DE3211047A1 - Vorzugsweise mit bindemittel angereicherte, zementierte carbidkoerper und verfahren zu ihrer herstellung - Google Patents
Vorzugsweise mit bindemittel angereicherte, zementierte carbidkoerper und verfahren zu ihrer herstellungInfo
- Publication number
- DE3211047A1 DE3211047A1 DE19823211047 DE3211047A DE3211047A1 DE 3211047 A1 DE3211047 A1 DE 3211047A1 DE 19823211047 DE19823211047 DE 19823211047 DE 3211047 A DE3211047 A DE 3211047A DE 3211047 A1 DE3211047 A1 DE 3211047A1
- Authority
- DE
- Germany
- Prior art keywords
- carbide
- cobalt
- cemented carbide
- layer
- binder
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 238000000034 method Methods 0.000 title claims description 35
- 238000004519 manufacturing process Methods 0.000 title claims description 10
- 229910017052 cobalt Inorganic materials 0.000 claims description 106
- 239000010941 cobalt Substances 0.000 claims description 106
- 239000010410 layer Substances 0.000 claims description 101
- GUTLYIVDDKVIGB-UHFFFAOYSA-N cobalt atom Chemical group [Co] GUTLYIVDDKVIGB-UHFFFAOYSA-N 0.000 claims description 100
- 239000011230 binding agent Substances 0.000 claims description 86
- 238000000576 coating method Methods 0.000 claims description 70
- 239000011248 coating agent Substances 0.000 claims description 63
- 229910045601 alloy Inorganic materials 0.000 claims description 57
- 239000000956 alloy Substances 0.000 claims description 57
- 238000005520 cutting process Methods 0.000 claims description 55
- 239000006104 solid solution Substances 0.000 claims description 47
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims description 35
- 229910052799 carbon Inorganic materials 0.000 claims description 34
- 239000000463 material Substances 0.000 claims description 33
- 150000001247 metal acetylides Chemical class 0.000 claims description 31
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 claims description 26
- 229910052721 tungsten Inorganic materials 0.000 claims description 26
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 claims description 24
- UONOETXJSWQNOL-UHFFFAOYSA-N tungsten carbide Chemical compound [W+]#[C-] UONOETXJSWQNOL-UHFFFAOYSA-N 0.000 claims description 24
- 229910052751 metal Inorganic materials 0.000 claims description 23
- 239000002184 metal Substances 0.000 claims description 23
- 239000000843 powder Substances 0.000 claims description 23
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 claims description 21
- WFKWXMTUELFFGS-UHFFFAOYSA-N tungsten Chemical compound [W] WFKWXMTUELFFGS-UHFFFAOYSA-N 0.000 claims description 21
- 239000010937 tungsten Substances 0.000 claims description 21
- 238000005245 sintering Methods 0.000 claims description 20
- 229910052720 vanadium Inorganic materials 0.000 claims description 20
- 238000002844 melting Methods 0.000 claims description 19
- 239000010936 titanium Substances 0.000 claims description 19
- 238000000227 grinding Methods 0.000 claims description 18
- 150000004767 nitrides Chemical class 0.000 claims description 18
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 claims description 17
- 238000010438 heat treatment Methods 0.000 claims description 17
- 229910052719 titanium Inorganic materials 0.000 claims description 17
- 239000001257 hydrogen Substances 0.000 claims description 16
- 229910052739 hydrogen Inorganic materials 0.000 claims description 16
- 210000000481 breast Anatomy 0.000 claims description 15
- 239000013043 chemical agent Substances 0.000 claims description 15
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 claims description 14
- 229910052757 nitrogen Inorganic materials 0.000 claims description 14
