GB833976A - Improvements in or relating to the production of ethylene - Google Patents

Improvements in or relating to the production of ethylene

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Publication number
GB833976A
GB833976A GB30195/58A GB3019558A GB833976A GB 833976 A GB833976 A GB 833976A GB 30195/58 A GB30195/58 A GB 30195/58A GB 3019558 A GB3019558 A GB 3019558A GB 833976 A GB833976 A GB 833976A
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United Kingdom
Prior art keywords
oxide
catalyst
activated
kieselguhr
oxides
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Expired
Application number
GB30195/58A
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Original Assignee
Individual
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Publication of GB833976A publication Critical patent/GB833976A/en
Expired legal-status Critical Current

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    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/90—Regeneration or reactivation
    • B01J23/94—Regeneration or reactivation of catalysts comprising metals, oxides or hydroxides of the iron group metals or copper
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/76—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/84—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/89—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with noble metals
    • B01J23/8933—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with noble metals also combined with metals, or metal oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C1/00—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon
    • C07C1/02—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon from oxides of a carbon
    • C07C1/04—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon from oxides of a carbon from carbon monoxide with hydrogen
    • C07C1/0425—Catalysts; their physical properties
    • C07C1/043—Catalysts; their physical properties characterised by the composition
    • C07C1/0435—Catalysts; their physical properties characterised by the composition containing a metal of group 8 or a compound thereof
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2521/00—Catalysts comprising the elements, oxides or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium or hafnium
    • C07C2521/02—Boron or aluminium; Oxides or hydroxides thereof
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2521/00—Catalysts comprising the elements, oxides or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium or hafnium
    • C07C2521/06—Silicon, titanium, zirconium or hafnium; Oxides or hydroxides thereof
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2521/00—Catalysts comprising the elements, oxides or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium or hafnium
    • C07C2521/10—Magnesium; Oxides or hydroxides thereof
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2523/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00
    • C07C2523/02—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of the alkali- or alkaline earth metals or beryllium
    • C07C2523/04—Alkali metals
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2523/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00
    • C07C2523/06—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of zinc, cadmium or mercury
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2523/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00
    • C07C2523/10—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of rare earths
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2523/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00
    • C07C2523/12—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of actinides
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2523/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00
    • C07C2523/16—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • C07C2523/20—Vanadium, niobium or tantalum
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2523/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00
    • C07C2523/16—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • C07C2523/20—Vanadium, niobium or tantalum
    • C07C2523/22—Vanadium
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2523/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00
    • C07C2523/16—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • C07C2523/24—Chromium, molybdenum or tungsten
    • C07C2523/26—Chromium
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2523/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00
    • C07C2523/16—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • C07C2523/24—Chromium, molybdenum or tungsten
    • C07C2523/28—Molybdenum
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2523/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00
    • C07C2523/16—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • C07C2523/24—Chromium, molybdenum or tungsten
    • C07C2523/30—Tungsten
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2523/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00
    • C07C2523/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of noble metals
    • C07C2523/48—Silver or gold
    • C07C2523/50—Silver
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2523/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00
    • C07C2523/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of the iron group metals or copper
    • C07C2523/72—Copper
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2527/00—Catalysts comprising the elements or compounds of halogens, sulfur, selenium, tellurium, phosphorus or nitrogen; Catalysts comprising carbon compounds
    • C07C2527/20—Carbon compounds
    • C07C2527/232—Carbonates
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00—Technologies relating to chemical industry
    • Y02P20/50—Improvements relating to the production of bulk chemicals
    • Y02P20/52—Improvements relating to the production of bulk chemicals using catalysts, e.g. selective catalysts
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00—Technologies relating to chemical industry
    • Y02P20/50—Improvements relating to the production of bulk chemicals
    • Y02P20/582—Recycling of unreacted starting or intermediate materials
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00—Technologies relating to chemical industry
    • Y02P20/50—Improvements relating to the production of bulk chemicals
    • Y02P20/584—Recycling of catalysts

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • General Chemical & Material Sciences (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Catalysts (AREA)

