DE60129817T2 - Polymermassen auf basis von linearem polyethylen sehr niedriger dichte und polyethylen hoher dichte (hdpe) - Google Patents
Polymermassen auf basis von linearem polyethylen sehr niedriger dichte und polyethylen hoher dichte (hdpe) Download PDFInfo
- Publication number
- DE60129817T2 DE60129817T2 DE60129817T DE60129817T DE60129817T2 DE 60129817 T2 DE60129817 T2 DE 60129817T2 DE 60129817 T DE60129817 T DE 60129817T DE 60129817 T DE60129817 T DE 60129817T DE 60129817 T2 DE60129817 T2 DE 60129817T2
- Authority
- DE
- Germany
- Prior art keywords
- polymer
- film
- vldpe
- density polyethylene
- hdpe
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
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- 229920000642 polymer Polymers 0.000 title claims abstract description 192
- 230000009021 linear effect Effects 0.000 title claims abstract description 22
- 229920001903 high density polyethylene Polymers 0.000 title claims description 97
- 239000004700 high-density polyethylene Substances 0.000 title claims description 97
- -1 POLYETHYLENE Polymers 0.000 title claims description 83
- 229920000573 polyethylene Polymers 0.000 title claims description 20
- 239000004698 Polyethylene Substances 0.000 title claims description 19
- 229920001866 very low density polyethylene Polymers 0.000 claims abstract description 138
- 239000004708 Very-low-density polyethylene Substances 0.000 claims abstract description 137
- 239000000203 mixture Substances 0.000 claims abstract description 120
- 229920002959 polymer blend Polymers 0.000 claims abstract description 48
- 238000000034 method Methods 0.000 claims description 118
- 238000009826 distribution Methods 0.000 claims description 45
- 239000000155 melt Substances 0.000 claims description 33
- 229920001577 copolymer Polymers 0.000 claims description 26
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 claims description 21
- 239000005977 Ethylene Substances 0.000 claims description 21
- 239000004711 α-olefin Substances 0.000 claims description 20
- 239000002356 single layer Substances 0.000 claims description 19
- 238000005259 measurement Methods 0.000 claims description 15
- 239000011888 foil Substances 0.000 claims description 13
- 239000000758 substrate Substances 0.000 claims description 11
- 239000012968 metallocene catalyst Substances 0.000 abstract description 35
- 229920000092 linear low density polyethylene Polymers 0.000 abstract description 22
- 239000004707 linear low-density polyethylene Substances 0.000 abstract description 22
- 229920010126 Linear Low Density Polyethylene (LLDPE) Polymers 0.000 abstract 1
- 239000010408 film Substances 0.000 description 149
- 239000010410 layer Substances 0.000 description 68
- 239000003054 catalyst Substances 0.000 description 55
- 230000008569 process Effects 0.000 description 55
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- 239000007789 gas Substances 0.000 description 41
- 239000002516 radical scavenger Substances 0.000 description 36
- 239000000047 product Substances 0.000 description 30
- 239000000178 monomer Substances 0.000 description 29
- NFHFRUOZVGFOOS-UHFFFAOYSA-N palladium;triphenylphosphane Chemical compound [Pd].C1=CC=CC=C1P(C=1C=CC=CC=1)C1=CC=CC=C1.C1=CC=CC=C1P(C=1C=CC=CC=1)C1=CC=CC=C1.C1=CC=CC=C1P(C=1C=CC=CC=1)C1=CC=CC=C1.C1=CC=CC=C1P(C=1C=CC=CC=1)C1=CC=CC=C1 NFHFRUOZVGFOOS-UHFFFAOYSA-N 0.000 description 27
- 238000006116 polymerization reaction Methods 0.000 description 27
- 239000003446 ligand Substances 0.000 description 26
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- 239000012071 phase Substances 0.000 description 22
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- 238000012685 gas phase polymerization Methods 0.000 description 21
