DE3035964A1 - Verfahren und einrichtung zur herstellung technisch reiner magnesiumverbindungen - Google Patents
Verfahren und einrichtung zur herstellung technisch reiner magnesiumverbindungenInfo
- Publication number
- DE3035964A1 DE3035964A1 DE19803035964 DE3035964A DE3035964A1 DE 3035964 A1 DE3035964 A1 DE 3035964A1 DE 19803035964 DE19803035964 DE 19803035964 DE 3035964 A DE3035964 A DE 3035964A DE 3035964 A1 DE3035964 A1 DE 3035964A1
- Authority
- DE
- Germany
- Prior art keywords
- suspension
- mgs03
- slurry
- magnesium
- hso3
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 229910000021 magnesium carbonate Inorganic materials 0.000 title claims abstract description 15
- 239000000725 suspension Substances 0.000 title claims abstract description 14
- 239000001095 magnesium carbonate Substances 0.000 title claims abstract description 13
- ZLNQQNXFFQJAID-UHFFFAOYSA-L magnesium carbonate Chemical compound [Mg+2].[O-]C([O-])=O ZLNQQNXFFQJAID-UHFFFAOYSA-L 0.000 title claims abstract description 13
- 235000014380 magnesium carbonate Nutrition 0.000 title claims abstract description 13
- 229910000514 dolomite Inorganic materials 0.000 title claims abstract description 5
- 239000010459 dolomite Substances 0.000 title claims abstract description 5
- 239000002912 waste gas Substances 0.000 title claims abstract 4
- 239000011777 magnesium Substances 0.000 title claims description 19
- 238000006243 chemical reaction Methods 0.000 title claims description 9
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 title description 5
- FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 title description 2
- 229910052749 magnesium Inorganic materials 0.000 title description 2
- 239000005864 Sulphur Substances 0.000 title 1
- 239000012535 impurity Substances 0.000 claims abstract description 16
- 239000002002 slurry Substances 0.000 claims abstract description 13
- 229910052943 magnesium sulfate Inorganic materials 0.000 claims abstract description 11
- LSNNMFCWUKXFEE-UHFFFAOYSA-M Bisulfite Chemical compound OS([O-])=O LSNNMFCWUKXFEE-UHFFFAOYSA-M 0.000 claims abstract description 9
- 229910000019 calcium carbonate Inorganic materials 0.000 claims abstract description 8
- 239000000395 magnesium oxide Substances 0.000 claims abstract description 8
- 238000000034 method Methods 0.000 claims description 19
- 239000007789 gas Substances 0.000 claims description 17
- 238000010521 absorption reaction Methods 0.000 claims description 10
- 159000000003 magnesium salts Chemical class 0.000 claims description 8
- 150000002681 magnesium compounds Chemical class 0.000 claims description 7
- 238000004519 manufacturing process Methods 0.000 claims description 6
- 229910052717 sulfur Inorganic materials 0.000 claims description 5
- 239000011593 sulfur Substances 0.000 claims description 5
- -1 #g (HSO3) 2 Chemical class 0.000 claims description 4
- 238000004140 cleaning Methods 0.000 claims description 4
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 4
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 claims description 3
- OSGAYBCDTDRGGQ-UHFFFAOYSA-L calcium sulfate Chemical compound [Ca+2].[O-]S([O-])(=O)=O OSGAYBCDTDRGGQ-UHFFFAOYSA-L 0.000 claims description 3
- 239000003546 flue gas Substances 0.000 claims description 3
- 229910052760 oxygen Inorganic materials 0.000 claims description 3
- 239000001301 oxygen Substances 0.000 claims description 3
- 239000010802 sludge Substances 0.000 claims description 3
- UGFAIRIUMAVXCW-UHFFFAOYSA-N Carbon monoxide Chemical compound [O+]#[C-] UGFAIRIUMAVXCW-UHFFFAOYSA-N 0.000 claims description 2
- 230000003647 oxidation Effects 0.000 claims description 2
- 238000007254 oxidation reaction Methods 0.000 claims description 2
- FAPWRFPIFSIZLT-UHFFFAOYSA-M Sodium chloride Chemical compound [Na+].[Cl-] FAPWRFPIFSIZLT-UHFFFAOYSA-M 0.000 claims 1
