DE69212722T2 - Verfahren zur Pfropfpolymerisation von Vinylmonomeren auf olefinischen Polymerteilchen - Google Patents
Verfahren zur Pfropfpolymerisation von Vinylmonomeren auf olefinischen PolymerteilchenInfo
- Publication number
- DE69212722T2 DE69212722T2 DE69212722T DE69212722T DE69212722T2 DE 69212722 T2 DE69212722 T2 DE 69212722T2 DE 69212722 T DE69212722 T DE 69212722T DE 69212722 T DE69212722 T DE 69212722T DE 69212722 T2 DE69212722 T2 DE 69212722T2
- Authority
- DE
- Germany
- Prior art keywords
- olefin polymer
- free radical
- particulate
- grafting
- polyolefin
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Fee Related
Links
- 239000000178 monomer Substances 0.000 title claims abstract description 44
- 238000000034 method Methods 0.000 title claims abstract description 29
- 125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 title claims abstract description 13
- 229920002554 vinyl polymer Polymers 0.000 title claims abstract description 13
- 229920000642 polymer Polymers 0.000 title claims abstract description 10
- 239000002245 particle Substances 0.000 title description 9
- 238000010559 graft polymerization reaction Methods 0.000 title description 2
- 229920000098 polyolefin Polymers 0.000 claims abstract description 62
- 150000003254 radicals Chemical class 0.000 claims abstract description 22
- 239000011148 porous material Substances 0.000 claims abstract description 17
- 239000003999 initiator Substances 0.000 claims abstract description 12
- 230000001678 irradiating effect Effects 0.000 claims abstract description 4
- -1 unsaturated cyclic anhydrides Chemical class 0.000 claims description 25
- 150000001336 alkenes Chemical class 0.000 claims description 13
- FPYJFEHAWHCUMM-UHFFFAOYSA-N maleic anhydride Chemical compound O=C1OC(=O)C=C1 FPYJFEHAWHCUMM-UHFFFAOYSA-N 0.000 claims description 13
- JRZJOMJEPLMPRA-UHFFFAOYSA-N olefin Natural products CCCCCCCC=C JRZJOMJEPLMPRA-UHFFFAOYSA-N 0.000 claims description 9
- 229920000578 graft copolymer Polymers 0.000 claims description 7
- 238000000354 decomposition reaction Methods 0.000 claims description 3
- 230000001590 oxidative effect Effects 0.000 claims description 3
- 230000005865 ionizing radiation Effects 0.000 claims description 2
- 238000010526 radical polymerization reaction Methods 0.000 claims description 2
- 150000002894 organic compounds Chemical class 0.000 claims 1
- 229920001112 grafted polyolefin Polymers 0.000 abstract description 2
- 230000005855 radiation Effects 0.000 abstract 1
- 239000002861 polymer material Substances 0.000 description 20
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 description 18
- 239000005977 Ethylene Substances 0.000 description 18
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 15
- 125000004432 carbon atom Chemical group C* 0.000 description 13
- VXNZUUAINFGPBY-UHFFFAOYSA-N ethyl ethylene Natural products CCC=C VXNZUUAINFGPBY-UHFFFAOYSA-N 0.000 description 11
- 229920001155 polypropylene Polymers 0.000 description 10
- 239000004743 Polypropylene Substances 0.000 description 9
- 150000002978 peroxides Chemical class 0.000 description 8
- 229910052757 nitrogen Inorganic materials 0.000 description 7
- 230000015556 catabolic process Effects 0.000 description 6
- 238000006731 degradation reaction Methods 0.000 description 6
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 5
- 238000006243 chemical reaction Methods 0.000 description 5
- 229920001903 high density polyethylene Polymers 0.000 description 5
- 239000004700 high-density polyethylene Substances 0.000 description 5
