DE60221398T2 - Pvc-lebensmittelverpackung enthaltend dioctylterephthalat-weichmacher, verfahr en zu deren herstellung, und verfahren zur umhüllung von nahrungsmitteln damit - Google Patents
Pvc-lebensmittelverpackung enthaltend dioctylterephthalat-weichmacher, verfahr en zu deren herstellung, und verfahren zur umhüllung von nahrungsmitteln damit Download PDFInfo
- Publication number
- DE60221398T2 DE60221398T2 DE60221398T DE60221398T DE60221398T2 DE 60221398 T2 DE60221398 T2 DE 60221398T2 DE 60221398 T DE60221398 T DE 60221398T DE 60221398 T DE60221398 T DE 60221398T DE 60221398 T2 DE60221398 T2 DE 60221398T2
- Authority
- DE
- Germany
- Prior art keywords
- plasticizer
- food
- food packaging
- polyvinyl chloride
- packaging material
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- 235000013305 food Nutrition 0.000 title claims abstract description 31
- 238000000034 method Methods 0.000 title claims abstract description 20
- 238000004519 manufacturing process Methods 0.000 title claims description 9
- 238000004806 packaging method and process Methods 0.000 title description 6
- APSBXTVYXVQYAB-UHFFFAOYSA-M sodium docusate Chemical compound [Na+].CCCCC(CC)COC(=O)CC(S([O-])(=O)=O)C(=O)OCC(CC)CCCC APSBXTVYXVQYAB-UHFFFAOYSA-M 0.000 title description 2
- 239000004014 plasticizer Substances 0.000 claims abstract description 65
- OEIWPNWSDYFMIL-UHFFFAOYSA-N dioctyl benzene-1,4-dicarboxylate Chemical compound CCCCCCCCOC(=O)C1=CC=C(C(=O)OCCCCCCCC)C=C1 OEIWPNWSDYFMIL-UHFFFAOYSA-N 0.000 claims abstract description 44
- 239000004800 polyvinyl chloride Substances 0.000 claims abstract description 39
- 229920000915 polyvinyl chloride Polymers 0.000 claims abstract description 38
- ZFMQKOWCDKKBIF-UHFFFAOYSA-N bis(3,5-difluorophenyl)phosphane Chemical compound FC1=CC(F)=CC(PC=2C=C(F)C=C(F)C=2)=C1 ZFMQKOWCDKKBIF-UHFFFAOYSA-N 0.000 claims abstract description 27
- 239000003381 stabilizer Substances 0.000 claims abstract description 9
- 239000005003 food packaging material Substances 0.000 claims description 18
- 239000000843 powder Substances 0.000 claims description 5
- 239000011888 foil Substances 0.000 claims description 2
- 229920000642 polymer Polymers 0.000 claims description 2
- 239000000203 mixture Substances 0.000 abstract description 26
- 239000011876 fused mixture Substances 0.000 abstract 1
- 238000012360 testing method Methods 0.000 description 21
- VLKZOEOYAKHREP-UHFFFAOYSA-N n-Hexane Chemical compound CCCCCC VLKZOEOYAKHREP-UHFFFAOYSA-N 0.000 description 15
- 238000000605 extraction Methods 0.000 description 14
- 239000000523 sample Substances 0.000 description 13
- 229920006280 packaging film Polymers 0.000 description 11
- 239000012785 packaging film Substances 0.000 description 11
- 230000004580 weight loss Effects 0.000 description 11
- 239000004615 ingredient Substances 0.000 description 9
- 239000011347 resin Substances 0.000 description 9
- 229920005989 resin Polymers 0.000 description 9
- 230000005012 migration Effects 0.000 description 8
- 238000013508 migration Methods 0.000 description 8
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 7
- 239000011575 calcium Substances 0.000 description 7
- 229910052799 carbon Inorganic materials 0.000 description 7
- 239000007788 liquid Substances 0.000 description 6
- 239000011701 zinc Substances 0.000 description 6
- 239000000463 material Substances 0.000 description 5
