DE2638755A1 - Copolyester mit arylatsequenzen und faeden auf basis dieser copolyester - Google Patents
Copolyester mit arylatsequenzen und faeden auf basis dieser copolyesterInfo
- Publication number
- DE2638755A1 DE2638755A1 DE19762638755 DE2638755A DE2638755A1 DE 2638755 A1 DE2638755 A1 DE 2638755A1 DE 19762638755 DE19762638755 DE 19762638755 DE 2638755 A DE2638755 A DE 2638755A DE 2638755 A1 DE2638755 A1 DE 2638755A1
- Authority
- DE
- Germany
- Prior art keywords
- formula
- groupings
- copolyesters
- sequences
- inherent viscosity
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Withdrawn
Links
- 229920001634 Copolyester Polymers 0.000 title claims description 27
- 150000002148 esters Chemical class 0.000 claims description 19
- 239000004721 Polyphenylene oxide Substances 0.000 claims description 17
- 229920000570 polyether Polymers 0.000 claims description 17
- 229920000642 polymer Polymers 0.000 claims description 14
- 125000001931 aliphatic group Chemical group 0.000 claims description 11
- GDBUZIKSJGRBJP-UHFFFAOYSA-N 4-acetoxy benzoic acid Chemical compound CC(=O)OC1=CC=C(C(O)=O)C=C1 GDBUZIKSJGRBJP-UHFFFAOYSA-N 0.000 claims description 10
- 125000002723 alicyclic group Chemical group 0.000 claims description 10
- 238000009987 spinning Methods 0.000 claims description 10
- 238000004519 manufacturing process Methods 0.000 claims description 9
- 150000002009 diols Chemical class 0.000 claims description 8
- 239000002253 acid Substances 0.000 claims description 5
- 150000001875 compounds Chemical class 0.000 claims description 5
- 238000000034 method Methods 0.000 claims description 5
- 239000000203 mixture Substances 0.000 claims description 5
- 229920001577 copolymer Polymers 0.000 claims description 3
- ISWSIDIOOBJBQZ-UHFFFAOYSA-N Phenol Chemical compound OC1=CC=CC=C1 ISWSIDIOOBJBQZ-UHFFFAOYSA-N 0.000 claims description 2
- 230000003252 repetitive effect Effects 0.000 claims 6
- 238000002360 preparation method Methods 0.000 claims 1
- 238000002844 melting Methods 0.000 description 16
- 230000008018 melting Effects 0.000 description 16
- 238000006243 chemical reaction Methods 0.000 description 13
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 11
- QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical compound CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 description 9
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 9
- 238000006068 polycondensation reaction Methods 0.000 description 8
- WPYMKLBDIGXBTP-UHFFFAOYSA-N benzoic acid Chemical compound OC(=O)C1=CC=CC=C1 WPYMKLBDIGXBTP-UHFFFAOYSA-N 0.000 description 6
- 239000000835 fiber Substances 0.000 description 5
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 4
- 238000010438 heat treatment Methods 0.000 description 4
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 4
- 229920000728 polyester Polymers 0.000 description 4
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 4
- 238000004804 winding Methods 0.000 description 4
- 239000005711 Benzoic acid Substances 0.000 description 3
- 235000010233 benzoic acid Nutrition 0.000 description 3
- 125000004432 carbon atom Chemical group C* 0.000 description 3
- BASFCYQUMIYNBI-UHFFFAOYSA-N platinum Substances [Pt] BASFCYQUMIYNBI-UHFFFAOYSA-N 0.000 description 3
- 230000001105 regulatory effect Effects 0.000 description 3
- QPFMBZIOSGYJDE-UHFFFAOYSA-N 1,1,2,2-tetrachloroethane Chemical compound ClC(Cl)C(Cl)Cl QPFMBZIOSGYJDE-UHFFFAOYSA-N 0.000 description 2
- SHSGDXCJYVZFTP-UHFFFAOYSA-N 4-ethoxybenzoic acid Chemical compound CCOC1=CC=C(C(O)=O)C=C1 SHSGDXCJYVZFTP-UHFFFAOYSA-N 0.000 description 2
- VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical compound [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 description 2
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 2
- 125000005907 alkyl ester group Chemical group 0.000 description 2
- -1 allyl ester Chemical class 0.000 description 2
- 229910000410 antimony oxide Inorganic materials 0.000 description 2
- ADCOVFLJGNWWNZ-UHFFFAOYSA-N antimony trioxide Chemical compound O=[Sb]O[Sb]=O ADCOVFLJGNWWNZ-UHFFFAOYSA-N 0.000 description 2
- WERYXYBDKMZEQL-UHFFFAOYSA-N butane-1,4-diol Chemical compound OCCCCO WERYXYBDKMZEQL-UHFFFAOYSA-N 0.000 description 2
- 239000003054 catalyst Substances 0.000 description 2
- 239000000945 filler Substances 0.000 description 2
- 229940071125 manganese acetate Drugs 0.000 description 2
- UOGMEBQRZBEZQT-UHFFFAOYSA-L manganese(2+);diacetate Chemical compound [Mn+2].CC([O-])=O.CC([O-])=O UOGMEBQRZBEZQT-UHFFFAOYSA-L 0.000 description 2
- 229910052757 nitrogen Inorganic materials 0.000 description 2
- 230000003287 optical effect Effects 0.000 description 2
- VTRUBDSFZJNXHI-UHFFFAOYSA-N oxoantimony Chemical compound [Sb]=O VTRUBDSFZJNXHI-UHFFFAOYSA-N 0.000 description 2
- JOXIMZWYDAKGHI-UHFFFAOYSA-N toluene-4-sulfonic acid Chemical compound CC1=CC=C(S(O)(=O)=O)C=C1 JOXIMZWYDAKGHI-UHFFFAOYSA-N 0.000 description 2
- HVLLSGMXQDNUAL-UHFFFAOYSA-N triphenyl phosphite Chemical compound C=1C=CC=CC=1OP(OC=1C=CC=CC=1)OC1=CC=CC=C1 HVLLSGMXQDNUAL-UHFFFAOYSA-N 0.000 description 2
- IHEDBVUTTQXGSJ-UHFFFAOYSA-M 2-[bis(2-oxidoethyl)amino]ethanolate;titanium(4+);hydroxide Chemical compound [OH-].[Ti+4].[O-]CCN(CC[O-])CC[O-] IHEDBVUTTQXGSJ-UHFFFAOYSA-M 0.000 description 1
- QTBSBXVTEAMEQO-UHFFFAOYSA-M Acetate Chemical compound CC([O-])=O QTBSBXVTEAMEQO-UHFFFAOYSA-M 0.000 description 1
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 description 1
- 239000005977 Ethylene Substances 0.000 description 1
- FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 description 1
- ALQSHHUCVQOPAS-UHFFFAOYSA-N Pentane-1,5-diol Chemical compound OCCCCCO ALQSHHUCVQOPAS-UHFFFAOYSA-N 0.000 description 1
- 229920003171 Poly (ethylene oxide) Polymers 0.000 description 1
- 125000000217 alkyl group Chemical group 0.000 description 1
- 239000003963 antioxidant agent Substances 0.000 description 1
- 230000005540 biological transmission Effects 0.000 description 1
- 229910000019 calcium carbonate Inorganic materials 0.000 description 1
- 238000005266 casting Methods 0.000 description 1
- 229910021446 cobalt carbonate Inorganic materials 0.000 description 1
- ZOTKGJBKKKVBJZ-UHFFFAOYSA-L cobalt(2+);carbonate Chemical compound [Co+2].[O-]C([O-])=O ZOTKGJBKKKVBJZ-UHFFFAOYSA-L 0.000 description 1
- JGFBRKRYDCGYKD-UHFFFAOYSA-N dibutyl(oxo)tin Chemical compound CCCC[Sn](=O)CCCC JGFBRKRYDCGYKD-UHFFFAOYSA-N 0.000 description 1
- 238000004821 distillation Methods 0.000 description 1
- 238000009826 distribution Methods 0.000 description 1
- 238000001035 drying Methods 0.000 description 1
- 239000000975 dye Substances 0.000 description 1
- 230000032050 esterification Effects 0.000 description 1
- 238000005886 esterification reaction Methods 0.000 description 1
- 125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 description 1
- 230000003619 fibrillary effect Effects 0.000 description 1
- 239000003365 glass fiber Substances 0.000 description 1
- 150000002334 glycols Chemical class 0.000 description 1
- XXMIOPMDWAUFGU-UHFFFAOYSA-N hexane-1,6-diol Chemical compound OCCCCCCO XXMIOPMDWAUFGU-UHFFFAOYSA-N 0.000 description 1
