DE2701461A1 - Acylperoxykohlensaeureester und deren verwendung zur herstellung von polymeren - Google Patents
Acylperoxykohlensaeureester und deren verwendung zur herstellung von polymerenInfo
- Publication number
- DE2701461A1 DE2701461A1 DE19772701461 DE2701461A DE2701461A1 DE 2701461 A1 DE2701461 A1 DE 2701461A1 DE 19772701461 DE19772701461 DE 19772701461 DE 2701461 A DE2701461 A DE 2701461A DE 2701461 A1 DE2701461 A1 DE 2701461A1
- Authority
- DE
- Germany
- Prior art keywords
- carbonic acid
- acylperoxy
- polymerization
- acid esters
- acid ester
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Ceased
Links
- 229920000642 polymer Polymers 0.000 title claims description 6
- 238000004519 manufacturing process Methods 0.000 title claims description 5
- 239000002253 acid Substances 0.000 title 1
- -1 Acyl peroxy carbonic acid esters Chemical class 0.000 claims description 18
- 238000006116 polymerization reaction Methods 0.000 claims description 17
- 150000004651 carbonic acid esters Chemical class 0.000 claims description 12
- 239000000178 monomer Substances 0.000 claims description 11
- 239000003999 initiator Substances 0.000 claims description 10
- 229920002379 silicone rubber Polymers 0.000 claims description 10
- 239000004945 silicone rubber Substances 0.000 claims description 10
- BZHJMEDXRYGGRV-UHFFFAOYSA-N Vinyl chloride Chemical compound ClC=C BZHJMEDXRYGGRV-UHFFFAOYSA-N 0.000 claims description 9
- 238000000034 method Methods 0.000 claims description 8
- VVQNEPGJFQJSBK-UHFFFAOYSA-N Methyl methacrylate Chemical compound COC(=O)C(C)=C VVQNEPGJFQJSBK-UHFFFAOYSA-N 0.000 claims description 7
- 238000004073 vulcanization Methods 0.000 claims description 7
- XTXRWKRVRITETP-UHFFFAOYSA-N Vinyl acetate Chemical compound CC(=O)OC=C XTXRWKRVRITETP-UHFFFAOYSA-N 0.000 claims description 5
- 229920006305 unsaturated polyester Polymers 0.000 claims description 5
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 claims description 4
- 150000003512 tertiary amines Chemical class 0.000 claims description 4
- 125000004432 carbon atom Chemical group C* 0.000 claims description 3
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 claims description 3
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 claims description 2
- 239000005977 Ethylene Substances 0.000 claims description 2
- 125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 claims description 2
- 230000000977 initiatory effect Effects 0.000 claims description 2
- 239000003505 polymerization initiator Substances 0.000 claims description 2
- BVKZGUZCCUSVTD-UHFFFAOYSA-N carbonic acid Chemical compound OC(O)=O BVKZGUZCCUSVTD-UHFFFAOYSA-N 0.000 claims 1
- 201000002266 mite infestation Diseases 0.000 claims 1
- 125000000913 palmityl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 claims 1
- 125000004079 stearyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 claims 1
- 150000002978 peroxides Chemical class 0.000 description 20
- RUXQWZJWMCHCHH-IZZDOVSWSA-N [(e)-1-pyridin-2-ylethylideneamino]urea Chemical compound NC(=O)N\N=C(/C)C1=CC=CC=N1 RUXQWZJWMCHCHH-IZZDOVSWSA-N 0.000 description 19
- 238000012360 testing method Methods 0.000 description 13
- 150000001875 compounds Chemical class 0.000 description 10
