DE60115335T2 - Polymerisationsverfahren von sulphonischen Monomeren - Google Patents

Polymerisationsverfahren von sulphonischen Monomeren Download PDF

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Publication number
DE60115335T2
DE60115335T2 DE60115335T DE60115335T DE60115335T2 DE 60115335 T2 DE60115335 T2 DE 60115335T2 DE 60115335 T DE60115335 T DE 60115335T DE 60115335 T DE60115335 T DE 60115335T DE 60115335 T2 DE60115335 T2 DE 60115335T2
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Germany
Prior art keywords
reactor
tfe
formula
polymerization
fluorinated
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Expired - Lifetime
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DE60115335T
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German (de)
English (en)
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DE60115335D1 (de
Inventor
Marco 28043 Bellinzago Apostolo
Vincenzo 20014 Nerviano Arcella
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Syensqo Specialty Polymers Italy SpA
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Solvay Solexis SpA
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Publication of DE60115335T2 publication Critical patent/DE60115335T2/de
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Expired - Lifetime legal-status Critical Current

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    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F214/00Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen
    • C08F214/18Monomers containing fluorine
    • C08F214/184Monomers containing fluorine with fluorinated vinyl ethers
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F216/00Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an alcohol, ether, aldehydo, ketonic, acetal or ketal radical
    • C08F216/12Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an alcohol, ether, aldehydo, ketonic, acetal or ketal radical by an ether radical
    • C08F216/14Monomers containing only one unsaturated aliphatic radical
    • C08F216/1466Monomers containing sulfur
    • C08F216/1475Monomers containing sulfur and oxygen

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  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Polymerisation Methods In General (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Graft Or Block Polymers (AREA)
  • Conductive Materials (AREA)
  • Fuel Cell (AREA)
DE60115335T 2000-06-23 2001-06-19 Polymerisationsverfahren von sulphonischen Monomeren Expired - Lifetime DE60115335T2 (de)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
ITMI001417 2000-06-23
IT2000MI001417A IT1318594B1 (it) 2000-06-23 2000-06-23 Processo di polimerizzazione di monomeri solfonici.

Publications (2)

Publication Number Publication Date
DE60115335D1 DE60115335D1 (de) 2006-01-05
DE60115335T2 true DE60115335T2 (de) 2006-08-03

Family

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Family Applications (1)

Application Number Title Priority Date Filing Date
DE60115335T Expired - Lifetime DE60115335T2 (de) 2000-06-23 2001-06-19 Polymerisationsverfahren von sulphonischen Monomeren

Country Status (6)

Country Link
US (1) US6555639B2 (https=)
EP (1) EP1172382B1 (https=)
JP (1) JP5075307B2 (https=)
CA (1) CA2351858C (https=)
DE (1) DE60115335T2 (https=)
IT (1) IT1318594B1 (https=)

