DE60115335T2 - Polymerisationsverfahren von sulphonischen Monomeren - Google Patents

Polymerisationsverfahren von sulphonischen Monomeren Download PDF

Info

Publication number
DE60115335T2
DE60115335T2 DE60115335T DE60115335T DE60115335T2 DE 60115335 T2 DE60115335 T2 DE 60115335T2 DE 60115335 T DE60115335 T DE 60115335T DE 60115335 T DE60115335 T DE 60115335T DE 60115335 T2 DE60115335 T2 DE 60115335T2
Authority
DE
Germany
Prior art keywords
reactor
tfe
formula
polymerization
fluorinated
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Lifetime
Application number
DE60115335T
Other languages
German (de)
English (en)
Other versions
DE60115335D1 (de
Inventor
Marco 28043 Bellinzago Apostolo
Vincenzo 20014 Nerviano Arcella
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Syensqo Specialty Polymers Italy SpA
Original Assignee
Solvay Solexis SpA
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Solvay Solexis SpA filed Critical Solvay Solexis SpA
Application granted granted Critical
Publication of DE60115335D1 publication Critical patent/DE60115335D1/de
Publication of DE60115335T2 publication Critical patent/DE60115335T2/de
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F214/00Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen
    • C08F214/18Monomers containing fluorine
    • C08F214/184Monomers containing fluorine with fluorinated vinyl ethers
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F216/00Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an alcohol, ether, aldehydo, ketonic, acetal or ketal radical
    • C08F216/12Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an alcohol, ether, aldehydo, ketonic, acetal or ketal radical by an ether radical
    • C08F216/14Monomers containing only one unsaturated aliphatic radical
    • C08F216/1466Monomers containing sulfur
    • C08F216/1475Monomers containing sulfur and oxygen

Landscapes

  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Polymerisation Methods In General (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Graft Or Block Polymers (AREA)
  • Conductive Materials (AREA)
  • Fuel Cell (AREA)
DE60115335T 2000-06-23 2001-06-19 Polymerisationsverfahren von sulphonischen Monomeren Expired - Lifetime DE60115335T2 (de)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
IT2000MI001417A IT1318594B1 (it) 2000-06-23 2000-06-23 Processo di polimerizzazione di monomeri solfonici.
ITMI001417 2000-06-23

Publications (2)

Publication Number Publication Date
DE60115335D1 DE60115335D1 (de) 2006-01-05
DE60115335T2 true DE60115335T2 (de) 2006-08-03

Family

ID=11445328

Family Applications (1)

Application Number Title Priority Date Filing Date
DE60115335T Expired - Lifetime DE60115335T2 (de) 2000-06-23 2001-06-19 Polymerisationsverfahren von sulphonischen Monomeren

Country Status (6)

Country Link
US (1) US6555639B2 (https=)
EP (1) EP1172382B1 (https=)
JP (1) JP5075307B2 (https=)
CA (1) CA2351858C (https=)
DE (1) DE60115335T2 (https=)
IT (1) IT1318594B1 (https=)

