DE2508084A1 - Verfahren zur herstellung von agglomeraten von wismuthaltigen kristallinen teilchen aus basischem kupfercarbonat - Google Patents
Verfahren zur herstellung von agglomeraten von wismuthaltigen kristallinen teilchen aus basischem kupfercarbonatInfo
- Publication number
- DE2508084A1 DE2508084A1 DE19752508084 DE2508084A DE2508084A1 DE 2508084 A1 DE2508084 A1 DE 2508084A1 DE 19752508084 DE19752508084 DE 19752508084 DE 2508084 A DE2508084 A DE 2508084A DE 2508084 A1 DE2508084 A1 DE 2508084A1
- Authority
- DE
- Germany
- Prior art keywords
- copper
- bismuth
- carbonate
- range
- agglomerates
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 229910052797 bismuth Inorganic materials 0.000 title claims description 62
- JCXGWMGPZLAOME-UHFFFAOYSA-N bismuth atom Chemical compound [Bi] JCXGWMGPZLAOME-UHFFFAOYSA-N 0.000 title claims description 62
- 238000000034 method Methods 0.000 title claims description 45
- 239000002245 particle Substances 0.000 title claims description 42
- GEZOTWYUIKXWOA-UHFFFAOYSA-L copper;carbonate Chemical compound [Cu+2].[O-]C([O-])=O GEZOTWYUIKXWOA-UHFFFAOYSA-L 0.000 title claims description 38
- 229940116318 copper carbonate Drugs 0.000 title claims description 37
- 238000004519 manufacturing process Methods 0.000 title claims description 23
- 230000008569 process Effects 0.000 title claims description 17
- 239000003054 catalyst Substances 0.000 claims description 65
- WSFSSNUMVMOOMR-UHFFFAOYSA-N Formaldehyde Chemical compound O=C WSFSSNUMVMOOMR-UHFFFAOYSA-N 0.000 claims description 35
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 claims description 30
- 239000010949 copper Substances 0.000 claims description 28
- 229910052802 copper Inorganic materials 0.000 claims description 26
- 125000002534 ethynyl group Chemical group [H]C#C* 0.000 claims description 22
- 238000010899 nucleation Methods 0.000 claims description 22
- 230000006911 nucleation Effects 0.000 claims description 22
- HSFWRNGVRCDJHI-UHFFFAOYSA-N alpha-acetylene Natural products C#C HSFWRNGVRCDJHI-UHFFFAOYSA-N 0.000 claims description 21
- 238000006243 chemical reaction Methods 0.000 claims description 16
- 239000013078 crystal Substances 0.000 claims description 16
- 238000001556 precipitation Methods 0.000 claims description 12
- 239000011541 reaction mixture Substances 0.000 claims description 12
- CDBYLPFSWZWCQE-UHFFFAOYSA-L Sodium Carbonate Chemical group [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 claims description 11
- SQDLRJMJSRRYGA-UHFFFAOYSA-N copper(i) acetylide Chemical compound [Cu+].[Cu+].[C-]#[C-] SQDLRJMJSRRYGA-UHFFFAOYSA-N 0.000 claims description 10
- BVKZGUZCCUSVTD-UHFFFAOYSA-M Bicarbonate Chemical compound OC([O-])=O BVKZGUZCCUSVTD-UHFFFAOYSA-M 0.000 claims description 9
- JPVYNHNXODAKFH-UHFFFAOYSA-N Cu2+ Chemical class [Cu+2] JPVYNHNXODAKFH-UHFFFAOYSA-N 0.000 claims description 9
- BVKZGUZCCUSVTD-UHFFFAOYSA-L Carbonate Chemical compound [O-]C([O-])=O BVKZGUZCCUSVTD-UHFFFAOYSA-L 0.000 claims description 8
- 229910052799 carbon Inorganic materials 0.000 claims description 7
- XTVVROIMIGLXTD-UHFFFAOYSA-N copper(II) nitrate Chemical group [Cu+2].[O-][N+]([O-])=O.[O-][N+]([O-])=O XTVVROIMIGLXTD-UHFFFAOYSA-N 0.000 claims description 7