- 239000007788 liquid Substances 0.000 description 20
- VPGLGRNSAYHXPY-UHFFFAOYSA-L zirconium(2+);dichloride Chemical compound Cl[Zr]Cl VPGLGRNSAYHXPY-UHFFFAOYSA-L 0.000 description 20
- 239000012190 activator Substances 0.000 description 19
- 125000000058 cyclopentadienyl group Chemical group C1(=CC=CC1)* 0.000 description 19
- 238000004519 manufacturing process Methods 0.000 description 19
- UHOVQNZJYSORNB-UHFFFAOYSA-N Benzene Chemical compound C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 description 18
- 125000004432 carbon atom Chemical group C* 0.000 description 18
- LIKMAJRDDDTEIG-UHFFFAOYSA-N 1-hexene Chemical compound CCCCC=C LIKMAJRDDDTEIG-UHFFFAOYSA-N 0.000 description 17
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- 239000002184 metal Substances 0.000 description 17
- 229910052723 transition metal Inorganic materials 0.000 description 17
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- 150000001993 dienes Chemical class 0.000 description 16
- KWKAKUADMBZCLK-UHFFFAOYSA-N 1-octene Chemical compound CCCCCCC=C KWKAKUADMBZCLK-UHFFFAOYSA-N 0.000 description 15
- 125000001183 hydrocarbyl group Chemical group 0.000 description 15
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 15
- 150000001450 anions Chemical class 0.000 description 14
- 238000006243 chemical reaction Methods 0.000 description 14
- 125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 description 13
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- 125000005842 heteroatom Chemical group 0.000 description 11
- 125000001436 propyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])[H] 0.000 description 11
- 238000012360 testing method Methods 0.000 description 11
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- 239000004702 low-density polyethylene Substances 0.000 description 10
- 150000003254 radicals Chemical class 0.000 description 10
- 239000000243 solution Substances 0.000 description 10
- HECLRDQVFMWTQS-RGOKHQFPSA-N 1755-01-7 Chemical compound C1[C@H]2[C@@H]3CC=C[C@@H]3[C@@H]1C=C2 HECLRDQVFMWTQS-RGOKHQFPSA-N 0.000 description 9
- 229910052796 boron Inorganic materials 0.000 description 9
- INYHZQLKOKTDAI-UHFFFAOYSA-N 5-ethenylbicyclo[2.2.1]hept-2-ene Chemical compound C1C2C(C=C)CC1C=C2 INYHZQLKOKTDAI-UHFFFAOYSA-N 0.000 description 8
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 description 8
- 229910052782 aluminium Inorganic materials 0.000 description 8
- 238000001816 cooling Methods 0.000 description 8
- 238000010828 elution Methods 0.000 description 8
- 239000012530 fluid Substances 0.000 description 8
- 229910052736 halogen Inorganic materials 0.000 description 8
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- 230000000670 limiting effect Effects 0.000 description 8
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- TVMXDCGIABBOFY-UHFFFAOYSA-N n-Octanol Natural products CCCCCCCC TVMXDCGIABBOFY-UHFFFAOYSA-N 0.000 description 8
- 229910052757 nitrogen Inorganic materials 0.000 description 8
- 239000004215 Carbon black (E152) Substances 0.000 description 7
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- 125000004122 cyclic group Chemical group 0.000 description 7
- 239000012954 diazonium Substances 0.000 description 7
- IJGRMHOSHXDMSA-UHFFFAOYSA-O diazynium Chemical compound [NH+]#N IJGRMHOSHXDMSA-UHFFFAOYSA-O 0.000 description 7
- 229920001179 medium density polyethylene Polymers 0.000 description 7
- 239000004701 medium-density polyethylene Substances 0.000 description 7
- 238000002156 mixing Methods 0.000 description 7
- 125000002524 organometallic group Chemical group 0.000 description 7
- 239000002245 particle Substances 0.000 description 7
