ATE72819T1 - Verfahren zur polymerisation von alpha-olefinen. - Google Patents
Verfahren zur polymerisation von alpha-olefinen.Info
- Publication number
- ATE72819T1 ATE72819T1 AT87900280T AT87900280T ATE72819T1 AT E72819 T1 ATE72819 T1 AT E72819T1 AT 87900280 T AT87900280 T AT 87900280T AT 87900280 T AT87900280 T AT 87900280T AT E72819 T1 ATE72819 T1 AT E72819T1
- Authority
- AT
- Austria
- Prior art keywords
- transition metal
- alpha
- ligand
- compound
- metal atom
- Prior art date
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F210/00—Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
- C08F210/16—Copolymers of ethene with alpha-alkenes, e.g. EP rubbers
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/62—Refractory metals or compounds thereof
- C08F4/64—Titanium, zirconium, hafnium or compounds thereof
- C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
- C08F4/65912—Component covered by group C08F4/64 containing a transition metal-carbon bond in combination with an organoaluminium compound
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/62—Refractory metals or compounds thereof
- C08F4/64—Titanium, zirconium, hafnium or compounds thereof
- C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
- C08F4/6592—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/62—Refractory metals or compounds thereof
- C08F4/64—Titanium, zirconium, hafnium or compounds thereof
- C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
- C08F4/6592—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring
- C08F4/65922—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring containing at least two cyclopentadienyl rings, fused or not
- C08F4/65925—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring containing at least two cyclopentadienyl rings, fused or not two cyclopentadienyl rings being mutually non-bridged
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
Applications Claiming Priority (3)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP29189385 | 1985-12-26 | ||
EP87900280A EP0250601B2 (de) | 1985-12-26 | 1986-12-25 | Katalysator für die polymerisation von alpha-olefinen |
PCT/JP1986/000650 WO1987003887A1 (en) | 1985-12-26 | 1986-12-25 | Process for polymerization of alpha-olefins |
Publications (1)
Publication Number | Publication Date |
---|---|
ATE72819T1 true ATE72819T1 (de) | 1992-03-15 |
Family
ID=17774814
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
AT87900280T ATE72819T1 (de) | 1985-12-26 | 1986-12-25 | Verfahren zur polymerisation von alpha-olefinen. |
Country Status (6)
Country | Link |
---|---|
EP (1) | EP0250601B2 (de) |
JP (1) | JPH0780930B2 (de) |
CN (1) | CN1013580B (de) |
AT (1) | ATE72819T1 (de) |
DE (1) | DE3684018D1 (de) |
WO (1) | WO1987003887A1 (de) |
Families Citing this family (37)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US5077255A (en) * | 1986-09-09 | 1991-12-31 | Exxon Chemical Patents Inc. | New supported polymerization catalyst |
US7163907B1 (en) * | 1987-01-30 | 2007-01-16 | Exxonmobil Chemical Patents Inc. | Aluminum-free monocyclopentadienyl metallocene catalysts for olefin polymerization |
IL85097A (en) † | 1987-01-30 | 1992-02-16 | Exxon Chemical Patents Inc | Catalysts based on derivatives of a bis(cyclopentadienyl)group ivb metal compound,their preparation and their use in polymerization processes |
US5055438A (en) * | 1989-09-13 | 1991-10-08 | Exxon Chemical Patents, Inc. | Olefin polymerization catalysts |
JP2573613B2 (ja) * | 1987-08-14 | 1997-01-22 | 三菱化学株式会社 | エチレンの重合法 |
