DE60115335T2 - Polymerisationsverfahren von sulphonischen Monomeren - Google Patents
Polymerisationsverfahren von sulphonischen Monomeren Download PDFInfo
- Publication number
- DE60115335T2 DE60115335T2 DE60115335T DE60115335T DE60115335T2 DE 60115335 T2 DE60115335 T2 DE 60115335T2 DE 60115335 T DE60115335 T DE 60115335T DE 60115335 T DE60115335 T DE 60115335T DE 60115335 T2 DE60115335 T2 DE 60115335T2
- Authority
- DE
- Germany
- Prior art keywords
- reactor
- tfe
- formula
- polymerization
- fluorinated
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F214/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen
- C08F214/18—Monomers containing fluorine
- C08F214/184—Monomers containing fluorine with fluorinated vinyl ethers
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F216/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an alcohol, ether, aldehydo, ketonic, acetal or ketal radical
- C08F216/12—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an alcohol, ether, aldehydo, ketonic, acetal or ketal radical by an ether radical
- C08F216/14—Monomers containing only one unsaturated aliphatic radical
- C08F216/1466—Monomers containing sulfur
- C08F216/1475—Monomers containing sulfur and oxygen
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Polymerisation Methods In General (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Graft Or Block Polymers (AREA)
- Conductive Materials (AREA)
- Fuel Cell (AREA)
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| IT2000MI001417A IT1318594B1 (it) | 2000-06-23 | 2000-06-23 | Processo di polimerizzazione di monomeri solfonici. |
| ITMI001417 | 2000-06-23 |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| DE60115335D1 DE60115335D1 (de) | 2006-01-05 |
| DE60115335T2 true DE60115335T2 (de) | 2006-08-03 |
Family
ID=11445328
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| DE60115335T Expired - Lifetime DE60115335T2 (de) | 2000-06-23 | 2001-06-19 | Polymerisationsverfahren von sulphonischen Monomeren |
Country Status (6)
| Country | Link |
|---|---|
| US (1) | US6555639B2 (https=) |
| EP (1) | EP1172382B1 (https=) |
| JP (1) | JP5075307B2 (https=) |
| CA (1) | CA2351858C (https=) |
| DE (1) | DE60115335T2 (https=) |
| IT (1) | IT1318594B1 (https=) |
Families Citing this family (43)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| ITMI20012744A1 (it) * | 2001-12-21 | 2003-06-21 | Ausimont Spa | Processo di polimerizzazione di monomeri solfonici |
| ITMI20020178A1 (it) * | 2002-02-01 | 2003-08-01 | Ausimont Spa | Uso di additivi fluorurati nell'etching o polishing di circuiti integrati |
| ITMI20020902A1 (it) | 2002-04-26 | 2003-10-27 | Ausimont Spa | Processo per preparare membrane ionomeriche |
| WO2004007576A1 (ja) * | 2002-06-14 | 2004-01-22 | Daikin Industries, Ltd. | 含フッ素共重合体製造方法、含フッ素共重合体及び成形体 |
| WO2004011508A1 (en) * | 2002-07-29 | 2004-02-05 | 3M Innovative Properties Company | Process for making a fluoroelastomer |
| FR2843398B1 (fr) * | 2002-08-09 | 2007-04-27 | Commissariat Energie Atomique | Polymeres fluores, membranes preparees a partir de ceux-ci et dispositif de pile a combustible comprenant ces membranes |
