DE60309020T2 - Buten-1-(co)polymere und verfahren zu ihrer herstellung - Google Patents
Buten-1-(co)polymere und verfahren zu ihrer herstellung Download PDFInfo
- Publication number
- DE60309020T2 DE60309020T2 DE60309020T DE60309020T DE60309020T2 DE 60309020 T2 DE60309020 T2 DE 60309020T2 DE 60309020 T DE60309020 T DE 60309020T DE 60309020 T DE60309020 T DE 60309020T DE 60309020 T2 DE60309020 T2 DE 60309020T2
- Authority
- DE
- Germany
- Prior art keywords
- butene
- homopolymers
- copolymers according
- copolymers
- molecular weight
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- VXNZUUAINFGPBY-UHFFFAOYSA-N 1-Butene Chemical compound CCC=C VXNZUUAINFGPBY-UHFFFAOYSA-N 0.000 title claims description 83
- 229920001577 copolymer Polymers 0.000 title claims description 31
- 238000000034 method Methods 0.000 title claims description 21
- 150000001875 compounds Chemical class 0.000 claims description 27
- 238000009826 distribution Methods 0.000 claims description 17
- 239000003054 catalyst Substances 0.000 claims description 16
- -1 ethylene, propylene Chemical group 0.000 claims description 13
- 229920001519 homopolymer Polymers 0.000 claims description 13
- 239000000155 melt Substances 0.000 claims description 11
- 125000004432 carbon atom Chemical group C* 0.000 claims description 7
- 239000007788 liquid Substances 0.000 claims description 7
- 238000004519 manufacturing process Methods 0.000 claims description 7
- 239000000178 monomer Substances 0.000 claims description 7
- 239000004711 α-olefin Substances 0.000 claims description 6
- UVGKQRAGAYVWQV-UHFFFAOYSA-N 2,3-dimethylbutan-2-yl(trimethoxy)silane Chemical compound CO[Si](OC)(OC)C(C)(C)C(C)C UVGKQRAGAYVWQV-UHFFFAOYSA-N 0.000 claims description 5
- 239000007787 solid Substances 0.000 claims description 5
- 239000004743 Polypropylene Substances 0.000 claims description 4
- 150000001336 alkenes Chemical class 0.000 claims description 4
- 238000004458 analytical method Methods 0.000 claims description 4
- 229920001155 polypropylene Polymers 0.000 claims description 4
- 230000000707 stereoselective effect Effects 0.000 claims description 4
- 125000005498 phthalate group Chemical class 0.000 claims 1
- 229920000642 polymer Polymers 0.000 description 24
- TWRXJAOTZQYOKJ-UHFFFAOYSA-L Magnesium chloride Chemical compound [Mg+2].[Cl-].[Cl-] TWRXJAOTZQYOKJ-UHFFFAOYSA-L 0.000 description 18
- VLKZOEOYAKHREP-UHFFFAOYSA-N n-Hexane Chemical compound CCCCCC VLKZOEOYAKHREP-UHFFFAOYSA-N 0.000 description 15
- 238000006116 polymerization reaction Methods 0.000 description 13
- 239000010936 titanium Substances 0.000 description 11
- 235000011147 magnesium chloride Nutrition 0.000 description 9
- 239000011949 solid catalyst Substances 0.000 description 9
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 8
- 239000000243 solution Substances 0.000 description 8
- 238000011282 treatment Methods 0.000 description 7
- 229920001083 polybutene Polymers 0.000 description 6
- RFFLAFLAYFXFSW-UHFFFAOYSA-N 1,2-dichlorobenzene Chemical compound ClC1=CC=CC=C1Cl RFFLAFLAYFXFSW-UHFFFAOYSA-N 0.000 description 5