Families Citing this family (43)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
ITMI20012744A1 (it) * 2001-12-21 2003-06-21 Ausimont Spa Processo di polimerizzazione di monomeri solfonici
ITMI20020178A1 (it) * 2002-02-01 2003-08-01 Ausimont Spa Uso di additivi fluorurati nell'etching o polishing di circuiti integrati
ITMI20020902A1 (it) 2002-04-26 2003-10-27 Ausimont Spa Processo per preparare membrane ionomeriche
AU2003241677A1 (en) * 2002-06-14 2004-02-02 Daikin Industries, Ltd. Process for producing fluorocopolymer, fluorocopolymer, and molded object
DE60335627D1 (de) 2002-07-29 2011-02-17 3M Innovative Properties Co Fluorelastomer und verfahren zur dessen herstellung
FR2843398B1 (fr) * 2002-08-09 2007-04-27 Commissariat Energie Atomique Polymeres fluores, membranes preparees a partir de ceux-ci et dispositif de pile a combustible comprenant ces membranes
US6828386B2 (en) 2002-09-20 2004-12-07 Ballard Power Systems Inc. Process for preparing graft copolymers and membranes formed therefrom
US7214740B2 (en) 2005-05-03 2007-05-08 3M Innovative Properties Company Fluorinated ionomers with reduced amounts of carbonyl end groups
CN100558753C (zh) 2005-10-17 2009-11-11 旭硝子株式会社 聚四氟乙烯水性乳化液、由其制得的聚四氟乙烯细粉和多孔体
ITMI20052508A1 (it) * 2005-12-28 2007-06-29 Solvay Solexis Spa Processo per ottenere ccm con subgasket
ITMI20052509A1 (it) * 2005-12-28 2007-06-29 Solvay Solexis Spa Assemblati per dispositivi elettrochimici
EP1873860A1 (en) 2006-06-28 2008-01-02 Solvay Solexis S.p.A. Catalyst-Polymer Liquid Dispersion for Fuel Cell Applications
ITMI20061261A1 (it) * 2006-06-29 2007-12-30 Solvay Solexis Spa Assemblati per dispositivi elettrochimici
WO2008132959A1 (ja) * 2007-04-13 2008-11-06 Asahi Glass Company, Limited 含フッ素カルボン酸化合物を用いた含フッ素ポリマーの製造方法
US8664282B2 (en) * 2007-12-20 2014-03-04 E I Du Pont De Nemours And Company Process to prepare crosslinkable trifluorostyrene polymers and membranes
US8071254B2 (en) 2007-12-27 2011-12-06 E. I. Du Pont De Nemours And Company Crosslinkable fluoropolymer, crosslinked fluoropolymers and crosslinked fluoropolymer membranes
US7989568B2 (en) * 2008-11-13 2011-08-02 E.I. Du Pont De Nemours And Company Fluorosulfonates
US7977426B2 (en) * 2008-11-13 2011-07-12 E. I. Du Pont De Nemours And Company Fluoroalkyl ether sulfonate surfactants
WO2011051168A1 (en) 2009-10-29 2011-05-05 Solvay Solexis S.P.A. Process for the isolation of sulfonyl fluoride polymers and polymers obtained therefrom
US9023554B2 (en) 2009-12-11 2015-05-05 Shandong Huaxia Shenzhou New Material Co., Ltd. Perfluorinated ion exchange resin, preparation method and use thereof
JP5486693B2 (ja) 2009-12-15 2014-05-07 シャンドン・フアシャ・シェンゾウ・ニュー・マテリアル・カンパニー・リミテッド 高交換容量過フッ化イオン交換樹脂、その調製方法、及び使用
JP5684283B2 (ja) * 2009-12-18 2015-03-11 ソルヴェイ・スペシャルティ・ポリマーズ・イタリー・エッセ・ピ・ア フルオロポリマーの製造方法
EP2588507B1 (en) 2010-07-01 2014-06-04 Solvay Specialty Polymers Italy S.p.A. Process for the treatment of sulfonyl fluoride polymers
EP2694195B1 (en) 2011-04-07 2018-12-19 Solvay Specialty Polymers Italy S.p.A. Process for the preparation of cross-linked fluorinated polymers
US20140199604A1 (en) 2011-06-06 2014-07-17 Solvay Specialty Polymers Italy S.P.A. Stable ion exchange fluorinated polymers and membranes obtained therefrom
EP2586800A1 (en) 2011-10-28 2013-05-01 Solvay Specialty Polymers Italy S.p.A. Process for the treatment of sulfonyl fluoride polymers with supercritical carbon dioxide
US9819041B2 (en) 2012-07-11 2017-11-14 Solvay Specialty Polymers Italy S.P.A. Mixed metallic oxides as scavengers for fluorinated ion exchange polymers
WO2014173782A1 (en) 2013-04-22 2014-10-30 Solvay Specialty Polymers Italy S.P.A. Cross-linkable polymers comprising sulfonic acid functional groups
RU2545182C1 (ru) * 2013-09-06 2015-03-27 Федеральное государственное бюджетное учреждение науки Институт катализа им. Г.К. Борескова Сибирского отделения Российской академии наук Способ получения сополимера тетрафторэтилена с 2-фторсульфонилперфторэтилвиниловым эфиром - прекурсора протонопроводящих мембран - методом эмульсионной сополимеризации
CN107075291B (zh) 2014-10-20 2020-10-23 索尔维特殊聚合物意大利有限公司 用于质子交换膜的液体组合物
US9944571B2 (en) 2014-11-19 2018-04-17 Solvay Specialty Polymers Italy S.P.A. One-pot process using heterogeneous catalyst
JP7023118B2 (ja) 2015-05-27 2022-02-21 ソルベイ スペシャルティ ポリマーズ イタリー エス.ピー.エー. 低結晶化度フルオロポリマー粒子のための粘着防止処理
US11059922B2 (en) 2016-10-28 2021-07-13 Solvay Specialty Polymers Italy S.P.A. Method for cross-linking polymers
KR102480848B1 (ko) 2017-03-10 2022-12-26 솔베이 스페셜티 폴리머즈 유에스에이, 엘.엘.씨. 용융-가공성 조성물
EP3375798A1 (en) 2017-03-17 2018-09-19 Solvay Specialty Polymers Italy S.p.A. Method for making fluoropolymers
US11591430B2 (en) 2017-03-17 2023-02-28 Solvay Specialty Polymers Italy S.P.A. Method for making fluoropolymers
RU2671812C1 (ru) * 2018-06-19 2018-11-07 Федеральное государственное бюджетное учреждение науки Институт высокомолекулярных соединений Российской академии наук Способ получения сополимера перфтор-3-оксапентенсульфонилфторида и тетрафторэтилена в качестве прекурсора перфторированных протонопроводящих мембран
TW202204892A (zh) * 2020-06-29 2022-02-01 美商瑟蘭斯國際股份有限公司 於乙酸乙烯酯製造之金屬離子原位分析
CA3243841A1 (en) 2022-03-01 2023-09-07 Syensqo Specialty Polymers Italy S.p.A. PROCESS FOR MANUFACTURING FLUOROPOLYMERS CONTAINING ION EXCHANGE GROUPS
WO2024132985A1 (en) 2022-12-19 2024-06-27 Solvay Specialty Polymers Italy S.P.A. Sio2 supported ceo2 as radical scavenger
WO2025133363A1 (en) 2023-12-21 2025-06-26 Specialty Operations France Compositions comprising cerium oxide/polyoxometalate particles and ion exchange polymer, and their use in proton exchange membranes or electrocatalyst layers
WO2025233235A1 (en) 2024-05-07 2025-11-13 Syensqo Specialty Polymers Italy S.p.A. Melt-processable fluoropolymer composition, preparation methods and uses thereof
WO2025238042A1 (en) 2024-05-17 2025-11-20 Syensqo Specialty Polymers Italy S.p.A. Improved fluorinated polymer composition and use thereof in an electrochemical device

