DE2553145B2 - Verkohlungsbeständige, vulkanisierbare Masse - Google Patents
Verkohlungsbeständige, vulkanisierbare MasseInfo
- Publication number
- DE2553145B2 DE2553145B2 DE2553145A DE2553145A DE2553145B2 DE 2553145 B2 DE2553145 B2 DE 2553145B2 DE 2553145 A DE2553145 A DE 2553145A DE 2553145 A DE2553145 A DE 2553145A DE 2553145 B2 DE2553145 B2 DE 2553145B2
- Authority
- DE
- Germany
- Prior art keywords
- weight
- tert
- ethylene
- peroxide
- charring
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Ceased
Links
- 150000001875 compounds Chemical class 0.000 title description 21
- 229920000573 polyethylene Polymers 0.000 claims description 29
- 150000002978 peroxides Chemical class 0.000 claims description 22
- CIHOLLKRGTVIJN-UHFFFAOYSA-N tert‐butyl hydroperoxide Chemical compound CC(C)(C)OO CIHOLLKRGTVIJN-UHFFFAOYSA-N 0.000 claims description 17
- FRIBMENBGGCKPD-UHFFFAOYSA-N 3-(2,3-dimethoxyphenyl)prop-2-enal Chemical compound COC1=CC=CC(C=CC=O)=C1OC FRIBMENBGGCKPD-UHFFFAOYSA-N 0.000 claims description 5
- 239000000463 material Substances 0.000 claims description 4
- AXWJKQDGIVWVEW-UHFFFAOYSA-N 2-(dimethylamino)butanedioic acid Chemical compound CN(C)C(C(O)=O)CC(O)=O AXWJKQDGIVWVEW-UHFFFAOYSA-N 0.000 claims description 3
- MHAJPDPJQMAIIY-UHFFFAOYSA-N Hydrogen peroxide Chemical compound OO MHAJPDPJQMAIIY-UHFFFAOYSA-N 0.000 claims description 3
- 238000004519 manufacturing process Methods 0.000 claims description 3
- 150000001451 organic peroxides Chemical class 0.000 claims description 3
- 239000000203 mixture Substances 0.000 description 40
- 238000012360 testing method Methods 0.000 description 17
- 239000005977 Ethylene Substances 0.000 description 12
- -1 organic Peroxide compounds Chemical class 0.000 description 12
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 description 11
- 239000003963 antioxidant agent Substances 0.000 description 11
- 239000003795 chemical substances by application Substances 0.000 description 9
- 238000000034 method Methods 0.000 description 9
- 238000004073 vulcanization Methods 0.000 description 9
- 238000001125 extrusion Methods 0.000 description 7
- 229920000642 polymer Polymers 0.000 description 7
- VXNZUUAINFGPBY-UHFFFAOYSA-N 1-Butene Chemical compound CCC=C VXNZUUAINFGPBY-UHFFFAOYSA-N 0.000 description 6
- UHOVQNZJYSORNB-UHFFFAOYSA-N Benzene Chemical compound C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 description 6
- 230000003078 antioxidant effect Effects 0.000 description 6
- 239000004020 conductor Substances 0.000 description 6
- 229920001577 copolymer Polymers 0.000 description 6
- 229920001519 homopolymer Polymers 0.000 description 6
- 150000002432 hydroperoxides Chemical class 0.000 description 6
- 238000010998 test method Methods 0.000 description 6
- 238000009413 insulation Methods 0.000 description 4
- 238000002360 preparation method Methods 0.000 description 4
- XMNIXWIUMCBBBL-UHFFFAOYSA-N 2-(2-phenylpropan-2-ylperoxy)propan-2-ylbenzene Chemical compound C=1C=CC=CC=1C(C)(C)OOC(C)(C)C1=CC=CC=C1 XMNIXWIUMCBBBL-UHFFFAOYSA-N 0.000 description 3
- DKGAVHZHDRPRBM-UHFFFAOYSA-N Tert-Butanol Chemical compound CC(C)(C)O DKGAVHZHDRPRBM-UHFFFAOYSA-N 0.000 description 3
- XTXRWKRVRITETP-UHFFFAOYSA-N Vinyl acetate Chemical compound CC(=O)OC=C XTXRWKRVRITETP-UHFFFAOYSA-N 0.000 description 3
- 238000004132 cross linking Methods 0.000 description 3
- 238000000354 decomposition reaction Methods 0.000 description 3
- 238000009795 derivation Methods 0.000 description 3
- 239000000155 melt Substances 0.000 description 3
- 230000002028 premature Effects 0.000 description 3
- 238000012545 processing Methods 0.000 description 3
