DE2557914C2 - - Google Patents
Info
- Publication number
- DE2557914C2 DE2557914C2 DE2557914A DE2557914A DE2557914C2 DE 2557914 C2 DE2557914 C2 DE 2557914C2 DE 2557914 A DE2557914 A DE 2557914A DE 2557914 A DE2557914 A DE 2557914A DE 2557914 C2 DE2557914 C2 DE 2557914C2
- Authority
- DE
- Germany
- Prior art keywords
- catalyst
- weight
- water vapor
- parts
- oil
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 239000003054 catalyst Substances 0.000 claims description 86
- 239000003921 oil Substances 0.000 claims description 57
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Chemical compound O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 57
- 238000000034 method Methods 0.000 claims description 52
- 238000006477 desulfuration reaction Methods 0.000 claims description 30
- 230000023556 desulfurization Effects 0.000 claims description 30
- 229910052739 hydrogen Inorganic materials 0.000 claims description 30
- 239000001257 hydrogen Substances 0.000 claims description 30
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 claims description 28
- 239000004215 Carbon black (E152) Substances 0.000 claims description 26
- 229930195733 hydrocarbon Natural products 0.000 claims description 26
- 150000002430 hydrocarbons Chemical class 0.000 claims description 25
- 229910052720 vanadium Inorganic materials 0.000 claims description 24
- LEONUFNNVUYDNQ-UHFFFAOYSA-N vanadium atom Chemical compound [V] LEONUFNNVUYDNQ-UHFFFAOYSA-N 0.000 claims description 23
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 claims description 22
- 229910052759 nickel Inorganic materials 0.000 claims description 11
- 239000012876 carrier material Substances 0.000 claims description 10
- 230000003197 catalytic effect Effects 0.000 claims description 10
- ZOKXTWBITQBERF-UHFFFAOYSA-N Molybdenum Chemical compound [Mo] ZOKXTWBITQBERF-UHFFFAOYSA-N 0.000 claims description 9
- 229910052751 metal Inorganic materials 0.000 claims description 9
- 239000002184 metal Substances 0.000 claims description 9
- 229910052750 molybdenum Inorganic materials 0.000 claims description 9
- 239000011733 molybdenum Substances 0.000 claims description 9
- 229910017052 cobalt Inorganic materials 0.000 claims description 8
- 239000010941 cobalt Substances 0.000 claims description 8
- GUTLYIVDDKVIGB-UHFFFAOYSA-N cobalt atom Chemical compound [Co] GUTLYIVDDKVIGB-UHFFFAOYSA-N 0.000 claims description 8
- 150000002739 metals Chemical class 0.000 claims description 8
- WFKWXMTUELFFGS-UHFFFAOYSA-N tungsten Chemical compound [W] WFKWXMTUELFFGS-UHFFFAOYSA-N 0.000 claims description 7
- 229910052721 tungsten Inorganic materials 0.000 claims description 7
- 239000010937 tungsten Substances 0.000 claims description 7
- 239000000463 material Substances 0.000 claims description 5
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims description 4
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 claims description 4
- 238000005984 hydrogenation reaction Methods 0.000 claims description 3
- 150000002431 hydrogen Chemical class 0.000 claims description 2
- 239000000377 silicon dioxide Substances 0.000 claims description 2
- 238000002474 experimental method Methods 0.000 description 15
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 description 9
- 229910052717 sulfur Inorganic materials 0.000 description 9
- 239000011593 sulfur Substances 0.000 description 9
- 230000009849 deactivation Effects 0.000 description 6
- 230000009286 beneficial effect Effects 0.000 description 5
- 238000004821 distillation Methods 0.000 description 5
- 239000002245 particle Substances 0.000 description 5
- 239000007789 gas Substances 0.000 description 4
- 230000000694 effects Effects 0.000 description 3
- 150000004763 sulfides Chemical class 0.000 description 3
- 238000006243 chemical reaction Methods 0.000 description 2
- 239000010779 crude oil Substances 0.000 description 2
- 238000011835 investigation Methods 0.000 description 2
- 239000007788 liquid Substances 0.000 description 2
- 239000000203 mixture Substances 0.000 description 2
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 1
- KFOLLPUZRCFERL-UHFFFAOYSA-N [O-2].[Mg+2].O=[Si]=O Chemical compound [O-2].[Mg+2].O=[Si]=O KFOLLPUZRCFERL-UHFFFAOYSA-N 0.000 description 1
