DE2841545C2 - Leuchtendes Erdalkaliphosphat - Google Patents
Leuchtendes ErdalkaliphosphatInfo
- Publication number
- DE2841545C2 DE2841545C2 DE2841545A DE2841545A DE2841545C2 DE 2841545 C2 DE2841545 C2 DE 2841545C2 DE 2841545 A DE2841545 A DE 2841545A DE 2841545 A DE2841545 A DE 2841545A DE 2841545 C2 DE2841545 C2 DE 2841545C2
- Authority
- DE
- Germany
- Prior art keywords
- luminous
- alkaline earth
- phosphate
- substances
- formula
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 229910019142 PO4 Inorganic materials 0.000 title claims description 33
- NBIIXXVUZAFLBC-UHFFFAOYSA-K phosphate Chemical compound [O-]P([O-])([O-])=O NBIIXXVUZAFLBC-UHFFFAOYSA-K 0.000 title claims description 20
- 239000010452 phosphate Substances 0.000 title claims description 20
- 229910052684 Cerium Inorganic materials 0.000 claims description 14
- 229910052771 Terbium Inorganic materials 0.000 claims description 12
- 239000013078 crystal Substances 0.000 claims description 5
- 229910052712 strontium Inorganic materials 0.000 claims description 5
- 229910052746 lanthanum Inorganic materials 0.000 claims description 4
- 229910052688 Gadolinium Inorganic materials 0.000 claims description 3
- 229910004283 SiO 4 Inorganic materials 0.000 claims description 3
- 229910052765 Lutetium Inorganic materials 0.000 claims description 2
- 229910052784 alkaline earth metal Inorganic materials 0.000 claims description 2
- 150000001342 alkaline earth metals Chemical class 0.000 claims description 2
- 229910052727 yttrium Inorganic materials 0.000 claims description 2
- 239000011575 calcium Substances 0.000 description 28
- 235000021317 phosphate Nutrition 0.000 description 27
- 239000000126 substance Substances 0.000 description 23
- 230000004907 flux Effects 0.000 description 14
- 150000003013 phosphoric acid derivatives Chemical class 0.000 description 12
- 150000001875 compounds Chemical class 0.000 description 8
- 239000000203 mixture Substances 0.000 description 7
- 230000005855 radiation Effects 0.000 description 7
- 239000012190 activator Substances 0.000 description 6
- 238000004519 manufacturing process Methods 0.000 description 6
- 238000010438 heat treatment Methods 0.000 description 5
- OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 description 4
- 229910052787 antimony Inorganic materials 0.000 description 4
- QSHDDOUJBYECFT-UHFFFAOYSA-N mercury Chemical compound [Hg] QSHDDOUJBYECFT-UHFFFAOYSA-N 0.000 description 4
- 238000001228 spectrum Methods 0.000 description 4
- 230000005284 excitation Effects 0.000 description 3
- 230000003595 spectral effect Effects 0.000 description 3
- 230000003213 activating effect Effects 0.000 description 2
- 150000004645 aluminates Chemical class 0.000 description 2
- 229910052788 barium Inorganic materials 0.000 description 2
- 238000009826 distribution Methods 0.000 description 2
- 150000002500 ions Chemical class 0.000 description 2
- 238000005259 measurement Methods 0.000 description 2
- 229910052756 noble gas Inorganic materials 0.000 description 2
- 101150058765 BACE1 gene Proteins 0.000 description 1
- OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 description 1
- 101150027751 Casr gene Proteins 0.000 description 1
- 229910052779 Neodymium Inorganic materials 0.000 description 1
- BPQQTUXANYXVAA-UHFFFAOYSA-N Orthosilicate Chemical group [O-][Si]([O-])([O-])[O-] BPQQTUXANYXVAA-UHFFFAOYSA-N 0.000 description 1
- ATJFFYVFTNAWJD-UHFFFAOYSA-N Tin Chemical compound [Sn] ATJFFYVFTNAWJD-UHFFFAOYSA-N 0.000 description 1
- WATWJIUSRGPENY-UHFFFAOYSA-N antimony atom Chemical compound [Sb] WATWJIUSRGPENY-UHFFFAOYSA-N 0.000 description 1
- 230000008033 biological extinction Effects 0.000 description 1
- 229910052791 calcium Inorganic materials 0.000 description 1
- ZMIGMASIKSOYAM-UHFFFAOYSA-N cerium Chemical compound [Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce] ZMIGMASIKSOYAM-UHFFFAOYSA-N 0.000 description 1