Abstract

By means of a catalyst, carbon monoxide and hydrogen are converted to a gaseous hydrocarbon mixture, predominantly ethylene, at normal or superatmospheric pressure (e.g. atmos.) and 350-520 DEG C., preferably 350-450 DEG C., with a preferred contact time of below 5 seconds; the fluidized bed method may be used. The catalyst is a mixture of four components, each of which may contain one or more of the specified ingredients: (1) (a) ZnO, CdO, Cu or Ag, with (b) an oxide of Cr, V, Nb, Ta, Mo, W or U; (2) a Group VIII metal or compound thereof; (3) an oxide or hydroxide of Al, Si, Ti, Zr, Hf, Th, Sc, Y, or of a rare earth element; (4) a carbonate, oxide or hydroxide of an alkali metal. Component (1) may be activated with an oxide of one or more of Mg, Zr, Hf, Th and the rare earth elements, while component (2) (which preferably constitutes not more than 10%, particularly 0.1-1% of the total catalyst weight) may be activated with one or more of Cu or Ag or oxides of Mg, Th, Mn, or the rare earths. The catalyst is preferably supported on an inert carrier of large surface area, particularly kieselguhr, pumice, ceramic material, a synthetic or natural silicate, fuller's earth or lignite ash. Alternatively the first or third components may serve as the carrier. Constituents specified in examples are oxides of Al, Cr, Mn, Zn and K; Cu, Ag and Co; and kieselguhr. Prior to use the catalyst may be reduced with hydrogen, optionally after having been activated by heating in air. Regeneration may be effected by heating in air, which may contain added nitrogen, followed by reduction.ALSO:By means of a catalyst, carbon monoxide and hydrogen are converted to a gaseous hydrocarbon mixture, predominantly ethylene, at normal or superatmospheric pressure (e.g. 20 atm.) and 350-520 DEG C., preferably 350-450 DEG C., with a preferred contact time of below 5 seconds; the fluidized bed method may be used. The catalyst is a mixture of four components, each of which may contain one or more of the specified ingredients: (1) (a) ZnO, CdO, Cu or Ag, with (b) an oxide of Cr, V, Nb, Ta, Mo, W or U; (2) a Group VIII metal or compound thereof; (3) an oxide or hydroxide of Al, Si, Ti, Zr, Hf, Th, Sc, Y, or of a rare earth element; (4) a carbonate, oxide or hydroxide of an alkali metal. Component (1) may be activated with an oxide of one or more of Mg, Zr, Hf, Th and the rare earth elements, while component (2) (which preferably constitutes not more than 10%, particularly 0.1-1% of the total catalyst weight) may be activated with one or more of Cu or Ag or oxides of Mg, Th, Mn, or the rare earths. The catalyst is preferably supported on an inert carrier of large surface area, particularly kieselguhr, pumice, ceramic material, a synthetic or natural silicate, fuller's earth or lignite ash. Alternatively, the first or third components may serve as the carrier. Constituents specified in examples are oxides of Al, Cr, Mn, Zn and K; Cu, Ag and Co; and kieselguhr.
GB30195/58A 1957-09-27 1958-09-22 Improvements in or relating to the production of ethylene Expired GB833976A (en)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
AT833976X 1957-09-27

Publications (1)

Publication Number Publication Date
GB833976A true GB833976A (en) 1960-05-04

Family

ID=3681886

Family Applications (1)

Application Number Title Priority Date Filing Date
GB30195/58A Expired GB833976A (en) 1957-09-27 1958-09-22 Improvements in or relating to the production of ethylene

Country Status (1)

Country Link
GB (1) GB833976A (en)

