DE2724360C3 - Verfahren zur Herstellung von thermoplastischen Formmassen auf Basis von Vinylpolymerisaten - Google Patents
Verfahren zur Herstellung von thermoplastischen Formmassen auf Basis von VinylpolymerisatenInfo
- Publication number
- DE2724360C3 DE2724360C3 DE2724360A DE2724360A DE2724360C3 DE 2724360 C3 DE2724360 C3 DE 2724360C3 DE 2724360 A DE2724360 A DE 2724360A DE 2724360 A DE2724360 A DE 2724360A DE 2724360 C3 DE2724360 C3 DE 2724360C3
- Authority
- DE
- Germany
- Prior art keywords
- evaporator
- monomers
- stage
- polymerization
- styrene
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 238000000034 method Methods 0.000 title claims description 78
- 229920002554 vinyl polymer Polymers 0.000 title claims description 15
- 150000001875 compounds Chemical class 0.000 title claims description 7
- 238000009757 thermoplastic moulding Methods 0.000 title description 3
- 238000002360 preparation method Methods 0.000 title 1
- 239000000178 monomer Substances 0.000 claims description 153
- 239000000203 mixture Substances 0.000 claims description 61
- 229920000642 polymer Polymers 0.000 claims description 55
- 238000006116 polymerization reaction Methods 0.000 claims description 52
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 claims description 51
- 235000020357 syrup Nutrition 0.000 claims description 30
- 239000006188 syrup Substances 0.000 claims description 30
- 238000006243 chemical reaction Methods 0.000 claims description 21
- NLHHRLWOUZZQLW-UHFFFAOYSA-N Acrylonitrile Chemical compound C=CC#N NLHHRLWOUZZQLW-UHFFFAOYSA-N 0.000 claims description 17
- 125000004432 carbon atom Chemical group C* 0.000 claims description 16
- NIXOWILDQLNWCW-UHFFFAOYSA-N 2-Propenoic acid Natural products OC(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 claims description 11
- 238000012662 bulk polymerization Methods 0.000 claims description 10
- 239000007787 solid Substances 0.000 claims description 10
- 125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 claims description 9
- FPYJFEHAWHCUMM-UHFFFAOYSA-N maleic anhydride Chemical compound O=C1OC(=O)C=C1 FPYJFEHAWHCUMM-UHFFFAOYSA-N 0.000 claims description 8
- 239000011261 inert gas Substances 0.000 claims description 7
- SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Chemical compound COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 claims description 6
- 238000009833 condensation Methods 0.000 claims description 6
- 230000005494 condensation Effects 0.000 claims description 6
- 150000002148 esters Chemical group 0.000 claims description 6
- GYCMBHHDWRMZGG-UHFFFAOYSA-N Methylacrylonitrile Chemical compound CC(=C)C#N GYCMBHHDWRMZGG-UHFFFAOYSA-N 0.000 claims description 5
- 238000004519 manufacturing process Methods 0.000 claims description 5
- 238000003756 stirring Methods 0.000 claims description 5
- 238000004140 cleaning Methods 0.000 claims description 4
- 235000008504 concentrate Nutrition 0.000 claims description 4
- 239000012141 concentrate Substances 0.000 claims description 4
- 239000000126 substance Substances 0.000 claims description 4
- VVQNEPGJFQJSBK-UHFFFAOYSA-N Methyl methacrylate Chemical compound COC(=O)C(C)=C VVQNEPGJFQJSBK-UHFFFAOYSA-N 0.000 claims description 3
- XYLMUPLGERFSHI-UHFFFAOYSA-N alpha-Methylstyrene Chemical compound CC(=C)C1=CC=CC=C1 XYLMUPLGERFSHI-UHFFFAOYSA-N 0.000 claims description 3
- OIWOHHBRDFKZNC-UHFFFAOYSA-N cyclohexyl 2-methylprop-2-enoate Chemical compound CC(=C)C(=O)OC1CCCCC1 OIWOHHBRDFKZNC-UHFFFAOYSA-N 0.000 claims description 3
- 238000000465 moulding Methods 0.000 claims description 3
- 229920002959 polymer blend Polymers 0.000 claims description 3
- 238000004817 gas chromatography Methods 0.000 claims description 2
- 125000003011 styrenyl group Chemical group [H]\C(*)=C(/[H])C1=C([H])C([H])=C([H])C([H])=C1[H] 0.000 claims description 2
- 239000004793 Polystyrene Substances 0.000 claims 2
- 229920002223 polystyrene Polymers 0.000 claims 2
- 238000009826 distribution Methods 0.000 claims 1
- 229920001519 homopolymer Polymers 0.000 claims 1
- 125000005397 methacrylic acid ester group Chemical group 0.000 claims 1
- 238000011084 recovery Methods 0.000 claims 1
- 229920006163 vinyl copolymer Polymers 0.000 claims 1
- 238000001704 evaporation Methods 0.000 description 40
- 230000008020 evaporation Effects 0.000 description 40
- 241000237858 Gastropoda Species 0.000 description 22
- 239000000047 product Substances 0.000 description 21
- ZMXDDKWLCZADIW-UHFFFAOYSA-N N,N-Dimethylformamide Chemical compound CN(C)C=O ZMXDDKWLCZADIW-UHFFFAOYSA-N 0.000 description 20
- 241000270295 Serpentes Species 0.000 description 18
- 239000003999 initiator Substances 0.000 description 17
- 239000003380 propellant Substances 0.000 description 17
- -1 2-vinylnaphtha-Hn Chemical compound 0.000 description 14
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 14
- 239000007789 gas Substances 0.000 description 14
