DE3230424C2 - - Google Patents
Info
- Publication number
- DE3230424C2 DE3230424C2 DE3230424A DE3230424A DE3230424C2 DE 3230424 C2 DE3230424 C2 DE 3230424C2 DE 3230424 A DE3230424 A DE 3230424A DE 3230424 A DE3230424 A DE 3230424A DE 3230424 C2 DE3230424 C2 DE 3230424C2
- Authority
- DE
- Germany
- Prior art keywords
- resin composition
- vinyl chloride
- glycerol
- thermoplastic resin
- composition according
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerol Natural products OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 claims description 64
- 235000011187 glycerol Nutrition 0.000 claims description 26
- BZHJMEDXRYGGRV-UHFFFAOYSA-N Vinyl chloride Chemical compound ClC=C BZHJMEDXRYGGRV-UHFFFAOYSA-N 0.000 claims description 25
- 239000011342 resin composition Substances 0.000 claims description 22
- 125000002252 acyl group Chemical group 0.000 claims description 21
- 239000004014 plasticizer Substances 0.000 claims description 19
- 125000004432 carbon atom Chemical group C* 0.000 claims description 15
- -1 glycerin ester Chemical class 0.000 claims description 15
- 229920001577 copolymer Polymers 0.000 claims description 11
- 235000014113 dietary fatty acids Nutrition 0.000 claims description 11
- 229930195729 fatty acid Natural products 0.000 claims description 11
- 239000000194 fatty acid Substances 0.000 claims description 11
- 229920005992 thermoplastic resin Polymers 0.000 claims description 10
- 229920000642 polymer Polymers 0.000 claims description 6
- KAKZBPTYRLMSJV-UHFFFAOYSA-N Butadiene Chemical compound C=CC=C KAKZBPTYRLMSJV-UHFFFAOYSA-N 0.000 claims description 4
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 claims description 4
- 239000005977 Ethylene Substances 0.000 claims description 4
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 claims description 4
- 229920001038 ethylene copolymer Polymers 0.000 claims description 4
- 125000002887 hydroxy group Chemical group [H]O* 0.000 claims description 4
- 125000004435 hydrogen atom Chemical class [H]* 0.000 claims description 3
- 239000003921 oil Substances 0.000 claims description 3
- NLHHRLWOUZZQLW-UHFFFAOYSA-N Acrylonitrile Chemical compound C=CC#N NLHHRLWOUZZQLW-UHFFFAOYSA-N 0.000 claims description 2
- 150000002314 glycerols Chemical class 0.000 claims description 2
- 125000005395 methacrylic acid group Chemical group 0.000 claims description 2
- 229920002959 polymer blend Polymers 0.000 claims description 2
- 229920000098 polyolefin Polymers 0.000 claims description 2
- 229910052799 carbon Inorganic materials 0.000 claims 1
- 235000019864 coconut oil Nutrition 0.000 claims 1
- 239000003240 coconut oil Substances 0.000 claims 1
- 229910052739 hydrogen Inorganic materials 0.000 claims 1
- 239000001257 hydrogen Substances 0.000 claims 1
- 238000002156 mixing Methods 0.000 claims 1
- 235000019198 oils Nutrition 0.000 claims 1
- 239000000203 mixture Substances 0.000 description 13
- 150000004665 fatty acids Chemical group 0.000 description 10
- QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical compound CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 description 9
- 229920005989 resin Polymers 0.000 description 7
- 239000011347 resin Substances 0.000 description 7
- MQIUGAXCHLFZKX-UHFFFAOYSA-N Di-n-octyl phthalate Natural products CCCCCCCCOC(=O)C1=CC=CC=C1C(=O)OCCCCCCCC MQIUGAXCHLFZKX-UHFFFAOYSA-N 0.000 description 6
- WFDIJRYMOXRFFG-UHFFFAOYSA-N acetic acid anhydride Natural products CC(=O)OC(C)=O WFDIJRYMOXRFFG-UHFFFAOYSA-N 0.000 description 6
- BJQHLKABXJIVAM-UHFFFAOYSA-N bis(2-ethylhexyl) phthalate Chemical compound CCCCC(CC)COC(=O)C1=CC=CC=C1C(=O)OCC(CC)CCCC BJQHLKABXJIVAM-UHFFFAOYSA-N 0.000 description 6
- ZFMQKOWCDKKBIF-UHFFFAOYSA-N bis(3,5-difluorophenyl)phosphane Chemical compound FC1=CC(F)=CC(PC=2C=C(F)C=C(F)C=2)=C1 ZFMQKOWCDKKBIF-UHFFFAOYSA-N 0.000 description 6
- 239000004800 polyvinyl chloride Substances 0.000 description 6
- 229920000915 polyvinyl chloride Polymers 0.000 description 6
- 230000007423 decrease Effects 0.000 description 5
- 238000011156 evaluation Methods 0.000 description 5
- 235000013162 Cocos nucifera Nutrition 0.000 description 4
- 244000060011 Cocos nucifera Species 0.000 description 4
- 239000003381 stabilizer Substances 0.000 description 4
- 238000010998 test method Methods 0.000 description 4
- URAYPUMNDPQOKB-UHFFFAOYSA-N triacetin Chemical compound CC(=O)OCC(OC(C)=O)COC(C)=O URAYPUMNDPQOKB-UHFFFAOYSA-N 0.000 description 4
- 230000000740 bleeding effect Effects 0.000 description 3
- 230000000052 comparative effect Effects 0.000 description 3
- YIWUKEYIRIRTPP-UHFFFAOYSA-N 2-ethylhexan-1-ol Chemical compound CCCCC(CC)CO YIWUKEYIRIRTPP-UHFFFAOYSA-N 0.000 description 2
- CSCPPACGZOOCGX-UHFFFAOYSA-N Acetone Chemical compound CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 description 2
- 150000002148 esters Chemical class 0.000 description 2
- 235000013773 glyceryl triacetate Nutrition 0.000 description 2
- 238000000465 moulding Methods 0.000 description 2
- 231100000252 nontoxic Toxicity 0.000 description 2
- 230000003000 nontoxic effect Effects 0.000 description 2
- 229960002622 triacetin Drugs 0.000 description 2
- 229920006163 vinyl copolymer Polymers 0.000 description 2
- LDVVTQMJQSCDMK-UHFFFAOYSA-N 1,3-dihydroxypropan-2-yl formate Chemical compound OCC(CO)OC=O LDVVTQMJQSCDMK-UHFFFAOYSA-N 0.000 description 1
- OEPOKWHJYJXUGD-UHFFFAOYSA-N 2-(3-phenylmethoxyphenyl)-1,3-thiazole-4-carbaldehyde Chemical compound O=CC1=CSC(C=2C=C(OCC=3C=CC=CC=3)C=CC=2)=N1 OEPOKWHJYJXUGD-UHFFFAOYSA-N 0.000 description 1
- 229920003171 Poly (ethylene oxide) Polymers 0.000 description 1
- 239000004698 Polyethylene Substances 0.000 description 1
- LWZFANDGMFTDAV-BURFUSLBSA-N [(2r)-2-[(2r,3r,4s)-3,4-dihydroxyoxolan-2-yl]-2-hydroxyethyl] dodecanoate Chemical compound CCCCCCCCCCCC(=O)OC[C@@H](O)[C@H]1OC[C@H](O)[C@H]1O LWZFANDGMFTDAV-BURFUSLBSA-N 0.000 description 1
- 230000021736 acetylation Effects 0.000 description 1