- OMPJBNCRMGITSC-UHFFFAOYSA-N Benzoylperoxide Chemical compound C=1C=CC=CC=1C(=O)OOC(=O)C1=CC=CC=C1 OMPJBNCRMGITSC-UHFFFAOYSA-N 0.000 description 9
- 239000004342 Benzoyl peroxide Substances 0.000 description 8
- 235000019400 benzoyl peroxide Nutrition 0.000 description 8
- BVKZGUZCCUSVTD-UHFFFAOYSA-L Carbonate Chemical compound [O-]C([O-])=O BVKZGUZCCUSVTD-UHFFFAOYSA-L 0.000 description 7
- UHOVQNZJYSORNB-UHFFFAOYSA-N Benzene Chemical compound C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 description 6
- 239000000203 mixture Substances 0.000 description 6
- VLKZOEOYAKHREP-UHFFFAOYSA-N n-Hexane Chemical compound CCCCCC VLKZOEOYAKHREP-UHFFFAOYSA-N 0.000 description 6
- 239000000725 suspension Substances 0.000 description 5
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 4
- FAPWRFPIFSIZLT-UHFFFAOYSA-M Sodium chloride Chemical compound [Na+].[Cl-] FAPWRFPIFSIZLT-UHFFFAOYSA-M 0.000 description 4
- 239000000523 sample Substances 0.000 description 4
- XEKOWRVHYACXOJ-UHFFFAOYSA-N Ethyl acetate Chemical compound CCOC(C)=O XEKOWRVHYACXOJ-UHFFFAOYSA-N 0.000 description 3
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 3
- 229920001971 elastomer Polymers 0.000 description 3
- 238000002474 experimental method Methods 0.000 description 3
- 238000010438 heat treatment Methods 0.000 description 3
- 229910052760 oxygen Inorganic materials 0.000 description 3
- 239000001301 oxygen Substances 0.000 description 3
- CSCPPACGZOOCGX-UHFFFAOYSA-N Acetone Chemical compound CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 description 2
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 2
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 description 2
- KFSLWBXXFJQRDL-UHFFFAOYSA-N Peracetic acid Chemical compound CC(=O)OO KFSLWBXXFJQRDL-UHFFFAOYSA-N 0.000 description 2
- 238000004132 cross linking Methods 0.000 description 2
- 239000012044 organic layer Substances 0.000 description 2
- 125000000864 peroxy group Chemical group O(O*)* 0.000 description 2
- 229920003023 plastic Polymers 0.000 description 2
- 239000004033 plastic Substances 0.000 description 2
- 229920001225 polyester resin Polymers 0.000 description 2
- 239000004645 polyester resin Substances 0.000 description 2
- 238000002360 preparation method Methods 0.000 description 2
- 239000011541 reaction mixture Substances 0.000 description 2
- 229920005989 resin Polymers 0.000 description 2
- 239000011347 resin Substances 0.000 description 2
- OPQYOFWUFGEMRZ-UHFFFAOYSA-N tert-butyl 2,2-dimethylpropaneperoxoate Chemical compound CC(C)(C)OOC(=O)C(C)(C)C OPQYOFWUFGEMRZ-UHFFFAOYSA-N 0.000 description 2
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 2
- WRXCBRHBHGNNQA-UHFFFAOYSA-N (2,4-dichlorobenzoyl) 2,4-dichlorobenzenecarboperoxoate Chemical compound ClC1=CC(Cl)=CC=C1C(=O)OOC(=O)C1=CC=C(Cl)C=C1Cl WRXCBRHBHGNNQA-UHFFFAOYSA-N 0.000 description 1
- UXUFTKZYJYGMGO-CMCWBKRRSA-N (2s,3s,4r,5r)-5-[6-amino-2-[2-[4-[3-(2-aminoethylamino)-3-oxopropyl]phenyl]ethylamino]purin-9-yl]-n-ethyl-3,4-dihydroxyoxolane-2-carboxamide Chemical compound O[C@@H]1[C@H](O)[C@@H](C(=O)NCC)O[C@H]1N1C2=NC(NCCC=3C=CC(CCC(=O)NCCN)=CC=3)=NC(N)=C2N=C1 UXUFTKZYJYGMGO-CMCWBKRRSA-N 0.000 description 1
- BDNDQOCRJGGSJO-UHFFFAOYSA-N 1-amino-2-phenylpropan-2-ol Chemical compound NCC(O)(C)C1=CC=CC=C1 BDNDQOCRJGGSJO-UHFFFAOYSA-N 0.000 description 1
