DE2930756A1 - Klotzhilfsmittel und verfahren zum faerben von cellulosefasern bzw. gemischen von cellulosefasern zusammen mit synthesefasern mit schwefel-, schwefelkuepen-, kuepen- und reaktivfarbstoffen - Google Patents
Klotzhilfsmittel und verfahren zum faerben von cellulosefasern bzw. gemischen von cellulosefasern zusammen mit synthesefasern mit schwefel-, schwefelkuepen-, kuepen- und reaktivfarbstoffenInfo
- Publication number
- DE2930756A1 DE2930756A1 DE19792930756 DE2930756A DE2930756A1 DE 2930756 A1 DE2930756 A1 DE 2930756A1 DE 19792930756 DE19792930756 DE 19792930756 DE 2930756 A DE2930756 A DE 2930756A DE 2930756 A1 DE2930756 A1 DE 2930756A1
- Authority
- DE
- Germany
- Prior art keywords
- sulfur
- weight
- percent
- vat
- general formula
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Withdrawn
Links
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 title claims description 71
- 229910052717 sulfur Inorganic materials 0.000 title claims description 71
- 239000011593 sulfur Substances 0.000 title claims description 70
- 238000000034 method Methods 0.000 title claims description 26
- 239000000203 mixture Substances 0.000 title claims description 20
- 239000000985 reactive dye Substances 0.000 title claims description 13
- 229920002678 cellulose Polymers 0.000 title claims description 5
- 239000001913 cellulose Substances 0.000 title claims description 5
- 230000000903 blocking effect Effects 0.000 title claims description 3
- 238000004040 coloring Methods 0.000 title description 3
- 239000000835 fiber Substances 0.000 title 3
- 208000030507 AIDS Diseases 0.000 title 1
- 230000015572 biosynthetic process Effects 0.000 title 1
- 238000003786 synthesis reaction Methods 0.000 title 1
- 150000001875 compounds Chemical class 0.000 claims description 29
- 238000004043 dyeing Methods 0.000 claims description 27
- 239000000984 vat dye Substances 0.000 claims description 19
- 125000004432 carbon atom Chemical group C* 0.000 claims description 15
- 229920003043 Cellulose fiber Polymers 0.000 claims description 10
- 239000004480 active ingredient Substances 0.000 claims description 8
- 229920002994 synthetic fiber Polymers 0.000 claims description 7
- 239000012209 synthetic fiber Substances 0.000 claims description 7
- 150000001768 cations Chemical class 0.000 claims description 4
- QGZKDVFQNNGYKY-UHFFFAOYSA-O Ammonium Chemical compound [NH4+] QGZKDVFQNNGYKY-UHFFFAOYSA-O 0.000 claims description 3
- 229910052783 alkali metal Inorganic materials 0.000 claims description 3
- 125000000217 alkyl group Chemical group 0.000 claims description 3
- 125000005037 alkyl phenyl group Chemical group 0.000 claims description 3
- 239000006185 dispersion Substances 0.000 claims description 3
- 150000001340 alkali metals Chemical class 0.000 claims description 2
- 239000007864 aqueous solution Substances 0.000 claims description 2
- 229910052739 hydrogen Inorganic materials 0.000 claims description 2
- 239000001257 hydrogen Substances 0.000 claims description 2
- 125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 claims description 2
- 125000003884 phenylalkyl group Chemical group 0.000 claims description 2
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 claims 1
- 238000001356 surgical procedure Methods 0.000 claims 1
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 39
- -1 aliphatic radical Chemical class 0.000 description 21
- 239000000975 dye Substances 0.000 description 17
- 229920000742 Cotton Polymers 0.000 description 15
- IAYPIBMASNFSPL-UHFFFAOYSA-N Ethylene oxide Chemical compound C1CO1 IAYPIBMASNFSPL-UHFFFAOYSA-N 0.000 description 15
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 15