- IWDCLRJOBJJRNH-UHFFFAOYSA-N p-cresol Chemical compound CC1=CC=C(O)C=C1 IWDCLRJOBJJRNH-UHFFFAOYSA-N 0.000 description 8
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Chemical compound O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 8
- CERQOIWHTDAKMF-UHFFFAOYSA-N Methacrylic acid Chemical compound CC(=C)C(O)=O CERQOIWHTDAKMF-UHFFFAOYSA-N 0.000 description 7
- 239000012535 impurity Substances 0.000 description 7
- 239000003112 inhibitor Substances 0.000 description 7
- 238000002156 mixing Methods 0.000 description 7
- 229910052757 nitrogen Inorganic materials 0.000 description 7
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 6
- VZCYOOQTPOCHFL-UHFFFAOYSA-N trans-butenedioic acid Natural products OC(=O)C=CC(O)=O VZCYOOQTPOCHFL-UHFFFAOYSA-N 0.000 description 6
- NIXOWILDQLNWCW-UHFFFAOYSA-M Acrylate Chemical compound [O-]C(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-M 0.000 description 5
- CERQOIWHTDAKMF-UHFFFAOYSA-M Methacrylate Chemical compound CC(=C)C([O-])=O CERQOIWHTDAKMF-UHFFFAOYSA-M 0.000 description 5
- OFOBLEOULBTSOW-UHFFFAOYSA-N Propanedioic acid Natural products OC(=O)CC(O)=O OFOBLEOULBTSOW-UHFFFAOYSA-N 0.000 description 5
- 238000007334 copolymerization reaction Methods 0.000 description 5
- 239000011976 maleic acid Substances 0.000 description 5
- QQONPFPTGQHPMA-UHFFFAOYSA-N Propene Chemical compound CC=C QQONPFPTGQHPMA-UHFFFAOYSA-N 0.000 description 4
- 125000005907 alkyl ester group Chemical group 0.000 description 4
- 125000000217 alkyl group Chemical group 0.000 description 4
- 229920001577 copolymer Polymers 0.000 description 4
- VZCYOOQTPOCHFL-UPHRSURJSA-N maleic acid Chemical compound OC(=O)\C=C/C(O)=O VZCYOOQTPOCHFL-UPHRSURJSA-N 0.000 description 4
- 229920005989 resin Polymers 0.000 description 4
- 239000011347 resin Substances 0.000 description 4
- 239000002253 acid Substances 0.000 description 3
- 125000003158 alcohol group Chemical group 0.000 description 3
- 125000001931 aliphatic group Chemical group 0.000 description 3
- 238000001816 cooling Methods 0.000 description 3
- 125000000959 isobutyl group Chemical group [H]C([H])([H])C([H])(C([H])([H])[H])C([H])([H])* 0.000 description 3
- 150000002825 nitriles Chemical class 0.000 description 3
- 230000009257 reactivity Effects 0.000 description 3
- 125000000999 tert-butyl group Chemical group [H]C([H])([H])C(*)(C([H])([H])[H])C([H])([H])[H] 0.000 description 3
- BQBSIHIZDSHADD-UHFFFAOYSA-N 2-ethenyl-4,5-dihydro-1,3-oxazole Chemical class C=CC1=NCCO1 BQBSIHIZDSHADD-UHFFFAOYSA-N 0.000 description 2
- IQFZHXDXHQHURM-UHFFFAOYSA-N 2-methylprop-2-enenitrile 5-phenylpenta-2,4-dienenitrile Chemical compound CC(=C)C#N.N#CC=CC=CC1=CC=CC=C1 IQFZHXDXHQHURM-UHFFFAOYSA-N 0.000 description 2
- HRPVXLWXLXDGHG-UHFFFAOYSA-N Acrylamide Chemical compound NC(=O)C=C HRPVXLWXLXDGHG-UHFFFAOYSA-N 0.000 description 2
- NLZUEZXRPGMBCV-UHFFFAOYSA-N Butylhydroxytoluene Chemical compound CC1=CC(C(C)(C)C)=C(O)C(C(C)(C)C)=C1 NLZUEZXRPGMBCV-UHFFFAOYSA-N 0.000 description 2
- VZCYOOQTPOCHFL-OWOJBTEDSA-N Fumaric acid Chemical compound OC(=O)\C=C\C(O)=O VZCYOOQTPOCHFL-OWOJBTEDSA-N 0.000 description 2
- XTXRWKRVRITETP-UHFFFAOYSA-N Vinyl acetate Chemical compound CC(=O)OC=C XTXRWKRVRITETP-UHFFFAOYSA-N 0.000 description 2
- 238000009825 accumulation Methods 0.000 description 2
- 150000008065 acid anhydrides Chemical class 0.000 description 2
- XXROGKLTLUQVRX-UHFFFAOYSA-N allyl alcohol Chemical compound OCC=C XXROGKLTLUQVRX-UHFFFAOYSA-N 0.000 description 2
- 150000008064 anhydrides Chemical class 0.000 description 2
- 239000012267 brine Substances 0.000 description 2
- MKUWVMRNQOOSAT-UHFFFAOYSA-N but-3-en-2-ol Chemical compound CC(O)C=C MKUWVMRNQOOSAT-UHFFFAOYSA-N 0.000 description 2
- HGCIXCUEYOPUTN-UHFFFAOYSA-N cyclohexene Chemical compound C1CCC=CC1 HGCIXCUEYOPUTN-UHFFFAOYSA-N 0.000 description 2
- 150000005690 diesters Chemical class 0.000 description 2
- 238000002474 experimental method Methods 0.000 description 2
- 238000004508 fractional distillation Methods 0.000 description 2
- 235000011087 fumaric acid Nutrition 0.000 description 2
- 239000008187 granular material Substances 0.000 description 2
- 238000005469 granulation Methods 0.000 description 2
- 230000003179 granulation Effects 0.000 description 2
- 238000001746 injection moulding Methods 0.000 description 2
- 239000000463 material Substances 0.000 description 2
- NWVVVBRKAWDGAB-UHFFFAOYSA-N p-methoxyphenol Chemical compound COC1=CC=C(O)C=C1 NWVVVBRKAWDGAB-UHFFFAOYSA-N 0.000 description 2
- 238000004806 packaging method and process Methods 0.000 description 2
- 125000004805 propylene group Chemical group [H]C([H])([H])C([H])([*:1])C([H])([H])[*:2] 0.000 description 2
- 238000004064 recycling Methods 0.000 description 2
- HPALAKNZSZLMCH-UHFFFAOYSA-M sodium;chloride;hydrate Chemical compound O.[Na+].[Cl-] HPALAKNZSZLMCH-UHFFFAOYSA-M 0.000 description 2
- MWNQXXOSWHCCOZ-UHFFFAOYSA-L sodium;oxido carbonate Chemical compound [Na+].[O-]OC([O-])=O MWNQXXOSWHCCOZ-UHFFFAOYSA-L 0.000 description 2