- 239000004215 Carbon black (E152) Substances 0.000 description 5
- 125000000217 alkyl group Chemical group 0.000 description 5
- 125000000753 cycloalkyl group Chemical group 0.000 description 5
- 238000005227 gel permeation chromatography Methods 0.000 description 5
- 229930195733 hydrocarbon Natural products 0.000 description 5
- 230000007774 longterm Effects 0.000 description 5
- 239000000203 mixture Substances 0.000 description 5
- 239000000047 product Substances 0.000 description 5
- 150000003377 silicon compounds Chemical class 0.000 description 5
- 238000003756 stirring Methods 0.000 description 5
- FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 description 4
- 230000009172 bursting Effects 0.000 description 4
- 238000006243 chemical reaction Methods 0.000 description 4
- MGWAVDBGNNKXQV-UHFFFAOYSA-N diisobutyl phthalate Chemical compound CC(C)COC(=O)C1=CC=CC=C1C(=O)OCC(C)C MGWAVDBGNNKXQV-UHFFFAOYSA-N 0.000 description 4
- 150000002430 hydrocarbons Chemical class 0.000 description 4
- 239000001257 hydrogen Substances 0.000 description 4
- 229910052739 hydrogen Inorganic materials 0.000 description 4
- 229910052749 magnesium Inorganic materials 0.000 description 4
- 239000011777 magnesium Substances 0.000 description 4
- 229910001629 magnesium chloride Inorganic materials 0.000 description 4
- 229910052757 nitrogen Inorganic materials 0.000 description 4
- YMWUJEATGCHHMB-UHFFFAOYSA-N Dichloromethane Chemical compound ClCCl YMWUJEATGCHHMB-UHFFFAOYSA-N 0.000 description 3
- 238000005481 NMR spectroscopy Methods 0.000 description 3
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 description 3
- YNLAOSYQHBDIKW-UHFFFAOYSA-M diethylaluminium chloride Chemical compound CC[Al](Cl)CC YNLAOSYQHBDIKW-UHFFFAOYSA-M 0.000 description 3
- 125000005842 heteroatom Chemical group 0.000 description 3
- 230000000379 polymerizing effect Effects 0.000 description 3
- 150000003609 titanium compounds Chemical class 0.000 description 3
- 238000004438 BET method Methods 0.000 description 2
- NLZUEZXRPGMBCV-UHFFFAOYSA-N Butylhydroxytoluene Chemical compound CC1=CC(C(C)(C)C)=C(O)C(C(C)(C)C)=C1 NLZUEZXRPGMBCV-UHFFFAOYSA-N 0.000 description 2
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 2
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 2
- 239000004793 Polystyrene Substances 0.000 description 2
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 description 2
- 150000004945 aromatic hydrocarbons Chemical class 0.000 description 2
- 125000003118 aryl group Chemical group 0.000 description 2
- WPYMKLBDIGXBTP-UHFFFAOYSA-N benzoic acid Chemical compound OC(=O)C1=CC=CC=C1 WPYMKLBDIGXBTP-UHFFFAOYSA-N 0.000 description 2
- 238000012662 bulk polymerization Methods 0.000 description 2
- 239000007795 chemical reaction product Substances 0.000 description 2
- MVPPADPHJFYWMZ-UHFFFAOYSA-N chlorobenzene Chemical compound ClC1=CC=CC=C1 MVPPADPHJFYWMZ-UHFFFAOYSA-N 0.000 description 2
- NNBZCPXTIHJBJL-UHFFFAOYSA-N decalin Chemical compound C1CCCC2CCCCC21 NNBZCPXTIHJBJL-UHFFFAOYSA-N 0.000 description 2
- PPQUYYAZSOKTQD-UHFFFAOYSA-M diethylalumanylium;iodide Chemical compound CC[Al](I)CC PPQUYYAZSOKTQD-UHFFFAOYSA-M 0.000 description 2