- 230000002745 absorbent Effects 0.000 claims 1
- 239000002250 absorbent Substances 0.000 claims 1
- 229910052925 anhydrite Inorganic materials 0.000 claims 1
- 238000010438 heat treatment Methods 0.000 claims 1
- 238000005201 scrubbing Methods 0.000 claims 1
- 239000011780 sodium chloride Substances 0.000 claims 1
- 238000005406 washing Methods 0.000 claims 1
- CSNNHWWHGAXBCP-UHFFFAOYSA-L Magnesium sulfate Chemical compound [Mg+2].[O-][S+2]([O-])([O-])[O-] CSNNHWWHGAXBCP-UHFFFAOYSA-L 0.000 abstract description 12
- VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical compound [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 abstract description 6
- 235000019341 magnesium sulphate Nutrition 0.000 abstract description 6
- 235000010216 calcium carbonate Nutrition 0.000 abstract description 3
- 229910052791 calcium Inorganic materials 0.000 abstract description 2
- 150000003839 salts Chemical class 0.000 abstract description 2
- RAHZWNYVWXNFOC-UHFFFAOYSA-N Sulphur dioxide Chemical compound O=S=O RAHZWNYVWXNFOC-UHFFFAOYSA-N 0.000 description 27
- JESHZQPNPCJVNG-UHFFFAOYSA-L magnesium;sulfite Chemical compound [Mg+2].[O-]S([O-])=O JESHZQPNPCJVNG-UHFFFAOYSA-L 0.000 description 9
- CPLXHLVBOLITMK-UHFFFAOYSA-N Magnesium oxide Chemical compound [Mg]=O CPLXHLVBOLITMK-UHFFFAOYSA-N 0.000 description 8
- 229910002092 carbon dioxide Inorganic materials 0.000 description 5
- 239000011575 calcium Substances 0.000 description 4
- 238000010586 diagram Methods 0.000 description 4
- LPHFLPKXBKBHRW-UHFFFAOYSA-L magnesium;hydrogen sulfite Chemical compound [Mg+2].OS([O-])=O.OS([O-])=O LPHFLPKXBKBHRW-UHFFFAOYSA-L 0.000 description 4
- LSNNMFCWUKXFEE-UHFFFAOYSA-L sulfite Chemical compound [O-]S([O-])=O LSNNMFCWUKXFEE-UHFFFAOYSA-L 0.000 description 4
- 235000010261 calcium sulphite Nutrition 0.000 description 3
- 150000002506 iron compounds Chemical class 0.000 description 3
- CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 description 2
- 159000000007 calcium salts Chemical class 0.000 description 2
- GBAOBIBJACZTNA-UHFFFAOYSA-L calcium sulfite Chemical compound [Ca+2].[O-]S([O-])=O GBAOBIBJACZTNA-UHFFFAOYSA-L 0.000 description 2
- 150000004649 carbonic acid derivatives Chemical class 0.000 description 2
- 238000003776 cleavage reaction Methods 0.000 description 2
- 239000010440 gypsum Substances 0.000 description 2
- 229910052602 gypsum Inorganic materials 0.000 description 2
- AXZKOIWUVFPNLO-UHFFFAOYSA-N magnesium;oxygen(2-) Chemical compound [O-2].[Mg+2] AXZKOIWUVFPNLO-UHFFFAOYSA-N 0.000 description 2
- 230000007017 scission Effects 0.000 description 2
- 150000004760 silicates Chemical class 0.000 description 2
- OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 description 1
- 235000008733 Citrus aurantifolia Nutrition 0.000 description 1
- QAOWNCQODCNURD-UHFFFAOYSA-L Sulfate Chemical compound [O-]S([O-])(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-L 0.000 description 1
- 235000011941 Tilia x europaea Nutrition 0.000 description 1
- 239000001175 calcium sulphate Substances 0.000 description 1
- 235000011132 calcium sulphate Nutrition 0.000 description 1
- 239000001569 carbon dioxide Substances 0.000 description 1
- 239000007795 chemical reaction product Substances 0.000 description 1
- 238000002485 combustion reaction Methods 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 238000011109 contamination Methods 0.000 description 1
- 235000013325 dietary fiber Nutrition 0.000 description 1
- 238000000605 extraction Methods 0.000 description 1
- 238000010304 firing Methods 0.000 description 1
- 230000004992 fission Effects 0.000 description 1
- 238000000227 grinding Methods 0.000 description 1
- 229910052500 inorganic mineral Inorganic materials 0.000 description 1