- 230000008569 process Effects 0.000 claims description 13
- 229910052723 transition metal Inorganic materials 0.000 claims description 13
- 150000004678 hydrides Chemical class 0.000 claims description 12
- 230000008018 melting Effects 0.000 claims description 12
- 150000003624 transition metals Chemical class 0.000 claims description 12
- 229910052759 nickel Inorganic materials 0.000 claims description 11
- MTPVUVINMAGMJL-UHFFFAOYSA-N trimethyl(1,1,2,2,2-pentafluoroethyl)silane Chemical compound C[Si](C)(C)C(F)(F)C(F)(F)F MTPVUVINMAGMJL-UHFFFAOYSA-N 0.000 claims description 11
- 230000015572 biosynthetic process Effects 0.000 claims description 10
- 229910052715 tantalum Inorganic materials 0.000 claims description 10
- GUVRBAGPIYLISA-UHFFFAOYSA-N tantalum atom Chemical compound [Ta] GUVRBAGPIYLISA-UHFFFAOYSA-N 0.000 claims description 10
- NRTOMJZYCJJWKI-UHFFFAOYSA-N Titanium nitride Chemical compound [Ti]#N NRTOMJZYCJJWKI-UHFFFAOYSA-N 0.000 claims description 9
- 239000000126 substance Substances 0.000 claims description 9
- 229910052742 iron Inorganic materials 0.000 claims description 7
- 229910052735 hafnium Inorganic materials 0.000 claims description 6
- VBJZVLUMGGDVMO-UHFFFAOYSA-N hafnium atom Chemical compound [Hf] VBJZVLUMGGDVMO-UHFFFAOYSA-N 0.000 claims description 6
- 239000010955 niobium Substances 0.000 claims description 6
- GUCVJGMIXFAOAE-UHFFFAOYSA-N niobium atom Chemical group [Nb] GUCVJGMIXFAOAE-UHFFFAOYSA-N 0.000 claims description 6
- QCWXUUIWCKQGHC-UHFFFAOYSA-N Zirconium Chemical compound [Zr] QCWXUUIWCKQGHC-UHFFFAOYSA-N 0.000 claims description 5
- 229910052782 aluminium Inorganic materials 0.000 claims description 5
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 claims description 5
- 238000002156 mixing Methods 0.000 claims description 5
- 229910052758 niobium Inorganic materials 0.000 claims description 5
- 239000000243 solution Substances 0.000 claims description 5
- LEONUFNNVUYDNQ-UHFFFAOYSA-N vanadium atom Chemical compound [V] LEONUFNNVUYDNQ-UHFFFAOYSA-N 0.000 claims description 5
- 229910052726 zirconium Inorganic materials 0.000 claims description 5
- 230000000737 periodic effect Effects 0.000 claims description 4
- JPNWDVUTVSTKMV-UHFFFAOYSA-N cobalt tungsten Chemical compound [Co].[W] JPNWDVUTVSTKMV-UHFFFAOYSA-N 0.000 claims description 3
- TWNQGVIAIRXVLR-UHFFFAOYSA-N oxo(oxoalumanyloxy)alumane Chemical compound O=[Al]O[Al]=O TWNQGVIAIRXVLR-UHFFFAOYSA-N 0.000 claims description 3
- -1 transition metal carbides Chemical class 0.000 claims description 2
- 238000009827 uniform distribution Methods 0.000 claims 3
- 238000009826 distribution Methods 0.000 claims 2
- 230000005496 eutectics Effects 0.000 claims 2
- 229910001092 metal group alloy Inorganic materials 0.000 claims 2
- AZDRQVAHHNSJOQ-UHFFFAOYSA-N alumane Chemical group [AlH3] AZDRQVAHHNSJOQ-UHFFFAOYSA-N 0.000 claims 1
- 239000011247 coating layer Substances 0.000 claims 1
- 150000002736 metal compounds Chemical class 0.000 claims 1
- 238000003825 pressing Methods 0.000 claims 1
- 239000000203 mixture Substances 0.000 description 48
- 239000000758 substrate Substances 0.000 description 31
- ATJFFYVFTNAWJD-UHFFFAOYSA-N Tin Chemical compound [Sn] ATJFFYVFTNAWJD-UHFFFAOYSA-N 0.000 description 24
- VNWKTOKETHGBQD-UHFFFAOYSA-N methane Chemical compound C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 description 20
- CYTYCFOTNPOANT-UHFFFAOYSA-N Perchloroethylene Chemical group ClC(Cl)=C(Cl)Cl CYTYCFOTNPOANT-UHFFFAOYSA-N 0.000 description 10
- 238000012360 testing method Methods 0.000 description 10
- 229950011008 tetrachloroethylene Drugs 0.000 description 10
- 238000007792 addition Methods 0.000 description 8
