DE60026177T2 - Stabilisatormischung - Google Patents
Stabilisatormischung Download PDFInfo
- Publication number
- DE60026177T2 DE60026177T2 DE60026177T DE60026177T DE60026177T2 DE 60026177 T2 DE60026177 T2 DE 60026177T2 DE 60026177 T DE60026177 T DE 60026177T DE 60026177 T DE60026177 T DE 60026177T DE 60026177 T2 DE60026177 T2 DE 60026177T2
- Authority
- DE
- Germany
- Prior art keywords
- sub
- alkyl
- alkenyl
- independently
- radicals
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- 239000000203 mixture Substances 0.000 title claims abstract description 142
- 239000003381 stabilizer Substances 0.000 title claims abstract description 49
- 150000001875 compounds Chemical class 0.000 claims abstract description 105
- 229910052739 hydrogen Inorganic materials 0.000 claims abstract description 57
- 239000001257 hydrogen Substances 0.000 claims abstract description 37
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 claims abstract description 36
- 239000001301 oxygen Substances 0.000 claims abstract description 19
- 229910052760 oxygen Inorganic materials 0.000 claims abstract description 19
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 claims abstract description 16
- 239000011368 organic material Substances 0.000 claims abstract description 12
- -1 -Hal Chemical group 0.000 claims description 177
- 125000003342 alkenyl group Chemical group 0.000 claims description 37
- 125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 claims description 36
- 125000000217 alkyl group Chemical group 0.000 claims description 34
- 238000000576 coating method Methods 0.000 claims description 31
- 229920002647 polyamide Polymers 0.000 claims description 25
- 239000011230 binding agent Substances 0.000 claims description 23
- 239000000463 material Substances 0.000 claims description 23
- 125000003884 phenylalkyl group Chemical group 0.000 claims description 23
- 150000001412 amines Chemical class 0.000 claims description 22
- 229910052751 metal Inorganic materials 0.000 claims description 22
- 239000002184 metal Substances 0.000 claims description 22
- 238000000034 method Methods 0.000 claims description 22
- 125000000392 cycloalkenyl group Chemical group 0.000 claims description 21
- 239000004952 Polyamide Substances 0.000 claims description 19
- 229910052799 carbon Inorganic materials 0.000 claims description 19
- 239000002023 wood Substances 0.000 claims description 18
- 239000003054 catalyst Substances 0.000 claims description 17
- 125000005037 alkyl phenyl group Chemical group 0.000 claims description 16
- 125000000304 alkynyl group Chemical group 0.000 claims description 16
- 125000000113 cyclohexyl group Chemical group [H]C1([H])C([H])([H])C([H])([H])C([H])(*)C([H])([H])C1([H])[H] 0.000 claims description 15
- 125000001624 naphthyl group Chemical group 0.000 claims description 14
- SNOOUWRIMMFWNE-UHFFFAOYSA-M sodium;6-[(3,4,5-trimethoxybenzoyl)amino]hexanoate Chemical compound [Na+].COC1=CC(C(=O)NCCCCCC([O-])=O)=CC(OC)=C1OC SNOOUWRIMMFWNE-UHFFFAOYSA-M 0.000 claims description 13
- 239000006096 absorbing agent Substances 0.000 claims description 12
- 150000001602 bicycloalkyls Chemical group 0.000 claims description 12
- 229920001169 thermoplastic Polymers 0.000 claims description 9
- 125000000753 cycloalkyl group Chemical group 0.000 claims description 8
- 229910052700 potassium Inorganic materials 0.000 claims description 8
- 230000000087 stabilizing effect Effects 0.000 claims description 8
- 239000000654 additive Substances 0.000 claims description 7
- 229910052783 alkali metal Inorganic materials 0.000 claims description 7