- 229920001519 homopolymer Polymers 0.000 description 5
- 239000001301 oxygen Substances 0.000 description 5
- 229910052760 oxygen Inorganic materials 0.000 description 5
- 239000000843 powder Substances 0.000 description 5
- 239000000047 product Substances 0.000 description 5
- WSSSPWUEQFSQQG-UHFFFAOYSA-N 4-methyl-1-pentene Chemical compound CC(C)CC=C WSSSPWUEQFSQQG-UHFFFAOYSA-N 0.000 description 4
- 238000004132 cross linking Methods 0.000 description 4
- NNBZCPXTIHJBJL-UHFFFAOYSA-N decalin Chemical compound C1CCCC2CCCCC21 NNBZCPXTIHJBJL-UHFFFAOYSA-N 0.000 description 4
- 229920001971 elastomer Polymers 0.000 description 4
- 239000000463 material Substances 0.000 description 4
- 229920000573 polyethylene Polymers 0.000 description 4
- QQONPFPTGQHPMA-UHFFFAOYSA-N propylene Natural products CC=C QQONPFPTGQHPMA-UHFFFAOYSA-N 0.000 description 4
- 125000004805 propylene group Chemical group [H]C([H])([H])C([H])([*:1])C([H])([H])[*:2] 0.000 description 4
- LIKMAJRDDDTEIG-UHFFFAOYSA-N 1-hexene Chemical compound CCCCC=C LIKMAJRDDDTEIG-UHFFFAOYSA-N 0.000 description 3
- YMWUJEATGCHHMB-UHFFFAOYSA-N Dichloromethane Chemical compound ClCCl YMWUJEATGCHHMB-UHFFFAOYSA-N 0.000 description 3
- 239000004698 Polyethylene Substances 0.000 description 3
- IAQRGUVFOMOMEM-UHFFFAOYSA-N butene Natural products CC=CC IAQRGUVFOMOMEM-UHFFFAOYSA-N 0.000 description 3
- 230000009849 deactivation Effects 0.000 description 3
- 229920001038 ethylene copolymer Polymers 0.000 description 3
- 238000010438 heat treatment Methods 0.000 description 3
- 229920000092 linear low density polyethylene Polymers 0.000 description 3
- 239000004707 linear low-density polyethylene Substances 0.000 description 3
- 239000007788 liquid Substances 0.000 description 3
- 229920001684 low density polyethylene Polymers 0.000 description 3
- 239000004702 low-density polyethylene Substances 0.000 description 3
- 239000000203 mixture Substances 0.000 description 3
- 238000010926 purge Methods 0.000 description 3
- 239000002904 solvent Substances 0.000 description 3
- ZGEGCLOFRBLKSE-UHFFFAOYSA-N 1-Heptene Chemical compound CCCCCC=C ZGEGCLOFRBLKSE-UHFFFAOYSA-N 0.000 description 2
- JAHNSTQSQJOJLO-UHFFFAOYSA-N 2-(3-fluorophenyl)-1h-imidazole Chemical compound FC1=CC=CC(C=2NC=CN=2)=C1 JAHNSTQSQJOJLO-UHFFFAOYSA-N 0.000 description 2
- 229920000181 Ethylene propylene rubber Polymers 0.000 description 2
- VZCYOOQTPOCHFL-OWOJBTEDSA-N Fumaric acid Chemical compound OC(=O)\C=C\C(O)=O VZCYOOQTPOCHFL-OWOJBTEDSA-N 0.000 description 2
- 239000012298 atmosphere Substances 0.000 description 2
- 229920001577 copolymer Polymers 0.000 description 2
- 238000010894 electron beam technology Methods 0.000 description 2
- HQQADJVZYDDRJT-UHFFFAOYSA-N ethene;prop-1-ene Chemical group C=C.CC=C HQQADJVZYDDRJT-UHFFFAOYSA-N 0.000 description 2
- 238000001125 extrusion Methods 0.000 description 2
- 230000014759 maintenance of location Effects 0.000 description 2
- QSHDDOUJBYECFT-UHFFFAOYSA-N mercury Chemical compound [Hg] QSHDDOUJBYECFT-UHFFFAOYSA-N 0.000 description 2
- 229910052753 mercury Inorganic materials 0.000 description 2
- LVHBHZANLOWSRM-UHFFFAOYSA-N methylenebutanedioic acid Natural products OC(=O)CC(=C)C(O)=O LVHBHZANLOWSRM-UHFFFAOYSA-N 0.000 description 2
- YWAKXRMUMFPDSH-UHFFFAOYSA-N pentene Chemical compound CCCC=C YWAKXRMUMFPDSH-UHFFFAOYSA-N 0.000 description 2
- 238000002459 porosimetry Methods 0.000 description 2
- 238000002360 preparation method Methods 0.000 description 2
- 229920001384 propylene homopolymer Polymers 0.000 description 2
