DE4304062A1 - Verfahren zur Herstellung von Tensidgranulaten - Google Patents
Verfahren zur Herstellung von TensidgranulatenInfo
- Publication number
- DE4304062A1 DE4304062A1 DE4304062A DE4304062A DE4304062A1 DE 4304062 A1 DE4304062 A1 DE 4304062A1 DE 4304062 A DE4304062 A DE 4304062A DE 4304062 A DE4304062 A DE 4304062A DE 4304062 A1 DE4304062 A1 DE 4304062A1
- Authority
- DE
- Germany
- Prior art keywords
- surfactant
- granules
- acid
- acid form
- weight
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Ceased
Links
- 239000004094 surface-active agent Substances 0.000 title claims abstract description 72
- 239000008187 granular material Substances 0.000 title claims abstract description 48
- 238000002360 preparation method Methods 0.000 title claims abstract description 30
- 238000000034 method Methods 0.000 title claims description 49
- 239000002253 acid Substances 0.000 claims abstract description 40
- 239000007787 solid Substances 0.000 claims abstract description 30
- 239000003945 anionic surfactant Substances 0.000 claims abstract description 28
- 238000001035 drying Methods 0.000 claims abstract description 25
- 239000000203 mixture Substances 0.000 claims abstract description 21
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 19
- 239000007788 liquid Substances 0.000 claims abstract description 17
- 238000005469 granulation Methods 0.000 claims abstract description 15
- 230000003179 granulation Effects 0.000 claims abstract description 15
- 239000003380 propellant Substances 0.000 claims abstract description 8
- 239000012670 alkaline solution Substances 0.000 claims abstract description 6
- 239000002245 particle Substances 0.000 claims description 14
- 239000000376 reactant Substances 0.000 claims description 12
- 239000003599 detergent Substances 0.000 claims description 10
- 150000002191 fatty alcohols Chemical class 0.000 claims description 10
- 150000007513 acids Chemical class 0.000 claims description 9
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 claims description 8
- 239000007844 bleaching agent Substances 0.000 claims description 8
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 claims description 6
- 239000002585 base Substances 0.000 claims description 6
- KRKNYBCHXYNGOX-UHFFFAOYSA-N citric acid Chemical class OC(=O)CC(O)(C(O)=O)CC(O)=O KRKNYBCHXYNGOX-UHFFFAOYSA-N 0.000 claims description 6
- 235000014113 dietary fatty acids Nutrition 0.000 claims description 6
- 239000000194 fatty acid Substances 0.000 claims description 6
- 229930195729 fatty acid Natural products 0.000 claims description 6
- 229920001223 polyethylene glycol Polymers 0.000 claims description 6
- 238000005406 washing Methods 0.000 claims description 6
- 229910021536 Zeolite Inorganic materials 0.000 claims description 5
- 230000002378 acidificating effect Effects 0.000 claims description 5
- 239000003513 alkali Substances 0.000 claims description 5
- HNPSIPDUKPIQMN-UHFFFAOYSA-N dioxosilane;oxo(oxoalumanyloxy)alumane Chemical compound O=[Si]=O.O=[Al]O[Al]=O HNPSIPDUKPIQMN-UHFFFAOYSA-N 0.000 claims description 5
- 150000002148 esters Chemical class 0.000 claims description 5
- 150000004665 fatty acids Chemical class 0.000 claims description 5
- 239000004615 ingredient Substances 0.000 claims description 5
- 239000010457 zeolite Substances 0.000 claims description 5