US6686488B2 (en) | 1989-08-31 | 2004-02-03 | The Dow Chemical Company | Constrained geometry addition polymerization catalysts |
NZ235032A (en) | 1989-08-31 | 1993-04-28 | Dow Chemical Co | Constrained geometry complexes of titanium, zirconium or hafnium comprising a substituted cyclopentadiene ligand; use as olefin polymerisation catalyst component |
US6075077A (en) * | 1989-08-31 | 2000-06-13 | The Dow Chemical Company | Asphalt, bitumen, and adhesive compositions |
US7041841B1 (en) | 1989-09-13 | 2006-05-09 | Exxonmobil Chemical Patents Inc. | Process for producing crystalline poly-α-olefins with a monocyclopentadienyl transition metal catalyst system |
US5547675A (en) * | 1989-09-13 | 1996-08-20 | Exxon Chemical Patents Inc. | Modified monocyclopentadienyl transition metal/alumoxane catalyst system for polymerization of olefins |
US5026798A (en) * | 1989-09-13 | 1991-06-25 | Exxon Chemical Patents Inc. | Process for producing crystalline poly-α-olefins with a monocyclopentadienyl transition metal catalyst system |
US5057475A (en) * | 1989-09-13 | 1991-10-15 | Exxon Chemical Patents Inc. | Mono-Cp heteroatom containing group IVB transition metal complexes with MAO: supported catalyst for olefin polymerization |
US6265338B1 (en) * | 1989-09-13 | 2001-07-24 | Exxon Chemical Patents, Inc. | Monocyclopentadienyl titanium metal compounds for ethylene-α-olefin copolymer production catalysts |
US5420217A (en) * | 1989-09-13 | 1995-05-30 | Exxon Chemical Patents Inc. | Process for producing amorphous poly-α-olefins with a monocyclopentadienyl transition metal catalyst system |
US5504169A (en) * | 1989-09-13 | 1996-04-02 | Exxon Chemical Patents Inc. | Process for producing amorphous poly-α-olefins with a monocyclopentadienyl transition metal catalyst system |
US5227440A (en) * | 1989-09-13 | 1993-07-13 | Exxon Chemical Patents Inc. | Mono-Cp heteroatom containing Group IVB transition metal complexes with MAO: supported catalysts for olefin polymerization |
US5064802A (en) * | 1989-09-14 | 1991-11-12 | The Dow Chemical Company | Metal complex compounds |
DE4004477A1 (de) * | 1990-02-14 | 1991-08-22 | Schering Ag | Verfahren zur herstellung von loesungen oligomerer methylaluminoxane |
US6294625B1 (en) | 1990-03-20 | 2001-09-25 | Exxonmobil Chemical Patents Inc. | Catalyst system of enhanced productivity and its use in polymerization process |
PL166690B1 (pl) * | 1990-06-04 | 1995-06-30 | Exxon Chemical Patents Inc | Sposób wytwarzania polimerów olefin PL |
ES2092913T5 (es) * | 1990-06-22 | 2002-10-16 | Exxonmobil Chem Patents Inc | Catalizadores a base de metaloceno de monociclopentadienilo exento de aluminio para la polimerizacion de olefinas. |
JP2545006B2 (ja) * | 1990-07-03 | 1996-10-16 | ザ ダウ ケミカル カンパニー | 付加重合触媒 |
CA2071706C (en) * | 1991-06-20 | 1996-09-17 | Junichi Imuta | Catalyst for olefin polymerization, process for the polymerization of olefin, and transition metal compound employable for the catalyst |
JP2816766B2 (ja) * | 1991-12-23 | 1998-10-27 | エクソン・ケミカル・パテンツ・インク | オレフィン重合用改質モノシクロペンタジエニル遷移金属/アルモキサン触媒系 |
US5288933A (en) * | 1992-04-16 | 1994-02-22 | Union Carbide Chemicals & Plastics Technology Corporation | Process for the production of polyethylene |
IT1256603B (it) * | 1992-10-30 | 1995-12-12 | Enichem Polimeri | Catalizzatore e procedimento per (co) polimerizzare le alfa-olefine |
EP0597502B1 (de) | 1992-11-13 | 2005-03-16 | Cryovac, Inc. | Wärmeschrumpfbare, durch Single-site-Katalyse hergestellte Copolymere enthaltende Folien. |