- KKEYFWRCBNTPAC-UHFFFAOYSA-N Terephthalic acid Chemical compound OC(=O)C1=CC=C(C(O)=O)C=C1 KKEYFWRCBNTPAC-UHFFFAOYSA-N 0.000 description 4
- 235000012343 cottonseed oil Nutrition 0.000 description 4
- 239000002385 cottonseed oil Substances 0.000 description 4
- 238000009472 formulation Methods 0.000 description 4
- 150000002148 esters Chemical class 0.000 description 3
- 238000002844 melting Methods 0.000 description 3
- 230000008018 melting Effects 0.000 description 3
- 238000012856 packing Methods 0.000 description 3
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 3
- 238000003809 water extraction Methods 0.000 description 3
- BZHJMEDXRYGGRV-UHFFFAOYSA-N Vinyl chloride Chemical compound ClC=C BZHJMEDXRYGGRV-UHFFFAOYSA-N 0.000 description 2
- IHBCFWWEZXPPLG-UHFFFAOYSA-N [Ca].[Zn] Chemical compound [Ca].[Zn] IHBCFWWEZXPPLG-UHFFFAOYSA-N 0.000 description 2
- 230000015572 biosynthetic process Effects 0.000 description 2
- 239000003814 drug Substances 0.000 description 2
- 229940079593 drug Drugs 0.000 description 2
- 239000011521 glass Substances 0.000 description 2
- 230000006872 improvement Effects 0.000 description 2
- QQVIHTHCMHWDBS-UHFFFAOYSA-N isophthalic acid Chemical compound OC(=O)C1=CC=CC(C(O)=O)=C1 QQVIHTHCMHWDBS-UHFFFAOYSA-N 0.000 description 2
- 239000000155 melt Substances 0.000 description 2
- 230000000704 physical effect Effects 0.000 description 2
- 230000008569 process Effects 0.000 description 2
- 239000007787 solid Substances 0.000 description 2
- 230000002745 absorbent Effects 0.000 description 1
- 239000002250 absorbent Substances 0.000 description 1
- WNLRTRBMVRJNCN-UHFFFAOYSA-L adipate(2-) Chemical compound [O-]C(=O)CCCCC([O-])=O WNLRTRBMVRJNCN-UHFFFAOYSA-L 0.000 description 1
- 238000013459 approach Methods 0.000 description 1
- 230000005540 biological transmission Effects 0.000 description 1
- SAOKZLXYCUGLFA-UHFFFAOYSA-N bis(2-ethylhexyl) adipate Chemical compound CCCCC(CC)COC(=O)CCCCC(=O)OCC(CC)CCCC SAOKZLXYCUGLFA-UHFFFAOYSA-N 0.000 description 1
- 239000003610 charcoal Substances 0.000 description 1
- 238000007906 compression Methods 0.000 description 1
- 230000006835 compression Effects 0.000 description 1
- 229920001577 copolymer Polymers 0.000 description 1
- 238000005520 cutting process Methods 0.000 description 1
- 230000003467 diminishing effect Effects 0.000 description 1
- 238000001647 drug administration Methods 0.000 description 1
- 230000009969 flowable effect Effects 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- 229920001519 homopolymer Polymers 0.000 description 1
- 239000000944 linseed oil Substances 0.000 description 1
- 235000021388 linseed oil Nutrition 0.000 description 1
- 239000005022 packaging material Substances 0.000 description 1
- 239000002245 particle Substances 0.000 description 1
- 230000035699 permeability Effects 0.000 description 1
- 230000009467 reduction Effects 0.000 description 1
- 239000011342 resin composition Substances 0.000 description 1
- 238000005096 rolling process Methods 0.000 description 1
- 239000000344 soap Substances 0.000 description 1
- 239000003549 soybean oil Substances 0.000 description 1
- 235000012424 soybean oil Nutrition 0.000 description 1
- 230000003068 static effect Effects 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 239000012855 volatile organic compound Substances 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J5/00—Manufacture of articles or shaped materials containing macromolecular substances
