DE60315595T2 - Mischungen von ionomer und polyethylen hoher dichte mit verbesserter schlagzähigkeit - Google Patents
Mischungen von ionomer und polyethylen hoher dichte mit verbesserter schlagzähigkeit Download PDFInfo
- Publication number
- DE60315595T2 DE60315595T2 DE60315595T DE60315595T DE60315595T2 DE 60315595 T2 DE60315595 T2 DE 60315595T2 DE 60315595 T DE60315595 T DE 60315595T DE 60315595 T DE60315595 T DE 60315595T DE 60315595 T2 DE60315595 T2 DE 60315595T2
- Authority
- DE
- Germany
- Prior art keywords
- maleic anhydride
- man
- high density
- ionomer
- ethylene polymer
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- 239000004700 high-density polyethylene Substances 0.000 title claims description 54
- 239000000203 mixture Substances 0.000 title claims description 50
- 229920000554 ionomer Polymers 0.000 title claims description 31
- 229920001903 high density polyethylene Polymers 0.000 claims description 49
- FPYJFEHAWHCUMM-UHFFFAOYSA-N maleic anhydride Chemical compound O=C1OC(=O)C=C1 FPYJFEHAWHCUMM-UHFFFAOYSA-N 0.000 claims description 44
- 229920000573 polyethylene Polymers 0.000 claims description 42
- HQQADJVZYDDRJT-UHFFFAOYSA-N ethene;prop-1-ene Chemical group C=C.CC=C HQQADJVZYDDRJT-UHFFFAOYSA-N 0.000 claims description 18
- 229920001971 elastomer Polymers 0.000 claims description 17
- 239000004708 Very-low-density polyethylene Substances 0.000 claims description 13
- 229920001866 very low density polyethylene Polymers 0.000 claims description 13
- 238000000034 method Methods 0.000 claims description 10
- 239000000178 monomer Substances 0.000 claims description 10
- 229920012753 Ethylene Ionomers Polymers 0.000 claims description 9
- 125000000816 ethylene group Chemical group [H]C([H])([*:1])C([H])([H])[*:2] 0.000 claims description 9
- 229920001912 maleic anhydride grafted polyethylene Polymers 0.000 claims description 9
- 150000001993 dienes Chemical class 0.000 claims description 8
- 239000005977 Ethylene Substances 0.000 claims description 7
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 claims description 6
- 238000002156 mixing Methods 0.000 claims description 4
- 229920001577 copolymer Polymers 0.000 description 16
- 229920003317 Fusabond® Polymers 0.000 description 15
- 229920000642 polymer Polymers 0.000 description 10
- 239000002253 acid Substances 0.000 description 9
- 239000000654 additive Substances 0.000 description 8
- -1 polyethylene Polymers 0.000 description 8
- 239000004698 Polyethylene Substances 0.000 description 7
- 229920001169 thermoplastic Polymers 0.000 description 7
- 239000004416 thermosoftening plastic Substances 0.000 description 7
- 229920001897 terpolymer Polymers 0.000 description 6
- 239000005035 Surlyn® Substances 0.000 description 5
- JKIJEFPNVSHHEI-UHFFFAOYSA-N Phenol, 2,4-bis(1,1-dimethylethyl)-, phosphite (3:1) Chemical compound CC(C)(C)C1=CC(C(C)(C)C)=CC=C1OP(OC=1C(=CC(=CC=1)C(C)(C)C)C(C)(C)C)OC1=CC=C(C(C)(C)C)C=C1C(C)(C)C JKIJEFPNVSHHEI-UHFFFAOYSA-N 0.000 description 4
- 230000000996 additive effect Effects 0.000 description 4
- 238000001746 injection moulding Methods 0.000 description 4
- 238000012360 testing method Methods 0.000 description 4
- VXNZUUAINFGPBY-UHFFFAOYSA-N 1-Butene Chemical compound CCC=C VXNZUUAINFGPBY-UHFFFAOYSA-N 0.000 description 3
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 description 3
- IAQRGUVFOMOMEM-UHFFFAOYSA-N butene Natural products CC=CC IAQRGUVFOMOMEM-UHFFFAOYSA-N 0.000 description 3
- 238000006243 chemical reaction Methods 0.000 description 3