- 235000011121 sodium hydroxide Nutrition 0.000 description 13
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 description 12
- 229910052799 carbon Inorganic materials 0.000 description 10
- 235000002639 sodium chloride Nutrition 0.000 description 10
- FAPWRFPIFSIZLT-UHFFFAOYSA-M Sodium chloride Chemical compound [Na+].[Cl-] FAPWRFPIFSIZLT-UHFFFAOYSA-M 0.000 description 8
- 239000006260 foam Substances 0.000 description 7
- 239000000463 material Substances 0.000 description 7
- 238000002360 preparation method Methods 0.000 description 7
- 239000011734 sodium Substances 0.000 description 7
- 159000000000 sodium salts Chemical class 0.000 description 7
- PGYZAKRTYUHXRA-UHFFFAOYSA-N 2,10-dinitro-12h-[1,4]benzothiazino[3,2-b]phenothiazin-3-one Chemical compound S1C2=CC(=O)C([N+]([O-])=O)=CC2=NC2=C1C=C1SC3=CC=C([N+](=O)[O-])C=C3NC1=C2 PGYZAKRTYUHXRA-UHFFFAOYSA-N 0.000 description 6
- LJKDOMVGKKPJBH-UHFFFAOYSA-N 2-ethylhexyl dihydrogen phosphate Chemical compound CCCCC(CC)COP(O)(O)=O LJKDOMVGKKPJBH-UHFFFAOYSA-N 0.000 description 6
- 229920001577 copolymer Polymers 0.000 description 6
- 150000005690 diesters Chemical class 0.000 description 6
- 239000000047 product Substances 0.000 description 6
- 239000000243 solution Substances 0.000 description 6
- NBIIXXVUZAFLBC-UHFFFAOYSA-N Phosphoric acid Chemical compound OP(O)(O)=O NBIIXXVUZAFLBC-UHFFFAOYSA-N 0.000 description 5
- CDBYLPFSWZWCQE-UHFFFAOYSA-L Sodium Carbonate Chemical compound [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 description 5
- 239000002253 acid Substances 0.000 description 5
- 238000010014 continuous dyeing Methods 0.000 description 5
- 239000011780 sodium chloride Substances 0.000 description 5
- 239000000126 substance Substances 0.000 description 5
- 239000000988 sulfur dye Substances 0.000 description 5
- 238000005406 washing Methods 0.000 description 5
- 238000009835 boiling Methods 0.000 description 4
- SEGLCEQVOFDUPX-UHFFFAOYSA-N di-(2-ethylhexyl)phosphoric acid Chemical compound CCCCC(CC)COP(O)(=O)OCC(CC)CCCC SEGLCEQVOFDUPX-UHFFFAOYSA-N 0.000 description 4
- 239000007788 liquid Substances 0.000 description 4
- 230000001590 oxidative effect Effects 0.000 description 4
- XAEFZNCEHLXOMS-UHFFFAOYSA-M potassium benzoate Chemical compound [K+].[O-]C(=O)C1=CC=CC=C1 XAEFZNCEHLXOMS-UHFFFAOYSA-M 0.000 description 4
- 150000003839 salts Chemical class 0.000 description 4
- NTHWMYGWWRZVTN-UHFFFAOYSA-N sodium silicate Chemical compound [Na+].[Na+].[O-][Si]([O-])=O NTHWMYGWWRZVTN-UHFFFAOYSA-N 0.000 description 4
- 238000010186 staining Methods 0.000 description 4
- FMKXFJQAVQXMPX-UHFFFAOYSA-N 4-(9h-carbazol-3-ylimino)cyclohexa-2,5-dien-1-one Chemical compound C1=CC(=O)C=CC1=NC1=CC=C(NC=2C3=CC=CC=2)C3=C1 FMKXFJQAVQXMPX-UHFFFAOYSA-N 0.000 description 3
- QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical compound CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 description 3
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 description 3
- KWYUFKZDYYNOTN-UHFFFAOYSA-M Potassium hydroxide Chemical compound [OH-].[K+] KWYUFKZDYYNOTN-UHFFFAOYSA-M 0.000 description 3
- GSEJCLTVZPLZKY-UHFFFAOYSA-N Triethanolamine Chemical compound OCCN(CCO)CCO GSEJCLTVZPLZKY-UHFFFAOYSA-N 0.000 description 3
- 239000013543 active substance Substances 0.000 description 3
- 239000013065 commercial product Substances 0.000 description 3
- JQVDAXLFBXTEQA-UHFFFAOYSA-N dibutylamine Chemical compound CCCCNCCCC JQVDAXLFBXTEQA-UHFFFAOYSA-N 0.000 description 3
- GRWZHXKQBITJKP-UHFFFAOYSA-N dithionous acid Chemical compound OS(=O)S(O)=O GRWZHXKQBITJKP-UHFFFAOYSA-N 0.000 description 3
- 238000001035 drying Methods 0.000 description 3