- 239000004611 light stabiliser Substances 0.000 claims description 7
- 125000006711 (C2-C12) alkynyl group Chemical group 0.000 claims description 6
- 125000003118 aryl group Chemical group 0.000 claims description 6
- 239000000049 pigment Substances 0.000 claims description 6
- 229910052708 sodium Inorganic materials 0.000 claims description 6
- QGZKDVFQNNGYKY-UHFFFAOYSA-O Ammonium Chemical compound [NH4+] QGZKDVFQNNGYKY-UHFFFAOYSA-O 0.000 claims description 5
- 239000003963 antioxidant agent Substances 0.000 claims description 5
- 150000001768 cations Chemical class 0.000 claims description 5
- 230000006378 damage Effects 0.000 claims description 5
- 229910052744 lithium Inorganic materials 0.000 claims description 5
- 125000000466 oxiranyl group Chemical group 0.000 claims description 5
- AQSJGOWTSHOLKH-UHFFFAOYSA-N phosphite(3-) Chemical class [O-]P([O-])[O-] AQSJGOWTSHOLKH-UHFFFAOYSA-N 0.000 claims description 5
- FJGQBLRYBUAASW-UHFFFAOYSA-N 2-(benzotriazol-2-yl)phenol Chemical class OC1=CC=CC=C1N1N=C2C=CC=CC2=N1 FJGQBLRYBUAASW-UHFFFAOYSA-N 0.000 claims description 4
- 230000008569 process Effects 0.000 claims description 4
- HWRLEEPNFJNTOP-UHFFFAOYSA-N 2-(1,3,5-triazin-2-yl)phenol Chemical class OC1=CC=CC=C1C1=NC=NC=N1 HWRLEEPNFJNTOP-UHFFFAOYSA-N 0.000 claims description 3
- 230000009471 action Effects 0.000 claims description 3
- 230000000996 additive effect Effects 0.000 claims description 3
- 239000003795 chemical substances by application Substances 0.000 claims description 3
- 239000003995 emulsifying agent Substances 0.000 claims description 3
- 239000003063 flame retardant Substances 0.000 claims description 3
- 230000009931 harmful effect Effects 0.000 claims description 3
- 239000006078 metal deactivator Substances 0.000 claims description 3
- FTWUXYZHDFCGSV-UHFFFAOYSA-N n,n'-diphenyloxamide Chemical class C=1C=CC=CC=1NC(=O)C(=O)NC1=CC=CC=C1 FTWUXYZHDFCGSV-UHFFFAOYSA-N 0.000 claims description 3
- 230000003287 optical effect Effects 0.000 claims description 3
- XRBCRPZXSCBRTK-UHFFFAOYSA-N phosphonous acid Chemical class OPO XRBCRPZXSCBRTK-UHFFFAOYSA-N 0.000 claims description 3
- 239000004014 plasticizer Substances 0.000 claims description 3
- HJIAMFHSAAEUKR-UHFFFAOYSA-N (2-hydroxyphenyl)-phenylmethanone Chemical class OC1=CC=CC=C1C(=O)C1=CC=CC=C1 HJIAMFHSAAEUKR-UHFFFAOYSA-N 0.000 claims description 2
- 125000006710 (C2-C12) alkenyl group Chemical group 0.000 claims description 2
- ACZGCWSMSTYWDQ-UHFFFAOYSA-N 3h-1-benzofuran-2-one Chemical class C1=CC=C2OC(=O)CC2=C1 ACZGCWSMSTYWDQ-UHFFFAOYSA-N 0.000 claims description 2
- 239000004215 Carbon black (E152) Substances 0.000 claims description 2
- 239000002216 antistatic agent Substances 0.000 claims description 2
- 239000002270 dispersing agent Substances 0.000 claims description 2
- 239000000945 filler Substances 0.000 claims description 2
- 229930195733 hydrocarbon Natural products 0.000 claims description 2
- 150000002443 hydroxylamines Chemical class 0.000 claims description 2
- JYGFTBXVXVMTGB-UHFFFAOYSA-N indolin-2-one Chemical compound C1=CC=C2NC(=O)CC2=C1 JYGFTBXVXVMTGB-UHFFFAOYSA-N 0.000 claims description 2
- 239000000314 lubricant Substances 0.000 claims description 2
- 239000002667 nucleating agent Substances 0.000 claims description 2
- 239000003380 propellant Substances 0.000 claims description 2
- 239000012744 reinforcing agent Substances 0.000 claims description 2
- 238000000518 rheometry Methods 0.000 claims description 2
- 208000027418 Wounds and injury Diseases 0.000 claims 1
- 208000014674 injury Diseases 0.000 claims 1
- XYFCBTPGUUZFHI-UHFFFAOYSA-O phosphonium Chemical compound [PH4+] XYFCBTPGUUZFHI-UHFFFAOYSA-O 0.000 claims 1
