DE2536488C2 - Verfahren zur herstellung ungesaettigter kohlenwasserstoffe - Google Patents
Verfahren zur herstellung ungesaettigter kohlenwasserstoffeInfo
- Publication number
- DE2536488C2 DE2536488C2 DE19752536488 DE2536488A DE2536488C2 DE 2536488 C2 DE2536488 C2 DE 2536488C2 DE 19752536488 DE19752536488 DE 19752536488 DE 2536488 A DE2536488 A DE 2536488A DE 2536488 C2 DE2536488 C2 DE 2536488C2
- Authority
- DE
- Germany
- Prior art keywords
- catalysts
- weight
- parts
- iron
- titanium
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 238000000034 method Methods 0.000 title claims description 14
- 238000004519 manufacturing process Methods 0.000 title claims description 6
- 229930195733 hydrocarbon Natural products 0.000 title description 8
- 150000002430 hydrocarbons Chemical class 0.000 title description 8
- 239000003054 catalyst Substances 0.000 claims description 39
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 claims description 24
- 238000006243 chemical reaction Methods 0.000 claims description 20
- 229910052739 hydrogen Inorganic materials 0.000 claims description 14
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 claims description 13
- 239000001257 hydrogen Substances 0.000 claims description 13
- 229910002090 carbon oxide Inorganic materials 0.000 claims description 12
- 229910052742 iron Inorganic materials 0.000 claims description 11
- 150000001336 alkenes Chemical class 0.000 claims description 10
- UGFAIRIUMAVXCW-UHFFFAOYSA-N Carbon monoxide Chemical class [O+]#[C-] UGFAIRIUMAVXCW-UHFFFAOYSA-N 0.000 claims description 9
- 229910017052 cobalt Inorganic materials 0.000 claims description 8
- 239000010941 cobalt Substances 0.000 claims description 8
- GUTLYIVDDKVIGB-UHFFFAOYSA-N cobalt atom Chemical compound [Co] GUTLYIVDDKVIGB-UHFFFAOYSA-N 0.000 claims description 8
- 239000010936 titanium Substances 0.000 claims description 8
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 claims description 7
- 230000000737 periodic effect Effects 0.000 claims description 7
- 229910052719 titanium Inorganic materials 0.000 claims description 7
- ZSLUVFAKFWKJRC-IGMARMGPSA-N 232Th Chemical compound [232Th] ZSLUVFAKFWKJRC-IGMARMGPSA-N 0.000 claims description 4
- 229910052776 Thorium Inorganic materials 0.000 claims description 4
- 229910052723 transition metal Inorganic materials 0.000 claims description 4
- 150000003624 transition metals Chemical class 0.000 claims description 4
- 239000000969 carrier Substances 0.000 claims description 3
- 239000012190 activator Substances 0.000 claims description 2
- 238000009903 catalytic hydrogenation reaction Methods 0.000 claims description 2
- 229930195735 unsaturated hydrocarbon Natural products 0.000 claims description 2
- 239000000463 material Substances 0.000 claims 1
- 230000015572 biosynthetic process Effects 0.000 description 11
- 239000000203 mixture Substances 0.000 description 9
- CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 description 8
- XLOMVQKBTHCTTD-UHFFFAOYSA-N Zinc monoxide Chemical compound [Zn]=O XLOMVQKBTHCTTD-UHFFFAOYSA-N 0.000 description 8
- 238000003786 synthesis reaction Methods 0.000 description 8
- 239000007789 gas Substances 0.000 description 7
- 238000005984 hydrogenation reaction Methods 0.000 description 6
- VNWKTOKETHGBQD-UHFFFAOYSA-N methane Chemical compound C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 description 6
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 4
- 239000011787 zinc oxide Substances 0.000 description 4
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 description 3
- 229910002091 carbon monoxide Inorganic materials 0.000 description 3
- -1 for example Chemical class 0.000 description 3
