DE2819161C2 - Wäßriges alkalisches Zinkbad zur Elektroplattierung und Verfahren zur Abscheidung von Glanzzink aus diesem Bad - Google Patents
Wäßriges alkalisches Zinkbad zur Elektroplattierung und Verfahren zur Abscheidung von Glanzzink aus diesem BadInfo
- Publication number
- DE2819161C2 DE2819161C2 DE19782819161 DE2819161A DE2819161C2 DE 2819161 C2 DE2819161 C2 DE 2819161C2 DE 19782819161 DE19782819161 DE 19782819161 DE 2819161 A DE2819161 A DE 2819161A DE 2819161 C2 DE2819161 C2 DE 2819161C2
- Authority
- DE
- Germany
- Prior art keywords
- bath
- zinc
- quaternary ammonium
- alkyl
- formula
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 title claims description 38
- 229910052725 zinc Inorganic materials 0.000 title claims description 38
- 239000011701 zinc Substances 0.000 title claims description 38
- 238000009713 electroplating Methods 0.000 title claims description 5
- 230000008021 deposition Effects 0.000 title description 3
- 238000000034 method Methods 0.000 title description 3
- 125000004432 carbon atom Chemical group C* 0.000 claims description 13
- 125000000217 alkyl group Chemical group 0.000 claims description 12
- -1 quaternary ammonium halide Chemical class 0.000 claims description 12
- 239000007795 chemical reaction product Substances 0.000 claims description 11
- 150000003856 quaternary ammonium compounds Chemical class 0.000 claims description 10
- 229910052736 halogen Inorganic materials 0.000 claims description 8
- PTFCDOFLOPIGGS-UHFFFAOYSA-N Zinc dication Chemical compound [Zn+2] PTFCDOFLOPIGGS-UHFFFAOYSA-N 0.000 claims description 6
- QJGQUHMNIGDVPM-UHFFFAOYSA-N nitrogen group Chemical group [N] QJGQUHMNIGDVPM-UHFFFAOYSA-N 0.000 claims description 6
- 229920000642 polymer Polymers 0.000 claims description 6
- 125000003178 carboxy group Chemical group [H]OC(*)=O 0.000 claims description 4
- 150000002367 halogens Chemical class 0.000 claims description 4
- 125000003545 alkoxy group Chemical group 0.000 claims description 3
- 239000002738 chelating agent Substances 0.000 claims description 3
- 125000002768 hydroxyalkyl group Chemical group 0.000 claims description 3
- 239000000654 additive Substances 0.000 claims description 2
- 125000004433 nitrogen atom Chemical group N* 0.000 claims description 2
- 150000002894 organic compounds Chemical class 0.000 claims description 2
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 36
- 238000000576 coating method Methods 0.000 description 17
- 239000011248 coating agent Substances 0.000 description 11
- 229910052751 metal Inorganic materials 0.000 description 11
- 239000002184 metal Substances 0.000 description 11
- 239000000047 product Substances 0.000 description 9
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 8
- 150000001875 compounds Chemical class 0.000 description 8
- 229910052757 nitrogen Inorganic materials 0.000 description 5
- CSPHGSFZFWKVDL-UHFFFAOYSA-M (3-chloro-2-hydroxypropyl)-trimethylazanium;chloride Chemical compound [Cl-].C[N+](C)(C)CC(O)CCl CSPHGSFZFWKVDL-UHFFFAOYSA-M 0.000 description 4
- XFXPMWWXUTWYJX-UHFFFAOYSA-N Cyanide Chemical compound N#[C-] XFXPMWWXUTWYJX-UHFFFAOYSA-N 0.000 description 4
- XLOMVQKBTHCTTD-UHFFFAOYSA-N Zinc monoxide Chemical compound [Zn]=O XLOMVQKBTHCTTD-UHFFFAOYSA-N 0.000 description 4
- KXZJHVJKXJLBKO-UHFFFAOYSA-N chembl1408157 Chemical compound N=1C2=CC=CC=C2C(C(=O)O)=CC=1C1=CC=C(O)C=C1 KXZJHVJKXJLBKO-UHFFFAOYSA-N 0.000 description 4
- 239000003795 chemical substances by application Substances 0.000 description 4