- SZVJSHCCFOBDDC-UHFFFAOYSA-N iron(II,III) oxide Inorganic materials O=[Fe]O[Fe]O[Fe]=O SZVJSHCCFOBDDC-UHFFFAOYSA-N 0.000 description 1
- 239000004571 lime Substances 0.000 description 1
- 235000010755 mineral Nutrition 0.000 description 1
- 239000011707 mineral Substances 0.000 description 1
- 239000000203 mixture Substances 0.000 description 1
- 239000004033 plastic Substances 0.000 description 1
- 229920003023 plastic Polymers 0.000 description 1
- 239000000047 product Substances 0.000 description 1
- 238000000746 purification Methods 0.000 description 1
- 239000002994 raw material Substances 0.000 description 1
- 239000013535 sea water Substances 0.000 description 1
- 238000000926 separation method Methods 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
- 239000007858 starting material Substances 0.000 description 1
- 238000003860 storage Methods 0.000 description 1
- 229910021653 sulphate ion Inorganic materials 0.000 description 1
- 239000002699 waste material Substances 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01F—COMPOUNDS OF THE METALS BERYLLIUM, MAGNESIUM, ALUMINIUM, CALCIUM, STRONTIUM, BARIUM, RADIUM, THORIUM, OR OF THE RARE-EARTH METALS
- C01F5/00—Compounds of magnesium
- C01F5/02—Magnesia
- C01F5/06—Magnesia by thermal decomposition of magnesium compounds
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
- B01D53/34—Chemical or biological purification of waste gases
- B01D53/46—Removing components of defined structure
- B01D53/48—Sulfur compounds
- B01D53/50—Sulfur oxides
- B01D53/501—Sulfur oxides by treating the gases with a solution or a suspension of an alkali or earth-alkali or ammonium compound
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B17/00—Sulfur; Compounds thereof
- C01B17/48—Sulfur dioxide; Sulfurous acid
- C01B17/50—Preparation of sulfur dioxide
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B17/00—Sulfur; Compounds thereof
- C01B17/48—Sulfur dioxide; Sulfurous acid
- C01B17/50—Preparation of sulfur dioxide
- C01B17/501—Preparation of sulfur dioxide by reduction of sulfur compounds
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01F—COMPOUNDS OF THE METALS BERYLLIUM, MAGNESIUM, ALUMINIUM, CALCIUM, STRONTIUM, BARIUM, RADIUM, THORIUM, OR OF THE RARE-EARTH METALS
- C01F11/00—Compounds of calcium, strontium, or barium
- C01F11/48—Sulfites
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01F—COMPOUNDS OF THE METALS BERYLLIUM, MAGNESIUM, ALUMINIUM, CALCIUM, STRONTIUM, BARIUM, RADIUM, THORIUM, OR OF THE RARE-EARTH METALS
- C01F5/00—Compounds of magnesium
- C01F5/02—Magnesia
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01F—COMPOUNDS OF THE METALS BERYLLIUM, MAGNESIUM, ALUMINIUM, CALCIUM, STRONTIUM, BARIUM, RADIUM, THORIUM, OR OF THE RARE-EARTH METALS
- C01F5/00—Compounds of magnesium
- C01F5/40—Magnesium sulfates
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01F—COMPOUNDS OF THE METALS BERYLLIUM, MAGNESIUM, ALUMINIUM, CALCIUM, STRONTIUM, BARIUM, RADIUM, THORIUM, OR OF THE RARE-EARTH METALS
- C01F5/00—Compounds of magnesium
- C01F5/42—Magnesium sulfites
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Inorganic Chemistry (AREA)
- Life Sciences & Earth Sciences (AREA)
- Geology (AREA)
- Engineering & Computer Science (AREA)
- Environmental & Geological Engineering (AREA)
- Biomedical Technology (AREA)
- Health & Medical Sciences (AREA)
- Analytical Chemistry (AREA)
- General Chemical & Material Sciences (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Physics & Mathematics (AREA)
- Thermal Sciences (AREA)
- Treating Waste Gases (AREA)
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| AT0490179A AT366986B (de) | 1979-07-16 | 1979-07-16 | Verfahren und einrichtung zur herstellung technisch reiner magnesiumverbindungen |