- MTZQAGJQAFMTAQ-UHFFFAOYSA-N ethyl benzoate Chemical compound CCOC(=O)C1=CC=CC=C1 MTZQAGJQAFMTAQ-UHFFFAOYSA-N 0.000 description 2
- 239000007789 gas Substances 0.000 description 2
- 150000004820 halides Chemical class 0.000 description 2
- 150000008282 halocarbons Chemical class 0.000 description 2
- 150000002431 hydrogen Chemical class 0.000 description 2
- VNWKTOKETHGBQD-UHFFFAOYSA-N methane Natural products C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 description 2
- QPJVMBTYPHYUOC-UHFFFAOYSA-N methyl benzoate Chemical compound COC(=O)C1=CC=CC=C1 QPJVMBTYPHYUOC-UHFFFAOYSA-N 0.000 description 2
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 2
- 238000002156 mixing Methods 0.000 description 2
- 239000012071 phase Substances 0.000 description 2
- XNGIFLGASWRNHJ-UHFFFAOYSA-N phthalic acid Chemical compound OC(=O)C1=CC=CC=C1C(O)=O XNGIFLGASWRNHJ-UHFFFAOYSA-N 0.000 description 2
- 230000037048 polymerization activity Effects 0.000 description 2
- 238000002360 preparation method Methods 0.000 description 2
- 239000012429 reaction media Substances 0.000 description 2
- 239000002904 solvent Substances 0.000 description 2
- 230000003595 spectral effect Effects 0.000 description 2
- 238000001228 spectrum Methods 0.000 description 2
- 239000000126 substance Substances 0.000 description 2
- 239000006228 supernatant Substances 0.000 description 2
- 229910052719 titanium Inorganic materials 0.000 description 2
- VFIOZKTXVHLWRA-UHFFFAOYSA-N (2-ethylpiperidin-1-yl)-dimethoxy-(1,1,1-trifluoropropan-2-yl)silane Chemical compound CCC1CCCCN1[Si](OC)(OC)C(C)C(F)(F)F VFIOZKTXVHLWRA-UHFFFAOYSA-N 0.000 description 1
- 125000000008 (C1-C10) alkyl group Chemical group 0.000 description 1
- WSLDOOZREJYCGB-UHFFFAOYSA-N 1,2-Dichloroethane Chemical compound ClCCCl WSLDOOZREJYCGB-UHFFFAOYSA-N 0.000 description 1
- LIKMAJRDDDTEIG-UHFFFAOYSA-N 1-hexene Chemical compound CCCCC=C LIKMAJRDDDTEIG-UHFFFAOYSA-N 0.000 description 1
- 238000001644 13C nuclear magnetic resonance spectroscopy Methods 0.000 description 1
- 239000005711 Benzoic acid Substances 0.000 description 1
- OKTJSMMVPCPJKN-OUBTZVSYSA-N Carbon-13 Chemical compound [13C] OKTJSMMVPCPJKN-OUBTZVSYSA-N 0.000 description 1
- VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 description 1
- 239000006057 Non-nutritive feed additive Substances 0.000 description 1
- CTQNGGLPUBDAKN-UHFFFAOYSA-N O-Xylene Chemical compound CC1=CC=CC=C1C CTQNGGLPUBDAKN-UHFFFAOYSA-N 0.000 description 1
- BLRPTPMANUNPDV-UHFFFAOYSA-N Silane Chemical compound [SiH4] BLRPTPMANUNPDV-UHFFFAOYSA-N 0.000 description 1
- KDYFGRWQOYBRFD-UHFFFAOYSA-N Succinic acid Natural products OC(=O)CCC(O)=O KDYFGRWQOYBRFD-UHFFFAOYSA-N 0.000 description 1
- 239000004809 Teflon Substances 0.000 description 1
- 229920006362 Teflon® Polymers 0.000 description 1
- 238000002083 X-ray spectrum Methods 0.000 description 1
- 238000006653 Ziegler-Natta catalysis Methods 0.000 description 1
- 239000011954 Ziegler–Natta catalyst Substances 0.000 description 1
- 230000001133 acceleration Effects 0.000 description 1