- 239000012298 atmosphere Substances 0.000 description 8
- 238000003801 milling Methods 0.000 description 8
- 239000002245 particle Substances 0.000 description 8
- 238000011156 evaluation Methods 0.000 description 7
- 238000005229 chemical vapour deposition Methods 0.000 description 6
- 238000001816 cooling Methods 0.000 description 6
- 229910000531 Co alloy Inorganic materials 0.000 description 5
- 239000003795 chemical substances by application Substances 0.000 description 4
- 229910002804 graphite Inorganic materials 0.000 description 4
- 239000010439 graphite Substances 0.000 description 4
- 239000012299 nitrogen atmosphere Substances 0.000 description 4
- 239000011148 porous material Substances 0.000 description 4
- 239000002904 solvent Substances 0.000 description 4
- XJDNKRIXUMDJCW-UHFFFAOYSA-J titanium tetrachloride Chemical compound Cl[Ti](Cl)(Cl)Cl XJDNKRIXUMDJCW-UHFFFAOYSA-J 0.000 description 4
- ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 description 3
- 238000009825 accumulation Methods 0.000 description 3
- 239000000654 additive Substances 0.000 description 3
- 238000004458 analytical method Methods 0.000 description 3
- 239000000460 chlorine Substances 0.000 description 3
- 229910052801 chlorine Inorganic materials 0.000 description 3
- 150000002739 metals Chemical class 0.000 description 3
- 239000004094 surface-active agent Substances 0.000 description 3
- XKRFYHLGVUSROY-UHFFFAOYSA-N Argon Chemical compound [Ar] XKRFYHLGVUSROY-UHFFFAOYSA-N 0.000 description 2
- 229910009043 WC-Co Inorganic materials 0.000 description 2
- 238000013459 approach Methods 0.000 description 2
- 239000012159 carrier gas Substances 0.000 description 2
- 230000008859 change Effects 0.000 description 2
- 210000000038 chest Anatomy 0.000 description 2
- 230000007423 decrease Effects 0.000 description 2
- 229910052734 helium Inorganic materials 0.000 description 2
- 238000001513 hot isostatic pressing Methods 0.000 description 2
- 230000001788 irregular Effects 0.000 description 2
- 239000012188 paraffin wax Substances 0.000 description 2
- 229920006395 saturated elastomer Polymers 0.000 description 2
- 239000007787 solid Substances 0.000 description 2
- 238000012982 x-ray structure analysis Methods 0.000 description 2
- KPZGRMZPZLOPBS-UHFFFAOYSA-N 1,3-dichloro-2,2-bis(chloromethyl)propane Chemical compound ClCC(CCl)(CCl)CCl KPZGRMZPZLOPBS-UHFFFAOYSA-N 0.000 description 1
- VZSRBBMJRBPUNF-UHFFFAOYSA-N 2-(2,3-dihydro-1H-inden-2-ylamino)-N-[3-oxo-3-(2,4,6,7-tetrahydrotriazolo[4,5-c]pyridin-5-yl)propyl]pyrimidine-5-carboxamide Chemical compound C1C(CC2=CC=CC=C12)NC1=NC=C(C=N1)C(=O)NCCC(N1CC2=C(CC1)NN=N2)=O VZSRBBMJRBPUNF-UHFFFAOYSA-N 0.000 description 1
- 229910018072 Al 2 O 3 Inorganic materials 0.000 description 1
- 229910001339 C alloy Inorganic materials 0.000 description 1
- 229910000640 Fe alloy Inorganic materials 0.000 description 1
- 229910000846 In alloy Inorganic materials 0.000 description 1
- 229910000990 Ni alloy Inorganic materials 0.000 description 1
- 229910010068 TiCl2 Inorganic materials 0.000 description 1
- 230000001464 adherent effect Effects 0.000 description 1
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 description 1
- 229910052786 argon Inorganic materials 0.000 description 1
- 150000001721 carbon Chemical class 0.000 description 1
- 239000006229 carbon black Substances 0.000 description 1
- 230000015556 catabolic process Effects 0.000 description 1
- 238000006243 chemical reaction Methods 0.000 description 1
- 230000001351 cycling effect Effects 0.000 description 1
- 238000006731 degradation reaction Methods 0.000 description 1
- 238000000151 deposition Methods 0.000 description 1