- 238000006640 acetylation reaction Methods 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 150000007513 acids Chemical class 0.000 description 1
- 229920000122 acrylonitrile butadiene styrene Polymers 0.000 description 1
- 150000005215 alkyl ethers Chemical class 0.000 description 1
- VBICKXHEKHSIBG-UHFFFAOYSA-N beta-monoglyceryl stearate Natural products CCCCCCCCCCCCCCCCCC(=O)OCC(O)CO VBICKXHEKHSIBG-UHFFFAOYSA-N 0.000 description 1
- 239000002738 chelating agent Substances 0.000 description 1
- 238000005253 cladding Methods 0.000 description 1
- 238000004140 cleaning Methods 0.000 description 1
- 238000000748 compression moulding Methods 0.000 description 1
- 238000001125 extrusion Methods 0.000 description 1
- 235000013305 food Nutrition 0.000 description 1
- 235000013373 food additive Nutrition 0.000 description 1
- 239000002778 food additive Substances 0.000 description 1
- 239000011521 glass Substances 0.000 description 1
- 230000005802 health problem Effects 0.000 description 1
- 230000002452 interceptive effect Effects 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 239000000314 lubricant Substances 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 1
- 239000012785 packaging film Substances 0.000 description 1
- 229920006280 packaging film Polymers 0.000 description 1
- 239000005022 packaging material Substances 0.000 description 1
- XNGIFLGASWRNHJ-UHFFFAOYSA-L phthalate(2-) Chemical compound [O-]C(=O)C1=CC=CC=C1C([O-])=O XNGIFLGASWRNHJ-UHFFFAOYSA-L 0.000 description 1
- 229920003023 plastic Polymers 0.000 description 1
- 239000004033 plastic Substances 0.000 description 1
- 229920000573 polyethylene Polymers 0.000 description 1
- 229950006451 sorbitan laurate Drugs 0.000 description 1
- 235000011067 sorbitan monolaureate Nutrition 0.000 description 1
- 229920001169 thermoplastic Polymers 0.000 description 1
- 239000004416 thermosoftening plastic Substances 0.000 description 1
- 238000005809 transesterification reaction Methods 0.000 description 1
- 150000003626 triacylglycerols Chemical class 0.000 description 1
- 230000004580 weight loss Effects 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/04—Oxygen-containing compounds
- C08K5/10—Esters; Ether-esters
- C08K5/101—Esters; Ether-esters of monocarboxylic acids
- C08K5/103—Esters; Ether-esters of monocarboxylic acids with polyalcohols
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Compositions Of Macromolecular Compounds (AREA)
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP56131236A JPS5832647A (ja) | 1981-08-21 | 1981-08-21 | 熱可塑性樹脂組成物 |
Publications (3)
| Publication Number | Publication Date |
|---|---|
| DE3230424A1 DE3230424A1 (de) | 1983-03-10 |
| DE3230424C2 true DE3230424C2 (en:Method) | 1992-05-07 |
| DE3230424C3 DE3230424C3 (de) | 1998-06-18 |
Family
ID=15053185
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| DE3230424A Expired - Lifetime DE3230424C3 (de) | 1981-08-21 | 1982-08-16 | Thermoplastische Harzmasse |
Country Status (4)
| Country | Link |
|---|---|
| US (1) | US4426477A (en:Method) |
