DE69710612T2 - Zeolith des im-5 -typs, dessen herstellung und katalytische verwendungen - Google Patents

Zeolith des im-5 -typs, dessen herstellung und katalytische verwendungen

Info

Publication number
DE69710612T2
DE69710612T2 DE69710612T DE69710612T DE69710612T2 DE 69710612 T2 DE69710612 T2 DE 69710612T2 DE 69710612 T DE69710612 T DE 69710612T DE 69710612 T DE69710612 T DE 69710612T DE 69710612 T2 DE69710612 T2 DE 69710612T2
Authority
DE
Germany
Prior art keywords
zeolite
cation
catalyst
group formed
bis
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Lifetime
Application number
DE69710612T
Other languages
German (de)
English (en)
Other versions
DE69710612D1 (de
Inventor
Eric Benazzi
Jean-Louis Guth
Loic Rouleau
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
IFP Energies nouvelles
Original Assignee
IFP Energies nouvelles
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by IFP Energies nouvelles filed Critical IFP Energies nouvelles
Application granted granted Critical
Publication of DE69710612D1 publication Critical patent/DE69710612D1/de
Publication of DE69710612T2 publication Critical patent/DE69710612T2/de
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G49/00—Treatment of hydrocarbon oils, in the presence of hydrogen or hydrogen-generating compounds, not provided for in a single one of groups C10G45/02, C10G45/32, C10G45/44, C10G45/58 or C10G47/00
    • C10G49/02—Treatment of hydrocarbon oils, in the presence of hydrogen or hydrogen-generating compounds, not provided for in a single one of groups C10G45/02, C10G45/32, C10G45/44, C10G45/58 or C10G47/00 characterised by the catalyst used
    • C10G49/08—Treatment of hydrocarbon oils, in the presence of hydrogen or hydrogen-generating compounds, not provided for in a single one of groups C10G45/02, C10G45/32, C10G45/44, C10G45/58 or C10G47/00 characterised by the catalyst used containing crystalline alumino-silicates, e.g. molecular sieves
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00—Catalysts comprising molecular sieves
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00—Catalysts comprising molecular sieves
    • B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B39/00—Compounds having molecular sieve and base-exchange properties, e.g. crystalline zeolites; Their preparation; After-treatment, e.g. ion-exchange or dealumination
    • C01B39/02—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof; Direct preparation thereof; Preparation thereof starting from a reaction mixture containing a crystalline zeolite of another type, or from preformed reactants; After-treatment thereof
    • C01B39/46—Other types characterised by their X-ray diffraction pattern and their defined composition
    • C01B39/48—Other types characterised by their X-ray diffraction pattern and their defined composition using at least one organic template directing agent

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Materials Engineering (AREA)
  • Geology (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • General Life Sciences & Earth Sciences (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Inorganic Chemistry (AREA)
  • General Chemical & Material Sciences (AREA)
  • Silicates, Zeolites, And Molecular Sieves (AREA)
  • Catalysts (AREA)
DE69710612T 1996-10-21 1997-10-17 Zeolith des im-5 -typs, dessen herstellung und katalytische verwendungen Expired - Lifetime DE69710612T2 (de)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
FR9612873A FR2754809B1 (fr) 1996-10-21 1996-10-21 Zeolithe im-5, son procede de preparation et ses applications catalytiques
PCT/FR1997/001868 WO1998017581A1 (fr) 1996-10-21 1997-10-17 Zeolithe im-5, son procede de preparation et ses applications catalytiques

Publications (2)

Publication Number Publication Date
DE69710612D1 DE69710612D1 (de) 2002-03-28
DE69710612T2 true DE69710612T2 (de) 2002-11-28

Family

ID=9496909

Family Applications (1)

Application Number Title Priority Date Filing Date
DE69710612T Expired - Lifetime DE69710612T2 (de) 1996-10-21 1997-10-17 Zeolith des im-5 -typs, dessen herstellung und katalytische verwendungen

Country Status (11)

Country Link
US (1) US6136290A (enExample)
EP (1) EP0946416B1 (enExample)
JP (1) JP4348651B2 (enExample)
KR (1) KR20000052636A (enExample)
CN (1) CN1234012A (enExample)
AU (1) AU4872297A (enExample)
BR (1) BR9712417A (enExample)
CA (1) CA2268803A1 (enExample)
DE (1) DE69710612T2 (enExample)
FR (1) FR2754809B1 (enExample)
WO (1) WO1998017581A1 (enExample)