- 150000004649 carbonic acid derivatives Chemical class 0.000 claims description 4
- 229910052757 nitrogen Inorganic materials 0.000 claims description 3
- 239000012190 activator Substances 0.000 claims description 2
- 229910052910 alkali metal silicate Inorganic materials 0.000 claims description 2
- 239000002280 amphoteric surfactant Substances 0.000 claims description 2
- 239000003093 cationic surfactant Substances 0.000 claims description 2
- 125000000864 peroxy group Chemical group O(O*)* 0.000 claims description 2
- 150000003839 salts Chemical class 0.000 claims description 2
- 150000004760 silicates Chemical class 0.000 claims description 2
- 239000002689 soil Substances 0.000 claims description 2
- 150000003467 sulfuric acid derivatives Chemical class 0.000 claims description 2
- ULUAUXLGCMPNKK-UHFFFAOYSA-N Sulfobutanedioic acid Chemical compound OC(=O)CC(C(O)=O)S(O)(=O)=O ULUAUXLGCMPNKK-UHFFFAOYSA-N 0.000 claims 1
- 239000003570 air Substances 0.000 claims 1
- 150000001450 anions Chemical class 0.000 claims 1
- 239000004744 fabric Substances 0.000 claims 1
- 239000002563 ionic surfactant Substances 0.000 claims 1
- 238000004519 manufacturing process Methods 0.000 abstract description 9
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 12
- -1 fatty alcohol sulfate Chemical class 0.000 description 9
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 8
- 238000009826 distribution Methods 0.000 description 7
- 238000006386 neutralization reaction Methods 0.000 description 7
- IAYPIBMASNFSPL-UHFFFAOYSA-N Ethylene oxide Chemical compound C1CO1 IAYPIBMASNFSPL-UHFFFAOYSA-N 0.000 description 6
- 239000000654 additive Substances 0.000 description 6
- 150000001298 alcohols Chemical class 0.000 description 6
- 239000006260 foam Substances 0.000 description 6
- 239000003112 inhibitor Substances 0.000 description 6
- 239000000126 substance Substances 0.000 description 6
- 125000004432 carbon atom Chemical group C* 0.000 description 5
- 239000012459 cleaning agent Substances 0.000 description 5
- 235000011837 pasties Nutrition 0.000 description 5
- 239000000047 product Substances 0.000 description 5
- 239000003760 tallow Substances 0.000 description 5
- MHAJPDPJQMAIIY-UHFFFAOYSA-N Hydrogen peroxide Chemical compound OO MHAJPDPJQMAIIY-UHFFFAOYSA-N 0.000 description 4
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 4
- CDBYLPFSWZWCQE-UHFFFAOYSA-L Sodium Carbonate Chemical compound [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 description 4
- 238000004140 cleaning Methods 0.000 description 4
- 239000000470 constituent Substances 0.000 description 4
- 239000000463 material Substances 0.000 description 4
- 239000000243 solution Substances 0.000 description 4
- 235000013162 Cocos nucifera Nutrition 0.000 description 3
- 244000060011 Cocos nucifera Species 0.000 description 3
- 239000004435 Oxo alcohol Substances 0.000 description 3
- 150000001875 compounds Chemical class 0.000 description 3
- 239000000975 dye Substances 0.000 description 3
- 239000002736 nonionic surfactant Substances 0.000 description 3
- 239000007921 spray Substances 0.000 description 3
- 238000001694 spray drying Methods 0.000 description 3
- JSPLKZUTYZBBKA-UHFFFAOYSA-N trioxidane Chemical group OOO JSPLKZUTYZBBKA-UHFFFAOYSA-N 0.000 description 3
- ALSTYHKOOCGGFT-KTKRTIGZSA-N (9Z)-octadecen-1-ol Chemical compound CCCCCCCC\C=C/CCCCCCCCO ALSTYHKOOCGGFT-KTKRTIGZSA-N 0.000 description 2
