JP4348651B2 - ゼオライトｉｍ―５、その調製方法およびその触媒的適用 - Google Patents
ゼオライトｉｍ―５、その調製方法およびその触媒的適用 Download PDFInfo
- Publication number
- JP4348651B2 JP4348651B2 JP51903598A JP51903598A JP4348651B2 JP 4348651 B2 JP4348651 B2 JP 4348651B2 JP 51903598 A JP51903598 A JP 51903598A JP 51903598 A JP51903598 A JP 51903598A JP 4348651 B2 JP4348651 B2 JP 4348651B2
- Authority
- JP
- Japan
- Prior art keywords
- zeolite
- group
- cation
- oxide
- catalyst
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Fee Related
Links
- 238000002360 preparation method Methods 0.000 title claims description 12
- 230000003197 catalytic effect Effects 0.000 title description 9
- HNPSIPDUKPIQMN-UHFFFAOYSA-N dioxosilane;oxo(oxoalumanyloxy)alumane Chemical compound O=[Si]=O.O=[Al]O[Al]=O HNPSIPDUKPIQMN-UHFFFAOYSA-N 0.000 claims description 136
- 239000010457 zeolite Substances 0.000 claims description 136
- 229910021536 Zeolite Inorganic materials 0.000 claims description 130
- 239000003054 catalyst Substances 0.000 claims description 68
- 239000000203 mixture Substances 0.000 claims description 62
- -1 alkali metal cation Chemical class 0.000 claims description 38
- 229910052751 metal Inorganic materials 0.000 claims description 35
- 239000002184 metal Substances 0.000 claims description 35
- 238000000034 method Methods 0.000 claims description 32
- 150000001768 cations Chemical class 0.000 claims description 29
- 229910052782 aluminium Inorganic materials 0.000 claims description 28
- 229910052710 silicon Inorganic materials 0.000 claims description 24
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 claims description 23
- 238000002441 X-ray diffraction Methods 0.000 claims description 22
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 claims description 20
- QGZKDVFQNNGYKY-UHFFFAOYSA-O Ammonium Chemical compound [NH4+] QGZKDVFQNNGYKY-UHFFFAOYSA-O 0.000 claims description 18
- 239000001257 hydrogen Substances 0.000 claims description 17
- 229910052739 hydrogen Inorganic materials 0.000 claims description 17
- 239000010703 silicon Substances 0.000 claims description 17
- 230000008569 process Effects 0.000 claims description 15
- 239000000126 substance Substances 0.000 claims description 15
- 229910052733 gallium Inorganic materials 0.000 claims description 14
- 150000002430 hydrocarbons Chemical class 0.000 claims description 14
- 239000002243 precursor Substances 0.000 claims description 14
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 claims description 13
- 229910052796 boron Inorganic materials 0.000 claims description 13
- 229930195733 hydrocarbon Natural products 0.000 claims description 13
- 229910052742 iron Inorganic materials 0.000 claims description 13
- GYHNNYVSQQEPJS-UHFFFAOYSA-N Gallium Chemical compound [Ga] GYHNNYVSQQEPJS-UHFFFAOYSA-N 0.000 claims description 11
- 239000002253 acid Substances 0.000 claims description 11
- 238000001354 calcination Methods 0.000 claims description 11
- 238000005336 cracking Methods 0.000 claims description 11
- 229910052697 platinum Inorganic materials 0.000 claims description 11
- 229910052702 rhenium Inorganic materials 0.000 claims description 11
- ZOXJGFHDIHLPTG-UHFFFAOYSA-N Boron Chemical compound [B] ZOXJGFHDIHLPTG-UHFFFAOYSA-N 0.000 claims description 10
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 claims description 10
- 229910052783 alkali metal Inorganic materials 0.000 claims description 10
- 238000000354 decomposition reaction Methods 0.000 claims description 10
- 229910052732 germanium Inorganic materials 0.000 claims description 10
- GNPVGFCGXDBREM-UHFFFAOYSA-N germanium atom Chemical compound [Ge] GNPVGFCGXDBREM-UHFFFAOYSA-N 0.000 claims description 10
- 229910052759 nickel Inorganic materials 0.000 claims description 10
- 229910052719 titanium Inorganic materials 0.000 claims description 10
- 239000010936 titanium Substances 0.000 claims description 10
- 229910052763 palladium Inorganic materials 0.000 claims description 9
- 150000003839 salts Chemical class 0.000 claims description 9
- 239000004215 Carbon black (E152) Substances 0.000 claims description 8
- 150000001875 compounds Chemical class 0.000 claims description 8
- 239000013078 crystal Substances 0.000 claims description 8
- 229910052718 tin Inorganic materials 0.000 claims description 7
- 229910001413 alkali metal ion Inorganic materials 0.000 claims description 6
- 150000001450 anions Chemical class 0.000 claims description 6
- 239000010949 copper Substances 0.000 claims description 6
- 229910052745 lead Inorganic materials 0.000 claims description 6
- 229910052703 rhodium Inorganic materials 0.000 claims description 6
- MZRGYDBVTPYSJS-UHFFFAOYSA-N 1-methylpyrrolidine pentane hydrobromide Chemical compound [Br-].CCCCC.C[NH+]1CCCC1 MZRGYDBVTPYSJS-UHFFFAOYSA-N 0.000 claims description 5
- 229910052802 copper Inorganic materials 0.000 claims description 5
- 229910052787 antimony Inorganic materials 0.000 claims description 4
- 229910052804 chromium Inorganic materials 0.000 claims description 4
- 125000004435 hydrogen atom Chemical group [H]* 0.000 claims description 4
- 229910052750 molybdenum Inorganic materials 0.000 claims description 4
- 230000000737 periodic effect Effects 0.000 claims description 4
- 229910052720 vanadium Inorganic materials 0.000 claims description 4
- 229910052725 zinc Inorganic materials 0.000 claims description 4
- 150000001340 alkali metals Chemical class 0.000 claims description 3
- 239000011230 binding agent Substances 0.000 claims description 3
- 229910052793 cadmium Inorganic materials 0.000 claims description 3
- 229910052791 calcium Inorganic materials 0.000 claims description 3
- 229910052749 magnesium Inorganic materials 0.000 claims description 3
- 229910052748 manganese Inorganic materials 0.000 claims description 3