- WGCNASOHLSPBMP-UHFFFAOYSA-N hydroxyacetaldehyde Natural products OCC=O WGCNASOHLSPBMP-UHFFFAOYSA-N 0.000 description 1
- 229910052749 magnesium Inorganic materials 0.000 description 1
- 239000011777 magnesium Substances 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 239000006224 matting agent Substances 0.000 description 1
- 229920005787 opaque polymer Polymers 0.000 description 1
- 229910052697 platinum Inorganic materials 0.000 description 1
- 229920000909 polytetrahydrofuran Polymers 0.000 description 1
- 239000000843 powder Substances 0.000 description 1
- 239000000376 reactant Substances 0.000 description 1
- 230000002787 reinforcement Effects 0.000 description 1
- 229920005989 resin Polymers 0.000 description 1
- 239000011347 resin Substances 0.000 description 1
- 230000000284 resting effect Effects 0.000 description 1
- 239000000377 silicon dioxide Substances 0.000 description 1
- 229920002545 silicone oil Polymers 0.000 description 1
- 239000003381 stabilizer Substances 0.000 description 1
- 239000007858 starting material Substances 0.000 description 1
- 238000005809 transesterification reaction Methods 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G63/00—Macromolecular compounds obtained by reactions forming a carboxylic ester link in the main chain of the macromolecule
- C08G63/66—Polyesters containing oxygen in the form of ether groups
- C08G63/664—Polyesters containing oxygen in the form of ether groups derived from hydroxy carboxylic acids
-
- D—TEXTILES; PAPER
- D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
- D01F—CHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
- D01F6/00—Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof
- D01F6/78—Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof from copolycondensation products
- D01F6/84—Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof from copolycondensation products from copolyesters
-
- D—TEXTILES; PAPER
- D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
- D01F—CHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
- D01F6/00—Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof
- D01F6/78—Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof from copolycondensation products
- D01F6/86—Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof from copolycondensation products from polyetheresters
Landscapes
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Textile Engineering (AREA)
- Health & Medical Sciences (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Polyesters Or Polycarbonates (AREA)
- Artificial Filaments (AREA)
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| FR7526737A FR2322162A1 (fr) | 1975-08-27 | 1975-08-27 | Copolyesters arylates sequences et leur procede d'obtention |
| FR7617484A FR2354401A2 (fr) | 1976-06-08 | 1976-06-08 | Fils a base de copolyesters arylates sequences et leur procede d'obtention |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| DE2638755A1 true DE2638755A1 (de) | 1977-03-10 |
Family
ID=26219049
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| DE19762638755 Withdrawn DE2638755A1 (de) | 1975-08-27 | 1976-08-27 | Copolyester mit arylatsequenzen und faeden auf basis dieser copolyester |
Country Status (16)
| Country | Link |
|---|---|
| US (1) | US4057597A (enue) |
| JP (1) | JPS5228595A (enue) |
| BR (1) | BR7605663A (enue) |
| CA (1) | CA1093739A (enue) |
| CH (1) | CH616693A5 (enue) |
| DD (2) | DD133690A5 (enue) |
| DE (1) | DE2638755A1 (enue) |
| DK (1) | DK387576A (enue) |
| ES (1) | ES451046A1 (enue) |