- 238000007747 plating Methods 0.000 description 4
- 229920002873 Polyethylenimine Polymers 0.000 description 3
- 125000005843 halogen group Chemical group 0.000 description 3
- 239000000203 mixture Substances 0.000 description 3
- NWONKYPBYAMBJT-UHFFFAOYSA-L zinc sulfate Chemical compound [Zn+2].[O-]S([O-])(=O)=O NWONKYPBYAMBJT-UHFFFAOYSA-L 0.000 description 3
- NLXLAEXVIDQMFP-UHFFFAOYSA-N Ammonia chloride Chemical compound [NH4+].[Cl-] NLXLAEXVIDQMFP-UHFFFAOYSA-N 0.000 description 2
- PVNIIMVLHYAWGP-UHFFFAOYSA-N Niacin Chemical compound OC(=O)C1=CC=CN=C1 PVNIIMVLHYAWGP-UHFFFAOYSA-N 0.000 description 2
- 150000008044 alkali metal hydroxides Chemical class 0.000 description 2
- 125000004181 carboxyalkyl group Chemical group 0.000 description 2
- 238000006243 chemical reaction Methods 0.000 description 2
- 230000000052 comparative effect Effects 0.000 description 2
- 238000000151 deposition Methods 0.000 description 2
- 238000009472 formulation Methods 0.000 description 2
- 239000007788 liquid Substances 0.000 description 2
- ZRSNZINYAWTAHE-UHFFFAOYSA-N p-methoxybenzaldehyde Chemical compound COC1=CC=C(C=O)C=C1 ZRSNZINYAWTAHE-UHFFFAOYSA-N 0.000 description 2
- 238000006116 polymerization reaction Methods 0.000 description 2
- 159000000000 sodium salts Chemical class 0.000 description 2
- 239000007858 starting material Substances 0.000 description 2
- FAGUFWYHJQFNRV-UHFFFAOYSA-N tetraethylenepentamine Chemical compound NCCNCCNCCNCCN FAGUFWYHJQFNRV-UHFFFAOYSA-N 0.000 description 2
- 239000011787 zinc oxide Substances 0.000 description 2
- KWIUHFFTVRNATP-UHFFFAOYSA-N Betaine Natural products C[N+](C)(C)CC([O-])=O KWIUHFFTVRNATP-UHFFFAOYSA-N 0.000 description 1
- KCXVZYZYPLLWCC-UHFFFAOYSA-N EDTA Chemical compound OC(=O)CN(CC(O)=O)CCN(CC(O)=O)CC(O)=O KCXVZYZYPLLWCC-UHFFFAOYSA-N 0.000 description 1
- IMROMDMJAWUWLK-UHFFFAOYSA-N Ethenol Chemical compound OC=C IMROMDMJAWUWLK-UHFFFAOYSA-N 0.000 description 1
- 108010010803 Gelatin Proteins 0.000 description 1
- KWIUHFFTVRNATP-UHFFFAOYSA-O N,N,N-trimethylglycinium Chemical compound C[N+](C)(C)CC(O)=O KWIUHFFTVRNATP-UHFFFAOYSA-O 0.000 description 1
- 239000001888 Peptone Substances 0.000 description 1
- 108010080698 Peptones Proteins 0.000 description 1
- 239000004698 Polyethylene Substances 0.000 description 1
- 239000004372 Polyvinyl alcohol Substances 0.000 description 1
- 229910000831 Steel Inorganic materials 0.000 description 1
- 125000000218 acetic acid group Chemical group C(C)(=O)* 0.000 description 1
- 150000001299 aldehydes Chemical class 0.000 description 1
- 229910052783 alkali metal Inorganic materials 0.000 description 1
- 230000029936 alkylation Effects 0.000 description 1
- 238000005804 alkylation reaction Methods 0.000 description 1
- 150000001412 amines Chemical class 0.000 description 1
- 125000003277 amino group Chemical group 0.000 description 1
- 235000019270 ammonium chloride Nutrition 0.000 description 1
- 150000003868 ammonium compounds Chemical class 0.000 description 1
- KCXMKQUNVWSEMD-UHFFFAOYSA-N benzyl chloride Chemical compound ClCC1=CC=CC=C1 KCXMKQUNVWSEMD-UHFFFAOYSA-N 0.000 description 1
- 229940073608 benzyl chloride Drugs 0.000 description 1
- 229960003237 betaine Drugs 0.000 description 1
- 230000006378 damage Effects 0.000 description 1
- 238000000354 decomposition reaction Methods 0.000 description 1
- 238000004070 electrodeposition Methods 0.000 description 1
- 125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 description 1
- 229920000159 gelatin Polymers 0.000 description 1
