DE2440269A1 - Verfahren zur herstellung von acrylnitril-vinylchlorid-copolymerisaten mit verbessertem weissgrad - Google Patents
Verfahren zur herstellung von acrylnitril-vinylchlorid-copolymerisaten mit verbessertem weissgradInfo
- Publication number
- DE2440269A1 DE2440269A1 DE19742440269 DE2440269A DE2440269A1 DE 2440269 A1 DE2440269 A1 DE 2440269A1 DE 19742440269 DE19742440269 DE 19742440269 DE 2440269 A DE2440269 A DE 2440269A DE 2440269 A1 DE2440269 A1 DE 2440269A1
- Authority
- DE
- Germany
- Prior art keywords
- parts
- polymerization
- vinyl chloride
- acrylonitrile
- test
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Withdrawn
Links
- 238000000034 method Methods 0.000 title claims description 23
- 230000008569 process Effects 0.000 title claims description 15
- 238000004519 manufacturing process Methods 0.000 title description 10
- GRFFKYTUNTWAGG-UHFFFAOYSA-N chloroethene;prop-2-enenitrile Chemical compound ClC=C.C=CC#N GRFFKYTUNTWAGG-UHFFFAOYSA-N 0.000 title description 2
- 238000006116 polymerization reaction Methods 0.000 claims description 51
- NLHHRLWOUZZQLW-UHFFFAOYSA-N Acrylonitrile Chemical compound C=CC#N NLHHRLWOUZZQLW-UHFFFAOYSA-N 0.000 claims description 30
- BZHJMEDXRYGGRV-UHFFFAOYSA-N Vinyl chloride Chemical compound ClC=C BZHJMEDXRYGGRV-UHFFFAOYSA-N 0.000 claims description 21
- 229920001577 copolymer Polymers 0.000 claims description 17
- 230000001590 oxidative effect Effects 0.000 claims description 14
- 150000001875 compounds Chemical class 0.000 claims description 12
- JRKICGRDRMAZLK-UHFFFAOYSA-L peroxydisulfate Chemical compound [O-]S(=O)(=O)OOS([O-])(=O)=O JRKICGRDRMAZLK-UHFFFAOYSA-L 0.000 claims description 10
- LSNNMFCWUKXFEE-UHFFFAOYSA-N Sulfurous acid Chemical compound OS(O)=O LSNNMFCWUKXFEE-UHFFFAOYSA-N 0.000 claims description 9
- 239000003054 catalyst Substances 0.000 claims description 6
- 238000007720 emulsion polymerization reaction Methods 0.000 claims description 5
- 229920000642 polymer Polymers 0.000 description 44
- 238000012360 testing method Methods 0.000 description 40
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 38
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 description 31
- 239000000243 solution Substances 0.000 description 31
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 25
- ZMXDDKWLCZADIW-UHFFFAOYSA-N N,N-Dimethylformamide Chemical compound CN(C)C=O ZMXDDKWLCZADIW-UHFFFAOYSA-N 0.000 description 24
- 239000008367 deionised water Substances 0.000 description 23
- 229910021641 deionized water Inorganic materials 0.000 description 23
- 229910052757 nitrogen Inorganic materials 0.000 description 19
- ROOXNKNUYICQNP-UHFFFAOYSA-N ammonium peroxydisulfate Substances [NH4+].[NH4+].[O-]S(=O)(=O)OOS([O-])(=O)=O ROOXNKNUYICQNP-UHFFFAOYSA-N 0.000 description 18
- VAZSKTXWXKYQJF-UHFFFAOYSA-N ammonium persulfate Chemical compound [NH4+].[NH4+].[O-]S(=O)OOS([O-])=O VAZSKTXWXKYQJF-UHFFFAOYSA-N 0.000 description 18
- 229910001870 ammonium persulfate Inorganic materials 0.000 description 18
- HRZFUMHJMZEROT-UHFFFAOYSA-L sodium disulfite Chemical compound [Na+].[Na+].[O-]S(=O)S([O-])(=O)=O HRZFUMHJMZEROT-UHFFFAOYSA-L 0.000 description 18
- 235000010262 sodium metabisulphite Nutrition 0.000 description 18
- 239000007787 solid Substances 0.000 description 15
- 229920000126 latex Polymers 0.000 description 14
- ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 description 13
- 239000000460 chlorine Substances 0.000 description 13