- 239000000243 solution Substances 0.000 description 2
- 239000003381 stabilizer Substances 0.000 description 2
- 229920000638 styrene acrylonitrile Polymers 0.000 description 2
- VZGDMQKNWNREIO-UHFFFAOYSA-N tetrachloromethane Chemical compound ClC(Cl)(Cl)Cl VZGDMQKNWNREIO-UHFFFAOYSA-N 0.000 description 2
- 229920001567 vinyl ester resin Polymers 0.000 description 2
- OXYKVVLTXXXVRT-UHFFFAOYSA-N (4-chlorobenzoyl) 4-chlorobenzenecarboperoxoate Chemical compound C1=CC(Cl)=CC=C1C(=O)OOC(=O)C1=CC=C(Cl)C=C1 OXYKVVLTXXXVRT-UHFFFAOYSA-N 0.000 description 1
- NQQRXZOPZBKCNF-NSCUHMNNSA-N (e)-but-2-enamide Chemical compound C\C=C\C(N)=O NQQRXZOPZBKCNF-NSCUHMNNSA-N 0.000 description 1
- KYPOHTVBFVELTG-OWOJBTEDSA-N (e)-but-2-enedinitrile Chemical compound N#C\C=C\C#N KYPOHTVBFVELTG-OWOJBTEDSA-N 0.000 description 1
- REODWKCLDITYSQ-WLHGVMLRSA-N (e)-but-2-enedioic acid;5-phenylpenta-2,4-dienenitrile Chemical compound OC(=O)\C=C\C(O)=O.N#CC=CC=CC1=CC=CC=C1 REODWKCLDITYSQ-WLHGVMLRSA-N 0.000 description 1
- REODWKCLDITYSQ-BTJKTKAUSA-N (z)-but-2-enedioic acid;5-phenylpenta-2,4-dienenitrile Chemical compound OC(=O)\C=C/C(O)=O.N#CC=CC=CC1=CC=CC=C1 REODWKCLDITYSQ-BTJKTKAUSA-N 0.000 description 1
- WBYWAXJHAXSJNI-VOTSOKGWSA-M .beta-Phenylacrylic acid Natural products [O-]C(=O)\C=C\C1=CC=CC=C1 WBYWAXJHAXSJNI-VOTSOKGWSA-M 0.000 description 1
- QWUWMCYKGHVNAV-UHFFFAOYSA-N 1,2-dihydrostilbene Chemical group C=1C=CC=CC=1CCC1=CC=CC=C1 QWUWMCYKGHVNAV-UHFFFAOYSA-N 0.000 description 1
- BQTPKSBXMONSJI-UHFFFAOYSA-N 1-cyclohexylpyrrole-2,5-dione Chemical compound O=C1C=CC(=O)N1C1CCCCC1 BQTPKSBXMONSJI-UHFFFAOYSA-N 0.000 description 1
- IGGDKDTUCAWDAN-UHFFFAOYSA-N 1-vinylnaphthalene Chemical compound C1=CC=C2C(C=C)=CC=CC2=C1 IGGDKDTUCAWDAN-UHFFFAOYSA-N 0.000 description 1
- YAJYJWXEWKRTPO-UHFFFAOYSA-N 2,3,3,4,4,5-hexamethylhexane-2-thiol Chemical compound CC(C)C(C)(C)C(C)(C)C(C)(C)S YAJYJWXEWKRTPO-UHFFFAOYSA-N 0.000 description 1
- FXNDIJDIPNCZQJ-UHFFFAOYSA-N 2,4,4-trimethylpent-1-ene Chemical group CC(=C)CC(C)(C)C FXNDIJDIPNCZQJ-UHFFFAOYSA-N 0.000 description 1
- OEPOKWHJYJXUGD-UHFFFAOYSA-N 2-(3-phenylmethoxyphenyl)-1,3-thiazole-4-carbaldehyde Chemical compound O=CC1=CSC(C=2C=C(OCC=3C=CC=CC=3)C=CC=2)=N1 OEPOKWHJYJXUGD-UHFFFAOYSA-N 0.000 description 1
- GFZMFCVDDFHSJK-UHFFFAOYSA-N 2-(methylideneamino)acetonitrile Chemical compound C=NCC#N GFZMFCVDDFHSJK-UHFFFAOYSA-N 0.000 description 1
- SAADORAEBXDJQA-UHFFFAOYSA-N 2-cyanobut-2-enoic acid Chemical compound CC=C(C#N)C(O)=O SAADORAEBXDJQA-UHFFFAOYSA-N 0.000 description 1
- XWRBMHSLXKNRJX-UHFFFAOYSA-N 2-ethenyl-1-oxidopyridin-1-ium Chemical compound [O-][N+]1=CC=CC=C1C=C XWRBMHSLXKNRJX-UHFFFAOYSA-N 0.000 description 1
- UIUTYKKZYFMBHJ-UHFFFAOYSA-N 2-ethenylphenanthrene Chemical compound C1=CC=C2C3=CC=C(C=C)C=C3C=CC2=C1 UIUTYKKZYFMBHJ-UHFFFAOYSA-N 0.000 description 1
- UKQJZQQPMIFNHE-UHFFFAOYSA-N 2-isocyanatoprop-1-ene Chemical compound CC(=C)N=C=O UKQJZQQPMIFNHE-UHFFFAOYSA-N 0.000 description 1
- 125000004200 2-methoxyethyl group Chemical group [H]C([H])([H])OC([H])([H])C([H])([H])* 0.000 description 1
- PSZAEHPBBUYICS-UHFFFAOYSA-N 2-methylidenepropanedioic acid Chemical compound OC(=O)C(=C)C(O)=O PSZAEHPBBUYICS-UHFFFAOYSA-N 0.000 description 1
- SUSFNWSANCTERM-UHFFFAOYSA-N 2-methylprop-2-enenitrile;2-methylpropyl 2-methylprop-2-enoate Chemical compound CC(=C)C#N.CC(C)COC(=O)C(C)=C SUSFNWSANCTERM-UHFFFAOYSA-N 0.000 description 1
- FFODZTFGFDDGQQ-UHFFFAOYSA-N 2-methylprop-2-enoic acid;5-phenylpenta-2,4-dienenitrile Chemical compound CC(=C)C(O)=O.N#CC=CC=CC1=CC=CC=C1 FFODZTFGFDDGQQ-UHFFFAOYSA-N 0.000 description 1
- MEPDWZCRGIWINX-UHFFFAOYSA-N 2-methylprop-2-enoic acid;prop-2-enenitrile;styrene Chemical compound C=CC#N.CC(=C)C(O)=O.C=CC1=CC=CC=C1 MEPDWZCRGIWINX-UHFFFAOYSA-N 0.000 description 1
- WJQOZHYUIDYNHM-UHFFFAOYSA-N 2-tert-Butylphenol Chemical class CC(C)(C)C1=CC=CC=C1O WJQOZHYUIDYNHM-UHFFFAOYSA-N 0.000 description 1
- KGIGUEBEKRSTEW-UHFFFAOYSA-N 2-vinylpyridine Chemical compound C=CC1=CC=CC=N1 KGIGUEBEKRSTEW-UHFFFAOYSA-N 0.000 description 1
- ORNUPNRNNSVZTC-UHFFFAOYSA-N 2-vinylthiophene Chemical compound C=CC1=CC=CS1 ORNUPNRNNSVZTC-UHFFFAOYSA-N 0.000 description 1
- PYSRRFNXTXNWCD-UHFFFAOYSA-N 3-(2-phenylethenyl)furan-2,5-dione Chemical compound O=C1OC(=O)C(C=CC=2C=CC=CC=2)=C1 PYSRRFNXTXNWCD-UHFFFAOYSA-N 0.000 description 1
- MTJGVAJYTOXFJH-UHFFFAOYSA-N 3-aminonaphthalene-1,5-disulfonic acid Chemical compound C1=CC=C(S(O)(=O)=O)C2=CC(N)=CC(S(O)(=O)=O)=C21 MTJGVAJYTOXFJH-UHFFFAOYSA-N 0.000 description 1
- DPZYLEIWHTWHCU-UHFFFAOYSA-N 3-ethenylpyridine Chemical compound C=CC1=CC=CN=C1 DPZYLEIWHTWHCU-UHFFFAOYSA-N 0.000 description 1
- YNWJPOVPFGCGLE-UHFFFAOYSA-N 4,4-diethoxybut-1-enylsilane Chemical compound C(C)OC(CC=C[SiH3])OCC YNWJPOVPFGCGLE-UHFFFAOYSA-N 0.000 description 1
- GQWAOUOHRMHSHL-UHFFFAOYSA-N 4-ethenyl-n,n-dimethylaniline Chemical compound CN(C)C1=CC=C(C=C)C=C1 GQWAOUOHRMHSHL-UHFFFAOYSA-N 0.000 description 1