- 230000004913 activation Effects 0.000 description 1
- 239000000654 additive Substances 0.000 description 1
- 125000005234 alkyl aluminium group Chemical group 0.000 description 1
- 239000003963 antioxidant agent Substances 0.000 description 1
- 150000007860 aryl ester derivatives Chemical class 0.000 description 1
- 150000005840 aryl radicals Chemical class 0.000 description 1
- 238000005452 bending Methods 0.000 description 1
- 235000010233 benzoic acid Nutrition 0.000 description 1
- 230000002902 bimodal effect Effects 0.000 description 1
- 238000009835 boiling Methods 0.000 description 1
- KDYFGRWQOYBRFD-NUQCWPJISA-N butanedioic acid Chemical compound O[14C](=O)CC[14C](O)=O KDYFGRWQOYBRFD-NUQCWPJISA-N 0.000 description 1
- IAQRGUVFOMOMEM-UHFFFAOYSA-N butene Natural products CC=CC IAQRGUVFOMOMEM-UHFFFAOYSA-N 0.000 description 1
- 238000004364 calculation method Methods 0.000 description 1
- 238000012512 characterization method Methods 0.000 description 1
- 230000000052 comparative effect Effects 0.000 description 1
- 238000005260 corrosion Methods 0.000 description 1
- 230000007797 corrosion Effects 0.000 description 1
- MEWFSXFFGFDHGV-UHFFFAOYSA-N cyclohexyl(trimethoxy)silane Chemical compound CO[Si](OC)(OC)C1CCCCC1 MEWFSXFFGFDHGV-UHFFFAOYSA-N 0.000 description 1
- SJJCABYOVIHNPZ-UHFFFAOYSA-N cyclohexyl-dimethoxy-methylsilane Chemical compound CO[Si](C)(OC)C1CCCCC1 SJJCABYOVIHNPZ-UHFFFAOYSA-N 0.000 description 1
- 230000007423 decrease Effects 0.000 description 1
- 230000001627 detrimental effect Effects 0.000 description 1
- JWCYDYZLEAQGJJ-UHFFFAOYSA-N dicyclopentyl(dimethoxy)silane Chemical compound C1CCCC1[Si](OC)(OC)C1CCCC1 JWCYDYZLEAQGJJ-UHFFFAOYSA-N 0.000 description 1
- 239000003085 diluting agent Substances 0.000 description 1
- AHUXYBVKTIBBJW-UHFFFAOYSA-N dimethoxy(diphenyl)silane Chemical compound C=1C=CC=CC=1[Si](OC)(OC)C1=CC=CC=C1 AHUXYBVKTIBBJW-UHFFFAOYSA-N 0.000 description 1
- VHPUZTHRFWIGAW-UHFFFAOYSA-N dimethoxy-di(propan-2-yl)silane Chemical compound CO[Si](OC)(C(C)C)C(C)C VHPUZTHRFWIGAW-UHFFFAOYSA-N 0.000 description 1
- 239000000839 emulsion Substances 0.000 description 1
- 150000002148 esters Chemical class 0.000 description 1
- 150000002170 ethers Chemical class 0.000 description 1
- 238000001125 extrusion Methods 0.000 description 1
- 239000000706 filtrate Substances 0.000 description 1
- 238000010528 free radical solution polymerization reaction Methods 0.000 description 1
- 238000000227 grinding Methods 0.000 description 1
- 125000005843 halogen group Chemical group 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- QWPPOHNGKGFGJK-UHFFFAOYSA-N hypochlorous acid Chemical class ClO QWPPOHNGKGFGJK-UHFFFAOYSA-N 0.000 description 1
- 239000003112 inhibitor Substances 0.000 description 1
- 238000002347 injection Methods 0.000 description 1
- 239000007924 injection Substances 0.000 description 1
- 239000011256 inorganic filler Substances 0.000 description 1
- 238000011835 investigation Methods 0.000 description 1
- 239000007791 liquid phase Substances 0.000 description 1
- 229920002521 macromolecule Polymers 0.000 description 1