- 229920001577 copolymer Polymers 0.000 description 74
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 description 46
- 239000010410 layer Substances 0.000 description 38
- 229920000642 polymer Polymers 0.000 description 34
- 150000003254 radicals Chemical class 0.000 description 34
- ZMXDDKWLCZADIW-UHFFFAOYSA-N N,N-Dimethylformamide Chemical compound CN(C)C=O ZMXDDKWLCZADIW-UHFFFAOYSA-N 0.000 description 33
- XEKOWRVHYACXOJ-UHFFFAOYSA-N Ethyl acetate Chemical compound CCOC(C)=O XEKOWRVHYACXOJ-UHFFFAOYSA-N 0.000 description 27
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 description 27
- 239000011248 coating agent Substances 0.000 description 25
- 229920005989 resin Polymers 0.000 description 25
- 239000011347 resin Substances 0.000 description 25
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 24
- 239000000047 product Substances 0.000 description 23
- 239000002904 solvent Substances 0.000 description 19
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 18
- 229920000573 polyethylene Polymers 0.000 description 18
- 239000003973 paint Substances 0.000 description 17
- 229920002857 polybutadiene Polymers 0.000 description 17
- MTHSVFCYNBDYFN-UHFFFAOYSA-N diethylene glycol Chemical compound OCCOCCO MTHSVFCYNBDYFN-UHFFFAOYSA-N 0.000 description 16
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 15
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 15
- 229920000159 gelatin Polymers 0.000 description 15
- 235000019322 gelatine Nutrition 0.000 description 15
- 229910052757 nitrogen Inorganic materials 0.000 description 15
- 150000002148 esters Chemical class 0.000 description 14
- 239000000243 solution Substances 0.000 description 14
- SGZWJGRZDJCDIM-UHFFFAOYSA-N 4-[4,6-bis(2,4-dihydroxyphenyl)-1,3,5-triazin-2-yl]benzene-1,3-diol Chemical class OC1=CC(O)=CC=C1C1=NC(C=2C(=CC(O)=CC=2)O)=NC(C=2C(=CC(O)=CC=2)O)=N1 SGZWJGRZDJCDIM-UHFFFAOYSA-N 0.000 description 13
- 108010010803 Gelatin Proteins 0.000 description 13
- 239000004743 Polypropylene Substances 0.000 description 13
- 238000007792 addition Methods 0.000 description 13
- 239000008273 gelatin Substances 0.000 description 13
- 235000011852 gelatine desserts Nutrition 0.000 description 13
- 229920001684 low density polyethylene Polymers 0.000 description 13
- 239000004702 low-density polyethylene Substances 0.000 description 13
- 239000004417 polycarbonate Substances 0.000 description 13
- 229920000915 polyvinyl chloride Polymers 0.000 description 13
- NIXOWILDQLNWCW-UHFFFAOYSA-M Acrylate Chemical compound [O-]C(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-M 0.000 description 12
- NLHHRLWOUZZQLW-UHFFFAOYSA-N Acrylonitrile Chemical compound C=CC#N NLHHRLWOUZZQLW-UHFFFAOYSA-N 0.000 description 12
- IMNFDUFMRHMDMM-UHFFFAOYSA-N N-Heptane Chemical compound CCCCCCC IMNFDUFMRHMDMM-UHFFFAOYSA-N 0.000 description 12
- CDBYLPFSWZWCQE-UHFFFAOYSA-L Sodium Carbonate Chemical compound [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 description 12
- 229920006324 polyoxymethylene Polymers 0.000 description 12
- 239000004800 polyvinyl chloride Substances 0.000 description 12
- 239000004721 Polyphenylene oxide Substances 0.000 description 11
- 150000001252 acrylic acid derivatives Chemical class 0.000 description 11
- 229920000122 acrylonitrile butadiene styrene Polymers 0.000 description 11
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- 239000004814 polyurethane Substances 0.000 description 10
- 150000003839 salts Chemical class 0.000 description 10
- 239000007787 solid Substances 0.000 description 10
- 229920000877 Melamine resin Polymers 0.000 description 9