- KFDVPJUYSDEJTH-UHFFFAOYSA-N 4-ethenylpyridine Chemical compound C=CC1=CC=NC=C1 KFDVPJUYSDEJTH-UHFFFAOYSA-N 0.000 description 1
- UMKWZZPKADNTRP-UHFFFAOYSA-N 4-ethenylpyrimidine Chemical compound C=CC1=CC=NC=N1 UMKWZZPKADNTRP-UHFFFAOYSA-N 0.000 description 1
- YEYMTOQDNGGXRS-UHFFFAOYSA-N 5-ethenyl-2H-1,3-oxazol-2-id-4-one Chemical class C(=C)C1C(N=[C-]O1)=O YEYMTOQDNGGXRS-UHFFFAOYSA-N 0.000 description 1
- 239000004342 Benzoyl peroxide Substances 0.000 description 1
- OMPJBNCRMGITSC-UHFFFAOYSA-N Benzoylperoxide Chemical compound C=1C=CC=CC=1C(=O)OOC(=O)C1=CC=CC=C1 OMPJBNCRMGITSC-UHFFFAOYSA-N 0.000 description 1
- CYNYAGJEPMDAOP-UHFFFAOYSA-N C(C(C)C)OC(C(=C)C)=O.C(C=C)#N.C(C(=C)C)#N Chemical compound C(C(C)C)OC(C(=C)C)=O.C(C=C)#N.C(C(=C)C)#N CYNYAGJEPMDAOP-UHFFFAOYSA-N 0.000 description 1
- PPPIUUUJCWLSJJ-UHFFFAOYSA-N C1(C=C/C(=O)O1)=O.C(C)(=O)OC=C.C(=CC1=CC=CC=C1)C=CC#N Chemical compound C1(C=C/C(=O)O1)=O.C(C)(=O)OC=C.C(=CC1=CC=CC=C1)C=CC#N PPPIUUUJCWLSJJ-UHFFFAOYSA-N 0.000 description 1
- HHYDMHXHGSXDKN-UHFFFAOYSA-N C1(C=C/C(=O)O1)=O.COC(C(=C)C)=O.C1(CCCCC1)OC(C(=C)C)=O Chemical compound C1(C=C/C(=O)O1)=O.COC(C(=C)C)=O.C1(CCCCC1)OC(C(=C)C)=O HHYDMHXHGSXDKN-UHFFFAOYSA-N 0.000 description 1
- WVPZMWPETUAYTP-UHFFFAOYSA-N CC(=O)C=C.N#CC=CC=CC1=CC=CC=C1 Chemical compound CC(=O)C=C.N#CC=CC=CC1=CC=CC=C1 WVPZMWPETUAYTP-UHFFFAOYSA-N 0.000 description 1
- WBYWAXJHAXSJNI-SREVYHEPSA-N Cinnamic acid Chemical compound OC(=O)\C=C/C1=CC=CC=C1 WBYWAXJHAXSJNI-SREVYHEPSA-N 0.000 description 1
- VQTUBCCKSQIDNK-UHFFFAOYSA-N Isobutene Chemical group CC(C)=C VQTUBCCKSQIDNK-UHFFFAOYSA-N 0.000 description 1
- YIVJZNGAASQVEM-UHFFFAOYSA-N Lauroyl peroxide Chemical compound CCCCCCCCCCCC(=O)OOC(=O)CCCCCCCCCCC YIVJZNGAASQVEM-UHFFFAOYSA-N 0.000 description 1
- MPQRDVWUOXDFJO-UHFFFAOYSA-N O=C1OC(=O)C=C1.N#CC(=C)CC=CC1=CC=CC=C1 Chemical compound O=C1OC(=O)C=C1.N#CC(=C)CC=CC1=CC=CC=C1 MPQRDVWUOXDFJO-UHFFFAOYSA-N 0.000 description 1
- 101150112468 OR51E2 gene Proteins 0.000 description 1
- 229920000147 Styrene maleic anhydride Polymers 0.000 description 1
- BZHJMEDXRYGGRV-UHFFFAOYSA-N Vinyl chloride Chemical compound ClC=C BZHJMEDXRYGGRV-UHFFFAOYSA-N 0.000 description 1
- 150000007513 acids Chemical class 0.000 description 1
- 238000007792 addition Methods 0.000 description 1
- 239000000654 additive Substances 0.000 description 1
- 230000032683 aging Effects 0.000 description 1
- 150000001298 alcohols Chemical class 0.000 description 1
- 125000004429 atom Chemical group 0.000 description 1
- 235000019400 benzoyl peroxide Nutrition 0.000 description 1
- 125000001797 benzyl group Chemical group [H]C1=C([H])C([H])=C(C([H])=C1[H])C([H])([H])* 0.000 description 1
- 238000009835 boiling Methods 0.000 description 1
- 244000309464 bull Species 0.000 description 1
- FAZCWSNJITUQDA-UHFFFAOYSA-N butyl 2-methylprop-2-enoate;2-methylidene-5-phenylpent-4-enenitrile Chemical compound CCCCOC(=O)C(C)=C.N#CC(=C)CC=CC1=CC=CC=C1 FAZCWSNJITUQDA-UHFFFAOYSA-N 0.000 description 1
- MVAUZYMUXCUOQI-UHFFFAOYSA-N butyl 2-methylprop-2-enoate;2-methylprop-2-enoic acid;styrene Chemical compound CC(=C)C(O)=O.C=CC1=CC=CC=C1.CCCCOC(=O)C(C)=C MVAUZYMUXCUOQI-UHFFFAOYSA-N 0.000 description 1
- SYMHKWRSBRSSOR-UHFFFAOYSA-N butyl 2-methylprop-2-enoate;5-phenylpenta-2,4-dienenitrile Chemical compound CCCCOC(=O)C(C)=C.N#CC=CC=CC1=CC=CC=C1 SYMHKWRSBRSSOR-UHFFFAOYSA-N 0.000 description 1
- CQEYYJKEWSMYFG-UHFFFAOYSA-N butyl acrylate Chemical compound CCCCOC(=O)C=C CQEYYJKEWSMYFG-UHFFFAOYSA-N 0.000 description 1
- 125000000484 butyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- IYCOKCJDXXJIIM-UHFFFAOYSA-N butyl prop-2-enoate;prop-2-enoic acid;styrene Chemical compound OC(=O)C=C.C=CC1=CC=CC=C1.CCCCOC(=O)C=C IYCOKCJDXXJIIM-UHFFFAOYSA-N 0.000 description 1
- JLSIEHRMXULWOA-UHFFFAOYSA-N carboxyoxy 3-ethyloctan-3-yl carbonate Chemical compound CCCCCC(CC)(CC)OC(=O)OOC(O)=O JLSIEHRMXULWOA-UHFFFAOYSA-N 0.000 description 1
- 239000007795 chemical reaction product Substances 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- 229930016911 cinnamic acid Natural products 0.000 description 1
- 235000013985 cinnamic acid Nutrition 0.000 description 1
- 238000010276 construction Methods 0.000 description 1
- LDHQCZJRKDOVOX-NSCUHMNNSA-N crotonic acid Chemical compound C\C=C\C(O)=O LDHQCZJRKDOVOX-NSCUHMNNSA-N 0.000 description 1
- 125000000753 cycloalkyl group Chemical group 0.000 description 1
- HPXRVTGHNJAIIH-UHFFFAOYSA-N cyclohexanol Chemical compound OC1CCCCC1 HPXRVTGHNJAIIH-UHFFFAOYSA-N 0.000 description 1
- YHCBNAJCIMIASL-UHFFFAOYSA-N cyclohexyl 2-methylprop-2-enoate;styrene Chemical compound C=CC1=CC=CC=C1.CC(=C)C(=O)OC1CCCCC1 YHCBNAJCIMIASL-UHFFFAOYSA-N 0.000 description 1
- FDKLLWKMYAMLIF-UHFFFAOYSA-N cyclopropane-1,1-dicarboxylic acid Chemical compound OC(=O)C1(C(O)=O)CC1 FDKLLWKMYAMLIF-UHFFFAOYSA-N 0.000 description 1
- 230000008021 deposition Effects 0.000 description 1
