DE3544909C2 - - Google Patents
Info
- Publication number
- DE3544909C2 DE3544909C2 DE3544909A DE3544909A DE3544909C2 DE 3544909 C2 DE3544909 C2 DE 3544909C2 DE 3544909 A DE3544909 A DE 3544909A DE 3544909 A DE3544909 A DE 3544909A DE 3544909 C2 DE3544909 C2 DE 3544909C2
- Authority
- DE
- Germany
- Prior art keywords
- copolymers
- dimethylaminopropylacrylamide
- acrylamide
- dmapaa
- sludge
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- 229920001577 copolymer Polymers 0.000 claims abstract description 21
- 239000008394 flocculating agent Substances 0.000 claims abstract description 13
- ZWAPMFBHEQZLGK-UHFFFAOYSA-N 5-(dimethylamino)-2-methylidenepentanamide Chemical compound CN(C)CCCC(=C)C(N)=O ZWAPMFBHEQZLGK-UHFFFAOYSA-N 0.000 claims description 31
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 24
- HRPVXLWXLXDGHG-UHFFFAOYSA-N Acrylamide Chemical compound NC(=O)C=C HRPVXLWXLXDGHG-UHFFFAOYSA-N 0.000 claims description 20
- 125000002091 cationic group Chemical group 0.000 claims description 14
- 239000010801 sewage sludge Substances 0.000 claims description 11
- 239000000178 monomer Substances 0.000 claims description 7
- 239000007864 aqueous solution Substances 0.000 claims description 6
- 239000002253 acid Substances 0.000 claims description 5
- 150000007513 acids Chemical class 0.000 claims description 4
- 229910052500 inorganic mineral Inorganic materials 0.000 claims description 4
- 239000011707 mineral Substances 0.000 claims description 4
- 230000001588 bifunctional effect Effects 0.000 claims description 3
- 238000000034 method Methods 0.000 claims description 3
- 150000001875 compounds Chemical class 0.000 claims description 2
- 229920000867 polyelectrolyte Polymers 0.000 claims description 2
- 239000010865 sewage Substances 0.000 abstract description 2
- 239000003295 industrial effluent Substances 0.000 abstract 1
- 238000000746 purification Methods 0.000 abstract 1
- 229920000642 polymer Polymers 0.000 description 21
- 239000000243 solution Substances 0.000 description 18
- 239000010802 sludge Substances 0.000 description 16
- 230000003750 conditioning effect Effects 0.000 description 12
- 239000000047 product Substances 0.000 description 10
- 238000005189 flocculation Methods 0.000 description 9
- 230000016615 flocculation Effects 0.000 description 9
- 238000006116 polymerization reaction Methods 0.000 description 8
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 description 7
- 230000000052 comparative effect Effects 0.000 description 7
- 230000000694 effects Effects 0.000 description 5
- OZAIFHULBGXAKX-UHFFFAOYSA-N 2-(2-cyanopropan-2-yldiazenyl)-2-methylpropanenitrile Chemical compound N#CC(C)(C)N=NC(C)(C)C#N OZAIFHULBGXAKX-UHFFFAOYSA-N 0.000 description 4
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 4
- NEHMKBQYUWJMIP-UHFFFAOYSA-N chloromethane Chemical compound ClC NEHMKBQYUWJMIP-UHFFFAOYSA-N 0.000 description 4
- 239000000706 filtrate Substances 0.000 description 4
- 239000007787 solid Substances 0.000 description 4
- CCTFAOUOYLVUFG-UHFFFAOYSA-N 2-(1-amino-1-imino-2-methylpropan-2-yl)azo-2-methylpropanimidamide Chemical compound NC(=N)C(C)(C)N=NC(C)(C)C(N)=N CCTFAOUOYLVUFG-UHFFFAOYSA-N 0.000 description 3
- QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical compound CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 description 3
- -1 cationic Acrylic acid derivatives Chemical class 0.000 description 3