- 125000001931 aliphatic group Chemical group 0.000 description 9
- KBPLFHHGFOOTCA-UHFFFAOYSA-N caprylic alcohol Natural products CCCCCCCCO KBPLFHHGFOOTCA-UHFFFAOYSA-N 0.000 description 9
- 238000001723 curing Methods 0.000 description 9
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- 239000011734 sodium Substances 0.000 description 9
- 239000007858 starting material Substances 0.000 description 9
- ZWEHNKRNPOVVGH-UHFFFAOYSA-N 2-Butanone Chemical compound CCC(C)=O ZWEHNKRNPOVVGH-UHFFFAOYSA-N 0.000 description 8
- 239000005062 Polybutadiene Substances 0.000 description 8
- 229920000180 alkyd Polymers 0.000 description 8
- DOIRQSBPFJWKBE-UHFFFAOYSA-N dibutyl phthalate Chemical compound CCCCOC(=O)C1=CC=CC=C1C(=O)OCCCC DOIRQSBPFJWKBE-UHFFFAOYSA-N 0.000 description 8
- 239000000976 ink Substances 0.000 description 8
- GLDOVTGHNKAZLK-UHFFFAOYSA-N octadecan-1-ol Chemical compound CCCCCCCCCCCCCCCCCCO GLDOVTGHNKAZLK-UHFFFAOYSA-N 0.000 description 8
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 7
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- 238000004128 high performance liquid chromatography Methods 0.000 description 7
- 150000002739 metals Chemical class 0.000 description 7
- 229920000570 polyether Polymers 0.000 description 7
- 239000005056 polyisocyanate Substances 0.000 description 7
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- 239000000843 powder Substances 0.000 description 7
- UHOVQNZJYSORNB-UHFFFAOYSA-N Benzene Chemical compound C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 description 6
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 description 6
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- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 6
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- 125000001424 substituent group Chemical group 0.000 description 4
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- VQMHSKWEJGIXGA-UHFFFAOYSA-N 2-(benzotriazol-2-yl)-6-dodecyl-4-methylphenol Chemical compound CCCCCCCCCCCCC1=CC(C)=CC(N2N=C3C=CC=CC3=N2)=C1O VQMHSKWEJGIXGA-UHFFFAOYSA-N 0.000 description 3
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- AXZKOIWUVFPNLO-UHFFFAOYSA-N magnesium;oxygen(2-) Chemical compound [O-2].[Mg+2] AXZKOIWUVFPNLO-UHFFFAOYSA-N 0.000 description 1
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- 125000005346 substituted cycloalkyl group Chemical group 0.000 description 1
- BDHFUVZGWQCTTF-UHFFFAOYSA-M sulfonate Chemical compound [O-]S(=O)=O BDHFUVZGWQCTTF-UHFFFAOYSA-M 0.000 description 1
- 150000003871 sulfonates Chemical class 0.000 description 1
- 229910052717 sulfur Inorganic materials 0.000 description 1
- 239000011593 sulfur Substances 0.000 description 1
- 150000003467 sulfuric acid derivatives Chemical class 0.000 description 1
- YBBRCQOCSYXUOC-UHFFFAOYSA-N sulfuryl dichloride Chemical compound ClS(Cl)(=O)=O YBBRCQOCSYXUOC-UHFFFAOYSA-N 0.000 description 1
- 238000004381 surface treatment Methods 0.000 description 1
- 239000004094 surface-active agent Substances 0.000 description 1
- 238000003786 synthesis reaction Methods 0.000 description 1
- 229920002994 synthetic fiber Polymers 0.000 description 1
- 239000012209 synthetic fiber Substances 0.000 description 1
- 239000003760 tallow Substances 0.000 description 1
- LMBFAGIMSUYTBN-MPZNNTNKSA-N teixobactin Chemical compound C([C@H](C(=O)N[C@@H]([C@@H](C)CC)C(=O)N[C@@H](CO)C(=O)N[C@H](CCC(N)=O)C(=O)N[C@H]([C@@H](C)CC)C(=O)N[C@@H]([C@@H](C)CC)C(=O)N[C@@H](CO)C(=O)N[C@H]1C(N[C@@H](C)C(=O)N[C@@H](C[C@@H]2NC(=N)NC2)C(=O)N[C@H](C(=O)O[C@H]1C)[C@@H](C)CC)=O)NC)C1=CC=CC=C1 LMBFAGIMSUYTBN-MPZNNTNKSA-N 0.000 description 1