| AT0633179A AT373226B (de) | 1979-07-16 | 1979-09-27 | Verfahren und einrichtung zur abgasentschwefelung mittels in wasser aufgeschlaemmtem mit caco3 ver- unreinigtem mgco3 |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| DE3035964A1 true DE3035964A1 (de) | 1981-04-02 |
| DE3035964C2 DE3035964C2 (GUID-C5D7CC26-194C-43D0-91A1-9AE8C70A9BFF.html) | 1989-02-02 |
Family
ID=25601645
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| DE19803035964 Granted DE3035964A1 (de) | 1979-07-16 | 1980-09-24 | Verfahren und einrichtung zur herstellung technisch reiner magnesiumverbindungen |
Country Status (3)
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE3247837A1 (de) * | 1982-01-14 | 1983-07-21 | Vysoká škola chemicko-technologická Praha, Praha | Verfahren zur reinigung eines magnesiumhaltigen rohstoffes |
Citations (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE2318569A1 (de) * | 1972-04-26 | 1973-11-15 | Suomen Talkki Oy | Verfahren zur herstellung von reinen magnesiumverbindungen |
| DE1592199B2 (de) * | 1965-11-09 | 1974-04-11 | Hartmann, Hellmut, Prof. Dr.-Ing., 3300 Braunschweig | Verfahren zur Herstellung von Magnesiumoxyd bzw. Magnesiumhydroxyd aus Dolomit |
| AT335403B (de) * | 1972-05-04 | 1977-03-10 | Suomen Talkki Oy | Verfahren zur herstellung einer magnesiumbisulfitlosung |
| DE2548741B2 (de) * | 1974-11-29 | 1978-04-20 | Waagner-Biro Ag, Wien | Verfahren zur kontinuierlichen Gewinnung von Magnesiumbisulfitlösungen |
| DE2363793B2 (de) * | 1972-12-21 | 1978-04-27 | Pullman Inc., Chicago, Ill. (V.St.A.) | Verfahren zur Entfernung von schwefelhaltigen Gasen aus Abgasen |
| AT343596B (de) * | 1974-03-22 | 1978-06-12 | Ver Refractories Ltd | Verfahren zur entfernung von verunreinigungen aus magnesiumhaltigen verbindungen |
-
1979
- 1979-07-16 AT AT0490179A patent/AT366986B/de not_active IP Right Cessation
- 1979-09-27 AT AT0633179A patent/AT373226B/de not_active IP Right Cessation
-
1980
- 1980-09-24 DE DE19803035964 patent/DE3035964A1/de active Granted
- 1980-09-26 SE SE8006751A patent/SE448866B/sv not_active IP Right Cessation
Patent Citations (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE1592199B2 (de) * | 1965-11-09 | 1974-04-11 | Hartmann, Hellmut, Prof. Dr.-Ing., 3300 Braunschweig | Verfahren zur Herstellung von Magnesiumoxyd bzw. Magnesiumhydroxyd aus Dolomit |
| DE2318569A1 (de) * | 1972-04-26 | 1973-11-15 | Suomen Talkki Oy | Verfahren zur herstellung von reinen magnesiumverbindungen |
| AT335403B (de) * | 1972-05-04 | 1977-03-10 | Suomen Talkki Oy | Verfahren zur herstellung einer magnesiumbisulfitlosung |
| DE2363793B2 (de) * | 1972-12-21 | 1978-04-27 | Pullman Inc., Chicago, Ill. (V.St.A.) | Verfahren zur Entfernung von schwefelhaltigen Gasen aus Abgasen |
| AT343596B (de) * | 1974-03-22 | 1978-06-12 | Ver Refractories Ltd | Verfahren zur entfernung von verunreinigungen aus magnesiumhaltigen verbindungen |
| DE2548741B2 (de) * | 1974-11-29 | 1978-04-20 | Waagner-Biro Ag, Wien | Verfahren zur kontinuierlichen Gewinnung von Magnesiumbisulfitlösungen |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE3247837A1 (de) * | 1982-01-14 | 1983-07-21 | Vysoká škola chemicko-technologická Praha, Praha | Verfahren zur reinigung eines magnesiumhaltigen rohstoffes |
Also Published As
| Publication number | Publication date |
|---|---|
| ATA490179A (de) | 1981-10-15 |
| AT366986B (de) | 1982-05-25 |
| SE448866B (sv) | 1987-03-23 |
| AT373226B (de) | 1983-12-27 |
| ATA633179A (de) | 1983-05-15 |
| SE8006751L (sv) | 1981-03-28 |
| DE3035964C2 (GUID-C5D7CC26-194C-43D0-91A1-9AE8C70A9BFF.html) | 1989-02-02 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| OP8 | Request for examination as to paragraph 44 patent law | ||
| D2 | Grant after examination | ||
| 8364 | No opposition during term of opposition | ||
| 8339 | Ceased/non-payment of the annual fee |