- C08J5/18—Manufacture of films or sheets
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B65—CONVEYING; PACKING; STORING; HANDLING THIN OR FILAMENTARY MATERIAL
- B65D—CONTAINERS FOR STORAGE OR TRANSPORT OF ARTICLES OR MATERIALS, e.g. BAGS, BARRELS, BOTTLES, BOXES, CANS, CARTONS, CRATES, DRUMS, JARS, TANKS, HOPPERS, FORWARDING CONTAINERS; ACCESSORIES, CLOSURES, OR FITTINGS THEREFOR; PACKAGING ELEMENTS; PACKAGES
- B65D65/00—Wrappers or flexible covers; Packaging materials of special type or form
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/04—Oxygen-containing compounds
- C08K5/10—Esters; Ether-esters
- C08K5/12—Esters; Ether-esters of cyclic polycarboxylic acids
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2327/00—Characterised by the use of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Derivatives of such polymers
- C08J2327/02—Characterised by the use of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Derivatives of such polymers not modified by chemical after-treatment
- C08J2327/04—Characterised by the use of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Derivatives of such polymers not modified by chemical after-treatment containing chlorine atoms
- C08J2327/06—Homopolymers or copolymers of vinyl chloride
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Manufacturing & Machinery (AREA)
- Health & Medical Sciences (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Materials Engineering (AREA)
- Mechanical Engineering (AREA)
- Wrappers (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Manufacture Of Macromolecular Shaped Articles (AREA)
- Packging For Living Organisms, Food Or Medicinal Products That Are Sensitive To Environmental Conditiond (AREA)
- Treatments Of Macromolecular Shaped Articles (AREA)
- Laminated Bodies (AREA)
Applications Claiming Priority (5)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US30141201P | 2001-06-29 | 2001-06-29 | |
| US301412P | 2001-06-29 | ||
| US09/992,483 US6675560B2 (en) | 2001-06-29 | 2001-11-26 | PVC food wrap formed from dioctyl terphthalate plasticizer, method of forming same and method of wrapping food therewith |
| US992483 | 2001-11-26 | ||
| PCT/US2002/019265 WO2003002640A1 (en) | 2001-06-29 | 2002-06-18 | Pvc food wrap formed from dioctyl terphthalate plasticizer, method of forming same and method of wrapping food therewith |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| DE60221398D1 DE60221398D1 (de) | 2007-09-06 |
| DE60221398T2 true DE60221398T2 (de) | 2008-02-21 |
Family
ID=26972352
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| DE60221398T Expired - Lifetime DE60221398T2 (de) | 2001-06-29 | 2002-06-18 | Pvc-lebensmittelverpackung enthaltend dioctylterephthalat-weichmacher, verfahr en zu deren herstellung, und verfahren zur umhüllung von nahrungsmitteln damit |
Country Status (6)
| Country | Link |
|---|---|
| US (1) | US6675560B2 (enExample) |
| EP (1) | EP1406954B1 (enExample) |
| JP (1) | JP4373205B2 (enExample) |
| AT (1) | ATE368068T1 (enExample) |
| DE (1) | DE60221398T2 (enExample) |
| WO (1) | WO2003002640A1 (enExample) |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2016005357A1 (de) * | 2014-07-08 | 2016-01-14 | Basf Se | Weichmacher-zusammensetzung, die aliphatische dicarbonsäureester und terephthalsäuredialkylester enthält |