- 239000012798 spherical particle Substances 0.000 description 2
- 229920006301 statistical copolymer Polymers 0.000 description 2
- 238000003756 stirring Methods 0.000 description 2
- 229920001897 terpolymer Polymers 0.000 description 2
- VZCYOOQTPOCHFL-UHFFFAOYSA-N trans-butenedioic acid Natural products OC(=O)C=CC(O)=O VZCYOOQTPOCHFL-UHFFFAOYSA-N 0.000 description 2
- 238000009827 uniform distribution Methods 0.000 description 2
- DMWVYCCGCQPJEA-UHFFFAOYSA-N 2,5-bis(tert-butylperoxy)-2,5-dimethylhexane Chemical group CC(C)(C)OOC(C)(C)CCC(C)(C)OOC(C)(C)C DMWVYCCGCQPJEA-UHFFFAOYSA-N 0.000 description 1
- YHQXBTXEYZIYOV-UHFFFAOYSA-N 3-methylbut-1-ene Chemical compound CC(C)C=C YHQXBTXEYZIYOV-UHFFFAOYSA-N 0.000 description 1
- RITONZMLZWYPHW-UHFFFAOYSA-N 3-methylhex-1-ene Chemical compound CCCC(C)C=C RITONZMLZWYPHW-UHFFFAOYSA-N 0.000 description 1
- OFNISBHGPNMTMS-UHFFFAOYSA-N 3-methylideneoxolane-2,5-dione Chemical compound C=C1CC(=O)OC1=O OFNISBHGPNMTMS-UHFFFAOYSA-N 0.000 description 1
- LDTAOIUHUHHCMU-UHFFFAOYSA-N 3-methylpent-1-ene Chemical compound CCC(C)C=C LDTAOIUHUHHCMU-UHFFFAOYSA-N 0.000 description 1
- 239000004215 Carbon black (E152) Substances 0.000 description 1
- OFOBLEOULBTSOW-UHFFFAOYSA-N Propanedioic acid Natural products OC(=O)CC(O)=O OFOBLEOULBTSOW-UHFFFAOYSA-N 0.000 description 1
- 238000010521 absorption reaction Methods 0.000 description 1
- 230000002411 adverse Effects 0.000 description 1
- 238000013019 agitation Methods 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 239000003054 catalyst Substances 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 238000001816 cooling Methods 0.000 description 1
- 150000001993 dienes Chemical class 0.000 description 1
- 229910001873 dinitrogen Inorganic materials 0.000 description 1
- 238000001035 drying Methods 0.000 description 1
- 238000005485 electric heating Methods 0.000 description 1
- 150000002148 esters Chemical class 0.000 description 1
- 239000010419 fine particle Substances 0.000 description 1
- VZCYOOQTPOCHFL-OWOJBTEDSA-L fumarate(2-) Chemical class [O-]C(=O)\C=C\C([O-])=O VZCYOOQTPOCHFL-OWOJBTEDSA-L 0.000 description 1
- 239000001530 fumaric acid Substances 0.000 description 1
- 239000011521 glass Substances 0.000 description 1
- 239000008187 granular material Substances 0.000 description 1
- 229930195733 hydrocarbon Natural products 0.000 description 1
- 150000002430 hydrocarbons Chemical class 0.000 description 1
- 239000004615 ingredient Substances 0.000 description 1
- VZCYOOQTPOCHFL-UPHRSURJSA-N maleic acid Chemical compound OC(=O)\C=C/C(O)=O VZCYOOQTPOCHFL-UPHRSURJSA-N 0.000 description 1
- 239000011976 maleic acid Substances 0.000 description 1
- 150000002688 maleic acid derivatives Chemical class 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 239000012299 nitrogen atmosphere Substances 0.000 description 1
- 239000011236 particulate material Substances 0.000 description 1
- 229920005604 random copolymer Polymers 0.000 description 1
- 239000012265 solid product Substances 0.000 description 1
- WYKYCHHWIJXDAO-UHFFFAOYSA-N tert-butyl 2-ethylhexaneperoxoate Chemical compound CCCCC(CC)C(=O)OOC(C)(C)C WYKYCHHWIJXDAO-UHFFFAOYSA-N 0.000 description 1
- 239000004711 α-olefin Substances 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F255/00—Macromolecular compounds obtained by polymerising monomers on to polymers of hydrocarbons as defined in group C08F10/00
- C08F255/02—Macromolecular compounds obtained by polymerising monomers on to polymers of hydrocarbons as defined in group C08F10/00 on to polymers of olefins having two or three carbon atoms