- 238000010899 nucleation Methods 0.000 claims description 3
- 230000006911 nucleation Effects 0.000 claims description 3
- 229910052698 phosphorus Inorganic materials 0.000 claims description 3
- 229910052709 silver Inorganic materials 0.000 claims description 3
- 229910052712 strontium Inorganic materials 0.000 claims description 3
- 229910052721 tungsten Inorganic materials 0.000 claims description 3
- 239000012736 aqueous medium Substances 0.000 claims description 2
- AVFZOVWCLRSYKC-UHFFFAOYSA-N 1-methylpyrrolidine Chemical compound CN1CCCC1 AVFZOVWCLRSYKC-UHFFFAOYSA-N 0.000 claims 2
- 230000015556 catabolic process Effects 0.000 claims 1
- 238000006731 degradation reaction Methods 0.000 claims 1
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 51
- 238000006243 chemical reaction Methods 0.000 description 30
- 239000000377 silicon dioxide Substances 0.000 description 25
- 238000005342 ion exchange Methods 0.000 description 23
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 description 21
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 description 19
- 239000000047 product Substances 0.000 description 19
- 238000006317 isomerization reaction Methods 0.000 description 18
- 230000015572 biosynthetic process Effects 0.000 description 17
- 238000005984 hydrogenation reaction Methods 0.000 description 17
- 239000011159 matrix material Substances 0.000 description 17
- 238000003786 synthesis reaction Methods 0.000 description 16
- 238000006356 dehydrogenation reaction Methods 0.000 description 15
- 239000007789 gas Substances 0.000 description 14
- CTQNGGLPUBDAKN-UHFFFAOYSA-N O-Xylene Chemical compound CC1=CC=CC=C1C CTQNGGLPUBDAKN-UHFFFAOYSA-N 0.000 description 13
- 239000008096 xylene Substances 0.000 description 13
- YNQLUTRBYVCPMQ-UHFFFAOYSA-N Ethylbenzene Chemical compound CCC1=CC=CC=C1 YNQLUTRBYVCPMQ-UHFFFAOYSA-N 0.000 description 12
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 12
- BASFCYQUMIYNBI-UHFFFAOYSA-N platinum Substances [Pt] BASFCYQUMIYNBI-UHFFFAOYSA-N 0.000 description 12
- 239000000463 material Substances 0.000 description 11
- 239000003085 diluting agent Substances 0.000 description 10
- 239000012071 phase Substances 0.000 description 10
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 10
- 229910001868 water Inorganic materials 0.000 description 10
- 229910052593 corundum Inorganic materials 0.000 description 9
- 238000010586 diagram Methods 0.000 description 9
- 229910001845 yogo sapphire Inorganic materials 0.000 description 9
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 8
- UAEPNZWRGJTJPN-UHFFFAOYSA-N methylcyclohexane Chemical compound CC1CCCCC1 UAEPNZWRGJTJPN-UHFFFAOYSA-N 0.000 description 8
- 239000011734 sodium Substances 0.000 description 8
- 238000003756 stirring Methods 0.000 description 8
- RWRDLPDLKQPQOW-UHFFFAOYSA-N tetrahydropyrrole Natural products C1CCNC1 RWRDLPDLKQPQOW-UHFFFAOYSA-N 0.000 description 8
- 229910052681 coesite Inorganic materials 0.000 description 7
- 229910052906 cristobalite Inorganic materials 0.000 description 7
- 238000001035 drying Methods 0.000 description 7
- 239000000243 solution Substances 0.000 description 7
- 229910052682 stishovite Inorganic materials 0.000 description 7
- 229910052905 tridymite Inorganic materials 0.000 description 7
- UHOVQNZJYSORNB-UHFFFAOYSA-N Benzene Chemical compound C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 description 6
- KKCBUQHMOMHUOY-UHFFFAOYSA-N Na2O Inorganic materials [O-2].[Na+].[Na+] KKCBUQHMOMHUOY-UHFFFAOYSA-N 0.000 description 6
- 239000000499 gel Substances 0.000 description 6
- 239000007791 liquid phase Substances 0.000 description 6
- 150000002739 metals Chemical class 0.000 description 6
- 239000000843 powder Substances 0.000 description 6
- 229910052708 sodium Inorganic materials 0.000 description 6
- 150000001336 alkenes Chemical class 0.000 description 5
- 238000005804 alkylation reaction Methods 0.000 description 5
- 125000003118 aryl group Chemical group 0.000 description 5
- 238000007323 disproportionation reaction Methods 0.000 description 5
- 238000005470 impregnation Methods 0.000 description 5
- 229910044991 metal oxide Inorganic materials 0.000 description 5
- 150000004706 metal oxides Chemical class 0.000 description 5
- 239000002808 molecular sieve Substances 0.000 description 5
- 150000002894 organic compounds Chemical class 0.000 description 5
- URGAHOPLAPQHLN-UHFFFAOYSA-N sodium aluminosilicate Chemical compound [Na+].[Al+3].[O-][Si]([O-])=O.[O-][Si]([O-])=O URGAHOPLAPQHLN-UHFFFAOYSA-N 0.000 description 5
- 238000005406 washing Methods 0.000 description 5
- 230000029936 alkylation Effects 0.000 description 4
- ANBBXQWFNXMHLD-UHFFFAOYSA-N aluminum;sodium;oxygen(2-) Chemical compound [O-2].[O-2].[Na+].[Al+3] ANBBXQWFNXMHLD-UHFFFAOYSA-N 0.000 description 4
- 238000004458 analytical method Methods 0.000 description 4
- 238000001636 atomic emission spectroscopy Methods 0.000 description 4
- 238000001914 filtration Methods 0.000 description 4
- 238000004519 manufacturing process Methods 0.000 description 4
- GYNNXHKOJHMOHS-UHFFFAOYSA-N methyl-cycloheptane Natural products CC1CCCCCC1 GYNNXHKOJHMOHS-UHFFFAOYSA-N 0.000 description 4
- 229910052757 nitrogen Inorganic materials 0.000 description 4
- 229920001343 polytetrafluoroethylene Polymers 0.000 description 4
- 239000004810 polytetrafluoroethylene Substances 0.000 description 4
- 229910001388 sodium aluminate Inorganic materials 0.000 description 4
- JHJLBTNAGRQEKS-UHFFFAOYSA-M sodium bromide Chemical compound [Na+].[Br-] JHJLBTNAGRQEKS-UHFFFAOYSA-M 0.000 description 4
- 239000011343 solid material Substances 0.000 description 4
- 230000003595 spectral effect Effects 0.000 description 4
- 238000010555 transalkylation reaction Methods 0.000 description 4
