DE508917C - Verfahren zur Vrbesserung von Brennstoffen und Treibmitteln - Google Patents

Verfahren zur Vrbesserung von Brennstoffen und Treibmitteln

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Publication number
DE508917C
DE508917C DEB119746D DEB0119746D DE508917C DE 508917 C DE508917 C DE 508917C DE B119746 D DEB119746 D DE B119746D DE B0119746 D DEB0119746 D DE B0119746D DE 508917 C DE508917 C DE 508917C
Authority
DE
Germany
Prior art keywords
gasoline
iron carbonyl
propellants
iron
nitrogen
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
DEB119746D
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English (en)
Inventor
Dr Wilhelm Gaus
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
IG Farbenindustrie AG
Original Assignee
IG Farbenindustrie AG
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by IG Farbenindustrie AG filed Critical IG Farbenindustrie AG
Priority to DEB119746D priority Critical patent/DE508917C/de
Application granted granted Critical
Publication of DE508917C publication Critical patent/DE508917C/de
Expired legal-status Critical Current

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Classifications

    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L1/00—Liquid carbonaceous fuels
    • C10L1/10—Liquid carbonaceous fuels containing additives
    • C10L1/103—Liquid carbonaceous fuels containing additives stabilisation of anti-knock agents
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L1/00—Liquid carbonaceous fuels
    • C10L1/10—Liquid carbonaceous fuels containing additives
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L1/00—Liquid carbonaceous fuels
    • C10L1/10—Liquid carbonaceous fuels containing additives
    • C10L1/12—Inorganic compounds
    • C10L1/1233—Inorganic compounds oxygen containing compounds, e.g. oxides, hydroxides, acids and salts thereof
    • C10L1/1241—Inorganic compounds oxygen containing compounds, e.g. oxides, hydroxides, acids and salts thereof metal carbonyls
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L1/00—Liquid carbonaceous fuels
    • C10L1/10—Liquid carbonaceous fuels containing additives
    • C10L1/14—Organic compounds
    • C10L1/18—Organic compounds containing oxygen
    • C10L1/182—Organic compounds containing oxygen containing hydroxy groups; Salts thereof
    • C10L1/1822—Organic compounds containing oxygen containing hydroxy groups; Salts thereof hydroxy group directly attached to (cyclo)aliphatic carbon atoms
    • C10L1/1824—Organic compounds containing oxygen containing hydroxy groups; Salts thereof hydroxy group directly attached to (cyclo)aliphatic carbon atoms mono-hydroxy
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L1/00—Liquid carbonaceous fuels
    • C10L1/10—Liquid carbonaceous fuels containing additives
    • C10L1/14—Organic compounds
    • C10L1/18—Organic compounds containing oxygen
    • C10L1/185—Ethers; Acetals; Ketals; Aldehydes; Ketones
    • C10L1/1857—Aldehydes; Ketones
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L1/00—Liquid carbonaceous fuels
    • C10L1/10—Liquid carbonaceous fuels containing additives
    • C10L1/14—Organic compounds
    • C10L1/18—Organic compounds containing oxygen
    • C10L1/19—Esters ester radical containing compounds; ester ethers; carbonic acid esters
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L1/00—Liquid carbonaceous fuels
    • C10L1/10—Liquid carbonaceous fuels containing additives
    • C10L1/14—Organic compounds
    • C10L1/22—Organic compounds containing nitrogen
    • C10L1/222—Organic compounds containing nitrogen containing at least one carbon-to-nitrogen single bond
    • C10L1/2222—(cyclo)aliphatic amines; polyamines (no macromolecular substituent 30C); quaternair ammonium compounds; carbamates
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L1/00—Liquid carbonaceous fuels
    • C10L1/10—Liquid carbonaceous fuels containing additives
    • C10L1/14—Organic compounds
    • C10L1/22—Organic compounds containing nitrogen
    • C10L1/222—Organic compounds containing nitrogen containing at least one carbon-to-nitrogen single bond
    • C10L1/223—Organic compounds containing nitrogen containing at least one carbon-to-nitrogen single bond having at least one amino group bound to an aromatic carbon atom
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L1/00—Liquid carbonaceous fuels
    • C10L1/10—Liquid carbonaceous fuels containing additives
    • C10L1/14—Organic compounds
    • C10L1/22—Organic compounds containing nitrogen
    • C10L1/23—Organic compounds containing nitrogen containing at least one nitrogen-to-oxygen bond, e.g. nitro-compounds, nitrates, nitrites
    • C10L1/231—Organic compounds containing nitrogen containing at least one nitrogen-to-oxygen bond, e.g. nitro-compounds, nitrates, nitrites nitro compounds; nitrates; nitrites
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L1/00—Liquid carbonaceous fuels
    • C10L1/10—Liquid carbonaceous fuels containing additives
    • C10L1/14—Organic compounds
    • C10L1/28—Organic compounds containing silicon
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L1/00—Liquid carbonaceous fuels
    • C10L1/10—Liquid carbonaceous fuels containing additives
    • C10L1/14—Organic compounds
    • C10L1/30—Organic compounds compounds not mentioned before (complexes)
    • C10L1/301—Organic compounds compounds not mentioned before (complexes) derived from metals
    • C10L1/303—Organic compounds compounds not mentioned before (complexes) derived from metals boron compounds