- 238000006243 chemical reaction Methods 0.000 description 2
- 239000013065 commercial product Substances 0.000 description 2
- 238000005265 energy consumption Methods 0.000 description 2
- 235000019387 fatty acid methyl ester Nutrition 0.000 description 2
- 238000009472 formulation Methods 0.000 description 2
- 239000007789 gas Substances 0.000 description 2
- 238000000227 grinding Methods 0.000 description 2
- GLDOVTGHNKAZLK-UHFFFAOYSA-N octadecan-1-ol Chemical compound CCCCCCCCCCCCCCCCCCO GLDOVTGHNKAZLK-UHFFFAOYSA-N 0.000 description 2
- 229940055577 oleyl alcohol Drugs 0.000 description 2
- XMLQWXUVTXCDDL-UHFFFAOYSA-N oleyl alcohol Natural products CCCCCCC=CCCCCCCCCCCO XMLQWXUVTXCDDL-UHFFFAOYSA-N 0.000 description 2
- 229920001296 polysiloxane Polymers 0.000 description 2
- 150000003138 primary alcohols Chemical class 0.000 description 2
- 238000007127 saponification reaction Methods 0.000 description 2
- 239000000377 silicon dioxide Substances 0.000 description 2
- 238000005507 spraying Methods 0.000 description 2
- KDYFGRWQOYBRFD-UHFFFAOYSA-N succinic acid Chemical compound OC(=O)CCC(O)=O KDYFGRWQOYBRFD-UHFFFAOYSA-N 0.000 description 2
- 150000003470 sulfuric acid monoesters Chemical class 0.000 description 2
- 239000001993 wax Substances 0.000 description 2
- HLZKNKRTKFSKGZ-UHFFFAOYSA-N 1-Tetradecanol Natural products CCCCCCCCCCCCCCO HLZKNKRTKFSKGZ-UHFFFAOYSA-N 0.000 description 1
- WBIQQQGBSDOWNP-UHFFFAOYSA-N 2-dodecylbenzenesulfonic acid Chemical compound CCCCCCCCCCCCC1=CC=CC=C1S(O)(=O)=O WBIQQQGBSDOWNP-UHFFFAOYSA-N 0.000 description 1
- XSVSPKKXQGNHMD-UHFFFAOYSA-N 5-bromo-3-methyl-1,2-thiazole Chemical compound CC=1C=C(Br)SN=1 XSVSPKKXQGNHMD-UHFFFAOYSA-N 0.000 description 1
- LSNNMFCWUKXFEE-UHFFFAOYSA-M Bisulfite Chemical compound OS([O-])=O LSNNMFCWUKXFEE-UHFFFAOYSA-M 0.000 description 1
- KRKNYBCHXYNGOX-UHFFFAOYSA-K Citrate Chemical compound [O-]C(=O)CC(O)(CC([O-])=O)C([O-])=O KRKNYBCHXYNGOX-UHFFFAOYSA-K 0.000 description 1
- 241000196324 Embryophyta Species 0.000 description 1
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 1
- 239000004165 Methyl ester of fatty acids Substances 0.000 description 1
- ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 description 1
- KWYUFKZDYYNOTN-UHFFFAOYSA-M Potassium hydroxide Chemical compound [OH-].[K+] KWYUFKZDYYNOTN-UHFFFAOYSA-M 0.000 description 1
- 101150107341 RERE gene Proteins 0.000 description 1
- 230000000996 additive effect Effects 0.000 description 1
- 150000001335 aliphatic alkanes Chemical class 0.000 description 1
- 150000003973 alkyl amines Chemical class 0.000 description 1
- 239000007864 aqueous solution Substances 0.000 description 1
- 244000052616 bacterial pathogen Species 0.000 description 1
- 150000001735 carboxylic acids Chemical class 0.000 description 1
- 229960000541 cetyl alcohol Drugs 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- 239000003086 colorant Substances 0.000 description 1
- 238000007257 deesterification reaction Methods 0.000 description 1
- 230000001419 dependent effect Effects 0.000 description 1
- 238000010790 dilution Methods 0.000 description 1
- 239000012895 dilution Substances 0.000 description 1
- 125000003438 dodecyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 description 1