- 238000013329 compounding Methods 0.000 description 3
- 239000006185 dispersion Substances 0.000 description 3
- AHAREKHAZNPPMI-UHFFFAOYSA-N hexa-1,3-diene Chemical compound CCC=CC=C AHAREKHAZNPPMI-UHFFFAOYSA-N 0.000 description 3
- 238000010348 incorporation Methods 0.000 description 3
- 239000002243 precursor Substances 0.000 description 3
- 239000004711 α-olefin Substances 0.000 description 3
- 229920002943 EPDM rubber Polymers 0.000 description 2
- VZCYOOQTPOCHFL-OWOJBTEDSA-N Fumaric acid Chemical compound OC(=O)\C=C\C(O)=O VZCYOOQTPOCHFL-OWOJBTEDSA-N 0.000 description 2
- 239000004609 Impact Modifier Substances 0.000 description 2
- 239000004952 Polyamide Substances 0.000 description 2
- 239000012963 UV stabilizer Substances 0.000 description 2
- 239000000956 alloy Substances 0.000 description 2
- 229910045601 alloy Inorganic materials 0.000 description 2
- 239000000806 elastomer Substances 0.000 description 2
- 238000001125 extrusion Methods 0.000 description 2
- 239000000835 fiber Substances 0.000 description 2
- 238000004519 manufacturing process Methods 0.000 description 2
- 238000000465 moulding Methods 0.000 description 2
- NFHFRUOZVGFOOS-UHFFFAOYSA-N palladium;triphenylphosphane Chemical compound [Pd].C1=CC=CC=C1P(C=1C=CC=CC=1)C1=CC=CC=C1.C1=CC=CC=C1P(C=1C=CC=CC=1)C1=CC=CC=C1.C1=CC=CC=C1P(C=1C=CC=CC=1)C1=CC=CC=C1.C1=CC=CC=C1P(C=1C=CC=CC=1)C1=CC=CC=C1 NFHFRUOZVGFOOS-UHFFFAOYSA-N 0.000 description 2
- 229920002647 polyamide Polymers 0.000 description 2
- 229920002959 polymer blend Polymers 0.000 description 2
- 238000006116 polymerization reaction Methods 0.000 description 2
- 239000012783 reinforcing fiber Substances 0.000 description 2
- 239000011347 resin Substances 0.000 description 2
- 229920005989 resin Polymers 0.000 description 2
- AZSKHRTUXHLAHS-UHFFFAOYSA-N tris(2,4-di-tert-butylphenyl) phosphate Chemical compound CC(C)(C)C1=CC(C(C)(C)C)=CC=C1OP(=O)(OC=1C(=CC(=CC=1)C(C)(C)C)C(C)(C)C)OC1=CC=C(C(C)(C)C)C=C1C(C)(C)C AZSKHRTUXHLAHS-UHFFFAOYSA-N 0.000 description 2
- 229910052725 zinc Inorganic materials 0.000 description 2
- 239000011701 zinc Substances 0.000 description 2
- SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Chemical compound COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 description 1
- JAHNSTQSQJOJLO-UHFFFAOYSA-N 2-(3-fluorophenyl)-1h-imidazole Chemical compound FC1=CC=CC(C=2NC=CN=2)=C1 JAHNSTQSQJOJLO-UHFFFAOYSA-N 0.000 description 1
- NIXOWILDQLNWCW-UHFFFAOYSA-N 2-Propenoic acid Natural products OC(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 description 1
- CTYWXRDQWMRIIM-UHFFFAOYSA-N 3-(3,5-ditert-butyl-4-hydroxyphenyl)prop-2-enoic acid Chemical compound CC(C)(C)C1=CC(C=CC(O)=O)=CC(C(C)(C)C)=C1O CTYWXRDQWMRIIM-UHFFFAOYSA-N 0.000 description 1
- KFAODMRSXPNDPT-UHFFFAOYSA-N 3-[3-tert-butyl-4-hydroxy-5-(2-methylbut-3-en-2-yl)phenyl]prop-2-enoic acid Chemical compound CC(C)(C)C1=C(C(=CC(=C1)C=CC(=O)O)C(C)(C)C=C)O KFAODMRSXPNDPT-UHFFFAOYSA-N 0.000 description 1
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 1
- OFOBLEOULBTSOW-UHFFFAOYSA-N Malonic acid Chemical compound OC(=O)CC(O)=O OFOBLEOULBTSOW-UHFFFAOYSA-N 0.000 description 1
- CERQOIWHTDAKMF-UHFFFAOYSA-N Methacrylic acid Chemical compound CC(=C)C(O)=O CERQOIWHTDAKMF-UHFFFAOYSA-N 0.000 description 1
- 239000006057 Non-nutritive feed additive Substances 0.000 description 1
- 229920010346 Very Low Density Polyethylene (VLDPE) Polymers 0.000 description 1
- 150000007854 aminals Chemical class 0.000 description 1
