DE2613642C2 - Verfahren zur Stabilisierung von Fluorkohlenstoffpolymerisaten - Google Patents
Verfahren zur Stabilisierung von FluorkohlenstoffpolymerisatenInfo
- Publication number
- DE2613642C2 DE2613642C2 DE2613642A DE2613642A DE2613642C2 DE 2613642 C2 DE2613642 C2 DE 2613642C2 DE 2613642 A DE2613642 A DE 2613642A DE 2613642 A DE2613642 A DE 2613642A DE 2613642 C2 DE2613642 C2 DE 2613642C2
- Authority
- DE
- Germany
- Prior art keywords
- copolymers
- melt viscosity
- copolymer
- melt
- weight
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 238000000034 method Methods 0.000 title claims description 16
- 230000000087 stabilizing effect Effects 0.000 title description 3
- 229920002313 fluoropolymer Polymers 0.000 title description 2
- 229920001577 copolymer Polymers 0.000 claims description 58
- 239000000155 melt Substances 0.000 claims description 27
- 238000010438 heat treatment Methods 0.000 claims description 13
- HCDGVLDPFQMKDK-UHFFFAOYSA-N hexafluoropropylene Chemical group FC(F)=C(F)C(F)(F)F HCDGVLDPFQMKDK-UHFFFAOYSA-N 0.000 claims description 11
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Chemical compound O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 10
- BFKJFAAPBSQJPD-UHFFFAOYSA-N tetrafluoroethene Chemical group FC(F)=C(F)F BFKJFAAPBSQJPD-UHFFFAOYSA-N 0.000 claims description 8
- 230000006641 stabilisation Effects 0.000 claims description 5
- 238000011105 stabilization Methods 0.000 claims description 5
- 239000000126 substance Substances 0.000 claims 1
- 239000000203 mixture Substances 0.000 description 14
- 239000006260 foam Substances 0.000 description 11
- 229920000642 polymer Polymers 0.000 description 8
- 229910052782 aluminium Inorganic materials 0.000 description 7
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 7
- 238000005187 foaming Methods 0.000 description 7
- 230000015572 biosynthetic process Effects 0.000 description 6
- 239000003999 initiator Substances 0.000 description 6
- 238000012360 testing method Methods 0.000 description 5
- 239000002270 dispersing agent Substances 0.000 description 4
- 238000004519 manufacturing process Methods 0.000 description 4
- 229910052751 metal Inorganic materials 0.000 description 4
- 239000002184 metal Substances 0.000 description 4
- 238000004364 calculation method Methods 0.000 description 3
- 239000011888 foil Substances 0.000 description 3
- 239000007789 gas Substances 0.000 description 3
- 229910001347 Stellite Inorganic materials 0.000 description 2
- ROOXNKNUYICQNP-UHFFFAOYSA-N ammonium peroxydisulfate Substances [NH4+].[NH4+].[O-]S(=O)(=O)OOS([O-])(=O)=O ROOXNKNUYICQNP-UHFFFAOYSA-N 0.000 description 2
- VAZSKTXWXKYQJF-UHFFFAOYSA-N ammonium persulfate Chemical compound [NH4+].[NH4+].[O-]S(=O)OOS([O-])=O VAZSKTXWXKYQJF-UHFFFAOYSA-N 0.000 description 2
- 229910001870 ammonium persulfate Inorganic materials 0.000 description 2
- YOALFLHFSFEMLP-UHFFFAOYSA-N azane;2,2,3,3,4,4,5,5,6,6,7,7,8,8,8-pentadecafluorooctanoic acid Chemical compound [NH4+].[O-]C(=O)C(F)(F)C(F)(F)C(F)(F)C(F)(F)C(F)(F)C(F)(F)C(F)(F)F YOALFLHFSFEMLP-UHFFFAOYSA-N 0.000 description 2
- 239000007795 chemical reaction product Substances 0.000 description 2
- 238000001125 extrusion Methods 0.000 description 2
- 239000003039 volatile agent Substances 0.000 description 2
- 230000002745 absorbent Effects 0.000 description 1
- 239000002250 absorbent Substances 0.000 description 1
- 229910045601 alloy Inorganic materials 0.000 description 1
- 239000000956 alloy Substances 0.000 description 1
- 235000008429 bread Nutrition 0.000 description 1
- -1 cationic Metal compound Chemical class 0.000 description 1
- AHICWQREWHDHHF-UHFFFAOYSA-N chromium;cobalt;iron;manganese;methane;molybdenum;nickel;silicon;tungsten Chemical compound C.[Si].[Cr].[Mn].[Fe].[Co].[Ni].[Mo].[W] AHICWQREWHDHHF-UHFFFAOYSA-N 0.000 description 1
- 230000001112 coagulating effect Effects 0.000 description 1
- 238000000576 coating method Methods 0.000 description 1