- 238000005259 measurement Methods 0.000 description 1
- 238000002844 melting Methods 0.000 description 1
- 230000008018 melting Effects 0.000 description 1
- 239000012528 membrane Substances 0.000 description 1
- 229910052751 metal Inorganic materials 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- 229940095102 methyl benzoate Drugs 0.000 description 1
- 125000001570 methylene group Chemical group [H]C([H])([*:1])[*:2] 0.000 description 1
- 150000002763 monocarboxylic acids Chemical class 0.000 description 1
- YCWSUKQGVSGXJO-NTUHNPAUSA-N nifuroxazide Chemical group C1=CC(O)=CC=C1C(=O)N\N=C\C1=CC=C([N+]([O-])=O)O1 YCWSUKQGVSGXJO-NTUHNPAUSA-N 0.000 description 1
- 239000002667 nucleating agent Substances 0.000 description 1
- 239000012766 organic filler Substances 0.000 description 1
- XNGIFLGASWRNHJ-UHFFFAOYSA-L phthalate(2-) Chemical compound [O-]C(=O)C1=CC=CC=C1C([O-])=O XNGIFLGASWRNHJ-UHFFFAOYSA-L 0.000 description 1
- 230000000704 physical effect Effects 0.000 description 1
- 229920001748 polybutylene Polymers 0.000 description 1
- 229920000098 polyolefin Polymers 0.000 description 1
- 229920002223 polystyrene Polymers 0.000 description 1
- 239000011148 porous material Substances 0.000 description 1
- QQONPFPTGQHPMA-UHFFFAOYSA-N propylene Natural products CC=C QQONPFPTGQHPMA-UHFFFAOYSA-N 0.000 description 1
- 125000004805 propylene group Chemical group [H]C([H])([H])C([H])([*:1])C([H])([H])[*:2] 0.000 description 1
- 229920001384 propylene homopolymer Polymers 0.000 description 1
- 238000009666 routine test Methods 0.000 description 1
- 229910000077 silane Inorganic materials 0.000 description 1
- 239000012265 solid product Substances 0.000 description 1
- 239000012798 spherical particle Substances 0.000 description 1
- 239000003381 stabilizer Substances 0.000 description 1
- 150000003900 succinic acid esters Chemical class 0.000 description 1
- 239000000725 suspension Substances 0.000 description 1
- 238000010557 suspension polymerization reaction Methods 0.000 description 1
- HXLWJGIPGJFBEZ-UHFFFAOYSA-N tert-butyl(trimethoxy)silane Chemical compound CO[Si](OC)(OC)C(C)(C)C HXLWJGIPGJFBEZ-UHFFFAOYSA-N 0.000 description 1
- NETBVGNWMHLXRP-UHFFFAOYSA-N tert-butyl-dimethoxy-methylsilane Chemical compound CO[Si](C)(OC)C(C)(C)C NETBVGNWMHLXRP-UHFFFAOYSA-N 0.000 description 1
- 238000012360 testing method Methods 0.000 description 1
- SQBBHCOIQXKPHL-UHFFFAOYSA-N tributylalumane Chemical compound CCCC[Al](CCCC)CCCC SQBBHCOIQXKPHL-UHFFFAOYSA-N 0.000 description 1
- VOITXYVAKOUIBA-UHFFFAOYSA-N triethylaluminium Chemical compound CC[Al](CC)CC VOITXYVAKOUIBA-UHFFFAOYSA-N 0.000 description 1
- ORYGRKHDLWYTKX-UHFFFAOYSA-N trihexylalumane Chemical compound CCCCCC[Al](CCCCCC)CCCCCC ORYGRKHDLWYTKX-UHFFFAOYSA-N 0.000 description 1
- MCULRUJILOGHCJ-UHFFFAOYSA-N triisobutylaluminium Chemical compound CC(C)C[Al](CC(C)C)CC(C)C MCULRUJILOGHCJ-UHFFFAOYSA-N 0.000 description 1
- LFXVBWRMVZPLFK-UHFFFAOYSA-N trioctylalumane Chemical compound CCCCCCCC[Al](CCCCCCCC)CCCCCCCC LFXVBWRMVZPLFK-UHFFFAOYSA-N 0.000 description 1