- XWJRZWPUXANVTN-UHFFFAOYSA-N 2,2,4,4-tetramethylpentaneperoxoic acid Chemical compound CC(C)(C)CC(C)(C)C(=O)OO XWJRZWPUXANVTN-UHFFFAOYSA-N 0.000 description 1
- 101001092910 Homo sapiens Serum amyloid P-component Proteins 0.000 description 1
- 101000834981 Homo sapiens Testis, prostate and placenta-expressed protein Proteins 0.000 description 1
- 229920003091 Methocel™ Polymers 0.000 description 1
- JLTDJTHDQAWBAV-UHFFFAOYSA-N N,N-dimethylaniline Chemical compound CN(C)C1=CC=CC=C1 JLTDJTHDQAWBAV-UHFFFAOYSA-N 0.000 description 1
- 235000014676 Phragmites communis Nutrition 0.000 description 1
- 239000004372 Polyvinyl alcohol Substances 0.000 description 1
- 102100036202 Serum amyloid P-component Human genes 0.000 description 1
- IDCBOTIENDVCBQ-UHFFFAOYSA-N TEPP Chemical compound CCOP(=O)(OCC)OP(=O)(OCC)OCC IDCBOTIENDVCBQ-UHFFFAOYSA-N 0.000 description 1
- 102100026164 Testis, prostate and placenta-expressed protein Human genes 0.000 description 1
- PQYJRMFWJJONBO-UHFFFAOYSA-N Tris(2,3-dibromopropyl) phosphate Chemical compound BrCC(Br)COP(=O)(OCC(Br)CBr)OCC(Br)CBr PQYJRMFWJJONBO-UHFFFAOYSA-N 0.000 description 1
- JUIBLDFFVYKUAC-UHFFFAOYSA-N [5-(2-ethylhexanoylperoxy)-2,5-dimethylhexan-2-yl] 2-ethylhexaneperoxoate Chemical compound CCCCC(CC)C(=O)OOC(C)(C)CCC(C)(C)OOC(=O)C(CC)CCCC JUIBLDFFVYKUAC-UHFFFAOYSA-N 0.000 description 1
- 125000000218 acetic acid group Chemical group C(C)(=O)* 0.000 description 1
- 239000000654 additive Substances 0.000 description 1
- 125000000217 alkyl group Chemical group 0.000 description 1
- 150000001412 amines Chemical class 0.000 description 1
- KQNZLOUWXSAZGD-UHFFFAOYSA-N benzylperoxymethylbenzene Chemical compound C=1C=CC=CC=1COOCC1=CC=CC=C1 KQNZLOUWXSAZGD-UHFFFAOYSA-N 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 238000012662 bulk polymerization Methods 0.000 description 1
- MMCOUVMKNAHQOY-UHFFFAOYSA-N carbonoperoxoic acid Chemical class OOC(O)=O MMCOUVMKNAHQOY-UHFFFAOYSA-N 0.000 description 1
- 238000006243 chemical reaction Methods 0.000 description 1
- 239000007795 chemical reaction product Substances 0.000 description 1
- FZFAMSAMCHXGEF-UHFFFAOYSA-N chloro formate Chemical compound ClOC=O FZFAMSAMCHXGEF-UHFFFAOYSA-N 0.000 description 1
- 229920001577 copolymer Polymers 0.000 description 1
- 238000007334 copolymerization reaction Methods 0.000 description 1
- XJOBOFWTZOKMOH-UHFFFAOYSA-N decanoyl decaneperoxoate Chemical compound CCCCCCCCCC(=O)OOC(=O)CCCCCCCCC XJOBOFWTZOKMOH-UHFFFAOYSA-N 0.000 description 1
- 238000000354 decomposition reaction Methods 0.000 description 1
- 238000002845 discoloration Methods 0.000 description 1
- 239000000284 extract Substances 0.000 description 1
- 239000000835 fiber Substances 0.000 description 1
- 239000012065 filter cake Substances 0.000 description 1
- 239000000706 filtrate Substances 0.000 description 1
- 239000012530 fluid Substances 0.000 description 1
- 235000011187 glycerol Nutrition 0.000 description 1
- 239000005337 ground glass Substances 0.000 description 1
- 229920001519 homopolymer Polymers 0.000 description 1
- 239000005457 ice water Substances 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 238000002156 mixing Methods 0.000 description 1