- 230000008021 deposition Effects 0.000 description 1
- 230000001627 detrimental effect Effects 0.000 description 1
- 239000006185 dispersion Substances 0.000 description 1
- 239000001307 helium Substances 0.000 description 1
- SWQJXJOGLNCZEY-UHFFFAOYSA-N helium atom Chemical compound [He] SWQJXJOGLNCZEY-UHFFFAOYSA-N 0.000 description 1
- 230000006872 improvement Effects 0.000 description 1
- 239000012535 impurity Substances 0.000 description 1
- 230000004941 influx Effects 0.000 description 1
- 238000011835 investigation Methods 0.000 description 1
- UGKDIUIOSMUOAW-UHFFFAOYSA-N iron nickel Chemical compound [Fe].[Ni] UGKDIUIOSMUOAW-UHFFFAOYSA-N 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 235000004213 low-fat Nutrition 0.000 description 1
- 235000012054 meals Nutrition 0.000 description 1
- 229910044991 metal oxide Inorganic materials 0.000 description 1
- 150000004706 metal oxides Chemical class 0.000 description 1
- 230000009467 reduction Effects 0.000 description 1
- 238000003303 reheating Methods 0.000 description 1
- 238000007789 sealing Methods 0.000 description 1
- 239000002344 surface layer Substances 0.000 description 1
- ZWYDDDAMNQQZHD-UHFFFAOYSA-L titanium(ii) chloride Chemical compound [Cl-].[Cl-].[Ti+2] ZWYDDDAMNQQZHD-UHFFFAOYSA-L 0.000 description 1
- 230000007704 transition Effects 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C29/00—Alloys based on carbides, oxides, nitrides, borides, or silicides, e.g. cermets, or other metal compounds, e.g. oxynitrides, sulfides
- C22C29/02—Alloys based on carbides, oxides, nitrides, borides, or silicides, e.g. cermets, or other metal compounds, e.g. oxynitrides, sulfides based on carbides or carbonitrides
- C22C29/06—Alloys based on carbides, oxides, nitrides, borides, or silicides, e.g. cermets, or other metal compounds, e.g. oxynitrides, sulfides based on carbides or carbonitrides based on carbides, but not containing other metal compounds
- C22C29/08—Alloys based on carbides, oxides, nitrides, borides, or silicides, e.g. cermets, or other metal compounds, e.g. oxynitrides, sulfides based on carbides or carbonitrides based on carbides, but not containing other metal compounds based on tungsten carbide
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C29/00—Alloys based on carbides, oxides, nitrides, borides, or silicides, e.g. cermets, or other metal compounds, e.g. oxynitrides, sulfides
- C22C29/02—Alloys based on carbides, oxides, nitrides, borides, or silicides, e.g. cermets, or other metal compounds, e.g. oxynitrides, sulfides based on carbides or carbonitrides
- C22C29/04—Alloys based on carbides, oxides, nitrides, borides, or silicides, e.g. cermets, or other metal compounds, e.g. oxynitrides, sulfides based on carbides or carbonitrides based on carbonitrides
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C29/00—Alloys based on carbides, oxides, nitrides, borides, or silicides, e.g. cermets, or other metal compounds, e.g. oxynitrides, sulfides
- C22C29/02—Alloys based on carbides, oxides, nitrides, borides, or silicides, e.g. cermets, or other metal compounds, e.g. oxynitrides, sulfides based on carbides or carbonitrides
- C22C29/06—Alloys based on carbides, oxides, nitrides, borides, or silicides, e.g. cermets, or other metal compounds, e.g. oxynitrides, sulfides based on carbides or carbonitrides based on carbides, but not containing other metal compounds
-
- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C30/00—Coating with metallic material characterised only by the composition of the metallic material, i.e. not characterised by the coating process