| US6828386B2 (en) | 2002-09-20 | 2004-12-07 | Ballard Power Systems Inc. | Process for preparing graft copolymers and membranes formed therefrom |
| US7214740B2 (en) * | 2005-05-03 | 2007-05-08 | 3M Innovative Properties Company | Fluorinated ionomers with reduced amounts of carbonyl end groups |
| EP1939222B2 (en) * | 2005-10-17 | 2019-09-04 | AGC Inc. | Process for producing an AQUEOUS POLYTETRAFLUOROETHYLENE EMULSION, AND POLYTETRAFLUOROETHYLENE FINE POWDER AND POROUS MATERIAL PRODUCED FROM THE SAME |
| ITMI20052509A1 (it) * | 2005-12-28 | 2007-06-29 | Solvay Solexis Spa | Assemblati per dispositivi elettrochimici |
| ITMI20052508A1 (it) * | 2005-12-28 | 2007-06-29 | Solvay Solexis Spa | Processo per ottenere ccm con subgasket |
| EP1873860A1 (en) * | 2006-06-28 | 2008-01-02 | Solvay Solexis S.p.A. | Catalyst-Polymer Liquid Dispersion for Fuel Cell Applications |
| ITMI20061261A1 (it) * | 2006-06-29 | 2007-12-30 | Solvay Solexis Spa | Assemblati per dispositivi elettrochimici |
| WO2008132959A1 (ja) * | 2007-04-13 | 2008-11-06 | Asahi Glass Company, Limited | 含フッ素カルボン酸化合物を用いた含フッ素ポリマーの製造方法 |
| EP2222761A1 (en) * | 2007-12-20 | 2010-09-01 | E. I. du Pont de Nemours and Company | Process to prepare crosslinkable trifluorostyrene polymers and membranes |
| US8071254B2 (en) | 2007-12-27 | 2011-12-06 | E. I. Du Pont De Nemours And Company | Crosslinkable fluoropolymer, crosslinked fluoropolymers and crosslinked fluoropolymer membranes |
| US7989568B2 (en) * | 2008-11-13 | 2011-08-02 | E.I. Du Pont De Nemours And Company | Fluorosulfonates |
| US7977426B2 (en) * | 2008-11-13 | 2011-07-12 | E. I. Du Pont De Nemours And Company | Fluoroalkyl ether sulfonate surfactants |
| EP2493940B2 (en) † | 2009-10-29 | 2018-08-29 | Solvay Specialty Polymers Italy S.p.A. | Process for the isolation of sulfonyl fluoride polymers and polymers obtained therefrom |
| US9023554B2 (en) | 2009-12-11 | 2015-05-05 | Shandong Huaxia Shenzhou New Material Co., Ltd. | Perfluorinated ion exchange resin, preparation method and use thereof |
| JP5486693B2 (ja) | 2009-12-15 | 2014-05-07 | シャンドン・フアシャ・シェンゾウ・ニュー・マテリアル・カンパニー・リミテッド | 高交換容量過フッ化イオン交換樹脂、その調製方法、及び使用 |
| JP5684283B2 (ja) * | 2009-12-18 | 2015-03-11 | ソルヴェイ・スペシャルティ・ポリマーズ・イタリー・エッセ・ピ・ア | フルオロポリマーの製造方法 |
| US8940846B2 (en) | 2010-07-01 | 2015-01-27 | Solvay Specialty Polymers Italy S.P.A. | Process for the treatment of sulfonyl fluoride polymers |
| KR101892317B1 (ko) | 2011-04-07 | 2018-08-27 | 솔베이 스페셜티 폴리머스 이태리 에스.피.에이. | 가교형 불소화 중합체의 제조 방법 |
| EP2719007A1 (en) | 2011-06-06 | 2014-04-16 | Solvay Specialty Polymers Italy S.p.A. | Stable ion exchange fluorinated polymers and membranes obtained therefrom |
| EP2586800A1 (en) | 2011-10-28 | 2013-05-01 | Solvay Specialty Polymers Italy S.p.A. | Process for the treatment of sulfonyl fluoride polymers with supercritical carbon dioxide |
| DK2872445T3 (da) | 2012-07-11 | 2019-12-09 | Solvay Specialty Polymers It | Blandingsmetaloxider som scavengers til fluorerede ionbytningspolymerer |
| WO2014173782A1 (en) | 2013-04-22 | 2014-10-30 | Solvay Specialty Polymers Italy S.P.A. | Cross-linkable polymers comprising sulfonic acid functional groups |
