DE3782243D1 - Katalysator zur polymerisierung von alpha-olefin und verfahren. - Google Patents
Katalysator zur polymerisierung von alpha-olefin und verfahren.Info
- Publication number
- DE3782243D1 DE3782243D1 DE8787905645T DE3782243T DE3782243D1 DE 3782243 D1 DE3782243 D1 DE 3782243D1 DE 8787905645 T DE8787905645 T DE 8787905645T DE 3782243 T DE3782243 T DE 3782243T DE 3782243 D1 DE3782243 D1 DE 3782243D1
- Authority
- DE
- Germany
- Prior art keywords
- alpha
- catalyst
- olefins
- transition metal
- solid catalyst
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Fee Related
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F110/00—Homopolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
- C08F110/02—Ethene
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/62—Refractory metals or compounds thereof
- C08F4/64—Titanium, zirconium, hafnium or compounds thereof
- C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
- C08F4/65912—Component covered by group C08F4/64 containing a transition metal-carbon bond in combination with an organoaluminium compound
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/62—Refractory metals or compounds thereof
- C08F4/64—Titanium, zirconium, hafnium or compounds thereof
- C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
- C08F4/65916—Component covered by group C08F4/64 containing a transition metal-carbon bond supported on a carrier, e.g. silica, MgCl2, polymer
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/62—Refractory metals or compounds thereof
- C08F4/64—Titanium, zirconium, hafnium or compounds thereof
- C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
- C08F4/6592—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/62—Refractory metals or compounds thereof
- C08F4/64—Titanium, zirconium, hafnium or compounds thereof
- C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
- C08F4/6592—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring
- C08F4/65922—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring containing at least two cyclopentadienyl rings, fused or not
- C08F4/65925—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring containing at least two cyclopentadienyl rings, fused or not two cyclopentadienyl rings being mutually non-bridged
Applications Claiming Priority (5)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP19803786 | 1986-08-26 | ||
JP19803886A JPH0832735B2 (ja) | 1986-08-26 | 1986-08-26 | オレフインの重合方法 |
JP61203638A JP2530624B2 (ja) | 1986-09-01 | 1986-09-01 | オレフインの重合方法 |
JP3459187A JPH0780936B2 (ja) | 1986-08-26 | 1987-02-19 | オレフインの重合方法 |
PCT/JP1987/000629 WO1988001626A1 (en) | 1986-08-26 | 1987-08-26 | CATALYST FOR POLYMERIZING alpha-OLEFIN AND POLYMERIZATION PROCESS |
Publications (2)
Publication Number | Publication Date |
---|---|
DE3782243D1 true DE3782243D1 (de) | 1992-11-19 |
DE3782243T2 DE3782243T2 (de) | 1993-03-04 |
Family
ID=27459955
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
DE8787905645T Expired - Fee Related DE3782243T2 (de) | 1986-08-26 | 1987-08-26 | Katalysator zur polymerisierung von alpha-olefin und verfahren. |
Country Status (5)
Country | Link |
---|---|
EP (1) | EP0279863B1 (de) |
AT (1) | ATE81512T1 (de) |
CA (1) | CA1319142C (de) |
DE (1) | DE3782243T2 (de) |
WO (1) | WO1988001626A1 (de) |
Families Citing this family (122)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
EP0287666B1 (de) * | 1986-09-24 | 1993-05-26 | Mitsui Petrochemical Industries, Ltd. | Polymerisierungsverfahren für olefine |