- 239000002244 precipitate Substances 0.000 claims description 7
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 7
- 150000001621 bismuth Chemical class 0.000 claims description 6
- 238000002360 preparation method Methods 0.000 claims description 6
- 229910000029 sodium carbonate Inorganic materials 0.000 claims description 6
- 239000003513 alkali Substances 0.000 claims description 5
- 125000004435 hydrogen atom Chemical class [H]* 0.000 claims description 5
- 239000012736 aqueous medium Substances 0.000 claims description 4
- 150000001721 carbon Chemical group 0.000 claims description 4
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims description 3
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 claims description 3
- 239000001257 hydrogen Substances 0.000 claims description 3
- 229910052739 hydrogen Inorganic materials 0.000 claims description 3
- 239000002609 medium Substances 0.000 claims description 3
- 239000000203 mixture Substances 0.000 claims description 3
- 229910052760 oxygen Inorganic materials 0.000 claims description 3
- 239000001301 oxygen Substances 0.000 claims description 3
- 239000002002 slurry Substances 0.000 claims description 3
- UIIMBOGNXHQVGW-UHFFFAOYSA-M sodium bicarbonate Substances [Na+].OC([O-])=O UIIMBOGNXHQVGW-UHFFFAOYSA-M 0.000 claims description 3
- 235000017557 sodium bicarbonate Nutrition 0.000 claims description 3
- 125000004432 carbon atom Chemical group C* 0.000 claims description 2
- VWWMOACCGFHMEV-UHFFFAOYSA-N dicarbide(2-) Chemical compound [C-]#[C-] VWWMOACCGFHMEV-UHFFFAOYSA-N 0.000 claims description 2
- RXPAJWPEYBDXOG-UHFFFAOYSA-N hydron;methyl 4-methoxypyridine-2-carboxylate;chloride Chemical compound Cl.COC(=O)C1=CC(OC)=CC=N1 RXPAJWPEYBDXOG-UHFFFAOYSA-N 0.000 claims description 2
- 125000004430 oxygen atom Chemical group O* 0.000 claims description 2
- 229910000030 sodium bicarbonate Inorganic materials 0.000 claims description 2
- 229910000288 alkali metal carbonate Inorganic materials 0.000 claims 1
- 150000008041 alkali metal carbonates Chemical class 0.000 claims 1
- 229910000009 copper(II) carbonate Inorganic materials 0.000 claims 1
- 235000019854 cupric carbonate Nutrition 0.000 claims 1
- 239000011646 cupric carbonate Substances 0.000 claims 1
- 241000907663 Siproeta stelenes Species 0.000 description 38
- 230000015572 biosynthetic process Effects 0.000 description 17
- 239000000243 solution Substances 0.000 description 11
- CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 description 8
- 239000000047 product Substances 0.000 description 7
- 238000009826 distribution Methods 0.000 description 6
- 239000000376 reactant Substances 0.000 description 6
- 244000052616 bacterial pathogen Species 0.000 description 5
- 238000012360 testing method Methods 0.000 description 5
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 4
- 239000001569 carbon dioxide Substances 0.000 description 4
- 229910002092 carbon dioxide Inorganic materials 0.000 description 4
- 150000001879 copper Chemical class 0.000 description 4
- 230000000694 effects Effects 0.000 description 4
- 238000001914 filtration Methods 0.000 description 4
- 239000011521 glass Substances 0.000 description 4
- 229910000014 Bismuth subcarbonate Inorganic materials 0.000 description 3