Cited By (13)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US8609910B1 (en) 2012-12-12 2013-12-17 Uop Llc Catalytic pyrolysis using UZM-39 aluminosilicate zeolite
US8609921B1 (en) 2012-12-12 2013-12-17 Uop Llc Aromatic transalkylation using UZM-44 aluminosilicate zeolite
US8609919B1 (en) 2012-12-12 2013-12-17 Uop Llc Aromatic transformation using UZM-44 aluminosilicate zeolite
US8609920B1 (en) 2012-12-12 2013-12-17 Uop Llc UZM-44 aluminosilicate zeolite
US8609911B1 (en) 2012-12-12 2013-12-17 Uop Llc Catalytic pyrolysis using UZM-44 aluminosilicate zeolite
US8618343B1 (en) 2012-12-12 2013-12-31 Uop Llc Aromatic transalkylation using UZM-39 aluminosilicate zeolite
US8633344B2 (en) 2011-12-22 2014-01-21 Uop Llc Aromatic transformation using UZM-39 aluminosilicate zeolite
US8642823B2 (en) 2011-12-22 2014-02-04 Uop Llc UZM-39 aluminosilicate zeolite
US8889939B2 (en) 2012-12-12 2014-11-18 Uop Llc Dehydrocyclodimerization using UZM-44 aluminosilicate zeolite
US8907151B2 (en) 2012-12-12 2014-12-09 Uop Llc Conversion of methane to aromatic compounds using UZM-39 aluminosilicate zeolite
US8912378B2 (en) 2012-12-12 2014-12-16 Uop Llc Dehydrocyclodimerization using UZM-39 aluminosilicate zeolite
US8921634B2 (en) 2012-12-12 2014-12-30 Uop Llc Conversion of methane to aromatic compounds using UZM-44 aluminosilicate zeolite
US9005573B2 (en) 2011-12-22 2015-04-14 Uop Llc Layered conversion synthesis of zeolites