- 229910052801 chlorine Inorganic materials 0.000 description 13
- USHAGKDGDHPEEY-UHFFFAOYSA-L potassium persulfate Chemical compound [K+].[K+].[O-]S(=O)(=O)OOS([O-])(=O)=O USHAGKDGDHPEEY-UHFFFAOYSA-L 0.000 description 13
- 239000004816 latex Substances 0.000 description 12
- RAHZWNYVWXNFOC-UHFFFAOYSA-N Sulphur dioxide Chemical compound O=S=O RAHZWNYVWXNFOC-UHFFFAOYSA-N 0.000 description 10
- 239000000835 fiber Substances 0.000 description 9
- DBMJMQXJHONAFJ-UHFFFAOYSA-M Sodium laurylsulphate Chemical compound [Na+].CCCCCCCCCCCCOS([O-])(=O)=O DBMJMQXJHONAFJ-UHFFFAOYSA-M 0.000 description 7
- 230000000052 comparative effect Effects 0.000 description 7
- MQLVWQSVRZVNIP-UHFFFAOYSA-L ferrous ammonium sulfate hexahydrate Chemical compound [NH4+].[NH4+].O.O.O.O.O.O.[Fe+2].[O-]S([O-])(=O)=O.[O-]S([O-])(=O)=O MQLVWQSVRZVNIP-UHFFFAOYSA-L 0.000 description 7
- 238000005259 measurement Methods 0.000 description 7
- 235000019333 sodium laurylsulphate Nutrition 0.000 description 7
- 239000000843 powder Substances 0.000 description 6
- -1 pyrosulphite Chemical compound 0.000 description 5
- NBIIXXVUZAFLBC-UHFFFAOYSA-N Phosphoric acid Chemical compound OP(O)(O)=O NBIIXXVUZAFLBC-UHFFFAOYSA-N 0.000 description 4
- 239000007853 buffer solution Substances 0.000 description 4
- 230000015271 coagulation Effects 0.000 description 4
- 238000005345 coagulation Methods 0.000 description 4
- 238000002474 experimental method Methods 0.000 description 4
- 239000000178 monomer Substances 0.000 description 4
- 238000010626 work up procedure Methods 0.000 description 4
- QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical compound CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 description 3
- CSCPPACGZOOCGX-UHFFFAOYSA-N Acetone Chemical compound CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 description 3
- WEVYAHXRMPXWCK-UHFFFAOYSA-N Acetonitrile Chemical compound CC#N WEVYAHXRMPXWCK-UHFFFAOYSA-N 0.000 description 3
- GRYLNZFGIOXLOG-UHFFFAOYSA-N Nitric acid Chemical compound O[N+]([O-])=O GRYLNZFGIOXLOG-UHFFFAOYSA-N 0.000 description 3
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 3
- 239000002253 acid Substances 0.000 description 3
- 229910017604 nitric acid Inorganic materials 0.000 description 3
- IAZDPXIOMUYVGZ-UHFFFAOYSA-N Dimethylsulphoxide Chemical compound CS(C)=O IAZDPXIOMUYVGZ-UHFFFAOYSA-N 0.000 description 2
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 description 2
- MHAJPDPJQMAIIY-UHFFFAOYSA-N Hydrogen peroxide Chemical compound OO MHAJPDPJQMAIIY-UHFFFAOYSA-N 0.000 description 2
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 2
- BAPJBEWLBFYGME-UHFFFAOYSA-N Methyl acrylate Chemical compound COC(=O)C=C BAPJBEWLBFYGME-UHFFFAOYSA-N 0.000 description 2
- 229920002821 Modacrylic Polymers 0.000 description 2
- DWAQJAXMDSEUJJ-UHFFFAOYSA-M Sodium bisulfite Chemical compound [Na+].OS([O-])=O DWAQJAXMDSEUJJ-UHFFFAOYSA-M 0.000 description 2
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 description 2
- 230000004913 activation Effects 0.000 description 2
- 229910000147 aluminium phosphate Inorganic materials 0.000 description 2
- 150000008064 anhydrides Chemical class 0.000 description 2
- TZCXTZWJZNENPQ-UHFFFAOYSA-L barium sulfate Chemical compound [Ba+2].[O-]S([O-])(=O)=O TZCXTZWJZNENPQ-UHFFFAOYSA-L 0.000 description 2
- 230000015572 biosynthetic process Effects 0.000 description 2
- INLLPKCGLOXCIV-UHFFFAOYSA-N bromoethene Chemical compound BrC=C INLLPKCGLOXCIV-UHFFFAOYSA-N 0.000 description 2