- 239000006082 mold release agent Substances 0.000 description 1
- GYVGXEWAOAAJEU-UHFFFAOYSA-N n,n,4-trimethylaniline Chemical compound CN(C)C1=CC=C(C)C=C1 GYVGXEWAOAAJEU-UHFFFAOYSA-N 0.000 description 1
- 230000006855 networking Effects 0.000 description 1
- 229910052757 nitrogen Inorganic materials 0.000 description 1
- JQDURWGNZCVESS-UHFFFAOYSA-N octadecyl carbonochloridate Chemical compound CCCCCCCCCCCCCCCCCCOC(Cl)=O JQDURWGNZCVESS-UHFFFAOYSA-N 0.000 description 1
- 238000012856 packing Methods 0.000 description 1
- 150000004965 peroxy acids Chemical class 0.000 description 1
- 229950010765 pivalate Drugs 0.000 description 1
- IUGYQRQAERSCNH-UHFFFAOYSA-N pivalic acid Chemical compound CC(C)(C)C(O)=O IUGYQRQAERSCNH-UHFFFAOYSA-N 0.000 description 1
- 229920002451 polyvinyl alcohol Polymers 0.000 description 1
- 239000000047 product Substances 0.000 description 1
- AOJFQRQNPXYVLM-UHFFFAOYSA-N pyridin-1-ium;chloride Chemical compound [Cl-].C1=CC=[NH+]C=C1 AOJFQRQNPXYVLM-UHFFFAOYSA-N 0.000 description 1
- ZNCXUFVDFVBRDO-UHFFFAOYSA-N pyridine;sulfuric acid Chemical compound [H+].[O-]S([O-])(=O)=O.C1=CC=[NH+]C=C1 ZNCXUFVDFVBRDO-UHFFFAOYSA-N 0.000 description 1
- 239000000376 reactant Substances 0.000 description 1
- 238000011076 safety test Methods 0.000 description 1
- 229920006395 saturated elastomer Polymers 0.000 description 1
- 229920000260 silastic Polymers 0.000 description 1
- 239000002904 solvent Substances 0.000 description 1
- 238000009987 spinning Methods 0.000 description 1
- 229910001220 stainless steel Inorganic materials 0.000 description 1
- 239000010935 stainless steel Substances 0.000 description 1
- 238000003860 storage Methods 0.000 description 1
- 239000004094 surface-active agent Substances 0.000 description 1
- 239000000375 suspending agent Substances 0.000 description 1
- 238000003786 synthesis reaction Methods 0.000 description 1
- 125000000999 tert-butyl group Chemical group [H]C([H])([H])C(*)(C([H])([H])[H])C([H])([H])[H] 0.000 description 1
- GPRLSGONYQIRFK-MNYXATJNSA-N triton Chemical compound [3H+] GPRLSGONYQIRFK-MNYXATJNSA-N 0.000 description 1
- 229920006337 unsaturated polyester resin Polymers 0.000 description 1
- 238000004383 yellowing Methods 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/04—Oxygen-containing compounds
- C08K5/14—Peroxides
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F299/00—Macromolecular compounds obtained by interreacting polymers involving only carbon-to-carbon unsaturated bond reactions, in the absence of non-macromolecular monomers
- C08F299/02—Macromolecular compounds obtained by interreacting polymers involving only carbon-to-carbon unsaturated bond reactions, in the absence of non-macromolecular monomers from unsaturated polycondensates
- C08F299/04—Macromolecular compounds obtained by interreacting polymers involving only carbon-to-carbon unsaturated bond reactions, in the absence of non-macromolecular monomers from unsaturated polycondensates from polyesters
- C08F299/0442—Catalysts
- C08F299/045—Peroxy-compounds
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/28—Oxygen or compounds releasing free oxygen
- C08F4/32—Organic compounds
- C08F4/34—Per-compounds with one peroxy-radical