Families Citing this family (73)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR2752567B1 (fr) * 1996-08-23 1998-10-16 Inst Francais Du Petrole Zeolithe nu-88, son procede de preparation et ses applications catalytiques
FR2758810B1 (fr) * 1997-01-24 1999-02-19 Inst Francais Du Petrole Zeolithe im-5 desaluminee
FR2758817B1 (fr) * 1997-01-24 1999-09-03 Inst Francais Du Petrole Procede de craquage de charges hydrocarbonees a l'aide d'un catalyseur comprenant une zeolithe im-5 eventuellement desaluminee
FR2769919B1 (fr) * 1997-10-16 1999-12-24 Inst Francais Du Petrole Procede pour l'amelioration du point d'ecoulement de charges paraffiniques avec un catalyseur a base de zeolithe im-5
ES2155761B1 (es) * 1998-12-22 2001-12-01 Univ Valencia Politecnica Zeolita itq-7.
FR2790001B1 (fr) * 1999-02-24 2001-04-27 Inst Francais Du Petrole Procede d'hydrocraquage avec un catalyseur comprenant une zeolithe im-5 et catalyseur comprenant une zeolithe im-5 et un element promoteur
NL1014299C2 (nl) 1999-02-24 2001-03-26 Inst Francais Du Petrole Werkwijze voor hydrokraken met een katalysator, die een zeoliet IM-5 bevat en katalysator, die een zeoliet IM-5 en een promotor-element bevat.
FR2790002B1 (fr) * 1999-02-24 2003-10-24 Inst Francais Du Petrole Procede d'hydrocraquage de charges hydrocarbonees en presence d'un catalyseur comprenant une zeolithe im-5 et un element du groupe vb
FR2794116B1 (fr) * 1999-05-11 2001-07-20 Inst Francais Du Petrole Zeolithe im-5 au phosphore, composition catalytique, sa preparation et son utilisation en craquage catalytique
ES2160497B1 (es) * 1999-06-17 2002-07-01 Univ Valencia Politecnica Catalizador para la eliminacion de oxidos de nitrogeno en presencia de oxigeno.
KR20040014433A (ko) * 2000-12-08 2004-02-14 엑손모빌 케미칼 패턴츠 인코포레이티드 결정성 분자 체
US6544495B1 (en) * 2001-07-13 2003-04-08 Chevron U.S.A. Inc. Zeolite SSZ-57 composition of matter and synthesis thereof
FR2837489B1 (fr) * 2002-03-20 2004-06-18 Inst Francais Du Petrole Solide cristallise im-6 de type metallophosphate et son procede de preparation
ES2208084B1 (es) * 2002-05-23 2005-10-01 Universidad Politecnica De Valencia Material cristalino microporoso de naturaleza zeolitica (zeolita itq-22), su metodo de sintesis y su uso como catalizador.
RU2328445C2 (ru) * 2002-05-23 2008-07-10 Консехо Супериор Де Инвестигасьонес Сьентификас Микропористый кристаллический цеолитный материал (цеолит itq-22), способ его получения и применение в качестве катализатора
ES2214141B1 (es) * 2003-02-14 2005-12-01 Universidad Politecnica De Valencia Uso de zeolita itq-22 en procesos de craqueo catalitico de compuestos organicos.
ATE469864T1 (de) * 2002-05-23 2010-06-15 Consejo Superior Investigacion Mikroporöses kristallines zeolithmaterial (zeolith itq-22), syntheseverfahren dafür und verwendung davon als katalysator
ES2217980B1 (es) * 2003-04-30 2005-12-16 Universidad Politecnica De Valencia Procedimiento para la alquilacion de compuestos aromaticos.
FR2852024B1 (fr) * 2003-03-05 2005-04-15 Inst Francais Du Petrole Solide cristallise im-10 et son procede de preparation
FR2858334B1 (fr) * 2003-07-30 2005-09-02 Inst Francais Du Petrole Solide cristallise im-11 de type structural lta et son procede de preparation
US7125821B2 (en) * 2003-09-05 2006-10-24 Exxonmobil Chemical Patents Inc. Low metal content catalyst compositions and processes for making and using same
FR2860224B1 (fr) * 2003-09-26 2006-06-02 Inst Francais Du Petrole Solide cristallise im-12 et son procede de preparation
US7615143B2 (en) * 2004-07-30 2009-11-10 Exxonmobil Chemical Patents Inc. Hydrothermally stable catalyst and its use in catalytic cracking
FR2877665B1 (fr) * 2004-11-09 2006-12-29 Inst Francais Du Petrole Procede de transalkylation d'hydrocarbures alkylaromatiques mis en oeuvre dans deux zones reactionnelles
US7108843B2 (en) * 2004-12-23 2006-09-19 Chevron U.S.A. Inc. Molecular sieve SSZ-70 composition of matter and synthesis thereof
AU2005322503B2 (en) * 2004-12-23 2011-05-26 Chevron U.S.A. Inc. Molecular sieve SSZ-70 composition of matter and synthesis thereof
US7083767B2 (en) * 2004-12-23 2006-08-01 Chevron U.S. A. Inc. Reduction of oxides of nitrogen in a gas stream using molecular sieve SSZ-70
US7084304B2 (en) * 2004-12-23 2006-08-01 Chevron U.S.A. Inc. Acylation using molecular sieve SSZ-70
US7084305B2 (en) * 2004-12-23 2006-08-01 Chevron U.S.A. Inc. Partial oxidation using molecular sieve SSZ-70