- 125000004432 carbon atom Chemical group C* 0.000 description 2
- 238000007796 conventional method Methods 0.000 description 2
- 238000007334 copolymerization reaction Methods 0.000 description 2
- 239000004744 fabric Substances 0.000 description 2
- 238000010438 heat treatment Methods 0.000 description 2
- 239000000203 mixture Substances 0.000 description 2
- 239000011734 sodium Substances 0.000 description 2
- 229910052708 sodium Inorganic materials 0.000 description 2
- 235000010267 sodium hydrogen sulphite Nutrition 0.000 description 2
- SZHIIIPPJJXYRY-UHFFFAOYSA-M sodium;2-methylprop-2-ene-1-sulfonate Chemical compound [Na+].CC(=C)CS([O-])(=O)=O SZHIIIPPJJXYRY-UHFFFAOYSA-M 0.000 description 2
- LSNNMFCWUKXFEE-UHFFFAOYSA-L sulfite Chemical compound [O-]S([O-])=O LSNNMFCWUKXFEE-UHFFFAOYSA-L 0.000 description 2
- 229910052717 sulfur Inorganic materials 0.000 description 2
- 239000011593 sulfur Substances 0.000 description 2
- NWONKYPBYAMBJT-UHFFFAOYSA-L zinc sulfate Chemical compound [Zn+2].[O-]S([O-])(=O)=O NWONKYPBYAMBJT-UHFFFAOYSA-L 0.000 description 2
- 229960001763 zinc sulfate Drugs 0.000 description 2
- 229910000368 zinc sulfate Inorganic materials 0.000 description 2
- BZCOSCNPHJNQBP-UPHRSURJSA-N (z)-2,3-dihydroxybut-2-enedioic acid Chemical compound OC(=O)C(\O)=C(\O)C(O)=O BZCOSCNPHJNQBP-UPHRSURJSA-N 0.000 description 1
- RNFJDJUURJAICM-UHFFFAOYSA-N 2,2,4,4,6,6-hexaphenoxy-1,3,5-triaza-2$l^{5},4$l^{5},6$l^{5}-triphosphacyclohexa-1,3,5-triene Chemical compound N=1P(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP=1(OC=1C=CC=CC=1)OC1=CC=CC=C1 RNFJDJUURJAICM-UHFFFAOYSA-N 0.000 description 1
- OEPOKWHJYJXUGD-UHFFFAOYSA-N 2-(3-phenylmethoxyphenyl)-1,3-thiazole-4-carbaldehyde Chemical compound O=CC1=CSC(C=2C=C(OCC=3C=CC=CC=3)C=CC=2)=N1 OEPOKWHJYJXUGD-UHFFFAOYSA-N 0.000 description 1
- DMSRIHVZKOZKRV-UHFFFAOYSA-N 2-methyl-1-(2-methylprop-2-enoylamino)propane-1-sulfonic acid Chemical compound CC(C)C(S(O)(=O)=O)NC(=O)C(C)=C DMSRIHVZKOZKRV-UHFFFAOYSA-N 0.000 description 1
- AGBXYHCHUYARJY-UHFFFAOYSA-N 2-phenylethenesulfonic acid Chemical compound OS(=O)(=O)C=CC1=CC=CC=C1 AGBXYHCHUYARJY-UHFFFAOYSA-N 0.000 description 1
- RWSOTUBLDIXVET-UHFFFAOYSA-N Dihydrogen sulfide Chemical class S RWSOTUBLDIXVET-UHFFFAOYSA-N 0.000 description 1
- VVQNEPGJFQJSBK-UHFFFAOYSA-N Methyl methacrylate Chemical compound COC(=O)C(C)=C VVQNEPGJFQJSBK-UHFFFAOYSA-N 0.000 description 1
- ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 description 1
- ULUAUXLGCMPNKK-UHFFFAOYSA-N Sulfobutanedioic acid Chemical class OC(=O)CC(C(O)=O)S(O)(=O)=O ULUAUXLGCMPNKK-UHFFFAOYSA-N 0.000 description 1
- XTXRWKRVRITETP-UHFFFAOYSA-N Vinyl acetate Chemical compound CC(=O)OC=C XTXRWKRVRITETP-UHFFFAOYSA-N 0.000 description 1
- 150000007513 acids Chemical class 0.000 description 1
- NIXOWILDQLNWCW-UHFFFAOYSA-N acrylic acid group Chemical group C(C=C)(=O)O NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 description 1
- 239000012190 activator Substances 0.000 description 1
- 239000000654 additive Substances 0.000 description 1
- 239000003513 alkali Substances 0.000 description 1
- 150000001447 alkali salts Chemical class 0.000 description 1
- 150000008055 alkyl aryl sulfonates Chemical class 0.000 description 1
- 229940045714 alkyl sulfonate alkylating agent Drugs 0.000 description 1
- 150000008052 alkyl sulfonates Chemical class 0.000 description 1
- 150000001412 amines Chemical class 0.000 description 1