- QQONPFPTGQHPMA-UHFFFAOYSA-N propylene Natural products CC=C QQONPFPTGQHPMA-UHFFFAOYSA-N 0.000 description 3
- 125000004805 propylene group Chemical group [H]C([H])([H])C([H])([*:1])C([H])([H])[*:2] 0.000 description 3
- HXIQYSLFEXIOAV-UHFFFAOYSA-N 2-tert-butyl-4-(5-tert-butyl-4-hydroxy-2-methylphenyl)sulfanyl-5-methylphenol Chemical compound CC1=CC(O)=C(C(C)(C)C)C=C1SC1=CC(C(C)(C)C)=C(O)C=C1C HXIQYSLFEXIOAV-UHFFFAOYSA-N 0.000 description 2
- KAKZBPTYRLMSJV-UHFFFAOYSA-N Butadiene Chemical compound C=CC=C KAKZBPTYRLMSJV-UHFFFAOYSA-N 0.000 description 2
- VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical compound [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 description 2
- JIGUQPWFLRLWPJ-UHFFFAOYSA-N Ethyl acrylate Chemical compound CCOC(=O)C=C JIGUQPWFLRLWPJ-UHFFFAOYSA-N 0.000 description 2
- RRHGJUQNOFWUDK-UHFFFAOYSA-N Isoprene Chemical compound CC(=C)C=C RRHGJUQNOFWUDK-UHFFFAOYSA-N 0.000 description 2
- BLRPTPMANUNPDV-UHFFFAOYSA-N Silane Chemical compound [SiH4] BLRPTPMANUNPDV-UHFFFAOYSA-N 0.000 description 2
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 description 2
- 239000000654 additive Substances 0.000 description 2
- 238000004364 calculation method Methods 0.000 description 2
- 229910052799 carbon Inorganic materials 0.000 description 2
- 239000004927 clay Substances 0.000 description 2
- 238000011156 evaluation Methods 0.000 description 2
- 238000002474 experimental method Methods 0.000 description 2
- 239000000945 filler Substances 0.000 description 2
- 239000011872 intimate mixture Substances 0.000 description 2
- VNWKTOKETHGBQD-UHFFFAOYSA-N methane Chemical compound C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 description 2
- 238000002156 mixing Methods 0.000 description 2
- PNJWIWWMYCMZRO-UHFFFAOYSA-N pent‐4‐en‐2‐one Natural products CC(=O)CC=C PNJWIWWMYCMZRO-UHFFFAOYSA-N 0.000 description 2
- 239000000843 powder Substances 0.000 description 2
- 230000002265 prevention Effects 0.000 description 2
- 229910000077 silane Inorganic materials 0.000 description 2
- UJXFNIQSAHCTTA-UHFFFAOYSA-N 1-butylperoxyhexane Chemical compound CCCCCCOOCCCC UJXFNIQSAHCTTA-UHFFFAOYSA-N 0.000 description 1
- KAJRUHJCBCZULP-UHFFFAOYSA-N 1-cyclohepta-1,3-dien-1-ylcyclohepta-1,3-diene Chemical compound C1CCC=CC=C1C1=CC=CCCC1 KAJRUHJCBCZULP-UHFFFAOYSA-N 0.000 description 1
- JGBAASVQPMTVHO-UHFFFAOYSA-N 2,5-dihydroperoxy-2,5-dimethylhexane Chemical compound OOC(C)(C)CCC(C)(C)OO JGBAASVQPMTVHO-UHFFFAOYSA-N 0.000 description 1
- 125000003143 4-hydroxybenzyl group Chemical group [H]C([*])([H])C1=C([H])C([H])=C(O[H])C([H])=C1[H] 0.000 description 1
- 229910018072 Al 2 O 3 Inorganic materials 0.000 description 1
- 239000004604 Blowing Agent Substances 0.000 description 1
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 1
- 239000004743 Polypropylene Substances 0.000 description 1
- XBDQKXXYIPTUBI-UHFFFAOYSA-M Propionate Chemical compound CCC([O-])=O XBDQKXXYIPTUBI-UHFFFAOYSA-M 0.000 description 1
- UCKMPCXJQFINFW-UHFFFAOYSA-N Sulphide Chemical compound [S-2] UCKMPCXJQFINFW-UHFFFAOYSA-N 0.000 description 1
- 239000012963 UV stabilizer Substances 0.000 description 1
- 238000013459 approach Methods 0.000 description 1
- 229910000019 calcium carbonate Inorganic materials 0.000 description 1
- 150000001721 carbon Chemical group 0.000 description 1
- 230000015556 catabolic process Effects 0.000 description 1
- 238000006243 chemical reaction Methods 0.000 description 1
- 229910052570 clay Inorganic materials 0.000 description 1
- 239000003086 colorant Substances 0.000 description 1
- 238000010835 comparative analysis Methods 0.000 description 1
- 230000000052 comparative effect Effects 0.000 description 1
- 229940125782 compound 2 Drugs 0.000 description 1
