DE60120432T2 - Holographisches speichermedium, das polyfunktionelle epoxidmonomere enthält, welche zur kationischen polymerisation fähig sind - Google Patents
Holographisches speichermedium, das polyfunktionelle epoxidmonomere enthält, welche zur kationischen polymerisation fähig sind Download PDFInfo
- Publication number
- DE60120432T2 DE60120432T2 DE60120432T DE60120432T DE60120432T2 DE 60120432 T2 DE60120432 T2 DE 60120432T2 DE 60120432 T DE60120432 T DE 60120432T DE 60120432 T DE60120432 T DE 60120432T DE 60120432 T2 DE60120432 T2 DE 60120432T2
- Authority
- DE
- Germany
- Prior art keywords
- group
- substituted
- unsubstituted
- aryl
- independently
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- 0 CCC(C)(C*)*N* Chemical compound CCC(C)(C*)*N* 0.000 description 6
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G59/00—Polycondensates containing more than one epoxy group per molecule; Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups
- C08G59/18—Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups ; e.g. general methods of curing
- C08G59/20—Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups ; e.g. general methods of curing characterised by the epoxy compounds used
- C08G59/32—Epoxy compounds containing three or more epoxy groups
- C08G59/3254—Epoxy compounds containing three or more epoxy groups containing atoms other than carbon, hydrogen, oxygen or nitrogen
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G77/00—Macromolecular compounds obtained by reactions forming a linkage containing silicon with or without sulfur, nitrogen, oxygen or carbon in the main chain of the macromolecule
- C08G77/04—Polysiloxanes
- C08G77/14—Polysiloxanes containing silicon bound to oxygen-containing groups
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G77/00—Macromolecular compounds obtained by reactions forming a linkage containing silicon with or without sulfur, nitrogen, oxygen or carbon in the main chain of the macromolecule
- C08G77/48—Macromolecular compounds obtained by reactions forming a linkage containing silicon with or without sulfur, nitrogen, oxygen or carbon in the main chain of the macromolecule in which at least two but not all the silicon atoms are connected by linkages other than oxygen atoms
- C08G77/50—Macromolecular compounds obtained by reactions forming a linkage containing silicon with or without sulfur, nitrogen, oxygen or carbon in the main chain of the macromolecule in which at least two but not all the silicon atoms are connected by linkages other than oxygen atoms by carbon linkages
-
- G—PHYSICS
- G03—PHOTOGRAPHY; CINEMATOGRAPHY; ANALOGOUS TECHNIQUES USING WAVES OTHER THAN OPTICAL WAVES; ELECTROGRAPHY; HOLOGRAPHY
- G03F—PHOTOMECHANICAL PRODUCTION OF TEXTURED OR PATTERNED SURFACES, e.g. FOR PRINTING, FOR PROCESSING OF SEMICONDUCTOR DEVICES; MATERIALS THEREFOR; ORIGINALS THEREFOR; APPARATUS SPECIALLY ADAPTED THEREFOR
- G03F7/00—Photomechanical, e.g. photolithographic, production of textured or patterned surfaces, e.g. printing surfaces; Materials therefor, e.g. comprising photoresists; Apparatus specially adapted therefor