- 238000002360 preparation method Methods 0.000 description 7
- 229910052726 zirconium Inorganic materials 0.000 description 7
- OJOWICOBYCXEKR-APPZFPTMSA-N (1S,4R)-5-ethylidenebicyclo[2.2.1]hept-2-ene Chemical compound CC=C1C[C@@H]2C[C@@H]1C=C2 OJOWICOBYCXEKR-APPZFPTMSA-N 0.000 description 6
- LWNGJAHMBMVCJR-UHFFFAOYSA-N (2,3,4,5,6-pentafluorophenoxy)boronic acid Chemical compound OB(O)OC1=C(F)C(F)=C(F)C(F)=C1F LWNGJAHMBMVCJR-UHFFFAOYSA-N 0.000 description 6
- PRBHEGAFLDMLAL-GQCTYLIASA-N (4e)-hexa-1,4-diene Chemical compound C\C=C\CC=C PRBHEGAFLDMLAL-GQCTYLIASA-N 0.000 description 6
- YBYIRNPNPLQARY-UHFFFAOYSA-N 1H-indene Natural products C1=CC=C2CC=CC2=C1 YBYIRNPNPLQARY-UHFFFAOYSA-N 0.000 description 6
- WSSSPWUEQFSQQG-UHFFFAOYSA-N 4-methyl-1-pentene Chemical compound CC(C)CC=C WSSSPWUEQFSQQG-UHFFFAOYSA-N 0.000 description 6
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 6
- 150000001336 alkenes Chemical class 0.000 description 6
- 238000005266 casting Methods 0.000 description 6
- 239000011248 coating agent Substances 0.000 description 6
- 230000000052 comparative effect Effects 0.000 description 6
- 239000001257 hydrogen Substances 0.000 description 6
- 229910052739 hydrogen Inorganic materials 0.000 description 6
- 125000003454 indenyl group Chemical group C1(C=CC2=CC=CC=C12)* 0.000 description 6
- SJYNFBVQFBRSIB-UHFFFAOYSA-N norbornadiene Chemical compound C1=CC2C=CC1C2 SJYNFBVQFBRSIB-UHFFFAOYSA-N 0.000 description 6
- QQONPFPTGQHPMA-UHFFFAOYSA-N propylene Natural products CC=C QQONPFPTGQHPMA-UHFFFAOYSA-N 0.000 description 6
- 125000004805 propylene group Chemical group [H]C([H])([H])C([H])([*:1])C([H])([H])[*:2] 0.000 description 6
- 239000000126 substance Substances 0.000 description 6
- WTQBISBWKRKLIJ-UHFFFAOYSA-N 5-methylidenebicyclo[2.2.1]hept-2-ene Chemical compound C1C2C(=C)CC1C=C2 WTQBISBWKRKLIJ-UHFFFAOYSA-N 0.000 description 5
- XJONFIGVOQMBIP-UHFFFAOYSA-L Cl[Zr](Cl)C1C=CC=C1 Chemical compound Cl[Zr](Cl)C1C=CC=C1 XJONFIGVOQMBIP-UHFFFAOYSA-L 0.000 description 5
- 239000011954 Ziegler–Natta catalyst Substances 0.000 description 5
- 239000000654 additive Substances 0.000 description 5
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 5
- 238000004458 analytical method Methods 0.000 description 5
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- 239000001301 oxygen Substances 0.000 description 5
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- 150000002978 peroxides Chemical class 0.000 description 5
- 239000002904 solvent Substances 0.000 description 5
- 229920001897 terpolymer Polymers 0.000 description 5
- ZGEGCLOFRBLKSE-UHFFFAOYSA-N 1-Heptene Chemical compound CCCCCC=C ZGEGCLOFRBLKSE-UHFFFAOYSA-N 0.000 description 4
- AFFLGGQVNFXPEV-UHFFFAOYSA-N 1-decene Chemical class CCCCCCCCC=C AFFLGGQVNFXPEV-UHFFFAOYSA-N 0.000 description 4
- CRSBERNSMYQZNG-UHFFFAOYSA-N 1-dodecene Chemical class CCCCCCCCCCC=C CRSBERNSMYQZNG-UHFFFAOYSA-N 0.000 description 4
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- AQZWEFBJYQSQEH-UHFFFAOYSA-N 2-methyloxaluminane Chemical compound C[Al]1CCCCO1 AQZWEFBJYQSQEH-UHFFFAOYSA-N 0.000 description 4
- FUDNBFMOXDUIIE-UHFFFAOYSA-N 3,7-dimethylocta-1,6-diene Chemical compound C=CC(C)CCC=C(C)C FUDNBFMOXDUIIE-UHFFFAOYSA-N 0.000 description 4
- BTBUEUYNUDRHOZ-UHFFFAOYSA-N Borate Chemical compound [O-]B([O-])[O-] BTBUEUYNUDRHOZ-UHFFFAOYSA-N 0.000 description 4
- 230000002292 Radical scavenging effect Effects 0.000 description 4
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 4
- QCWXUUIWCKQGHC-UHFFFAOYSA-N Zirconium Chemical compound [Zr] QCWXUUIWCKQGHC-UHFFFAOYSA-N 0.000 description 4
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- 238000011088 calibration curve Methods 0.000 description 4