- 150000001412 amines Chemical class 0.000 description 1
- 150000008064 anhydrides Chemical class 0.000 description 1
- 239000003963 antioxidant agent Substances 0.000 description 1
- 238000000071 blow moulding Methods 0.000 description 1
- 125000004432 carbon atom Chemical group C* 0.000 description 1
- 239000006229 carbon black Substances 0.000 description 1
- 150000001732 carboxylic acid derivatives Chemical class 0.000 description 1
- 238000012512 characterization method Methods 0.000 description 1
- 239000003086 colorant Substances 0.000 description 1
- 230000003247 decreasing effect Effects 0.000 description 1
- 230000001419 dependent effect Effects 0.000 description 1
- 150000001991 dicarboxylic acids Chemical class 0.000 description 1
- 229920003244 diene elastomer Polymers 0.000 description 1
- 238000009826 distribution Methods 0.000 description 1
- 210000003195 fascia Anatomy 0.000 description 1
- 239000011152 fibreglass Substances 0.000 description 1
- 239000011888 foil Substances 0.000 description 1
- 239000001530 fumaric acid Substances 0.000 description 1
- 239000003365 glass fiber Substances 0.000 description 1
- 229920006158 high molecular weight polymer Polymers 0.000 description 1
- 239000007970 homogeneous dispersion Substances 0.000 description 1
- 238000011065 in-situ storage Methods 0.000 description 1
- 238000002347 injection Methods 0.000 description 1
- 239000007924 injection Substances 0.000 description 1
- 239000000543 intermediate Substances 0.000 description 1
- 239000004611 light stabiliser Substances 0.000 description 1
- 229920001684 low density polyethylene Polymers 0.000 description 1
- 239000004702 low-density polyethylene Substances 0.000 description 1
- 239000011159 matrix material Substances 0.000 description 1
- 238000005259 measurement Methods 0.000 description 1
- 239000000155 melt Substances 0.000 description 1
- 238000002844 melting Methods 0.000 description 1
- 230000008018 melting Effects 0.000 description 1
- HNEGQIOMVPPMNR-NSCUHMNNSA-N mesaconic acid Chemical compound OC(=O)C(/C)=C/C(O)=O HNEGQIOMVPPMNR-NSCUHMNNSA-N 0.000 description 1
- 229910052751 metal Inorganic materials 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- 229910000000 metal hydroxide Inorganic materials 0.000 description 1
- 150000004692 metal hydroxides Chemical class 0.000 description 1
- 229910021645 metal ion Inorganic materials 0.000 description 1
- 229910044991 metal oxide Inorganic materials 0.000 description 1
- 150000004706 metal oxides Chemical class 0.000 description 1
- 125000001570 methylene group Chemical group [H]C([H])([*:1])[*:2] 0.000 description 1
- LVHBHZANLOWSRM-UHFFFAOYSA-N methylenebutanedioic acid Natural products OC(=O)CC(=C)C(O)=O LVHBHZANLOWSRM-UHFFFAOYSA-N 0.000 description 1
- HNEGQIOMVPPMNR-UHFFFAOYSA-N methylfumaric acid Natural products OC(=O)C(C)=CC(O)=O HNEGQIOMVPPMNR-UHFFFAOYSA-N 0.000 description 1
- 238000004452 microanalysis Methods 0.000 description 1
- 239000012764 mineral filler Substances 0.000 description 1
- 238000006386 neutralization reaction Methods 0.000 description 1
- 230000003472 neutralizing effect Effects 0.000 description 1
- 239000002667 nucleating agent Substances 0.000 description 1
- 230000000704 physical effect Effects 0.000 description 1
- 239000000049 pigment Substances 0.000 description 1
- 239000004014 plasticizer Substances 0.000 description 1
- 230000000379 polymerizing effect Effects 0.000 description 1
- 229920000098 polyolefin Polymers 0.000 description 1