- G03F7/0005—Production of optical devices or components in so far as characterised by the lithographic processes or materials used therefor
- G03F7/001—Phase modulating patterns, e.g. refractive index patterns
-
- G—PHYSICS
- G03—PHOTOGRAPHY; CINEMATOGRAPHY; ANALOGOUS TECHNIQUES USING WAVES OTHER THAN OPTICAL WAVES; ELECTROGRAPHY; HOLOGRAPHY
- G03F—PHOTOMECHANICAL PRODUCTION OF TEXTURED OR PATTERNED SURFACES, e.g. FOR PRINTING, FOR PROCESSING OF SEMICONDUCTOR DEVICES; MATERIALS THEREFOR; ORIGINALS THEREFOR; APPARATUS SPECIALLY ADAPTED THEREFOR
- G03F7/00—Photomechanical, e.g. photolithographic, production of textured or patterned surfaces, e.g. printing surfaces; Materials therefor, e.g. comprising photoresists; Apparatus specially adapted therefor
- G03F7/004—Photosensitive materials
- G03F7/075—Silicon-containing compounds
- G03F7/0755—Non-macromolecular compounds containing Si-O, Si-C or Si-N bonds
-
- G—PHYSICS
- G03—PHOTOGRAPHY; CINEMATOGRAPHY; ANALOGOUS TECHNIQUES USING WAVES OTHER THAN OPTICAL WAVES; ELECTROGRAPHY; HOLOGRAPHY
- G03F—PHOTOMECHANICAL PRODUCTION OF TEXTURED OR PATTERNED SURFACES, e.g. FOR PRINTING, FOR PROCESSING OF SEMICONDUCTOR DEVICES; MATERIALS THEREFOR; ORIGINALS THEREFOR; APPARATUS SPECIALLY ADAPTED THEREFOR
- G03F7/00—Photomechanical, e.g. photolithographic, production of textured or patterned surfaces, e.g. printing surfaces; Materials therefor, e.g. comprising photoresists; Apparatus specially adapted therefor
- G03F7/004—Photosensitive materials
- G03F7/075—Silicon-containing compounds
- G03F7/0757—Macromolecular compounds containing Si-O, Si-C or Si-N bonds
-
- G—PHYSICS
- G03—PHOTOGRAPHY; CINEMATOGRAPHY; ANALOGOUS TECHNIQUES USING WAVES OTHER THAN OPTICAL WAVES; ELECTROGRAPHY; HOLOGRAPHY
- G03H—HOLOGRAPHIC PROCESSES OR APPARATUS
- G03H1/00—Holographic processes or apparatus using light, infrared or ultraviolet waves for obtaining holograms or for obtaining an image from them; Details peculiar thereto
- G03H1/02—Details of features involved during the holographic process; Replication of holograms without interference recording
-
- G—PHYSICS
- G11—INFORMATION STORAGE
- G11B—INFORMATION STORAGE BASED ON RELATIVE MOVEMENT BETWEEN RECORD CARRIER AND TRANSDUCER
- G11B7/00—Recording or reproducing by optical means, e.g. recording using a thermal beam of optical radiation by modifying optical properties or the physical structure, reproducing using an optical beam at lower power by sensing optical properties; Record carriers therefor
- G11B7/24—Record carriers characterised by shape, structure or physical properties, or by the selection of the material
- G11B7/2403—Layers; Shape, structure or physical properties thereof
- G11B7/24035—Recording layers
- G11B7/24044—Recording layers for storing optical interference patterns, e.g. holograms; for storing data in three dimensions [3D], e.g. volume storage
-
- G—PHYSICS
- G11—INFORMATION STORAGE
- G11B—INFORMATION STORAGE BASED ON RELATIVE MOVEMENT BETWEEN RECORD CARRIER AND TRANSDUCER
- G11B7/00—Recording or reproducing by optical means, e.g. recording using a thermal beam of optical radiation by modifying optical properties or the physical structure, reproducing using an optical beam at lower power by sensing optical properties; Record carriers therefor