- 230000000052 comparative effect Effects 0.000 description 1
- 239000004744 fabric Substances 0.000 description 1
- 239000011521 glass Substances 0.000 description 1
- 229910052738 indium Inorganic materials 0.000 description 1
- 229910052500 inorganic mineral Inorganic materials 0.000 description 1
- 229910052909 inorganic silicate Inorganic materials 0.000 description 1
- 238000004020 luminiscence type Methods 0.000 description 1
- 229910052748 manganese Inorganic materials 0.000 description 1
- 229910052753 mercury Inorganic materials 0.000 description 1
- 238000000034 method Methods 0.000 description 1
- 239000011707 mineral Substances 0.000 description 1
- 150000002835 noble gases Chemical class 0.000 description 1
- CVPJXKJISAFJDU-UHFFFAOYSA-A nonacalcium;magnesium;hydrogen phosphate;iron(2+);hexaphosphate Chemical group [Mg+2].[Ca+2].[Ca+2].[Ca+2].[Ca+2].[Ca+2].[Ca+2].[Ca+2].[Ca+2].[Ca+2].[Fe+2].OP([O-])([O-])=O.OP([O-])([O-])=O.[O-]P([O-])([O-])=O.[O-]P([O-])([O-])=O.[O-]P([O-])([O-])=O.[O-]P([O-])([O-])=O.[O-]P([O-])([O-])=O.[O-]P([O-])([O-])=O CVPJXKJISAFJDU-UHFFFAOYSA-A 0.000 description 1
- VSIIXMUUUJUKCM-UHFFFAOYSA-D pentacalcium;fluoride;triphosphate Chemical group [F-].[Ca+2].[Ca+2].[Ca+2].[Ca+2].[Ca+2].[O-]P([O-])([O-])=O.[O-]P([O-])([O-])=O.[O-]P([O-])([O-])=O VSIIXMUUUJUKCM-UHFFFAOYSA-D 0.000 description 1
- 125000002467 phosphate group Chemical group [H]OP(=O)(O[H])O[*] 0.000 description 1
- 238000002360 preparation method Methods 0.000 description 1
- 239000010453 quartz Substances 0.000 description 1
- 238000010791 quenching Methods 0.000 description 1
- 230000000171 quenching effect Effects 0.000 description 1
- 230000000717 retained effect Effects 0.000 description 1
- 229910052706 scandium Inorganic materials 0.000 description 1
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N silicon dioxide Inorganic materials O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
- 239000007858 starting material Substances 0.000 description 1
- 230000004936 stimulating effect Effects 0.000 description 1
- 238000006467 substitution reaction Methods 0.000 description 1
- 239000000725 suspension Substances 0.000 description 1
- 229910052718 tin Inorganic materials 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
- C09K11/00—Luminescent, e.g. electroluminescent, chemiluminescent materials
- C09K11/08—Luminescent, e.g. electroluminescent, chemiluminescent materials containing inorganic luminescent materials
- C09K11/77—Luminescent, e.g. electroluminescent, chemiluminescent materials containing inorganic luminescent materials containing rare earth metals
- C09K11/7766—Luminescent, e.g. electroluminescent, chemiluminescent materials containing inorganic luminescent materials containing rare earth metals containing two or more rare earth metals
- C09K11/7777—Phosphates
- C09K11/7778—Phosphates with alkaline earth metals
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
- C09K11/00—Luminescent, e.g. electroluminescent, chemiluminescent materials
- C09K11/08—Luminescent, e.g. electroluminescent, chemiluminescent materials containing inorganic luminescent materials
- C09K11/77—Luminescent, e.g. electroluminescent, chemiluminescent materials containing inorganic luminescent materials containing rare earth metals
- C09K11/7709—Phosphates
- C09K11/771—Phosphates with alkaline earth metals
Landscapes
- Chemical & Material Sciences (AREA)
- Inorganic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Organic Chemistry (AREA)
- Luminescent Compositions (AREA)
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| NLAANVRAGE7710776,A NL186458B (nl) | 1977-10-03 | 1977-10-03 | Werkwijze voor de bereiding van een luminescerend aardalkalimetaalfosfaat; luminescerend scherm; lagedrukkwikdampontladingslamp. |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| DE2841545A1 DE2841545A1 (de) | 1979-04-12 |
| DE2841545C2 true DE2841545C2 (de) | 1986-03-13 |
Family
ID=19829274
