DE68913361T2 - Verfahren zur Herstellung von wasserfreien Natriumsulfidkristallen. - Google Patents
Verfahren zur Herstellung von wasserfreien Natriumsulfidkristallen.Info
- Publication number
- DE68913361T2 DE68913361T2 DE68913361T DE68913361T DE68913361T2 DE 68913361 T2 DE68913361 T2 DE 68913361T2 DE 68913361 T DE68913361 T DE 68913361T DE 68913361 T DE68913361 T DE 68913361T DE 68913361 T2 DE68913361 T2 DE 68913361T2
- Authority
- DE
- Germany
- Prior art keywords
- crystals
- sodium sulfide
- na2s
- torr
- anhydrous sodium
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Fee Related
Links
- GRVFOGOEDUUMBP-UHFFFAOYSA-N sodium sulfide (anhydrous) Chemical compound [Na+].[Na+].[S-2] GRVFOGOEDUUMBP-UHFFFAOYSA-N 0.000 title claims description 73
- 239000013078 crystal Substances 0.000 title claims description 64
- 238000000034 method Methods 0.000 title claims description 16
- 230000008569 process Effects 0.000 title claims description 14
- 238000004519 manufacturing process Methods 0.000 title description 3
- 229910052979 sodium sulfide Inorganic materials 0.000 claims description 44
- 230000007704 transition Effects 0.000 claims description 19
- 150000004682 monohydrates Chemical class 0.000 claims description 15
- 238000010438 heat treatment Methods 0.000 claims description 6
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 27
- 238000003756 stirring Methods 0.000 description 13
- 239000007795 chemical reaction product Substances 0.000 description 10
- 238000002844 melting Methods 0.000 description 8
- 230000008018 melting Effects 0.000 description 8
- 238000006243 chemical reaction Methods 0.000 description 6
- 239000007787 solid Substances 0.000 description 6
- 239000000047 product Substances 0.000 description 5
- 229910001220 stainless steel Inorganic materials 0.000 description 5
- 239000010935 stainless steel Substances 0.000 description 5
- RKTYLMNFRDHKIL-UHFFFAOYSA-N copper;5,10,15,20-tetraphenylporphyrin-22,24-diide Chemical compound [Cu+2].C1=CC(C(=C2C=CC([N-]2)=C(C=2C=CC=CC=2)C=2C=CC(N=2)=C(C=2C=CC=CC=2)C2=CC=C3[N-]2)C=2C=CC=CC=2)=NC1=C3C1=CC=CC=C1 RKTYLMNFRDHKIL-UHFFFAOYSA-N 0.000 description 4
- 230000018044 dehydration Effects 0.000 description 4
- 238000006297 dehydration reaction Methods 0.000 description 4
- 229910004874 Na2S 9H2O Inorganic materials 0.000 description 3
- 238000002441 X-ray diffraction Methods 0.000 description 2
- 150000008064 anhydrides Chemical class 0.000 description 2
- 239000007864 aqueous solution Substances 0.000 description 2
- 238000001816 cooling Methods 0.000 description 2
- GVPWHKZIJBODOX-UHFFFAOYSA-N dibenzyl disulfide Chemical compound C=1C=CC=CC=1CSSCC1=CC=CC=C1 GVPWHKZIJBODOX-UHFFFAOYSA-N 0.000 description 2
- 238000002360 preparation method Methods 0.000 description 2
- 239000000126 substance Substances 0.000 description 2
- 239000000988 sulfur dye Substances 0.000 description 2
- OCJBOOLMMGQPQU-UHFFFAOYSA-N 1,4-dichlorobenzene Chemical compound ClC1=CC=C(Cl)C=C1 OCJBOOLMMGQPQU-UHFFFAOYSA-N 0.000 description 1
- 239000004734 Polyphenylene sulfide Substances 0.000 description 1
- 238000005054 agglomeration Methods 0.000 description 1
- 230000002776 aggregation Effects 0.000 description 1
- 238000004458 analytical method Methods 0.000 description 1