- 229940060296 dodecylbenzenesulfonic acid Drugs 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 230000002708 enhancing effect Effects 0.000 description 1
- 125000004185 ester group Chemical group 0.000 description 1
- 238000007046 ethoxylation reaction Methods 0.000 description 1
- 239000010419 fine particle Substances 0.000 description 1
- 239000012530 fluid Substances 0.000 description 1
- 229930182470 glycoside Natural products 0.000 description 1
- 150000004679 hydroxides Chemical class 0.000 description 1
- WQYVRQLZKVEZGA-UHFFFAOYSA-N hypochlorite Chemical class Cl[O-] WQYVRQLZKVEZGA-UHFFFAOYSA-N 0.000 description 1
- 238000010348 incorporation Methods 0.000 description 1
- 239000011261 inert gas Substances 0.000 description 1
- CDAISMWEOUEBRE-GPIVLXJGSA-N inositol Chemical compound O[C@H]1[C@H](O)[C@@H](O)[C@H](O)[C@H](O)[C@@H]1O CDAISMWEOUEBRE-GPIVLXJGSA-N 0.000 description 1
- 238000005259 measurement Methods 0.000 description 1
- 238000002844 melting Methods 0.000 description 1
- 230000008018 melting Effects 0.000 description 1
- 150000004702 methyl esters Chemical class 0.000 description 1
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 1
- 239000004200 microcrystalline wax Substances 0.000 description 1
- 235000019808 microcrystalline wax Nutrition 0.000 description 1
- 239000011259 mixed solution Substances 0.000 description 1
- 229940043348 myristyl alcohol Drugs 0.000 description 1
- 125000001421 myristyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- GOQYKNQRPGWPLP-UHFFFAOYSA-N n-heptadecyl alcohol Natural products CCCCCCCCCCCCCCCCCO GOQYKNQRPGWPLP-UHFFFAOYSA-N 0.000 description 1
- BXWNKGSJHAJOGX-UHFFFAOYSA-N n-hexadecyl alcohol Natural products CCCCCCCCCCCCCCCCO BXWNKGSJHAJOGX-UHFFFAOYSA-N 0.000 description 1
- SXLLDUPXUVRMEE-UHFFFAOYSA-N nonanediperoxoic acid Chemical compound OOC(=O)CCCCCCCC(=O)OO SXLLDUPXUVRMEE-UHFFFAOYSA-N 0.000 description 1
- 238000006384 oligomerization reaction Methods 0.000 description 1
- 229920000620 organic polymer Polymers 0.000 description 1
- MMCOUVMKNAHQOY-UHFFFAOYSA-L oxido carbonate Chemical compound [O-]OC([O-])=O MMCOUVMKNAHQOY-UHFFFAOYSA-L 0.000 description 1
- 125000000913 palmityl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- 239000000049 pigment Substances 0.000 description 1
- 229910052700 potassium Inorganic materials 0.000 description 1
- 239000011591 potassium Substances 0.000 description 1
- 239000000843 powder Substances 0.000 description 1
- 239000011541 reaction mixture Substances 0.000 description 1
- 230000001105 regulatory effect Effects 0.000 description 1
- 230000000717 retained effect Effects 0.000 description 1
- 238000012216 screening Methods 0.000 description 1
- 150000003333 secondary alcohols Chemical class 0.000 description 1
- 239000000344 soap Substances 0.000 description 1
- 229910052708 sodium Inorganic materials 0.000 description 1
- 239000011734 sodium Substances 0.000 description 1
- 229910000029 sodium carbonate Inorganic materials 0.000 description 1
- 239000012418 sodium perborate tetrahydrate Substances 0.000 description 1
- IBDSNZLUHYKHQP-UHFFFAOYSA-N sodium;3-oxidodioxaborirane;tetrahydrate Chemical compound O.O.O.O.[Na+].[O-]B1OO1 IBDSNZLUHYKHQP-UHFFFAOYSA-N 0.000 description 1
- 239000012265 solid product Substances 0.000 description 1
- 239000007858 starting material Substances 0.000 description 1