- 150000003512 tertiary amines Chemical class 0.000 description 1
- 238000012360 testing method Methods 0.000 description 1
- WHRNULOCNSKMGB-UHFFFAOYSA-N tetrahydrofuran thf Chemical compound C1CCOC1.C1CCOC1 WHRNULOCNSKMGB-UHFFFAOYSA-N 0.000 description 1
- WUPCFMITFBVJMS-UHFFFAOYSA-N tetrakis(1,2,2,6,6-pentamethylpiperidin-4-yl) butane-1,2,3,4-tetracarboxylate Chemical compound C1C(C)(C)N(C)C(C)(C)CC1OC(=O)CC(C(=O)OC1CC(C)(C)N(C)C(C)(C)C1)C(C(=O)OC1CC(C)(C)N(C)C(C)(C)C1)CC(=O)OC1CC(C)(C)N(C)C(C)(C)C1 WUPCFMITFBVJMS-UHFFFAOYSA-N 0.000 description 1
- NZNAAUDJKMURFU-UHFFFAOYSA-N tetrakis(2,2,6,6-tetramethylpiperidin-4-yl) butane-1,2,3,4-tetracarboxylate Chemical compound C1C(C)(C)NC(C)(C)CC1OC(=O)CC(C(=O)OC1CC(C)(C)NC(C)(C)C1)C(C(=O)OC1CC(C)(C)NC(C)(C)C1)CC(=O)OC1CC(C)(C)NC(C)(C)C1 NZNAAUDJKMURFU-UHFFFAOYSA-N 0.000 description 1
- 239000004753 textile Substances 0.000 description 1
- 229920002803 thermoplastic polyurethane Polymers 0.000 description 1
- 150000003568 thioethers Chemical class 0.000 description 1
- 239000013008 thixotropic agent Substances 0.000 description 1
- 230000009974 thixotropic effect Effects 0.000 description 1
- 210000001519 tissue Anatomy 0.000 description 1
- 239000004408 titanium dioxide Substances 0.000 description 1
- 235000010215 titanium dioxide Nutrition 0.000 description 1
- YONPGGFAJWQGJC-UHFFFAOYSA-K titanium(iii) chloride Chemical compound Cl[Ti](Cl)Cl YONPGGFAJWQGJC-UHFFFAOYSA-K 0.000 description 1
- 229960000984 tocofersolan Drugs 0.000 description 1
- 229930003799 tocopherol Natural products 0.000 description 1
- 239000011732 tocopherol Substances 0.000 description 1
- 235000019149 tocopherols Nutrition 0.000 description 1
- 125000003944 tolyl group Chemical group 0.000 description 1
- VZCYOOQTPOCHFL-UHFFFAOYSA-N trans-butenedioic acid Natural products OC(=O)C=CC(O)=O VZCYOOQTPOCHFL-UHFFFAOYSA-N 0.000 description 1
- KHPCPRHQVVSZAH-UHFFFAOYSA-N trans-cinnamyl beta-D-glucopyranoside Natural products OC1C(O)C(O)C(CO)OC1OCC=CC1=CC=CC=C1 KHPCPRHQVVSZAH-UHFFFAOYSA-N 0.000 description 1
- 239000010875 treated wood Substances 0.000 description 1
- IVIIAEVMQHEPAY-UHFFFAOYSA-N tridodecyl phosphite Chemical compound CCCCCCCCCCCCOP(OCCCCCCCCCCCC)OCCCCCCCCCCCC IVIIAEVMQHEPAY-UHFFFAOYSA-N 0.000 description 1
- CNUJLMSKURPSHE-UHFFFAOYSA-N trioctadecyl phosphite Chemical compound CCCCCCCCCCCCCCCCCCOP(OCCCCCCCCCCCCCCCCCC)OCCCCCCCCCCCCCCCCCC CNUJLMSKURPSHE-UHFFFAOYSA-N 0.000 description 1
- 238000009281 ultraviolet germicidal irradiation Methods 0.000 description 1
- 238000002211 ultraviolet spectrum Methods 0.000 description 1
- 229920006305 unsaturated polyester Polymers 0.000 description 1
- 150000003672 ureas Chemical class 0.000 description 1
- JOYRKODLDBILNP-UHFFFAOYSA-N urethane group Chemical group NC(=O)OCC JOYRKODLDBILNP-UHFFFAOYSA-N 0.000 description 1
- 235000019154 vitamin C Nutrition 0.000 description 1
- 239000011718 vitamin C Substances 0.000 description 1
- 235000019165 vitamin E Nutrition 0.000 description 1
- 239000011709 vitamin E Substances 0.000 description 1
- 229940046009 vitamin E Drugs 0.000 description 1
- 239000001993 wax Substances 0.000 description 1
- 238000010626 work up procedure Methods 0.000 description 1
- 229910052724 xenon Inorganic materials 0.000 description 1
- FHNFHKCVQCLJFQ-UHFFFAOYSA-N xenon atom Chemical compound [Xe] FHNFHKCVQCLJFQ-UHFFFAOYSA-N 0.000 description 1
- 239000001043 yellow dye Substances 0.000 description 1
- 150000003751 zinc Chemical class 0.000 description 1
- 239000004711 α-olefin Substances 0.000 description 1
- 239000002076 α-tocopherol Substances 0.000 description 1