MY103812A (en) † | 1988-02-12 | 1993-09-30 | Mitsui Chemicals Inc | Olefin polymerization catalyst and process for the polymerization of olefins. |
US5200103A (en) * | 1988-08-01 | 1993-04-06 | Exxon Chemical Patents Inc. | Ethylene alpha-olefin copolymer substituted Mannich base lubricant dispsersant additives |
US5345002A (en) * | 1988-08-01 | 1994-09-06 | Exxon Chemical Patents Inc. | Ethylene alpha-olefin copolymer substituted hydroxy aromatic compounds |
US5186851A (en) * | 1988-08-01 | 1993-02-16 | Exxon Chemical Patents Inc. | Ethylene alpha-olefin copolymer substituted mannich base lubricant dispersant additives |
CA2034759C (en) * | 1988-08-01 | 2003-06-03 | Won R. Song | Novel ethylene alpha-olefin polymer substituted mono- and dicarboxylic acid dispersant additives |
US5229022A (en) * | 1988-08-01 | 1993-07-20 | Exxon Chemical Patents Inc. | Ethylene alpha-olefin polymer substituted mono- and dicarboxylic acid dispersant additives (PT-920) |
US5759967A (en) * | 1988-08-01 | 1998-06-02 | Exxon Chemical Patents Inc | Ethylene α-olefin/diene interpolymer-substituted carboxylic acid dispersant additives |
US5128056A (en) * | 1988-08-01 | 1992-07-07 | Exxon Chemical Patents Inc. | Ethylene alpha-olefin copolymer substituted amino phenol mannich base lubricant dispersant additives |
US5266223A (en) * | 1988-08-01 | 1993-11-30 | Exxon Chemical Patents Inc. | Ethylene alpha-olefin polymer substituted mono-and dicarboxylic acid dispersant additives |
US5017299A (en) * | 1988-08-01 | 1991-05-21 | Exxon Chemical Patents, Inc. | Novel ethylene alpha-olefin copolymer substituted Mannich base lubricant dispersant additives |
US5277833A (en) * | 1988-08-01 | 1994-01-11 | Exxon Chemical Patents Inc. | Ethylene alpha-olefin polymer substituted mono-and dicarboxylic acid lubricant dispersant additives |
US5350532A (en) * | 1988-08-01 | 1994-09-27 | Exxon Chemical Patents Inc. | Borated ethylene alpha-olefin polymer substituted mono- and dicarboxylic acid dispersant additives |
US5225091A (en) * | 1988-08-01 | 1993-07-06 | Exxon Chemical Patents Inc. | Ethylene alpha-olefin polymer substituted thiocarboxylic acid lubricant dispersant additives |
US4914253A (en) * | 1988-11-04 | 1990-04-03 | Exxon Chemical Patents Inc. | Method for preparing polyethylene wax by gas phase polymerization |
EP0685496A1 (de) * | 1988-12-26 | 1995-12-06 | Mitsui Petrochemical Industries, Ltd. | Olefincopolymere und Verfahren zur Herstellung davon |
EP0507876B1 (de) † | 1990-01-02 | 1995-05-17 | Exxon Chemical Patents Inc. | Ionische metallocenkatalysatoren auf träger für olefinpolymerisation |
US5151204A (en) * | 1990-02-01 | 1992-09-29 | Exxon Chemical Patents Inc. | Oleaginous compositions containing novel ethylene alpha-olefin polymer viscosity index improver additive |
US5225092A (en) * | 1990-02-01 | 1993-07-06 | Exxon Chemical Patents Inc. | Ethylene alpha-olefin polymer substituted amine dispersant additives |
EP0522581B1 (de) * | 1991-07-11 | 1997-10-15 | Idemitsu Kosan Company Limited | Verfahren zur Herstellung von Polymeren auf Olefinbasis und Olefin-Polymerisationskatalysatoren |
DE69224600T2 (de) * | 1991-11-12 | 1998-08-27 | Nippon Oil Co Ltd | Katalysatorbestandteile für Olefinpolymerisation |
WO1993013140A1 (en) † | 1991-12-23 | 1993-07-08 | Exxon Chemical Patents Inc. | A modified monocyclopentadienyl transition metal/alumoxane catalyst system for polymerization of olefins |