- 239000007795 chemical reaction product Substances 0.000 description 3
- FWIZHMQARNODNX-UHFFFAOYSA-L dibismuth;oxygen(2-);carbonate Chemical compound [O-2].[O-2].[Bi+3].[Bi+3].[O-]C([O-])=O FWIZHMQARNODNX-UHFFFAOYSA-L 0.000 description 3
- 239000003112 inhibitor Substances 0.000 description 3
- FVAUCKIRQBBSSJ-UHFFFAOYSA-M sodium iodide Chemical compound [Na+].[I-] FVAUCKIRQBBSSJ-UHFFFAOYSA-M 0.000 description 3
- 230000009466 transformation Effects 0.000 description 3
- VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical compound [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 description 2
- KBZSNAZVDVIXKL-UHFFFAOYSA-L bismuth copper carbonate Chemical compound [Cu+2].[Bi+3].[O-]C([O-])=O KBZSNAZVDVIXKL-UHFFFAOYSA-L 0.000 description 2
- 229910000416 bismuth oxide Inorganic materials 0.000 description 2
- 150000004649 carbonic acid derivatives Chemical class 0.000 description 2
- 230000003197 catalytic effect Effects 0.000 description 2
- 238000000975 co-precipitation Methods 0.000 description 2
- 238000002425 crystallisation Methods 0.000 description 2
- 230000008025 crystallization Effects 0.000 description 2
- TYIXMATWDRGMPF-UHFFFAOYSA-N dibismuth;oxygen(2-) Chemical compound [O-2].[O-2].[O-2].[Bi+3].[Bi+3] TYIXMATWDRGMPF-UHFFFAOYSA-N 0.000 description 2
- 238000011156 evaluation Methods 0.000 description 2
- 230000002349 favourable effect Effects 0.000 description 2
- 239000008098 formaldehyde solution Substances 0.000 description 2
- 239000007789 gas Substances 0.000 description 2
- BDAGIHXWWSANSR-UHFFFAOYSA-N methanoic acid Natural products OC=O BDAGIHXWWSANSR-UHFFFAOYSA-N 0.000 description 2
- 230000003472 neutralizing effect Effects 0.000 description 2
- 229910052757 nitrogen Inorganic materials 0.000 description 2
- BWHMMNNQKKPAPP-UHFFFAOYSA-L potassium carbonate Chemical compound [K+].[K+].[O-]C([O-])=O BWHMMNNQKKPAPP-UHFFFAOYSA-L 0.000 description 2
- 239000012266 salt solution Substances 0.000 description 2
- 238000003756 stirring Methods 0.000 description 2
- 239000000126 substance Substances 0.000 description 2
- 238000009827 uniform distribution Methods 0.000 description 2
- 238000005406 washing Methods 0.000 description 2
- OSWFIVFLDKOXQC-UHFFFAOYSA-N 4-(3-methoxyphenyl)aniline Chemical compound COC1=CC=CC(C=2C=CC(N)=CC=2)=C1 OSWFIVFLDKOXQC-UHFFFAOYSA-N 0.000 description 1
- QPLDLSVMHZLSFG-UHFFFAOYSA-N Copper oxide Chemical compound [Cu]=O QPLDLSVMHZLSFG-UHFFFAOYSA-N 0.000 description 1
- 239000005751 Copper oxide Substances 0.000 description 1
- VMQMZMRVKUZKQL-UHFFFAOYSA-N Cu+ Chemical compound [Cu+] VMQMZMRVKUZKQL-UHFFFAOYSA-N 0.000 description 1
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 1
- NPKGQBIUYHHPOT-UHFFFAOYSA-N [Cu+2].[C-]#[C-] Chemical compound [Cu+2].[C-]#[C-] NPKGQBIUYHHPOT-UHFFFAOYSA-N 0.000 description 1
- 238000010521 absorption reaction Methods 0.000 description 1
- 239000007864 aqueous solution Substances 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 229940036358 bismuth subcarbonate Drugs 0.000 description 1
- 238000009395 breeding Methods 0.000 description 1
- 230000001488 breeding effect Effects 0.000 description 1
- 229910000019 calcium carbonate Inorganic materials 0.000 description 1