- PXXNTAGJWPJAGM-UHFFFAOYSA-N vertaline Natural products C1C2C=3C=C(OC)C(OC)=CC=3OC(C=C3)=CC=C3CCC(=O)OC1CC1N2CCCC1 PXXNTAGJWPJAGM-UHFFFAOYSA-N 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
- 239000003643 water by type Substances 0.000 description 1
- 238000010626 work up procedure Methods 0.000 description 1
- 239000008096 xylene Substances 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
- C08F10/04—Monomers containing three or four carbon atoms
- C08F10/08—Butenes
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F16—ENGINEERING ELEMENTS AND UNITS; GENERAL MEASURES FOR PRODUCING AND MAINTAINING EFFECTIVE FUNCTIONING OF MACHINES OR INSTALLATIONS; THERMAL INSULATION IN GENERAL
- F16L—PIPES; JOINTS OR FITTINGS FOR PIPES; SUPPORTS FOR PIPES, CABLES OR PROTECTIVE TUBING; MEANS FOR THERMAL INSULATION IN GENERAL
- F16L9/00—Rigid pipes
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F110/00—Homopolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
- C08F110/04—Monomers containing three or four carbon atoms
- C08F110/08—Butenes
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F210/00—Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
- C08F210/04—Monomers containing three or four carbon atoms
- C08F210/08—Butenes
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- General Engineering & Computer Science (AREA)
- Mechanical Engineering (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
- Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Rigid Pipes And Flexible Pipes (AREA)
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| EP02077095 | 2002-05-29 | ||
| EP02077095 | 2002-05-29 | ||
| PCT/EP2003/003593 WO2003099883A1 (en) | 2002-05-29 | 2003-04-07 | Butene-1 (co)polymers and process for their preparation |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| DE60309020D1 DE60309020D1 (de) | 2006-11-23 |
| DE60309020T2 true DE60309020T2 (de) | 2007-05-10 |
Family
ID=29558381
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| DE60309020T Expired - Lifetime DE60309020T2 (de) | 2002-05-29 | 2003-04-07 | Buten-1-(co)polymere und verfahren zu ihrer herstellung |
Country Status (16)
| Country | Link |
|---|---|
| US (1) | US6998458B2 (enExample) |
| EP (1) | EP1507806B1 (enExample) |
| JP (2) | JP5255175B2 (enExample) |
| KR (1) | KR100892901B1 (enExample) |
| CN (1) | CN1294161C (enExample) |
| AR (1) | AR039858A1 (enExample) |
| AT (1) | ATE342288T1 (enExample) |
| AU (1) | AU2003229617A1 (enExample) |
| BR (1) | BR0304880A (enExample) |
| CA (1) | CA2452034A1 (enExample) |
| DE (1) | DE60309020T2 (enExample) |
| ES (1) | ES2272981T3 (enExample) |
| PL (1) | PL372289A1 (enExample) |
| RU (1) | RU2315063C2 (enExample) |
| TR (1) | TR200302316T1 (enExample) |
| WO (1) | WO2003099883A1 (enExample) |
Families Citing this family (29)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| BR0305247A (pt) * | 2002-06-13 | 2004-09-21 | Basell Poliolefine Spa | Processo de preparação de copolìmeros de etileno |
| KR100472771B1 (ko) | 2003-08-30 | 2005-03-14 | 주식회사 일렘테크놀러지홀딩스 | 고입체규칙성 폴리부텐-1 중합체 및 이의 고활성 제조방법 |
| EP1765886A1 (en) | 2004-07-13 | 2007-03-28 | Basell Polyolefine GmbH | Metallocene compounds, ligands used in their preparation, preparation of 1-butene polymers and 1-butene polymers therefrom |