- C23C30/005—Coating with metallic material characterised only by the composition of the metallic material, i.e. not characterised by the coating process on hard metal substrates
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B22—CASTING; POWDER METALLURGY
- B22F—WORKING METALLIC POWDER; MANUFACTURE OF ARTICLES FROM METALLIC POWDER; MAKING METALLIC POWDER; APPARATUS OR DEVICES SPECIALLY ADAPTED FOR METALLIC POWDER
- B22F2998/00—Supplementary information concerning processes or compositions relating to powder metallurgy
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Mechanical Engineering (AREA)
- Metallurgy (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Powder Metallurgy (AREA)
- Ceramic Products (AREA)
- Chemical Vapour Deposition (AREA)
- Compositions Of Oxide Ceramics (AREA)
- Cutting Tools, Boring Holders, And Turrets (AREA)
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US24846581A | 1981-03-27 | 1981-03-27 |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| DE3211047A1 true DE3211047A1 (de) | 1982-11-25 |
| DE3211047C2 DE3211047C2 (enrdf_load_stackoverflow) | 1988-02-11 |
Family
ID=22939253
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| DE19823211047 Granted DE3211047A1 (de) | 1981-03-27 | 1982-03-25 | Vorzugsweise mit bindemittel angereicherte, zementierte carbidkoerper und verfahren zu ihrer herstellung |
Country Status (22)
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE3744573A1 (de) * | 1987-01-05 | 1988-07-14 | Toshiba Tungaloy Co Ltd | Oberflaechenraffinierter sinterlegierungskoerper und verfahren zu dessen herstellung |
| US6124040A (en) * | 1993-11-30 | 2000-09-26 | Widia Gmbh | Composite and process for the production thereof |
| US6655882B2 (en) | 1999-02-23 | 2003-12-02 | Kennametal Inc. | Twist drill having a sintered cemented carbide body, and like tools, and use thereof |
Families Citing this family (27)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS6047906B2 (ja) * | 1981-09-25 | 1985-10-24 | 三菱マテリアル株式会社 | 切削用表面被覆スロ−アウエイチツプ |
| US4548786A (en) * | 1983-04-28 | 1985-10-22 | General Electric Company | Coated carbide cutting tool insert |
| US4497874A (en) * | 1983-04-28 | 1985-02-05 | General Electric Company | Coated carbide cutting tool insert |
| DE3332260A1 (de) * | 1983-09-07 | 1985-03-28 | Fried. Krupp Gmbh, 4300 Essen | Beschichteter hartmetallkoerper |
| JPS60165340A (ja) * | 1984-02-09 | 1985-08-28 | Toshiba Tungaloy Co Ltd | 選択的に部分改質した焼結合金 |
| KR870000309B1 (ko) * | 1984-05-29 | 1987-02-26 | 한국과학기술원 | 절삭 공구용 질화규소 소결체 및 그의 제조 방법 |
| DE3574738D1 (de) * | 1984-11-13 | 1990-01-18 | Santrade Ltd | Gesinterte hartmetallegierung zum gesteinsbohren und zum schneiden von mineralien. |
| US4649084A (en) * | 1985-05-06 | 1987-03-10 | General Electric Company | Process for adhering an oxide coating on a cobalt-enriched zone, and articles made from said process |
| JP2684721B2 (ja) * | 1988-10-31 | 1997-12-03 | 三菱マテリアル株式会社 | 表面被覆炭化タングステン基超硬合金製切削工具およびその製造法 |
| US5204167A (en) * | 1989-02-23 | 1993-04-20 | Toshiba Tungaloy Co., Ltd. | Diamond-coated sintered body excellent in adhesion and process for preparing the same |
| DE69025582T3 (de) * | 1989-12-27 | 2001-05-31 | Sumitomo Electric Industries, Ltd. | Beschichteter Hartmetallkörper und Verfahren zu seiner Herstellung |
| CA2092932C (en) * | 1992-04-17 | 1996-12-31 | Katsuya Uchino | Coated cemented carbide member and method of manufacturing the same |
| SE514181C2 (sv) | 1995-04-05 | 2001-01-15 | Sandvik Ab | Belagt hårmetallskär för fräsning av gjutjärn |
| US5786069A (en) | 1995-09-01 | 1998-07-28 | Sandvik Ab | Coated turning insert |
| US6554548B1 (en) | 2000-08-11 | 2003-04-29 | Kennametal Inc. | Chromium-containing cemented carbide body having a surface zone of binder enrichment |