- 150000001470 diamides Chemical class 0.000 description 1
- 150000001991 dicarboxylic acids Chemical class 0.000 description 1
- 238000007323 disproportionation reaction Methods 0.000 description 1
- WNAHIZMDSQCWRP-UHFFFAOYSA-N dodecane-1-thiol Chemical compound CCCCCCCCCCCCS WNAHIZMDSQCWRP-UHFFFAOYSA-N 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- UJLCHHFPPBNULS-UHFFFAOYSA-N ethenyl acetate 3-(2-phenylethenyl)furan-2,5-dione Chemical compound CC(=O)OC=C.O=C1OC(=O)C(C=CC=2C=CC=CC=2)=C1 UJLCHHFPPBNULS-UHFFFAOYSA-N 0.000 description 1
- UUMKGFFZSCKTIY-UHFFFAOYSA-N ethenyl acetate;5-phenylpenta-2,4-dienenitrile Chemical compound CC(=O)OC=C.N#CC=CC=CC1=CC=CC=C1 UUMKGFFZSCKTIY-UHFFFAOYSA-N 0.000 description 1
- NKSJNEHGWDZZQF-UHFFFAOYSA-N ethenyl(trimethoxy)silane Chemical compound CO[Si](OC)(OC)C=C NKSJNEHGWDZZQF-UHFFFAOYSA-N 0.000 description 1
- GCSJLQSCSDMKTP-UHFFFAOYSA-N ethenyl(trimethyl)silane Chemical compound C[Si](C)(C)C=C GCSJLQSCSDMKTP-UHFFFAOYSA-N 0.000 description 1
- 125000005670 ethenylalkyl group Chemical group 0.000 description 1
- XUCNUKMRBVNAPB-UHFFFAOYSA-N fluoroethene Chemical compound FC=C XUCNUKMRBVNAPB-UHFFFAOYSA-N 0.000 description 1
- 238000005194 fractionation Methods 0.000 description 1
- 239000001530 fumaric acid Substances 0.000 description 1
- 150000002238 fumaric acids Chemical class 0.000 description 1
- UMORIIZQJQHCBX-UHFFFAOYSA-N furan-2,5-dione;methyl 2-methylprop-2-enoate;styrene Chemical compound COC(=O)C(C)=C.O=C1OC(=O)C=C1.C=CC1=CC=CC=C1 UMORIIZQJQHCBX-UHFFFAOYSA-N 0.000 description 1
- AYBSOYWZTRUFMW-UHFFFAOYSA-N furan-2,5-dione;prop-2-enenitrile;styrene Chemical compound C=CC#N.O=C1OC(=O)C=C1.C=CC1=CC=CC=C1 AYBSOYWZTRUFMW-UHFFFAOYSA-N 0.000 description 1
- 125000003055 glycidyl group Chemical group C(C1CO1)* 0.000 description 1
- WARQUFORVQESFF-UHFFFAOYSA-N isocyanatoethene Chemical compound C=CN=C=O WARQUFORVQESFF-UHFFFAOYSA-N 0.000 description 1
- 239000000314 lubricant Substances 0.000 description 1
- 150000002689 maleic acids Chemical class 0.000 description 1
- 239000000155 melt Substances 0.000 description 1
- 150000002734 metacrylic acid derivatives Chemical class 0.000 description 1
- 125000005395 methacrylic acid group Chemical group 0.000 description 1
- 238000010327 methods by industry Methods 0.000 description 1
- CLANNGNFKWVXHA-UHFFFAOYSA-N methyl 2-methylprop-2-enoate;2-methylprop-2-enoic acid;styrene Chemical compound CC(=C)C(O)=O.COC(=O)C(C)=C.C=CC1=CC=CC=C1 CLANNGNFKWVXHA-UHFFFAOYSA-N 0.000 description 1
- LGDNMDSHQLWPAK-UHFFFAOYSA-N methyl 2-methylprop-2-enoate;5-phenylpenta-2,4-dienenitrile Chemical compound COC(=O)C(C)=C.N#CC=CC=CC1=CC=CC=C1 LGDNMDSHQLWPAK-UHFFFAOYSA-N 0.000 description 1
- WGOHKAZPXXKHGK-UHFFFAOYSA-N methyl 2-methylprop-2-enoate;prop-2-enamide;styrene Chemical compound NC(=O)C=C.COC(=O)C(C)=C.C=CC1=CC=CC=C1 WGOHKAZPXXKHGK-UHFFFAOYSA-N 0.000 description 1
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 1
- WBYWAXJHAXSJNI-UHFFFAOYSA-N methyl p-hydroxycinnamate Natural products OC(=O)C=CC1=CC=CC=C1 WBYWAXJHAXSJNI-UHFFFAOYSA-N 0.000 description 1
- 150000005673 monoalkenes Chemical class 0.000 description 1
- PJUIMOJAAPLTRJ-UHFFFAOYSA-N monothioglycerol Chemical compound OCC(O)CS PJUIMOJAAPLTRJ-UHFFFAOYSA-N 0.000 description 1
- SEEYREPSKCQBBF-UHFFFAOYSA-N n-methylmaleimide Chemical compound CN1C(=O)C=CC1=O SEEYREPSKCQBBF-UHFFFAOYSA-N 0.000 description 1
- KKFHAJHLJHVUDM-UHFFFAOYSA-N n-vinylcarbazole Chemical compound C1=CC=C2N(C=C)C3=CC=CC=C3C2=C1 KKFHAJHLJHVUDM-UHFFFAOYSA-N 0.000 description 1
- 125000002560 nitrile group Chemical group 0.000 description 1
- 230000003287 optical effect Effects 0.000 description 1
- HVAMZGADVCBITI-UHFFFAOYSA-M pent-4-enoate Chemical compound [O-]C(=O)CCC=C HVAMZGADVCBITI-UHFFFAOYSA-M 0.000 description 1
- 125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 description 1
- 230000010287 polarization Effects 0.000 description 1
- SCUZVMOVTVSBLE-UHFFFAOYSA-N prop-2-enenitrile;styrene Chemical compound C=CC#N.C=CC1=CC=CC=C1 SCUZVMOVTVSBLE-UHFFFAOYSA-N 0.000 description 1
- BWJUFXUULUEGMA-UHFFFAOYSA-N propan-2-yl propan-2-yloxycarbonyloxy carbonate Chemical compound CC(C)OC(=O)OOC(=O)OC(C)C BWJUFXUULUEGMA-UHFFFAOYSA-N 0.000 description 1
- 238000000746 purification Methods 0.000 description 1
- 239000000376 reactant Substances 0.000 description 1
- 238000010992 reflux Methods 0.000 description 1
- 238000007086 side reaction Methods 0.000 description 1
- 235000020374 simple syrup Nutrition 0.000 description 1
- OPQYOFWUFGEMRZ-UHFFFAOYSA-N tert-butyl 2,2-dimethylpropaneperoxoate Chemical compound CC(C)(C)OOC(=O)C(C)(C)C OPQYOFWUFGEMRZ-UHFFFAOYSA-N 0.000 description 1
- LZNNQFTUVNQGDG-UHFFFAOYSA-N tert-butyl 2-methylprop-2-enoate;2-methylprop-2-enenitrile Chemical compound CC(=C)C#N.CC(=C)C(=O)OC(C)(C)C LZNNQFTUVNQGDG-UHFFFAOYSA-N 0.000 description 1
- BWSZXUOMATYHHI-UHFFFAOYSA-N tert-butyl octaneperoxoate Chemical compound CCCCCCCC(=O)OOC(C)(C)C BWSZXUOMATYHHI-UHFFFAOYSA-N 0.000 description 1
