GB1300734A - Improvements in or relating to the catalytic polymerisation of olefins - Google Patents
Improvements in or relating to the catalytic polymerisation of olefinsInfo
- Publication number
- GB1300734A GB1300734A GB5049568A GB5049568A GB1300734A GB 1300734 A GB1300734 A GB 1300734A GB 5049568 A GB5049568 A GB 5049568A GB 5049568 A GB5049568 A GB 5049568A GB 1300734 A GB1300734 A GB 1300734A
- Authority
- GB
- United Kingdom
- Prior art keywords
- olefins
- transition metal
- mixing
- metal
- catalyst
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
Abstract
1300734 Polymerizing olefins SHELL INTERNATIONALE RESEARCH MAATSCHAPPIJ NV 13 Jan 1970 [24 Oct 1968] 50495/68 Heading C3P Olefins are polymerized with the aid of a catalyst composition formed by mixing a transition metal compound in which the transition metal is in a valency state below its normal maximum with a metal alkyl (this term excluding a metal alkyl halide) by a process which comprises forming a liquid catalyst-containing dispersion having up to 1À0 millimole per litre of transition metal, by mixing the transition metal compound with the metal alkyl in the presence of a liquid diluent and contacting thetransition metal compound during and/or immediately after mixing the metal alkyl therewith, with one or more olefins under conditions in which only a minor amount of olefincontaining polymer is formed. In the example polyethylene is prepared using as catalyst a dispersion of TiCl 3 /Al(C 2 H 5 ) 3 in hexane which had been treated with ethylene for 30 seconds at 250 and 500 p.s.i.g.
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
GB5049568A GB1300734A (en) | 1968-10-24 | 1968-10-24 | Improvements in or relating to the catalytic polymerisation of olefins |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
GB5049568A GB1300734A (en) | 1968-10-24 | 1968-10-24 | Improvements in or relating to the catalytic polymerisation of olefins |
Publications (1)
Publication Number | Publication Date |
---|---|
GB1300734A true GB1300734A (en) | 1972-12-20 |
Family
ID=10456112
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
GB5049568A Expired GB1300734A (en) | 1968-10-24 | 1968-10-24 | Improvements in or relating to the catalytic polymerisation of olefins |
Country Status (1)
Country | Link |
---|---|
GB (1) | GB1300734A (en) |
Cited By (16)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
FR2358426A1 (en) * | 1976-07-15 | 1978-02-10 | Mitsui Toatsu Chemicals | PROCESS FOR POLYMERIZATION OF ETHYLENE OR A-OLEFINS, CATALYSTS USED AND NEW PRODUCTS THUS OBTAINED |
US4187385A (en) * | 1976-05-17 | 1980-02-05 | Mitsui Toatsu Chemical, Inc. | Process for the polymerization of ethylene or alpha-olefins and catalyst therefor |
US4190614A (en) * | 1976-04-13 | 1980-02-26 | Mitsui Toatsu Chemicals, Incorporated | Method for the production of low density copolymers of ethylene |
EP0011914A1 (en) * | 1978-09-26 | 1980-06-11 | Exxon Research And Engineering Company | Titanium trichloride catalyst composition and its use in the polymerization of alpha-olefins |
US4276400A (en) * | 1977-09-28 | 1981-06-30 | Eastman Kodak Company | Olefin polymerization process using pretreated catalyst |
DE3103990A1 (en) * | 1980-02-05 | 1981-12-03 | Chisso Corp., Osaka | METHOD FOR PRODUCING (ALPHA) -OLEFIN POLYMERS |
US4325837A (en) | 1980-08-12 | 1982-04-20 | Phillips Petroleum Company | Catalyst, method of producing the catalyst, and polymerization process employing the catalyst |
US4326988A (en) | 1980-08-12 | 1982-04-27 | Phillips Petroleum Company | Catalyst, method of producing the catalyst, and polymerization process employing the catalyst |
FR2539134A1 (en) * | 1983-01-11 | 1984-07-13 | Raffinage Cie Francaise | Process for the preparation of catalyst compositions for olefin polymerisation, catalyst compositions prepared by this process and application of the said compositions |
US4543400A (en) * | 1978-09-26 | 1985-09-24 | Exxon Research & Engineering Co. | Titanium trichloride catalyst component and the process for the production thereof |
US4665047A (en) * | 1986-08-15 | 1987-05-12 | Shell Oil Company | Stabilization of metallocene/aluminoxane catalysts |
EP0230019A2 (en) * | 1985-12-24 | 1987-07-29 | BASF Aktiengesellschaft | Process for preparing ethyl polymers by means of a Ziegler catalyst system |