- 125000000129 anionic group Chemical group 0.000 description 1
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 230000008901 benefit Effects 0.000 description 1
- 230000005540 biological transmission Effects 0.000 description 1
- 238000005034 decoration Methods 0.000 description 1
- 235000019329 dioctyl sodium sulphosuccinate Nutrition 0.000 description 1
- YHAIUSTWZPMYGG-UHFFFAOYSA-L disodium;2,2-dioctyl-3-sulfobutanedioate Chemical compound [Na+].[Na+].CCCCCCCCC(C([O-])=O)(C(C([O-])=O)S(O)(=O)=O)CCCCCCCC YHAIUSTWZPMYGG-UHFFFAOYSA-L 0.000 description 1
- 238000000578 dry spinning Methods 0.000 description 1
- 239000003792 electrolyte Substances 0.000 description 1
- 230000008030 elimination Effects 0.000 description 1
- 238000003379 elimination reaction Methods 0.000 description 1
- 239000003995 emulsifying agent Substances 0.000 description 1
- 230000002349 favourable effect Effects 0.000 description 1
- 239000002657 fibrous material Substances 0.000 description 1
- 239000003063 flame retardant Substances 0.000 description 1
- 239000002930 fur substitute Substances 0.000 description 1
- 229910001385 heavy metal Inorganic materials 0.000 description 1
- 230000006698 induction Effects 0.000 description 1
- 239000003999 initiator Substances 0.000 description 1
- 150000008040 ionic compounds Chemical class 0.000 description 1
- 150000002500 ions Chemical class 0.000 description 1
- XEEYBQQBJWHFJM-UHFFFAOYSA-N iron Substances [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 1
- 229910052742 iron Inorganic materials 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 125000005395 methacrylic acid group Chemical group 0.000 description 1
- 150000007522 mineralic acids Chemical class 0.000 description 1
- 150000007524 organic acids Chemical class 0.000 description 1
- 229910052760 oxygen Inorganic materials 0.000 description 1
- 239000001301 oxygen Substances 0.000 description 1
- 150000002978 peroxides Chemical class 0.000 description 1
- 125000000864 peroxy group Chemical group O(O*)* 0.000 description 1
- 229920002239 polyacrylonitrile Polymers 0.000 description 1
- 229920002959 polymer blend Polymers 0.000 description 1
- 230000000379 polymerizing effect Effects 0.000 description 1
- 239000011591 potassium Substances 0.000 description 1
- 229910052939 potassium sulfate Inorganic materials 0.000 description 1
- 238000012673 precipitation polymerization Methods 0.000 description 1
- 230000009257 reactivity Effects 0.000 description 1
- 230000009467 reduction Effects 0.000 description 1
- 235000011121 sodium hydroxide Nutrition 0.000 description 1
- CHQMHPLRPQMAMX-UHFFFAOYSA-L sodium persulfate Substances [Na+].[Na+].[O-]S(=O)(=O)OOS([O-])(=O)=O CHQMHPLRPQMAMX-UHFFFAOYSA-L 0.000 description 1
- 239000002904 solvent Substances 0.000 description 1
- 238000009987 spinning Methods 0.000 description 1
- 239000003381 stabilizer Substances 0.000 description 1
- 230000002195 synergetic effect Effects 0.000 description 1
- 239000004753 textile Substances 0.000 description 1
- 229920001567 vinyl ester resin Polymers 0.000 description 1
- 125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 description 1
- 238000002166 wet spinning Methods 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F220/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride ester, amide, imide or nitrile thereof
- C08F220/02—Monocarboxylic acids having less than ten carbon atoms; Derivatives thereof
- C08F220/42—Nitriles