- 125000000392 cycloalkenyl group Chemical group 0.000 description 4
- AFABGHUZZDYHJO-UHFFFAOYSA-N dimethyl butane Natural products CCCC(C)C AFABGHUZZDYHJO-UHFFFAOYSA-N 0.000 description 4
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Classifications
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- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
- C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
- C08L23/04—Homopolymers or copolymers of ethene
- C08L23/08—Copolymers of ethene
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J5/00—Manufacture of articles or shaped materials containing macromolecular substances
- C08J5/18—Manufacture of films or sheets
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B27/00—Layered products comprising a layer of synthetic resin
- B32B27/32—Layered products comprising a layer of synthetic resin comprising polyolefins
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B27/00—Layered products comprising a layer of synthetic resin
- B32B27/32—Layered products comprising a layer of synthetic resin comprising polyolefins
- B32B27/322—Layered products comprising a layer of synthetic resin comprising polyolefins comprising halogenated polyolefins, e.g. PTFE
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F210/00—Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
- C08F210/16—Copolymers of ethene with alpha-alkenes, e.g. EP rubbers
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
- C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
- C08L23/04—Homopolymers or copolymers of ethene
- C08L23/06—Polyethene
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
- C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
- C08L23/04—Homopolymers or copolymers of ethene
- C08L23/08—Copolymers of ethene
- C08L23/0807—Copolymers of ethene with unsaturated hydrocarbons only containing four or more carbon atoms
- C08L23/0815—Copolymers of ethene with unsaturated hydrocarbons only containing four or more carbon atoms with aliphatic 1-olefins containing one carbon-to-carbon double bond
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D123/00—Coating compositions based on homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Coating compositions based on derivatives of such polymers
- C09D123/02—Coating compositions based on homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Coating compositions based on derivatives of such polymers not modified by chemical after-treatment
- C09D123/04—Homopolymers or copolymers of ethene
- C09D123/08—Copolymers of ethene
- C09D123/0807—Copolymers of ethene with unsaturated hydrocarbons only containing more than three carbon atoms
- C09D123/0815—Copolymers of ethene with aliphatic 1-olefins
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2323/00—Characterised by the use of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Derivatives of such polymers
- C08J2323/02—Characterised by the use of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Derivatives of such polymers not modified by chemical after treatment
- C08J2323/04—Homopolymers or copolymers of ethene
- C08J2323/08—Copolymers of ethene
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/02—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2314/00—Polymer mixtures characterised by way of preparation
- C08L2314/06—Metallocene or single site catalysts
Landscapes
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- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
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- Engineering & Computer Science (AREA)
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- Materials Engineering (AREA)
- Wood Science & Technology (AREA)