- 230000001419 dependent effect Effects 0.000 description 3
- 230000007062 hydrolysis Effects 0.000 description 3
- 238000006460 hydrolysis reaction Methods 0.000 description 3
- 239000002245 particle Substances 0.000 description 3
- 239000000843 powder Substances 0.000 description 3
- 238000012360 testing method Methods 0.000 description 3
- NIXOWILDQLNWCW-UHFFFAOYSA-N 2-Propenoic acid Natural products OC(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 description 2
- ROSDSFDQCJNGOL-UHFFFAOYSA-N Dimethylamine Chemical compound CNC ROSDSFDQCJNGOL-UHFFFAOYSA-N 0.000 description 2
- 150000001412 amines Chemical class 0.000 description 2
- 230000015572 biosynthetic process Effects 0.000 description 2
- 238000004140 cleaning Methods 0.000 description 2
- 230000001143 conditioned effect Effects 0.000 description 2
- 238000007334 copolymerization reaction Methods 0.000 description 2
- 238000010438 heat treatment Methods 0.000 description 2
- 238000004519 manufacturing process Methods 0.000 description 2
- 125000005397 methacrylic acid ester group Chemical group 0.000 description 2
- 229940050176 methyl chloride Drugs 0.000 description 2
- CNPHCSFIDKZQAK-UHFFFAOYSA-N n-prop-2-enylprop-2-enamide Chemical compound C=CCNC(=O)C=C CNPHCSFIDKZQAK-UHFFFAOYSA-N 0.000 description 2
- 229910052757 nitrogen Inorganic materials 0.000 description 2
- USHAGKDGDHPEEY-UHFFFAOYSA-L potassium persulfate Chemical compound [K+].[K+].[O-]S(=O)(=O)OOS([O-])(=O)=O USHAGKDGDHPEEY-UHFFFAOYSA-L 0.000 description 2
- 238000003825 pressing Methods 0.000 description 2
- 239000002002 slurry Substances 0.000 description 2
- 238000003756 stirring Methods 0.000 description 2
- 238000003860 storage Methods 0.000 description 2
- 238000004065 wastewater treatment Methods 0.000 description 2
- MSAHTMIQULFMRG-UHFFFAOYSA-N 1,2-diphenyl-2-propan-2-yloxyethanone Chemical compound C=1C=CC=CC=1C(OC(C)C)C(=O)C1=CC=CC=C1 MSAHTMIQULFMRG-UHFFFAOYSA-N 0.000 description 1
- SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Chemical compound COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 description 1
- DPBJAVGHACCNRL-UHFFFAOYSA-N 2-(dimethylamino)ethyl prop-2-enoate Chemical compound CN(C)CCOC(=O)C=C DPBJAVGHACCNRL-UHFFFAOYSA-N 0.000 description 1
- 235000008733 Citrus aurantifolia Nutrition 0.000 description 1
- 241000196324 Embryophyta Species 0.000 description 1
- CERQOIWHTDAKMF-UHFFFAOYSA-N Methacrylic acid Chemical class CC(=C)C(O)=O CERQOIWHTDAKMF-UHFFFAOYSA-N 0.000 description 1
- DWAQJAXMDSEUJJ-UHFFFAOYSA-M Sodium bisulfite Chemical compound [Na+].OS([O-])=O DWAQJAXMDSEUJJ-UHFFFAOYSA-M 0.000 description 1
- 235000011941 Tilia x europaea Nutrition 0.000 description 1
- 238000005054 agglomeration Methods 0.000 description 1
- 230000002776 aggregation Effects 0.000 description 1
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 1
- 229920003118 cationic copolymer Polymers 0.000 description 1
- 229920006317 cationic polymer Polymers 0.000 description 1
- 239000007795 chemical reaction product Substances 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- 238000005352 clarification Methods 0.000 description 1
- 238000003776 cleavage reaction Methods 0.000 description 1
- VAYGXNSJCAHWJZ-UHFFFAOYSA-N dimethyl sulfate Chemical compound COS(=O)(=O)OC VAYGXNSJCAHWJZ-UHFFFAOYSA-N 0.000 description 1
- 238000001035 drying Methods 0.000 description 1
- 125000004185 ester group Chemical group 0.000 description 1