- C08F220/44—Acrylonitrile
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F214/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen
- C08F214/02—Monomers containing chlorine
- C08F214/04—Monomers containing two carbon atoms
- C08F214/06—Vinyl chloride
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
- Polymerization Catalysts (AREA)
- Polymerisation Methods In General (AREA)
Priority Applications (14)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DE19742440269 DE2440269A1 (de) | 1974-08-22 | 1974-08-22 | Verfahren zur herstellung von acrylnitril-vinylchlorid-copolymerisaten mit verbessertem weissgrad |
| AT644775A AT335732B (de) | 1974-08-22 | 1975-08-20 | Verfahren zur herstellung von acrylnitril-vinylchlorid-copolymerisaten mit verbessertem weissgrad |
| CA233,817A CA1043941A (en) | 1974-08-22 | 1975-08-20 | Process for the production of acrylonitrile-vinyl chloride copolymers with improved whiteness |
| DD18795575A DD121115A5 (enExample) | 1974-08-22 | 1975-08-20 | |
| IT2646875A IT1041952B (it) | 1974-08-22 | 1975-08-20 | Processo per la produzione di colpolimerizzati acrilonitrilovi nilclorurici con migliorato grado di bianchezza |
| GB3457475A GB1510714A (en) | 1974-08-22 | 1975-08-20 | Process for the production of acrylonitrile-vinyl chloride copolymers with whiteness |
| LU73226A LU73226A1 (enExample) | 1974-08-22 | 1975-08-20 | |
| BE159317A BE832573A (fr) | 1974-08-22 | 1975-08-20 | Procede de preparation de copolymeres acrylonitrilechlorure de vinyle presentant un degre de blanc ameliore |
| NL7509892A NL7509892A (nl) | 1974-08-22 | 1975-08-20 | Werkwijze voor de bereiding van copolymeren van acrylonitrile en vinylchloride met een grote wit- heidsgraad. |
| ES440369A ES440369A1 (es) | 1974-08-22 | 1975-08-21 | Procedimiento para preparar copolimeros de acrilonitrilo- cloruro de vinilo quimicamente unitarios. |
| JP10069775A JPS5147085A (ja) | 1974-08-22 | 1975-08-21 | Kairyosaretahakushokudoojusuru akurironitoriruuenkabinirukyojugotainoseizohoho |
| DK377875A DK135170C (da) | 1974-08-22 | 1975-08-21 | Fremgangsmade til fremstilling af kemisk ensartede acrylonitril-vinylchlorid-copolymerisater med forbedret hvidhedsgrad |
| IE183875A IE41515B1 (en) | 1974-08-22 | 1975-08-21 | Process for the production of acrylonitrile-yinyl chloride copolymers with improved whiteness |
| FR7526083A FR2282436A1 (fr) | 1974-08-22 | 1975-08-22 | Procede de preparation de copolymeres acrylonitrile-chlorure de vinyle presentant un degre de blanc ameliore |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DE19742440269 DE2440269A1 (de) | 1974-08-22 | 1974-08-22 | Verfahren zur herstellung von acrylnitril-vinylchlorid-copolymerisaten mit verbessertem weissgrad |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| DE2440269A1 true DE2440269A1 (de) | 1976-03-04 |
Family
ID=5923820
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| DE19742440269 Withdrawn DE2440269A1 (de) | 1974-08-22 | 1974-08-22 | Verfahren zur herstellung von acrylnitril-vinylchlorid-copolymerisaten mit verbessertem weissgrad |
Country Status (14)
| Country | Link |
|---|---|
| JP (1) | JPS5147085A (enExample) |
| AT (1) | AT335732B (enExample) |
| BE (1) | BE832573A (enExample) |
| CA (1) | CA1043941A (enExample) |
| DD (1) | DD121115A5 (enExample) |
| DE (1) | DE2440269A1 (enExample) |
| DK (1) | DK135170C (enExample) |
| ES (1) | ES440369A1 (enExample) |
| FR (1) | FR2282436A1 (enExample) |
| GB (1) | GB1510714A (enExample) |