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 2
- UQSXHKLRYXJYBZ-UHFFFAOYSA-N Iron oxide Chemical compound [Fe]=O UQSXHKLRYXJYBZ-UHFFFAOYSA-N 0.000 description 2
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 description 2
- KJTLSVCANCCWHF-UHFFFAOYSA-N Ruthenium Chemical compound [Ru] KJTLSVCANCCWHF-UHFFFAOYSA-N 0.000 description 2
- 229910052799 carbon Inorganic materials 0.000 description 2
- 239000007795 chemical reaction product Substances 0.000 description 2
- 229910052751 metal Inorganic materials 0.000 description 2
- 239000002184 metal Substances 0.000 description 2
- 150000002739 metals Chemical class 0.000 description 2
- BASFCYQUMIYNBI-UHFFFAOYSA-N platinum Chemical compound [Pt] BASFCYQUMIYNBI-UHFFFAOYSA-N 0.000 description 2
- BWHMMNNQKKPAPP-UHFFFAOYSA-L potassium carbonate Chemical compound [K+].[K+].[O-]C([O-])=O BWHMMNNQKKPAPP-UHFFFAOYSA-L 0.000 description 2
- 238000001556 precipitation Methods 0.000 description 2
- 239000000047 product Substances 0.000 description 2
- 229910052707 ruthenium Inorganic materials 0.000 description 2
- 238000005245 sintering Methods 0.000 description 2
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 description 1
- 239000005977 Ethylene Substances 0.000 description 1
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 1
- 239000003513 alkali Substances 0.000 description 1
- 229910052782 aluminium Inorganic materials 0.000 description 1
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 1
- 239000007864 aqueous solution Substances 0.000 description 1
- 125000004432 carbon atom Chemical group C* 0.000 description 1
- 229910002092 carbon dioxide Inorganic materials 0.000 description 1
- 239000001569 carbon dioxide Substances 0.000 description 1
- 150000004649 carbonic acid derivatives Chemical class 0.000 description 1
- 239000012876 carrier material Substances 0.000 description 1
- 239000003153 chemical reaction reagent Substances 0.000 description 1
- 238000004140 cleaning Methods 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 239000000470 constituent Substances 0.000 description 1
- 230000009849 deactivation Effects 0.000 description 1
- 230000008021 deposition Effects 0.000 description 1
- 238000005474 detonation Methods 0.000 description 1
- 239000000446 fuel Substances 0.000 description 1
- 150000004677 hydrates Chemical class 0.000 description 1
- 239000004615 ingredient Substances 0.000 description 1
- HCWCAKKEBCNQJP-UHFFFAOYSA-N magnesium orthosilicate Chemical compound [Mg+2].[Mg+2].[O-][Si]([O-])([O-])[O-] HCWCAKKEBCNQJP-UHFFFAOYSA-N 0.000 description 1
- 239000000395 magnesium oxide Substances 0.000 description 1
- CPLXHLVBOLITMK-UHFFFAOYSA-N magnesium oxide Inorganic materials [Mg]=O CPLXHLVBOLITMK-UHFFFAOYSA-N 0.000 description 1
- 239000000391 magnesium silicate Substances 0.000 description 1
- 229910052919 magnesium silicate Inorganic materials 0.000 description 1
- 235000019792 magnesium silicate Nutrition 0.000 description 1
- AXZKOIWUVFPNLO-UHFFFAOYSA-N magnesium;oxygen(2-) Chemical compound [O-2].[Mg+2] AXZKOIWUVFPNLO-UHFFFAOYSA-N 0.000 description 1
- QSHDDOUJBYECFT-UHFFFAOYSA-N mercury Chemical compound [Hg] QSHDDOUJBYECFT-UHFFFAOYSA-N 0.000 description 1
- 229910052753 mercury Inorganic materials 0.000 description 1
- VUZPPFZMUPKLLV-UHFFFAOYSA-N methane;hydrate Chemical compound C.O VUZPPFZMUPKLLV-UHFFFAOYSA-N 0.000 description 1
- 238000002156 mixing Methods 0.000 description 1
- 229910052759 nickel Inorganic materials 0.000 description 1
- TWNQGVIAIRXVLR-UHFFFAOYSA-N oxo(oxoalumanyloxy)alumane Chemical compound O=[Al]O[Al]=O TWNQGVIAIRXVLR-UHFFFAOYSA-N 0.000 description 1
- 229910052697 platinum Inorganic materials 0.000 description 1
- 229910000027 potassium carbonate Inorganic materials 0.000 description 1