Family Cites Families (22)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4035565A (en) 1975-03-27 1977-07-12 E. I. Du Pont De Nemours And Company Fluoropolymer containing a small amount of bromine-containing olefin units
SE7712836L (sv) * 1976-12-02 1978-06-03 Du Pont Polyfluoroallyloxiforeningar
JPS53125491A (en) 1977-04-08 1978-11-01 Daikin Ind Ltd Fluorine-containing polymer easily curable and its curable composition
US4564662A (en) 1984-02-23 1986-01-14 Minnesota Mining And Manufacturing Company Fluorocarbon elastomer
DE3662142D1 (en) 1985-03-28 1989-03-30 Daikin Ind Ltd Novel fluorovinyl ether and copolymer comprising the same
IT1187684B (it) 1985-07-08 1987-12-23 Montefluos Spa Procedimento per la preparazione di fluoroelastomeri vulcanizzabili e prodotti cosi' ottenuti
US4694045A (en) 1985-12-11 1987-09-15 E. I. Du Pont De Nemours And Company Base resistant fluoroelastomers
IL82308A (en) 1986-06-26 1990-11-29 Ausimont Spa Microemulsions containing perfluoropolyethers
IT1204903B (it) * 1986-06-26 1989-03-10 Ausimont Spa Processo di polimerizzazione in dispersione acquosa di monomeri florati
US4940525A (en) * 1987-05-08 1990-07-10 The Dow Chemical Company Low equivalent weight sulfonic fluoropolymers
JPS63304009A (ja) 1987-06-04 1988-12-12 Nippon Mektron Ltd パ−オキサイド加硫可能な含フッ素エラストマ−の製造方法
IT1235545B (it) 1989-07-10 1992-09-09 Ausimont Srl Fluoroelastomeri dotati di migliore processabilita' e procedimento di preparazione
IT1271136B (it) * 1993-03-23 1997-05-27 Ausimont Spa Processo di (co)polimerizzazione in emulsione acquosa di monomeri olefinici fluorurati
JP3487652B2 (ja) * 1993-10-12 2004-01-19 旭化成株式会社 官能基含有パーフルオロカーボン系共重合体の製造方法、及び官能基含有パーフルオロカーボン系共重合体組成物
US5608022A (en) * 1993-10-12 1997-03-04 Asahi Kasei Kogyo Kabushiki Kaisha Perfluorocarbon copolymer containing functional groups and a method for producing it
IT1265461B1 (it) * 1993-12-29 1996-11-22 Ausimont Spa Fluoroelastomeri comprendenti unita' monomeriche derivanti da una bis-olefina
CA2248045C (en) * 1996-04-04 2006-11-07 Novartis Ag High water content porous polymer
JP3804197B2 (ja) * 1997-07-24 2006-08-02 旭硝子株式会社 フッ素化モノマーの回収方法
ITMI981519A1 (it) * 1998-07-02 2000-01-02 Ausimont Spa Processodi polimerizzazione del tfe
IT1308628B1 (it) * 1999-02-23 2002-01-09 Ausimont Spa Composizioni fluoroelastomeriche.
US6429258B1 (en) * 1999-05-20 2002-08-06 E. I. Du Pont De Nemours & Company Polymerization of fluoromonomers
US20030148158A1 (en) * 1999-12-29 2003-08-07 Ameduri Bruno Michel Fluorosulphonated elastomers with low glass transition based on vinylidene fluoride

Also Published As

Publication number Publication date
EP1172382A2 (en) 2002-01-16
ITMI20001417A0 (it) 2000-06-23
DE60115335D1 (de) 2006-01-05
US20020013439A1 (en) 2002-01-31
EP1172382B1 (en) 2005-11-30
CA2351858C (en) 2011-03-22
CA2351858A1 (en) 2001-12-23
ITMI20001417A1 (it) 2001-12-23
JP2002088103A (ja) 2002-03-27
EP1172382A3 (en) 2003-09-24
JP5075307B2 (ja) 2012-11-21
IT1318594B1 (it) 2003-08-27
US6555639B2 (en) 2003-04-29

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