| GB (1) | GB1559313A (enue) |
| IE (1) | IE43419B1 (enue) |
| LU (1) | LU75663A1 (enue) |
| NL (1) | NL7609363A (enue) |
| PL (1) | PL105235B1 (enue) |
| RO (1) | RO71727A (enue) |
| SE (2) | SE7609482L (enue) |
Families Citing this family (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US6045906A (en) | 1984-03-15 | 2000-04-04 | Cytec Technology Corp. | Continuous, linearly intermixed fiber tows and composite molded article thereform |
| US5225489A (en) * | 1987-03-05 | 1993-07-06 | Allied-Signal Inc. | Composites of thermoplastic and thermoplastic polymers having therein short fibers derived from anisotropic polymers |
| US4980232A (en) * | 1987-03-05 | 1990-12-25 | Allied-Signal Inc. | Short fibers composed of antisotropic polymers and composites of thermoplastic and/or thermoset resins and such fibers |
Family Cites Families (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| FR921683A (fr) | 1943-08-23 | 1947-05-14 | Calico Printers Ass Ltd | Nouveaux produits synthétiques fortement polymérisés, leur procédé de fabrication et leurs applications |
| US2728747A (en) * | 1952-10-22 | 1955-12-27 | Gen Mills Inc | Polyester resins |
| DE1720440B2 (de) | 1967-03-01 | 1980-12-18 | Dart Industries Inc., Los Angeles, Calif. (V.St.A.) | Polyester und Verfahren zu seiner Herstellung |
| JPS5645942B2 (enue) * | 1973-01-18 | 1981-10-29 | ||
| GB1443109A (en) * | 1973-06-30 | 1976-07-21 | Toyo Boseki | Film having excellent slip characterisitcs and its production |
| US3917743A (en) * | 1974-03-07 | 1975-11-04 | Du Pont | Copolyetherester blends |
-
1976
- 1976-08-23 NL NL7609363A patent/NL7609363A/xx not_active Application Discontinuation
- 1976-08-25 JP JP51100717A patent/JPS5228595A/ja active Pending
- 1976-08-25 US US05/717,677 patent/US4057597A/en not_active Expired - Lifetime
- 1976-08-25 IE IE1897/76A patent/IE43419B1/en unknown
- 1976-08-26 CH CH1085976A patent/CH616693A5/fr not_active IP Right Cessation
- 1976-08-26 DK DK387576A patent/DK387576A/da unknown
- 1976-08-26 DD DD7600199692A patent/DD133690A5/xx unknown
- 1976-08-26 CA CA259,965A patent/CA1093739A/fr not_active Expired
- 1976-08-26 SE SE7609482A patent/SE7609482L/xx unknown
- 1976-08-26 GB GB35614/76A patent/GB1559313A/en not_active Expired
- 1976-08-26 DD DD194488A patent/DD126516A5/xx unknown
- 1976-08-26 LU LU75663A patent/LU75663A1/xx unknown
- 1976-08-27 DE DE19762638755 patent/DE2638755A1/de not_active Withdrawn
- 1976-08-27 PL PL1976192047A patent/PL105235B1/pl not_active IP Right Cessation
- 1976-08-27 RO RO7687386A patent/RO71727A/ro unknown
- 1976-08-27 ES ES451046A patent/ES451046A1/es not_active Expired
- 1976-08-27 BR BR7605663A patent/BR7605663A/pt unknown
-
1981
- 1981-01-28 SE SE8100579A patent/SE8100579L/sv unknown
Also Published As
| Publication number | Publication date |
|---|---|
| LU75663A1 (enue) | 1977-03-31 |
| NL7609363A (nl) | 1977-03-01 |
| US4057597A (en) | 1977-11-08 |
| IE43419B1 (en) | 1981-02-25 |
| SE7609482L (sv) | 1977-02-28 |
| CH616693A5 (enue) | 1980-04-15 |
| SE8100579L (sv) | 1981-01-28 |
| PL105235B1 (pl) | 1979-09-29 |
| BR7605663A (pt) | 1977-08-09 |
| RO71727A (ro) | 1980-12-30 |
| DD133690A5 (de) | 1979-01-17 |
| DD126516A5 (enue) | 1977-07-20 |
| DK387576A (da) | 1977-02-28 |
| PL192047A1 (pl) | 1978-02-13 |
| ES451046A1 (es) | 1977-11-16 |
| CA1093739A (fr) | 1981-01-13 |
| GB1559313A (en) | 1980-01-16 |
| IE43419L (en) | 1977-02-27 |
| JPS5228595A (en) | 1977-03-03 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| 8139 | Disposal/non-payment of the annual fee |