- G11B7/24—Record carriers characterised by shape, structure or physical properties, or by the selection of the material
- G11B7/241—Record carriers characterised by shape, structure or physical properties, or by the selection of the material characterised by the selection of the material
- G11B7/242—Record carriers characterised by shape, structure or physical properties, or by the selection of the material characterised by the selection of the material of recording layers
- G11B7/244—Record carriers characterised by shape, structure or physical properties, or by the selection of the material characterised by the selection of the material of recording layers comprising organic materials only
- G11B7/245—Record carriers characterised by shape, structure or physical properties, or by the selection of the material characterised by the selection of the material of recording layers comprising organic materials only containing a polymeric component
-
- G—PHYSICS
- G03—PHOTOGRAPHY; CINEMATOGRAPHY; ANALOGOUS TECHNIQUES USING WAVES OTHER THAN OPTICAL WAVES; ELECTROGRAPHY; HOLOGRAPHY
- G03H—HOLOGRAPHIC PROCESSES OR APPARATUS
- G03H1/00—Holographic processes or apparatus using light, infrared or ultraviolet waves for obtaining holograms or for obtaining an image from them; Details peculiar thereto
- G03H1/02—Details of features involved during the holographic process; Replication of holograms without interference recording
- G03H2001/026—Recording materials or recording processes
- G03H2001/0264—Organic recording material
-
- G—PHYSICS
- G03—PHOTOGRAPHY; CINEMATOGRAPHY; ANALOGOUS TECHNIQUES USING WAVES OTHER THAN OPTICAL WAVES; ELECTROGRAPHY; HOLOGRAPHY
- G03H—HOLOGRAPHIC PROCESSES OR APPARATUS
- G03H2260/00—Recording materials or recording processes
- G03H2260/12—Photopolymer
Landscapes
- Chemical & Material Sciences (AREA)
- Physics & Mathematics (AREA)
- General Physics & Mathematics (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Spectroscopy & Molecular Physics (AREA)
- Holo Graphy (AREA)
- Epoxy Resins (AREA)
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US22812100P | 2000-08-28 | 2000-08-28 | |
| US228121P | 2000-08-28 | ||
| PCT/US2001/026828 WO2002019040A2 (en) | 2000-08-28 | 2001-08-28 | Holographic storage medium comprising polyfunctional epoxy monomers capable of undergoing cationic polymerization |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| DE60120432D1 DE60120432D1 (de) | 2006-07-20 |
| DE60120432T2 true DE60120432T2 (de) | 2007-01-04 |
Family
ID=22855887
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| DE60120432T Expired - Lifetime DE60120432T2 (de) | 2000-08-28 | 2001-08-28 | Holographisches speichermedium, das polyfunktionelle epoxidmonomere enthält, welche zur kationischen polymerisation fähig sind |
Country Status (10)
| Country | Link |
|---|---|
| US (4) | US6784300B2 (https=) |
| EP (1) | EP1317498B1 (https=) |
| JP (1) | JP2004507513A (https=) |
| KR (1) | KR100749304B1 (https=) |
| AT (1) | ATE328939T1 (https=) |
| AU (1) | AU2001286860A1 (https=) |
| CA (1) | CA2424366A1 (https=) |
| DE (1) | DE60120432T2 (https=) |
| TW (1) | TWI251000B (https=) |
| WO (1) | WO2002019040A2 (https=) |