- 239000008273 gelatin Substances 0.000 description 1
- 235000019322 gelatine Nutrition 0.000 description 1
- 235000011852 gelatine desserts Nutrition 0.000 description 1
- 239000003292 glue Substances 0.000 description 1
- 150000002314 glycerols Chemical class 0.000 description 1
- 125000004435 hydrogen atom Chemical group [H]* 0.000 description 1
- 125000001449 isopropyl group Chemical group [H]C([H])([H])C([H])(*)C([H])([H])[H] 0.000 description 1
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 1
- 125000004123 n-propyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])* 0.000 description 1
- 229960003512 nicotinic acid Drugs 0.000 description 1
- 235000001968 nicotinic acid Nutrition 0.000 description 1
- 239000011664 nicotinic acid Substances 0.000 description 1
- MGFYIUFZLHCRTH-UHFFFAOYSA-N nitrilotriacetic acid Chemical compound OC(=O)CN(CC(O)=O)CC(O)=O MGFYIUFZLHCRTH-UHFFFAOYSA-N 0.000 description 1
- 150000003867 organic ammonium compounds Chemical class 0.000 description 1
- 235000019319 peptone Nutrition 0.000 description 1
- 229920001281 polyalkylene Polymers 0.000 description 1
- 229920000573 polyethylene Polymers 0.000 description 1
- 229920002451 polyvinyl alcohol Polymers 0.000 description 1
- 125000002924 primary amino group Chemical group [H]N([H])* 0.000 description 1
- 125000001453 quaternary ammonium group Chemical group 0.000 description 1
- 238000005956 quaternization reaction Methods 0.000 description 1
- 239000000376 reactant Substances 0.000 description 1
- 238000010992 reflux Methods 0.000 description 1
- 150000003839 salts Chemical class 0.000 description 1
- DLPNNXVXJKWJTK-UHFFFAOYSA-M sodium;hydroxy-(4-methoxyphenyl)methanesulfonate Chemical compound [Na+].COC1=CC=C(C(O)S([O-])(=O)=O)C=C1 DLPNNXVXJKWJTK-UHFFFAOYSA-M 0.000 description 1
- 239000010959 steel Substances 0.000 description 1
- 238000006467 substitution reaction Methods 0.000 description 1
- 150000003512 tertiary amines Chemical class 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
- C25D—PROCESSES FOR THE ELECTROLYTIC OR ELECTROPHORETIC PRODUCTION OF COATINGS; ELECTROFORMING; APPARATUS THEREFOR
- C25D3/00—Electroplating: Baths therefor
- C25D3/02—Electroplating: Baths therefor from solutions
- C25D3/22—Electroplating: Baths therefor from solutions of zinc
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G73/00—Macromolecular compounds obtained by reactions forming a linkage containing nitrogen with or without oxygen or carbon in the main chain of the macromolecule, not provided for in groups C08G12/00 - C08G71/00
- C08G73/02—Polyamines
- C08G73/0206—Polyalkylene(poly)amines
- C08G73/0213—Preparatory process
- C08G73/0226—Quaternisation of polyalkylene(poly)amines
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Engineering & Computer Science (AREA)
- Polymers & Plastics (AREA)
- Medicinal Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Electrochemistry (AREA)
- Materials Engineering (AREA)
- Metallurgy (AREA)
- Electroplating And Plating Baths Therefor (AREA)
- Electrolytic Production Of Non-Metals, Compounds, Apparatuses Therefor (AREA)
- Macromolecular Compounds Obtained By Forming Nitrogen-Containing Linkages In General (AREA)
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US79380577A | 1977-05-04 | 1977-05-04 |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| DE2819161A1 DE2819161A1 (de) | 1978-11-16 |
| DE2819161C2 true DE2819161C2 (de) | 1982-11-11 |
Family
ID=25160844