- 239000003792 electrolyte Substances 0.000 description 3
- 150000002148 esters Chemical class 0.000 description 3
- NLFBCYMMUAKCPC-KQQUZDAGSA-N ethyl (e)-3-[3-amino-2-cyano-1-[(e)-3-ethoxy-3-oxoprop-1-enyl]sulfanyl-3-oxoprop-1-enyl]sulfanylprop-2-enoate Chemical compound CCOC(=O)\C=C\SC(=C(C#N)C(N)=O)S\C=C\C(=O)OCC NLFBCYMMUAKCPC-KQQUZDAGSA-N 0.000 description 3
- OEQRECGPDUFLOK-UHFFFAOYSA-N n,n-dibutyl-11-hydroxynonadecanamide Chemical compound CCCCCCCCC(O)CCCCCCCCCC(=O)N(CCCC)CCCC OEQRECGPDUFLOK-UHFFFAOYSA-N 0.000 description 3
- 235000011007 phosphoric acid Nutrition 0.000 description 3
- 235000019353 potassium silicate Nutrition 0.000 description 3
- 239000004753 textile Substances 0.000 description 3
- 229920005682 EO-PO block copolymer Polymers 0.000 description 2
- 229920000297 Rayon Polymers 0.000 description 2
- 241001584775 Tunga penetrans Species 0.000 description 2
- XSQUKJJJFZCRTK-UHFFFAOYSA-N Urea Chemical compound NC(N)=O XSQUKJJJFZCRTK-UHFFFAOYSA-N 0.000 description 2
- 239000004202 carbamide Substances 0.000 description 2
- PZTQVMXMKVTIRC-UHFFFAOYSA-L chembl2028348 Chemical compound [Ca+2].[O-]S(=O)(=O)C1=CC(C)=CC=C1N=NC1=C(O)C(C([O-])=O)=CC2=CC=CC=C12 PZTQVMXMKVTIRC-UHFFFAOYSA-L 0.000 description 2
- MXDLSTFDVJKXGG-UHFFFAOYSA-L dipotassium;2-ethylhexyl phosphate Chemical compound [K+].[K+].CCCCC(CC)COP([O-])([O-])=O MXDLSTFDVJKXGG-UHFFFAOYSA-L 0.000 description 2
- OVFWQJVENRZWTG-UHFFFAOYSA-L disodium 5-hydroxy-6-[[3-(2-sulfonatooxyethylsulfonyl)phenyl]diazenyl]naphthalene-1-sulfonate Chemical compound [Na+].[Na+].Oc1c(ccc2c(cccc12)S([O-])(=O)=O)N=Nc1cccc(c1)S(=O)(=O)CCOS([O-])(=O)=O OVFWQJVENRZWTG-UHFFFAOYSA-L 0.000 description 2
- GRWZHXKQBITJKP-UHFFFAOYSA-L dithionite(2-) Chemical compound [O-]S(=O)S([O-])=O GRWZHXKQBITJKP-UHFFFAOYSA-L 0.000 description 2
- 239000004744 fabric Substances 0.000 description 2
- HTENFZMEHKCNMD-UHFFFAOYSA-N helio brilliant orange rk Chemical compound C1=CC=C2C(=O)C(C=C3Br)=C4C5=C2C1=C(Br)C=C5C(=O)C1=CC=CC3=C14 HTENFZMEHKCNMD-UHFFFAOYSA-N 0.000 description 2
- 235000019239 indanthrene blue RS Nutrition 0.000 description 2
- UHOKSCJSTAHBSO-UHFFFAOYSA-N indanthrone blue Chemical compound C1=CC=C2C(=O)C3=CC=C4NC5=C6C(=O)C7=CC=CC=C7C(=O)C6=CC=C5NC4=C3C(=O)C2=C1 UHOKSCJSTAHBSO-UHFFFAOYSA-N 0.000 description 2
- 230000003647 oxidation Effects 0.000 description 2
- 238000007254 oxidation reaction Methods 0.000 description 2
- 229920000728 polyester Polymers 0.000 description 2
- 159000000001 potassium salts Chemical class 0.000 description 2
- VDWRBVKXEXWMIT-UHFFFAOYSA-M potassium;bis(2-ethylhexyl) phosphate Chemical compound [K+].CCCCC(CC)COP([O-])(=O)OCC(CC)CCCC VDWRBVKXEXWMIT-UHFFFAOYSA-M 0.000 description 2
- 150000003254 radicals Chemical class 0.000 description 2
- 239000002964 rayon Substances 0.000 description 2
- 239000000344 soap Substances 0.000 description 2
- 238000009736 wetting Methods 0.000 description 2
- HHRBXFKKCGVRAF-UHFFFAOYSA-N 10-hydroxy-n-methyl-n-phenyloctadecanamide Chemical compound CCCCCCCCC(O)CCCCCCCCC(=O)N(C)C1=CC=CC=C1 HHRBXFKKCGVRAF-UHFFFAOYSA-N 0.000 description 1
- SLRMQYXOBQWXCR-UHFFFAOYSA-N 2154-56-5 Chemical compound [CH2]C1=CC=CC=C1 SLRMQYXOBQWXCR-UHFFFAOYSA-N 0.000 description 1
- SOFRHZUTPGJWAM-UHFFFAOYSA-N 3-hydroxy-4-[(2-methoxy-5-nitrophenyl)diazenyl]-N-(3-nitrophenyl)naphthalene-2-carboxamide Chemical compound COc1ccc(cc1N=Nc1c(O)c(cc2ccccc12)C(=O)Nc1cccc(c1)[N+]([O-])=O)[N+]([O-])=O SOFRHZUTPGJWAM-UHFFFAOYSA-N 0.000 description 1
- STRAHSCTRLRZNU-UHFFFAOYSA-N 4-(9h-carbazol-3-ylamino)phenol Chemical compound C1=CC(O)=CC=C1NC1=CC=C(NC=2C3=CC=CC=2)C3=C1 STRAHSCTRLRZNU-UHFFFAOYSA-N 0.000 description 1