US5604043A (en) * | 1993-09-20 | 1997-02-18 | W.R. Grace & Co.-Conn. | Heat shrinkable films containing single site catalyzed copolymers having long chain branching |
SK42096A3 (en) * | 1995-03-29 | 1997-03-05 | Union Carbide Chem Plastic | Ethylene polymers with better transparency, increased toughness, with low ratio of extractable fraction and with better workability |
EP1426386B1 (de) | 1997-07-09 | 2007-05-30 | Maruzen Petrochemical Co., Ltd. | Katalysatorbestandteil zur Olefinpolymerisation |
US7053160B1 (en) | 1998-11-25 | 2006-05-30 | Basell Polyolefine Gmbh | Metallocene monohalogenides |
EP1361226A3 (de) * | 1998-11-25 | 2004-01-02 | Basell Polyolefine GmbH | Verfahren zur Aufreinigung von Metallocenen |
WO2003008459A1 (en) | 2001-07-20 | 2003-01-30 | University Of Maryland, College Park | Method for production of multimodal polyolefins of tunable composition, molecular weight, and polydispersity |
AU2002357251B2 (en) | 2001-12-21 | 2009-07-30 | Dow Global Technologies Inc. | Additive for rendering inert acidic or halogen-containing compounds contained in olefin polymers |
CA2471363C (en) | 2001-12-21 | 2014-02-11 | Human Genome Sciences, Inc. | Albumin fusion proteins |
CN102453122B (zh) * | 2010-10-19 | 2013-07-03 | 中国石油化工股份有限公司 | 一种负载型茂金属催化剂及其制备方法 |
US11485815B2 (en) | 2018-04-11 | 2022-11-01 | Mitsui Chemicals, Inc. | 4-methyl-1-pentene polymer particle and method for producing 4-methyl-1-pentene resin |
Family Cites Families (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3306919A (en) * | 1958-01-15 | 1967-02-28 | Union Carbide Corp | Cyclopentadienyl titanium compounds |
DE3007433C2 (de) † | 1980-02-28 | 1982-06-16 | Maizena Gmbh, 2000 Hamburg | Verfahren zur Herstellung von Polymermassen aus Polyolefinen und Stärke und/oder Lignin sowie gegebenenfalls Cellulosefasern |
US4530914A (en) * | 1983-06-06 | 1985-07-23 | Exxon Research & Engineering Co. | Process and catalyst for producing polyethylene having a broad molecular weight distribution |
EP0226663A1 (de) † | 1985-11-08 | 1987-07-01 | Texas Instruments Holland B.V. | Thermostat |
WO1987003889A1 (en) † | 1985-12-24 | 1987-07-02 | Mitsui Petrochemical Industries, Ltd. | Process for polymerization of alpha-olefins |
-
1986
- 1986-12-24 JP JP61306618A patent/JPH0780930B2/ja not_active Expired - Fee Related
- 1986-12-25 EP EP87900280A patent/EP0250601B2/de not_active Expired - Lifetime
- 1986-12-25 AT AT87900280T patent/ATE72819T1/de not_active IP Right Cessation
- 1986-12-25 DE DE8787900280T patent/DE3684018D1/de not_active Expired - Fee Related
- 1986-12-25 WO PCT/JP1986/000650 patent/WO1987003887A1/en active IP Right Grant
-
1988
- 1988-03-23 CN CN88102227.6A patent/CN1013580B/zh not_active Expired
Also Published As
Publication number | Publication date |
---|---|
EP0250601A1 (de) | 1988-01-07 |
CN1036016A (zh) | 1989-10-04 |
EP0250601B1 (de) | 1992-02-26 |
JPH0780930B2 (ja) | 1995-08-30 |
JPS62230802A (ja) | 1987-10-09 |
WO1987003887A1 (en) | 1987-07-02 |
DE3684018D1 (de) | 1992-04-02 |
EP0250601B2 (de) | 2003-07-02 |
CN1013580B (zh) | 1991-08-21 |
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Legal Events
Date | Code | Title | Description |
---|---|---|---|
UEP | Publication of translation of european patent specification | ||
UEP | Publication of translation of european patent specification |
Ref document number: 0250601 Country of ref document: EP |
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REN | Ceased due to non-payment of the annual fee |