| DE602005005334T2 (de) | 2004-07-22 | 2009-03-26 | Basell Polyolefine Gmbh | 1-butenpolymerzusammensetzung |
| KR20070043798A (ko) | 2004-07-22 | 2007-04-25 | 바젤 폴리올레핀 게엠베하 | 분획가능한 1-부텐 중합체의 제조방법 |
| JP5567764B2 (ja) * | 2004-10-18 | 2014-08-06 | バーゼル・ポリオレフィン・イタリア・ソチエタ・ア・レスポンサビリタ・リミタータ | 低アイソタクチシティを有するブテン−１（コ）ポリマー |
| CA2584395A1 (en) * | 2004-10-18 | 2006-04-27 | Basell Poliolefine Italia S.R.L. | Butene-1 (co)polymers having low isotacticity |
| KR20070080086A (ko) * | 2006-02-06 | 2007-08-09 | 주식회사 엘지화학 | 부텐-1 (공)중합체 및 그의 제조방법 |
| CN101522732B (zh) * | 2006-08-08 | 2012-06-13 | 巴塞尔聚烯烃意大利有限责任公司 | 1-丁烯共聚物 |
| JP5377307B2 (ja) * | 2006-08-08 | 2013-12-25 | バーゼル・ポリオレフィン・イタリア・ソチエタ・ア・レスポンサビリタ・リミタータ | ブテン−１コポリマー |
| ATE482982T1 (de) | 2007-04-27 | 2010-10-15 | Basell Poliolefine Srl | Buten-1-terpolymere und herstellungsverfahren dafür |
| EP2215166B1 (en) * | 2007-11-27 | 2014-06-04 | Basell Poliolefine Italia S.r.l. | Mixtures of bitumen and polymer compositions |
| EP2222781B1 (en) | 2007-12-18 | 2014-01-15 | Basell Poliolefine Italia S.r.l. | Transparent polyolefin compositions |
| EP2254919A1 (en) * | 2008-03-20 | 2010-12-01 | Basell Poliolefine Italia S.R.L. | 1-butene copolymers |
| BRPI0910237A2 (pt) * | 2008-03-20 | 2015-09-29 | Basell Poliolefine Srl | copolímeros de 1-buteno |
| KR20100133987A (ko) * | 2008-03-20 | 2010-12-22 | 바셀 폴리올레핀 이탈리아 에스.알.엘 | 1-부텐 삼원중합체 |
| JP2011515518A (ja) * | 2008-03-20 | 2011-05-19 | バーゼル・ポリオレフィン・イタリア・ソチエタ・ア・レスポンサビリタ・リミタータ | １−ブテン系ポリマー類の組成物類 |
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| KR101632090B1 (ko) * | 2008-09-24 | 2016-06-20 | 바셀 폴리올레핀 이탈리아 에스.알.엘 | 양호한 백화 저항성을 갖는 폴리올레핀 조성물 |
| RU2381236C1 (ru) * | 2008-09-25 | 2010-02-10 | Институт Катализа Им. Г.К. Борескова Сибирского Отделения Российской Академии Наук | Катализатор и способ получения полиэтилена и сополимеров этилена с альфа-олефинами с узким молекулярно-массовым распределением |
| SG172819A1 (en) * | 2008-12-31 | 2011-08-29 | Dow Global Technologies Llc | Enhanced procatalyst composition and process |
| EP2671894A1 (en) | 2012-06-08 | 2013-12-11 | Basell Poliolefine Italia S.r.l. | Catalyst components for the polymerization of butene-1 |
| EP2757114A1 (en) | 2013-01-18 | 2014-07-23 | Basell Poliolefine Italia S.r.l. | Catalyst components for the polymerization of olefins |
| CN103288993B (zh) * | 2013-07-01 | 2015-06-03 | 青岛科技大学 | 高等规度球形聚丁烯-1及其制备方法 |
| CN106893020B (zh) * | 2015-12-17 | 2019-10-11 | 中国石油天然气股份有限公司 | 一种球形聚丁烯-1的制备方法 |
| CN106893021B (zh) * | 2015-12-17 | 2019-03-12 | 中国石油天然气股份有限公司 | 一种高等规度聚丁烯-1的合成方法 |
| CN106893007B (zh) * | 2015-12-17 | 2019-05-07 | 中国石油天然气股份有限公司 | 一种高等规度球形聚丁烯-1的制备方法 |
| WO2020127296A1 (en) * | 2018-12-19 | 2020-06-25 | Basell Poliolefine Italia S.R.L. | Polyolefin fibres |
| CN115819648B (zh) * | 2023-02-20 | 2023-05-09 | 山东东方宏业新材料科技有限公司 | 一种基于连续法的聚丁烯-1的生产工艺及生产系统 |
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| GB1603724A (en) * | 1977-05-25 | 1981-11-25 | Montedison Spa | Components and catalysts for the polymerisation of alpha-olefins |