| IE (1) | IE41515B1 (enExample) |
| IT (1) | IT1041952B (enExample) |
| LU (1) | LU73226A1 (enExample) |
| NL (1) | NL7509892A (enExample) |
Families Citing this family (9)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE2633592C2 (de) * | 1976-07-27 | 1982-06-03 | Bayer Ag, 5090 Leverkusen | Verfahren zur kontinuierlichen Herstellung von Acrylnitril-Vinylchlorid- Copolymerisaten |
| DE2702053A1 (de) * | 1977-01-19 | 1978-07-20 | Bayer Ag | Herstellung von copolymerisaten aus acrylnitril und vinylchlorid |
| JPS5472114U (enExample) * | 1977-10-31 | 1979-05-22 | ||
| JPS57196544U (enExample) * | 1981-06-08 | 1982-12-13 | ||
| JPS5831142U (ja) * | 1981-08-26 | 1983-03-01 | 沖電気工業株式会社 | ドツト印字ヘツド |
| JPS5892052U (ja) * | 1981-12-18 | 1983-06-22 | シチズン時計株式会社 | 印字ヘツド |
| LU84607A1 (fr) * | 1983-01-26 | 1984-10-24 | Oreal | Compositions alcooliques ou hydroalcooliques contenant des essences naturelles et du benzylidene camphre ou ses derives |
| DE3328276A1 (de) * | 1983-08-05 | 1985-02-21 | Hoechst Ag, 6230 Frankfurt | Polyacrylnitrile mit geringem k-wert, verfahren zu ihrer herstellung und geeignete verwendung |
| AU6236100A (en) * | 1999-08-12 | 2001-03-13 | Standard Oil Company, The | Melt processable multipolymers of acrylonitrile monomer, halogenated monomers and olefinically unsaturated monomers and the process to make them and products therefrom |
Family Cites Families (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE1918414A1 (de) * | 1969-04-11 | 1970-10-15 | Huels Chemische Werke Ag | Verfahren zur Herstellung von Mischpolymerisaten des Vinylchlorids |
| DE1915537A1 (de) * | 1969-03-26 | 1970-10-15 | Monsanto Co | Emulsions-Polymerisation von Vinyl-Chlorid |
-
1974
- 1974-08-22 DE DE19742440269 patent/DE2440269A1/de not_active Withdrawn
-
1975
- 1975-08-20 IT IT2646875A patent/IT1041952B/it active
- 1975-08-20 LU LU73226A patent/LU73226A1/xx unknown
- 1975-08-20 NL NL7509892A patent/NL7509892A/xx not_active Application Discontinuation
- 1975-08-20 GB GB3457475A patent/GB1510714A/en not_active Expired
- 1975-08-20 CA CA233,817A patent/CA1043941A/en not_active Expired
- 1975-08-20 BE BE159317A patent/BE832573A/xx unknown
- 1975-08-20 DD DD18795575A patent/DD121115A5/xx unknown
- 1975-08-20 AT AT644775A patent/AT335732B/de not_active IP Right Cessation
- 1975-08-21 IE IE183875A patent/IE41515B1/en unknown
- 1975-08-21 DK DK377875A patent/DK135170C/da active
- 1975-08-21 JP JP10069775A patent/JPS5147085A/ja active Granted
- 1975-08-21 ES ES440369A patent/ES440369A1/es not_active Expired
- 1975-08-22 FR FR7526083A patent/FR2282436A1/fr active Granted
Also Published As
| Publication number | Publication date |
|---|---|
| BE832573A (fr) | 1976-02-20 |
| JPS5723691B2 (enExample) | 1982-05-20 |
| IE41515L (en) | 1976-02-22 |
| IT1041952B (it) | 1980-01-10 |
| DD121115A5 (enExample) | 1976-07-12 |
| LU73226A1 (enExample) | 1976-05-31 |
| FR2282436B1 (enExample) | 1979-05-18 |
| DK377875A (da) | 1976-02-23 |
| DK135170B (da) | 1977-03-14 |
| DK135170C (da) | 1977-08-22 |
| GB1510714A (en) | 1978-05-17 |
| AT335732B (de) | 1977-03-25 |
| FR2282436A1 (fr) | 1976-03-19 |
| ES440369A1 (es) | 1977-03-01 |
| IE41515B1 (en) | 1980-01-16 |
| NL7509892A (nl) | 1976-02-24 |
| JPS5147085A (ja) | 1976-04-22 |
| CA1043941A (en) | 1978-12-05 |
| ATA644775A (de) | 1976-07-15 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| 8110 | Request for examination paragraph 44 | ||
| 8130 | Withdrawal |