- LUFPJJNWMYZRQE-UHFFFAOYSA-N benzylsulfanylmethylbenzene Chemical compound C=1C=CC=CC=1CSCC1=CC=CC=C1 LUFPJJNWMYZRQE-UHFFFAOYSA-N 0.000 description 1
- 230000008859 change Effects 0.000 description 1
- 230000006911 nucleation Effects 0.000 description 1
- 238000010899 nucleation Methods 0.000 description 1
- 239000008188 pellet Substances 0.000 description 1
- 229920000069 polyphenylene sulfide Polymers 0.000 description 1
- 239000000843 powder Substances 0.000 description 1
- 238000001556 precipitation Methods 0.000 description 1
- 239000011347 resin Substances 0.000 description 1
- 229920005989 resin Polymers 0.000 description 1
- 238000007086 side reaction Methods 0.000 description 1
- 239000000243 solution Substances 0.000 description 1
- 239000007858 starting material Substances 0.000 description 1
- 230000009466 transformation Effects 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B17/00—Sulfur; Compounds thereof
- C01B17/22—Alkali metal sulfides or polysulfides
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B17/00—Sulfur; Compounds thereof
- C01B17/22—Alkali metal sulfides or polysulfides
- C01B17/38—Dehydration
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
- C01P2006/00—Physical properties of inorganic compounds
- C01P2006/32—Thermal properties
- C01P2006/33—Phase transition temperatures
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
- C01P2006/00—Physical properties of inorganic compounds
- C01P2006/80—Compositional purity
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
- C01P2006/00—Physical properties of inorganic compounds
- C01P2006/80—Compositional purity
- C01P2006/82—Compositional purity water content
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Inorganic Chemistry (AREA)
- Polymers With Sulfur, Phosphorus Or Metals In The Main Chain (AREA)
- Inorganic Compounds Of Heavy Metals (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Crystals, And After-Treatments Of Crystals (AREA)
- Pharmaceuticals Containing Other Organic And Inorganic Compounds (AREA)
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP13485488 | 1988-05-31 | ||
| JP63309263A JPH0251404A (ja) | 1988-05-31 | 1988-12-06 | 無水硫化ナトリウム結晶の製造法 |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| DE68913361D1 DE68913361D1 (de) | 1994-04-07 |
| DE68913361T2 true DE68913361T2 (de) | 1994-06-01 |
Family
ID=26468833
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| DE68913361T Expired - Fee Related DE68913361T2 (de) | 1988-05-31 | 1989-05-29 | Verfahren zur Herstellung von wasserfreien Natriumsulfidkristallen. |
Country Status (6)
| Country | Link |
|---|---|
| US (1) | US5173088A (enExample) |
| EP (1) | EP0345136B1 (enExample) |
| JP (1) | JPH0251404A (enExample) |
| KR (1) | KR900017901A (enExample) |
| DE (1) | DE68913361T2 (enExample) |
| ES (1) | ES2049833T3 (enExample) |
Families Citing this family (14)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP3408577B2 (ja) * | 1993-04-22 | 2003-05-19 | ナガオ株式会社 | 不活性ガスによる硫化ソーダ有形物の脱水方法 |
| JP3408576B2 (ja) * | 1993-04-22 | 2003-05-19 | ナガオ株式会社 | 不活性ガスでの硫化ソーダ有形物の脱水方法 |
| US6503474B1 (en) | 1997-12-16 | 2003-01-07 | Degussa Ag | Process for the preparation of anhydrous sodium sulfide |
| DE19755760A1 (de) * | 1997-12-16 | 1999-06-24 | Degussa | Verfahren zur Herstellung von wasserfreiem Natriumsulfid |