- 238000001816 cooling Methods 0.000 description 1
- 238000005260 corrosion Methods 0.000 description 1
- 230000007797 corrosion Effects 0.000 description 1
- 239000013536 elastomeric material Substances 0.000 description 1
- 238000010292 electrical insulation Methods 0.000 description 1
- 239000004744 fabric Substances 0.000 description 1
- 238000007429 general method Methods 0.000 description 1
- 239000011521 glass Substances 0.000 description 1
- 238000011065 in-situ storage Methods 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 239000000178 monomer Substances 0.000 description 1
- 238000000465 moulding Methods 0.000 description 1
- 230000000704 physical effect Effects 0.000 description 1
- 238000006116 polymerization reaction Methods 0.000 description 1
- USHAGKDGDHPEEY-UHFFFAOYSA-L potassium persulfate Chemical compound [K+].[K+].[O-]S(=O)(=O)OOS([O-])(=O)=O USHAGKDGDHPEEY-UHFFFAOYSA-L 0.000 description 1
- 238000012545 processing Methods 0.000 description 1
- 239000007870 radical polymerization initiator Substances 0.000 description 1
- 239000000344 soap Substances 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
- 238000003756 stirring Methods 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J3/00—Processes of treating or compounding macromolecular substances
- C08J3/005—Processes for mixing polymers
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L27/00—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers
- C08L27/02—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers not modified by chemical after-treatment
- C08L27/12—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers not modified by chemical after-treatment containing fluorine atoms
- C08L27/18—Homopolymers or copolymers or tetrafluoroethene
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2327/00—Characterised by the use of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Derivatives of such polymers
- C08J2327/02—Characterised by the use of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Derivatives of such polymers not modified by chemical after-treatment
- C08J2327/12—Characterised by the use of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Derivatives of such polymers not modified by chemical after-treatment containing fluorine atoms
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Processes Of Treating Macromolecular Substances (AREA)
- Processing And Handling Of Plastics And Other Materials For Molding In General (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
- Manufacture Of Porous Articles, And Recovery And Treatment Of Waste Products (AREA)
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US05/564,902 US4001351A (en) | 1975-04-03 | 1975-04-03 | Process for preparing tetrafluoroethylene-hexafluoropropylene copolymer blends |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| DE2613642A1 DE2613642A1 (de) | 1976-10-21 |
| DE2613642C2 true DE2613642C2 (de) | 1986-04-24 |
Family
ID=24256368
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| DE2613642A Expired DE2613642C2 (de) | 1975-04-03 | 1976-03-31 | Verfahren zur Stabilisierung von Fluorkohlenstoffpolymerisaten |
Country Status (7)
| Country | Link |
|---|---|
| US (1) | US4001351A (enExample) |
| JP (1) | JPS5932496B2 (enExample) |
| DE (1) | DE2613642C2 (enExample) |
| FR (1) | FR2306218A1 (enExample) |
| GB (1) | GB1489174A (enExample) |
| IT (1) | IT1058956B (enExample) |
| NL (1) | NL7603482A (enExample) |
Families Citing this family (24)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS6023689B2 (ja) | 1976-02-17 | 1985-06-08 | ダイキン工業株式会社 | テトラフルオロエチレン／ヘキサフルオロプロピレン共重合体の製造方法 |
| JPS58174407A (ja) * | 1982-03-08 | 1983-10-13 | Daikin Ind Ltd | 押出性の改良された含フツ素共重合体 |
| JPS60155275A (ja) * | 1984-01-24 | 1985-08-15 | Sumitomo Chem Co Ltd | 被覆用樹脂組成物 |
| US4675380A (en) * | 1985-10-25 | 1987-06-23 | E. I. Du Pont De Nemours And Company | Melt-processible tetrafluoroethylene/perfluoroolefin copolymer granules and processes for preparing them |