- LAUOSUDBLUVWDD-UHFFFAOYSA-N tert-butyl prop-2-enoate;5-phenylpenta-2,4-dienenitrile Chemical compound CC(C)(C)OC(=O)C=C.N#CC=CC=CC1=CC=CC=C1 LAUOSUDBLUVWDD-UHFFFAOYSA-N 0.000 description 1
- 229920001169 thermoplastic Polymers 0.000 description 1
- 239000004416 thermosoftening plastic Substances 0.000 description 1
- LDHQCZJRKDOVOX-UHFFFAOYSA-N trans-crotonic acid Natural products CC=CC(O)=O LDHQCZJRKDOVOX-UHFFFAOYSA-N 0.000 description 1
- 238000002834 transmittance Methods 0.000 description 1
- 230000007306 turnover Effects 0.000 description 1
- KOZCZZVUFDCZGG-UHFFFAOYSA-N vinyl benzoate Chemical compound C=COC(=O)C1=CC=CC=C1 KOZCZZVUFDCZGG-UHFFFAOYSA-N 0.000 description 1
- DGVVWUTYPXICAM-UHFFFAOYSA-N β‐Mercaptoethanol Chemical compound OCCS DGVVWUTYPXICAM-UHFFFAOYSA-N 0.000 description 1
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J19/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
- B01J19/24—Stationary reactors without moving elements inside
- B01J19/2415—Tubular reactors
- B01J19/243—Tubular reactors spirally, concentrically or zigzag wound
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F6/00—Post-polymerisation treatments
- C08F6/26—Treatment of polymers prepared in bulk also solid polymers or polymer melts
- C08F6/28—Purification
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2219/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
- B01J2219/00049—Controlling or regulating processes
- B01J2219/00051—Controlling the temperature
- B01J2219/00074—Controlling the temperature by indirect heating or cooling employing heat exchange fluids
- B01J2219/00087—Controlling the temperature by indirect heating or cooling employing heat exchange fluids with heat exchange elements outside the reactor
- B01J2219/00094—Jackets
Landscapes
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Organic Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Polymerisation Methods In General (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
Priority Applications (8)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DE2724360A DE2724360C3 (de) | 1977-05-28 | 1977-05-28 | Verfahren zur Herstellung von thermoplastischen Formmassen auf Basis von Vinylpolymerisaten |
| US05/908,763 US4181788A (en) | 1977-05-28 | 1978-05-23 | Process for the production of thermoplastic molding materials based on vinyl polymers |
| GB21923/78A GB1601524A (en) | 1977-05-28 | 1978-05-24 | Process for the production of thermoplastic moulding materials based on vinyl polymers |
| NLAANVRAGE7805690,A NL188093C (nl) | 1977-05-28 | 1978-05-25 | Werkwijze ter bereiding van thermoplastische vormmassa's op basis van vinylpolymeren. |
| FR7815779A FR2392035A1 (fr) | 1977-05-28 | 1978-05-26 | Procede de fabrication de masses de moulage thermoplastiques a base de polymeres vinyliques |
| IT49566/78A IT1104659B (it) | 1977-05-28 | 1978-05-26 | Procedimento per produrre masse da stampaggio termoplastiche a base di polimeri vinilici |
| JP6240778A JPS53147788A (en) | 1977-05-28 | 1978-05-26 | Process for producing thermoplastic moldable material composed of vinyl polymer |
| BE188074A BE867529A (fr) | 1977-05-28 | 1978-05-26 | Procede de fabrication de masses de moulage thermoplastiques a base de polymeres vinyliques |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DE2724360A DE2724360C3 (de) | 1977-05-28 | 1977-05-28 | Verfahren zur Herstellung von thermoplastischen Formmassen auf Basis von Vinylpolymerisaten |
Publications (3)
| Publication Number | Publication Date |
|---|---|
| DE2724360A1 DE2724360A1 (de) | 1978-12-21 |
| DE2724360B2 DE2724360B2 (de) | 1981-03-12 |
| DE2724360C3 true DE2724360C3 (de) | 1988-03-24 |
Family
ID=6010215
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| DE2724360A Expired DE2724360C3 (de) | 1977-05-28 | 1977-05-28 | Verfahren zur Herstellung von thermoplastischen Formmassen auf Basis von Vinylpolymerisaten |
Country Status (8)
Families Citing this family (59)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE2908352A1 (de) * | 1979-03-03 | 1980-09-18 | Bayer Ag | Verfahren zur getrennten ableitung der einzelnen phasenstroeme einer mehrphasenstroemung |
| JPH0323840Y2 (US07534539-20090519-C00603.png) * | 1980-11-29 | 1991-05-23 | ||
| USRE32217E (en) * | 1982-11-12 | 1986-07-29 | The Dow Chemical Company | Graft copolymerization process |
| US4558098A (en) * | 1982-12-28 | 1985-12-10 | Mitsubishi Rayon Co., Ltd. | Methacrylic resin composition |
| JPS62501156A (ja) * | 1985-05-06 | 1987-05-07 | ザ・ダウ・ケミカル・カンパニ− | 強化耐候性熱可塑性プラスチックの製造方法 |
| DE3703551A1 (de) | 1987-02-06 | 1988-08-18 | Bayer Ag | Leimungsmittel fuer papier |
| DE4011382A1 (de) * | 1990-04-07 | 1991-10-10 | Bayer Ag | Kontinuierliches verfahren zur trennung von loesungen und suspensionen in einem rieselfaehigen feststoff und in ein weitgehend feststoffreies destillat |
