DE3781058T2 - Natrium-kalkstein-doppelalkalirauchgasentschwefelungsverfahren mit kalksteinverwendung. - Google Patents
Natrium-kalkstein-doppelalkalirauchgasentschwefelungsverfahren mit kalksteinverwendung.Info
- Publication number
- DE3781058T2 DE3781058T2 DE8787103964T DE3781058T DE3781058T2 DE 3781058 T2 DE3781058 T2 DE 3781058T2 DE 8787103964 T DE8787103964 T DE 8787103964T DE 3781058 T DE3781058 T DE 3781058T DE 3781058 T2 DE3781058 T2 DE 3781058T2
- Authority
- DE
- Germany
- Prior art keywords
- limestone
- circuit
- regeneration
- post
- absorber
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Fee Related
Links
- 239000006028 limestone Substances 0.000 title claims abstract description 115
- 235000019738 Limestone Nutrition 0.000 title claims abstract description 107
- 238000000034 method Methods 0.000 title claims abstract description 61
- 230000008569 process Effects 0.000 title claims abstract description 52
- 238000006477 desulfuration reaction Methods 0.000 title claims abstract description 12
- 230000008929 regeneration Effects 0.000 claims abstract description 111
- 238000011069 regeneration method Methods 0.000 claims abstract description 111
- 239000006096 absorbing agent Substances 0.000 claims abstract description 83
- 239000007787 solid Substances 0.000 claims abstract description 76
- 239000002002 slurry Substances 0.000 claims abstract description 60
- 239000002562 thickening agent Substances 0.000 claims abstract description 56
- 238000006243 chemical reaction Methods 0.000 claims abstract description 27
- 239000003546 flue gas Substances 0.000 claims abstract description 19
- UGFAIRIUMAVXCW-UHFFFAOYSA-N Carbon monoxide Chemical compound [O+]#[C-] UGFAIRIUMAVXCW-UHFFFAOYSA-N 0.000 claims abstract description 18
- GEHJYWRUCIMESM-UHFFFAOYSA-L sodium sulfite Chemical compound [Na+].[Na+].[O-]S([O-])=O GEHJYWRUCIMESM-UHFFFAOYSA-L 0.000 claims abstract description 14
- 239000003513 alkali Substances 0.000 claims abstract description 11
- 230000023556 desulfurization Effects 0.000 claims abstract description 11
- DWAQJAXMDSEUJJ-UHFFFAOYSA-M Sodium bisulfite Chemical compound [Na+].OS([O-])=O DWAQJAXMDSEUJJ-UHFFFAOYSA-M 0.000 claims abstract description 8
- 235000010267 sodium hydrogen sulphite Nutrition 0.000 claims abstract description 8
- 235000010265 sodium sulphite Nutrition 0.000 claims abstract description 7
- 239000007788 liquid Substances 0.000 claims description 24
- VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical compound [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 claims description 16
- RAHZWNYVWXNFOC-UHFFFAOYSA-N Sulphur dioxide Chemical compound O=S=O RAHZWNYVWXNFOC-UHFFFAOYSA-N 0.000 claims description 16
- LSNNMFCWUKXFEE-UHFFFAOYSA-M Bisulfite Chemical compound OS([O-])=O LSNNMFCWUKXFEE-UHFFFAOYSA-M 0.000 claims description 12
- LSNNMFCWUKXFEE-UHFFFAOYSA-N Sulfurous acid Chemical compound OS(O)=O LSNNMFCWUKXFEE-UHFFFAOYSA-N 0.000 claims description 9
- 239000006227 byproduct Substances 0.000 claims description 8
- GBAOBIBJACZTNA-UHFFFAOYSA-L calcium sulfite Chemical compound [Ca+2].[O-]S([O-])=O GBAOBIBJACZTNA-UHFFFAOYSA-L 0.000 claims description 8
- 235000010261 calcium sulphite Nutrition 0.000 claims description 8
- QAOWNCQODCNURD-UHFFFAOYSA-L Sulfate Chemical compound [O-]S([O-])(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-L 0.000 claims description 7
- 239000012141 concentrate Substances 0.000 claims description 6
- 239000007789 gas Substances 0.000 claims description 5
- 238000000926 separation method Methods 0.000 claims description 5