| RU2545182C1 (ru) * | 2013-09-06 | 2015-03-27 | Федеральное государственное бюджетное учреждение науки Институт катализа им. Г.К. Борескова Сибирского отделения Российской академии наук | Способ получения сополимера тетрафторэтилена с 2-фторсульфонилперфторэтилвиниловым эфиром - прекурсора протонопроводящих мембран - методом эмульсионной сополимеризации |
| EP3209710B1 (en) | 2014-10-20 | 2020-12-09 | Solvay Specialty Polymers Italy S.p.A. | Liquid composition for proton exchange membranes |
| US9944571B2 (en) | 2014-11-19 | 2018-04-17 | Solvay Specialty Polymers Italy S.P.A. | One-pot process using heterogeneous catalyst |
| US20180179342A1 (en) | 2015-05-27 | 2018-06-28 | Solvay Specialty Polymers Italy S.P.A. | Anti-sticking treatment for low cristallinity fluoropolymer particles |
| JP7096241B6 (ja) | 2016-10-28 | 2023-12-22 | ソルベイ スペシャルティ ポリマーズ イタリー エス.ピー.エー. | ポリマーを架橋する方法 |
| JP7676110B2 (ja) | 2017-03-10 | 2025-05-14 | ソルベイ スペシャルティ ポリマーズ ユーエスエー, エルエルシー | 溶融加工可能な組成物 |
| EP3375798A1 (en) | 2017-03-17 | 2018-09-19 | Solvay Specialty Polymers Italy S.p.A. | Method for making fluoropolymers |
| KR102719413B1 (ko) * | 2017-03-17 | 2024-10-21 | 솔베이 스페셜티 폴리머스 이태리 에스.피.에이. | 플루오로중합체의 제조 방법 |
| RU2671812C1 (ru) * | 2018-06-19 | 2018-11-07 | Федеральное государственное бюджетное учреждение науки Институт высокомолекулярных соединений Российской академии наук | Способ получения сополимера перфтор-3-оксапентенсульфонилфторида и тетрафторэтилена в качестве прекурсора перфторированных протонопроводящих мембран |
| TW202204892A (zh) * | 2020-06-29 | 2022-02-01 | 美商瑟蘭斯國際股份有限公司 | 於乙酸乙烯酯製造之金屬離子原位分析 |
| AU2023227088A1 (en) | 2022-03-01 | 2024-08-22 | Syensqo Specialty Polymers Italy S.p.A. | Method for making fluoropolymers containing ion exchange groups |
| CN120936681A (zh) | 2022-12-19 | 2025-11-11 | 世索科特殊聚合物意大利有限公司 | 作为自由基清除剂的SiO2负载的CeO2 |
| WO2025133362A1 (en) | 2023-12-21 | 2025-06-26 | Specialty Operations France | Cerium oxide/polyoxometalate particle dispersions and their use in the preparation of proton exchange membranes or electrocatalyst layers |
| WO2025233235A1 (en) | 2024-05-07 | 2025-11-13 | Syensqo Specialty Polymers Italy S.p.A. | Melt-processable fluoropolymer composition, preparation methods and uses thereof |
| WO2025238042A1 (en) | 2024-05-17 | 2025-11-20 | Syensqo Specialty Polymers Italy S.p.A. | Improved fluorinated polymer composition and use thereof in an electrochemical device |
Family Cites Families (22)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4035565A (en) | 1975-03-27 | 1977-07-12 | E. I. Du Pont De Nemours And Company | Fluoropolymer containing a small amount of bromine-containing olefin units |
| SE7712836L (sv) * | 1976-12-02 | 1978-06-03 | Du Pont | Polyfluoroallyloxiforeningar |
| JPS53125491A (en) | 1977-04-08 | 1978-11-01 | Daikin Ind Ltd | Fluorine-containing polymer easily curable and its curable composition |
| US4564662A (en) | 1984-02-23 | 1986-01-14 | Minnesota Mining And Manufacturing Company | Fluorocarbon elastomer |
| DE3662142D1 (en) | 1985-03-28 | 1989-03-30 | Daikin Ind Ltd | Novel fluorovinyl ether and copolymer comprising the same |