- 238000010931 ester hydrolysis Methods 0.000 description 1
- 150000002148 esters Chemical class 0.000 description 1
- 238000002474 experimental method Methods 0.000 description 1
- 239000004744 fabric Substances 0.000 description 1
- 239000012065 filter cake Substances 0.000 description 1
- 238000001914 filtration Methods 0.000 description 1
- 229920001519 homopolymer Polymers 0.000 description 1
- 239000010842 industrial wastewater Substances 0.000 description 1
- 239000003999 initiator Substances 0.000 description 1
- 239000004571 lime Substances 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 125000005395 methacrylic acid group Chemical group 0.000 description 1
- 238000002156 mixing Methods 0.000 description 1
- 239000000203 mixture Substances 0.000 description 1
- 239000010841 municipal wastewater Substances 0.000 description 1
- ULDIVZQLPBUHAG-UHFFFAOYSA-N n',n',2,2-tetramethylpropane-1,3-diamine Chemical group CN(C)CC(C)(C)CN ULDIVZQLPBUHAG-UHFFFAOYSA-N 0.000 description 1
- DFENKTCEEGOWLB-UHFFFAOYSA-N n,n-bis(methylamino)-2-methylidenepentanamide Chemical compound CCCC(=C)C(=O)N(NC)NC DFENKTCEEGOWLB-UHFFFAOYSA-N 0.000 description 1
- 239000011368 organic material Substances 0.000 description 1
- 239000001301 oxygen Substances 0.000 description 1
- 229910052760 oxygen Inorganic materials 0.000 description 1
- 238000010526 radical polymerization reaction Methods 0.000 description 1
- 150000003839 salts Chemical class 0.000 description 1
- 230000007017 scission Effects 0.000 description 1
- 235000010267 sodium hydrogen sulphite Nutrition 0.000 description 1
- 230000006641 stabilisation Effects 0.000 description 1
- 238000011105 stabilization Methods 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 230000000007 visual effect Effects 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F220/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride ester, amide, imide or nitrile thereof
- C08F220/02—Monocarboxylic acids having less than ten carbon atoms; Derivatives thereof
- C08F220/52—Amides or imides
- C08F220/54—Amides, e.g. N,N-dimethylacrylamide or N-isopropylacrylamide
- C08F220/56—Acrylamide; Methacrylamide
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F1/00—Treatment of water, waste water, or sewage
- C02F1/52—Treatment of water, waste water, or sewage by flocculation or precipitation of suspended impurities
- C02F1/54—Treatment of water, waste water, or sewage by flocculation or precipitation of suspended impurities using organic material
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Environmental & Geological Engineering (AREA)
- Life Sciences & Earth Sciences (AREA)
- Water Supply & Treatment (AREA)
- Engineering & Computer Science (AREA)
- Hydrology & Water Resources (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Separation Of Suspended Particles By Flocculating Agents (AREA)
- Treatment Of Sludge (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
Priority Applications (9)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DE19853544909 DE3544909A1 (de) | 1985-12-19 | 1985-12-19 | Copolymere aus acrylamid und dimethylaminopropylacrylamid als flockungsmittel und verfahren zum entwaessern von klaerschlaemmen unter verwendung dieser flockungsmittel |
| AT86117354T ATE53597T1 (de) | 1985-12-19 | 1986-12-12 | Copolymere aus acrylamid und dimethylaminopropylacrylamid als flockungsmittel und verfahren zum entwaessern von klaerschlaemmen unter verwendung dieser flockungsmittel. |