Families Citing this family (34)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| AU2001264832A1 (en) * | 2000-05-23 | 2001-12-03 | Aprilis, Inc. | Data storage medium comprising colloidal metal and preparation process thereof |
| ATE328939T1 (de) | 2000-08-28 | 2006-06-15 | Aprilis Inc | Holographisches speichermedium, das polyfunktionelle epoxidmonomere enthält, welche zur kationischen polymerisation fähig sind |
| WO2004011522A1 (ja) * | 2002-07-30 | 2004-02-05 | Toagosei Co., Ltd. | ホログラム記録用組成物およびその硬化方法ならびに硬化物 |
| WO2004038515A2 (en) | 2002-10-22 | 2004-05-06 | Zebra Imaging, Inc. | Active digital hologram display |
| AU2003301206A1 (en) | 2002-12-23 | 2004-07-22 | Aprilis, Inc. | Sensitizer dyes for photoacid generating systems |
| US20050187308A1 (en) * | 2004-02-20 | 2005-08-25 | Korea Advanced Institute Of Science And Technology | Method of preparing photopolymer with enhanced optical quality using nanoporous membrane and photopolymer prepared by the same |
| US20070260089A1 (en) * | 2004-03-26 | 2007-11-08 | Albemarle Corporation | Method for the Synthesis of Quaternary Ammonium Compounds and Compositions Thereof |
| JP4629367B2 (ja) * | 2004-05-31 | 2011-02-09 | 東レ・ダウコーニング株式会社 | 活性エネルギー線硬化型オルガノポリシロキサン樹脂組成物、光伝送部材およびその製造方法 |
| US7122290B2 (en) * | 2004-06-15 | 2006-10-17 | General Electric Company | Holographic storage medium |
| US7111806B2 (en) | 2004-08-05 | 2006-09-26 | Esselte | Spool for supply of image receiving medium |
| US7897296B2 (en) * | 2004-09-30 | 2011-03-01 | General Electric Company | Method for holographic storage |
| US20060078802A1 (en) * | 2004-10-13 | 2006-04-13 | Chan Kwok P | Holographic storage medium |
| US20060199081A1 (en) * | 2005-03-04 | 2006-09-07 | General Electric Company | Holographic storage medium, article and method |
| US8034514B2 (en) * | 2005-03-08 | 2011-10-11 | Nippon Steel Chemical Co., Ltd. | Photosensitive resin composition for volume phase hologram recording and optical information recording medium using the same |
| JP2009511638A (ja) * | 2005-10-18 | 2009-03-19 | ディーシーイー アプリリス,インコーポレイテッド | ホログラフィックストレージのための、カチオン重合をサポートするシロキサン化合物を含む光重合可能な媒体 |
| US20070167407A1 (en) * | 2005-12-20 | 2007-07-19 | Albemarle Corporation | Quaternary ammonium borate compositions and substrate preservative solutions containing them |
| CA2634747C (en) * | 2005-12-29 | 2014-09-09 | The University Of Akron | Photocurable polymers for ophthalmic applications |
| US8163443B2 (en) * | 2006-03-09 | 2012-04-24 | Nippon Steel Chemical Co., Ltd. | Photosensitive resin composition for volume phase hologram recording and optical information recording medium using the same |
| US8222364B2 (en) * | 2006-04-11 | 2012-07-17 | Dow Corning Corporation | Composition including a siloxane and a method of forming the same |
| WO2007124459A2 (en) * | 2006-04-20 | 2007-11-01 | Inphase Technologies, Inc. | Index-contrasting-photoactive polymerizable materials, and articles and methods using same |
| JP2008195616A (ja) | 2007-02-08 | 2008-08-28 | Fujifilm Corp | 重合性化合物、光記録用組成物、ホログラフィック記録媒体および情報記録方法 |
| CA2683905A1 (en) | 2007-04-11 | 2008-10-23 | Bayer Materialscience Ag | Advantageous recording media for holographic applications |