| US6582675B2 (en) | 2000-03-28 | 2003-06-24 | Degussa Ag | Method for the preparation of anhydrous sodium sulfide |
| JP3828090B2 (ja) * | 2003-04-15 | 2006-09-27 | 勝華科技股▲ふん▼有限公司 | 昇華純化方法 |
| US20050136125A1 (en) * | 2003-10-22 | 2005-06-23 | Roth Mark B. | Methods, compositions and devices for inducing stasis in cells, tissues, organs, and organisms |
| CA2542426A1 (en) * | 2003-10-22 | 2005-05-06 | Fred Hutchinson Cancer Research Center | Methods, compositions and devices for inducing stasis in cells |
| US20050170019A1 (en) * | 2003-10-22 | 2005-08-04 | Fred Hutchinson Cancer Research Center | Methods, compositions and devices for inducing stasis in cells |
| PT1879599E (pt) | 2005-04-20 | 2014-01-23 | Hutchinson Fred Cancer Res | Métodos, composições e artigos de fabrico para aumentar a capacidade de sobrevivência de células, tecidos, órgãos, e organismos |
| CN103241716A (zh) * | 2013-04-22 | 2013-08-14 | 中国石油化工股份有限公司 | 一种合成聚苯硫醚用结晶硫化钠脱水的加热控制方法 |
| CN108147372B (zh) * | 2017-12-05 | 2020-01-17 | 宜宾天原集团股份有限公司 | 聚苯硫醚生产中硫化钠反应前体的制备方法 |
| CN116281875A (zh) * | 2021-12-14 | 2023-06-23 | 南风化工(运城)集团有限公司 | 一种无水硫化钠的生产方法 |
| CN115947314A (zh) * | 2022-12-26 | 2023-04-11 | 南风化工(运城)集团有限公司 | 一种无水硫化钠的生产方法 |
Family Cites Families (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US2477959A (en) * | 1944-10-03 | 1949-08-02 | Worthington Pump & Mach Corp | Balanced heat system for vacuum drying |
| US2533163A (en) * | 1948-12-27 | 1950-12-05 | Gen Aniline & Film Corp | Dehydration of sodium sulfide |
| US3235329A (en) * | 1962-10-01 | 1966-02-15 | Fmc Corp | Novel sodium carbonate-sodium bicarbonate compositions |
| SU363658A1 (ru) * | 1970-05-19 | 1972-12-25 | А. М. Бикинеев, Ю. И. Огородников , Е. И. Пономарева Институт металлургии , обогащени Казахской ССР | Способ получения безводного сернистого натрия |
| US4039617A (en) * | 1975-06-17 | 1977-08-02 | Allied Chemical Corporation | Recovery of soda values and heat from sodium carbonate crystallizer purge liquors |
| US3992159A (en) * | 1975-06-23 | 1976-11-16 | Bell Telephone Laboratories, Incorporated | Process for purification by cryogenic sublimation |
| IL51692A (en) * | 1977-03-18 | 1981-05-20 | Sadan Abraham | Process for dehydrating hydrated salts in solar ponds |
| JPS6428207A (en) * | 1987-07-23 | 1989-01-30 | Sankyo Kasei Kk | Sodium sulfide anhydrous single crystal and production thereof |
-
1988
- 1988-12-06 JP JP63309263A patent/JPH0251404A/ja active Granted
-
1989
- 1989-05-26 US US07/357,497 patent/US5173088A/en not_active Expired - Fee Related
- 1989-05-29 DE DE68913361T patent/DE68913361T2/de not_active Expired - Fee Related
- 1989-05-29 EP EP89401456A patent/EP0345136B1/en not_active Expired - Lifetime
- 1989-05-29 ES ES89401456T patent/ES2049833T3/es not_active Expired - Lifetime
- 1989-05-30 KR KR1019890007239A patent/KR900017901A/ko not_active Withdrawn
Also Published As
| Publication number | Publication date |
|---|---|
| US5173088A (en) | 1992-12-22 |
| KR900017901A (ko) | 1990-12-20 |
| JPH0512285B2 (enExample) | 1993-02-17 |
| EP0345136A1 (en) | 1989-12-06 |
| JPH0251404A (ja) | 1990-02-21 |
| EP0345136B1 (en) | 1994-03-02 |
| DE68913361D1 (de) | 1994-04-07 |
| ES2049833T3 (es) | 1994-05-01 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| 8364 | No opposition during term of opposition | ||
| 8339 | Ceased/non-payment of the annual fee |