| JP (1) | JPS5832647A (en:Method) |
| DE (1) | DE3230424C3 (en:Method) |
| FR (1) | FR2511693B1 (en:Method) |
Families Citing this family (49)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS6035040A (ja) * | 1983-08-05 | 1985-02-22 | Riken Vitamin Co Ltd | メチルセルロ−ス皮膜あるいはフイルムの改質方法 |
| JPS6035039A (ja) * | 1983-08-05 | 1985-02-22 | Riken Vitamin Co Ltd | カルボキシメチルセルロ−スナトリウム皮膜あるいはフイルムの改質方法 |
| JPS60112847A (ja) * | 1983-11-25 | 1985-06-19 | Asahi Chem Ind Co Ltd | 塩化ビニリデン系樹脂組成物 |
| DE3571992D1 (en) * | 1984-04-17 | 1989-09-07 | Ici Plc | Treatment of aqueous suspensions of vinyl chloride polymers |
| US4686148A (en) * | 1985-07-15 | 1987-08-11 | W. R. Grace & Co., Cryovac Div. | Vinylidene chloride composition and film made therefrom |
| US5248531A (en) * | 1987-01-13 | 1993-09-28 | Terumo Kabushiki Kaisha | Hemolysis depressant and plasticizer |
| JPS63175056A (ja) * | 1987-01-13 | 1988-07-19 | Terumo Corp | 塩化ビニル系樹脂用可塑剤 |
| EP0537863B1 (en) * | 1987-01-13 | 1997-07-02 | Terumo Kabushiki Kaisha | Use of a triglyceride compound as a hemolysis depressant |
| US4843117A (en) * | 1987-02-17 | 1989-06-27 | The Dow Chemical Company | Dimethyl sulfone as a solid solvent for vinylidene chloride containing polymers |
| JPS6485660A (en) * | 1987-02-19 | 1989-03-30 | Nippon Medical Supply | Suture coated with sugar fatty acid ester |
| US6291565B1 (en) | 1994-05-19 | 2001-09-18 | The Dow Chemical Company | Food packaging film |
| US5969026A (en) * | 1997-06-26 | 1999-10-19 | Techmer Pm | Wettable polymer fibers |
| DE60006227T2 (de) * | 1999-05-21 | 2004-08-05 | 3M Innovative Properties Co., Saint Paul | Antimikrobielle gegenstände |
| US6762339B1 (en) | 1999-05-21 | 2004-07-13 | 3M Innovative Properties Company | Hydrophilic polypropylene fibers having antimicrobial activity |
| WO2001000722A1 (en) * | 1999-06-30 | 2001-01-04 | Perstorp Ab | Plasticiser for polymeric compositions |
| US6949597B2 (en) * | 1999-08-19 | 2005-09-27 | Danisco A/S | Composition |
| GB9919683D0 (en) * | 1999-08-19 | 1999-10-20 | Danisco | Composition |
| WO2001014466A1 (en) * | 1999-08-19 | 2001-03-01 | Danisco A/S | Specific acylated gylcerol compounds for plasticisers in polymers |
| US6734242B2 (en) * | 2000-08-18 | 2004-05-11 | Danisco A/S | Composition |
| DE102004031325A1 (de) * | 2004-06-29 | 2006-01-19 | Bayer Healthcare Ag | Wirkstoffhaltige feste Formkörper zur äußerlichen Anwendung gegen Parasiten an Tieren |
| GB0700076D0 (en) * | 2007-01-03 | 2007-02-07 | Danisco | Compound |
| JP4800242B2 (ja) * | 2007-03-06 | 2011-10-26 | 三菱樹脂株式会社 | 積層ストレッチフィルムおよびその製造方法 |
| WO2009102877A1 (en) | 2008-02-15 | 2009-08-20 | Union Carbide Chemicals & Plastics Technology Llc (Formerly Union Carbide Chemicals & Plastics Technology Corporation) | A replacement plasticizer system for phthalate-plasticized formulations |
| KR20100031391A (ko) * | 2008-09-12 | 2010-03-22 | 에스케이에너지 주식회사 | 가소제 및 이를 포함한 폴리염화비닐 수지 조성물 |
| JP5230349B2 (ja) * | 2008-10-21 | 2013-07-10 | オカモト株式会社 | 塩化ビニル系樹脂ストレッチフィルム |
