IT1256603B - Catalizzatore e procedimento per (co) polimerizzare le alfa-olefine - Google Patents

Catalizzatore e procedimento per (co) polimerizzare le alfa-olefine

Info

Publication number
IT1256603B
IT1256603B ITMI922491A ITMI922491A IT1256603B IT 1256603 B IT1256603 B IT 1256603B IT MI922491 A ITMI922491 A IT MI922491A IT MI922491 A ITMI922491 A IT MI922491A IT 1256603 B IT1256603 B IT 1256603B
Authority
IT
Italy
Prior art keywords
catalyst
olefins
procedure
alpha
polymerizing alpha
Prior art date
Application number
ITMI922491A
Other languages
English (en)
Inventor
Luciano Luciani
Federico Milani
Original Assignee
Enichem Polimeri
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Enichem Polimeri filed Critical Enichem Polimeri
Publication of ITMI922491A0 publication Critical patent/ITMI922491A0/it
Priority to ITMI922491A priority Critical patent/IT1256603B/it
Priority to AT93202907T priority patent/ATE168384T1/de
Priority to DE69319690T priority patent/DE69319690T2/de
Priority to EP93202907A priority patent/EP0595390B1/en
Priority to US08/138,980 priority patent/US5529966A/en
Priority to HU9302984A priority patent/HU217576B/hu
Priority to CZ19932255A priority patent/CZ287777B6/cs
Priority to CA002109156A priority patent/CA2109156A1/en
Priority to JP5270411A priority patent/JPH06199925A/ja
Priority to RU93049608A priority patent/RU2119386C1/ru
Priority to FI934790A priority patent/FI934790A/fi
Priority to BR9304428A priority patent/BR9304428A/pt
Publication of ITMI922491A1 publication Critical patent/ITMI922491A1/it
Application granted granted Critical
Publication of IT1256603B publication Critical patent/IT1256603B/it

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/65912—Component covered by group C08F4/64 containing a transition metal-carbon bond in combination with an organoaluminium compound
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/6592—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring
    • C08F4/65922—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring containing at least two cyclopentadienyl rings, fused or not
    • C08F4/65925—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring containing at least two cyclopentadienyl rings, fused or not two cyclopentadienyl rings being mutually non-bridged

Abstract

Un catalizzatore attivo nella polimerizzazione delle alfa-olefine è formato da:(a) un derivato bis-(ciclopentadienil) bis(ammide) di un elemento del gruppo IVB della tavola periodica degli elementi, definibile con la formula: (FORMULA I) dove M rappresenta un metallo del gruppo IVB, ciascuno tra R1, R2, R3 e R4, e Cp hanno il significato riportato nelle descrizioni, e (b) un co-catalizzatore di alluminossano.Questo catalizzatore trova impiego nei procedimenti di polimerizzazione e di copolimerizzazione dell'etilene e delle altre alfa-olefine.
ITMI922491A 1992-10-30 1992-10-30 Catalizzatore e procedimento per (co) polimerizzare le alfa-olefine IT1256603B (it)

Priority Applications (12)

Application Number Priority Date Filing Date Title
ITMI922491A IT1256603B (it) 1992-10-30 1992-10-30 Catalizzatore e procedimento per (co) polimerizzare le alfa-olefine
AT93202907T ATE168384T1 (de) 1992-10-30 1993-10-19 Katalysator und verfahren zur (co)polymerisation von alpha-olefinen
DE69319690T DE69319690T2 (de) 1992-10-30 1993-10-19 Katalysator und Verfahren zur (Co)Polymerisation von Alpha-Olefinen
EP93202907A EP0595390B1 (en) 1992-10-30 1993-10-19 Catalyst and process for (co)polymerizing alpha-olefins
US08/138,980 US5529966A (en) 1992-10-30 1993-10-21 Catalyst and process for (co)polymerizing alpha-olefins
HU9302984A HU217576B (hu) 1992-10-30 1993-10-21 Katalizátor és eljárás alfa-olefinek (ko)polimerizálására
CZ19932255A CZ287777B6 (en) 1992-10-30 1993-10-25 Catalyst for polymerization of ethylene and copolymerization of ethylene with other alpha-olefins and process for making thereof
CA002109156A CA2109156A1 (en) 1992-10-30 1993-10-25 Catalyst and process for (co) polymerizing alpha-olefins
JP5270411A JPH06199925A (ja) 1992-10-30 1993-10-28 α− オレフィンの重合用触媒及び重合方法
RU93049608A RU2119386C1 (ru) 1992-10-30 1993-10-28 Катализатор и способ (со)полимеризации альфа-олефинов
FI934790A FI934790A (fi) 1992-10-30 1993-10-29 Katalysator och foerfarande foer (ko)polymerisering av alfaolefiner
BR9304428A BR9304428A (pt) 1992-10-30 1993-10-29 Catalisador e processo para (CO)polimerização de etileno e outras alfa-olefinas

