—Packaged device or kit
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10S435/00—Chemistry: molecular biology and microbiology
- Y10S435/8215—Microorganisms
- Y10S435/822—Microorganisms using bacteria or actinomycetales
- Y10S435/843—Corynebacterium
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10S435/00—Chemistry: molecular biology and microbiology
- Y10S435/975—Kit
Landscapes
- Life Sciences & Earth Sciences (AREA)
- Microbiology (AREA)
- Biodiversity & Conservation Biology (AREA)
- Hydrology & Water Resources (AREA)
- Engineering & Computer Science (AREA)
- Environmental & Geological Engineering (AREA)
- Water Supply & Treatment (AREA)
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Toxicology (AREA)
- Health & Medical Sciences (AREA)
- Micro-Organisms Or Cultivation Processes Thereof (AREA)
- Preparation Of Compounds By Using Micro-Organisms (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
- Purification Treatments By Anaerobic Or Anaerobic And Aerobic Bacteria Or Animals (AREA)
- Apparatus Associated With Microorganisms And Enzymes (AREA)
- Immobilizing And Processing Of Enzymes And Microorganisms (AREA)
- Measuring Or Testing Involving Enzymes Or Micro-Organisms (AREA)
- Agricultural Chemicals And Associated Chemicals (AREA)
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US08/769,080 US5863750A (en) | 1996-12-18 | 1996-12-18 | Methods for the detoxification of nitrile and/or amide compounds |
| PCT/US1997/023862 WO1998027016A1 (en) | 1996-12-18 | 1997-12-18 | Methods for the detoxification of nitrile and/or amide compounds |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| DE69710617D1 DE69710617D1 (de) | 2002-03-28 |
| DE69710617T2 true DE69710617T2 (de) | 2002-07-18 |
Family
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Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| DE69710617T Expired - Lifetime DE69710617T2 (de) | 1996-12-18 | 1997-12-18 | Verfahren zur entgiftung von nitril- und/oder amid-verbindungen |
Country Status (11)
| Country | Link |
|---|---|
| US (2) | US5863750A (https=) |
| EP (1) | EP0958252B1 (https=) |
| JP (1) | JP2002513324A (https=) |
| KR (1) | KR100574770B1 (https=) |
| AT (1) | ATE213489T1 (https=) |
| AU (1) | AU721240B2 (https=) |
| CA (1) | CA2275413A1 (https=) |
| DE (1) | DE69710617T2 (https=) |
| ES (1) | ES2173511T3 (https=) |
| NO (1) | NO992975L (https=) |
| WO (1) | WO1998027016A1 (https=) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE102013207197A1 (de) * | 2013-04-22 | 2014-10-23 | Helmholtz-Zentrum Dresden - Rossendorf E.V. | Verfahren und System zur Abtrennung von Schwermetallen |
Families Citing this family (20)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US5863750A (en) * | 1996-12-18 | 1999-01-26 | Cytec Tech Corp | Methods for the detoxification of nitrile and/or amide compounds |
| US6060265A (en) * | 1996-12-18 | 2000-05-09 | Cytec Technology Corporation | Methods for the detoxification of nitrile and/or amide compounds |
| US6068774A (en) * | 1997-03-17 | 2000-05-30 | Osprey Biotechnics, Inc. | Biological control of agricultural waste odor |
| JP4185607B2 (ja) * | 1998-12-15 | 2008-11-26 | ダイセル化学工業株式会社 | 新規な微生物及びアミド化合物の製造方法 |
| US6395142B1 (en) * | 1999-10-14 | 2002-05-28 | Chemcycles, Inc. | Method and apparatus for purifying low grade acetonitrile and other constituents from hazardous waste |
| WO2001070936A1 (en) * | 2000-03-21 | 2001-09-27 | Mitsubishi Rayon Co., Ltd. | Method of culturing microorganism |