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical group OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 3
- 229910000323 aluminium silicate Inorganic materials 0.000 description 3
- 150000001491 aromatic compounds Chemical class 0.000 description 3
- 238000004523 catalytic cracking Methods 0.000 description 3
- 239000011651 chromium Substances 0.000 description 3
- 238000002425 crystallisation Methods 0.000 description 3
- 230000008025 crystallization Effects 0.000 description 3
- 230000018044 dehydration Effects 0.000 description 3
- 238000006297 dehydration reaction Methods 0.000 description 3
- 150000002431 hydrogen Chemical class 0.000 description 3
- 150000002736 metal compounds Chemical class 0.000 description 3
- JRZJOMJEPLMPRA-UHFFFAOYSA-N olefin Natural products CCCCCCCC=C JRZJOMJEPLMPRA-UHFFFAOYSA-N 0.000 description 3
- 239000012188 paraffin wax Substances 0.000 description 3
- 230000005855 radiation Effects 0.000 description 3
- 239000007787 solid Substances 0.000 description 3
- 230000000153 supplemental effect Effects 0.000 description 3
- 238000011282 treatment Methods 0.000 description 3
- 239000011701 zinc Substances 0.000 description 3
- FYGHSUNMUKGBRK-UHFFFAOYSA-N 1,2,3-trimethylbenzene Chemical compound CC1=CC=CC(C)=C1C FYGHSUNMUKGBRK-UHFFFAOYSA-N 0.000 description 2
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 description 2
- NLXLAEXVIDQMFP-UHFFFAOYSA-N Ammonia chloride Chemical compound [NH4+].[Cl-] NLXLAEXVIDQMFP-UHFFFAOYSA-N 0.000 description 2
- CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 description 2
- VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 description 2
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 2
- XDTMQSROBMDMFD-UHFFFAOYSA-N Cyclohexane Chemical compound C1CCCCC1 XDTMQSROBMDMFD-UHFFFAOYSA-N 0.000 description 2
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 2
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 description 2
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 2
- 229910002651 NO3 Inorganic materials 0.000 description 2
- NHNBFGGVMKEFGY-UHFFFAOYSA-N Nitrate Chemical compound [O-][N+]([O-])=O NHNBFGGVMKEFGY-UHFFFAOYSA-N 0.000 description 2
- MWUXSHHQAYIFBG-UHFFFAOYSA-N Nitric oxide Chemical compound O=[N] MWUXSHHQAYIFBG-UHFFFAOYSA-N 0.000 description 2
- ATUOYWHBWRKTHZ-UHFFFAOYSA-N Propane Chemical compound CCC ATUOYWHBWRKTHZ-UHFFFAOYSA-N 0.000 description 2
- QQONPFPTGQHPMA-UHFFFAOYSA-N Propene Chemical compound CC=C QQONPFPTGQHPMA-UHFFFAOYSA-N 0.000 description 2
- QAOWNCQODCNURD-UHFFFAOYSA-L Sulfate Chemical compound [O-]S([O-])(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-L 0.000 description 2
- 239000000654 additive Substances 0.000 description 2
- 230000000996 additive effect Effects 0.000 description 2
- 239000000443 aerosol Substances 0.000 description 2
- 150000001335 aliphatic alkanes Chemical class 0.000 description 2
- 229910000272 alkali metal oxide Inorganic materials 0.000 description 2
- 150000004996 alkyl benzenes Chemical class 0.000 description 2
- AZDRQVAHHNSJOQ-UHFFFAOYSA-N alumane Chemical class [AlH3] AZDRQVAHHNSJOQ-UHFFFAOYSA-N 0.000 description 2
- 238000005899 aromatization reaction Methods 0.000 description 2
- 238000004364 calculation method Methods 0.000 description 2
- 238000004517 catalytic hydrocracking Methods 0.000 description 2
- 238000006555 catalytic reaction Methods 0.000 description 2
- 238000005341 cation exchange Methods 0.000 description 2
- RWGFKTVRMDUZSP-UHFFFAOYSA-N cumene Chemical compound CC(C)C1=CC=CC=C1 RWGFKTVRMDUZSP-UHFFFAOYSA-N 0.000 description 2
- 238000004090 dissolution Methods 0.000 description 2
- 150000002170 ethers Chemical group 0.000 description 2
- 239000012530 fluid Substances 0.000 description 2
- 239000008240 homogeneous mixture Substances 0.000 description 2
- 239000011572 manganese Substances 0.000 description 2
- 239000002609 medium Substances 0.000 description 2
- 239000008188 pellet Substances 0.000 description 2
- 239000011148 porous material Substances 0.000 description 2
- 239000000376 reactant Substances 0.000 description 2
- 230000009467 reduction Effects 0.000 description 2
- 229920006395 saturated elastomer Polymers 0.000 description 2
- 238000000926 separation method Methods 0.000 description 2
- 239000008247 solid mixture Substances 0.000 description 2
- 239000007790 solid phase Substances 0.000 description 2
- 238000001179 sorption measurement Methods 0.000 description 2
- 230000003068 static effect Effects 0.000 description 2
- VXNZUUAINFGPBY-UHFFFAOYSA-N 1-Butene Chemical compound CCC=C VXNZUUAINFGPBY-UHFFFAOYSA-N 0.000 description 1
- HYFLWBNQFMXCPA-UHFFFAOYSA-N 1-ethyl-2-methylbenzene Chemical compound CCC1=CC=CC=C1C HYFLWBNQFMXCPA-UHFFFAOYSA-N 0.000 description 1
- XXZFCJVFXKCILB-UHFFFAOYSA-N 1-methylpyrrolidine;hydrobromide Chemical compound [Br-].C[NH+]1CCCC1 XXZFCJVFXKCILB-UHFFFAOYSA-N 0.000 description 1
- FMCTUGXDLWLZFX-UHFFFAOYSA-N 1-methylpyrrolidine;pentane Chemical compound CCCCC.CN1CCCC1 FMCTUGXDLWLZFX-UHFFFAOYSA-N 0.000 description 1
- QTBSBXVTEAMEQO-UHFFFAOYSA-M Acetate Chemical compound CC([O-])=O QTBSBXVTEAMEQO-UHFFFAOYSA-M 0.000 description 1
- CPELXLSAUQHCOX-UHFFFAOYSA-M Bromide Chemical compound [Br-] CPELXLSAUQHCOX-UHFFFAOYSA-M 0.000 description 1
- JJMMCPGHZJMTQM-UHFFFAOYSA-N CCCCCC.CN1CCCC1 Chemical compound CCCCCC.CN1CCCC1 JJMMCPGHZJMTQM-UHFFFAOYSA-N 0.000 description 1
- VYZAMTAEIAYCRO-UHFFFAOYSA-N Chromium Chemical compound [Cr] VYZAMTAEIAYCRO-UHFFFAOYSA-N 0.000 description 1
- KRKNYBCHXYNGOX-UHFFFAOYSA-K Citrate Chemical compound [O-]C(=O)CC(O)(CC([O-])=O)C([O-])=O KRKNYBCHXYNGOX-UHFFFAOYSA-K 0.000 description 1
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 1
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 description 1
- ZOKXTWBITQBERF-UHFFFAOYSA-N Molybdenum Chemical compound [Mo] ZOKXTWBITQBERF-UHFFFAOYSA-N 0.000 description 1