| DE4011383A1 (de) * | 1990-04-07 | 1991-10-10 | Bayer Ag | Kontinuierliches verfahren zum aufkonzentrieren von polymerloesungen bis zu einem geforderten spezifikationsgrad an restloesungsmittel |
| DE4441846A1 (de) | 1994-11-24 | 1996-05-30 | Bayer Ag | ABS-Formmassen mit neuartiger Morphologie |
| DE19827852A1 (de) * | 1998-06-23 | 1999-12-30 | Bayer Ag | Verfahren zur Isolierung von Polymeren aus Lösungen |
| DE19926622A1 (de) * | 1999-06-11 | 2000-12-14 | Bayer Ag | Thermoplastische Formmassen |
| DE19941491A1 (de) | 1999-09-01 | 2001-03-15 | Bayer Ag | Thermoplastische Formmassen auf Basis bestimmter Pfropfkautschukkomponenten |
| IT1314260B1 (it) | 1999-12-03 | 2002-12-06 | Enichem Spa | Procedimento per la produzione di polimeri vinilaromaticieventualmente contenenti un nitrile etilenicamente insaturo. |
| DE10008420A1 (de) * | 2000-02-23 | 2001-08-30 | Bayer Ag | Polymerzusammensetzungen mit verbesserter Eigenschaftskonstanz |
| DE10145773A1 (de) * | 2001-09-17 | 2003-04-03 | Bayer Ag | ABS-Zusammensetzungen mit verbesserten Eigenschaftskombinationen |
| DE10223646A1 (de) | 2002-05-28 | 2003-12-11 | Bayer Ag | Verfahren zur Herstellung von ABS-Zusammensetzungen mit verbesserten Zähigkeitseigenschaften |
| US20050267288A1 (en) * | 2002-07-03 | 2005-12-01 | Jsr Corporation | Method of removing solvent from polymer solution and solvent removing apparatus |
| DE102005060827A1 (de) | 2005-12-20 | 2007-06-28 | Lanxess Deutschland Gmbh | Pfropfkautschuke mit verbesserter Beständigkeit gegen thermooxidativen Abbau |
| DE102007035462A1 (de) | 2007-07-28 | 2009-01-29 | Lanxess Deutschland Gmbh | Verfahren zur Herstellung von Pfropfkautschuken |
| DE102007045959A1 (de) | 2007-09-26 | 2009-04-09 | Lanxess Deutschland Gmbh | Verfahren zur Herstellung von Kautschuklatices mit definiertem stabilem Gelgehalt für die ABS-Herstellung |
| ES2934639T3 (es) | 2010-08-16 | 2023-02-23 | Ineos Styrolution Group Gmbh | Procedimiento para la preparación de látex de caucho aglomerado y el uso de los mismos para la fabricación de composiciones poliméricas |
| WO2013080969A1 (ja) * | 2011-11-28 | 2013-06-06 | 旭化成ケミカルズ株式会社 | スチームストリッピング装置及びこれを用いたスチームストリッピング仕上げ方法 |
| CN109219621B (zh) | 2015-12-02 | 2021-01-12 | 英力士苯领集团股份公司 | 生产具有改进性能的abs塑料的方法 |
| KR20220155613A (ko) | 2016-09-27 | 2022-11-23 | 이네오스 스티롤루션 그룹 게엠베하 | Asa 플라스틱을 생산하는 개선된 방법 |
| JP6919189B2 (ja) * | 2016-12-16 | 2021-08-18 | 三菱ケミカル株式会社 | 貯蔵または重合容器の洗浄方法 |
| ES2860198T5 (es) | 2017-04-24 | 2024-04-26 | Ineos Styrolution Group Gmbh | Procedimiento mejorado para la preparación de copolímeros de injerto de ABS |
| ES2887590T3 (es) | 2017-07-05 | 2021-12-23 | Ineos Styrolution Group Gmbh | Composición de resina termoplástica de copolímero de estireno con resistencia UV mejorada |
| EP3649196B1 (en) | 2017-07-05 | 2021-06-09 | INEOS Styrolution Group GmbH | Thermoplastic resin composition with improved uv resistance |
| CN111094445B (zh) | 2017-07-05 | 2023-12-19 | 英力士苯领集团股份公司 | 抗紫外线能力增强的热塑性树脂组合物 |
| WO2019020685A1 (en) | 2017-07-26 | 2019-01-31 | Ineos Styrolution Group Gmbh | SCRATCH-RESISTANT STYRENE COPOLYMER COMPOSITION CONTAINING NANOPARTICLES OF INORGANIC METALLIC COMPOUND |
| EP3658624B1 (en) | 2017-07-26 | 2022-10-26 | INEOS Styrolution Group GmbH | Impact modified styrene copolymer composition comprising polysiloxane additive having improved abrasion characteristics |
| EP3658622B1 (en) | 2017-07-26 | 2021-09-08 | INEOS Styrolution Group GmbH | Scratch-resistant styrene copolymer composition containing modified organopolysiloxane compounds |
| EP3658619B1 (en) | 2017-07-26 | 2022-12-21 | INEOS Styrolution Group GmbH | Scratch-resistant styrene copolymer composition containing amide wax |
| KR102511937B1 (ko) | 2017-07-26 | 2023-03-17 | 이네오스 스티롤루션 그룹 게엠베하 | 개선된 마모 특성을 갖는 폴리실록산 첨가제를 포함하는 충격 개질된 스티렌 코폴리머 조성물 |
| CN111133049A (zh) | 2017-07-26 | 2020-05-08 | 英力士苯领集团股份公司 | 残留光泽改善的苯乙烯共聚物组合物 |
| KR102592897B1 (ko) | 2017-12-11 | 2023-10-20 | 이네오스 스티롤루션 그룹 게엠베하 | 개선된 가공 및 충격 강도를 갖는 충격 개질된 열가소성 성형 조성물의 생산 공정 |
| CN111727220A (zh) | 2017-12-19 | 2020-09-29 | 英力士苯领集团股份公司 | 高抗疲劳性abs |
| KR102626347B1 (ko) | 2017-12-19 | 2024-01-16 | 이네오스 스티롤루션 그룹 게엠베하 | 취입 성형을 위한 abs 열가소성 성형 조성물 |
| CN111989366B (zh) | 2018-02-16 | 2023-08-29 | 英力士苯领集团股份公司 | 高耐热性abs模塑组合物 |
| WO2019201784A1 (en) | 2018-04-16 | 2019-10-24 | Ineos Styrolution Group Gmbh | Ultra-high flow acrylonitrile butadiene styrene copolymer compositions |
| WO2019201782A1 (en) | 2018-04-16 | 2019-10-24 | Ineos Styrolution Group Gmbh | Ultra-high flow styrene acrylonitrile copolymer compositions |
| KR20210028182A (ko) | 2018-06-20 | 2021-03-11 | 이네오스 스티롤루션 그룹 게엠베하 | 높은 내열성 충격 개질된 폴리카르보네이트 배합물 |
| US11807752B2 (en) | 2018-07-24 | 2023-11-07 | Ineos Styrolution Group Gmbh | Process for preparing graft rubber compositions with improved dewatering |
| US11680127B2 (en) | 2018-08-29 | 2023-06-20 | Ineos Styrolution Group Gmbh | Process for the production of graft copolymer powder compositions and thermoplastic resin compositions |