- 229940012831 stearyl alcohol Drugs 0.000 description 1
- 239000001384 succinic acid Substances 0.000 description 1
- 238000006277 sulfonation reaction Methods 0.000 description 1
- 150000003460 sulfonic acids Chemical class 0.000 description 1
- 229910052715 tantalum Inorganic materials 0.000 description 1
- GUVRBAGPIYLISA-UHFFFAOYSA-N tantalum atom Chemical compound [Ta] GUVRBAGPIYLISA-UHFFFAOYSA-N 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D11/00—Special methods for preparing compositions containing mixtures of detergents
- C11D11/0082—Special methods for preparing compositions containing mixtures of detergents one or more of the detergent ingredients being in a liquefied state, e.g. slurry, paste or melt, and the process resulting in solid detergent particles such as granules, powders or beads
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D17/00—Detergent materials or soaps characterised by their shape or physical properties
- C11D17/06—Powder; Flakes; Free-flowing mixtures; Sheets
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D11/00—Special methods for preparing compositions containing mixtures of detergents
- C11D11/04—Special methods for preparing compositions containing mixtures of detergents by chemical means, e.g. by sulfonating in the presence of other compounding ingredients followed by neutralising
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D17/00—Detergent materials or soaps characterised by their shape or physical properties
- C11D17/06—Powder; Flakes; Free-flowing mixtures; Sheets
- C11D17/065—High-density particulate detergent compositions
Landscapes
- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Detergent Compositions (AREA)
- Compounds Of Unknown Constitution (AREA)
- Glanulating (AREA)
Priority Applications (10)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DE4304062A DE4304062A1 (de) | 1993-02-11 | 1993-02-11 | Verfahren zur Herstellung von Tensidgranulaten |
| AT94906207T ATE152477T1 (de) | 1993-02-11 | 1994-02-02 | Verfahren zur herstellung von tensidgranulaten |
| EP94906207A EP0683814B1 (de) | 1993-02-11 | 1994-02-02 | Verfahren zur herstellung von tensidgranulaten |
| KR1019950703269A KR100297272B1 (ko) | 1993-02-11 | 1994-02-02 | 계면활성제과립의제조방법 |
| PCT/EP1994/000301 WO1994018303A1 (de) | 1993-02-11 | 1994-02-02 | Verfahren zur herstellung von tensidgranulaten |
| DE59402608T DE59402608D1 (de) | 1993-02-11 | 1994-02-02 | Verfahren zur herstellung von tensidgranulaten |
| JP6517628A JPH08506368A (ja) | 1993-02-11 | 1994-02-02 | 界面活性剤顆粒の製造方法 |
| ES94906207T ES2101507T3 (es) | 1993-02-11 | 1994-02-02 | Procedimiento para la obtencion de granulados tensioactivos. |
| MYPI94000305A MY110838A (en) | 1993-02-11 | 1994-02-09 | A process for the production of surfactant granules |
| US08/763,923 US5739097A (en) | 1993-02-11 | 1996-12-12 | Process for the production of surfactant granules |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DE4304062A DE4304062A1 (de) | 1993-02-11 | 1993-02-11 | Verfahren zur Herstellung von Tensidgranulaten |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| DE4304062A1 true DE4304062A1 (de) | 1994-08-18 |
Family
ID=6480201
Family Applications (2)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| DE4304062A Ceased DE4304062A1 (de) | 1993-02-11 | 1993-02-11 | Verfahren zur Herstellung von Tensidgranulaten |