- UFWIBTONFRDIAS-UHFFFAOYSA-N Naphthalene Chemical compound C1=CC=CC2=CC=CC=C21 UFWIBTONFRDIAS-UHFFFAOYSA-N 0.000 description 1
- 229910019142 PO4 Inorganic materials 0.000 description 1
- 239000004113 Sepiolite Substances 0.000 description 1
- 229910004298 SiO 2 Inorganic materials 0.000 description 1
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 description 1
- ATJFFYVFTNAWJD-UHFFFAOYSA-N Tin Chemical group [Sn] ATJFFYVFTNAWJD-UHFFFAOYSA-N 0.000 description 1
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 description 1
- QCWXUUIWCKQGHC-UHFFFAOYSA-N Zirconium Chemical compound [Zr] QCWXUUIWCKQGHC-UHFFFAOYSA-N 0.000 description 1
- MCMNRKCIXSYSNV-UHFFFAOYSA-N ZrO2 Inorganic materials O=[Zr]=O MCMNRKCIXSYSNV-UHFFFAOYSA-N 0.000 description 1
- 150000007513 acids Chemical class 0.000 description 1
- 230000009471 action Effects 0.000 description 1
- 230000004913 activation Effects 0.000 description 1
- 239000004964 aerogel Substances 0.000 description 1
- 150000001298 alcohols Chemical class 0.000 description 1
- 150000001338 aliphatic hydrocarbons Chemical class 0.000 description 1
- 239000003513 alkali Substances 0.000 description 1
- 150000008044 alkali metal hydroxides Chemical class 0.000 description 1
- 229910052910 alkali metal silicate Inorganic materials 0.000 description 1
- VXAUWWUXCIMFIM-UHFFFAOYSA-M aluminum;oxygen(2-);hydroxide Chemical compound [OH-].[O-2].[Al+3] VXAUWWUXCIMFIM-UHFFFAOYSA-M 0.000 description 1
- 150000001412 amines Chemical class 0.000 description 1
- 235000019270 ammonium chloride Nutrition 0.000 description 1
- 150000003868 ammonium compounds Chemical class 0.000 description 1
- 235000011114 ammonium hydroxide Nutrition 0.000 description 1
- 150000003863 ammonium salts Chemical class 0.000 description 1
- WATWJIUSRGPENY-UHFFFAOYSA-N antimony atom Chemical compound [Sb] WATWJIUSRGPENY-UHFFFAOYSA-N 0.000 description 1
- 150000004945 aromatic hydrocarbons Chemical class 0.000 description 1
- 229910052785 arsenic Inorganic materials 0.000 description 1
- RQNWIZPPADIBDY-UHFFFAOYSA-N arsenic atom Chemical compound [As] RQNWIZPPADIBDY-UHFFFAOYSA-N 0.000 description 1
- 229960000892 attapulgite Drugs 0.000 description 1
- 239000002585 base Substances 0.000 description 1
- 239000000440 bentonite Substances 0.000 description 1
- 229910000278 bentonite Inorganic materials 0.000 description 1
- SVPXDRXYRYOSEX-UHFFFAOYSA-N bentoquatam Chemical compound O.O=[Si]=O.O=[Al]O[Al]=O SVPXDRXYRYOSEX-UHFFFAOYSA-N 0.000 description 1
- 229910052797 bismuth Chemical group 0.000 description 1
- JCXGWMGPZLAOME-UHFFFAOYSA-N bismuth atom Chemical group [Bi] JCXGWMGPZLAOME-UHFFFAOYSA-N 0.000 description 1
- 150000003842 bromide salts Chemical class 0.000 description 1
- 239000001273 butane Substances 0.000 description 1
- IAQRGUVFOMOMEM-UHFFFAOYSA-N butene Natural products CC=CC IAQRGUVFOMOMEM-UHFFFAOYSA-N 0.000 description 1
- 125000004432 carbon atom Chemical group C* 0.000 description 1
- 229910002092 carbon dioxide Inorganic materials 0.000 description 1
- 239000001569 carbon dioxide Substances 0.000 description 1
- 239000007795 chemical reaction product Substances 0.000 description 1
- 150000003841 chloride salts Chemical class 0.000 description 1
- 239000004927 clay Substances 0.000 description 1
- 239000008119 colloidal silica Substances 0.000 description 1
- 230000009849 deactivation Effects 0.000 description 1
- 239000007857 degradation product Substances 0.000 description 1
- GUJOJGAPFQRJSV-UHFFFAOYSA-N dialuminum;dioxosilane;oxygen(2-);hydrate Chemical compound O.[O-2].[O-2].[O-2].[Al+3].[Al+3].O=[Si]=O.O=[Si]=O.O=[Si]=O.O=[Si]=O GUJOJGAPFQRJSV-UHFFFAOYSA-N 0.000 description 1
- 238000011156 evaluation Methods 0.000 description 1
- 230000001747 exhibiting effect Effects 0.000 description 1
- 125000000524 functional group Chemical group 0.000 description 1
- 239000008125 glucin Substances 0.000 description 1
- 239000008187 granular material Substances 0.000 description 1
- 238000000227 grinding Methods 0.000 description 1
- 230000026030 halogenation Effects 0.000 description 1
- 238000005658 halogenation reaction Methods 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- 229910052734 helium Inorganic materials 0.000 description 1
- 239000001307 helium Substances 0.000 description 1
- SWQJXJOGLNCZEY-UHFFFAOYSA-N helium atom Chemical compound [He] SWQJXJOGLNCZEY-UHFFFAOYSA-N 0.000 description 1
- XMBWDFGMSWQBCA-UHFFFAOYSA-N hydrogen iodide Chemical compound I XMBWDFGMSWQBCA-UHFFFAOYSA-N 0.000 description 1
- GPRLSGONYQIRFK-UHFFFAOYSA-N hydron Chemical compound [H+] GPRLSGONYQIRFK-UHFFFAOYSA-N 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-M hydroxide Chemical compound [OH-] XLYOFNOQVPJJNP-UHFFFAOYSA-M 0.000 description 1
- 150000004679 hydroxides Chemical class 0.000 description 1
- 239000012535 impurity Substances 0.000 description 1
- 239000003701 inert diluent Substances 0.000 description 1
- 239000011261 inert gas Substances 0.000 description 1
- 229910010272 inorganic material Inorganic materials 0.000 description 1
- 239000011147 inorganic material Substances 0.000 description 1
- 150000002500 ions Chemical class 0.000 description 1
- WPBNNNQJVZRUHP-UHFFFAOYSA-L manganese(2+);methyl n-[[2-(methoxycarbonylcarbamothioylamino)phenyl]carbamothioyl]carbamate;n-[2-(sulfidocarbothioylamino)ethyl]carbamodithioate Chemical compound [Mn+2].[S-]C(=S)NCCNC([S-])=S.COC(=O)NC(=S)NC1=CC=CC=C1NC(=S)NC(=O)OC WPBNNNQJVZRUHP-UHFFFAOYSA-L 0.000 description 1
- VUZPPFZMUPKLLV-UHFFFAOYSA-N methane;hydrate Chemical compound C.O VUZPPFZMUPKLLV-UHFFFAOYSA-N 0.000 description 1
- 230000011987 methylation Effects 0.000 description 1
- 238000007069 methylation reaction Methods 0.000 description 1
- 150000007522 mineralic acids Chemical class 0.000 description 1