Families Citing this family (43)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
ITMI20012744A1 (it) * 2001-12-21 2003-06-21 Ausimont Spa Processo di polimerizzazione di monomeri solfonici
ITMI20020178A1 (it) * 2002-02-01 2003-08-01 Ausimont Spa Uso di additivi fluorurati nell'etching o polishing di circuiti integrati
ITMI20020902A1 (it) 2002-04-26 2003-10-27 Ausimont Spa Processo per preparare membrane ionomeriche
WO2004007576A1 (ja) * 2002-06-14 2004-01-22 Daikin Industries, Ltd. 含フッ素共重合体製造方法、含フッ素共重合体及び成形体
WO2004011508A1 (en) * 2002-07-29 2004-02-05 3M Innovative Properties Company Process for making a fluoroelastomer
FR2843398B1 (fr) * 2002-08-09 2007-04-27 Commissariat Energie Atomique Polymeres fluores, membranes preparees a partir de ceux-ci et dispositif de pile a combustible comprenant ces membranes
US6828386B2 (en) 2002-09-20 2004-12-07 Ballard Power Systems Inc. Process for preparing graft copolymers and membranes formed therefrom
US7214740B2 (en) * 2005-05-03 2007-05-08 3M Innovative Properties Company Fluorinated ionomers with reduced amounts of carbonyl end groups
EP1939222B2 (en) * 2005-10-17 2019-09-04 AGC Inc. Process for producing an AQUEOUS POLYTETRAFLUOROETHYLENE EMULSION, AND POLYTETRAFLUOROETHYLENE FINE POWDER AND POROUS MATERIAL PRODUCED FROM THE SAME
ITMI20052509A1 (it) * 2005-12-28 2007-06-29 Solvay Solexis Spa Assemblati per dispositivi elettrochimici
ITMI20052508A1 (it) * 2005-12-28 2007-06-29 Solvay Solexis Spa Processo per ottenere ccm con subgasket
EP1873860A1 (en) * 2006-06-28 2008-01-02 Solvay Solexis S.p.A. Catalyst-Polymer Liquid Dispersion for Fuel Cell Applications
ITMI20061261A1 (it) * 2006-06-29 2007-12-30 Solvay Solexis Spa Assemblati per dispositivi elettrochimici
WO2008132959A1 (ja) * 2007-04-13 2008-11-06 Asahi Glass Company, Limited 含フッ素カルボン酸化合物を用いた含フッ素ポリマーの製造方法
EP2222761A1 (en) * 2007-12-20 2010-09-01 E. I. du Pont de Nemours and Company Process to prepare crosslinkable trifluorostyrene polymers and membranes
US8071254B2 (en) 2007-12-27 2011-12-06 E. I. Du Pont De Nemours And Company Crosslinkable fluoropolymer, crosslinked fluoropolymers and crosslinked fluoropolymer membranes
US7989568B2 (en) * 2008-11-13 2011-08-02 E.I. Du Pont De Nemours And Company Fluorosulfonates
US7977426B2 (en) * 2008-11-13 2011-07-12 E. I. Du Pont De Nemours And Company Fluoroalkyl ether sulfonate surfactants
EP2493940B2 (en) 2009-10-29 2018-08-29 Solvay Specialty Polymers Italy S.p.A. Process for the isolation of sulfonyl fluoride polymers and polymers obtained therefrom
US9023554B2 (en) 2009-12-11 2015-05-05 Shandong Huaxia Shenzhou New Material Co., Ltd. Perfluorinated ion exchange resin, preparation method and use thereof
JP5486693B2 (ja) 2009-12-15 2014-05-07 シャンドン・フアシャ・シェンゾウ・ニュー・マテリアル・カンパニー・リミテッド 高交換容量過フッ化イオン交換樹脂、その調製方法、及び使用
JP5684283B2 (ja) * 2009-12-18 2015-03-11 ソルヴェイ・スペシャルティ・ポリマーズ・イタリー・エッセ・ピ・ア フルオロポリマーの製造方法
US8940846B2 (en) 2010-07-01 2015-01-27 Solvay Specialty Polymers Italy S.P.A. Process for the treatment of sulfonyl fluoride polymers
KR101892317B1 (ko) 2011-04-07 2018-08-27 솔베이 스페셜티 폴리머스 이태리 에스.피.에이. 가교형 불소화 중합체의 제조 방법
EP2719007A1 (en) 2011-06-06 2014-04-16 Solvay Specialty Polymers Italy S.p.A. Stable ion exchange fluorinated polymers and membranes obtained therefrom
EP2586800A1 (en) 2011-10-28 2013-05-01 Solvay Specialty Polymers Italy S.p.A. Process for the treatment of sulfonyl fluoride polymers with supercritical carbon dioxide
DK2872445T3 (da) 2012-07-11 2019-12-09 Solvay Specialty Polymers It Blandingsmetaloxider som scavengers til fluorerede ionbytningspolymerer
WO2014173782A1 (en) 2013-04-22 2014-10-30 Solvay Specialty Polymers Italy S.P.A. Cross-linkable polymers comprising sulfonic acid functional groups
RU2545182C1 (ru) * 2013-09-06 2015-03-27 Федеральное государственное бюджетное учреждение науки Институт катализа им. Г.К. Борескова Сибирского отделения Российской академии наук Способ получения сополимера тетрафторэтилена с 2-фторсульфонилперфторэтилвиниловым эфиром - прекурсора протонопроводящих мембран - методом эмульсионной сополимеризации
EP3209710B1 (en) 2014-10-20 2020-12-09 Solvay Specialty Polymers Italy S.p.A. Liquid composition for proton exchange membranes
US9944571B2 (en) 2014-11-19 2018-04-17 Solvay Specialty Polymers Italy S.P.A. One-pot process using heterogeneous catalyst
US20180179342A1 (en) 2015-05-27 2018-06-28 Solvay Specialty Polymers Italy S.P.A. Anti-sticking treatment for low cristallinity fluoropolymer particles
JP7096241B6 (ja) 2016-10-28 2023-12-22 ソルベイ スペシャルティ ポリマーズ イタリー エス.ピー.エー. ポリマーを架橋する方法
JP7676110B2 (ja) 2017-03-10 2025-05-14 ソルベイ スペシャルティ ポリマーズ ユーエスエー, エルエルシー 溶融加工可能な組成物
EP3375798A1 (en) 2017-03-17 2018-09-19 Solvay Specialty Polymers Italy S.p.A. Method for making fluoropolymers
KR102719413B1 (ko) * 2017-03-17 2024-10-21 솔베이 스페셜티 폴리머스 이태리 에스.피.에이. 플루오로중합체의 제조 방법
RU2671812C1 (ru) * 2018-06-19 2018-11-07 Федеральное государственное бюджетное учреждение науки Институт высокомолекулярных соединений Российской академии наук Способ получения сополимера перфтор-3-оксапентенсульфонилфторида и тетрафторэтилена в качестве прекурсора перфторированных протонопроводящих мембран
TW202204892A (zh) * 2020-06-29 2022-02-01 美商瑟蘭斯國際股份有限公司 於乙酸乙烯酯製造之金屬離子原位分析
AU2023227088A1 (en) 2022-03-01 2024-08-22 Syensqo Specialty Polymers Italy S.p.A. Method for making fluoropolymers containing ion exchange groups
CN120936681A (zh) 2022-12-19 2025-11-11 世索科特殊聚合物意大利有限公司 作为自由基清除剂的SiO2负载的CeO2
WO2025133362A1 (en) 2023-12-21 2025-06-26 Specialty Operations France Cerium oxide/polyoxometalate particle dispersions and their use in the preparation of proton exchange membranes or electrocatalyst layers
WO2025233235A1 (en) 2024-05-07 2025-11-13 Syensqo Specialty Polymers Italy S.p.A. Melt-processable fluoropolymer composition, preparation methods and uses thereof
WO2025238042A1 (en) 2024-05-17 2025-11-20 Syensqo Specialty Polymers Italy S.p.A. Improved fluorinated polymer composition and use thereof in an electrochemical device