- 238000002360 preparation method Methods 0.000 description 1
- QQONPFPTGQHPMA-UHFFFAOYSA-N propylene Natural products CC=C QQONPFPTGQHPMA-UHFFFAOYSA-N 0.000 description 1
- 125000004805 propylene group Chemical group [H]C([H])([H])C([H])([*:1])C([H])([H])[*:2] 0.000 description 1
- 239000000376 reactant Substances 0.000 description 1
- 239000012748 slip agent Substances 0.000 description 1
- 229910052708 sodium Inorganic materials 0.000 description 1
- 239000011734 sodium Substances 0.000 description 1
- 239000007921 spray Substances 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- VZCYOOQTPOCHFL-UHFFFAOYSA-N trans-butenedioic acid Natural products OC(=O)C=CC(O)=O VZCYOOQTPOCHFL-UHFFFAOYSA-N 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
- C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
- C08L23/04—Homopolymers or copolymers of ethene
- C08L23/06—Polyethene
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
- C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
- C08L23/04—Homopolymers or copolymers of ethene
- C08L23/08—Copolymers of ethene
- C08L23/0846—Copolymers of ethene with unsaturated hydrocarbons containing atoms other than carbon or hydrogen
- C08L23/0869—Copolymers of ethene with unsaturated hydrocarbons containing atoms other than carbon or hydrogen with unsaturated acids, e.g. [meth]acrylic acid; with unsaturated esters, e.g. [meth]acrylic acid esters
- C08L23/0876—Salts thereof, i.e. ionomers
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L51/00—Compositions of graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers
- C08L51/06—Compositions of graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers grafted on to homopolymers or copolymers of aliphatic hydrocarbons containing only one carbon-to-carbon double bond
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Processes Of Treating Macromolecular Substances (AREA)
- Manufacture Of Macromolecular Shaped Articles (AREA)
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US56654 | 1998-04-07 | ||
| US10/056,654 US6569947B1 (en) | 2002-01-25 | 2002-01-25 | Ionomer/high density polyethylene blends with improved impact |
| PCT/US2003/001792 WO2003064520A2 (en) | 2002-01-25 | 2003-01-22 | Ionomer/high density polyethylene blends with improved impact resistance |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| DE60315595D1 DE60315595D1 (de) | 2007-09-27 |
| DE60315595T2 true DE60315595T2 (de) | 2008-05-08 |
Family
ID=22005811
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| DE60315595T Expired - Lifetime DE60315595T2 (de) | 2002-01-25 | 2003-01-22 | Mischungen von ionomer und polyethylen hoher dichte mit verbesserter schlagzähigkeit |
Country Status (6)
| Country | Link |
|---|---|
| US (1) | US6569947B1 (enExample) |
| EP (1) | EP1468045B1 (enExample) |
| JP (1) | JP2005516096A (enExample) |
| CN (1) | CN1622974A (enExample) |
| DE (1) | DE60315595T2 (enExample) |
| WO (1) | WO2003064520A2 (enExample) |
Families Citing this family (29)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US6596815B1 (en) * | 2002-01-25 | 2003-07-22 | E. I. Du Pont De Nemours And Company | Ionomer/high density polyethylene blends with improved flow |
| US20060020086A1 (en) * | 2002-09-19 | 2006-01-26 | Dennis Smith | Ionomer modified polypropylene compound for superior scratch performance,low blushing and molded in color with controllable gloss |
| US6953619B2 (en) * | 2003-02-12 | 2005-10-11 | E. I. Du Pont De Nemours And Company | Conductive thermoplastic compositions and antennas thereof |