Landscapes

  • Chemical & Material Sciences (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Solid Fuels And Fuel-Associated Substances (AREA)

Description

Das Hauptpatent 448 620 betrifft ein Verfahren zur Darstellung von verbesserten Brennstoffen, bestehend in dem Zusatz von Eisencarbonyl zu flüssigen Brennstoffen.
Es wurde nun gefunden, daß Benzin und benzinartige Kohlenwasserstoffe (Gasolin u. dgl.), die einen Zusatz von Eisencarbonyl gemäß Hauptpatent erhalten haben, vielfach noch weiter verbessert werden können, indem man außerdem das Klopfen vermindernde lösliche sauerstoff- oder stickstoffhaltige organische Verbindungen zufügt, mit Ausnahme solcher sauerstoff- oder stickstoffhaltiger Verbindungen, welche gleichzeitig Halogen enthalten. Die zur Vermeidung des Klopfens bei der Verwendung als Motortreibstoff erforderliche Menge Eisencarbonyl kann hierdurch verringert werden. Auch die Ablagerung von Eisenoxyd wird unverhältnismäßig stark verringert.
Beispiel 1
97 Volumen Gasolin, 0,10 Volumen Eisencarbonyl, 3 Volumen Methanol (wasserfrei).
Statt Methanol kann man andere Alkohole, wie z. B. Isobutylalkohol, oder andere sauerstoffhaltige Verbindungen, wie Aldehyde, z. B. Isobutylaldehyd, Ketone oder Ester, z. B. Methylformiat, oder stickstoffhaltige Verbindungen, z. B. Anilin, Butylamin, Benzylanilin, oder Nitroverbindungen, z. B. Nitrobenzol, verwenden. Gleichzeitig können die im Patent 491 431 vorgesehenen Zusätze oder andere in dem Brennstoff lösliche Verbindungen von Metallen oder metallähnlichen Elementen erfolgen.
Als weitere Beispiele seien angeführt:
Gasolin + 0,1 % Eisencarbonyl + 1 % Monomethylanilin
Gasolin + 0,15 % Eisencarbonyl + 10 % Aceton
Gasolin + 0,15 % Eisencarbonyl + 10 % Aceton + 0,15 % Borsäureäthylester
Gasolin + 0,15 % Eisencarbonyl + 10 % Methyläthylketon
Gasolin + 0,15 % Eisencarbonyl + 10 % Methyläthylketon + 0,02 % Chloroform
Gasolin + 0,15 % Eisencarbonyl + 5 % Cyclohexanon
Gasolin + 0,15 % Eisencarbonyl + 5 % Cyclohexanon + 0,02 % Siliciumtetraäthyl
Gasolin + 0,2 % Eisencarbonyl + 1 % Chinon
Gasolin + 0,2 % Eisencarbonyl + 1 % Chinon + 0,01 % Fe-Acetessigester
Gasolin + 0,15 % Eisencarbonyl + 10 % Acetaldehyd
Gasolin + 0,15 % Eisencarbonyl + 10 % Acetaldehyd + 0,015 % Äthylenchlorid + 0,2 % Borsäuremethylester
Gasolin + 0,10 % Eisencarbonyl + 10 % Benzaldehyd
Gasolin + 0,10 % Eisencarbonyl + 3 % Anilin
Gasolin + 0,10 % Eisencarbonyl + 3 % Anilin + 0,02 % Chlorbenzol
Gasolin + 0,10 % Eisencarbonyl + 3 % Anilin + 0,01 % Methylammoniumchlorid + 0,15 % Zinkoleat
Gasolin + 0,10 % Eisencarbonyl + 5 % Toluidin
Gasolin + 0,10 % Eisencarbonyl + 5 % Toluidin + 0,2 % Berylliumpropionat
Gasolin + 0,15 % Eisencarbonyl + 3 % Isobutylamin
Gasolin + 0,15 % Eisencarbonyl + 3 % Isobutylamin + 0,01 % Chlorbenzol
Gasolin + 0,1 % Eisencarbonyl + 3 % Methylxylidin
Gasolin + 0,1 % Eisencarbonyl + 2 % Äthylanilin
Gasolin + 0,1 % Eisencarbonyl + 2 % Äthylanilin + 0,1 % Calciumnaphthenat
Gasolin + 0,2 % Eisencarbonyl + 2 % Nitrotoluol.