- 238000002156 mixing Methods 0.000 description 1
- 239000011733 molybdenum Substances 0.000 description 1
- 229910052901 montmorillonite Inorganic materials 0.000 description 1
- IJDNQMDRQITEOD-UHFFFAOYSA-N n-butane Chemical compound CCCC IJDNQMDRQITEOD-UHFFFAOYSA-N 0.000 description 1
- OFBQJSOFQDEBGM-UHFFFAOYSA-N n-pentane Natural products CCCCC OFBQJSOFQDEBGM-UHFFFAOYSA-N 0.000 description 1
- 229910017464 nitrogen compound Inorganic materials 0.000 description 1
- 150000002830 nitrogen compounds Chemical class 0.000 description 1
- 229910000510 noble metal Inorganic materials 0.000 description 1
- 229910052755 nonmetal Inorganic materials 0.000 description 1
- 238000006384 oligomerization reaction Methods 0.000 description 1
- 150000007524 organic acids Chemical group 0.000 description 1
- 150000002892 organic cations Chemical class 0.000 description 1
- 239000011368 organic material Substances 0.000 description 1
- 230000003647 oxidation Effects 0.000 description 1
- 238000007254 oxidation reaction Methods 0.000 description 1
- 229910052625 palygorskite Inorganic materials 0.000 description 1
- 239000002245 particle Substances 0.000 description 1
- NBIIXXVUZAFLBC-UHFFFAOYSA-K phosphate Chemical compound [O-]P([O-])([O-])=O NBIIXXVUZAFLBC-UHFFFAOYSA-K 0.000 description 1
- 239000010452 phosphate Substances 0.000 description 1
- 239000000049 pigment Substances 0.000 description 1
- 238000001556 precipitation Methods 0.000 description 1
- 239000001294 propane Substances 0.000 description 1
- 230000001698 pyrogenic effect Effects 0.000 description 1
- 125000001453 quaternary ammonium group Chemical group 0.000 description 1
- 239000011541 reaction mixture Substances 0.000 description 1
- 230000003014 reinforcing effect Effects 0.000 description 1
- 238000007363 ring formation reaction Methods 0.000 description 1
- 229910052707 ruthenium Inorganic materials 0.000 description 1
- 239000012266 salt solution Substances 0.000 description 1
- 229910052624 sepiolite Inorganic materials 0.000 description 1
- 235000019355 sepiolite Nutrition 0.000 description 1
- 150000004760 silicates Chemical class 0.000 description 1
- RMAQACBXLXPBSY-UHFFFAOYSA-N silicic acid Chemical compound O[Si](O)(O)O RMAQACBXLXPBSY-UHFFFAOYSA-N 0.000 description 1
- 235000012239 silicon dioxide Nutrition 0.000 description 1
- 229920002379 silicone rubber Polymers 0.000 description 1
- NTHWMYGWWRZVTN-UHFFFAOYSA-N sodium silicate Chemical compound [Na+].[Na+].[O-][Si]([O-])=O NTHWMYGWWRZVTN-UHFFFAOYSA-N 0.000 description 1
- 229910052717 sulfur Inorganic materials 0.000 description 1
- 239000011593 sulfur Substances 0.000 description 1
- 230000001629 suppression Effects 0.000 description 1
- 239000000725 suspension Substances 0.000 description 1
- 239000004408 titanium dioxide Substances 0.000 description 1
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N titanium dioxide Inorganic materials O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 description 1
- 150000004684 trihydrates Chemical class 0.000 description 1
- GPPXJZIENCGNKB-UHFFFAOYSA-N vanadium Chemical compound [V]#[V] GPPXJZIENCGNKB-UHFFFAOYSA-N 0.000 description 1
- 229910052726 zirconium Inorganic materials 0.000 description 1
Images
Classifications
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G49/00—Treatment of hydrocarbon oils, in the presence of hydrogen or hydrogen-generating compounds, not provided for in a single one of groups C10G45/02, C10G45/32, C10G45/44, C10G45/58 or C10G47/00
- C10G49/02—Treatment of hydrocarbon oils, in the presence of hydrogen or hydrogen-generating compounds, not provided for in a single one of groups C10G45/02, C10G45/32, C10G45/44, C10G45/58 or C10G47/00 characterised by the catalyst used
- C10G49/08—Treatment of hydrocarbon oils, in the presence of hydrogen or hydrogen-generating compounds, not provided for in a single one of groups C10G45/02, C10G45/32, C10G45/44, C10G45/58 or C10G47/00 characterised by the catalyst used containing crystalline alumino-silicates, e.g. molecular sieves
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J29/00—Catalysts comprising molecular sieves
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J29/00—Catalysts comprising molecular sieves
- B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B39/00—Compounds having molecular sieve and base-exchange properties, e.g. crystalline zeolites; Their preparation; After-treatment, e.g. ion-exchange or dealumination
- C01B39/02—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof; Direct preparation thereof; Preparation thereof starting from a reaction mixture containing a crystalline zeolite of another type, or from preformed reactants; After-treatment thereof
- C01B39/46—Other types characterised by their X-ray diffraction pattern and their defined composition
- C01B39/48—Other types characterised by their X-ray diffraction pattern and their defined composition using at least one organic template directing agent
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Life Sciences & Earth Sciences (AREA)
- Materials Engineering (AREA)
- Life Sciences & Earth Sciences (AREA)
- Geology (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Crystallography & Structural Chemistry (AREA)
- Inorganic Chemistry (AREA)
- General Chemical & Material Sciences (AREA)
- Silicates, Zeolites, And Molecular Sieves (AREA)
- Catalysts (AREA)
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| FR96/12873 | 1996-10-21 | ||
| FR9612873A FR2754809B1 (fr) | 1996-10-21 | 1996-10-21 | Zeolithe im-5, son procede de preparation et ses applications catalytiques |
| PCT/FR1997/001868 WO1998017581A1 (fr) | 1996-10-21 | 1997-10-17 | Zeolithe im-5, son procede de preparation et ses applications catalytiques |
Publications (3)