Family Cites Families (22)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4035565A (en) 1975-03-27 1977-07-12 E. I. Du Pont De Nemours And Company Fluoropolymer containing a small amount of bromine-containing olefin units
SE7712836L (sv) * 1976-12-02 1978-06-03 Du Pont Polyfluoroallyloxiforeningar
JPS53125491A (en) 1977-04-08 1978-11-01 Daikin Ind Ltd Fluorine-containing polymer easily curable and its curable composition
US4564662A (en) 1984-02-23 1986-01-14 Minnesota Mining And Manufacturing Company Fluorocarbon elastomer
DE3662142D1 (en) 1985-03-28 1989-03-30 Daikin Ind Ltd Novel fluorovinyl ether and copolymer comprising the same
IT1187684B (it) 1985-07-08 1987-12-23 Montefluos Spa Procedimento per la preparazione di fluoroelastomeri vulcanizzabili e prodotti cosi' ottenuti
US4694045A (en) 1985-12-11 1987-09-15 E. I. Du Pont De Nemours And Company Base resistant fluoroelastomers
IL82308A (en) 1986-06-26 1990-11-29 Ausimont Spa Microemulsions containing perfluoropolyethers
IT1204903B (it) * 1986-06-26 1989-03-10 Ausimont Spa Processo di polimerizzazione in dispersione acquosa di monomeri florati
US4940525A (en) * 1987-05-08 1990-07-10 The Dow Chemical Company Low equivalent weight sulfonic fluoropolymers
JPS63304009A (ja) 1987-06-04 1988-12-12 Nippon Mektron Ltd パ−オキサイド加硫可能な含フッ素エラストマ−の製造方法
IT1235545B (it) 1989-07-10 1992-09-09 Ausimont Srl Fluoroelastomeri dotati di migliore processabilita' e procedimento di preparazione
IT1271136B (it) * 1993-03-23 1997-05-27 Ausimont Spa Processo di (co)polimerizzazione in emulsione acquosa di monomeri olefinici fluorurati
WO1995010541A1 (en) * 1993-10-12 1995-04-20 Asahi Kasei Kogyo Kabushiki Kaisha Perfluorocarbon copolymer having functional groups and process for producing the same
JP3487652B2 (ja) * 1993-10-12 2004-01-19 旭化成株式会社 官能基含有パーフルオロカーボン系共重合体の製造方法、及び官能基含有パーフルオロカーボン系共重合体組成物
IT1265461B1 (it) * 1993-12-29 1996-11-22 Ausimont Spa Fluoroelastomeri comprendenti unita' monomeriche derivanti da una bis-olefina
ATE254641T1 (de) * 1996-03-27 2003-12-15 Commw Scient Ind Res Org Poröses polymer mit hohem wassergehalt
JP3804197B2 (ja) * 1997-07-24 2006-08-02 旭硝子株式会社 フッ素化モノマーの回収方法
ITMI981519A1 (it) * 1998-07-02 2000-01-02 Ausimont Spa Processodi polimerizzazione del tfe
IT1308628B1 (it) * 1999-02-23 2002-01-09 Ausimont Spa Composizioni fluoroelastomeriche.
US6429258B1 (en) * 1999-05-20 2002-08-06 E. I. Du Pont De Nemours & Company Polymerization of fluoromonomers
WO2001049757A1 (fr) * 1999-12-29 2001-07-12 HYDRO-QUéBEC Elastomeres fluorosulfones a faible tg a base de fluorure de vinylidene