| AU2003296731B2 (en) * | 2003-01-08 | 2009-07-09 | Basf Aktiengesellschaft | Methods for preserving and/or storing cells having a nitrilase or nitrile hydratase activity |
| JP4389064B2 (ja) * | 2003-05-28 | 2009-12-24 | 三井化学株式会社 | ニトリルヒドラターゼ活性を維持または向上させる方法 |
| US7214509B2 (en) * | 2003-06-30 | 2007-05-08 | University Of Iowa Research Foundation | Methods and compositions for degradation of nitroaromatic and nitramine pollutants |
| US20050089987A1 (en) * | 2003-10-27 | 2005-04-28 | Lonza Ltd. | Polyacryamide beads containing encapsulated cells |
| GB0416101D0 (en) * | 2004-07-19 | 2004-08-18 | Ciba Spec Chem Water Treat Ltd | Process for preparing monomers and polymers thereof |
| NZ570825A (en) * | 2006-01-30 | 2012-05-25 | Univ Georgia State Res Found | Induction and stabilization of enzymatic activity in microorganisms |
| US7943549B2 (en) * | 2007-04-02 | 2011-05-17 | Georgia State University Research Foundation, Inc. | Biological-based catalyst to delay plant development processes |
| MX361278B (es) | 2013-03-14 | 2018-12-03 | Univ Georgia State Res Found | Inhibición o reducción del crecimiento de hongos. |
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| JP6519996B2 (ja) * | 2014-07-01 | 2019-05-29 | 株式会社大林組 | シアン化合物の分解促進剤、及びそれを用いた分解促進方法 |
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| CN115231772B (zh) * | 2022-07-15 | 2023-08-04 | 江苏蓝必盛化工环保股份有限公司 | 一种二甲基甲酰胺废水生物处理方法 |
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-
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- 1996-12-18 US US08/769,080 patent/US5863750A/en not_active Expired - Lifetime
-
1997
- 1997-12-18 ES ES97952637T patent/ES2173511T3/es not_active Expired - Lifetime
- 1997-12-18 KR KR19997005484A patent/KR100574770B1/ko not_active Expired - Fee Related
- 1997-12-18 WO PCT/US1997/023862 patent/WO1998027016A1/en not_active Ceased
- 1997-12-18 AU AU56202/98A patent/AU721240B2/en not_active Ceased
- 1997-12-18 CA CA 2275413 patent/CA2275413A1/en not_active Abandoned
- 1997-12-18 AT AT97952637T patent/ATE213489T1/de active
- 1997-12-18 JP JP52803798A patent/JP2002513324A/ja not_active Ceased
- 1997-12-18 DE DE69710617T patent/DE69710617T2/de not_active Expired - Lifetime
- 1997-12-18 EP EP97952637A patent/EP0958252B1/en not_active Expired - Lifetime
-
1999
- 1999-06-17 NO NO992975A patent/NO992975L/no not_active Application Discontinuation
- 1999-06-18 US US09/335,973 patent/US6132985A/en not_active Expired - Fee Related
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE102013207197A1 (de) * | 2013-04-22 | 2014-10-23 | Helmholtz-Zentrum Dresden - Rossendorf E.V. | Verfahren und System zur Abtrennung von Schwermetallen |
| DE102013207197B4 (de) * | 2013-04-22 | 2019-05-02 | Helmholtz-Zentrum Dresden - Rossendorf E.V. | Verfahren zur Abtrennung von Schwermetallen, Verwendung des Verfahrens und Verwendung eines Systems zur Aufreinigung schwermetallbelasteter Gewässer oder zum Nachweis von Schwermetallen in Gewässern |
Also Published As
| Publication number | Publication date |
|---|---|
| WO1998027016A1 (en) | 1998-06-25 |
| ES2173511T3 (es) | 2002-10-16 |
| EP0958252B1 (en) | 2002-02-20 |
| US6132985A (en) | 2000-10-17 |
| KR20000057662A (ko) | 2000-09-25 |
| AU5620298A (en) | 1998-07-15 |
| ATE213489T1 (de) | 2002-03-15 |
| JP2002513324A (ja) | 2002-05-08 |
| NO992975L (no) | 1999-08-17 |
| CA2275413A1 (en) | 1998-06-25 |
| AU721240B2 (en) | 2000-06-29 |
| KR100574770B1 (ko) | 2006-04-28 |
| US5863750A (en) | 1999-01-26 |
| DE69710617D1 (de) | 2002-03-28 |
| NO992975D0 (no) | 1999-06-17 |
| EP0958252A1 (en) | 1999-11-24 |
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