US6143854A (en) | 1993-08-06 | 2000-11-07 | Exxon Chemical Patents, Inc. | Polymerization catalysts, their production and use |
US5240894A (en) * | 1992-05-18 | 1993-08-31 | Exxon Chemical Patents Inc. | Method for making and using a supported metallocene catalyst system |
DE69307472T2 (de) * | 1992-11-10 | 1997-05-15 | Mitsubishi Chem Corp | Verfahren zur Herstellung von Alpha-Olefinpolymeren |
CA2110649C (en) * | 1992-12-17 | 2004-10-26 | Jacob Emert | Gel-free alpha-olefin dispersant additives useful in oleaginous compositions |
CA2110463C (en) * | 1992-12-17 | 2005-02-08 | Jacob Emert | Gel-free ethylene interpolymer dispersant additives useful in oleaginous compositions |
CA2156528A1 (en) † | 1993-03-25 | 1994-09-29 | Frederick Yip-Kwai Lo | Process for forming a granular resin |
EP0696293B2 (de) † | 1993-04-26 | 2009-06-17 | Univation Technologies, LLC | Verfahren zur polymerisation von monomeren in fliessbetten |
IT1264680B1 (it) | 1993-07-07 | 1996-10-04 | Spherilene Srl | Catalizzatori supportati per la polimerizzazione delle olefine |
US5422325A (en) * | 1993-09-17 | 1995-06-06 | Exxon Chemical Patents Inc. | Supported polymerization catalysts, their production and use |
FI96866C (fi) | 1993-11-05 | 1996-09-10 | Borealis As | Tuettu olefiinipolymerointikatalyytti, sen valmistus ja käyttö |
FI95276C (fi) * | 1993-12-03 | 1996-01-10 | Borealis As | Olefiinien polymerointikatalyytti ja menetelmä sen valmistamiseksi |
US5491207A (en) * | 1993-12-14 | 1996-02-13 | Exxon Chemical Patents Inc. | Process of producing high molecular weight ethylene-α-olefin elastomers with an indenyl metallocene catalyst system |
US5595950A (en) * | 1993-12-20 | 1997-01-21 | Exxon Chemical Patents, Inc. | Polymerization catalyst systems, their production and use |
US6391817B1 (en) | 1993-12-28 | 2002-05-21 | Exxonmobil Chemical Patents Inc. | Method for producing a prepolymerized catalyst |
DE4406964A1 (de) * | 1994-03-03 | 1995-09-07 | Basf Ag | Geträgerte Metalloxenkomplexe mit heterofunktionellen Gruppen am Cyclopentadienylsystem als Katalysatorsysteme |
TW454020B (en) † | 1994-08-09 | 2001-09-11 | Mitsui Chemicals Inc | Olefin polymerization catalyst |
JPH11508932A (ja) * | 1995-07-06 | 1999-08-03 | エクソン・ケミカル・パテンツ・インク | 予備重合され担持されたメタロセン触媒系の製造方法 |
DE19527652A1 (de) * | 1995-07-28 | 1997-01-30 | Hoechst Ag | Metallocenverbindung |
US6090740A (en) * | 1996-02-08 | 2000-07-18 | Exxon Chemical Patents Inc. | Supported metallocene catalyst systems |
EP0816394B1 (de) * | 1996-06-26 | 2002-01-30 | BP Chemicals S.N.C. | Verfahren zur Ethylenpolymerisation in der Gasphase |
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-
1987
- 1987-08-26 EP EP87905645A patent/EP0279863B1/de not_active Revoked
- 1987-08-26 AT AT87905645T patent/ATE81512T1/de not_active IP Right Cessation
- 1987-08-26 WO PCT/JP1987/000629 patent/WO1988001626A1/ja not_active Application Discontinuation
- 1987-08-26 DE DE8787905645T patent/DE3782243T2/de not_active Expired - Fee Related
-
1988
- 1988-04-18 CA CA000564390A patent/CA1319142C/en not_active Expired - Fee Related
Also Published As
Publication number | Publication date |
---|---|
EP0279863A1 (de) | 1988-08-31 |
WO1988001626A1 (en) | 1988-03-10 |
DE3782243T2 (de) | 1993-03-04 |
EP0279863B1 (de) | 1992-10-14 |
EP0279863A4 (de) | 1988-08-29 |
ATE81512T1 (de) | 1992-10-15 |
CA1319142C (en) | 1993-06-15 |
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