| JP2010202801A (ja) * | 2009-03-04 | 2010-09-16 | Nitto Denko Corp | 熱硬化性シリコーン樹脂用組成物 |
| WO2010107784A1 (en) | 2009-03-16 | 2010-09-23 | Stx Aprilis, Inc. | Methods for activation control of photopolymerization for holographic data storage using at least two wavelengths |
| US8323854B2 (en) * | 2009-04-23 | 2012-12-04 | Akonia Holographics, Llc | Photopolymer media with enhanced dynamic range |
| KR101426629B1 (ko) | 2009-11-25 | 2014-08-05 | 다이니치 세이카 고교 가부시키가이샤 | 폴리실록산 변성 폴리히드록시 폴리우레탄 수지 및 그 제조방법, 상기 수지를 이용한 감열 기록 재료, 인조 피혁, 열가소성 폴리올레핀 수지 표피재, 웨더스트립용 재료 및 웨더스트립 |
| JP2011132208A (ja) * | 2009-11-25 | 2011-07-07 | Dainichiseika Color & Chem Mfg Co Ltd | 5員環環状カーボネートポリシロキサン化合物およびその製造方法 |
| US8703648B2 (en) | 2009-11-26 | 2014-04-22 | Dainichiseika Color & Chemicals Mfg. Co., Ltd. | Polysiloxane-modified polyhydroxy polyurethane resin, method for producing same, heat-sensitive recording material using the resin, imitation leather, thermoplastic polyolefin resin skin material, material for weather strip, and weather strip |
| GB2476275A (en) | 2009-12-17 | 2011-06-22 | Dublin Inst Of Technology | Photosensitive holographic recording medium comprising glycerol |
| WO2011162237A1 (ja) | 2010-06-24 | 2011-12-29 | 大日精化工業株式会社 | 自己架橋型ポリヒドロキシポリウレタン樹脂、該樹脂を含む樹脂材料、該樹脂の製造方法、該樹脂を用いてなる擬革、表皮材及びウェザーストリップ用材料 |
| US10000609B2 (en) | 2010-08-26 | 2018-06-19 | Dainichiseika Color & Chemicals Mfg. Co., Ltd. | Self-crosslinking polysiloxane-modified polyhydroxy polyurethane resin, resin material containing same, method for producing same, artificial leather comprising same, and thermoplastic polyolefin skin material comprising same |
| WO2012137726A1 (ja) | 2011-04-04 | 2012-10-11 | 大日精化工業株式会社 | 自己架橋型ポリシロキサン変性ポリヒドロキシポリウレタン樹脂、該樹脂の製造方法、該樹脂を含む樹脂材料および該樹脂を利用した擬革 |
| WO2015182143A1 (ja) * | 2014-05-30 | 2015-12-03 | 東レ・ダウコーニング株式会社 | 有機ケイ素化合物、硬化性シリコーン組成物、および半導体装置 |
| KR102470706B1 (ko) * | 2014-12-19 | 2022-11-28 | 다우 실리콘즈 코포레이션 | 축합 가교결합 입자의 제조 방법 |
Family Cites Families (19)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| BE655303A (https=) * | 1963-11-12 | 1965-03-01 | ||
| JPS6017377B2 (ja) * | 1979-07-31 | 1985-05-02 | 信越化学工業株式会社 | 重合性オルガノポリシロキサンの製造方法 |
| US5037861A (en) | 1989-08-09 | 1991-08-06 | General Electric Company | Novel highly reactive silicon-containing epoxides |
| US5075154A (en) * | 1990-03-23 | 1991-12-24 | General Electric Company | UV-curable silphenylene-containing epoxy functional silicones |
| DE4023556A1 (de) * | 1990-07-25 | 1992-01-30 | Goldschmidt Ag Th | Haertbare epoxygruppen aufweisende organopolysiloxane, verfahren zu ihrer herstellung und ihre verwendung als haertbare beschichtungsmittel mit abhaesiven eigenschaften |
| JP3015139B2 (ja) * | 1991-04-23 | 2000-03-06 | 東レ・ダウコーニング・シリコーン株式会社 | オルガノポリシロキサンおよびその製造方法 |
| TW268969B (https=) * | 1992-10-02 | 1996-01-21 | Minnesota Mining & Mfg | |
| US5484950A (en) | 1992-12-21 | 1996-01-16 | Polyset Company, Inc. | Process for selective monoaddition to silanes containing two silicon-hydrogen bonds and products thereof |
| US5292827A (en) * | 1993-02-25 | 1994-03-08 | General Electric Company | Epoxy-capped branched silicones and copolymers thereof |