| EP86117354A EP0228637B1 (de) | 1985-12-19 | 1986-12-12 | Copolymere aus Acrylamid und Dimethylaminopropylacrylamid als Flockungsmittel und Verfahren zum Entwässern von Klärschlämmen unter Verwendung dieser Flockungsmittel |
| DE8686117354T DE3671900D1 (de) | 1985-12-19 | 1986-12-12 | Copolymere aus acrylamid und dimethylaminopropylacrylamid als flockungsmittel und verfahren zum entwaessern von klaerschlaemmen unter verwendung dieser flockungsmittel. |
| CA000525473A CA1286448C (en) | 1985-12-19 | 1986-12-16 | Flocculating agents based upon copolymers of acrylamide and dimethylaminopropylacrylamide for use in dewatering sludge |
| AU66576/86A AU584765B2 (en) | 1985-12-19 | 1986-12-16 | Copolymer of acrylamide and dimethylaminopropylacrylamide as flocculating agents and process for dewatering sludge by use of these flocculating agents. |
| JP61299053A JPH0763720B2 (ja) | 1985-12-19 | 1986-12-17 | 水溶性粉末状凝集剤及びこの凝集剤を使用する下水汚泥の脱水方法 |
| US08/120,707 US5512646A (en) | 1985-12-19 | 1993-09-13 | Water soluble powdered cationic polyelectrolyte comprising a copolymer of acrylamide and dimethylaminopropylacrylamide essentially free of bifunctional compounds |
| US08/863,999 US6228964B1 (en) | 1985-12-19 | 1997-05-27 | Water soluble, powdered, cationic polyelectrolyte comprising a copolymer of acrylamide and dimethylaminopropylacrylamide essentially free of bifunctional compounds |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DE19853544909 DE3544909A1 (de) | 1985-12-19 | 1985-12-19 | Copolymere aus acrylamid und dimethylaminopropylacrylamid als flockungsmittel und verfahren zum entwaessern von klaerschlaemmen unter verwendung dieser flockungsmittel |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| DE3544909A1 DE3544909A1 (de) | 1987-06-25 |
| DE3544909C2 true DE3544909C2 (en, 2012) | 1991-10-24 |
Family
ID=6288833
Family Applications (2)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| DE19853544909 Granted DE3544909A1 (de) | 1985-12-19 | 1985-12-19 | Copolymere aus acrylamid und dimethylaminopropylacrylamid als flockungsmittel und verfahren zum entwaessern von klaerschlaemmen unter verwendung dieser flockungsmittel |
| DE8686117354T Expired - Lifetime DE3671900D1 (de) | 1985-12-19 | 1986-12-12 | Copolymere aus acrylamid und dimethylaminopropylacrylamid als flockungsmittel und verfahren zum entwaessern von klaerschlaemmen unter verwendung dieser flockungsmittel. |
Family Applications After (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| DE8686117354T Expired - Lifetime DE3671900D1 (de) | 1985-12-19 | 1986-12-12 | Copolymere aus acrylamid und dimethylaminopropylacrylamid als flockungsmittel und verfahren zum entwaessern von klaerschlaemmen unter verwendung dieser flockungsmittel. |
Country Status (7)
| Country | Link |
|---|---|
| US (2) | US5512646A (en, 2012) |
| EP (1) | EP0228637B1 (en, 2012) |
| JP (1) | JPH0763720B2 (en, 2012) |
| AT (1) | ATE53597T1 (en, 2012) |
| AU (1) | AU584765B2 (en, 2012) |
| CA (1) | CA1286448C (en, 2012) |
| DE (2) | DE3544909A1 (en, 2012) |
Families Citing this family (21)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS63234007A (ja) * | 1987-03-23 | 1988-09-29 | Kohjin Co Ltd | 水溶性が良好なカチオン性重合体 |
| DE3905049A1 (de) * | 1989-02-18 | 1990-08-23 | Stockhausen Chem Fab Gmbh | Verfahren zur stoerstoffixierung bei der papierherstellung |