Cited By (13)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR2321465A1 (en) * 1975-08-16 1977-03-18 Ruhrchemie Ag PROCESS FOR THE PREPARATION OF UNSATURATED HYDROCARBONS
EP0016851A1 (en) * 1978-09-20 1980-10-15 The Dow Chemical Company Process for producing olefins from carbon monoxide and hydrogen
FR2543945A2 (en) * 1982-03-26 1984-10-12 Inst Francais Du Petrole Process for the manufacture of a mixture of methanol and higher alcohols from synthesis gas
US4593015A (en) * 1978-05-15 1986-06-03 The Standard Oil Company Catalyst for the preparation of alcohols from synthesis gas
US4609678A (en) * 1978-05-15 1986-09-02 The Standard Oil Company Preparation of alcohols from synthesis gas
US4639431A (en) * 1985-07-11 1987-01-27 Exxon Research And Engineering Company Catalysts in Fischer-Tropsch process for producing olefins
US4657885A (en) * 1985-07-11 1987-04-14 Exxon Research And Engineering Company Cerium promoted Fischer-Tropsch catalysts
US4665238A (en) * 1985-01-22 1987-05-12 Uop Inc. Process for the synthesis of alkylaromatic compounds
US4668656A (en) * 1978-05-15 1987-05-26 The Standard Oil Company Catalyst for the preparation of alcohols from synthesis gas
CN102290261A (en) * 2011-05-27 2011-12-21 浙江乐银合金有限公司 Silver copper based metal oxide electrical contact material containing adding elements and preparation method thereof
EP2422876A1 (en) * 2010-08-20 2012-02-29 Shell Internationale Research Maatschappij B.V. Process for preparing olefins from synthesis gas using a cobalt and manganese containing catalyst
US9827555B2 (en) 2013-07-31 2017-11-28 Saudi Basic Industries Corporation Catalyst for conversion of synthesis gas
CN109701626A (en) * 2017-10-26 2019-05-03 中国石油化工股份有限公司 For one-step method from syngas producing light olefins catalyst, preparation and application thereof

Cited By (16)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR2321465A1 (en) * 1975-08-16 1977-03-18 Ruhrchemie Ag PROCESS FOR THE PREPARATION OF UNSATURATED HYDROCARBONS
US4668656A (en) * 1978-05-15 1987-05-26 The Standard Oil Company Catalyst for the preparation of alcohols from synthesis gas
US4593015A (en) * 1978-05-15 1986-06-03 The Standard Oil Company Catalyst for the preparation of alcohols from synthesis gas
US4609678A (en) * 1978-05-15 1986-09-02 The Standard Oil Company Preparation of alcohols from synthesis gas
EP0016851A1 (en) * 1978-09-20 1980-10-15 The Dow Chemical Company Process for producing olefins from carbon monoxide and hydrogen
FR2543945A2 (en) * 1982-03-26 1984-10-12 Inst Francais Du Petrole Process for the manufacture of a mixture of methanol and higher alcohols from synthesis gas
US4665238A (en) * 1985-01-22 1987-05-12 Uop Inc. Process for the synthesis of alkylaromatic compounds
DE3636900A1 (en) * 1985-07-11 1988-05-11 Exxon Research Engineering Co CATALYST FOR THE HYDROCARBON SYNTHESIS, METHOD FOR THE PRODUCTION THEREOF AND THE SYNTHESIS METHOD OF HYDROCARBONS
US4657885A (en) * 1985-07-11 1987-04-14 Exxon Research And Engineering Company Cerium promoted Fischer-Tropsch catalysts
US4639431A (en) * 1985-07-11 1987-01-27 Exxon Research And Engineering Company Catalysts in Fischer-Tropsch process for producing olefins
EP2422876A1 (en) * 2010-08-20 2012-02-29 Shell Internationale Research Maatschappij B.V. Process for preparing olefins from synthesis gas using a cobalt and manganese containing catalyst
CN102290261A (en) * 2011-05-27 2011-12-21 浙江乐银合金有限公司 Silver copper based metal oxide electrical contact material containing adding elements and preparation method thereof
CN102290261B (en) * 2011-05-27 2014-04-09 张树堂 Silver copper based metal oxide electrical contact material containing adding elements and preparation method thereof
US9827555B2 (en) 2013-07-31 2017-11-28 Saudi Basic Industries Corporation Catalyst for conversion of synthesis gas
CN109701626A (en) * 2017-10-26 2019-05-03 中国石油化工股份有限公司 For one-step method from syngas producing light olefins catalyst, preparation and application thereof
CN109701626B (en) * 2017-10-26 2021-10-01 中国石油化工股份有限公司 Catalyst for preparing low-carbon olefin by synthesis gas one-step method, preparation and application thereof

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