| JP3532675B2 (ja) * | 1994-10-03 | 2004-05-31 | 日本ペイント株式会社 | 体積ホログラム記録用感光性組成物、及びそれを用いた記録媒体ならびに体積ホログラム形成方法 |
| DE69616813T2 (de) | 1995-10-06 | 2002-07-18 | Polaroid Corp., Cambridge | Halographisches aufzeichnungsmaterial und verfahren |
| US5863970A (en) * | 1995-12-06 | 1999-01-26 | Polyset Company, Inc. | Epoxy resin composition with cycloaliphatic epoxy-functional siloxane |
| US5874187A (en) | 1996-08-15 | 1999-02-23 | Lucent Technologies Incorporated | Photo recording medium |
| DE19648283A1 (de) | 1996-11-21 | 1998-05-28 | Thera Ges Fuer Patente | Polymerisierbare Massen auf der Basis von Epoxiden |
| US20030157414A1 (en) * | 1997-11-13 | 2003-08-21 | Pradeep K. Dhal | Holographic medium and process for use thereof |
| US6391999B1 (en) | 1998-02-06 | 2002-05-21 | Rensselaer Polytechnic Institute | Epoxy alkoxy siloxane oligomers |
| AU2001264832A1 (en) * | 2000-05-23 | 2001-12-03 | Aprilis, Inc. | Data storage medium comprising colloidal metal and preparation process thereof |
| US6852766B1 (en) * | 2000-06-15 | 2005-02-08 | 3M Innovative Properties Company | Multiphoton photosensitization system |
| ATE328939T1 (de) | 2000-08-28 | 2006-06-15 | Aprilis Inc | Holographisches speichermedium, das polyfunktionelle epoxidmonomere enthält, welche zur kationischen polymerisation fähig sind |
-
2001
- 2001-08-28 AT AT01966336T patent/ATE328939T1/de not_active IP Right Cessation
- 2001-08-28 KR KR1020037003021A patent/KR100749304B1/ko not_active Expired - Fee Related
- 2001-08-28 WO PCT/US2001/026828 patent/WO2002019040A2/en not_active Ceased
- 2001-08-28 US US09/941,166 patent/US6784300B2/en not_active Expired - Fee Related
- 2001-08-28 CA CA002424366A patent/CA2424366A1/en not_active Abandoned
- 2001-08-28 AU AU2001286860A patent/AU2001286860A1/en not_active Abandoned
- 2001-08-28 JP JP2002523098A patent/JP2004507513A/ja active Pending
- 2001-08-28 DE DE60120432T patent/DE60120432T2/de not_active Expired - Lifetime
- 2001-08-28 TW TW090121147A patent/TWI251000B/zh not_active IP Right Cessation
- 2001-08-28 EP EP01966336A patent/EP1317498B1/en not_active Expired - Lifetime
-
2004
- 2004-07-13 US US10/890,425 patent/US7070886B2/en not_active Expired - Fee Related
-
2006
- 2006-03-20 US US11/385,979 patent/US7332249B2/en not_active Expired - Fee Related
-
2007
- 2007-12-27 US US12/005,652 patent/US20100280260A1/en not_active Abandoned
Also Published As
| Publication number | Publication date |
|---|---|
| US20040249181A1 (en) | 2004-12-09 |
| ATE328939T1 (de) | 2006-06-15 |
| TWI251000B (en) | 2006-03-11 |
| DE60120432D1 (de) | 2006-07-20 |
| US20070293637A1 (en) | 2007-12-20 |
| US7332249B2 (en) | 2008-02-19 |
| WO2002019040A3 (en) | 2002-05-30 |
| EP1317498B1 (en) | 2006-06-07 |
| KR20030045790A (ko) | 2003-06-11 |
| EP1317498A2 (en) | 2003-06-11 |
| CA2424366A1 (en) | 2002-03-07 |
| JP2004507513A (ja) | 2004-03-11 |
| US6784300B2 (en) | 2004-08-31 |
| KR100749304B1 (ko) | 2007-08-14 |
| AU2001286860A1 (en) | 2002-03-13 |
| WO2002019040A2 (en) | 2002-03-07 |
| US7070886B2 (en) | 2006-07-04 |
| US20100280260A1 (en) | 2010-11-04 |
| WO2002019040A9 (en) | 2002-07-25 |
| US20020068223A1 (en) | 2002-06-06 |
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