| RU2681631C1 (ru) * | 2018-03-29 | 2019-03-11 | Федеральное государственное бюджетное образовательное учреждение высшего образования "Уфимский государственный нефтяной технический университет" | Пластификатор поливинилхлорида |
Families Citing this family (32)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| ES2242831T3 (es) * | 2002-06-28 | 2005-11-16 | THE PROCTER & GAMBLE COMPANY | Metodo y aparato para fabricar bolsas llenas y precintadas. |
| WO2006063147A2 (en) * | 2004-12-08 | 2006-06-15 | Kenneth Robert Hepp | Software system for automated design in multi-step sheet metal forming |
| US8524731B2 (en) * | 2005-03-07 | 2013-09-03 | The University Of Chicago | Use of opioid antagonists to attenuate endothelial cell proliferation and migration |
| US8372912B2 (en) | 2005-08-12 | 2013-02-12 | Eastman Chemical Company | Polyvinyl chloride compositions |
| DE102006001795A1 (de) * | 2006-01-12 | 2007-07-19 | Oxeno Olefinchemie Gmbh | Terephthalsäuredialkylester und deren Verwendung |
| US7594586B2 (en) * | 2006-08-05 | 2009-09-29 | Cai Edward Z | Vacuum generating device for sealing perishable products and method of use |
| PL2057241T3 (pl) * | 2006-08-30 | 2012-12-31 | Eastman Chem Co | Tereftalany jako plastyfikatory w kompozycjach polimeru octanu winylu |
| EP2057243B1 (en) | 2006-08-30 | 2013-01-23 | Eastman Chemical Company | Sealant compositions having a novel plasticizer |
| KR100812512B1 (ko) | 2007-06-25 | 2008-03-11 | 주식회사 엘지화학 | 지우개용 염화비닐계 수지 조성물 |
| KR100872686B1 (ko) | 2007-06-26 | 2008-12-10 | 주식회사 엘지화학 | 전선 외장 피복재용 염화비닐계 수지 조성물 |
| KR100838474B1 (ko) | 2007-06-26 | 2008-06-16 | 주식회사 엘지화학 | 투명 연질 시트용 염화비닐계 수지 조성물 |
| US20120128844A1 (en) * | 2010-03-31 | 2012-05-24 | Katherine Gentry | Food Safe Vinyl Fondant Mat |
| JP6059911B2 (ja) * | 2011-08-31 | 2017-01-11 | リケンテクノス株式会社 | 塩化ビニル樹脂組成物 |
| US9993389B2 (en) | 2011-09-19 | 2018-06-12 | Fenwal, Inc. | Red blood cell products and the storage of red blood cells in containers free of phthalate plasticizer |
| CN102504437B (zh) * | 2011-10-19 | 2013-10-30 | 江南大学 | 一种环保型聚氯乙烯一次性手套的制备方法 |
| CN103975010B (zh) * | 2012-10-10 | 2016-04-20 | Lg化学株式会社 | 增塑剂、增塑剂组合物、耐热树脂组合物及其制备方法 |
| US9085670B2 (en) | 2012-10-10 | 2015-07-21 | Lg Chem, Ltd. | Plasticizer, plasticizer composition, heat-resistant resin composition and method for preparing the same |
| US10398625B2 (en) | 2013-03-13 | 2019-09-03 | Fenwal, Inc. | Medical containers with terephthalate plasticizer for storing red blood cell products |
| JP5895895B2 (ja) * | 2013-04-23 | 2016-03-30 | 住友金属鉱山株式会社 | 熱線遮蔽塩化ビニルフィルム製造用組成物およびその製造方法、並びに、熱線遮蔽塩化ビニルフィルム、熱線遮蔽合わせ透明基材 |
| DE202013105795U1 (de) * | 2013-12-19 | 2014-02-11 | Konrad Hornschuch Ag | Flächengebilde und daraus hergestellte Tischdecke |
| US9309183B2 (en) * | 2014-02-20 | 2016-04-12 | Basf Corporation | Plasticizer composition comprising di(2-ethylhexyl) terephthalate |
| KR102554521B1 (ko) | 2014-02-20 | 2023-07-11 | 프레제니우스 카비 도이치란트 게엠베하 | 적혈구 제품, 혈장 및 혈소판의 보관을 위한 비-ｄｅｈｐ 가소제를 갖는 의료용 컨테이너 및 시스템 구성요소 |
| EP3112409A1 (en) | 2015-06-30 | 2017-01-04 | Scg Chemicals Co. Ltd. | Plasticizer composition |
| JP6503947B2 (ja) * | 2015-07-13 | 2019-04-24 | 日立金属株式会社 | 塩化ビニル樹脂組成物並びにこれを用いた電線及びケーブル |
| ES2744073T3 (es) * | 2015-09-30 | 2020-02-21 | Basf Se | Composición de plastificante que contiene ésteres de ácido dicarboxílico poliméricos y dialquilésteres de ácido tereftálico |
| CN106609010A (zh) * | 2015-10-22 | 2017-05-03 | 闫允璋 | 一种改性pvc防水材料 |
| CN106609012A (zh) * | 2015-10-22 | 2017-05-03 | 闫允璋 | 一种耐寒pvc防水材料 |