- 238000006555 catalytic reaction Methods 0.000 description 1
- 230000008859 change Effects 0.000 description 1
- 229910000431 copper oxide Inorganic materials 0.000 description 1
- ORTQZVOHEJQUHG-UHFFFAOYSA-L copper(II) chloride Chemical compound Cl[Cu]Cl ORTQZVOHEJQUHG-UHFFFAOYSA-L 0.000 description 1
- 230000007423 decrease Effects 0.000 description 1
- 230000006735 deficit Effects 0.000 description 1
- 230000008021 deposition Effects 0.000 description 1
- 230000006866 deterioration Effects 0.000 description 1
- 238000010586 diagram Methods 0.000 description 1
- 239000006185 dispersion Substances 0.000 description 1
- 238000001035 drying Methods 0.000 description 1
- 239000000428 dust Substances 0.000 description 1
- 230000008030 elimination Effects 0.000 description 1
- 238000003379 elimination reaction Methods 0.000 description 1
- 238000002474 experimental method Methods 0.000 description 1
- 239000010419 fine particle Substances 0.000 description 1
- 235000019253 formic acid Nutrition 0.000 description 1
- 238000004817 gas chromatography Methods 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- 230000000887 hydrating effect Effects 0.000 description 1
- 230000006872 improvement Effects 0.000 description 1
- 230000001788 irregular Effects 0.000 description 1
- 230000007774 longterm Effects 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 230000005012 migration Effects 0.000 description 1
- 238000013508 migration Methods 0.000 description 1
- 230000003278 mimic effect Effects 0.000 description 1
- 238000006386 neutralization reaction Methods 0.000 description 1
- 238000006116 polymerization reaction Methods 0.000 description 1
- 235000015497 potassium bicarbonate Nutrition 0.000 description 1
- 229910000027 potassium carbonate Inorganic materials 0.000 description 1
- 235000011181 potassium carbonates Nutrition 0.000 description 1
- 239000012429 reaction media Substances 0.000 description 1
- 239000000523 sample Substances 0.000 description 1
- 229920006395 saturated elastomer Polymers 0.000 description 1
- 235000015424 sodium Nutrition 0.000 description 1
- 235000009518 sodium iodide Nutrition 0.000 description 1
- 239000003351 stiffener Substances 0.000 description 1
- 238000013517 stratification Methods 0.000 description 1
- 230000001502 supplementing effect Effects 0.000 description 1
- 238000003786 synthesis reaction Methods 0.000 description 1
- 238000012546 transfer Methods 0.000 description 1
- 230000007704 transition Effects 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F9/00—Compounds containing elements of Groups 5 or 15 of the Periodic Table
- C07F9/94—Bismuth compounds
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J27/00—Catalysts comprising the elements or compounds of halogens, sulfur, selenium, tellurium, phosphorus or nitrogen; Catalysts comprising carbon compounds
- B01J27/20—Carbon compounds
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
- B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
- B01J31/22—Organic complexes
- B01J31/2282—Unsaturated compounds used as ligands
- B01J31/2286—Alkynes, e.g. acetylides
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01G—COMPOUNDS CONTAINING METALS NOT COVERED BY SUBCLASSES C01D OR C01F