| WO2020064594A1 (en) | 2018-09-25 | 2020-04-02 | Ineos Styrolution Group Gmbh | Heat resistant abs composition with reduced odor for automotive interior application |
| CN114938651B (zh) | 2019-08-21 | 2023-12-26 | 英力士苯领集团股份公司 | 高escr、高颜色和热稳定性、低分层倾向的用于片材挤出和热成型的abs成型组合物 |
| WO2021122694A1 (en) | 2019-12-17 | 2021-06-24 | Ineos Styrolution Group Gmbh | Dual initiator grafting process of polybutadiene latex by styrene/acrylonitrile |
| US20230203293A1 (en) | 2020-05-29 | 2023-06-29 | Ineos Styrolution Group Gmbh | Low-density abs composites |
| EP4225819A1 (en) | 2020-10-08 | 2023-08-16 | INEOS Styrolution Group GmbH | Preparation of diene polymer latex of high gel content and controlled cross linking |
| WO2022175283A1 (de) | 2021-02-16 | 2022-08-25 | Ineos Styrolution Group Gmbh | Verfahren zur herstellung einer thermoplastischen formmasse enthaltend ein thermoplastisches copolymer a und ein pfropfcopolymer b |
| US20240174853A1 (en) | 2021-03-16 | 2024-05-30 | Ineos Styrolutjion Group Gmbh | Abs molding composition with improved surface quality for plating applications |
| EP4352160A1 (en) | 2021-06-11 | 2024-04-17 | INEOS Styrolution Group GmbH | A process for the preparation of low-density abs composites |
| US20240287302A1 (en) | 2021-06-23 | 2024-08-29 | Ineos Styrolution Group Gmbh | Weather resistant asa molding composition |
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| WO2024028309A1 (de) | 2022-08-04 | 2024-02-08 | Ineos Styrolution Group Gmbh | Thermoplastische abs-formmassen mit einer guten eigenschaftskombination von verarbeitbarkeit und oberflächenqualität |
| WO2024028311A1 (de) | 2022-08-04 | 2024-02-08 | Ineos Styrolution Group Gmbh | Thermoplastische abs-formmasse mit guter eigenschaftskombination von verarbeitbarkeit und oberflächenqualität |
| WO2024068772A1 (de) * | 2022-09-29 | 2024-04-04 | Ineos Styrolution Group Gmbh | Verfahren zur herstellung eines copolymers ausgehend von mindestens einer aromatischen vinylverbindung |
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| US2530409A (en) * | 1948-05-27 | 1950-11-21 | Dow Chemical Co | Method for polymerizing styrene |
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| GB875853A (en) * | 1959-07-03 | 1961-08-23 | Ici Ltd | Improved process for the production of polymeric material |
| BE608078A (US07534539-20090519-C00603.png) * | 1961-06-16 | |||
| GB1046185A (en) * | 1963-09-27 | 1966-10-19 | Mobay Chemical Corp | Process for the recovery of polycarbonates from solutions thereof |
| GB1193151A (en) * | 1967-06-15 | 1970-05-28 | Oreal | Coloured Polymers |
| DE1921045B2 (de) * | 1969-04-25 | 1976-11-11 | Bayer Ag, 5090 Leverkusen | Verfahren zum gewinnen einer polymerschmelze aus einer polymerloesung |
| DE1964946C3 (de) * | 1969-12-24 | 1980-09-18 | Bayer Ag, 5090 Leverkusen | Vorrichtung zum Konzentrieren einer Lösung oder Suspension bis zum plastischen Zustand |
| US4015064A (en) * | 1974-06-24 | 1977-03-29 | Tenneco Chemicals, Inc. | Manufacture of polyvinyl chloride of low vinyl chloride monomer content |
| JPS5111882A (en) * | 1974-07-20 | 1976-01-30 | Sumitomo Chemical Co | Mihannotanryotaio jokyosuruhoho |
| JPS5169587A (en) * | 1974-12-13 | 1976-06-16 | Tetsukosha Kk | Jugotaichuno zanzonenkabinirutanryotaijokyohoho |
| US4107421A (en) * | 1976-08-13 | 1978-08-15 | Continental Oil Company | Removal of vinyl halide from polyvinyl halide |
-
1977
- 1977-05-28 DE DE2724360A patent/DE2724360C3/de not_active Expired
-
1978
- 1978-05-23 US US05/908,763 patent/US4181788A/en not_active Expired - Lifetime
- 1978-05-24 GB GB21923/78A patent/GB1601524A/en not_active Expired
- 1978-05-25 NL NLAANVRAGE7805690,A patent/NL188093C/xx not_active IP Right Cessation
- 1978-05-26 FR FR7815779A patent/FR2392035A1/fr active Granted
- 1978-05-26 IT IT49566/78A patent/IT1104659B/it active
- 1978-05-26 JP JP6240778A patent/JPS53147788A/ja active Granted
- 1978-05-26 BE BE188074A patent/BE867529A/xx not_active IP Right Cessation
Also Published As
| Publication number | Publication date |
|---|---|
| DE2724360B2 (de) | 1981-03-12 |
| FR2392035B1 (US07534539-20090519-C00603.png) | 1984-08-17 |
| US4181788A (en) | 1980-01-01 |
| DE2724360A1 (de) | 1978-12-21 |
| NL188093C (nl) | 1992-04-01 |
| NL188093B (nl) | 1991-11-01 |
| JPS53147788A (en) | 1978-12-22 |
| JPS5643242B2 (US07534539-20090519-C00603.png) | 1981-10-12 |
| IT1104659B (it) | 1985-10-28 |
| GB1601524A (en) | 1981-10-28 |
| IT7849566A0 (it) | 1978-05-26 |
| BE867529A (fr) | 1978-11-27 |
| FR2392035A1 (fr) | 1978-12-22 |
| NL7805690A (nl) | 1978-11-30 |
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| Date | Code | Title | Description |
|---|---|---|---|
| OAP | Request for examination filed | ||
| OD | Request for examination | ||
| 8263 | Opposition against grant of a patent | ||
| C3 | Grant after two publication steps (3rd publication) | ||
| 8339 | Ceased/non-payment of the annual fee |