- 235000004835 α-tocopherol Nutrition 0.000 description 1
- 239000011590 β-tocopherol Substances 0.000 description 1
- 235000007680 β-tocopherol Nutrition 0.000 description 1
- 239000002478 γ-tocopherol Substances 0.000 description 1
- QUEDXNHFTDJVIY-UHFFFAOYSA-N γ-tocopherol Chemical class OC1=C(C)C(C)=C2OC(CCCC(C)CCCC(C)CCCC(C)C)(C)CCC2=C1 QUEDXNHFTDJVIY-UHFFFAOYSA-N 0.000 description 1
- QUEDXNHFTDJVIY-DQCZWYHMSA-N γ-tocopherol Chemical compound OC1=C(C)C(C)=C2O[C@@](CCC[C@H](C)CCC[C@H](C)CCCC(C)C)(C)CCC2=C1 QUEDXNHFTDJVIY-DQCZWYHMSA-N 0.000 description 1
- 239000002446 δ-tocopherol Substances 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/16—Nitrogen-containing compounds
- C08K5/34—Heterocyclic compounds having nitrogen in the ring
- C08K5/3467—Heterocyclic compounds having nitrogen in the ring having more than two nitrogen atoms in the ring
- C08K5/3477—Six-membered rings
- C08K5/3492—Triazines
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D251/00—Heterocyclic compounds containing 1,3,5-triazine rings
- C07D251/02—Heterocyclic compounds containing 1,3,5-triazine rings not condensed with other rings
- C07D251/12—Heterocyclic compounds containing 1,3,5-triazine rings not condensed with other rings having three double bonds between ring members or between ring members and non-ring members
- C07D251/14—Heterocyclic compounds containing 1,3,5-triazine rings not condensed with other rings having three double bonds between ring members or between ring members and non-ring members with hydrogen or carbon atoms directly attached to at least one ring carbon atom
- C07D251/24—Heterocyclic compounds containing 1,3,5-triazine rings not condensed with other rings having three double bonds between ring members or between ring members and non-ring members with hydrogen or carbon atoms directly attached to at least one ring carbon atom to three ring carbon atoms
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Paints Or Removers (AREA)
- Anti-Oxidant Or Stabilizer Compositions (AREA)
- Plural Heterocyclic Compounds (AREA)
Applications Claiming Priority (5)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CH236899 | 1999-12-23 | ||
| CH236899 | 1999-12-23 | ||
| CH6192000 | 2000-03-31 | ||
| CH6192000 | 2000-03-31 | ||
| PCT/EP2000/012734 WO2001047900A1 (en) | 1999-12-23 | 2000-12-14 | Stabilizer mixture |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| DE60026177D1 DE60026177D1 (de) | 2006-04-27 |
| DE60026177T2 true DE60026177T2 (de) | 2006-08-03 |
Family
ID=25690275
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| DE60026177T Expired - Lifetime DE60026177T2 (de) | 1999-12-23 | 2000-12-14 | Stabilisatormischung |
Country Status (15)
| Country | Link |
|---|---|
| US (1) | US6913712B2 (https=) |
| EP (1) | EP1242391B1 (https=) |
| JP (1) | JP4907823B2 (https=) |
| KR (1) | KR100729944B1 (https=) |
| CN (1) | CN1245393C (https=) |
| AT (1) | ATE318260T1 (https=) |
| AU (1) | AU779668B2 (https=) |
| BR (1) | BRPI0017036B1 (https=) |
| CA (1) | CA2392889A1 (https=) |
| DE (1) | DE60026177T2 (https=) |
| DK (1) | DK1242391T3 (https=) |
| ES (1) | ES2258035T3 (https=) |
| MX (1) | MXPA02006120A (https=) |
| PT (1) | PT1242391E (https=) |
| WO (1) | WO2001047900A1 (https=) |
Families Citing this family (23)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE10051266A1 (de) * | 2000-10-16 | 2002-04-25 | Basf Ag | Verfahren zur Filtration einer Flüssigkeit, mit einem Filterhilfsmittel und Verfahren zu deren Herstellung |
| DE10215147A1 (de) * | 2002-04-05 | 2003-10-16 | Basf Ag | Verwendung von Polymerisation, enthaltend thermoplastische Polymere als Filterhilfs- und/oder Stabilisierungsmittel |