- VDBJCDWTNCKRTF-UHFFFAOYSA-N 6'-hydroxyspiro[2-benzofuran-3,9'-9ah-xanthene]-1,3'-dione Chemical compound O1C(=O)C2=CC=CC=C2C21C1C=CC(=O)C=C1OC1=CC(O)=CC=C21 VDBJCDWTNCKRTF-UHFFFAOYSA-N 0.000 description 1
- IDXWQJNXMQJTCW-UHFFFAOYSA-N 7-methyloctyl dihydrogen phosphate Chemical compound CC(C)CCCCCCOP(O)(O)=O IDXWQJNXMQJTCW-UHFFFAOYSA-N 0.000 description 1
- NLXLAEXVIDQMFP-UHFFFAOYSA-N Ammonium chloride Substances [NH4+].[Cl-] NLXLAEXVIDQMFP-UHFFFAOYSA-N 0.000 description 1
- VHUUQVKOLVNVRT-UHFFFAOYSA-N Ammonium hydroxide Chemical compound [NH4+].[OH-] VHUUQVKOLVNVRT-UHFFFAOYSA-N 0.000 description 1
- DRSHXJFUUPIBHX-UHFFFAOYSA-N COc1ccc(cc1)N1N=CC2C=NC(Nc3cc(OC)c(OC)c(OCCCN4CCN(C)CC4)c3)=NC12 Chemical compound COc1ccc(cc1)N1N=CC2C=NC(Nc3cc(OC)c(OC)c(OCCCN4CCN(C)CC4)c3)=NC12 DRSHXJFUUPIBHX-UHFFFAOYSA-N 0.000 description 1
- HDFFVHSMHLDSLO-UHFFFAOYSA-N Dibenzyl phosphate Chemical compound C=1C=CC=CC=1COP(=O)(O)OCC1=CC=CC=C1 HDFFVHSMHLDSLO-UHFFFAOYSA-N 0.000 description 1
- AEQFHTYISHCYEV-UHFFFAOYSA-N N(CCO)(CCO)CCO.C(C1=CC=CC=C1)OP(=O)(O)O Chemical compound N(CCO)(CCO)CCO.C(C1=CC=CC=C1)OP(=O)(O)O AEQFHTYISHCYEV-UHFFFAOYSA-N 0.000 description 1
- WFMDNPDLHMQLBA-UHFFFAOYSA-N N(CCO)(CCO)CCO.C(C1=CC=CC=C1)OP(=O)(OCC1=CC=CC=C1)O Chemical compound N(CCO)(CCO)CCO.C(C1=CC=CC=C1)OP(=O)(OCC1=CC=CC=C1)O WFMDNPDLHMQLBA-UHFFFAOYSA-N 0.000 description 1
- 229910019142 PO4 Inorganic materials 0.000 description 1
- 239000004952 Polyamide Substances 0.000 description 1
- GOOHAUXETOMSMM-UHFFFAOYSA-N Propylene oxide Chemical compound CC1CO1 GOOHAUXETOMSMM-UHFFFAOYSA-N 0.000 description 1
- KXXFHLLUPUAVRY-UHFFFAOYSA-J [Na+].[Na+].[Na+].[Cu++].[O-]C(=O)C1=CC=C(C=C1N=N[C-](N=NC1=C([O-])C(NC2=NC(F)=NC(NCCOCCS(=O)(=O)C=C)=N2)=CC(=C1)S([O-])(=O)=O)C1=CC=CC=C1)S([O-])(=O)=O Chemical compound [Na+].[Na+].[Na+].[Cu++].[O-]C(=O)C1=CC=C(C=C1N=N[C-](N=NC1=C([O-])C(NC2=NC(F)=NC(NCCOCCS(=O)(=O)C=C)=N2)=CC(=C1)S([O-])(=O)=O)C1=CC=CC=C1)S([O-])(=O)=O KXXFHLLUPUAVRY-UHFFFAOYSA-J 0.000 description 1
- 238000010521 absorption reaction Methods 0.000 description 1
- 150000007513 acids Chemical class 0.000 description 1
- 150000008044 alkali metal hydroxides Chemical class 0.000 description 1
- 150000001447 alkali salts Chemical class 0.000 description 1
- 150000001412 amines Chemical class 0.000 description 1
- 229910021529 ammonia Inorganic materials 0.000 description 1
- 235000011114 ammonium hydroxide Nutrition 0.000 description 1
- YTFJQDNGSQJFNA-UHFFFAOYSA-N benzyl dihydrogen phosphate Chemical compound OP(O)(=O)OCC1=CC=CC=C1 YTFJQDNGSQJFNA-UHFFFAOYSA-N 0.000 description 1
- 125000001797 benzyl group Chemical group [H]C1=C([H])C([H])=C(C([H])=C1[H])C([H])([H])* 0.000 description 1
- CELFQJLWIWWAPB-UHFFFAOYSA-N bis(7-methyloctyl) hydrogen phosphate Chemical compound CC(C)CCCCCCOP(O)(=O)OCCCCCCC(C)C CELFQJLWIWWAPB-UHFFFAOYSA-N 0.000 description 1
- YMEPVPIIHONYLV-UHFFFAOYSA-N bisbenzimidazo[2,1-b:1',2'-j]benzo[lmn][3,8]phenanthroline-6,9-dione Chemical compound C1=CC=C2N(C(C3=CC=C4C(N5C6=CC=CC=C6N=C5C=5C=CC6=C3C4=5)=O)=O)C6=NC2=C1 YMEPVPIIHONYLV-UHFFFAOYSA-N 0.000 description 1
- 238000004061 bleaching Methods 0.000 description 1
- 235000012745 brilliant blue FCF Nutrition 0.000 description 1
- HMVVJYXWTGGFDR-UHFFFAOYSA-N carbanthrene red g 2b Chemical compound C1=C(C2=3)C(=O)C4=CC=CC=C4C=3N(CC)N=C2C=C1C(=C1)C=C2C(=O)C3=CC=CC=C3C3=C2C1=NN3CC HMVVJYXWTGGFDR-UHFFFAOYSA-N 0.000 description 1
- 238000010924 continuous production Methods 0.000 description 1