| JP4703123B2 (ja) * | 2004-03-23 | 2011-06-15 | 京セラ株式会社 | 表面被覆ＴｉＣＮ基サーメットの製造方法 |
| JP4936741B2 (ja) * | 2005-03-22 | 2012-05-23 | 京セラ株式会社 | 表面被覆工具および切削工具 |
| JP4936742B2 (ja) * | 2005-03-22 | 2012-05-23 | 京セラ株式会社 | 表面被覆工具および切削工具 |
| DE102006018947A1 (de) * | 2006-04-24 | 2007-10-25 | Tutec Gmbh | Verfahren zur Herstellung eines Hartmetallkörpers, Pulver zur Herstellung eines Hartmetalls und Hartmetallkörper |
| SE0700602L (sv) * | 2007-03-13 | 2008-09-14 | Sandvik Intellectual Property | Hårdmetallskär och metod att tillverka detsamma |
| JP5590329B2 (ja) * | 2011-02-03 | 2014-09-17 | 三菱マテリアル株式会社 | 硬質被覆層がすぐれた耐チッピング性、耐欠損性を備える表面被覆切削工具 |
| EP2821166B1 (en) * | 2013-07-04 | 2016-04-20 | Sandvik Intellectual Property AB | A method for manufacturing a wear resistant component comprising mechanically interlocked cemented carbide bodies |
| CN109881073B (zh) * | 2019-04-26 | 2020-05-22 | 中南大学 | 具有粘结金属富集层表面结构的合金及其制备方法与应用 |
| JP7173426B1 (ja) * | 2021-04-01 | 2022-11-16 | 住友電気工業株式会社 | 超硬合金及び切削工具 |
| EP4166261A1 (en) * | 2021-10-15 | 2023-04-19 | Sandvik Machining Solutions AB | Method for manufacturing a sintered article and a sintered article |
| WO2023062158A1 (en) * | 2021-10-15 | 2023-04-20 | Sandvik Machining Solutions Ab | A method for manufacturing a sintered article and a sintered article |
| CN114277299B (zh) * | 2021-12-28 | 2022-10-04 | 九江金鹭硬质合金有限公司 | 一种抗焊接开裂的高硬度硬质合金板条 |
Citations (26)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| GB395134A (en) * | 1931-08-28 | 1933-07-13 | Tool Metal Mfg Company Ltd | Improvements in hard alloys |
| DE622347C (de) * | 1931-07-19 | 1935-11-26 | Fried Krupp Akt Ges Gussstahlf | Verfahren zur Herstellung von Hartmetallegierungen fuer Arbeitsgeraete und Werkzeuge aus Wolframkarbid und einem zusaetzlichen Hilfsmetall |
| GB439379A (en) * | 1933-08-19 | 1935-12-05 | British Thomson Houston Co Ltd | Improvements in and relating to hard alloys |
| US2074847A (en) * | 1933-08-19 | 1937-03-23 | Gen Electric | Hard alloy |
| DE650001C (de) * | 1931-08-29 | 1937-09-09 | Fried Krupp Akt Ges | Gesinterte Hartmetallegierungen |
| GB478534A (en) * | 1935-12-02 | 1938-01-20 | Krupp Ag | Improved sintered hard metal alloys |
| US2123046A (en) * | 1935-12-02 | 1938-07-05 | Gen Electric | Sintered hard metal alloys |
| GB763409A (en) * | 1953-10-21 | 1956-12-12 | Uddeholms Ab | Hard metal alloy and method for producing the same |
| US3564683A (en) * | 1967-06-14 | 1971-02-23 | Wolfgang Schedler | Cutting of deposit forming steel and cutting tools for such steels |
| US3616506A (en) * | 1969-01-02 | 1971-11-02 | Sandvikens Jernverks Ab | Insert for machining steel or similar material |
| US3736107A (en) * | 1971-05-26 | 1973-05-29 | Gen Electric | Coated cemented carbide product |
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| US3955038A (en) * | 1973-04-09 | 1976-05-04 | Sandvik Aktiebolag | Hard metal body |
| US3967035A (en) * | 1973-03-12 | 1976-06-29 | General Electric Company | Coated cemented carbide product |
| US3994692A (en) * | 1974-05-29 | 1976-11-30 | Erwin Rudy | Sintered carbonitride tool materials |
| DE2263210B2 (de) * | 1972-02-04 | 1977-03-17 | Metallwerk Plansee AG & Co. KG, Reutte, Tirol (Österreich) | Verschleissteil aus hartmetall, insbesondere fuer werkzeuge |
| US4035541A (en) * | 1975-11-17 | 1977-07-12 | Kennametal Inc. | Sintered cemented carbide body coated with three layers |
| US4046517A (en) * | 1975-02-14 | 1977-09-06 | Ltd. Dijet Industrial Co | Cemented carbide material for cutting operation |
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| JPS5487719A (en) * | 1977-12-23 | 1979-07-12 | Sumitomo Electric Industries | Super hard alloy and method of making same |