| WO2006102673A1 (en) * | 2005-03-24 | 2006-09-28 | E. I. Du Pont De Nemours And Company | Transponder overmolded with ethylene copolymers |
| US7875655B2 (en) | 2006-01-20 | 2011-01-25 | Material Innovations, Llc | Carpet waste composite |
| US20090036566A1 (en) * | 2007-07-30 | 2009-02-05 | City University Of Hong Kong | Biodegradable composite, product made therefrom, and method of manufacture thereof |
| US20100021753A1 (en) * | 2008-07-25 | 2010-01-28 | E. I. Du Pont De Nemours And Company | Multizone wood polymer composite article |
| EP2376283B1 (en) | 2008-12-19 | 2017-07-05 | Fiber Composites, LLC | Wood-plastic composites utilizing ionomer capstocks and methods of manufacture |
| CN101942126B (zh) * | 2009-07-08 | 2012-08-08 | 中国石油天然气股份有限公司 | 一种透明抗静电聚乙烯薄膜母料 |
| CN102167857A (zh) * | 2010-02-26 | 2011-08-31 | 张万鹏 | 乙丙橡胶接枝马来酸酐改性聚乙烯板材及其制法 |
| CN103265746A (zh) * | 2013-04-23 | 2013-08-28 | 蓝星（北京）特种纤维技术研发中心有限公司 | 一种聚乙烯组合物及其制备方法 |
| DE102013218957A1 (de) | 2013-09-20 | 2015-03-26 | Evonik Industries Ag | Formmasse auf Basis eines teilaromatischen Copolyamids |
| CN106232725A (zh) | 2014-04-29 | 2016-12-14 | 纳幕尔杜邦公司 | 具有改善的背板的光伏电池 |
| CN106457789A (zh) | 2014-04-29 | 2017-02-22 | 纳幕尔杜邦公司 | 具有改善的多层背板的光伏电池 |
| CN106232724A (zh) | 2014-04-29 | 2016-12-14 | 纳幕尔杜邦公司 | 具有改善的背板的太阳能电池模块 |
| JP6398662B2 (ja) * | 2014-12-03 | 2018-10-03 | 日立金属株式会社 | ノンハロゲン架橋性樹脂組成物、架橋絶縁電線及びケーブル |
| TW201840705A (zh) * | 2016-12-19 | 2018-11-16 | 德商科思創德意志股份有限公司 | 具有良好機械性質的熱塑性組成物 |
| US11161091B2 (en) * | 2018-02-28 | 2021-11-02 | Dow Global Technologies Llc | Composition for odor suppression |
| CN108485031A (zh) * | 2018-04-02 | 2018-09-04 | 安徽理工大学 | 一种改性导爆管配方 |
| CN109081998A (zh) * | 2018-07-10 | 2018-12-25 | 浙江琛盛新材料科技有限公司 | 一种共挤料生产配方及工艺 |
| CN112424279A (zh) | 2018-07-31 | 2021-02-26 | 性能材料北美股份有限公司 | 具有增强抗蠕变性的乙烯酸共聚物的离聚物 |
| EP3830187B1 (en) | 2018-07-31 | 2022-11-02 | Dow Global Technologies LLC | Ionomers of ethylene acid copolymers with enhanced creep resistance |
| WO2020169548A1 (en) | 2019-02-18 | 2020-08-27 | Total Research & Technology Feluy | Polyolefin compositions and process to produce such compositions by the addition of coupling agents |
| WO2020169552A1 (en) | 2019-02-18 | 2020-08-27 | Total Research & Technology Feluy | Polyolefin compositions and process to produce such compositions by the addition of ionomers |
| WO2020169549A1 (en) | 2019-02-18 | 2020-08-27 | Total Research & Technology Feluy | Polyolefin compositions and process to produce such compositions by the addition of coupling agents |
| US11572646B2 (en) | 2020-11-18 | 2023-02-07 | Material Innovations Llc | Composite building materials and methods of manufacture |
| US12172421B2 (en) | 2020-11-18 | 2024-12-24 | Rise Building Products Llc | Composite building materials and methods of manufacture |
| KR20240042038A (ko) | 2021-08-11 | 2024-04-01 | 다우 글로벌 테크놀로지스 엘엘씨 | 난연성 중합체 조성물 |
| CN120077097A (zh) | 2022-11-15 | 2025-05-30 | 陶氏环球技术有限责任公司 | 阻燃聚合物组合物 |
Family Cites Families (22)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4351931A (en) | 1961-06-26 | 1982-09-28 | E. I. Du Pont De Nemours And Company | Polyethylene copolymers |
| NL129542C (enExample) | 1961-08-31 | 1900-01-01 | ||
| US3520861A (en) | 1968-12-26 | 1970-07-21 | Dow Chemical Co | Copolymers of ethylene |
| US4026967A (en) | 1976-06-25 | 1977-05-31 | E. I. Du Pont De Nemours And Company | Process for making grafted polymeric material |