- Life Sciences & Earth Sciences (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
- Laminated Bodies (AREA)
- Manufacture Of Macromolecular Shaped Articles (AREA)
- Processes Of Treating Macromolecular Substances (AREA)
- Extrusion Moulding Of Plastics Or The Like (AREA)
- Organic Insulating Materials (AREA)
- Materials For Medical Uses (AREA)
- Artificial Filaments (AREA)
Applications Claiming Priority (13)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US21357100P | 2000-06-22 | 2000-06-22 | |
| US213571P | 2000-06-22 | ||
| US24320800P | 2000-10-25 | 2000-10-25 | |
| US243208P | 2000-10-25 | ||
| US27080201P | 2001-02-23 | 2001-02-23 | |
| US270802P | 2001-02-23 | ||
| US27856701P | 2001-03-23 | 2001-03-23 | |
| US27831501P | 2001-03-23 | 2001-03-23 | |
| US27856001P | 2001-03-23 | 2001-03-23 | |
| US278567P | 2001-03-23 | ||
| US278560P | 2001-03-23 | ||
| US278315P | 2001-03-23 | ||
| PCT/US2001/020078 WO2001098409A1 (en) | 2000-06-22 | 2001-06-22 | Very low density polyethylene and high density polyethylene blends |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| DE60129817D1 DE60129817D1 (de) | 2007-09-20 |
| DE60129817T2 true DE60129817T2 (de) | 2007-12-06 |
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| DE60129817T Expired - Lifetime DE60129817T2 (de) | 2000-06-22 | 2001-06-22 | Polymermassen auf basis von linearem polyethylen sehr niedriger dichte und polyethylen hoher dichte (hdpe) |
| DE60138924T Expired - Lifetime DE60138924D1 (de) | 2000-06-22 | 2001-06-22 | Polyethylene mischungen |
| DE60141580T Expired - Lifetime DE60141580D1 (de) | 2000-06-22 | 2001-06-22 | Mischungen aus mit metallocenkatalysatoren hergestelltem polyethylen sehr niedriger dichte und polyethylen mit geringer dichte |
| DE60128377T Expired - Lifetime DE60128377T2 (de) | 2000-06-22 | 2001-06-22 | Metallocenkatalysatoren hergestelltem polyethylen sehr niedriger dichte |
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| Application Number | Title | Priority Date | Filing Date |
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| DE60138924T Expired - Lifetime DE60138924D1 (de) | 2000-06-22 | 2001-06-22 | Polyethylene mischungen |
| DE60141580T Expired - Lifetime DE60141580D1 (de) | 2000-06-22 | 2001-06-22 | Mischungen aus mit metallocenkatalysatoren hergestelltem polyethylen sehr niedriger dichte und polyethylen mit geringer dichte |
| DE60128377T Expired - Lifetime DE60128377T2 (de) | 2000-06-22 | 2001-06-22 | Metallocenkatalysatoren hergestelltem polyethylen sehr niedriger dichte |
Country Status (11)
| Country | Link |
|---|---|
| EP (5) | EP1810992A1 (enExample) |
| JP (4) | JP2004506049A (enExample) |
| KR (2) | KR20030019454A (enExample) |
| CN (5) | CN100386196C (enExample) |
| AT (4) | ATE432960T1 (enExample) |
| AU (4) | AU2001270108A1 (enExample) |
| BR (2) | BR0111934A (enExample) |
| CA (4) | CA2414050C (enExample) |
| DE (4) | DE60129817T2 (enExample) |
| ES (3) | ES2325308T3 (enExample) |
| WO (4) | WO2001098409A1 (enExample) |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE102008005466A1 (de) * | 2008-01-21 | 2009-07-23 | Fiberweb Berlin Gmbh | Polymermischung |
| DE102024111209A1 (de) | 2024-04-22 | 2025-10-23 | Rkw Se | Etikettenfolie |
Families Citing this family (97)
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- 2001-06-22 AT AT01950414T patent/ATE361946T1/de not_active IP Right Cessation
- 2001-06-22 WO PCT/US2001/020078 patent/WO2001098409A1/en not_active Ceased
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| DE102008005466A1 (de) * | 2008-01-21 | 2009-07-23 | Fiberweb Berlin Gmbh | Polymermischung |
| DE102024111209A1 (de) | 2024-04-22 | 2025-10-23 | Rkw Se | Etikettenfolie |
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