- 239000008262 pumice Substances 0.000 description 1
- 229920006395 saturated elastomer Polymers 0.000 description 1
- 150000004760 silicates Chemical class 0.000 description 1
- RMAQACBXLXPBSY-UHFFFAOYSA-N silicic acid Chemical compound O[Si](O)(O)O RMAQACBXLXPBSY-UHFFFAOYSA-N 0.000 description 1
- 235000012239 silicon dioxide Nutrition 0.000 description 1
- 239000004575 stone Substances 0.000 description 1
- OGIDPMRJRNCKJF-UHFFFAOYSA-N titanium oxide Inorganic materials [Ti]=O OGIDPMRJRNCKJF-UHFFFAOYSA-N 0.000 description 1
- 239000004711 α-olefin Substances 0.000 description 1
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
- B01J23/76—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
- B01J23/80—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with zinc, cadmium or mercury
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
- B01J23/74—Iron group metals
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C1/00—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon
- C07C1/02—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon from oxides of a carbon
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C2521/00—Catalysts comprising the elements, oxides or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium or hafnium
- C07C2521/06—Silicon, titanium, zirconium or hafnium; Oxides or hydroxides thereof
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C2523/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00
- C07C2523/12—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of actinides
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C2523/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00
- C07C2523/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of the iron group metals or copper
- C07C2523/74—Iron group metals
- C07C2523/745—Iron
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C2523/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00
- C07C2523/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of the iron group metals or copper
- C07C2523/74—Iron group metals
- C07C2523/75—Cobalt
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C2523/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00
- C07C2523/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of the iron group metals or copper
- C07C2523/76—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups C07C2523/02 - C07C2523/36
- C07C2523/78—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups C07C2523/02 - C07C2523/36 with alkali- or alkaline earth metals or beryllium
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C2523/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00
- C07C2523/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of the iron group metals or copper
- C07C2523/76—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups C07C2523/02 - C07C2523/36
- C07C2523/80—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups C07C2523/02 - C07C2523/36 with zinc, cadmium or mercury
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C2523/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00
- C07C2523/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of the iron group metals or copper
- C07C2523/76—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups C07C2523/02 - C07C2523/36
- C07C2523/83—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups C07C2523/02 - C07C2523/36 with rare earths or actinides
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Materials Engineering (AREA)
- General Chemical & Material Sciences (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
- Catalysts (AREA)