- 235000010269 sulphur dioxide Nutrition 0.000 claims description 5
- 229910000019 calcium carbonate Inorganic materials 0.000 claims description 3
- 238000005119 centrifugation Methods 0.000 claims description 2
- 238000001914 filtration Methods 0.000 claims description 2
- 239000003795 chemical substances by application Substances 0.000 abstract 1
- 230000001172 regenerating effect Effects 0.000 abstract 1
- 239000000243 solution Substances 0.000 description 74
- 230000009257 reactivity Effects 0.000 description 11
- CDBYLPFSWZWCQE-UHFFFAOYSA-L Sodium Carbonate Chemical compound [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 description 8
- 238000013461 design Methods 0.000 description 6
- 239000002245 particle Substances 0.000 description 6
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 6
- 238000010521 absorption reaction Methods 0.000 description 5
- 230000002378 acidificating effect Effects 0.000 description 5
- 238000013459 approach Methods 0.000 description 5
- 235000008733 Citrus aurantifolia Nutrition 0.000 description 4
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 4
- 235000011941 Tilia x europaea Nutrition 0.000 description 4
- 239000007864 aqueous solution Substances 0.000 description 4
- 230000008901 benefit Effects 0.000 description 4
- 230000007423 decrease Effects 0.000 description 4
- 239000012065 filter cake Substances 0.000 description 4
- 239000004571 lime Substances 0.000 description 4
- 230000004048 modification Effects 0.000 description 4
- 238000012986 modification Methods 0.000 description 4
- 239000011734 sodium Substances 0.000 description 4
- 229910052708 sodium Inorganic materials 0.000 description 4
- 235000017550 sodium carbonate Nutrition 0.000 description 4
- 229910000029 sodium carbonate Inorganic materials 0.000 description 4
- 230000006872 improvement Effects 0.000 description 3
- 238000004886 process control Methods 0.000 description 3
- 239000012492 regenerant Substances 0.000 description 3
- CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 description 2
- VTLYFUHAOXGGBS-UHFFFAOYSA-N Fe3+ Chemical compound [Fe+3] VTLYFUHAOXGGBS-UHFFFAOYSA-N 0.000 description 2
- 235000010216 calcium carbonate Nutrition 0.000 description 2
- 238000005352 clarification Methods 0.000 description 2
- 238000010586 diagram Methods 0.000 description 2
- 230000005484 gravity Effects 0.000 description 2
- 239000012452 mother liquor Substances 0.000 description 2
- 238000006386 neutralization reaction Methods 0.000 description 2
- 230000009467 reduction Effects 0.000 description 2
- 239000010802 sludge Substances 0.000 description 2
- CWYNVVGOOAEACU-UHFFFAOYSA-N Fe2+ Chemical compound [Fe+2] CWYNVVGOOAEACU-UHFFFAOYSA-N 0.000 description 1
- KRHYYFGTRYWZRS-UHFFFAOYSA-M Fluoride anion Chemical compound [F-] KRHYYFGTRYWZRS-UHFFFAOYSA-M 0.000 description 1
- FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 description 1
- JLVVSXFLKOJNIY-UHFFFAOYSA-N Magnesium ion Chemical compound [Mg+2] JLVVSXFLKOJNIY-UHFFFAOYSA-N 0.000 description 1
- -1 SO2 Chemical class 0.000 description 1
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 description 1
- 230000002411 adverse Effects 0.000 description 1
- 238000013019 agitation Methods 0.000 description 1
- 238000000498 ball milling Methods 0.000 description 1
- 239000001569 carbon dioxide Substances 0.000 description 1
- 229910002092 carbon dioxide Inorganic materials 0.000 description 1
- 239000003245 coal Substances 0.000 description 1
- 239000011362 coarse particle Substances 0.000 description 1