- 238000007906 compression Methods 0.000 description 1
- 230000006835 compression Effects 0.000 description 1
- 230000003750 conditioning effect Effects 0.000 description 1
- OSPDFFCOJRYDNX-UHFFFAOYSA-N cumene;hydrogen peroxide;2-hydroperoxy-2-methylpropane Chemical compound OO.CC(C)(C)OO.CC(C)C1=CC=CC=C1 OSPDFFCOJRYDNX-UHFFFAOYSA-N 0.000 description 1
- 230000003247 decreasing effect Effects 0.000 description 1
- 230000007547 defect Effects 0.000 description 1
- 238000009826 distribution Methods 0.000 description 1
- 239000000975 dye Substances 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 229920001038 ethylene copolymer Polymers 0.000 description 1
- 235000012438 extruded product Nutrition 0.000 description 1
- 238000009472 formulation Methods 0.000 description 1
- 239000007863 gel particle Substances 0.000 description 1
- 238000000227 grinding Methods 0.000 description 1
- 150000002430 hydrocarbons Chemical class 0.000 description 1
- 239000004615 ingredient Substances 0.000 description 1
- 238000004898 kneading Methods 0.000 description 1
- 239000000314 lubricant Substances 0.000 description 1
- 239000006078 metal deactivator Substances 0.000 description 1
- 150000002826 nitrites Chemical class 0.000 description 1
- 238000010606 normalization Methods 0.000 description 1
- 230000010355 oscillation Effects 0.000 description 1
- 125000004430 oxygen atom Chemical group O* 0.000 description 1
- 239000002245 particle Substances 0.000 description 1
- YWAKXRMUMFPDSH-UHFFFAOYSA-N pentene Chemical compound CCCC=C YWAKXRMUMFPDSH-UHFFFAOYSA-N 0.000 description 1
- 125000002081 peroxide group Chemical group 0.000 description 1
- 150000002989 phenols Chemical class 0.000 description 1
- 229920001155 polypropylene Polymers 0.000 description 1
- 239000004800 polyvinyl chloride Substances 0.000 description 1
- 229920000915 polyvinyl chloride Polymers 0.000 description 1
- 238000005096 rolling process Methods 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
- 239000011343 solid material Substances 0.000 description 1
- 239000002904 solvent Substances 0.000 description 1
- 239000003381 stabilizer Substances 0.000 description 1
- 239000000758 substrate Substances 0.000 description 1
- 239000000454 talc Substances 0.000 description 1
- 229910052623 talc Inorganic materials 0.000 description 1
- 125000000999 tert-butyl group Chemical group [H]C([H])([H])C(*)(C([H])([H])[H])C([H])([H])[H] 0.000 description 1
- 229920001169 thermoplastic Polymers 0.000 description 1
- 239000004416 thermosoftening plastic Substances 0.000 description 1
- 238000012546 transfer Methods 0.000 description 1
- 125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/04—Oxygen-containing compounds
- C08K5/14—Peroxides
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Organic Insulating Materials (AREA)
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US52785374A | 1974-11-27 | 1974-11-27 |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| DE2553145A1 DE2553145A1 (de) | 1976-08-12 |
| DE2553145B2 true DE2553145B2 (de) | 1979-05-03 |
Family
ID=24103196
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| DE2553145A Ceased DE2553145B2 (de) | 1974-11-27 | 1975-11-26 | Verkohlungsbeständige, vulkanisierbare Masse |
Country Status (12)
| Country | Link |
|---|---|
| JP (1) | JPS5177645A (ref) |
| AU (1) | AU508622B2 (ref) |
| BE (1) | BE835963A (ref) |
| BR (1) | BR7507822A (ref) |
| CA (1) | CA1047200A (ref) |
| DE (1) | DE2553145B2 (ref) |
| FR (1) | FR2292737A1 (ref) |
| GB (2) | GB1535040A (ref) |
| IN (1) | IN144417B (ref) |
| IT (1) | IT1049872B (ref) |
| NL (1) | NL7513797A (ref) |
| SE (1) | SE413902B (ref) |