- VAVKOHVLNBBLQE-UHFFFAOYSA-I copper;trisodium;5-acetamido-4-oxido-3-[[2-oxido-5-(2-sulfonatooxyethylsulfonyl)phenyl]diazenyl]naphthalene-2,7-disulfonate Chemical compound [Na+].[Na+].[Na+].[Cu+2].[O-]C1=C2C(NC(=O)C)=CC(S([O-])(=O)=O)=CC2=CC(S([O-])(=O)=O)=C1N=NC1=CC(S(=O)(=O)CCOS([O-])(=O)=O)=CC=C1[O-] VAVKOHVLNBBLQE-UHFFFAOYSA-I 0.000 description 1
- 125000005131 dialkylammonium group Chemical group 0.000 description 1
- 238000002845 discoloration Methods 0.000 description 1
- DHHGSXPASZBLGC-UHFFFAOYSA-L disodium 6-acetamido-4-hydroxy-3-[[4-(2-sulfonatooxyethylsulfonyl)phenyl]diazenyl]naphthalene-2-sulfonate Chemical compound C(C)(=O)NC=1C=C2C(=C(C(=CC2=CC=1)S(=O)(=O)[O-])N=NC1=CC=C(C=C1)S(=O)(=O)CCOS(=O)(=O)[O-])O.[Na+].[Na+] DHHGSXPASZBLGC-UHFFFAOYSA-L 0.000 description 1
- 238000009826 distribution Methods 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 230000032050 esterification Effects 0.000 description 1
- 238000005886 esterification reaction Methods 0.000 description 1
- 229920005676 ethylene-propylene block copolymer Polymers 0.000 description 1
- 230000003311 flocculating effect Effects 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- 125000004435 hydrogen atom Chemical group [H]* 0.000 description 1
- GPRLSGONYQIRFK-UHFFFAOYSA-N hydron Chemical compound [H+] GPRLSGONYQIRFK-UHFFFAOYSA-N 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- AJDUTMFFZHIJEM-UHFFFAOYSA-N n-(9,10-dioxoanthracen-1-yl)-4-[4-[[4-[4-[(9,10-dioxoanthracen-1-yl)carbamoyl]phenyl]phenyl]diazenyl]phenyl]benzamide Chemical compound O=C1C2=CC=CC=C2C(=O)C2=C1C=CC=C2NC(=O)C(C=C1)=CC=C1C(C=C1)=CC=C1N=NC(C=C1)=CC=C1C(C=C1)=CC=C1C(=O)NC1=CC=CC2=C1C(=O)C1=CC=CC=C1C2=O AJDUTMFFZHIJEM-UHFFFAOYSA-N 0.000 description 1
- DGBWPZSGHAXYGK-UHFFFAOYSA-N perinone Chemical compound C12=NC3=CC=CC=C3N2C(=O)C2=CC=C3C4=C2C1=CC=C4C(=O)N1C2=CC=CC=C2N=C13 DGBWPZSGHAXYGK-UHFFFAOYSA-N 0.000 description 1
- NBIIXXVUZAFLBC-UHFFFAOYSA-K phosphate Chemical compound [O-]P([O-])([O-])=O NBIIXXVUZAFLBC-UHFFFAOYSA-K 0.000 description 1
- 239000010452 phosphate Substances 0.000 description 1
- 229920002647 polyamide Polymers 0.000 description 1
- 229920000768 polyamine Polymers 0.000 description 1
- 229920002338 polyhydroxyethylmethacrylate Polymers 0.000 description 1
- 229920001296 polysiloxane Polymers 0.000 description 1
- 235000011118 potassium hydroxide Nutrition 0.000 description 1
- 239000000843 powder Substances 0.000 description 1
- 239000002994 raw material Substances 0.000 description 1
- KUIXZSYWBHSYCN-UHFFFAOYSA-L remazol brilliant blue r Chemical compound [Na+].[Na+].C1=C(S([O-])(=O)=O)C(N)=C2C(=O)C3=CC=CC=C3C(=O)C2=C1NC1=CC=CC(S(=O)(=O)CCOS([O-])(=O)=O)=C1 KUIXZSYWBHSYCN-UHFFFAOYSA-L 0.000 description 1
- DHHGSXPASZBLGC-VPMNAVQSSA-L remazole orange-3R Chemical compound [Na+].[Na+].OC=1C2=CC(NC(=O)C)=CC=C2C=C(S([O-])(=O)=O)C=1\N=N\C1=CC=C(S(=O)(=O)CCOS([O-])(=O)=O)C=C1 DHHGSXPASZBLGC-VPMNAVQSSA-L 0.000 description 1
- GHMLBKRAJCXXBS-UHFFFAOYSA-N resorcinol Chemical compound OC1=CC=CC(O)=C1 GHMLBKRAJCXXBS-UHFFFAOYSA-N 0.000 description 1
- 238000004904 shortening Methods 0.000 description 1
- 238000010025 steaming Methods 0.000 description 1
- 125000000542 sulfonic acid group Chemical group 0.000 description 1
- 230000002195 synergetic effect Effects 0.000 description 1
- GSEJCLTVZPLZKY-UHFFFAOYSA-O triethanolammonium Chemical compound OCC[NH+](CCO)CCO GSEJCLTVZPLZKY-UHFFFAOYSA-O 0.000 description 1
- LWIHDJKSTIGBAC-UHFFFAOYSA-K tripotassium phosphate Chemical compound [K+].[K+].[K+].[O-]P([O-])([O-])=O LWIHDJKSTIGBAC-UHFFFAOYSA-K 0.000 description 1
- DLPITEUCXDBWSF-UHFFFAOYSA-K trisodium N-[8-oxido-7-[[2-oxido-4-(2-sulfooxyethylsulfonyl)phenyl]diazenyl]-3,6-disulfonaphthalen-1-yl]ethanimidate Chemical compound CC(=NC1=C2C(=CC(=C1)S(=O)(=O)O)C=C(C(=C2[O-])N=NC3=C(C=C(C=C3)S(=O)(=O)CCOS(=O)(=O)O)[O-])S(=O)(=O)O)[O-].[Na+].[Na+].[Na+] DLPITEUCXDBWSF-UHFFFAOYSA-K 0.000 description 1