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
ITMI922491A IT1256603B (it) 1992-10-30 1992-10-30 Catalizzatore e procedimento per (co) polimerizzare le alfa-olefine

Publications (3)

Publication Number Publication Date
ITMI922491A0 ITMI922491A0 (it) 1992-10-30
ITMI922491A1 ITMI922491A1 (it) 1994-04-30
IT1256603B true IT1256603B (it) 1995-12-12

Family

ID=11364201

Family Applications (1)

Application Number Title Priority Date Filing Date
ITMI922491A IT1256603B (it) 1992-10-30 1992-10-30 Catalizzatore e procedimento per (co) polimerizzare le alfa-olefine

Country Status (12)

Country Link
US (1) US5529966A (it)
EP (1) EP0595390B1 (it)
JP (1) JPH06199925A (it)
AT (1) ATE168384T1 (it)
BR (1) BR9304428A (it)
CA (1) CA2109156A1 (it)
CZ (1) CZ287777B6 (it)
DE (1) DE69319690T2 (it)
FI (1) FI934790A (it)
HU (1) HU217576B (it)
IT (1) IT1256603B (it)
RU (1) RU2119386C1 (it)

Families Citing this family (13)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
IT1272939B (it) * 1995-02-01 1997-07-01 Enichem Spa Catalizzatore metallocenico supportato per la (co)polimerizzazione delle olefine
US5527752A (en) * 1995-03-29 1996-06-18 Union Carbide Chemicals & Plastics Technology Corporation Catalysts for the production of polyolefins
DE19516801A1 (de) * 1995-05-08 1996-11-14 Hoechst Ag Organometallverbindung
IT1275777B1 (it) * 1995-07-06 1997-10-17 Enichem Spa Catalizzatore metallocenico per la (co)polimerizzazione delle olefine
DE19546500A1 (de) * 1995-12-13 1997-06-19 Hoechst Ag Verfahren zur Herstellung eines Cycloolefincopolymeren
DE19546501A1 (de) 1995-12-13 1997-06-19 Hoechst Ag Metallocenverbindung
IT1282364B1 (it) * 1996-01-16 1998-03-20 Enichem Spa Catalizzatore metallocenico supportato per la (co) polimerizzazione delle alfa-olefine
US5959044A (en) * 1996-07-08 1999-09-28 Villar; Juan Carlos Method of controlling continuous ethylene-limited metallocene-catalyzed copolymerization systems
DE19630580A1 (de) * 1996-07-30 1998-02-05 Studiengesellschaft Kohle Mbh Organochrom-Verbindungen enthaltende Katalysatoren und ihre Verwendung in der Alkenpolymerisation
US6207608B1 (en) 1996-08-09 2001-03-27 University Of Iowa Research Foundation Olefin polymerization with direct use of ansa-metallocene amide complexes as catalysts
US6339035B1 (en) 1999-02-22 2002-01-15 Phillips Petroleum Company Catalyst and process for polymerizing olefins
US6559088B1 (en) * 1999-02-22 2003-05-06 Fina Technology, Inc. Ziegler-Natta catalyst with amine for polymerization
KR100421552B1 (ko) * 2000-12-18 2004-03-09 삼성아토피나주식회사 올레핀 중합용 촉매 및 이를 이용한 중합 방법

Family Cites Families (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH0780930B2 (ja) * 1985-12-26 1995-08-30 三井石油化学工業株式会社 α−オレフインの重合方法
US5055438A (en) * 1989-09-13 1991-10-08 Exxon Chemical Patents, Inc. Olefin polymerization catalysts

Also Published As

Publication number Publication date
HU9302984D0 (en) 1994-01-28
DE69319690D1 (de) 1998-08-20
EP0595390B1 (en) 1998-07-15
DE69319690T2 (de) 1999-04-08
EP0595390A1 (en) 1994-05-04
CZ225593A3 (en) 1994-05-18
ITMI922491A1 (it) 1994-04-30
FI934790A (fi) 1994-05-01
CA2109156A1 (en) 1994-05-01
CZ287777B6 (en) 2001-01-17
HUT66385A (en) 1994-11-28
FI934790A0 (fi) 1993-10-29
ATE168384T1 (de) 1998-08-15
RU2119386C1 (ru) 1998-09-27
BR9304428A (pt) 1994-07-05
JPH06199925A (ja) 1994-07-19
US5529966A (en) 1996-06-25
HU217576B (hu) 2000-02-28
ITMI922491A0 (it) 1992-10-30

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Legal Events

Date Code Title Description
0001 Granted
TA Fee payment date (situation as of event date), data collected since 19931001

Effective date: 19971014