Claims (1)

  1. Verfahren zur Verbesserung von Brennstoffen und Treibmitteln gemäß Patent 448 620, dadurch gekennzeichnet, daß dem Benzin neben Eisencarbonyl noch das Klopfen verhindernde lösliche sauerstoff- oder stickstoffhaltige organische Verbindungen zugesetzt werden mit Ausnahme solcher sauerstoff- oder stickstoffhaltigen Verbindungen, welche gleichzeitig Halogen enthalten.
DEB119746D 1925-05-09 1925-05-09 Verfahren zur Vrbesserung von Brennstoffen und Treibmitteln Expired DE508917C (de)

Priority Applications (1)

Application Number Priority Date Filing Date Title
DEB119746D DE508917C (de) 1925-05-09 1925-05-09 Verfahren zur Vrbesserung von Brennstoffen und Treibmitteln

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
DEB119746D DE508917C (de) 1925-05-09 1925-05-09 Verfahren zur Vrbesserung von Brennstoffen und Treibmitteln

Publications (1)

Publication Number Publication Date
DE508917C true DE508917C (de) 1933-07-17

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ID=6995117

Family Applications (1)

Application Number Title Priority Date Filing Date
DEB119746D Expired DE508917C (de) 1925-05-09 1925-05-09 Verfahren zur Vrbesserung von Brennstoffen und Treibmitteln

Country Status (1)

Country Link
DE (1) DE508917C (de)

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE886972C (de) * 1950-02-01 1953-08-20 Basf Ag Motortreibstoff
WO1998026028A1 (en) * 1996-12-09 1998-06-18 Orr William C Fuel compositions exhibiting improved fuel stability
EP2231550B1 (de) * 2007-12-05 2012-05-23 W. R. Grace & Co.-Conn Chromreduzierende übergangsmetallcarbonyle

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE886972C (de) * 1950-02-01 1953-08-20 Basf Ag Motortreibstoff
WO1998026028A1 (en) * 1996-12-09 1998-06-18 Orr William C Fuel compositions exhibiting improved fuel stability
EP2231550B1 (de) * 2007-12-05 2012-05-23 W. R. Grace & Co.-Conn Chromreduzierende übergangsmetallcarbonyle

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