| US4981936A (en) * | 1989-04-14 | 1991-01-01 | Polypure, Inc. | Terpolymer of oxyalkyene acrylates, acrylamides and quaternary monomers |
| DE10119685A1 (de) * | 2001-04-20 | 2002-10-24 | Stockhausen Chem Fab Gmbh | Entfernung nicht-wasserlöslicher Substanzen aus Metallaufschlüssen |
| DE10333478A1 (de) | 2003-07-22 | 2005-03-10 | Stockhausen Chem Fab Gmbh | Verfahren zur Behandlung von wässrigem Schlamm, danach hergestelltes Material und dessen Verwendung |
| DE10337763A1 (de) * | 2003-08-14 | 2005-03-17 | Stockhausen Gmbh | Pulverförmige, wasserlösliche kationische Polymerzusammensetzung, Verfahren zu ihrer Herstellung und ihre Verwendung |
| DE10337764A1 (de) * | 2003-08-14 | 2005-03-17 | Stockhausen Gmbh | Pulverförmige, wasserlösliche kationische Polymerzusammensetzung, Verfahren zu ihrer Herstellung und ihre Verwendung |
| CN100528951C (zh) * | 2003-12-15 | 2009-08-19 | 吸收剂科技有限公司 | 一种含有具生物活性的促生长添加剂的超吸收聚合物产品的制造和使用方法 |
| US7425595B2 (en) * | 2003-12-15 | 2008-09-16 | Absorbent Technologies, Inc. | Superabsorbent polymer products including a beneficial additive and methods of making and application |
| US20050261399A1 (en) * | 2004-05-19 | 2005-11-24 | David Hunkeler | Powdered flocculants prepared by using evaporative cooling to coat polymeric materials on a porous substrate |
| EP1781709A4 (en) * | 2004-08-27 | 2011-07-06 | Absorbent Technologies Inc | SUPER ABSORBING POLYMERS IN AGRICULTURAL APPLICATIONS |
| US20070167330A1 (en) * | 2006-01-17 | 2007-07-19 | Savich Milan H | Superabsorbent polymer applicator |
| US20070163172A1 (en) * | 2006-01-17 | 2007-07-19 | Savich Milan H | Biodegradable mat containing superabsorbent polymers |
| US7607259B2 (en) * | 2006-01-17 | 2009-10-27 | Absorbent Technologies, Inc. | Superabsorbent polymer root dip |
| US8343469B2 (en) | 2009-07-02 | 2013-01-01 | Hercules Incorporated | Cationic synthetic polymers with improved solubility and performance in surfactant-based systems and use in personal care and household applications |
| US8568701B2 (en) | 2009-07-02 | 2013-10-29 | Hercules Incorporated | Cationic synthetic polymers with improved solubility and performance in phosphate surfactant-based systems and use in personal care and household applications |
| DE102010019375A1 (de) * | 2010-05-04 | 2011-11-10 | Crenox Gmbh | Flockungshilfsmittel für die Titandioxidherstellung |
| US9596801B2 (en) | 2010-10-25 | 2017-03-21 | Vjs Investments Limited | Superabsorbent polymer seed coatings and associated methods |
| US11730193B2 (en) | 2019-12-15 | 2023-08-22 | Shaheen Innovations Holding Limited | Hookah device |
| CN111392806B (zh) * | 2020-03-24 | 2022-11-08 | 山东鑫泰水处理技术股份有限公司 | 一种印染废水复合脱色剂及其制备方法 |
| CN112940178B (zh) * | 2021-02-03 | 2022-10-14 | 中国海洋石油集团有限公司 | 一种可降解清水剂的应用 |
Family Cites Families (19)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3014896A (en) * | 1956-10-17 | 1961-12-26 | Union Carbide Corp | Polymeric flocculating agents and process for the production thereof |
| US3661868A (en) * | 1970-05-01 | 1972-05-09 | Dow Chemical Co | Flocculant |
| JPS529093A (en) * | 1975-07-10 | 1977-01-24 | Sumitomo Chem Co Ltd | Preparation of water-soluble cationic high-polymer |
| FR2471391A1 (fr) * | 1979-12-14 | 1981-06-19 | Hoechst France | Polyelectrolytes cationiques forts, en poudre, a base d'acrylamide et d'acrylate de dimethylaminoethyle quaternise ou salifie et leur utilisation pour la floculation des suspensions de matieres solides et la coalescence des emulsions |