- CNGGOAOYPQGTLH-UHFFFAOYSA-N [O-2].[O-2].[Mg+2].[Al+3] Chemical compound [O-2].[O-2].[Mg+2].[Al+3] CNGGOAOYPQGTLH-UHFFFAOYSA-N 0.000 description 1
- HHUIAYDQMNHELC-UHFFFAOYSA-N [O-2].[O-2].[O-2].[Al+3].[Al+3].O=[Si]=O Chemical compound [O-2].[O-2].[O-2].[Al+3].[Al+3].O=[Si]=O HHUIAYDQMNHELC-UHFFFAOYSA-N 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 238000004523 catalytic cracking Methods 0.000 description 1
- 238000009903 catalytic hydrogenation reaction Methods 0.000 description 1
- 239000002826 coolant Substances 0.000 description 1
- 230000003247 decreasing effect Effects 0.000 description 1
- 230000008021 deposition Effects 0.000 description 1
- AZRCNKIZGKJWOA-UHFFFAOYSA-N dioxosilane oxygen(2-) zirconium(4+) Chemical compound [O-2].[O-2].[Zr+4].O=[Si]=O AZRCNKIZGKJWOA-UHFFFAOYSA-N 0.000 description 1
- 230000008020 evaporation Effects 0.000 description 1
- 238000001704 evaporation Methods 0.000 description 1
- 230000000887 hydrating effect Effects 0.000 description 1
- 238000002347 injection Methods 0.000 description 1
- 239000007924 injection Substances 0.000 description 1
- 239000000395 magnesium oxide Substances 0.000 description 1
- CPLXHLVBOLITMK-UHFFFAOYSA-N magnesium oxide Inorganic materials [Mg]=O CPLXHLVBOLITMK-UHFFFAOYSA-N 0.000 description 1
- AXZKOIWUVFPNLO-UHFFFAOYSA-N magnesium;oxygen(2-) Chemical compound [O-2].[Mg+2] AXZKOIWUVFPNLO-UHFFFAOYSA-N 0.000 description 1
- TWNQGVIAIRXVLR-UHFFFAOYSA-N oxo(oxoalumanyloxy)alumane Chemical compound O=[Al]O[Al]=O TWNQGVIAIRXVLR-UHFFFAOYSA-N 0.000 description 1
- RVTZCBVAJQQJTK-UHFFFAOYSA-N oxygen(2-);zirconium(4+) Chemical compound [O-2].[O-2].[Zr+4] RVTZCBVAJQQJTK-UHFFFAOYSA-N 0.000 description 1
- 230000000737 periodic effect Effects 0.000 description 1
- 239000003208 petroleum Substances 0.000 description 1
- 235000012239 silicon dioxide Nutrition 0.000 description 1
- 239000000758 substrate Substances 0.000 description 1
- 150000003464 sulfur compounds Chemical class 0.000 description 1
- 238000004227 thermal cracking Methods 0.000 description 1
- -1 vanadium Hydrocarbon Chemical class 0.000 description 1
- 150000003682 vanadium compounds Chemical class 0.000 description 1
- 229910001928 zirconium oxide Inorganic materials 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G45/00—Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds
- C10G45/02—Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds to eliminate hetero atoms without changing the skeleton of the hydrocarbon involved and without cracking into lower boiling hydrocarbons; Hydrofinishing
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G2300/00—Aspects relating to hydrocarbon processing covered by groups C10G1/00 - C10G99/00
- C10G2300/10—Feedstock materials
- C10G2300/107—Atmospheric residues having a boiling point of at least about 538 °C
Landscapes
- Chemical & Material Sciences (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Production Of Liquid Hydrocarbon Mixture For Refining Petroleum (AREA)
- Catalysts (AREA)
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| NLAANVRAGE7503466,A NL182489C (nl) | 1975-03-24 | 1975-03-24 | Werkwijze voor het ontzwavelen van zware vanadiumhoudende koolwaterstoffen. |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| DE2557914A1 DE2557914A1 (de) | 1976-10-07 |
| DE2557914C2 true DE2557914C2 (en, 2012) | 1988-10-06 |
Family
ID=19823443
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| DE19752557914 Granted DE2557914A1 (de) | 1975-03-24 | 1975-12-22 | Verfahren zur katalytischen hydrierenden entschwefelung von schweren kohlenwasserstoffoelen |
Country Status (11)
| Country | Link |
|---|---|
| US (1) | US4052295A (en, 2012) |
| JP (1) | JPS5929634B2 (en, 2012) |
| BE (1) | BE836992A (en, 2012) |
| CA (1) | CA1074717A (en, 2012) |
| DE (1) | DE2557914A1 (en, 2012) |
| FR (1) | FR2305486A1 (en, 2012) |
| GB (1) | GB1525509A (en, 2012) |
| IT (1) | IT1051699B (en, 2012) |
| NL (1) | NL182489C (en, 2012) |
| SE (1) | SE412410B (en, 2012) |
| ZA (1) | ZA757932B (en, 2012) |
Families Citing this family (9)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4272357A (en) * | 1976-03-29 | 1981-06-09 | Mobil Oil Corporation | Desulfurization and demetalation of heavy charge stocks |