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F255/00—Macromolecular compounds obtained by polymerising monomers on to polymers of hydrocarbons as defined in group C08F10/00
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Graft Or Block Polymers (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
- Organic Insulating Materials (AREA)
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US71868191A | 1991-06-21 | 1991-06-21 |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| DE69212722D1 DE69212722D1 (de) | 1996-09-19 |
| DE69212722T2 true DE69212722T2 (de) | 1997-01-23 |
Family
ID=24887055
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| DE69212722T Expired - Fee Related DE69212722T2 (de) | 1991-06-21 | 1992-06-12 | Verfahren zur Pfropfpolymerisation von Vinylmonomeren auf olefinischen Polymerteilchen |
Country Status (18)
| Country | Link |
|---|---|
| EP (1) | EP0519341B1 (enExample) |
| JP (1) | JP3202067B2 (enExample) |
| KR (1) | KR100231675B1 (enExample) |
| CN (1) | CN1044375C (enExample) |
| AT (1) | ATE141297T1 (enExample) |
| AU (1) | AU1829692A (enExample) |
| BR (1) | BR9202326A (enExample) |
| CA (1) | CA2071650C (enExample) |
| CZ (2) | CZ287098B6 (enExample) |
| DE (1) | DE69212722T2 (enExample) |
| DK (1) | DK0519341T3 (enExample) |
| FI (1) | FI922878L (enExample) |
| HU (1) | HUT65142A (enExample) |
| IL (1) | IL102166A0 (enExample) |
| MX (1) | MX9203003A (enExample) |
| NO (1) | NO922434L (enExample) |
| TW (1) | TW200495B (enExample) |
| ZA (1) | ZA924249B (enExample) |
Families Citing this family (19)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| IT1260495B (it) * | 1992-05-29 | 1996-04-09 | Himont Inc | Concentrati adatti alla preparazione di poliolefine funzionalizzate e processo di funzionalizzazione mediante detti concentrati |
| US5817707A (en) * | 1996-05-06 | 1998-10-06 | Montell North America Inc. | Process for making propylene graft copolymers using a redox initiator system |
| CN1123613C (zh) * | 1998-12-03 | 2003-10-08 | 中国石化齐鲁石油化工公司 | 高分子热熔粘合剂及其制造方法 |
| EP1038893A1 (en) * | 1999-03-19 | 2000-09-27 | Fina Research S.A. | Production of polypropylene having improved properties |
| KR20010109848A (ko) * | 2000-06-02 | 2001-12-12 | 강경석 | 라디칼 활성화제를 이용한 폴리올레핀 섬유의 기상그라프트 중합방법 |
| EP1170305A1 (en) | 2000-07-05 | 2002-01-09 | ATOFINA Research | Production of polyolefins having improved properties |
| EP1305349A2 (en) | 2000-07-28 | 2003-05-02 | E.I. Dupont De Nemours And Company | Grafting of polyolefins |
| US6518327B1 (en) | 2000-11-02 | 2003-02-11 | Basell Poliolefine Italia S.P.A. | Irradiation process for making olefin graft copolymers with low weight side chains |
| US6444722B1 (en) * | 2000-11-02 | 2002-09-03 | Basell Poliolefine Italia S.P.A. | Making polyolefin graft copolymers with low molecular weight side chains using a polymeric peroxide as an initiator |
| JP4371411B2 (ja) | 2001-08-02 | 2009-11-25 | 旭化成ケミカルズ株式会社 | 焼結体、樹脂粒子及びその製造方法 |
| WO2004078808A2 (en) * | 2003-03-04 | 2004-09-16 | Basell Poliolefine Italia S.R.L. | Polyolefin grafted poly(vinyl alcohol) and process for producing same |
| US7825180B2 (en) | 2005-10-21 | 2010-11-02 | Chemtura Corporation | Thermoplastic blend compositions as soft coupling agents |
| CN100455620C (zh) * | 2006-03-03 | 2009-01-28 | 中国科学院长春应用化学研究所 | 一种功能化聚烯烃长效流滴膜及其制备方法 |
| DE102007011825B3 (de) | 2007-03-12 | 2008-05-15 | Deutsche Gumtec Ag | Verfahren zur Modifizierung von Gummi- und Thermoplastabfällen mittels Pfropfung während eines Mahlprozesses sowie Verwendung der so modifizierten Gummi-und Thermoplastabfälle |