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Polymerization Catalysts (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Macromonomer-Based Addition Polymer (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US05/696,463 US4051310A (en) | 1976-06-16 | 1976-06-16 | Thermally stable high molecular weight acyl peroxycarbonic esters |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| DE2701461A1 true DE2701461A1 (de) | 1977-12-29 |
Family
ID=24797178
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| DE19772701461 Ceased DE2701461A1 (de) | 1976-06-16 | 1977-01-14 | Acylperoxykohlensaeureester und deren verwendung zur herstellung von polymeren |
Country Status (8)
| Country | Link |
|---|---|
| US (3) | US4051310A (enExample) |
| JP (1) | JPS52153917A (enExample) |
| BE (1) | BE851145A (enExample) |
| CA (1) | CA1057770A (enExample) |
| DE (1) | DE2701461A1 (enExample) |
| FR (1) | FR2355004A1 (enExample) |
| GB (1) | GB1528670A (enExample) |
| IT (1) | IT1086877B (enExample) |
Families Citing this family (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS6045209B2 (ja) * | 1976-07-20 | 1985-10-08 | 住友化学工業株式会社 | 連続重合方法 |
| US4370459A (en) * | 1980-07-07 | 1983-01-25 | Argus Chemical Corporation | Polymerizing unsaturated monomers with gem-diperoxyester catalyst |
| US4372877A (en) * | 1981-11-05 | 1983-02-08 | U.S. Peroxygen Company | Di(acylperoxy)-1,4-cyclohexane dimethanol-bis-carbonates |
| US4590008A (en) * | 1984-06-07 | 1986-05-20 | Ppg Industries, Inc. | Novel organic peroxydicarbonates |
| US4647641A (en) * | 1984-12-05 | 1987-03-03 | Pennwalt Corporation | Curable organopolysiloxane compositions |
| US4916184A (en) * | 1988-01-13 | 1990-04-10 | Loctite Corporation | Adhesive compositions comprising maleic acid peroxy compounds as adhesive promoters |
Family Cites Families (9)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| NL120371C (enExample) * | 1959-01-16 | |||
| US3652524A (en) * | 1967-12-26 | 1972-03-28 | Argus Chem | Process for polymerizing vinyl chloride with low molecular weight acyl peroxycarbonic esters |
| US3585232A (en) * | 1967-12-26 | 1971-06-15 | Argus Chem | Low molecular weight acyl peroxycarbonic esters |
| NL136294C (enExample) * | 1968-04-24 | |||
| US3903065A (en) * | 1968-11-14 | 1975-09-02 | Kema Nord Ab | Process for polymerizing vinyl chloride |
| GB1254349A (en) * | 1969-05-05 | 1971-11-17 | Bp Chem Int Ltd | Polymerisation process |
| US3932372A (en) * | 1970-07-20 | 1976-01-13 | Argus Chemical Corporation | Peroxide co-initiator system for polymerization |
| US3821273A (en) * | 1970-07-30 | 1974-06-28 | Pennwalt Corp | Novel dialkyl peroxydicarbonates |
| US3985232A (en) * | 1975-05-05 | 1976-10-12 | Container Corporation Of America | Carton and display panel |
-
1976
- 1976-06-16 US US05/696,463 patent/US4051310A/en not_active Expired - Lifetime
- 1976-12-22 CA CA268,617A patent/CA1057770A/en not_active Expired
- 1976-12-23 GB GB53797/76A patent/GB1528670A/en not_active Expired
-
1977
- 1977-01-12 JP JP227777A patent/JPS52153917A/ja active Pending
- 1977-01-14 DE DE19772701461 patent/DE2701461A1/de not_active Ceased
- 1977-02-04 BE BE174716A patent/BE851145A/xx not_active IP Right Cessation
- 1977-03-07 US US05/774,833 patent/US4069239A/en not_active Expired - Lifetime
- 1977-03-30 IT IT48731/77A patent/IT1086877B/it active