| US4235703A (en) * | 1979-03-27 | 1980-11-25 | Conoco, Inc. | Method for producing premium coke from residual oil |
| US4560466A (en) * | 1984-10-29 | 1985-12-24 | Phillips Petroleum Company | Hydrodemetallization of heavy oils in the presence of water |
| US20020056664A1 (en) * | 2000-09-07 | 2002-05-16 | Julie Chabot | Extension of catalyst cycle length in residuum desulfurization processes |
| WO2009073436A2 (en) * | 2007-11-28 | 2009-06-11 | Saudi Arabian Oil Company | Process for catalytic hydrotreating of sour crude oils |
| EP2300566B1 (en) * | 2008-07-14 | 2016-09-07 | Saudi Arabian Oil Company | Process for the treatment of heavy oils using light hydrocarbon components as a diluent |
| WO2010009082A1 (en) * | 2008-07-14 | 2010-01-21 | Saudi Arabian Oil Company | A prerefining process for the hydrodesulfurization of heavy sour crude oils to produce sweeter lighter crudes using moving catalyst system |
| US8372267B2 (en) * | 2008-07-14 | 2013-02-12 | Saudi Arabian Oil Company | Process for the sequential hydroconversion and hydrodesulfurization of whole crude oil |
| US8491779B2 (en) * | 2009-06-22 | 2013-07-23 | Saudi Arabian Oil Company | Alternative process for treatment of heavy crudes in a coking refinery |
Family Cites Families (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3116234A (en) * | 1959-12-08 | 1963-12-31 | Shell Oil Co | Process for the catalytic desulfurization of hydrocarbon oils |
| CA641066A (en) * | 1960-03-09 | 1962-05-08 | Shell Oil Company | Process for the catalytic desulfurization of hydrocarbon oils |
| US3471398A (en) * | 1967-03-08 | 1969-10-07 | Universal Oil Prod Co | Method for the conversion of hydrocarbons |
| US3536607A (en) * | 1968-11-08 | 1970-10-27 | Universal Oil Prod Co | Process for the conversion of hydrocarbons |
| US3501396A (en) * | 1969-04-14 | 1970-03-17 | Universal Oil Prod Co | Hydrodesulfurization of asphaltene-containing black oil |
| US3617481A (en) * | 1969-12-11 | 1971-11-02 | Exxon Research Engineering Co | Combination deasphalting-coking-hydrotreating process |
| US3753894A (en) * | 1971-02-26 | 1973-08-21 | Exxon Research Engineering Co | Water injection between catalyst beds in hydrodesulfurization of residuum feed |
| DE2332834A1 (de) * | 1973-06-28 | 1975-01-23 | Exxon Research Engineering Co | Hydrodesulfurierung von rueckstandsoelen |
-
1975
- 1975-03-24 NL NLAANVRAGE7503466,A patent/NL182489C/xx not_active IP Right Cessation
- 1975-11-24 CA CA240,234A patent/CA1074717A/en not_active Expired
- 1975-12-22 ZA ZA00757932A patent/ZA757932B/xx unknown
- 1975-12-22 JP JP50152025A patent/JPS5929634B2/ja not_active Expired
- 1975-12-22 GB GB52346/75A patent/GB1525509A/en not_active Expired
- 1975-12-22 DE DE19752557914 patent/DE2557914A1/de active Granted
- 1975-12-22 IT IT30645/75A patent/IT1051699B/it active
- 1975-12-22 SE SE7514535A patent/SE412410B/xx not_active IP Right Cessation
- 1975-12-22 FR FR7539340A patent/FR2305486A1/fr active Granted
- 1975-12-23 BE BE1007100A patent/BE836992A/xx not_active IP Right Cessation
-
1976
- 1976-02-09 US US05/656,544 patent/US4052295A/en not_active Expired - Lifetime
Also Published As
| Publication number | Publication date |
|---|---|
| SE412410B (sv) | 1980-03-03 |
| SE7514535L (sv) | 1976-09-25 |
| NL182489C (nl) | 1988-03-16 |
| NL182489B (nl) | 1987-10-16 |
| DE2557914A1 (de) | 1976-10-07 |
| NL7503466A (nl) | 1976-09-28 |
| US4052295A (en) | 1977-10-04 |
| JPS51111208A (en) | 1976-10-01 |
| CA1074717A (en) | 1980-04-01 |
| FR2305486A1 (fr) | 1976-10-22 |
| ZA757932B (en) | 1976-12-29 |
| JPS5929634B2 (ja) | 1984-07-21 |
| GB1525509A (en) | 1978-09-20 |
| AU8777775A (en) | 1977-06-30 |
| FR2305486B1 (en, 2012) | 1978-05-19 |
| IT1051699B (it) | 1981-05-20 |
| BE836992A (nl) | 1976-06-23 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| 8110 | Request for examination paragraph 44 | ||
| 8128 | New person/name/address of the agent |
Representative=s name: JUNG, E., DIPL.-CHEM. DR.PHIL. SCHIRDEWAHN, J., DI |
|
| 8125 | Change of the main classification |
Ipc: C10G 65/04 |
|
| D2 | Grant after examination | ||
| 8364 | No opposition during term of opposition | ||
| 8339 | Ceased/non-payment of the annual fee |