| JPH075743B2 (ja) * | 1986-12-22 | 1995-01-25 | ダイキン工業株式会社 | テトラフルオロエチレン系共重合体粉末およびその製造法 |
| JPH02102247A (ja) * | 1988-10-07 | 1990-04-13 | Daikin Ind Ltd | 溶融型フッ素樹脂組成物 |
| US5478905A (en) * | 1995-02-06 | 1995-12-26 | E. I. Du Pont De Nemours And Company | Amorphous tetrafluoroethylene/hexafluoropropylene copolymers |
| US6133389A (en) * | 1995-02-06 | 2000-10-17 | E. I. Du Pont De Nemours And Company | Amorphous tetrafluoroethylene-hexafluoropropylene copolymers |
| WO1996024624A2 (en) * | 1995-02-06 | 1996-08-15 | E.I. Du Pont De Nemours And Company | Amorphous tetrafluoroethylene-hexafluoropropylene copolymers |
| US5741855A (en) * | 1996-06-10 | 1998-04-21 | Raychem Corporation | Compatibilized fluoroplastic blends |
| US5726214A (en) * | 1996-12-26 | 1998-03-10 | E. I. Du Pont De Nemours And Company | Self-foaming fluoropolymer composition |
| CN100379772C (zh) * | 1998-03-09 | 2008-04-09 | 大金工业株式会社 | 稳定化的含氟聚合物及使含氟聚合物稳定化的方法 |
| US6541588B1 (en) * | 1999-01-29 | 2003-04-01 | 3M Innovative Properties Company | Tetrafluoroethylene/hexafluoropropylene copolymers with higher drawability |
| DE10033514A1 (de) | 2000-07-11 | 2002-02-07 | Dyneon Gmbh | FEP mit erhöhter Wechselbiegefestigkeit und geringen Düsenablagerungen |
| US6583226B1 (en) | 2001-06-28 | 2003-06-24 | 3M Innovative Properties Company | FEP with increased flexural fatigue strength and a low level of die deposits |
| WO2003022923A1 (en) * | 2001-09-11 | 2003-03-20 | Daikin Industries, Ltd. | Fluorine-containing resin composition, method for producing the same, and cable having coating comprising the same |
| US7169854B2 (en) | 2001-09-11 | 2007-01-30 | Daikin Industries, Ltd. | Fluororesin composition, process for preparing the same and cable coated with the same |
| US6743508B2 (en) | 2002-01-17 | 2004-06-01 | Daikin America, Inc. | Fep pellet |
| US6703464B2 (en) * | 2002-01-17 | 2004-03-09 | Daikin America, Inc. | Flourine-containing copolymer |
| ATE546471T1 (de) * | 2003-03-25 | 2012-03-15 | 3M Innovative Properties Co | In der schmelze verarbeitbare thermoplastische fluorpolymere mit verbesserter verarbeitbarkeit und verfahren zu ihrer herstellung |
| KR20140107412A (ko) * | 2011-12-14 | 2014-09-04 | 다이킨 고교 가부시키가이샤 | 절연 전선 |
| EP2881430B1 (en) * | 2012-08-06 | 2016-11-23 | Daikin Industries, Ltd. | Resin composition and molded article |
| CN105408422B (zh) * | 2013-07-25 | 2018-03-27 | 大金工业株式会社 | 热塑性树脂组合物和成型品 |
| WO2016056431A1 (ja) * | 2014-10-10 | 2016-04-14 | ダイキン工業株式会社 | 樹脂組成物および成形品 |
Family Cites Families (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| NL110421C (enExample) * | 1957-03-29 | |||
| NL251214A (enExample) * | 1959-05-05 |
-
1975
- 1975-04-03 US US05/564,902 patent/US4001351A/en not_active Expired - Lifetime
-
1976
- 1976-03-31 DE DE2613642A patent/DE2613642C2/de not_active Expired
- 1976-04-01 FR FR7609465A patent/FR2306218A1/fr active Granted
- 1976-04-01 GB GB13270/76A patent/GB1489174A/en not_active Expired
- 1976-04-01 JP JP51035236A patent/JPS5932496B2/ja not_active Expired
- 1976-04-02 NL NL7603482A patent/NL7603482A/xx not_active Application Discontinuation
- 1976-04-02 IT IT21915/76A patent/IT1058956B/it active
Also Published As
| Publication number | Publication date |
|---|---|
| USB564902I5 (enExample) | 1976-03-23 |
| FR2306218A1 (fr) | 1976-10-29 |
| US4001351A (en) | 1977-01-04 |
| IT1058956B (it) | 1982-05-10 |
| FR2306218B1 (enExample) | 1980-02-08 |
| NL7603482A (nl) | 1976-10-05 |
| GB1489174A (en) | 1977-10-19 |
| JPS51122156A (en) | 1976-10-26 |
| DE2613642A1 (de) | 1976-10-21 |
| JPS5932496B2 (ja) | 1984-08-09 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| 8110 | Request for examination paragraph 44 | ||
| 8162 | Independent application | ||
| D2 | Grant after examination | ||
| 8363 | Opposition against the patent | ||
| 8331 | Complete revocation |