- 1977-04-14 FR FR7711286A patent/FR2355004A1/fr active Granted
- 1977-07-21 US US05/817,634 patent/US4129613A/en not_active Expired - Lifetime
Also Published As
| Publication number | Publication date |
|---|---|
| CA1057770A (en) | 1979-07-03 |
| IT1086877B (it) | 1985-05-31 |
| BE851145A (fr) | 1977-05-31 |
| US4129613A (en) | 1978-12-12 |
| FR2355004B1 (enExample) | 1983-11-18 |
| FR2355004A1 (fr) | 1978-01-13 |
| JPS52153917A (en) | 1977-12-21 |
| GB1528670A (en) | 1978-10-18 |
| US4069239A (en) | 1978-01-17 |
| US4051310A (en) | 1977-09-27 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| DE827554C (de) | Verfahren zum Polymerisieren von Verbindungen vom Vinyltyp | |
| DE1135176B (de) | Verfahren zur Herstellung phosphorhaltiger Mischpolymerisate | |
| EP0289713B1 (de) | Verfahren zur Herstellung von Copolymerisaten mit hohem Polymerisationsgrad | |
| DE1068014B (de) | Verfahren zur Herstellung von festen Äthylenpolymeren | |
| DE2829807C2 (enExample) | ||
| DE2726008C2 (de) | Peroxycarbonat und Verfahren zu seiner Herstellung | |
| DE2701461A1 (de) | Acylperoxykohlensaeureester und deren verwendung zur herstellung von polymeren | |
| DE1149905B (de) | Verfahren zur Polymerisation von Vinylmonomeren | |
| DE953119C (de) | Verfahren zur Herstellung von Vinylchloridpolymeren | |
| DE1104182B (de) | Polymerisationskatalysator fuer die Block- und Loesungspolymerisation | |
| DE947024C (de) | Verfahren zur Herstellung von Mischpolymerisaten auf Grundlage von Vinylidencyanid | |
| DE3538951C2 (de) | Katalysator zur Polymerisation von Olefinen, Verfahren zu dessen Herstellung, Polymerisationsverfahren und Katalysatorkomponente | |
| DE1116409B (de) | Verfahren zur Polymerisation von Vinylverbindungen | |
| DE2164482A1 (de) | Initatoren fuer radikalisch auszuloesende polymerisationsreaktionen | |
| DE69121321T2 (de) | Polymerperoxid, Polymerisationsinitiator und Verfahren zur Herstellung von Blockcopolymeren | |
| DE1793809A1 (de) | Azopolymere und verfahren zu ihrer herstellung | |
| DE1131407B (de) | Verfahren zur Polymerisation ungesaettigter Verbindungen | |
| DE2914701A1 (de) | Thiocarbamylhydroxylamin-verbindungen und deren verwendung als polymerisationsinitiatoren | |
| DE1927761A1 (de) | Verfahren zur Polymerisation olefinisch ungesaettigter Verbindungen | |
| DE1795081C3 (de) | Verfahren zur Herstellung von Fluorolefinpolymerisaten | |
| DE1092659B (de) | Verfahren zum Polymerisieren von olefinisch ungesaettigten Verbindungen | |
| DE2127595A1 (de) | Hartwigs- und Polymerisationsverfahren unter Anwendung von beta-substituierten Diperoxyketalen | |
| DE2558209A1 (de) | Verfahren zur herstellung eines vinylhalogenid-homopolymeren, vinylhalogenid-copolymeren oder vinylhalogenid-pfropfpolymeren | |
| DE3048079A1 (de) | Verfahren zur herstellung von polymeren und mischpolymeren aus vinylchlorid | |
| DE3807564C2 (de) | Diisopropylbenzol-bisperneoalkanoate, Verfahren zu ihrer Herstellung und ihre Verwendung als Polymerisationsinitiatoren |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| 8110 | Request for examination paragraph 44 | ||
| 8128 | New person/name/address of the agent |
Representative=s name: SPLANEMANN, R., DIPL.-ING. REITZNER, B., DIPL.-CHE |
|
| 8131 | Rejection |