| MX2011010163A (es) | 2009-03-27 | 2011-10-10 | 3M Innovative Properties Co | Aditivos de fusion de polipropileno hidrofilico. |
| GB0914572D0 (en) | 2009-08-20 | 2009-09-30 | Danisco | Process |
| US8552098B2 (en) * | 2009-09-30 | 2013-10-08 | Dow Global Technologies Llc | Purified acetylated derivatives of castor oil and compositions including same |
| WO2011041363A1 (en) * | 2009-09-30 | 2011-04-07 | Dow Global Technologies Llc | Acetylated glycerin esters and their blends with epoxidized fatty acid esters |
| CN102630243B (zh) | 2009-09-30 | 2015-02-18 | 陶氏环球技术有限责任公司 | 乙酰基化的12-羟基硬脂酸的甘油酯及其与脂肪酸酯的共混物 |
| WO2011041380A1 (en) | 2009-09-30 | 2011-04-07 | Dow Global Technologies Llc | Acetylated derivatives of castor oil and their blends with epoxidized fatty acid esters |
| CN102791788B (zh) | 2009-09-30 | 2014-09-24 | 陶氏环球技术有限责任公司 | 具有环氧化脂肪酸酯增塑剂的热稳定聚合物组合物 |
| KR101773606B1 (ko) * | 2010-05-04 | 2017-09-12 | 에스케이이노베이션 주식회사 | 가소제 및 이의 제조방법 |
| MX2012013102A (es) | 2010-05-10 | 2012-12-17 | Dow Global Technologies Llc | Composiciones de pvc flexibles con plastificantes derivados de fuentes renovables. |
| TW201209168A (en) | 2010-07-28 | 2012-03-01 | Dow Global Technologies Llc | Plasticizers made from oil extracted from microorganisms and polar polymeric compositions comprising the same |
| MX357165B (es) | 2012-02-08 | 2018-06-28 | Dow Global Technologies Llc | Composiciones de plastificante y metodos para fabricar composiciones de plastificante. |
| US9371445B2 (en) * | 2012-03-30 | 2016-06-21 | Kaneka Corporation | Biodegradable polyester resin composition |
| US9394425B2 (en) | 2012-06-22 | 2016-07-19 | Dow Global Technologies Llc | Acetylated polyol hydroxystearate plasticizers and plasticized polymeric compositions |
| WO2014003892A2 (en) | 2012-06-26 | 2014-01-03 | Dow Global Technologies Llc | Plasticizers and plasticized polymeric compositions |
| WO2014061026A1 (en) | 2012-10-18 | 2014-04-24 | Dow Global Technologies Llc | Epoxidized fatty acid alkyl ester plasticizers and methods for making epoxidized fatty acid alkyl ester plasticizers |
| MX378691B (es) | 2012-11-12 | 2025-03-11 | Dow Global Technologies Llc | Plastificantes de ester de alquilo de acido graso epoxidado y metodos para fabricar plastificantes de ester de alquilo de acido graso epoxidado. |
| JP6189967B2 (ja) | 2012-11-12 | 2017-08-30 | ダウ グローバル テクノロジーズ エルエルシー | エポキシ化脂肪酸アルキルエステルを作製するための方法 |
| JP6178658B2 (ja) * | 2013-08-08 | 2017-08-09 | リケンテクノス株式会社 | 医療用放射線滅菌対応塩化ビニル樹脂組成物およびそれからなる医療用器具 |
| JP6148570B2 (ja) * | 2013-08-08 | 2017-06-14 | リケンテクノス株式会社 | 医療用放射線滅菌対応塩化ビニル樹脂組成物およびそれからなる医療用器具 |
| ES2651449T3 (es) | 2013-08-09 | 2018-01-26 | Silgan Holdings Inc. | Composición polimérica con terminación de cadena, uso de la misma y procedimiento de preparación |
| EP3259311A4 (en) * | 2015-02-19 | 2018-12-12 | Fine Organic Industries Private Limited | A bio based plasticizer with improved properties and processing characteristics of polymer |