| WO2014069474A1 (ja) | 2012-10-30 | 2014-05-08 | 株式会社クラレ | 多孔質グラフト共重合体粒子、その製造方法及びそれを用いた吸着材 |
| CN103319664B (zh) * | 2013-07-10 | 2015-07-22 | 哈尔滨理工大学 | 马来酸酐固相接枝氯化聚氯乙烯制备方法 |
| JP6192487B2 (ja) * | 2013-10-30 | 2017-09-06 | 株式会社クラレ | 多孔質グラフト共重合体粒子、その製造方法及びそれを用いた吸着材 |
| JP2015155536A (ja) * | 2014-01-20 | 2015-08-27 | 三井化学株式会社 | 酸変性ポリオレフィン粒子及びその製造方法 |
| TWI816395B (zh) | 2021-05-12 | 2023-09-21 | 奧地利商柏列利斯股份公司 | 高熔融強度聚丙烯 |
Family Cites Families (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CA892730A (en) * | 1969-02-21 | 1972-02-08 | Dasgupta Sharda | Inducing dyeability in polypropylene by radiation induced grafting |
| FR2056057A5 (enExample) * | 1969-08-26 | 1971-05-14 | Raffinage Cie Francaise | |
| CA2031406C (en) * | 1989-12-21 | 2002-05-28 | Paolo Galli | Graft copolymers of polyolefins and a method of producing same |
| US5140074A (en) * | 1990-01-26 | 1992-08-18 | Himont Incorporated | Method of producing olefin polymer graft copolymers |
-
1992
- 1992-06-10 ZA ZA924249A patent/ZA924249B/xx unknown
- 1992-06-10 IL IL102166A patent/IL102166A0/xx unknown
- 1992-06-12 EP EP92109898A patent/EP0519341B1/en not_active Expired - Lifetime
- 1992-06-12 DE DE69212722T patent/DE69212722T2/de not_active Expired - Fee Related
- 1992-06-12 AT AT92109898T patent/ATE141297T1/de not_active IP Right Cessation
- 1992-06-12 DK DK92109898.4T patent/DK0519341T3/da active
- 1992-06-16 AU AU18296/92A patent/AU1829692A/en not_active Abandoned
- 1992-06-18 HU HU9202036A patent/HUT65142A/hu unknown
- 1992-06-18 FI FI922878A patent/FI922878L/fi not_active Application Discontinuation
- 1992-06-18 MX MX9203003A patent/MX9203003A/es not_active IP Right Cessation
- 1992-06-19 KR KR1019920010648A patent/KR100231675B1/ko not_active Expired - Lifetime
- 1992-06-19 TW TW081104814A patent/TW200495B/zh active
- 1992-06-19 CZ CS19921908A patent/CZ287098B6/cs not_active IP Right Cessation
- 1992-06-19 JP JP16090392A patent/JP3202067B2/ja not_active Expired - Fee Related
- 1992-06-19 CA CA002071650A patent/CA2071650C/en not_active Expired - Fee Related
- 1992-06-19 NO NO92922434A patent/NO922434L/no unknown
- 1992-06-19 BR BR929202326A patent/BR9202326A/pt not_active IP Right Cessation
- 1992-06-20 CN CN92104910A patent/CN1044375C/zh not_active Expired - Fee Related
-
1999
- 1999-09-08 CZ CZ19993176A patent/CZ286833B6/cs not_active IP Right Cessation
Also Published As
| Publication number | Publication date |
|---|---|
| IL102166A0 (en) | 1993-01-14 |
| KR930000554A (ko) | 1993-01-15 |
| FI922878A0 (fi) | 1992-06-18 |
| CN1069036A (zh) | 1993-02-17 |
| JPH05178943A (ja) | 1993-07-20 |
| DE69212722D1 (de) | 1996-09-19 |
| HU9202036D0 (en) | 1992-09-28 |
| FI922878A7 (fi) | 1992-12-22 |
| ATE141297T1 (de) | 1996-08-15 |
| KR100231675B1 (ko) | 1999-11-15 |
| CZ287098B6 (cs) | 2000-09-13 |
| DK0519341T3 (da) | 1996-09-02 |
| HUT65142A (en) | 1994-04-28 |
| CN1044375C (zh) | 1999-07-28 |
| CZ286833B6 (cs) | 2000-07-12 |
| JP3202067B2 (ja) | 2001-08-27 |
| BR9202326A (pt) | 1993-01-19 |
| CA2071650C (en) | 2003-04-29 |
| CA2071650A1 (en) | 1992-12-22 |
| TW200495B (enExample) | 1993-02-21 |
| MX9203003A (es) | 1993-02-01 |
| CZ190892A3 (en) | 1993-02-17 |
| NO922434L (no) | 1992-12-22 |
| FI922878L (fi) | 1992-12-22 |
| EP0519341B1 (en) | 1996-08-14 |
| ZA924249B (en) | 1993-03-31 |
| EP0519341A1 (en) | 1992-12-23 |
| AU1829692A (en) | 1992-12-24 |
| NO922434D0 (no) | 1992-06-19 |
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