| FR2390983A1 (fr) * | 1977-05-16 | 1978-12-15 | Hoechst France | Polyelectrolytes cationiques en poudre, a base d'acrylamide et d'acrylate de dimethyl-aminoethyle quaternise ou salifie, leur procede d'obtention et leur utilisation |
| DE2848627C2 (de) * | 1978-11-09 | 1982-02-04 | Röhm GmbH, 6100 Darmstadt | Verfahren zur Herstellung eines flüssigen, unmittelbar polymerisierbaren Gemisches aus Acrylamid und Quaternierungsprodukten von tertiären Aminoalkylestern oder tertiären Aminoalkylamiden der Acryl- oder Methacrylsäure |
| JPS5571703A (en) * | 1978-11-25 | 1980-05-30 | Sanyo Chem Ind Ltd | Preparation of water-soluble particulate polymer |
| EP0038573B1 (de) * | 1978-12-27 | 1985-09-04 | Chemische Fabrik Stockhausen GmbH | Polymerisate von alpha,beta-ungesättigten N-substituierten Carbonsäureamiden und ihre Verwendung als Sedimentations-, Flockungs-, Entwässerungs- und Retentionshilfsmittel |
| JPS5681315A (en) * | 1979-12-07 | 1981-07-03 | Mitsubishi Chem Ind Ltd | Production of water-soluble bead polymer |
| US4297256A (en) * | 1979-12-26 | 1981-10-27 | The Dow Chemical Company | Preparation of water-immiscible, acid-soluble N-(aminomethyl)-α,.beta. |
| JPS5849410A (ja) * | 1981-09-19 | 1983-03-23 | Sanyo Chem Ind Ltd | カチオン性高分子凝集剤 |
| JPS5924708A (ja) * | 1982-08-02 | 1984-02-08 | Kohjin Co Ltd | アクリルアミド系カチオン性重合体の製造方法 |
| JPS59135212A (ja) * | 1983-01-24 | 1984-08-03 | Nitto Chem Ind Co Ltd | カチオン性重合体の製造方法 |
| JPS59193911A (ja) * | 1983-04-18 | 1984-11-02 | Kohjin Co Ltd | 高吸収性高分子物質 |
| DE3327600A1 (de) * | 1983-07-30 | 1985-02-14 | Sandoz-Patent-GmbH, 7850 Lörrach | Copolymerisat- und tensidhaltige praeparate, deren herstellung und verwendung |
| JPS60210608A (ja) * | 1984-04-04 | 1985-10-23 | Mitsui Toatsu Chem Inc | 水溶性高分子量重合体粉末の製造方法 |
| JPH0794502B2 (ja) * | 1984-05-15 | 1995-10-11 | 三井東圧化学株式会社 | 水溶性高分子量重合体粉末の製造方法 |
| GB8512937D0 (en) * | 1985-05-22 | 1985-06-26 | Allied Colloids Ltd | Water treatment |
| DE3624813A1 (de) * | 1986-07-23 | 1988-03-10 | Stockhausen Chem Fab Gmbh | Amphotere wasserloesliche polymere, verfahren zu ihrer herstellung und ihre verwendung als dispergierhilfsmittel |
-
1985
- 1985-12-19 DE DE19853544909 patent/DE3544909A1/de active Granted
-
1986
- 1986-12-12 DE DE8686117354T patent/DE3671900D1/de not_active Expired - Lifetime
- 1986-12-12 EP EP86117354A patent/EP0228637B1/de not_active Expired - Lifetime
- 1986-12-12 AT AT86117354T patent/ATE53597T1/de not_active IP Right Cessation
- 1986-12-16 AU AU66576/86A patent/AU584765B2/en not_active Ceased
- 1986-12-16 CA CA000525473A patent/CA1286448C/en not_active Expired - Lifetime
- 1986-12-17 JP JP61299053A patent/JPH0763720B2/ja not_active Expired - Lifetime
-
1993
- 1993-09-13 US US08/120,707 patent/US5512646A/en not_active Expired - Lifetime
-
1997
- 1997-05-27 US US08/863,999 patent/US6228964B1/en not_active Expired - Fee Related
Also Published As
| Publication number | Publication date |
|---|---|
| EP0228637A3 (en) | 1987-09-23 |
| AU584765B2 (en) | 1989-06-01 |
| US6228964B1 (en) | 2001-05-08 |
| DE3544909A1 (de) | 1987-06-25 |
| EP0228637B1 (de) | 1990-06-13 |
| ATE53597T1 (de) | 1990-06-15 |
| CA1286448C (en) | 1991-07-16 |
| DE3671900D1 (de) | 1990-07-19 |
| EP0228637A2 (de) | 1987-07-15 |
| JPS62201915A (ja) | 1987-09-05 |
| JPH0763720B2 (ja) | 1995-07-12 |
| AU6657686A (en) | 1987-06-25 |
| US5512646A (en) | 1996-04-30 |
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