| KR101675556B1 (ko) * | 2016-01-29 | 2016-11-14 | 대덕인더스트리 주식회사 | 전선 피복재료용 수지 조성물 및 전선 피복재료용 펠릿의 제조방법 |
| CN109563305A (zh) * | 2016-08-01 | 2019-04-02 | 巴斯夫欧洲公司 | 增塑剂组合物 |
| KR102710486B1 (ko) * | 2018-11-22 | 2024-09-27 | 애경케미칼주식회사 | 가소제 조성물 및 이를 이용한 수지 조성물 |
| CN114773745A (zh) * | 2022-03-10 | 2022-07-22 | 镇江双晟新材料有限公司 | 一种pvc低收缩地板膜及其制备方法 |
| CN115725144B (zh) * | 2022-12-21 | 2023-08-18 | 江南大学 | 一种耐变形的家用游泳池聚氯乙烯膜材料 |
Family Cites Families (12)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US2671769A (en) | 1953-01-02 | 1954-03-09 | Monsanto Chemicals | Reduction of extraction of dioctylphthalates from plasticized vinyl chloride polymer compositions |
| GB851753A (en) | 1956-11-23 | 1960-10-19 | Union Carbide Corp | Vinyl chloride resin compositions |
| FR1508345A (fr) | 1966-11-24 | 1968-01-05 | Composition de résines vinyliques, notamment pour pellicules rétractables | |
| US3929867A (en) | 1973-08-06 | 1975-12-30 | Eastman Kodak Co | Mixed ester plastic additive |
| DE3123465A1 (de) | 1981-06-12 | 1982-12-30 | Perstorp AB, 28400 Perstorp | Sekundaerstabilisator, hauptsaechlich fuer vinylchloridpolymere |
| US4929749A (en) * | 1989-03-15 | 1990-05-29 | Synergistics Industries, Limited | Production of terephthalate esters by degradative transesterification of scrap or virgin terephthalate polyesters |
| US5101064A (en) * | 1989-03-15 | 1992-03-31 | Synergistics Industries Limited | Production of terephthalate esters by degradative transesterification of scrap or virgin terephthalate polyesters |
| US5272236A (en) | 1991-10-15 | 1993-12-21 | The Dow Chemical Company | Elastic substantially linear olefin polymers |
| JPH0958612A (ja) * | 1995-08-25 | 1997-03-04 | Hoshizaki Electric Co Ltd | 食品のパック方法 |
| JP3712308B2 (ja) * | 1997-03-14 | 2005-11-02 | 旭電化工業株式会社 | 食品包装フィルム用ポリ塩化ビニル系樹脂組成物 |
| US6235363B1 (en) * | 1998-05-06 | 2001-05-22 | Avery Dennison Corporation | Composite construction containing barrier layer |
| JP2000290418A (ja) * | 1999-04-06 | 2000-10-17 | Asahi Denka Kogyo Kk | 発泡成形用塩化ビニル系樹脂組成物 |
-
2001
- 2001-11-26 US US09/992,483 patent/US6675560B2/en not_active Expired - Lifetime
-
2002
- 2002-06-18 AT AT02739918T patent/ATE368068T1/de not_active IP Right Cessation
- 2002-06-18 DE DE60221398T patent/DE60221398T2/de not_active Expired - Lifetime
- 2002-06-18 EP EP02739918A patent/EP1406954B1/en not_active Expired - Lifetime
- 2002-06-18 WO PCT/US2002/019265 patent/WO2003002640A1/en not_active Ceased
- 2002-06-18 JP JP2003509016A patent/JP4373205B2/ja not_active Expired - Fee Related
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2016005357A1 (de) * | 2014-07-08 | 2016-01-14 | Basf Se | Weichmacher-zusammensetzung, die aliphatische dicarbonsäureester und terephthalsäuredialkylester enthält |
| RU2681631C1 (ru) * | 2018-03-29 | 2019-03-11 | Федеральное государственное бюджетное образовательное учреждение высшего образования "Уфимский государственный нефтяной технический университет" | Пластификатор поливинилхлорида |
Also Published As
| Publication number | Publication date |
|---|---|
| JP4373205B2 (ja) | 2009-11-25 |
| WO2003002640A1 (en) | 2003-01-09 |
| EP1406954A1 (en) | 2004-04-14 |
| ATE368068T1 (de) | 2007-08-15 |
| DE60221398D1 (de) | 2007-09-06 |
| US6675560B2 (en) | 2004-01-13 |
| JP2005517045A (ja) | 2005-06-09 |
| EP1406954B1 (en) | 2007-07-25 |
| US20030014948A1 (en) | 2003-01-23 |
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