- 238000012937 correction Methods 0.000 description 1
- 239000013078 crystal Substances 0.000 description 1
- 230000007547 defect Effects 0.000 description 1
- 230000009977 dual effect Effects 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 239000012527 feed solution Substances 0.000 description 1
- 239000012535 impurity Substances 0.000 description 1
- 150000002500 ions Chemical class 0.000 description 1
- 239000011777 magnesium Substances 0.000 description 1
- 229910052749 magnesium Inorganic materials 0.000 description 1
- 230000007246 mechanism Effects 0.000 description 1
- 239000003595 mist Substances 0.000 description 1
- 239000000203 mixture Substances 0.000 description 1
- 230000002035 prolonged effect Effects 0.000 description 1
- 230000001737 promoting effect Effects 0.000 description 1
- 230000003134 recirculating effect Effects 0.000 description 1
- 239000007921 spray Substances 0.000 description 1
- LSNNMFCWUKXFEE-UHFFFAOYSA-L sulfite Chemical compound [O-]S([O-])=O LSNNMFCWUKXFEE-UHFFFAOYSA-L 0.000 description 1
- 239000011593 sulfur Substances 0.000 description 1
- 229910052717 sulfur Inorganic materials 0.000 description 1
- XTQHKBHJIVJGKJ-UHFFFAOYSA-N sulfur monoxide Chemical class S=O XTQHKBHJIVJGKJ-UHFFFAOYSA-N 0.000 description 1
- 229910052815 sulfur oxide Inorganic materials 0.000 description 1
- 239000004291 sulphur dioxide Substances 0.000 description 1
- 238000011144 upstream manufacturing Methods 0.000 description 1
- 238000013022 venting Methods 0.000 description 1
- 230000035899 viability Effects 0.000 description 1
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
- B01D53/34—Chemical or biological purification of waste gases
- B01D53/46—Removing components of defined structure
- B01D53/48—Sulfur compounds
- B01D53/50—Sulfur oxides
- B01D53/501—Sulfur oxides by treating the gases with a solution or a suspension of an alkali or earth-alkali or ammonium compound
Landscapes
- Engineering & Computer Science (AREA)
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Biomedical Technology (AREA)
- Environmental & Geological Engineering (AREA)
- Analytical Chemistry (AREA)
- General Chemical & Material Sciences (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Treating Waste Gases (AREA)
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US06/877,820 US4687648A (en) | 1986-06-24 | 1986-06-24 | Sodium-limestone double alkali flue gas desulfurization process with improved limestone utilization |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| DE3781058D1 DE3781058D1 (de) | 1992-09-17 |
| DE3781058T2 true DE3781058T2 (de) | 1993-02-11 |
Family
ID=25370790
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| DE8787103964T Expired - Fee Related DE3781058T2 (de) | 1986-06-24 | 1987-03-18 | Natrium-kalkstein-doppelalkalirauchgasentschwefelungsverfahren mit kalksteinverwendung. |
Country Status (9)
| Country | Link |
|---|---|
| US (1) | US4687648A (show.php) |
| EP (1) | EP0253951B1 (show.php) |
| JP (1) | JPS634834A (show.php) |
| CN (1) | CN1009071B (show.php) |
| AT (1) | ATE79299T1 (show.php) |
| CA (1) | CA1261119A (show.php) |
| DE (1) | DE3781058T2 (show.php) |
| ES (1) | ES2004280A6 (show.php) |
| MX (1) | MX166302B (show.php) |
Families Citing this family (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2691041B2 (ja) * | 1990-02-14 | 1997-12-17 | 三菱重工業株式会社 | フライアッシュを含む吸収液スラリーの処理方法 |
| SE501523C2 (sv) * | 1993-01-21 | 1995-03-06 | Flaekt Ab | Sätt och anordning vid rening av svaveldioxidinnehållande gaser |