| DE59402608T Expired - Fee Related DE59402608D1 (de) | 1993-02-11 | 1994-02-02 | Verfahren zur herstellung von tensidgranulaten |
Family Applications After (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| DE59402608T Expired - Fee Related DE59402608D1 (de) | 1993-02-11 | 1994-02-02 | Verfahren zur herstellung von tensidgranulaten |
Country Status (8)
| Country | Link |
|---|---|
| EP (1) | EP0683814B1 (ja) |
| JP (1) | JPH08506368A (ja) |
| KR (1) | KR100297272B1 (ja) |
| AT (1) | ATE152477T1 (ja) |
| DE (2) | DE4304062A1 (ja) |
| ES (1) | ES2101507T3 (ja) |
| MY (1) | MY110838A (ja) |
| WO (1) | WO1994018303A1 (ja) |
Cited By (11)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO1996003488A1 (de) * | 1994-07-25 | 1996-02-08 | Henkel Kommanditgesellschaft Auf Aktien | Verfahren zur herstellung von tensidgranulaten |
| WO1996017922A1 (de) * | 1994-12-08 | 1996-06-13 | Henkel Kommanditgesellschaft Auf Aktien | Feste, rieselfähige zubereitungen |
| WO1998058047A1 (en) * | 1997-06-16 | 1998-12-23 | Unilever Plc | Production of detergent granulates |
| WO2000018871A1 (de) * | 1998-09-29 | 2000-04-06 | Henkel Kommanditgesellschaft Auf Aktien | Granulationsverfahren |
| WO2000018872A1 (de) * | 1998-09-29 | 2000-04-06 | Henkel Kommanditgesellschaft Auf Aktien | Granulationsverfahren |
| US6056905A (en) * | 1997-06-16 | 2000-05-02 | Lever Brothers Company Division Of Conopco, Inc. | Production of detergent granulates |
| WO2000027961A1 (de) * | 1998-11-09 | 2000-05-18 | Henkel Kommanditgesellschaft Auf Aktien | Tensid-granulate durch wirbelschichtgranulation |
| WO2000031230A1 (de) * | 1998-11-23 | 2000-06-02 | Cognis Deutschland Gmbh | Verfahren zur herstellung von tensidgranulaten |
| WO2000053713A1 (de) * | 1999-03-11 | 2000-09-14 | Henkel Kommanditgesellschaft Auf Aktien | Granulationsverfahren |
| US6133223A (en) * | 1997-06-27 | 2000-10-17 | Lever Brothers Company, Division Of Conopco, Inc. | Production of detergent granulates |
| DE10212169A1 (de) * | 2002-03-19 | 2003-10-02 | Sued Chemie Ag | Waschmittelzusatz mit hohem Gehalt an nichtionischen Tensiden und schnellem Auflösevermögen |
Families Citing this family (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| GB9417354D0 (en) * | 1994-08-26 | 1994-10-19 | Unilever Plc | Detergent particles and process for their production |
| DE19519139A1 (de) * | 1995-05-30 | 1996-12-05 | Henkel Kgaa | Granulares Wasch- oder Reinigungsmittel mit hoher Schüttdichte |
| DE19822941A1 (de) * | 1998-05-22 | 1999-11-25 | Henkel Kgaa | Verfahren zur Herstellung von Wasch- und Reinigungsmitteln |
| DE29905721U1 (de) * | 1999-03-27 | 1999-06-10 | Henkel KGaA, 40589 Düsseldorf | Alkylbenzolsulfonat-Granulate |
| DE10123622A1 (de) * | 2001-05-15 | 2002-11-28 | Henkel Kgaa | Verfahren zur Herstellung von Tensidgranulaten |
| JP5403961B2 (ja) * | 2008-07-14 | 2014-01-29 | 花王株式会社 | 粒状アニオン界面活性剤の製造法 |
Family Cites Families (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4462543A (en) * | 1981-12-24 | 1984-07-31 | The Procter & Gamble Company | Nozzle |
| DE3741401A1 (de) * | 1987-12-07 | 1989-06-15 | Henkel Kgaa | Verfahren zur herstellung von festen oder pastenfoermigen produkten |
| DE4127323A1 (de) * | 1991-08-20 | 1993-02-25 | Henkel Kgaa | Verfahren zur herstellung von tensidgranulaten |
-
1993
- 1993-02-11 DE DE4304062A patent/DE4304062A1/de not_active Ceased