- DCYIADGZPJOOFN-UHFFFAOYSA-N vat brown 1 Chemical compound C1=CC=C2C(=O)C3=CC=C4C(C5=C(C6=C7C(C8=CC=CC=C8C6=O)=O)NC6=C8C(=O)C9=CC=CC=C9C(C8=CC=C65)=O)=C7NC4=C3C(=O)C2=C1 DCYIADGZPJOOFN-UHFFFAOYSA-N 0.000 description 1
- KOTVVDDZWMCZBT-UHFFFAOYSA-N vat violet 1 Chemical compound C1=CC=C[C]2C(=O)C(C=CC3=C4C=C(C=5C=6C(C([C]7C=CC=CC7=5)=O)=CC=C5C4=6)Cl)=C4C3=C5C=C(Cl)C4=C21 KOTVVDDZWMCZBT-UHFFFAOYSA-N 0.000 description 1
- BMZAOXGPXCPSTH-UHFFFAOYSA-N vatred14 Chemical compound C12=NC3=CC=CC=C3N2C(=O)C2=CC=C3C4=C2C1=CC=C4C(=O)N1C2=CC=CC=C2N=C13.C1=CC=C2N(C(C3=CC=C4C(N5C6=CC=CC=C6N=C5C=5C=CC6=C3C4=5)=O)=O)C6=NC2=C1 BMZAOXGPXCPSTH-UHFFFAOYSA-N 0.000 description 1
- 239000002351 wastewater Substances 0.000 description 1
Classifications
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
- D06P1/00—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
- D06P1/44—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders
- D06P1/667—Organo-phosphorus compounds
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
- D06P1/00—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
- D06P1/22—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using vat dyestuffs including indigo
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
- D06P1/00—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
- D06P1/30—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using sulfur dyes
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
- D06P1/00—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
- D06P1/44—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders
- D06P1/60—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders using compositions containing polyethers
- D06P1/613—Polyethers without nitrogen
- D06P1/6138—Polymerisation products of glycols, e.g. Carbowax, Pluronics
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
- D06P1/00—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
- D06P1/44—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders
- D06P1/62—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders using compositions containing low-molecular-weight organic compounds with sulfate, sulfonate, sulfenic or sulfinic groups
- D06P1/628—Compounds containing nitrogen
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
- D06P3/00—Special processes of dyeing or printing textiles, or dyeing leather, furs, or solid macromolecular substances in any form, classified according to the material treated
- D06P3/58—Material containing hydroxyl groups
- D06P3/60—Natural or regenerated cellulose
- D06P3/66—Natural or regenerated cellulose using reactive dyes
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10S8/00—Bleaching and dyeing; fluid treatment and chemical modification of textiles and fibers
- Y10S8/916—Natural fiber dyeing
- Y10S8/918—Cellulose textile
Landscapes
- Engineering & Computer Science (AREA)
- Textile Engineering (AREA)
- Coloring (AREA)
Priority Applications (9)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DE19792930756 DE2930756A1 (de) | 1979-07-28 | 1979-07-28 | Klotzhilfsmittel und verfahren zum faerben von cellulosefasern bzw. gemischen von cellulosefasern zusammen mit synthesefasern mit schwefel-, schwefelkuepen-, kuepen- und reaktivfarbstoffen |
| US06/171,303 US4300903A (en) | 1979-07-28 | 1980-07-23 | Padding auxiliaries and processes for dyeing cellulose fibers or mixtures of cellulose fibers and synthetic fibers with sulphur dyestuffs, sulphur vat dyestuffs, vat dyestuffs and reactive dyestuffs |