| EP1308084A1 (en) * | 2002-10-02 | 2003-05-07 | Ciba SC Holding AG | Synergistic UV absorber combination |
| AU2003303818A1 (en) * | 2003-01-29 | 2004-08-23 | Ciba Specialty Chemicals Holding Inc. | Ink-jet ink and recording material |
| GB2408516A (en) * | 2003-11-28 | 2005-06-01 | Avecia Ltd | Fibres treated with antimicrobial agents |
| US20050208234A1 (en) * | 2004-03-19 | 2005-09-22 | Agfa-Gevaert | Ink-jet recording material |
| US20070078203A1 (en) * | 2005-10-04 | 2007-04-05 | Gohill Bharatkumar B | Propylene copolymer compositions |
| WO2008065016A1 (en) * | 2006-11-27 | 2008-06-05 | Ciba Holding Inc. | Bitumen or asphalt compositions stabilised against weathering |
| KR101541431B1 (ko) * | 2007-01-15 | 2015-08-03 | 시바 홀딩 인크 | 2-하이드록시 페닐 트리아진에 의해 ｕｖ 안정화된 착색된 투명 피복물 |
| US20080250977A1 (en) * | 2007-04-16 | 2008-10-16 | Andrew Mason | Oxime free anti-skinning combination |
| CN102681077A (zh) * | 2007-06-14 | 2012-09-19 | 株式会社日本触媒 | 偏振板以及使用其的图像显示装置 |
| WO2009112425A1 (en) * | 2008-03-12 | 2009-09-17 | Basf Se | An optical film for a flat panel display |
| JP5300385B2 (ja) * | 2008-09-10 | 2013-09-25 | 株式会社日本触媒 | 熱可塑性樹脂組成物とそれを用いたフィルム |
| JP5230363B2 (ja) * | 2008-11-05 | 2013-07-10 | 株式会社日本触媒 | 熱可塑性樹脂組成物の製造方法 |
| ES2463674T3 (es) | 2009-01-19 | 2014-05-28 | Basf Se | Pigmentos negros orgánicos y su preparación |
| JP5525183B2 (ja) * | 2009-04-22 | 2014-06-18 | 株式会社カネカ | 光学用フィルム |
| JP2012014043A (ja) * | 2010-07-02 | 2012-01-19 | Oji Paper Co Ltd | 光学用粘着剤、光学用粘着シート及び光学フィルタ |
| KR102087442B1 (ko) * | 2012-03-26 | 2020-03-10 | 스미또모 가가꾸 가부시키가이샤 | 혼합물 및 그 제조 방법 |
| US9267038B2 (en) | 2014-01-07 | 2016-02-23 | Honeywell International Inc. | Asphalt binder compositions and methods to make and use same |
| KR102467553B1 (ko) * | 2015-12-14 | 2022-11-17 | 현대모비스 주식회사 | 리얼우드 필름, 이의 제조방법 및 이를 포함하는 성형품 |
| KR102096511B1 (ko) | 2017-12-29 | 2020-04-02 | 주식회사 엘엠에스 | 2종 이상의 염료를 포함하는 점착 조성물, 점착 시트, 및 이를 포함하는 디스플레이 장치 |
| CN113201017B (zh) * | 2021-04-29 | 2022-07-01 | 宁波中苑颜料有限公司 | 一种基于三嗪衍生物的有机颜料分散剂及其制备方法 |
| JPWO2023238958A1 (https=) * | 2022-06-10 | 2023-12-14 |
Family Cites Families (21)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| NL275368A (https=) | 1961-03-06 | |||
| US3113940A (en) * | 1961-07-13 | 1963-12-10 | Monsanto Res Corp | Aromatic partial ethers of tris (2-hydroxyphenyl) triazine |
| US3113941A (en) * | 1961-07-13 | 1963-12-10 | Monsanto Res Corp | Esters of hydroxyaryltriazines |
| US3113942A (en) * | 1961-07-13 | 1963-12-10 | Monsanto Res Corp | Mono-alkyl ethers of tris (2-hydroxyphenyl) triazines |
| CH484695A (de) * | 1962-10-30 | 1970-01-31 | Ciba Geigy | Verwendung von neuen Hydroxyphenyl-1,3,5-triazinen als Ultraviolettschutzmittel ausserhalb der Textilindustrie |
| BE639330A (https=) * | 1962-10-30 | |||
| NL130993C (https=) * | 1963-02-07 | |||
| CH469053A (de) * | 1963-07-26 | 1969-02-28 | Ciba Geigy | Verwendung von neuen Hydroxyphenyl-1,3,5-triazinen als Schutzmittel gegen Ultraviolettstrahlung für nichttextile organische Materialien |
| ATE151097T1 (de) | 1989-12-05 | 1997-04-15 | Ciba Geigy | Stabilisiertes organisches material |
| DK0444323T3 (da) | 1990-02-28 | 1997-04-07 | Cytec Tech Corp | Stabilisering af overtræk med højt faststofindhold med flydende sammensætninger af triazin-UV-absorptionsmidler |
| EP0531258B1 (de) * | 1991-09-05 | 1997-09-10 | Ciba SC Holding AG | UV-Absorber enthaltendes photographisches Material |
| DE4340725B4 (de) | 1992-12-03 | 2005-11-24 | Ciba Speciality Chemicals Holding Inc. | UV-Absorber |
| TW308601B (https=) * | 1995-01-18 | 1997-06-21 | Ciba Sc Holding Ag | |