-
1994
- 1994-02-02 DE DE59402608T patent/DE59402608D1/de not_active Expired - Fee Related
- 1994-02-02 ES ES94906207T patent/ES2101507T3/es not_active Expired - Lifetime
- 1994-02-02 KR KR1019950703269A patent/KR100297272B1/ko not_active IP Right Cessation
- 1994-02-02 JP JP6517628A patent/JPH08506368A/ja active Pending
- 1994-02-02 WO PCT/EP1994/000301 patent/WO1994018303A1/de active IP Right Grant
- 1994-02-02 EP EP94906207A patent/EP0683814B1/de not_active Expired - Lifetime
- 1994-02-02 AT AT94906207T patent/ATE152477T1/de not_active IP Right Cessation
- 1994-02-09 MY MYPI94000305A patent/MY110838A/en unknown
Cited By (17)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO1996003488A1 (de) * | 1994-07-25 | 1996-02-08 | Henkel Kommanditgesellschaft Auf Aktien | Verfahren zur herstellung von tensidgranulaten |
| WO1996017922A1 (de) * | 1994-12-08 | 1996-06-13 | Henkel Kommanditgesellschaft Auf Aktien | Feste, rieselfähige zubereitungen |
| WO1998058047A1 (en) * | 1997-06-16 | 1998-12-23 | Unilever Plc | Production of detergent granulates |
| US6429184B1 (en) | 1997-06-16 | 2002-08-06 | Lever & Brothers Company, Division Of Conopco, Inc. | Production of detergent granulates |
| US6056905A (en) * | 1997-06-16 | 2000-05-02 | Lever Brothers Company Division Of Conopco, Inc. | Production of detergent granulates |
| AU743892B2 (en) * | 1997-06-16 | 2002-02-07 | Unilever Plc | Production of detergent granulates |
| US6274544B1 (en) | 1997-06-16 | 2001-08-14 | Lever Brothers Company, Division Of Conopco, Inc. | Production of detergent granulates |
| US6133223A (en) * | 1997-06-27 | 2000-10-17 | Lever Brothers Company, Division Of Conopco, Inc. | Production of detergent granulates |
| WO2000018872A1 (de) * | 1998-09-29 | 2000-04-06 | Henkel Kommanditgesellschaft Auf Aktien | Granulationsverfahren |
| WO2000018871A1 (de) * | 1998-09-29 | 2000-04-06 | Henkel Kommanditgesellschaft Auf Aktien | Granulationsverfahren |
| US6468957B1 (en) | 1998-09-29 | 2002-10-22 | Henkel Kommanditgesellschaft Auf Aktien | Granulation method |
| US6683042B1 (en) | 1998-09-29 | 2004-01-27 | Henkel Kommanditgesellschaft Auf Aktien (Henkel Kgaa) | Granulation method |
| WO2000027961A1 (de) * | 1998-11-09 | 2000-05-18 | Henkel Kommanditgesellschaft Auf Aktien | Tensid-granulate durch wirbelschichtgranulation |
| DE19851454B4 (de) * | 1998-11-09 | 2010-11-04 | Henkel Ag & Co. Kgaa | Tensid-Granulate durch Wirbelschichtgranulation |
| WO2000031230A1 (de) * | 1998-11-23 | 2000-06-02 | Cognis Deutschland Gmbh | Verfahren zur herstellung von tensidgranulaten |
| WO2000053713A1 (de) * | 1999-03-11 | 2000-09-14 | Henkel Kommanditgesellschaft Auf Aktien | Granulationsverfahren |
| DE10212169A1 (de) * | 2002-03-19 | 2003-10-02 | Sued Chemie Ag | Waschmittelzusatz mit hohem Gehalt an nichtionischen Tensiden und schnellem Auflösevermögen |
Also Published As
| Publication number | Publication date |
|---|---|
| EP0683814B1 (de) | 1997-05-02 |
| ES2101507T3 (es) | 1997-07-01 |
| JPH08506368A (ja) | 1996-07-09 |
| WO1994018303A1 (de) | 1994-08-18 |
| ATE152477T1 (de) | 1997-05-15 |
| EP0683814A1 (de) | 1995-11-29 |
| KR960701192A (ko) | 1996-02-24 |
| MY110838A (en) | 1999-05-31 |
| KR100297272B1 (ko) | 2001-11-30 |
| DE59402608D1 (de) | 1997-06-05 |
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