| Publication Number | Publication Date |
|---|---|
| JP2001502652A JP2001502652A (ja) | 2001-02-27 |
| JP2001502652A5 JP2001502652A5 (enExample) | 2005-06-16 |
| JP4348651B2 true JP4348651B2 (ja) | 2009-10-21 |
Family
ID=9496909
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP51903598A Expired - Fee Related JP4348651B2 (ja) | 1996-10-21 | 1997-10-17 | ゼオライトｉｍ―５、その調製方法およびその触媒的適用 |
Country Status (11)
| Country | Link |
|---|---|
| US (1) | US6136290A (enExample) |
| EP (1) | EP0946416B1 (enExample) |
| JP (1) | JP4348651B2 (enExample) |
| KR (1) | KR20000052636A (enExample) |
| CN (1) | CN1234012A (enExample) |
| AU (1) | AU4872297A (enExample) |
| BR (1) | BR9712417A (enExample) |
| CA (1) | CA2268803A1 (enExample) |
| DE (1) | DE69710612T2 (enExample) |
| FR (1) | FR2754809B1 (enExample) |
| WO (1) | WO1998017581A1 (enExample) |
Families Citing this family (85)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| FR2752567B1 (fr) * | 1996-08-23 | 1998-10-16 | Inst Francais Du Petrole | Zeolithe nu-88, son procede de preparation et ses applications catalytiques |
| FR2758817B1 (fr) * | 1997-01-24 | 1999-09-03 | Inst Francais Du Petrole | Procede de craquage de charges hydrocarbonees a l'aide d'un catalyseur comprenant une zeolithe im-5 eventuellement desaluminee |
| FR2758810B1 (fr) * | 1997-01-24 | 1999-02-19 | Inst Francais Du Petrole | Zeolithe im-5 desaluminee |
| FR2769919B1 (fr) * | 1997-10-16 | 1999-12-24 | Inst Francais Du Petrole | Procede pour l'amelioration du point d'ecoulement de charges paraffiniques avec un catalyseur a base de zeolithe im-5 |
| ES2155761B1 (es) * | 1998-12-22 | 2001-12-01 | Univ Valencia Politecnica | Zeolita itq-7. |
| FR2790002B1 (fr) * | 1999-02-24 | 2003-10-24 | Inst Francais Du Petrole | Procede d'hydrocraquage de charges hydrocarbonees en presence d'un catalyseur comprenant une zeolithe im-5 et un element du groupe vb |
| FR2790001B1 (fr) * | 1999-02-24 | 2001-04-27 | Inst Francais Du Petrole | Procede d'hydrocraquage avec un catalyseur comprenant une zeolithe im-5 et catalyseur comprenant une zeolithe im-5 et un element promoteur |
| NL1014299C2 (nl) * | 1999-02-24 | 2001-03-26 | Inst Francais Du Petrole | Werkwijze voor hydrokraken met een katalysator, die een zeoliet IM-5 bevat en katalysator, die een zeoliet IM-5 en een promotor-element bevat. |
| FR2794116B1 (fr) * | 1999-05-11 | 2001-07-20 | Inst Francais Du Petrole | Zeolithe im-5 au phosphore, composition catalytique, sa preparation et son utilisation en craquage catalytique |
| ES2160497B1 (es) * | 1999-06-17 | 2002-07-01 | Univ Valencia Politecnica | Catalizador para la eliminacion de oxidos de nitrogeno en presencia de oxigeno. |
| ATE390387T1 (de) * | 2000-12-08 | 2008-04-15 | Exxonmobil Chem Patents Inc | Kristalline molekularsiebe |
| US6544495B1 (en) * | 2001-07-13 | 2003-04-08 | Chevron U.S.A. Inc. | Zeolite SSZ-57 composition of matter and synthesis thereof |
| FR2837489B1 (fr) * | 2002-03-20 | 2004-06-18 | Inst Francais Du Petrole | Solide cristallise im-6 de type metallophosphate et son procede de preparation |
| ES2208084B1 (es) * | 2002-05-23 | 2005-10-01 | Universidad Politecnica De Valencia | Material cristalino microporoso de naturaleza zeolitica (zeolita itq-22), su metodo de sintesis y su uso como catalizador. |
| ES2214141B1 (es) * | 2003-02-14 | 2005-12-01 | Universidad Politecnica De Valencia | Uso de zeolita itq-22 en procesos de craqueo catalitico de compuestos organicos. |
| ES2217980B1 (es) * | 2003-04-30 | 2005-12-16 | Universidad Politecnica De Valencia | Procedimiento para la alquilacion de compuestos aromaticos. |
| EP1514844B1 (en) * | 2002-05-23 | 2010-06-02 | Consejo Superior De Investigaciones Cientificas | Microporous crystalline zeolite material (zeolite itq-22), synthesis method thereof and use of same as a catalyst |
| RU2328445C2 (ru) * | 2002-05-23 | 2008-07-10 | Консехо Супериор Де Инвестигасьонес Сьентификас | Микропористый кристаллический цеолитный материал (цеолит itq-22), способ его получения и применение в качестве катализатора |
| FR2852024B1 (fr) * | 2003-03-05 | 2005-04-15 | Inst Francais Du Petrole | Solide cristallise im-10 et son procede de preparation |
| FR2858334B1 (fr) * | 2003-07-30 | 2005-09-02 | Inst Francais Du Petrole | Solide cristallise im-11 de type structural lta et son procede de preparation |
| US7125821B2 (en) * | 2003-09-05 | 2006-10-24 | Exxonmobil Chemical Patents Inc. | Low metal content catalyst compositions and processes for making and using same |
| FR2860224B1 (fr) * | 2003-09-26 | 2006-06-02 | Inst Francais Du Petrole | Solide cristallise im-12 et son procede de preparation |
| US7615143B2 (en) * | 2004-07-30 | 2009-11-10 | Exxonmobil Chemical Patents Inc. | Hydrothermally stable catalyst and its use in catalytic cracking |
| FR2877665B1 (fr) * | 2004-11-09 | 2006-12-29 | Inst Francais Du Petrole | Procede de transalkylation d'hydrocarbures alkylaromatiques mis en oeuvre dans deux zones reactionnelles |
| US7084304B2 (en) * | 2004-12-23 | 2006-08-01 | Chevron U.S.A. Inc. | Acylation using molecular sieve SSZ-70 |
| US7108843B2 (en) * | 2004-12-23 | 2006-09-19 | Chevron U.S.A. Inc. | Molecular sieve SSZ-70 composition of matter and synthesis thereof |
| US7084305B2 (en) * | 2004-12-23 | 2006-08-01 | Chevron U.S.A. Inc. | Partial oxidation using molecular sieve SSZ-70 |
| US7083767B2 (en) * | 2004-12-23 | 2006-08-01 | Chevron U.S. A. Inc. | Reduction of oxides of nitrogen in a gas stream using molecular sieve SSZ-70 |
| KR101237446B1 (ko) * | 2004-12-23 | 2013-02-26 | 셰브런 유.에스.에이.인크. | 분자체 ｓｓｚ-70 조성물 및 이의 합성 |
| JP5475289B2 (ja) * | 2005-12-28 | 2014-04-16 | シェブロン ユー．エス．エー． インコーポレイテッド | 分子ふるいｓｓｚ−７４組成物及びその合成 |
| FR2908127B1 (fr) * | 2006-11-07 | 2009-02-06 | Inst Francais Du Petrole | Solide cristallise im-15 et son procede de preparation |