| GB2015536A (en) * | 1978-03-03 | 1979-09-12 | Elf Union | Bitumens modified by polymers |
| DE2646433C3 (de) * | 1975-10-14 | 1980-02-21 | Ngk Spark Plug Co., Ltd., Nagoya, Aichi (Japan) | Sinterlegierung |
| JPS569365A (en) * | 1979-07-02 | 1981-01-30 | Mitsubishi Metal Corp | Surface coated solid carbide alloy material |
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|---|---|---|---|---|
| US2979811A (en) * | 1958-10-24 | 1961-04-18 | Nat Twist Drill & Tool Company | Cemented carbide body having wettable surface and method of producing same |
| CA986337A (en) * | 1971-05-28 | 1976-03-30 | Brian A. Mynard | Ruthenium or osmium on hard metal |
| US3971656A (en) * | 1973-06-18 | 1976-07-27 | Erwin Rudy | Spinodal carbonitride alloys for tool and wear applications |
| US4049876A (en) * | 1974-10-18 | 1977-09-20 | Sumitomo Electric Industries, Ltd. | Cemented carbonitride alloys |
| US4150195A (en) * | 1976-06-18 | 1979-04-17 | Sumitomo Electric Industries, Ltd. | Surface-coated cemented carbide article and a process for the production thereof |
| JPS5773104A (en) * | 1980-10-27 | 1982-05-07 | Mitsubishi Metal Corp | Surface-coated superhard alloy member and its production |
-
1982
- 1982-03-01 CA CA000397349A patent/CA1174438A/en not_active Expired
- 1982-03-02 GB GB8206119A patent/GB2095702B/en not_active Expired
- 1982-03-09 IE IE537/82A patent/IE52544B1/en unknown
- 1982-03-15 NZ NZ200007A patent/NZ200007A/en unknown
- 1982-03-15 ZA ZA821717A patent/ZA821717B/xx unknown
- 1982-03-18 AU AU81688/82A patent/AU539101B2/en not_active Expired
- 1982-03-19 NL NLAANVRAGE8201161,A patent/NL188172C/xx not_active IP Right Cessation
- 1982-03-22 MX MX191909A patent/MX156716A/es unknown
- 1982-03-24 CH CH1798/82A patent/CH653055A5/fr not_active IP Right Cessation
- 1982-03-24 LU LU84034A patent/LU84034A1/fr unknown
- 1982-03-25 DE DE19823211047 patent/DE3211047A1/de active Granted
- 1982-03-25 BE BE0/207667A patent/BE892634A/fr not_active IP Right Cessation
- 1982-03-25 IT IT20395/82A patent/IT1151523B/it active
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- 1982-03-26 FI FI821074A patent/FI74304C/fi not_active IP Right Cessation
- 1982-03-26 IL IL65359A patent/IL65359A/xx not_active IP Right Cessation
- 1982-03-26 FR FR828205232A patent/FR2502613B1/fr not_active Expired - Lifetime
- 1982-03-26 PT PT74670A patent/PT74670B/pt unknown
- 1982-03-26 JP JP57048787A patent/JPH0674462B2/ja not_active Expired - Lifetime
- 1982-03-26 SE SE8201930A patent/SE459100C/sv not_active IP Right Cessation
- 1982-03-26 NO NO821021A patent/NO165628C/no not_active IP Right Cessation
- 1982-03-27 ES ES510886A patent/ES8308589A1/es not_active Expired
-
1983
- 1983-03-30 ES ES1983271281U patent/ES271281Y/es not_active Expired
-
1988
- 1988-12-20 JP JP63321859A patent/JPH0629475B1/ja active Pending
- 1988-12-20 JP JP63321859A patent/JPH01201436A/ja active Pending
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1989
- 1989-01-18 MX MX014579A patent/MX170393B/es unknown
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Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE3744573A1 (de) * | 1987-01-05 | 1988-07-14 | Toshiba Tungaloy Co Ltd | Oberflaechenraffinierter sinterlegierungskoerper und verfahren zu dessen herstellung |
| US6124040A (en) * | 1993-11-30 | 2000-09-26 | Widia Gmbh | Composite and process for the production thereof |
| US6655882B2 (en) | 1999-02-23 | 2003-12-02 | Kennametal Inc. | Twist drill having a sintered cemented carbide body, and like tools, and use thereof |
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