Priority Applications (10)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DE19752536488 DE2536488C2 (de) | 1975-08-16 | 1975-08-16 | Verfahren zur herstellung ungesaettigter kohlenwasserstoffe |
| NL7510634.A NL163761C (nl) | 1975-08-16 | 1975-09-09 | Werkwijze voor de bereiding van gasvormige alkenen uit koolmonoxyde en waterstof. |
| CA258,718A CA1053266A (en) | 1975-08-16 | 1976-08-09 | Process for the manufacture of unsaturated hydrocarbons |
| BE169683A BE845033A (fr) | 1975-08-16 | 1976-08-09 | Procede de preparation d'hydrocarbures insatures |
| GB33125/76A GB1512743A (en) | 1975-08-16 | 1976-08-09 | Process for the manufacture of unsaturated hydrocarbons |
| AU16675/76A AU505520B2 (en) | 1975-08-16 | 1976-08-09 | Unsaturated hydrocarbons |
| FR7624297A FR2321465A1 (fr) | 1975-08-16 | 1976-08-09 | Procede de preparation d'hydrocarbures insatures |
| ZA764763A ZA764763B (en) | 1975-08-16 | 1976-08-09 | Process for the manufacture of unsaturated hydrocarbons |
| JP51097653A JPS5223005A (en) | 1975-08-16 | 1976-08-16 | Process for preparing unsaturated hydrocarbon |
| US06/321,086 US4564642A (en) | 1975-08-16 | 1981-11-13 | Process for the manufacture of unsaturated hydrocarbons |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DE19752536488 DE2536488C2 (de) | 1975-08-16 | 1975-08-16 | Verfahren zur herstellung ungesaettigter kohlenwasserstoffe |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| DE2536488B1 DE2536488B1 (de) | 1976-12-30 |
| DE2536488C2 true DE2536488C2 (de) | 1977-08-25 |
Family
ID=5954098
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| DE19752536488 Expired DE2536488C2 (de) | 1975-08-16 | 1975-08-16 | Verfahren zur herstellung ungesaettigter kohlenwasserstoffe |
Country Status (10)
| Country | Link |
|---|---|
| US (1) | US4564642A (enExample) |
| JP (1) | JPS5223005A (enExample) |
| AU (1) | AU505520B2 (enExample) |
| BE (1) | BE845033A (enExample) |
| CA (1) | CA1053266A (enExample) |
| DE (1) | DE2536488C2 (enExample) |
| FR (1) | FR2321465A1 (enExample) |
| GB (1) | GB1512743A (enExample) |
| NL (1) | NL163761C (enExample) |
| ZA (1) | ZA764763B (enExample) |
Families Citing this family (18)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE3130988A1 (de) * | 1981-08-05 | 1983-02-24 | Schering Ag, 1000 Berlin Und 4619 Bergkamen | Katalysator und verfahren zur herstellung von olefinen - insbesondere linearen (alpha)-olefinen - aus synthesegas |
| US4613624A (en) * | 1981-10-13 | 1986-09-23 | Chevron Research Company | Conversion of synthesis gas to diesel fuel and catalyst therefor |
| GB2119277B (en) * | 1982-05-03 | 1985-11-20 | Air Prod & Chem | Olefin synthesis catalysts |
| CA1220776A (en) * | 1983-07-07 | 1987-04-21 | Rocco A. Fiato | Iron on titania catalyst and its use for hydrocarbon synthesis |
| JPS6097050A (ja) * | 1983-07-07 | 1985-05-30 | エクソン リサ−チ アンド エンヂニアリング コムパニ− | チタニア上担持鉄触媒および炭化水素合成のためのその使用 |
| GB2169614A (en) * | 1984-12-31 | 1986-07-16 | Mobil Oil Corp | Producing alpha-olefins and their conversion into lubricants |
| US4717702A (en) * | 1985-04-26 | 1988-01-05 | Shell Internationale Research Maatschappij Bv | Catalyst for conversion of synthesis gas to diesel fuel and process for preparation of such catalyst |
| US4657885A (en) * | 1985-07-11 | 1987-04-14 | Exxon Research And Engineering Company | Cerium promoted Fischer-Tropsch catalysts |
| US4639431A (en) * | 1985-07-11 | 1987-01-27 | Exxon Research And Engineering Company | Catalysts in Fischer-Tropsch process for producing olefins |
| JP2621860B2 (ja) * | 1986-08-25 | 1997-06-18 | 株式会社東芝 | タービンのヘルパ駆動装置 |
| US5109027A (en) * | 1989-06-13 | 1992-04-28 | Amoco Corporation | Catalytic process for producing olefins or higher alcohols from synthesis gas |
| CN1293027C (zh) * | 2002-10-08 | 2007-01-03 | 碳氢技术公司 | 一种使用骨架铁催化剂由合成气制备烃产物的浆态相工艺过程 |