| WO1997003642A1 (en) * | 1995-07-22 | 1997-02-06 | Ciba Specialty Chemicals Holding Inc. | Sunscreen compositions |
| DE59710714D1 (de) * | 1996-08-23 | 2003-10-16 | Ciba Sc Holding Ag | Verwendung von ausgewählten Benzotriazol- und Triazinderivaten zum Schützen von menschlichem Haar vor der schädigenden Einwirkung von UV-Strahlung |
| BE1012529A3 (fr) * | 1996-09-13 | 2000-12-05 | Ciba Sc Holding Ag | Melange de triaryltriazines et son utilisation pour la stabilisation de materiaux organiques. |
| GB2319523B (en) | 1996-11-20 | 2000-11-08 | Ciba Sc Holding Ag | Hydroxyphenyltriazines |
| US6090370A (en) * | 1997-06-27 | 2000-07-18 | Ciba Specialty Chemicals Corporation | Use of selected benzotriazole and triazine derivatives for protecting human hair from the harmful effects of UV radiation |
| KR100548980B1 (ko) * | 1997-08-20 | 2006-02-03 | 시바 스페셜티 케미칼스 홀딩 인크. | 비스(레조르시닐)트리아진 유도체를 포함하는 화장품 제형 |
| US6117997A (en) * | 1997-11-19 | 2000-09-12 | Ciba Specialty Chemicals Corporation | Hydroxyphenyltriazines |
| JP2000026435A (ja) * | 1998-05-07 | 2000-01-25 | Ciba Specialty Chem Holding Inc | トリスレゾリシニルトリアジン |
-
2000
- 2000-12-14 ES ES00991600T patent/ES2258035T3/es not_active Expired - Lifetime
- 2000-12-14 AT AT00991600T patent/ATE318260T1/de not_active IP Right Cessation
- 2000-12-14 MX MXPA02006120A patent/MXPA02006120A/es active IP Right Grant
- 2000-12-14 CA CA002392889A patent/CA2392889A1/en not_active Abandoned
- 2000-12-14 CN CNB008176914A patent/CN1245393C/zh not_active Expired - Lifetime
- 2000-12-14 BR BRPI0017036A patent/BRPI0017036B1/pt not_active IP Right Cessation
- 2000-12-14 EP EP00991600A patent/EP1242391B1/en not_active Expired - Lifetime
- 2000-12-14 US US10/168,219 patent/US6913712B2/en not_active Expired - Lifetime
- 2000-12-14 PT PT00991600T patent/PT1242391E/pt unknown
- 2000-12-14 DE DE60026177T patent/DE60026177T2/de not_active Expired - Lifetime
- 2000-12-14 KR KR1020027008092A patent/KR100729944B1/ko not_active Expired - Fee Related
- 2000-12-14 WO PCT/EP2000/012734 patent/WO2001047900A1/en not_active Ceased
- 2000-12-14 DK DK00991600T patent/DK1242391T3/da active
- 2000-12-14 AU AU33639/01A patent/AU779668B2/en not_active Ceased
- 2000-12-14 JP JP2001549372A patent/JP4907823B2/ja not_active Expired - Fee Related
Also Published As
| Publication number | Publication date |
|---|---|
| CN1245393C (zh) | 2006-03-15 |
| KR20020089312A (ko) | 2002-11-29 |
| JP4907823B2 (ja) | 2012-04-04 |
| CN1413199A (zh) | 2003-04-23 |
| DE60026177D1 (de) | 2006-04-27 |
| ES2258035T3 (es) | 2006-08-16 |
| JP2003519132A (ja) | 2003-06-17 |
| DK1242391T3 (da) | 2006-04-24 |
| EP1242391B1 (en) | 2006-02-22 |
| KR100729944B1 (ko) | 2007-06-20 |
| ATE318260T1 (de) | 2006-03-15 |
| MXPA02006120A (es) | 2002-12-05 |
| BRPI0017036B1 (pt) | 2016-09-27 |
| BR0017036A (pt) | 2003-01-07 |
| WO2001047900A1 (en) | 2001-07-05 |
| US6913712B2 (en) | 2005-07-05 |
| AU3363901A (en) | 2001-07-09 |
| AU779668B2 (en) | 2005-02-03 |
| EP1242391A1 (en) | 2002-09-25 |
| US20030096993A1 (en) | 2003-05-22 |
| PT1242391E (pt) | 2006-06-30 |
| CA2392889A1 (en) | 2001-07-05 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| 8328 | Change in the person/name/address of the agent |
Representative=s name: PFENNING MEINIG & PARTNER GBR, 80339 MUENCHEN |
|
| 8364 | No opposition during term of opposition | ||
| 8327 | Change in the person/name/address of the patent owner |
Owner name: CIBA HOLDING INC., BASEL, CH |
|
| 8328 | Change in the person/name/address of the agent |
Representative=s name: MAIWALD PATENTANWALTSGESELLSCHAFT MBH, 80335 MUENC |