| EP80104312A EP0023341B1 (de) | 1979-07-28 | 1980-07-23 | Klotzhilfsmittel, Verfahren zu seiner Herstellung und Verfahren zum Färben von Cellulosefasern bzw. Gemischen von Cellulosefasern zusammen mit Synthesefasern mit Schwefel-, Schwefelküpen-, Küpen- und Reaktivfarbstoffen |
| DE8080104312T DE3066276D1 (en) | 1979-07-28 | 1980-07-23 | Padding aid, process for its preparation and process for dyeing cellulosic fibres or mixtures of cellulosic fibres together with synthetic fibres with sulphur, sulphur vat, vat and reactive dyestuffs |
| AT80104312T ATE5981T1 (de) | 1979-07-28 | 1980-07-23 | Klotzhilfsmittel, verfahren zu seiner herstellung und verfahren zum faerben von cellulosefasern bzw. gemischen von cellulosefasern zusammen mit synthesefasern mit schwefel-, schwefelkuepen-, kuepen- und reaktivfarbstoffen. |
| JP10140480A JPS5620685A (en) | 1979-07-28 | 1980-07-25 | Dyeing of cellulose fiber or mixture of cellulose fiber and synthetic fiber by sulfide * sulfide vat * vat and reactive dyestuff and padding auxiliary agent |
| ZA00804515A ZA804515B (en) | 1979-07-28 | 1980-07-25 | Padding auxiliaries and processes for dyeing cellulose fibres or mixtures of cellulose fibres and synthetic fibres with sulphur dyestuffs, sulphur vat dyestuffs, vat dyestuffs and reactivedyestuffs |
| AR281910A AR222237A1 (es) | 1979-07-28 | 1980-07-25 | Agentes auxiliares de impregnacion y procedimiento para tenir fibras |
| BR8004717A BR8004717A (pt) | 1979-07-28 | 1980-07-28 | Composicao auxiliar de tingimento e processo para o tingimento de fibras de celulose ou misturas de fibras de celulose juntamente com fibras sinteticas com corantes de enxofre,corantes de cuba de enxofre,corante de cuba e corantes reativos |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DE19792930756 DE2930756A1 (de) | 1979-07-28 | 1979-07-28 | Klotzhilfsmittel und verfahren zum faerben von cellulosefasern bzw. gemischen von cellulosefasern zusammen mit synthesefasern mit schwefel-, schwefelkuepen-, kuepen- und reaktivfarbstoffen |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| DE2930756A1 true DE2930756A1 (de) | 1981-02-26 |
Family
ID=6077078
Family Applications (2)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| DE19792930756 Withdrawn DE2930756A1 (de) | 1979-07-28 | 1979-07-28 | Klotzhilfsmittel und verfahren zum faerben von cellulosefasern bzw. gemischen von cellulosefasern zusammen mit synthesefasern mit schwefel-, schwefelkuepen-, kuepen- und reaktivfarbstoffen |
| DE8080104312T Expired DE3066276D1 (en) | 1979-07-28 | 1980-07-23 | Padding aid, process for its preparation and process for dyeing cellulosic fibres or mixtures of cellulosic fibres together with synthetic fibres with sulphur, sulphur vat, vat and reactive dyestuffs |
Family Applications After (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| DE8080104312T Expired DE3066276D1 (en) | 1979-07-28 | 1980-07-23 | Padding aid, process for its preparation and process for dyeing cellulosic fibres or mixtures of cellulosic fibres together with synthetic fibres with sulphur, sulphur vat, vat and reactive dyestuffs |
Country Status (8)
| Country | Link |
|---|---|
| US (1) | US4300903A (enExample) |
| EP (1) | EP0023341B1 (enExample) |
| JP (1) | JPS5620685A (enExample) |
| AR (1) | AR222237A1 (enExample) |
| AT (1) | ATE5981T1 (enExample) |
| BR (1) | BR8004717A (enExample) |
| DE (2) | DE2930756A1 (enExample) |
| ZA (1) | ZA804515B (enExample) |
Families Citing this family (9)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| FR2551474B1 (fr) * | 1983-09-01 | 1986-12-05 | Sandoz Sa | Procede de traitement de matieres textiles cellulosiques |