| IT1096661B (it) * | 1978-06-13 | 1985-08-26 | Montedison Spa | Procedimento per la preparazione di prodotti in forma sferoidale solidi a temperatura ambiente |
| IT1098272B (it) * | 1978-08-22 | 1985-09-07 | Montedison Spa | Componenti,di catalizzatori e catalizzatori per la polimerizzazione delle alfa-olefine |
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| IT1230134B (it) | 1989-04-28 | 1991-10-14 | Himont Inc | Componenti e catalizzatori per la polimerizzazione di olefine. |
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| IT1262933B (it) * | 1992-01-31 | 1996-07-22 | Montecatini Tecnologie Srl | Processo per la polimerizzazione in fase gas di alfa-olefine |
| IT1262934B (it) | 1992-01-31 | 1996-07-22 | Montecatini Tecnologie Srl | Componenti e catalizzatori per la polimerizzazione di olefine |
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-
2003
- 2003-04-07 DE DE60309020T patent/DE60309020T2/de not_active Expired - Lifetime
- 2003-04-07 BR BR0304880-2A patent/BR0304880A/pt not_active IP Right Cessation
- 2003-04-07 WO PCT/EP2003/003593 patent/WO2003099883A1/en not_active Ceased
- 2003-04-07 CA CA002452034A patent/CA2452034A1/en not_active Abandoned
- 2003-04-07 RU RU2004102908/04A patent/RU2315063C2/ru active
- 2003-04-07 KR KR1020047010399A patent/KR100892901B1/ko not_active Expired - Lifetime
- 2003-04-07 CN CNB038007363A patent/CN1294161C/zh not_active Expired - Lifetime
- 2003-04-07 JP JP2004508136A patent/JP5255175B2/ja not_active Expired - Lifetime
- 2003-04-07 ES ES03722409T patent/ES2272981T3/es not_active Expired - Lifetime
- 2003-04-07 AT AT03722409T patent/ATE342288T1/de not_active IP Right Cessation
- 2003-04-07 US US10/490,097 patent/US6998458B2/en not_active Expired - Lifetime
- 2003-04-07 AU AU2003229617A patent/AU2003229617A1/en not_active Abandoned
- 2003-04-07 TR TR2003/02316T patent/TR200302316T1/xx unknown
- 2003-04-07 EP EP03722409A patent/EP1507806B1/en not_active Expired - Lifetime
- 2003-04-07 PL PL03372289A patent/PL372289A1/xx unknown
- 2003-05-23 AR ARP030101800A patent/AR039858A1/es unknown
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Also Published As
| Publication number | Publication date |
|---|---|
| JP2013136770A (ja) | 2013-07-11 |
| JP2005527676A (ja) | 2005-09-15 |
| RU2315063C2 (ru) | 2008-01-20 |
| DE60309020D1 (de) | 2006-11-23 |
| EP1507806B1 (en) | 2006-10-11 |
| WO2003099883A1 (en) | 2003-12-04 |
| CN1294161C (zh) | 2007-01-10 |
| RU2004102908A (ru) | 2005-06-10 |
| AR039858A1 (es) | 2005-03-02 |
| US6998458B2 (en) | 2006-02-14 |
| KR20040111341A (ko) | 2004-12-31 |
| ATE342288T1 (de) | 2006-11-15 |
| US20040254313A1 (en) | 2004-12-16 |
| KR100892901B1 (ko) | 2009-04-15 |
| TR200302316T1 (tr) | 2005-04-21 |
| AU2003229617A1 (en) | 2003-12-12 |
| PL372289A1 (en) | 2005-07-11 |
| EP1507806A1 (en) | 2005-02-23 |
| ES2272981T3 (es) | 2007-05-01 |
| CA2452034A1 (en) | 2003-12-04 |
| CN1537122A (zh) | 2004-10-13 |
| BR0304880A (pt) | 2004-08-03 |
| JP5255175B2 (ja) | 2013-08-07 |
| JP5670495B2 (ja) | 2015-02-18 |
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