| CN101318132B (zh) * | 2007-06-08 | 2010-09-01 | 中山大学 | 一种负载型纳米铁氧化物/硅藻土复催化剂的制备方法 |
| KR100904297B1 (ko) * | 2007-10-26 | 2009-06-25 | 한국화학연구원 | 연속적인 2단계 촉매 반응을 이용한 합성가스로부터 경질올레핀의 제조방법 |
| EP2314557A1 (en) | 2009-10-23 | 2011-04-27 | Netherlands Organisation for Scientific Research (Advanced Chemical Technologies for Sustainability) | Production of lower olefins from synthesis gas |
| EP2694457B1 (en) * | 2011-04-04 | 2019-06-19 | Dow Global Technologies LLC | Improved fischer-tropsch process for converting synthesis gas to a lower olefin |
| CN104918698B (zh) | 2013-07-18 | 2016-10-12 | 中国石油大学(北京) | 一种铁基加氢催化剂及其应用 |
| US9737192B2 (en) * | 2014-01-28 | 2017-08-22 | Haier Us Appliance Solutions, Inc. | Door latch interruption upon detection of current leakage |
Family Cites Families (13)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US2271259A (en) * | 1937-01-20 | 1942-01-27 | American Lurgi Corp | Process for synthesizing hydrocarbons |
| US2231990A (en) * | 1937-08-05 | 1941-02-18 | Dreyfus Henry | Manufacture of hydrocarbons |
| US2318602A (en) * | 1938-06-02 | 1943-05-11 | Standard Catalytic Co | Synthesis of hydrocarbons |
| US2279052A (en) * | 1938-06-07 | 1942-04-07 | Standard Catalytie Company | Production of hydrocarbons |
| US2289731A (en) * | 1938-11-07 | 1942-07-14 | Hydrocarbon Synthesis Corp | Method for the reativation of catalysts for the hydrogenation of carbon oxide |
| US2455419A (en) * | 1944-10-11 | 1948-12-07 | Standard Oil Co | Synthesis of hydrocarbons and regeneration of synthesis catalyst |
| US2615911A (en) * | 1947-03-21 | 1952-10-28 | Kellogg M W Co | Synthesis of organic compounds |
| US2666077A (en) * | 1948-01-31 | 1954-01-12 | Kellogg M W Co | Process for hydrogenation of carbon monoxide |
| US2700676A (en) * | 1949-04-22 | 1955-01-25 | Kellogg M W Co | Synthesis of organic compounds |
| DE922883C (de) * | 1949-10-04 | 1955-01-27 | Basf Ag | Verfahren zur Herstellung ungesaettigter, insbesondere gasfoermiger Kohlenwasserstoffe |
| US2960518A (en) * | 1957-09-27 | 1960-11-15 | Peters Kurt | Ethylene production process |
| GB833976A (en) * | 1957-09-27 | 1960-05-04 | Kurt Peters | Improvements in or relating to the production of ethylene |
| US4151190A (en) * | 1976-05-21 | 1979-04-24 | The Dow Chemical Company | Process for producing C2 -C4 hydrocarbons from carbon monoxide and hydrogen |
-
1975
- 1975-08-16 DE DE19752536488 patent/DE2536488C2/de not_active Expired
- 1975-09-09 NL NL7510634.A patent/NL163761C/xx not_active IP Right Cessation
-
1976
- 1976-08-09 BE BE169683A patent/BE845033A/xx not_active IP Right Cessation
- 1976-08-09 ZA ZA764763A patent/ZA764763B/xx unknown
- 1976-08-09 FR FR7624297A patent/FR2321465A1/fr active Granted
- 1976-08-09 AU AU16675/76A patent/AU505520B2/en not_active Expired
- 1976-08-09 CA CA258,718A patent/CA1053266A/en not_active Expired
- 1976-08-09 GB GB33125/76A patent/GB1512743A/en not_active Expired
- 1976-08-16 JP JP51097653A patent/JPS5223005A/ja active Granted
-
1981
- 1981-11-13 US US06/321,086 patent/US4564642A/en not_active Expired - Fee Related
Also Published As
| Publication number | Publication date |
|---|---|
| FR2321465B1 (enExample) | 1979-09-28 |
| CA1053266A (en) | 1979-04-24 |
| FR2321465A1 (fr) | 1977-03-18 |
| BE845033A (fr) | 1977-02-09 |
| JPS5223005A (en) | 1977-02-21 |
| GB1512743A (en) | 1978-06-01 |
| US4564642A (en) | 1986-01-14 |
| AU505520B2 (en) | 1979-11-22 |
| AU1667576A (en) | 1978-02-16 |
| NL163761B (nl) | 1980-05-16 |
| JPS5443482B2 (enExample) | 1979-12-20 |
| ZA764763B (en) | 1977-07-27 |
| NL163761C (nl) | 1980-10-15 |
| NL7510634A (nl) | 1977-02-18 |
| DE2536488B1 (de) | 1976-12-30 |
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