EP0279863B1 (en) * | 1986-08-26 | 1992-10-14 | Mitsui Petrochemical Industries, Ltd. | Catalyst for polymerizing alpha-olefin and polymerization process |
US5654248A (en) * | 1986-08-26 | 1997-08-05 | Mitsui Petrochemical Industries, Ltd. | Catalyst for polymerizing alpha-olefins and process for polymerization |
US5912202A (en) * | 1997-01-10 | 1999-06-15 | Union Carbide Chemicals & Plastics Technology Corporation | Olefin polymerization catalyst composition having increased activity |
US6063726A (en) * | 1986-08-26 | 2000-05-16 | Mitsui Chemicals, Inc. | Catalyst for polymerizing alpha-olefins and process for polymerization |
-
1968
- 1968-10-24 GB GB5049568A patent/GB1300734A/en not_active Expired
Cited By (22)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US4190614A (en) * | 1976-04-13 | 1980-02-26 | Mitsui Toatsu Chemicals, Incorporated | Method for the production of low density copolymers of ethylene |
US4187385A (en) * | 1976-05-17 | 1980-02-05 | Mitsui Toatsu Chemical, Inc. | Process for the polymerization of ethylene or alpha-olefins and catalyst therefor |
US4158088A (en) * | 1976-07-15 | 1979-06-12 | Mitsui Toatsu Chemicals, Inc. | Process for the polymerization of ethylene or α-olefins and catalyst therefor |
FR2358426A1 (en) * | 1976-07-15 | 1978-02-10 | Mitsui Toatsu Chemicals | PROCESS FOR POLYMERIZATION OF ETHYLENE OR A-OLEFINS, CATALYSTS USED AND NEW PRODUCTS THUS OBTAINED |
US4276400A (en) * | 1977-09-28 | 1981-06-30 | Eastman Kodak Company | Olefin polymerization process using pretreated catalyst |
US4543400A (en) * | 1978-09-26 | 1985-09-24 | Exxon Research & Engineering Co. | Titanium trichloride catalyst component and the process for the production thereof |
EP0011914A1 (en) * | 1978-09-26 | 1980-06-11 | Exxon Research And Engineering Company | Titanium trichloride catalyst composition and its use in the polymerization of alpha-olefins |
DE3153128C2 (en) * | 1980-02-05 | 1987-12-03 | Chisso Corp., Osaka, Jp | |
DE3103990C2 (en) * | 1980-02-05 | 1986-10-30 | Chisso Corp., Osaka | Process for the polymerization of ethylene, propylene and / or butene- (1) |
DE3103990A1 (en) * | 1980-02-05 | 1981-12-03 | Chisso Corp., Osaka | METHOD FOR PRODUCING (ALPHA) -OLEFIN POLYMERS |
US4326988A (en) | 1980-08-12 | 1982-04-27 | Phillips Petroleum Company | Catalyst, method of producing the catalyst, and polymerization process employing the catalyst |
US4325837A (en) | 1980-08-12 | 1982-04-20 | Phillips Petroleum Company | Catalyst, method of producing the catalyst, and polymerization process employing the catalyst |
FR2539134A1 (en) * | 1983-01-11 | 1984-07-13 | Raffinage Cie Francaise | Process for the preparation of catalyst compositions for olefin polymerisation, catalyst compositions prepared by this process and application of the said compositions |
US4713430A (en) * | 1985-12-24 | 1987-12-15 | Basf Aktiengesellschaft | Preparation of ethene polymers by means of a Ziegler catalyst system |
EP0230019A2 (en) * | 1985-12-24 | 1987-07-29 | BASF Aktiengesellschaft | Process for preparing ethyl polymers by means of a Ziegler catalyst system |
EP0230019A3 (en) * | 1985-12-24 | 1989-07-26 | Basf Aktiengesellschaft | Process for preparing ethyl polymers by means of a ziegler catalyst system |
US4665047A (en) * | 1986-08-15 | 1987-05-12 | Shell Oil Company | Stabilization of metallocene/aluminoxane catalysts |
EP0279863B1 (en) * | 1986-08-26 | 1992-10-14 | Mitsui Petrochemical Industries, Ltd. | Catalyst for polymerizing alpha-olefin and polymerization process |
US5654248A (en) * | 1986-08-26 | 1997-08-05 | Mitsui Petrochemical Industries, Ltd. | Catalyst for polymerizing alpha-olefins and process for polymerization |
US6063726A (en) * | 1986-08-26 | 2000-05-16 | Mitsui Chemicals, Inc. | Catalyst for polymerizing alpha-olefins and process for polymerization |
US5912202A (en) * | 1997-01-10 | 1999-06-15 | Union Carbide Chemicals & Plastics Technology Corporation | Olefin polymerization catalyst composition having increased activity |
US6166154A (en) * | 1997-01-10 | 2000-12-26 | Union Carbide Chemicals & Plastics Technology Corporation | Olefin polymerization catalyst composition having increased activity |
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Legal Events
Date | Code | Title | Description |
---|---|---|---|
PS | Patent sealed | ||
PLNP | Patent lapsed through nonpayment of renewal fees |