ES2820232T3 (es) * 2005-12-28 2021-04-20 Chevron Usa Inc Composición de materia de tamiz molecular SSZ-74
FR2908127B1 (fr) * 2006-11-07 2009-02-06 Inst Francais Du Petrole Solide cristallise im-15 et son procede de preparation
FR2922546B1 (fr) 2007-10-22 2010-02-12 Inst Francais Du Petrole Utilisation d'un catalyseur a base d'im-5 pour la transformation d'alcools ayant au moins deux atomes de carbone en base carburants diesel
US7651677B1 (en) * 2008-09-12 2010-01-26 Exxonmobil Research And Engineering Co. Method of preparing SSZ-74
FR2940266B1 (fr) * 2008-12-18 2010-12-31 Inst Francais Du Petrole Solide cristallise im-20 et son procede de preparation
CA2693582A1 (en) * 2009-02-27 2010-08-27 Chevron U.S.A. Inc. Synthesis of molecular sieve ssz-74 using a hydroxide-mediated gel
CN102040460B (zh) * 2009-10-22 2014-08-20 中国石油化工股份有限公司 一种甲苯甲醇甲基化反应的方法
CN102205251B (zh) * 2010-03-31 2014-01-15 中国石油化工股份有限公司 一种p-im-5分子筛及其在甲苯烷基化反应中的应用
FR2959749B1 (fr) 2010-05-06 2012-06-01 Inst Francais Du Petrole Procede flexible de transformation de l'ethanol en distillats moyens.
CN102452666B (zh) * 2010-10-21 2013-06-26 中国石油化工股份有限公司 一种合成im-5分子筛的方法
CN102452667B (zh) * 2010-10-21 2014-12-03 中国石油化工股份有限公司 一种复合模板剂合成im-5分子筛的方法
CA2844120C (en) 2011-08-04 2019-07-02 Exxonmobil Chemical Patents Inc. Emm-23 molecular sieve material, its synthesis and use
RU2601462C2 (ru) * 2011-08-19 2016-11-10 Эксонмобил Кемикэл Пейтентс Инк. Молекулярное сито емм-22, его синтез и применение
CN103101927B (zh) * 2011-11-10 2014-12-31 中国石油化工股份有限公司 一种im-5分子筛纤维及其合成方法
CN103101926B (zh) 2011-11-10 2014-10-15 中国石油化工股份有限公司 一种空心球形im-5分子筛及其制备方法
CN103101928B (zh) * 2011-11-10 2015-04-01 中国石油化工股份有限公司 一种超细纳米im-5分子筛及其合成方法
CN103693654B (zh) * 2012-09-28 2018-07-31 中国石油化工股份有限公司 一种合成im-5分子筛的方法
CN103708491B (zh) * 2012-09-28 2015-07-29 中国石油化工股份有限公司 合成im-5分子筛的方法
CN104117385B (zh) * 2013-04-28 2016-12-28 中国石油化工股份有限公司 一种改性im‑5分子筛及催化剂和应用
CN104710264B (zh) * 2013-12-16 2017-03-01 中国石油化工股份有限公司 一种液相法稀乙烯制乙苯的方法
JP6661615B2 (ja) * 2014-09-03 2020-03-11 エクソンモービル リサーチ アンド エンジニアリング カンパニーＥｘｘｏｎ Ｒｅｓｅａｒｃｈ Ａｎｄ Ｅｎｇｉｎｅｅｒｉｎｇ Ｃｏｍｐａｎｙ 新規合成結晶材料のｅｍｍ−２６、その調製、およびその使用
CN106391099B (zh) * 2015-07-31 2019-03-22 中国石油化工股份有限公司 一种烷基化催化剂及其应用
CN106391100B (zh) * 2015-07-31 2019-03-22 中国石油化工股份有限公司 一种改性im-5分子筛及其制备方法和应用
CN106397092B (zh) * 2015-07-31 2019-07-19 中国石油化工股份有限公司 一种烷基化方法
CN106608638B (zh) * 2015-10-26 2019-04-16 中国石油化工股份有限公司 一种制备多级孔y型分子筛的方法
CN107020145B (zh) * 2016-01-29 2020-11-13 中国石油化工股份有限公司 一种介孔im-5分子筛及制备方法
US10737945B2 (en) 2016-04-27 2020-08-11 China Petroleum & Chemical Corporation Molecular sieve, its preparation and application thereof
CN107311199B (zh) * 2016-04-27 2019-11-15 中国石油化工股份有限公司 一种分子筛的制造方法及其产品和产品的应用
CN107413376B (zh) * 2016-05-24 2020-06-16 中国石油化工股份有限公司 甲醇芳构化催化剂及制备方法与应用
CN107999118B (zh) * 2016-10-28 2021-08-06 中国石油化工股份有限公司 一种芳烃和合成气烷基化催化剂及其制备方法与应用
CN109592697B (zh) * 2017-09-30 2022-07-12 中国石油化工股份有限公司 Im-5分子筛及其合成方法
CN112090443B (zh) * 2019-06-17 2023-03-10 中国石油化工股份有限公司 加氢脱氧催化剂及其应用和环己烷的制备方法
FR3097856B1 (fr) * 2019-06-28 2022-01-07 Ifp Energies Now Solide cristallise izm-5 et son procede de preparation
JP7417711B2 (ja) * 2019-07-29 2024-01-18 シェブロン ユー．エス．エー． インコーポレイテッド モレキュラーシーブｓｓｚ－１１８及びその合成と使用
US12037255B2 (en) * 2019-08-27 2024-07-16 ExxonMobil Technology and Engineering Company Zeolite syntheses using diquaternary structure directing agents
CN112679298B (zh) * 2019-10-18 2022-12-13 中国石油化工股份有限公司 含乙烯的反应气气相法制乙苯的方法
US11084766B1 (en) 2020-02-18 2021-08-10 Uop Llc Toluene disproportionation using an enhanced UZM-39 aluminosilicate zeolite
CN111795985A (zh) * 2020-07-03 2020-10-20 青海西钢特殊钢科技开发有限公司 一种炼钢用铝线中钛元素含量测定方法
FR3135264B1 (fr) 2022-05-06 2026-01-09 Totalenergies Onetech Procédé de fabrication d’un carburéacteur, carburéacteur et installation associés
FR3135263B1 (fr) 2022-05-06 2026-01-09 Totalenergies Onetech Procédé de fabrication d’un carburéacteur comprenant une étape de conversion d’un flux d’alcool dans un lit fluidisé, carburéacteur et installation associés
FR3135265B1 (fr) 2022-05-06 2026-01-09 Totalenergies Onetech Procédé d’obtention d’hydrocarbures, et installation associée
CN115364890B (zh) * 2022-08-29 2024-03-19 中国石油大学(北京) 一种负载型甲烷热催化裂解催化剂及其制备方法与应用
CN117800357B (zh) * 2024-01-05 2024-08-23 陕西探微日新化工有限公司 一种im-5分子筛合成方法及改性方法
WO2026088973A1 (ja) * 2024-10-22 2026-04-30 三井化学株式会社 変性アルミノシリケートの製造方法および芳香族ポリヒドロキシド化合物の製造方法