- C01G3/00—Compounds of copper
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C33/00—Unsaturated compounds having hydroxy or O-metal groups bound to acyclic carbon atoms
- C07C33/04—Acyclic alcohols with carbon-to-carbon triple bonds
- C07C33/042—Acyclic alcohols with carbon-to-carbon triple bonds with only one triple bond
- C07C33/044—Alkynediols
- C07C33/046—Butynediols
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F1/00—Compounds containing elements of Groups 1 or 11 of the Periodic Table
- C07F1/08—Copper compounds
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Inorganic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Catalysts (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
- Inorganic Compounds Of Heavy Metals (AREA)
Description
IC-6157 | min | -JA- | Nooh zuzusetzende |
- | Tabelle I | Lösung, | |
(Keimbildung) | Malachitherstellung | cm^ CuNO5 | |
150 | |||
125 | |||
Zeit, | r-iaip^ratur, C | 22 | |
O | 35 | -0- | |
10 | 70 | ||
72 | |||
35 | 75 | ||
Temperatur, | Malachitherstellung | PH | (Keimbildung) | |
Zeit, | 0C | Noch zuzusetzende | 6,5 | (bei Umwandlung aller Stoffe in Malachit pH-Änderung auf 7,5) |
min | 85 | Lösung, cm3 CuNO^ | 6,5 | |
O | 75 | 140 | 6,5 | |
15 | 75 | 125 | 7,4 | |
27 | 75 | 100 | 7,4 | |
35 | 75 | 50 | 6,7 | |
41 | 75 | 25 | ||
50 | -0- | |||
T34 'al
JjJ. , 7" |
Zeit, h | Katalyse mit | Wismut | |
Ver- ' such Nr. |
15 | 210 | Zeitausbeute, C2H2/Cu.h |
Cupren |
1 | 15 | 175 | 0,75 | keines |
2 | 10 | 207 | 0,63 > | keines |
3 | 8 | 85 | 0,6 | keines |
4 | 5 | 187 | 0,7 | keines |
5 | 3 | 205 | 0,7-0,6 | keines |
6 | 2 | 0,7 | keines | |
7 . | 1 | 105 | keines | |
8 | 1 | 102 | 0,5 | etwas |
9 | 0 | 90 | 0,65 | etwas |
10 | 5 | 100 | 0,5 | etwas |
11 | 0,5 | viel | ||
(Bi0)pC0-3 ohne gemeinsame Ausfällung zum Malachit zugesetzt
Claims (15)
pH-Wert von etwa 6,5 durchführt.
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US44547674A | 1974-02-25 | 1974-02-25 |
Publications (2)
Publication Number | Publication Date |
---|---|
DE2508084A1 true DE2508084A1 (de) | 1975-08-28 |
DE2508084C2 DE2508084C2 (de) | 1984-06-07 |
Family
ID=23769056
Family Applications (2)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
DE19752560545 Expired DE2560545C2 (de) | 1974-02-25 | 1975-02-25 | Wismuthaltige kristalline Teilchen aus basischem Kupfercarbonat (Malachit) und Verfahren zu ihrer Herstellung |
DE19752508084 Expired DE2508084C2 (de) | 1974-02-25 | 1975-02-25 | Wismuthaltige, teilchenförmige Kupfer(I)-acetylidkomplexe, Verfahren zu ihrer Herstellung und deren Verwendung |
Family Applications Before (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
DE19752560545 Expired DE2560545C2 (de) | 1974-02-25 | 1975-02-25 | Wismuthaltige kristalline Teilchen aus basischem Kupfercarbonat (Malachit) und Verfahren zu ihrer Herstellung |
Country Status (7)
Country | Link |
---|---|
JP (2) | JPS594380B2 (de) |
BE (1) | BE825446A (de) |
DE (2) | DE2560545C2 (de) |
FR (2) | FR2264034B1 (de) |
GB (2) | GB1501459A (de) |
IT (1) | IT1033129B (de) |
NL (1) | NL183087C (de) |
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE2735465A1 (de) * | 1976-08-05 | 1978-02-09 | Du Pont | Verfahren zur herstellung von mit wismut modifiziertem, sphaeroidischem malachit |