Also Published As

Publication number Publication date
US20020013439A1 (en) 2002-01-31
ITMI20001417A0 (it) 2000-06-23
CA2351858A1 (en) 2001-12-23
JP2002088103A (ja) 2002-03-27
ITMI20001417A1 (it) 2001-12-23
EP1172382A2 (en) 2002-01-16
JP5075307B2 (ja) 2012-11-21
EP1172382B1 (en) 2005-11-30
DE60115335D1 (de) 2006-01-05
EP1172382A3 (en) 2003-09-24
IT1318594B1 (it) 2003-08-27
US6555639B2 (en) 2003-04-29
CA2351858C (en) 2011-03-22

Similar Documents

Publication Publication Date Title
DE60115335T2 (de) Polymerisationsverfahren von sulphonischen Monomeren
DE60225235T2 (de) Polymerisationsverfahren von Sulfonmonomeren
DE2650979C2 (de) Verfahren zur Herstellung eines fluorierten Copolymeren mit Ionenaustauschgruppen
DE60133511T2 (de) Fluorierte Ionomere
DE69835366T2 (de) Verfahren zur herstellung von perfluorvinylethersulfonsäure-derivaten
DE69516485T2 (de) Mikroemulsionen von Fluorpolyoxyalkylenen in Mischung mit Kohlenwasserstoffen und ihre Verwendung in (Co)Polymerisationsverfahren fluorierter Monomeren
DE69405680T2 (de) Verfahren zur (Co)polymerisation von fluorenthaltenden olefinischen Monomeren in wässriger Emulsion
DE69500675T2 (de) Neue fluor-enthaltende thermoplastische Elastomere mit höheren mechanischen und elastischen Eigenschaften und Verfahren zur Herstellung derselben
DE69406408T2 (de) Fluorelastomere, enthaltend Monomerderivaten aus einem Bis-Olefin
DE69512564T2 (de) Neue peroxidhärtbare Fluorelastomere, besonderes geeignet zur Herstellung von O-Ringen
DE2746416C2 (de) Verfahren zur Herstellung eines fluorierten Copolymeren mit Ionenaustauschergruppen
DE60202875T2 (de) Fluor enthaltende funktionnelle polymere und ionomere davon
DE69402675T2 (de) Fluor-enthaltende thermoplastische Elastomere, mit höheren mechanischen und elastischen Eigenschaften
DE69414627T2 (de) Fluorelastomere ausgestattet mit grosser Beständigkeit gegenüber polaren Lösungsmitteln und Basen
GB1590357A (en) Cation exchange membrane of fluorinated polymer for electrolysis and preparation thereof
DE69509489T2 (de) Thermisch verarbeitbare Tetrafluorethylencopolymere
DE2938995A1 (de) Kationenaustauschmembran aus fluoriertem polymeren fuer eine elektrolyse und elektrolyse unter verwendung der membran
DE69403692T2 (de) Radikalisches (co)Polymerisationsverfahren von fluorhaltigen olefinischen Monomeren
WO2012088258A1 (en) Fluoropolymer compositions and purification methods thereof
DE60036962T2 (de) Verfahren zur polymerisation von fluorenthaltenden monomeren in wässriger emulsion
DE60220635T2 (de) Fluorierte Ionomere
JPS60250009A (ja) スルホン酸型官能基を有するパ−フルオロカ−ボン重合体の製造方法
DE602005002303T2 (de) Fluoroelastomergele
DE60020776T2 (de) Perhalogenierte thermoplastische Chlortrifluorethylen-Copolymere
JP3525462B2 (ja) フッ素化モノマーの回収方法

Legal Events

Date Code Title Description
8364 No opposition during term of opposition