Families Citing this family (11)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4692497A (en) * | 1984-09-04 | 1987-09-08 | Acushnet Company | Process for curing a polymer and product thereof |
| US4546980A (en) * | 1984-09-04 | 1985-10-15 | Acushnet Company | Process for making a solid golf ball |
| ITMI960029U1 (it) * | 1996-01-18 | 1997-07-18 | Atochem Elf Italia | Composizioni perossidiche con resistenza allo scorch |
| IT1305320B1 (it) | 1998-04-21 | 2001-05-04 | Atochem Elf Italia | Composizioni perossidiche con migliorata resistenza allo scorch perla reticolazione di elastomeri e poliolefine |
| IT1305321B1 (it) * | 1998-04-21 | 2001-05-04 | Atochem Elf Italia | Composizioni perossidiche con migliorata resistenza allo scorch per lareticolazione di elastomeri e poliolefine |
| IT1305324B1 (it) * | 1998-04-21 | 2001-05-04 | Atochem Elf Italia | Composizioni perossidiche con migliorata resistenza allo scorch per lareticolazione di elastomeri e poliolefine. |
| IT1304174B1 (it) | 1998-12-17 | 2001-03-08 | Atochem Elf Italia | Composizioni perossidiche |
| JP5407877B2 (ja) * | 2010-01-08 | 2014-02-05 | 日油株式会社 | エチレン−酢酸ビニル共重合体組成物及び架橋物 |
| WO2013181784A1 (zh) | 2012-06-04 | 2013-12-12 | 北京低碳清洁能源研究所 | 一种加工性能改善的交联聚乙烯组合物 |
| CN104411763A (zh) | 2012-06-13 | 2015-03-11 | 北京低碳清洁能源研究所 | 一种交联聚乙烯组合物 |
| WO2016149898A1 (en) * | 2015-03-23 | 2016-09-29 | Arkema (Changshu) Fluorochemical Co., Ltd. | CURABLE COMPOSITION COMPRISING AN ETHYLENE POLYMER, A MONOPEROXYCARBONATE AND A t-ALKYL HYDROPEROXIDE |
Family Cites Families (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| NL225045A (ref) * | 1957-04-29 | |||
| GB1092225A (en) * | 1965-11-10 | 1967-11-22 | Standard Telephones Cables Ltd | Improvements in or relating to the extrusion of chemically crossed linked polymer or copolymers |
| NL6816346A (ref) * | 1967-11-18 | 1969-05-20 | ||
| US3661877A (en) * | 1970-05-21 | 1972-05-09 | Reichhold Chemicals Inc | Polymeric compositions and method of preparation |
| JPS4931304B1 (ref) * | 1970-06-20 | 1974-08-20 |
-
1975
- 1975-11-03 CA CA239,199A patent/CA1047200A/en not_active Expired
- 1975-11-26 IT IT29673/75A patent/IT1049872B/it active
- 1975-11-26 NL NL7513797A patent/NL7513797A/xx not_active Application Discontinuation
- 1975-11-26 AU AU86951/75A patent/AU508622B2/en not_active Ceased
- 1975-11-26 BE BE162191A patent/BE835963A/xx not_active IP Right Cessation
- 1975-11-26 IN IN2257/CAL/75A patent/IN144417B/en unknown
- 1975-11-26 DE DE2553145A patent/DE2553145B2/de not_active Ceased
- 1975-11-26 GB GB48656/75A patent/GB1535040A/en not_active Expired
- 1975-11-26 FR FR7536197A patent/FR2292737A1/fr active Granted
- 1975-11-26 BR BR7507822*A patent/BR7507822A/pt unknown
- 1975-11-26 SE SE7513323A patent/SE413902B/xx not_active IP Right Cessation
- 1975-11-26 JP JP50140868A patent/JPS5177645A/ja active Pending
- 1975-11-26 GB GB28079/78A patent/GB1536972A/en not_active Expired
Also Published As
| Publication number | Publication date |
|---|---|
| NL7513797A (nl) | 1976-05-31 |
| BR7507822A (pt) | 1976-08-10 |
| DE2553145A1 (de) | 1976-08-12 |
| IT1049872B (it) | 1981-02-10 |
| CA1047200A (en) | 1979-01-23 |
| GB1535040A (en) | 1978-12-06 |
| AU508622B2 (en) | 1980-03-27 |
| AU8695175A (en) | 1977-06-02 |
| GB1536972A (en) | 1978-12-29 |
| FR2292737B1 (ref) | 1980-01-25 |
| IN144417B (ref) | 1978-05-06 |
| JPS5177645A (ref) | 1976-07-06 |
| BE835963A (fr) | 1976-05-26 |
| SE7513323L (sv) | 1976-05-28 |
| SE413902B (sv) | 1980-06-30 |
| FR2292737A1 (fr) | 1976-06-25 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| 8227 | New person/name/address of the applicant |
Free format text: UNION CARBIDE CORP., 06817 DANBURY, CONN., US |
|
| 8235 | Patent refused |