Families Citing this family (11)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
GB2039268B (en) | 1978-12-15 | 1983-01-19 | Exxon Research Engineering Co | Metal extraction by solid-liquid agglomerates |
DE3417629C1 (de) * | 1984-05-12 | 1985-01-24 | Th. Goldschmidt Ag, 4300 Essen | Verfahren zur Herstellung von basischem Kupfercarbonat |
JPS60252078A (ja) * | 1984-05-30 | 1985-12-12 | Mitsubishi Motors Corp | 車両のウインドガラス搬送位置決め装置 |
JPH0311107Y2 (de) * | 1986-02-21 | 1991-03-18 | ||
JPH0447026Y2 (de) * | 1986-03-10 | 1992-11-06 | ||
DE102005042185A1 (de) * | 2005-09-06 | 2007-03-08 | Basf Ag | Verfahren zur Abtrennung von polymeren Nebenprodukten aus 1,4-Butindiol |
WO2010041402A1 (ja) * | 2008-10-07 | 2010-04-15 | 日本曹達株式会社 | テトラフルオロ化合物の製造方法 |
CN111589836B (zh) * | 2019-09-16 | 2021-10-26 | 徐光耀 | 含乙炔化物的废料处理方法 |
CN111747439B (zh) * | 2020-07-13 | 2023-08-29 | 泰兴冶炼厂有限公司 | 一种超高纯碱式碳酸铜制备工艺 |
CN115703647A (zh) * | 2021-08-06 | 2023-02-17 | 阮氏化工(常熟)有限公司 | 利用酸性蚀刻废液连续化生产碱式碳酸铜的方法 |
CN114873653B (zh) * | 2022-05-11 | 2023-10-13 | 金驰能源材料有限公司 | 碱式碳酸钴及其制备方法 |
Citations (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US2300969A (en) * | 1939-09-07 | 1942-11-03 | Gen Aniline & Film Corp | Production of alkinols |
US3650985A (en) * | 1967-10-23 | 1972-03-21 | Du Pont | Ethynylation catalyst catalyst preparation and process |
-
1975
- 1975-02-12 BE BE153285A patent/BE825446A/xx not_active IP Right Cessation
- 1975-02-24 NL NL7502177A patent/NL183087C/xx not_active IP Right Cessation
- 1975-02-24 IT IT2058475A patent/IT1033129B/it active
- 1975-02-24 FR FR7505627A patent/FR2264034B1/fr not_active Expired
- 1975-02-25 DE DE19752560545 patent/DE2560545C2/de not_active Expired
- 1975-02-25 GB GB787775A patent/GB1501459A/en not_active Expired
- 1975-02-25 DE DE19752508084 patent/DE2508084C2/de not_active Expired
- 1975-02-25 JP JP2250175A patent/JPS594380B2/ja not_active Expired
- 1975-07-18 FR FR7522506A patent/FR2330647A1/fr active Granted
-
1978
- 1978-04-03 GB GB1296178A patent/GB1555297A/en not_active Expired
-
1983
- 1983-07-15 JP JP12805183A patent/JPS5931720A/ja active Granted
Patent Citations (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US2300969A (en) * | 1939-09-07 | 1942-11-03 | Gen Aniline & Film Corp | Production of alkinols |
US3650985A (en) * | 1967-10-23 | 1972-03-21 | Du Pont | Ethynylation catalyst catalyst preparation and process |
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE2735465A1 (de) * | 1976-08-05 | 1978-02-09 | Du Pont | Verfahren zur herstellung von mit wismut modifiziertem, sphaeroidischem malachit |
Also Published As
Publication number | Publication date |
---|---|
GB1501459A (en) | 1978-02-15 |
JPS50119797A (de) | 1975-09-19 |
FR2330647A1 (fr) | 1977-06-03 |
DE2508084C2 (de) | 1984-06-07 |
JPS6113691B2 (de) | 1986-04-15 |
JPS594380B2 (ja) | 1984-01-30 |
NL183087C (nl) | 1988-07-18 |
BE825446A (fr) | 1975-08-12 |
GB1555297A (en) | 1979-11-07 |
FR2330647B1 (de) | 1981-06-26 |
FR2264034A1 (de) | 1975-10-10 |
FR2264034B1 (de) | 1981-06-26 |
IT1033129B (it) | 1979-07-10 |
NL7502177A (nl) | 1975-08-27 |
NL183087B (nl) | 1988-02-16 |
DE2560545C2 (de) | 1986-05-07 |
JPS5931720A (ja) | 1984-02-20 |
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