| FR2922546B1 (fr) * | 2007-10-22 | 2010-02-12 | Inst Francais Du Petrole | Utilisation d'un catalyseur a base d'im-5 pour la transformation d'alcools ayant au moins deux atomes de carbone en base carburants diesel |
| US7651677B1 (en) * | 2008-09-12 | 2010-01-26 | Exxonmobil Research And Engineering Co. | Method of preparing SSZ-74 |
| FR2940266B1 (fr) * | 2008-12-18 | 2010-12-31 | Inst Francais Du Petrole | Solide cristallise im-20 et son procede de preparation |
| CA2693582A1 (en) * | 2009-02-27 | 2010-08-27 | Chevron U.S.A. Inc. | Synthesis of molecular sieve ssz-74 using a hydroxide-mediated gel |
| CN102040460B (zh) * | 2009-10-22 | 2014-08-20 | 中国石油化工股份有限公司 | 一种甲苯甲醇甲基化反应的方法 |
| CN102205251B (zh) * | 2010-03-31 | 2014-01-15 | 中国石油化工股份有限公司 | 一种p-im-5分子筛及其在甲苯烷基化反应中的应用 |
| FR2959749B1 (fr) | 2010-05-06 | 2012-06-01 | Inst Francais Du Petrole | Procede flexible de transformation de l'ethanol en distillats moyens. |
| CN102452667B (zh) * | 2010-10-21 | 2014-12-03 | 中国石油化工股份有限公司 | 一种复合模板剂合成im-5分子筛的方法 |
| CN102452666B (zh) * | 2010-10-21 | 2013-06-26 | 中国石油化工股份有限公司 | 一种合成im-5分子筛的方法 |
| KR101923248B1 (ko) * | 2011-08-04 | 2018-11-28 | 엑손모빌 케미칼 패턴츠 인코포레이티드 | Emm-23 분자체 물질, 그의 합성 및 용도 |
| WO2013028303A1 (en) * | 2011-08-19 | 2013-02-28 | Exxonmobil Chemical Patents Inc. | Emm-22 molecular sieve material, its synthesis and use |
| CN103101927B (zh) | 2011-11-10 | 2014-12-31 | 中国石油化工股份有限公司 | 一种im-5分子筛纤维及其合成方法 |
| CN103101928B (zh) * | 2011-11-10 | 2015-04-01 | 中国石油化工股份有限公司 | 一种超细纳米im-5分子筛及其合成方法 |
| CN103101926B (zh) * | 2011-11-10 | 2014-10-15 | 中国石油化工股份有限公司 | 一种空心球形im-5分子筛及其制备方法 |
| SG11201402970RA (en) * | 2011-12-22 | 2014-11-27 | Uop Llc | Uzm-39 aluminosilicate zeolite |
| JP2015515429A (ja) | 2011-12-22 | 2015-05-28 | ユーオーピー エルエルシー | ゼオライトの層状転化合成 |
| JP5852749B2 (ja) | 2011-12-22 | 2016-02-03 | ユーオーピー エルエルシー | Ｕｚｍ−３９アルミノシリケートゼオライトを用いた芳香族化合物の転化反応 |
| CN103693654B (zh) * | 2012-09-28 | 2018-07-31 | 中国石油化工股份有限公司 | 一种合成im-5分子筛的方法 |
| CN103708491B (zh) * | 2012-09-28 | 2015-07-29 | 中国石油化工股份有限公司 | 合成im-5分子筛的方法 |
| US8609921B1 (en) * | 2012-12-12 | 2013-12-17 | Uop Llc | Aromatic transalkylation using UZM-44 aluminosilicate zeolite |
| WO2014093416A1 (en) | 2012-12-12 | 2014-06-19 | Uop Llc | Dehydrocyclodimerization using uzm-39 aluminosilicate zeolite |
| WO2014093461A1 (en) | 2012-12-12 | 2014-06-19 | Uop Llc | Conversion of methane to aromatic compounds using uzm-39 aluminosilicate zeolite |
| US8618343B1 (en) | 2012-12-12 | 2013-12-31 | Uop Llc | Aromatic transalkylation using UZM-39 aluminosilicate zeolite |
| WO2014093440A1 (en) | 2012-12-12 | 2014-06-19 | Uop Llc | Conversion of methane to aromatic compounds using uzm-44 aluminosilicate zeolite |
| US8609910B1 (en) | 2012-12-12 | 2013-12-17 | Uop Llc | Catalytic pyrolysis using UZM-39 aluminosilicate zeolite |
| US8889939B2 (en) | 2012-12-12 | 2014-11-18 | Uop Llc | Dehydrocyclodimerization using UZM-44 aluminosilicate zeolite |
| US8609911B1 (en) | 2012-12-12 | 2013-12-17 | Uop Llc | Catalytic pyrolysis using UZM-44 aluminosilicate zeolite |
| US8609920B1 (en) * | 2012-12-12 | 2013-12-17 | Uop Llc | UZM-44 aluminosilicate zeolite |
| US8609919B1 (en) | 2012-12-12 | 2013-12-17 | Uop Llc | Aromatic transformation using UZM-44 aluminosilicate zeolite |
| CN104117385B (zh) * | 2013-04-28 | 2016-12-28 | 中国石油化工股份有限公司 | 一种改性im‑5分子筛及催化剂和应用 |
| CN104710264B (zh) * | 2013-12-16 | 2017-03-01 | 中国石油化工股份有限公司 | 一种液相法稀乙烯制乙苯的方法 |
| US10464817B2 (en) | 2014-09-03 | 2019-11-05 | Exxonmobil Research And Engineering Company | EMM-26, a novel synthetic crystalline material, its preparation, and its use |
| CN106391100B (zh) * | 2015-07-31 | 2019-03-22 | 中国石油化工股份有限公司 | 一种改性im-5分子筛及其制备方法和应用 |
| CN106391099B (zh) * | 2015-07-31 | 2019-03-22 | 中国石油化工股份有限公司 | 一种烷基化催化剂及其应用 |
| CN106397092B (zh) * | 2015-07-31 | 2019-07-19 | 中国石油化工股份有限公司 | 一种烷基化方法 |
| CN106608638B (zh) * | 2015-10-26 | 2019-04-16 | 中国石油化工股份有限公司 | 一种制备多级孔y型分子筛的方法 |
| CN107020145B (zh) * | 2016-01-29 | 2020-11-13 | 中国石油化工股份有限公司 | 一种介孔im-5分子筛及制备方法 |
| US10737945B2 (en) | 2016-04-27 | 2020-08-11 | China Petroleum & Chemical Corporation | Molecular sieve, its preparation and application thereof |
| CN107311190B (zh) * | 2016-04-27 | 2020-06-16 | 中国石油化工股份有限公司 | 一种分子筛、其制造方法及其应用 |
| CN107413376B (zh) * | 2016-05-24 | 2020-06-16 | 中国石油化工股份有限公司 | 甲醇芳构化催化剂及制备方法与应用 |
| CN107999118B (zh) * | 2016-10-28 | 2021-08-06 | 中国石油化工股份有限公司 | 一种芳烃和合成气烷基化催化剂及其制备方法与应用 |
| CN109592697B (zh) * | 2017-09-30 | 2022-07-12 | 中国石油化工股份有限公司 | Im-5分子筛及其合成方法 |
| CN112090443B (zh) * | 2019-06-17 | 2023-03-10 | 中国石油化工股份有限公司 | 加氢脱氧催化剂及其应用和环己烷的制备方法 |
| FR3097856B1 (fr) * | 2019-06-28 | 2022-01-07 | Ifp Energies Now | Solide cristallise izm-5 et son procede de preparation |
| US10822243B1 (en) * | 2019-07-29 | 2020-11-03 | Chevron U.S.A. Inc. | Molecular sieve SSZ-118, its synthesis and use |
| EP4021850A1 (en) * | 2019-08-27 | 2022-07-06 | ExxonMobil Technology and Engineering Company | Zeolite syntheses using diquaternary structure directing agents |
| CN112679298B (zh) * | 2019-10-18 | 2022-12-13 | 中国石油化工股份有限公司 | 含乙烯的反应气气相法制乙苯的方法 |
| US11084766B1 (en) | 2020-02-18 | 2021-08-10 | Uop Llc | Toluene disproportionation using an enhanced UZM-39 aluminosilicate zeolite |
| CN111795985A (zh) * | 2020-07-03 | 2020-10-20 | 青海西钢特殊钢科技开发有限公司 | 一种炼钢用铝线中钛元素含量测定方法 |
| FR3135264A1 (fr) | 2022-05-06 | 2023-11-10 | Totalenergies Onetech | Procédé de fabrication d’un carburéacteur, carburéacteur et installation associés |
| FR3135263A1 (fr) | 2022-05-06 | 2023-11-10 | Totalenergies Onetech | Procédé de fabrication d’un carburéacteur comprenant une étape de conversion d’un flux d’alcool dans un lit fluidisé, carburéacteur et installation associés |
| FR3135265A1 (fr) | 2022-05-06 | 2023-11-10 | Totalenergies Onetech | Procédé d’obtention d’hydrocarbures, et installation associée |