| CN1086147C (zh) * | 1999-04-14 | 2002-06-12 | 唐山市新世纪环保设计研究所 | 消烟除尘脱硫烟气净化剂 |
| CN1102072C (zh) * | 2000-05-30 | 2003-02-26 | 华南理工大学 | 二氧化硫工业烟气脱除方法 |
| CN100390061C (zh) * | 2005-09-02 | 2008-05-28 | 吕国锋 | 一种用工业副产无水硫酸钠制备无水亚硫酸钠的方法 |
| CN101874975B (zh) * | 2009-12-14 | 2012-05-23 | 哈尔滨工业大学 | 双碱式半干法烟气脱硫装置及工艺 |
| CN111013371A (zh) * | 2019-12-22 | 2020-04-17 | 上海交通大学 | 一种钠碱循环脱硫过程中副产物硫酸钠的处理及再生方法 |
| CN118788117B (zh) * | 2024-06-17 | 2025-05-13 | 北京中科润宇环保科技股份有限公司 | 多污染物烟气净化装置及控制方法 |
Family Cites Families (13)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS5033988B2 (show.php) * | 1971-10-05 | 1975-11-05 | ||
| JPS5626616B2 (show.php) * | 1972-09-19 | 1981-06-19 | ||
| JPS5545493B2 (show.php) * | 1972-11-10 | 1980-11-18 | ||
| US3961021A (en) * | 1973-09-25 | 1976-06-01 | Kureha Kagaku Kogyo Kabushiki Kaisha | Method for removing sulfur dioxide from combustion exhaust gas |
| US3944649A (en) * | 1973-12-13 | 1976-03-16 | Combustion Equipment Associates, Inc. | Multistage process for removing sulfur dioxide from stack gases |
| US4331640A (en) * | 1978-06-26 | 1982-05-25 | Kureha Kagaku Kogyo Kabushiki Kaisha | Process for removing sulfur dioxide from an exhaust gas containing the same |
| US4313924A (en) * | 1979-05-10 | 1982-02-02 | Neptune Airpol, Inc. | Process for removal of sulfur dioxide from gas streams |
| US4261962A (en) * | 1979-07-11 | 1981-04-14 | The Foundation At New Jersey Institute Of Technology | Sodium sulfite regeneration method using limestone slurry |
| US4388282A (en) * | 1981-12-22 | 1983-06-14 | Research-Cottrell, Inc. | Method for regeneration of sodium sulfite from spent flue gas desulfurization processes |
| US4410500A (en) * | 1982-05-10 | 1983-10-18 | Fmc Corporation | Sodium-limestone double alkali flue gas desulfurization method |
| US4431618A (en) * | 1982-10-12 | 1984-02-14 | Fmc Corporation | Process control of continuous sodium-limestone flue gas desulfurization system |
| US4462969A (en) * | 1983-06-10 | 1984-07-31 | Central Illinois Public Service Company | Regeneration of sulfur dioxide scrubber liquor |
| US4540556A (en) * | 1983-06-10 | 1985-09-10 | Central Illinois Public Service Company | Dual alkali scrubber liquor regeneration with production of gypsum |
-
1986
- 1986-06-24 US US06/877,820 patent/US4687648A/en not_active Expired - Fee Related
-
1987
- 1987-03-11 CA CA000531797A patent/CA1261119A/en not_active Expired
- 1987-03-18 AT AT87103964T patent/ATE79299T1/de not_active IP Right Cessation
- 1987-03-18 DE DE8787103964T patent/DE3781058T2/de not_active Expired - Fee Related
- 1987-03-18 EP EP87103964A patent/EP0253951B1/en not_active Expired - Lifetime
- 1987-03-31 CN CN87102506A patent/CN1009071B/zh not_active Expired
- 1987-03-31 JP JP62076531A patent/JPS634834A/ja active Granted
- 1987-04-01 ES ES8700936A patent/ES2004280A6/es not_active Expired
- 1987-04-01 MX MX005850A patent/MX166302B/es unknown
Also Published As
| Publication number | Publication date |
|---|---|
| US4687648A (en) | 1987-08-18 |
| CN87102506A (zh) | 1988-01-06 |
| JPS634834A (ja) | 1988-01-09 |
| CA1261119A (en) | 1989-09-26 |
| EP0253951A2 (en) | 1988-01-27 |
| ES2004280A6 (es) | 1988-12-16 |
| JPS6351731B2 (show.php) | 1988-10-14 |
| EP0253951B1 (en) | 1992-08-12 |
| EP0253951A3 (en) | 1990-05-23 |
| CN1009071B (zh) | 1990-08-08 |
| ATE79299T1 (de) | 1992-08-15 |
| MX166302B (es) | 1992-12-25 |
| DE3781058D1 (de) | 1992-09-17 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| 8364 | No opposition during term of opposition | ||
| 8339 | Ceased/non-payment of the annual fee |