| ES2011061B3 (es) * | 1986-04-07 | 1989-12-16 | Ciba-Geigy Ag | Procedimiento para la tintura de fibras celulosicas. |
| US4801303A (en) * | 1987-06-01 | 1989-01-31 | Sandoz Ltd. | One-bath dyeing of polyester-cellulosic blends using disperse and sulfur dyes |
| JPS63315680A (ja) * | 1987-06-17 | 1988-12-23 | 日本サ−ファクタント工業株式会社 | 反応性染料用均染剤及び染色方法 |
| US4886518A (en) * | 1987-10-01 | 1989-12-12 | Ciba-Geigy Corporation | Dyeing cellulose fibres without incurring ending with colorless pyrimidine, triazine, aromatic, furfuryl or quinolinyl compound |
| JPH0241479A (ja) * | 1988-07-27 | 1990-02-09 | Dai Ichi Kogyo Seiyaku Co Ltd | セルロース繊維および半合成繊維用一浴精練染色助剤 |
| IL137672A0 (en) * | 2000-08-03 | 2001-10-31 | Dpharm Ltd | Derivatives of branched-chain lipophilic molecules and uses thereof |
| CN110105228B (zh) * | 2019-06-05 | 2020-07-28 | 中国科学院兰州化学物理研究所 | 一种质子型离子液体及其制备方法和作为水基润滑添加剂的应用 |
| EP4011987A1 (de) * | 2020-12-10 | 2022-06-15 | Clariant International Ltd | Salze von n,n-dialkyl-(sulfooxy)-fettsäureamidat als dispergiermittel für pigmentpräparationen |
Family Cites Families (10)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US2067927A (en) * | 1934-09-03 | 1937-01-19 | Nat Aniline & Chem Co Inc | Art of dyeing with vat dyes |
| FR847911A (fr) * | 1937-12-22 | 1939-10-19 | Ig Farbenindustrie Ag | Préparations et pâtes d'impression à base de colorants à cuve et procédé d'impression au moyen de ces produits |
| FR1396294A (fr) * | 1963-05-28 | 1965-04-16 | Hoechst Ag | Mouillant égalisant moussant peu |
| DE1245898C2 (de) * | 1964-10-23 | 1973-01-25 | Hoechst Ag | Schaumarmes, egalisierendes Netzmittel |
| US3657145A (en) * | 1967-12-01 | 1972-04-18 | Petrolite Corp | Demulsification with linear polymeric phosphorus-containing esters |
| CH524722A (de) * | 1968-06-28 | 1972-03-15 | Sandoz Ag | Verfahren zur Herstellung egaler, endengleicher Färbungen mit wasserlöslichen Leukoschwefelsäureestern von Küpenfarbstoffen auf cellulosehaltigen Textilmaterialien |
| DE2036587B2 (de) * | 1970-07-23 | 1973-02-15 | Knapsack AG, 5033 Hurth Knapsack | Verfahren zur herstellung von phosphor- und halogenhaltigen polyolen |
| CA1050039A (en) * | 1974-05-28 | 1979-03-06 | Edward N. Walsh | Method of preparing stable condensation products using a lewis acid catalyst |
| MX143103A (es) * | 1975-05-28 | 1981-03-17 | Hoechst Ag | Composiciones mejorada de colorantes de dispersion |
| US4198204A (en) * | 1976-11-27 | 1980-04-15 | Hoechst Aktiengesellschaft | Short liquor dyeing process for piece goods, made from cellulose fibers, in rope form |
-
1979
- 1979-07-28 DE DE19792930756 patent/DE2930756A1/de not_active Withdrawn
-
1980
- 1980-07-23 DE DE8080104312T patent/DE3066276D1/de not_active Expired
- 1980-07-23 EP EP80104312A patent/EP0023341B1/de not_active Expired
- 1980-07-23 AT AT80104312T patent/ATE5981T1/de active
- 1980-07-23 US US06/171,303 patent/US4300903A/en not_active Expired - Lifetime
- 1980-07-25 AR AR281910A patent/AR222237A1/es active
- 1980-07-25 JP JP10140480A patent/JPS5620685A/ja active Granted
- 1980-07-25 ZA ZA00804515A patent/ZA804515B/xx unknown
- 1980-07-28 BR BR8004717A patent/BR8004717A/pt unknown
Also Published As
| Publication number | Publication date |
|---|---|
| DE3066276D1 (en) | 1984-03-01 |
| BR8004717A (pt) | 1981-02-10 |
| JPS6343508B2 (enExample) | 1988-08-31 |
| ATE5981T1 (de) | 1984-02-15 |
| EP0023341B1 (de) | 1984-01-25 |
| JPS5620685A (en) | 1981-02-26 |
| AR222237A1 (es) | 1981-04-30 |
| EP0023341A2 (de) | 1981-02-04 |
| US4300903A (en) | 1981-11-17 |
| EP0023341A3 (en) | 1981-07-08 |
| ZA804515B (en) | 1981-07-29 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| 8130 | Withdrawal |