| WO2018193462A2 (en) * | 2017-04-19 | 2018-10-25 | Fine Organic Industries Ltd. | A glycerol derivative for polymer applications |
| KR102236924B1 (ko) * | 2017-12-04 | 2021-04-07 | 주식회사 엘지화학 | 가소제 조성물 및 이를 포함하는 수지 조성물 |
| WO2023054207A1 (ja) * | 2021-09-30 | 2023-04-06 | 日本ゼオン株式会社 | 塩化ビニル樹脂組成物、塩化ビニル樹脂成形体および積層体 |
Family Cites Families (14)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US2633456A (en) | 1949-01-17 | 1953-03-31 | Wingfoot Corp | Plastic film |
| FR1060166A (fr) * | 1952-07-04 | 1954-03-31 | Pechiney | Plastifiant obtenu à partir de l'huile de ricin |
| US3390115A (en) | 1964-12-29 | 1968-06-25 | Eastman Kodak Co | Polyvinyl chloride adhesive compositions |
| US3578621A (en) | 1968-08-27 | 1971-05-11 | Carlisle Chemical Works | Diesters exhibiting internal-external lubricating properties in structural resins |
| US4072790A (en) | 1974-12-17 | 1978-02-07 | The Goodyear Tire & Rubber Company | Extrudable compounded polyvinyl chloride |
| JPS5423378B2 (en:Method) | 1975-01-31 | 1979-08-13 | ||
| JPS5364297A (en) | 1976-11-19 | 1978-06-08 | Kureha Chem Ind Co Ltd | Modified vinylidene chloride type polymer composition |
| JPS5456647A (en) * | 1977-10-12 | 1979-05-07 | Hitachi Chem Co Ltd | Vinyl chloride resin composition |
| JPS5474847A (en) * | 1977-11-29 | 1979-06-15 | Riken Vitamin Co Ltd | Vinyl chloride resin film for food packaging |
| JPS6043861B2 (ja) * | 1977-12-22 | 1985-09-30 | 理研ビタミン油株式会社 | 防曇性のすぐれた塩化ビニル系樹脂組成物 |
| JPS553457A (en) * | 1978-06-23 | 1980-01-11 | C I Kasei Co Ltd | Method of controlling static electricity on rigid vinyl chloride resin |
| EP0010975B1 (en) * | 1978-11-06 | 1983-05-18 | TATE & LYLE PUBLIC LIMITED COMPANY | Gramophone record composition and gramophone records produced therefrom |
| JPS5620056A (en) * | 1979-07-30 | 1981-02-25 | Lion Corp | Antistatic resin composition with extremely improved blooming property |
| US4363891A (en) | 1981-05-14 | 1982-12-14 | Glyco Inc. | Glyceryl monostearate plastic lubricants |
-
1981
- 1981-08-21 JP JP56131236A patent/JPS5832647A/ja active Granted
-
1982
- 1982-08-13 US US06/407,805 patent/US4426477A/en not_active Expired - Lifetime
- 1982-08-16 DE DE3230424A patent/DE3230424C3/de not_active Expired - Lifetime
- 1982-08-23 FR FR8214446A patent/FR2511693B1/fr not_active Expired
Also Published As
| Publication number | Publication date |
|---|---|
| US4426477A (en) | 1984-01-17 |
| FR2511693B1 (fr) | 1986-03-07 |
| JPH0335331B2 (en:Method) | 1991-05-27 |
| DE3230424A1 (de) | 1983-03-10 |
| FR2511693A1 (fr) | 1983-02-25 |
| DE3230424C3 (de) | 1998-06-18 |
| JPS5832647A (ja) | 1983-02-25 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| 8110 | Request for examination paragraph 44 | ||
| D2 | Grant after examination | ||
| 8363 | Opposition against the patent | ||
| 8366 | Restricted maintained after opposition proceedings | ||
| 8305 | Restricted maintenance of patent after opposition | ||
| D4 | Patent maintained restricted | ||
| 8330 | Complete disclaimer |