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US4941963A (en) * 1989-08-30 1990-07-17 Mobil Oil Corp. Synthesis of crystalline ZSM-11 structure
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Cited By (15)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US8633344B2 (en) 2011-12-22 2014-01-21 Uop Llc Aromatic transformation using UZM-39 aluminosilicate zeolite
US9005573B2 (en) 2011-12-22 2015-04-14 Uop Llc Layered conversion synthesis of zeolites
US8992885B2 (en) 2011-12-22 2015-03-31 Uop Llc UZM-39 aluminosilicate zeolite
US8642823B2 (en) 2011-12-22 2014-02-04 Uop Llc UZM-39 aluminosilicate zeolite
US8623321B1 (en) 2012-12-12 2014-01-07 Uop Llc UZM-44 aluminosilicate zeolite
US8618343B1 (en) 2012-12-12 2013-12-31 Uop Llc Aromatic transalkylation using UZM-39 aluminosilicate zeolite
US8609910B1 (en) 2012-12-12 2013-12-17 Uop Llc Catalytic pyrolysis using UZM-39 aluminosilicate zeolite
US8609911B1 (en) 2012-12-12 2013-12-17 Uop Llc Catalytic pyrolysis using UZM-44 aluminosilicate zeolite
US8609920B1 (en) 2012-12-12 2013-12-17 Uop Llc UZM-44 aluminosilicate zeolite
US8889939B2 (en) 2012-12-12 2014-11-18 Uop Llc Dehydrocyclodimerization using UZM-44 aluminosilicate zeolite
US8907151B2 (en) 2012-12-12 2014-12-09 Uop Llc Conversion of methane to aromatic compounds using UZM-39 aluminosilicate zeolite
US8912378B2 (en) 2012-12-12 2014-12-16 Uop Llc Dehydrocyclodimerization using UZM-39 aluminosilicate zeolite
US8921634B2 (en) 2012-12-12 2014-12-30 Uop Llc Conversion of methane to aromatic compounds using UZM-44 aluminosilicate zeolite
US8609919B1 (en) 2012-12-12 2013-12-17 Uop Llc Aromatic transformation using UZM-44 aluminosilicate zeolite
US8609921B1 (en) 2012-12-12 2013-12-17 Uop Llc Aromatic transalkylation using UZM-44 aluminosilicate zeolite

Also Published As

Publication number Publication date
EP0946416B1 (fr) 2002-02-20
CA2268803A1 (fr) 1998-04-30
KR20000052636A (ko) 2000-08-25
FR2754809A1 (fr) 1998-04-24
BR9712417A (pt) 1999-10-26
WO1998017581A1 (fr) 1998-04-30
FR2754809B1 (fr) 2003-04-04
JP2001502652A (ja) 2001-02-27
DE69710612D1 (de) 2002-03-28
EP0946416A1 (fr) 1999-10-06
US6136290A (en) 2000-10-24
JP4348651B2 (ja) 2009-10-21
AU4872297A (en) 1998-05-15
CN1234012A (zh) 1999-11-03

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