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| DE2841545A Expired DE2841545C2 (de) | 1977-10-03 | 1978-09-23 | Leuchtendes Erdalkaliphosphat |
Country Status (7)
| Country | Link |
|---|---|
| US (1) | US4151443A (enExample) |
| JP (1) | JPS5457480A (enExample) |
| CA (1) | CA1111634A (enExample) |
| DE (1) | DE2841545C2 (enExample) |
| FR (1) | FR2404663A1 (enExample) |
| GB (1) | GB2009217B (enExample) |
| NL (1) | NL186458B (enExample) |
Families Citing this family (9)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| NL7807274A (nl) * | 1978-03-10 | 1979-09-12 | Philips Nv | Luminescerende stof, luminescerend scherm voorzien van een dergelijke stof en lagedrukkwikdampontladingslamp voorzien van een dergelijk scherm. |
| JPS6010065B2 (ja) * | 1981-06-16 | 1985-03-14 | 株式会社東芝 | 緑色発光螢光体 |
| JPS57207678A (en) * | 1981-06-18 | 1982-12-20 | Toshiba Corp | Fluorescent lamp |
| DE3431692A1 (de) * | 1984-08-29 | 1986-03-06 | Friedrich 7800 Freiburg Wolff | Leuchtstofflampe |
| WO1994029403A1 (en) * | 1993-01-13 | 1994-12-22 | Mickellsun Pty. Ltd. | Luminescent material |
| JP2008222988A (ja) * | 2007-03-16 | 2008-09-25 | Nagoya Institute Of Technology | 広帯域発光蛍光体及びその製造方法並びに母体の選択方法 |
| CN101824322A (zh) * | 2009-03-05 | 2010-09-08 | 建兴电子科技股份有限公司 | 荧光材料及应用其的荧光灯 |
| EP2532725B1 (en) * | 2010-02-04 | 2014-11-26 | Ocean's King Lighting Science&Technology Co., Ltd. | Terbium doped phosphate-based green luminescent material and preparation method thereof |
| DE102010045368A1 (de) * | 2010-09-14 | 2012-03-15 | Merck Patent Gmbh | Silicophosphat-Leuchtstoffe |
Family Cites Families (9)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3025423A (en) * | 1959-05-04 | 1962-03-13 | Westinghouse Electric Corp | Lamp, phosphor and method |
| FR1260254A (fr) * | 1960-05-03 | 1961-05-05 | Westinghouse Electric Corp | Fabrication d'une nouvelle matière luminescente |
| DE1263204B (de) * | 1966-01-13 | 1968-03-14 | Berliner Gluehlampen Werk Veb | Erdalkali-Yttrium-Orthophosphat-Leuchtstoffe, insbesondere fuer Hochdruckquecksilberdampfentladungslampen |
| US3422024A (en) * | 1966-02-03 | 1969-01-14 | Westinghouse Electric Corp | Strontium and barium substituted lanthanum phosphate phosphors |
| US3525698A (en) * | 1967-10-20 | 1970-08-25 | American Cyanamid Co | Cerium and lanthanide activated alkaline earth metal phosphate phosphors |
| FR1590705A (enExample) * | 1968-09-26 | 1970-04-20 | ||
| US3893939A (en) * | 1973-01-04 | 1975-07-08 | Us Energy | Activated phosphors having matrices of yttrium-transition metal compound |
| NL7307627A (enExample) * | 1973-06-01 | 1974-12-03 | ||
| NL7508990A (nl) * | 1974-08-06 | 1976-02-10 | Thorn Electrical Ind Ltd | Luminescerende materialen en hun bereiding. |
-
1977
- 1977-10-03 NL NLAANVRAGE7710776,A patent/NL186458B/xx not_active Application Discontinuation
-
1978
- 1978-08-24 US US05/936,398 patent/US4151443A/en not_active Expired - Lifetime
- 1978-09-23 DE DE2841545A patent/DE2841545C2/de not_active Expired
- 1978-09-28 CA CA312,266A patent/CA1111634A/en not_active Expired
- 1978-09-29 GB GB7838621A patent/GB2009217B/en not_active Expired
- 1978-09-29 FR FR7827901A patent/FR2404663A1/fr active Granted
- 1978-09-30 JP JP11993778A patent/JPS5457480A/ja active Granted
Also Published As
| Publication number | Publication date |
|---|---|
| US4151443A (en) | 1979-04-24 |
| DE2841545A1 (de) | 1979-04-12 |
| JPS5457480A (en) | 1979-05-09 |
| FR2404663B1 (enExample) | 1983-01-07 |
| CA1111634A (en) | 1981-11-03 |
| FR2404663A1 (fr) | 1979-04-27 |
| GB2009217A (en) | 1979-06-13 |
| NL186458B (nl) | 1990-07-02 |
| JPS6118952B2 (enExample) | 1986-05-15 |
| GB2009217B (en) | 1982-03-17 |
| NL7710776A (nl) | 1979-04-05 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| 8110 | Request for examination paragraph 44 | ||
| D2 | Grant after examination | ||
| 8364 | No opposition during term of opposition | ||
| 8339 | Ceased/non-payment of the annual fee |