| IT1187684B (it) | 1985-07-08 | 1987-12-23 | Montefluos Spa | Procedimento per la preparazione di fluoroelastomeri vulcanizzabili e prodotti cosi' ottenuti |
| US4694045A (en) | 1985-12-11 | 1987-09-15 | E. I. Du Pont De Nemours And Company | Base resistant fluoroelastomers |
| IL82308A (en) | 1986-06-26 | 1990-11-29 | Ausimont Spa | Microemulsions containing perfluoropolyethers |
| IT1204903B (it) * | 1986-06-26 | 1989-03-10 | Ausimont Spa | Processo di polimerizzazione in dispersione acquosa di monomeri florati |
| US4940525A (en) * | 1987-05-08 | 1990-07-10 | The Dow Chemical Company | Low equivalent weight sulfonic fluoropolymers |
| JPS63304009A (ja) | 1987-06-04 | 1988-12-12 | Nippon Mektron Ltd | パ−オキサイド加硫可能な含フッ素エラストマ−の製造方法 |
| IT1235545B (it) | 1989-07-10 | 1992-09-09 | Ausimont Srl | Fluoroelastomeri dotati di migliore processabilita' e procedimento di preparazione |
| IT1271136B (it) * | 1993-03-23 | 1997-05-27 | Ausimont Spa | Processo di (co)polimerizzazione in emulsione acquosa di monomeri olefinici fluorurati |
| WO1995010541A1 (en) * | 1993-10-12 | 1995-04-20 | Asahi Kasei Kogyo Kabushiki Kaisha | Perfluorocarbon copolymer having functional groups and process for producing the same |
| JP3487652B2 (ja) * | 1993-10-12 | 2004-01-19 | 旭化成株式会社 | 官能基含有パーフルオロカーボン系共重合体の製造方法、及び官能基含有パーフルオロカーボン系共重合体組成物 |
| IT1265461B1 (it) * | 1993-12-29 | 1996-11-22 | Ausimont Spa | Fluoroelastomeri comprendenti unita' monomeriche derivanti da una bis-olefina |
| ATE254641T1 (de) * | 1996-03-27 | 2003-12-15 | Commw Scient Ind Res Org | Poröses polymer mit hohem wassergehalt |
| JP3804197B2 (ja) * | 1997-07-24 | 2006-08-02 | 旭硝子株式会社 | フッ素化モノマーの回収方法 |
| ITMI981519A1 (it) * | 1998-07-02 | 2000-01-02 | Ausimont Spa | Processodi polimerizzazione del tfe |
| IT1308628B1 (it) * | 1999-02-23 | 2002-01-09 | Ausimont Spa | Composizioni fluoroelastomeriche. |
| US6429258B1 (en) * | 1999-05-20 | 2002-08-06 | E. I. Du Pont De Nemours & Company | Polymerization of fluoromonomers |
| WO2001049757A1 (fr) * | 1999-12-29 | 2001-07-12 | HYDRO-QUéBEC | Elastomeres fluorosulfones a faible tg a base de fluorure de vinylidene |
-
2000
- 2000-06-23 IT IT2000MI001417A patent/IT1318594B1/it active
-
2001
- 2001-06-19 EP EP01114614A patent/EP1172382B1/en not_active Expired - Lifetime
- 2001-06-19 DE DE60115335T patent/DE60115335T2/de not_active Expired - Lifetime
- 2001-06-22 US US09/886,106 patent/US6555639B2/en not_active Expired - Lifetime
- 2001-06-22 JP JP2001189803A patent/JP5075307B2/ja not_active Expired - Fee Related
- 2001-06-26 CA CA2351858A patent/CA2351858C/en not_active Expired - Fee Related
Also Published As
| Publication number | Publication date |
|---|---|
| US20020013439A1 (en) | 2002-01-31 |
| ITMI20001417A0 (it) | 2000-06-23 |
| CA2351858A1 (en) | 2001-12-23 |
| JP2002088103A (ja) | 2002-03-27 |
| ITMI20001417A1 (it) | 2001-12-23 |
| EP1172382A2 (en) | 2002-01-16 |
| JP5075307B2 (ja) | 2012-11-21 |
| EP1172382B1 (en) | 2005-11-30 |
| DE60115335D1 (de) | 2006-01-05 |
| EP1172382A3 (en) | 2003-09-24 |
| IT1318594B1 (it) | 2003-08-27 |
| US6555639B2 (en) | 2003-04-29 |
| CA2351858C (en) | 2011-03-22 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| 8364 | No opposition during term of opposition |