| CN115364890B (zh) * | 2022-08-29 | 2024-03-19 | 中国石油大学(北京) | 一种负载型甲烷热催化裂解催化剂及其制备方法与应用 |
| CN117800357B (zh) * | 2024-01-05 | 2024-08-23 | 陕西探微日新化工有限公司 | 一种im-5分子筛合成方法及改性方法 |
Family Cites Families (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4557919A (en) * | 1983-04-12 | 1985-12-10 | Teijin Petrochemical Industries Ltd. | Production of crystalline zeolites |
| US4941963A (en) * | 1989-08-30 | 1990-07-17 | Mobil Oil Corp. | Synthesis of crystalline ZSM-11 structure |
| US5068096A (en) * | 1991-04-08 | 1991-11-26 | Mobil Oil Corporation | Synthesis of crystalline silicate MCM-47 |
-
1996
- 1996-10-21 FR FR9612873A patent/FR2754809B1/fr not_active Expired - Fee Related
-
1997
- 1997-10-17 DE DE69710612T patent/DE69710612T2/de not_active Expired - Lifetime
- 1997-10-17 CN CN97199011A patent/CN1234012A/zh active Pending
- 1997-10-17 AU AU48722/97A patent/AU4872297A/en not_active Abandoned
- 1997-10-17 EP EP97911293A patent/EP0946416B1/fr not_active Expired - Lifetime
- 1997-10-17 JP JP51903598A patent/JP4348651B2/ja not_active Expired - Fee Related
- 1997-10-17 WO PCT/FR1997/001868 patent/WO1998017581A1/fr not_active Ceased
- 1997-10-17 CA CA002268803A patent/CA2268803A1/fr not_active Abandoned
- 1997-10-17 BR BR9712417-6A patent/BR9712417A/pt not_active Application Discontinuation
- 1997-10-17 KR KR1019990703399A patent/KR20000052636A/ko not_active Withdrawn
- 1997-10-21 US US08/955,117 patent/US6136290A/en not_active Expired - Lifetime
Also Published As
| Publication number | Publication date |
|---|---|
| FR2754809B1 (fr) | 2003-04-04 |
| JP2001502652A (ja) | 2001-02-27 |
| EP0946416A1 (fr) | 1999-10-06 |
| KR20000052636A (ko) | 2000-08-25 |
| EP0946416B1 (fr) | 2002-02-20 |
| FR2754809A1 (fr) | 1998-04-24 |
| WO1998017581A1 (fr) | 1998-04-30 |
| BR9712417A (pt) | 1999-10-26 |
| US6136290A (en) | 2000-10-24 |
| AU4872297A (en) | 1998-05-15 |
| DE69710612T2 (de) | 2002-11-28 |
| CA2268803A1 (fr) | 1998-04-30 |
| DE69710612D1 (de) | 2002-03-28 |
| CN1234012A (zh) | 1999-11-03 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| JP4348651B2 (ja) | ゼオライトｉｍ―５、その調製方法およびその触媒的適用 | |
| JP4135121B2 (ja) | ゼオライトｎｕ−８８、その調製方法およびその触媒としての使用 | |
| JP4595105B2 (ja) | 構造化剤の前駆体を用いるｅｕｏ構造型ゼオライトの調製方法およびｃ８芳香族化合物の異性化触媒としてのその使用 | |
| KR0144466B1 (ko) | 제올 라이트를 사용한 촉매반응 | |
| KR100195902B1 (ko) | 제올라이트 | |
| US4537754A (en) | Zeolite EU-1 and a method of making zeolite EU-1 | |
| JP4595106B2 (ja) | ゼオライト材料種を用いるｅｕｏ型構造を有するゼオライトの調製方法およびａｃ８異性化触媒としてのその使用 | |
| EP0054386B1 (en) | Zeolites | |
| US4876412A (en) | Zeolite EU-2 | |
| CA1098104A (en) | Silica-containing material and manufacture of hydrocarbons catalysed thereby | |
| GB2077709A (en) | Zeolite EU-2 | |
| KR100734335B1 (ko) | Ｅｕｏ 구조 유형의 제올라이트를 제조하는 방법, 이방법에 따라 제조된 제올라이트 및 ｃ8 방향족 화합물을이성질화시키는 촉매로서 상기 제올라이트의 용도 | |
| JPS623090B2 (enExample) | ||
| JPH0576453B2 (enExample) | ||
| EP0526252B1 (en) | Zeolite-type material | |
| JP4928678B2 (ja) | 低いＳｉ／Ａｌ比を有するＥＵＯ構造型ゼオライトおよびＣ８−芳香族留分の異性化用触媒としてのその使用 | |
| KR101258717B1 (ko) | Ｎ,ｎ-디메틸-ｎ,ｎ-디(3,3-디메틸부틸)암모늄 양이온을함유하는 ｅｕｏ 구조형 제올라이트 및 이의 제조 방법 | |
| MXPA97006330A (en) | Zeolita nu-88, procedure for its preparation and its applications cataliti | |
| MXPA99003438A (en) | Im-5 zeolite, method of preparation and catalytic applications thereof |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| A521 | Request for written amendment filed |
Free format text: JAPANESE INTERMEDIATE CODE: A523 Effective date: 20041014 |
|
| A621 | Written request for application examination |
Free format text: JAPANESE INTERMEDIATE CODE: A621 Effective date: 20041014 |
|
| A131 | Notification of reasons for refusal |
Free format text: JAPANESE INTERMEDIATE CODE: A131 Effective date: 20080115 |
|
| A521 | Request for written amendment filed |
Free format text: JAPANESE INTERMEDIATE CODE: A523 Effective date: 20080410 |
|
| A02 | Decision of refusal |
Free format text: JAPANESE INTERMEDIATE CODE: A02 Effective date: 20081202 |
|
| A521 | Request for written amendment filed |
Free format text: JAPANESE INTERMEDIATE CODE: A523 Effective date: 20090312 |
|
| A521 | Request for written amendment filed |
Free format text: JAPANESE INTERMEDIATE CODE: A523 Effective date: 20090422 |
|
| A521 | Request for written amendment filed |
Free format text: JAPANESE INTERMEDIATE CODE: A523 Effective date: 20090410 |
|
| A911 | Transfer to examiner for re-examination before appeal (zenchi) |
Free format text: JAPANESE INTERMEDIATE CODE: A911 Effective date: 20090528 |
|
| TRDD | Decision of grant or rejection written | ||
| A01 | Written decision to grant a patent or to grant a registration (utility model) |
Free format text: JAPANESE INTERMEDIATE CODE: A01 Effective date: 20090609 |
|
| A01 | Written decision to grant a patent or to grant a registration (utility model) |
Free format text: JAPANESE INTERMEDIATE CODE: A01 |
|
| A61 | First payment of annual fees (during grant procedure) |
Free format text: JAPANESE INTERMEDIATE CODE: A61 Effective date: 20090709 |
|
| FPAY | Renewal fee payment (event date is renewal date of database) |
Free format text: PAYMENT UNTIL: 20120731 Year of fee payment: 3 |
|
| R150 | Certificate of patent or registration of utility model |
Free format text: JAPANESE INTERMEDIATE CODE: R150 |
|
| FPAY | Renewal fee payment (event date is renewal date of database) |
Free format text: PAYMENT UNTIL: 20120731 Year of fee payment: 3 |
|
| FPAY | Renewal fee payment (event date is renewal date of database) |
Free format text: PAYMENT UNTIL: 20130731 Year of fee payment: 4 |
|
| R250 | Receipt of annual fees |
Free format text: JAPANESE INTERMEDIATE CODE: R250 |
|
| R250 | Receipt of annual fees |
Free format text: JAPANESE INTERMEDIATE CODE: R250 |
|
| LAPS | Cancellation because of no payment of annual fees |