| US4248990A (en) | 1979-04-05 | 1981-02-03 | E. I. Du Pont De Nemours & Company | Nonrandom copolymers of ethylene and unsaturated acid |
| US4252924A (en) | 1979-04-05 | 1981-02-24 | E. I. Du Pont De Nemours And Company | Continuous process for the preparation of nonrandom ethylene/acid copolymer |
| JPS5723642A (en) * | 1980-07-17 | 1982-02-06 | Mitsubishi Petrochem Co Ltd | Olefinic polymer composition containing inorganic filler |
| US4387188A (en) | 1981-02-23 | 1983-06-07 | E. I. Du Pont De Nemours And Company | Molding resins based on blends of acid copolymer/linear polyolefin/reinforcing fiber |
| US5091478A (en) | 1986-11-14 | 1992-02-25 | E. I. Du Pont De Nemours And Company | Partially grafted thermoplastic compositions |
| US4839412A (en) * | 1986-11-25 | 1989-06-13 | E. I. Du Pont De Nemours And Company | Ethylene copolymer compositions |
| US4992486A (en) | 1989-11-14 | 1991-02-12 | E. I. Du Pont De Nemours And Company | White-pigmented, melt-stable ethylene/carboxylic acid copolymer compositions |
| US5089332A (en) | 1989-11-14 | 1992-02-18 | E. I. Du Pont De Nemours And Company | Laminates with adhesive layer of white-pigmented, melt-stable ethylene/carboxylic acid copolymer compositions |
| US5118746A (en) | 1991-02-11 | 1992-06-02 | E. I. Du Pont De Nemours And Company | Fire retardant melt stable ethylene/carboxylic acid copolymer composition |
| US5160788A (en) | 1991-02-11 | 1992-11-03 | E. I. Du Pont De Nemours And Company | Laminates with adhesive layers of fire retardant, melt stable ethylene/carboxylic acid copolymer compositions |
| US5439974A (en) * | 1991-11-27 | 1995-08-08 | Quantum Chemical Corporation | Propylene-based extrudable adhesive blends |
| US5721314A (en) | 1993-12-07 | 1998-02-24 | E. I. Du Pont De Nemours And Company | Thermoformable thermoplastic polymer alloy compositions |
| US5643999A (en) | 1995-03-28 | 1997-07-01 | E. I. Du Pont De Nemours And Company | Co-extrudable adhesives with good age-down resistance |
| US5866658A (en) | 1996-08-26 | 1999-02-02 | E. I. Du Pont De Nemours And Company | High performance ionomer blends |
| EP0963402A1 (en) * | 1997-02-28 | 1999-12-15 | The Dow Chemical Company | Filled polyethylene compositions |
| JP4462641B2 (ja) * | 1997-02-28 | 2010-05-12 | イー・アイ・デュポン・ドウ・ヌムール・アンド・カンパニー | モノカルボン酸とジカルボン酸の両方を含むエチレンのコポリマーをベースとする新規のイオノマーと、このようなイオノマーを含むポリアミド・ブレンド |
| DE69705123T2 (de) * | 1997-12-10 | 2001-11-15 | E.I. Du Pont De Nemours And Co., Wilmington | Durch Hitze verformbare thermoplastische Polymermassen |
| US6207761B1 (en) | 1999-03-18 | 2001-03-27 | A. Schulman, Inc. | Ionomer/rubber/polyolefin blend and uses thereof |
-
2002
- 2002-01-25 US US10/056,654 patent/US6569947B1/en not_active Expired - Lifetime
-
2003
- 2003-01-22 EP EP03710708A patent/EP1468045B1/en not_active Expired - Lifetime
- 2003-01-22 WO PCT/US2003/001792 patent/WO2003064520A2/en not_active Ceased
- 2003-01-22 JP JP2003564127A patent/JP2005516096A/ja active Pending
- 2003-01-22 CN CN03802745.3A patent/CN1622974A/zh active Pending
- 2003-01-22 DE DE60315595T patent/DE60315595T2/de not_active Expired - Lifetime
Also Published As
| Publication number | Publication date |
|---|---|
| US6569947B1 (en) | 2003-05-27 |
| DE60315595D1 (de) | 2007-09-27 |
| EP1468045B1 (en) | 2007-08-15 |
| JP2005516096A (ja) | 2005-06-02 |
| WO2003064520A3 (en) | 2004-08-05 |
| WO2003064520A2 (en) | 2003-08-07 |
| EP1468045A2 (en) | 2004-10-20 |
| CN1622974A (zh) | 2005-06-01 |
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