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| DE19782819161 Expired DE2819161C2 (de) | 1977-05-04 | 1978-05-02 | Wäßriges alkalisches Zinkbad zur Elektroplattierung und Verfahren zur Abscheidung von Glanzzink aus diesem Bad |
Country Status (7)
| Country | Link |
|---|---|
| JP (1) | JPS53137833A (enrdf_load_stackoverflow) |
| AU (1) | AU519624B2 (enrdf_load_stackoverflow) |
| CA (1) | CA1119997A (enrdf_load_stackoverflow) |
| DE (1) | DE2819161C2 (enrdf_load_stackoverflow) |
| FR (1) | FR2389688B1 (enrdf_load_stackoverflow) |
| GB (1) | GB1603446A (enrdf_load_stackoverflow) |
| NL (1) | NL185359C (enrdf_load_stackoverflow) |
Families Citing this family (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US5435898A (en) * | 1994-10-25 | 1995-07-25 | Enthone-Omi Inc. | Alkaline zinc and zinc alloy electroplating baths and processes |
| ES2416984T3 (es) * | 2010-09-21 | 2013-08-05 | Dr.Ing. Max Schlötter Gmbh & Co. Kg | Regeneración de electrolitos de cinc-níquel alcalinos mediante la eliminación de iones cianuro con la ayuda de compuestos de amonio cuaternario solubles |
| ES2681836T3 (es) * | 2015-09-10 | 2018-09-17 | Atotech Deutschland Gmbh | Composición de baño para chapado de cobre |
Family Cites Families (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3853718A (en) * | 1973-01-05 | 1974-12-10 | Oxy Metal Finishing Corp | Method to improve zinc deposition employing multi-nitrogen quaternaries |
| FR2276394A2 (fr) * | 1974-06-28 | 1976-01-23 | Popescu Francine | Zingage electrolytique brillant en bain alcalin |
-
1978
- 1978-04-11 CA CA000300888A patent/CA1119997A/en not_active Expired
- 1978-04-21 FR FR7811895A patent/FR2389688B1/fr not_active Expired
- 1978-04-28 GB GB1699178A patent/GB1603446A/en not_active Expired
- 1978-05-02 DE DE19782819161 patent/DE2819161C2/de not_active Expired
- 1978-05-03 AU AU35726/78A patent/AU519624B2/en not_active Expired
- 1978-05-03 NL NL7804809A patent/NL185359C/xx not_active IP Right Cessation
- 1978-05-04 JP JP5364078A patent/JPS53137833A/ja active Granted
Also Published As
| Publication number | Publication date |
|---|---|
| NL185359C (nl) | 1990-03-16 |
| AU519624B2 (en) | 1981-12-17 |
| NL7804809A (nl) | 1978-11-07 |
| NL185359B (nl) | 1989-10-16 |
| GB1603446A (en) | 1981-11-25 |
| JPS5628997B2 (enrdf_load_stackoverflow) | 1981-07-06 |
| FR2389688B1 (enrdf_load_stackoverflow) | 1983-01-28 |
| DE2819161A1 (de) | 1978-11-16 |
| CA1119997A (en) | 1982-03-16 |
| JPS53137833A (en) | 1978-12-01 |
| FR2389688A1 (enrdf_load_stackoverflow) | 1978-12-01 |
| AU3572678A (en) | 1979-11-08 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| OAP | Request for examination filed | ||
| OD | Request for examination | ||
| D2 | Grant after examination | ||
| 8380 | Miscellaneous part iii |
Free format text: DER VERTRETER IST NACHZUTRAGEN HAUCK, H., DIPL.-ING. DIPL.-WIRTSCH.-ING. SCHMITZ, W., DIPL-PHYS. GRAALFS, E., DIPL.-ING. WEHNERT, W., DIPL.-ING. CARSTENS, W., DIPL.-PHYS. DOERING, W., DR.-ING., PAT.-ANW., 2000 HAMBURG, 8000 MUENCHEN U.4000 DUESSELDORF |
|
| 8327 | Change in the person/name/address of the patent owner |
Owner name: OMI INTERNATIONAL CORP. (EINE GESELLSCHAFT N.D.GES |
|
| 8328 | Change in the person/name/address of the agent |
Free format text: HAUCK, H., DIPL.-ING. DIPL.-WIRTSCH.-ING., 8000 MUENCHEN SCHMITZ, W., DIPL.-PHYS. GRAALFS, E., DIPL.-ING., 2000 HAMBURG WEHNERT, W., DIPL.-ING., 8000 MUENCHEN DOERING, W., DIPL.-WIRTSCH.-ING. DR.-ING., PAT.-ANW., 4000 DUESSELDORF |
|
| 8339 | Ceased/non-payment of the annual fee |