DE2419490C3 - Verfahren zur Herstellung von Mangandioxid - Google Patents
Verfahren zur Herstellung von MangandioxidInfo
- Publication number
- DE2419490C3 DE2419490C3 DE2419490A DE2419490A DE2419490C3 DE 2419490 C3 DE2419490 C3 DE 2419490C3 DE 2419490 A DE2419490 A DE 2419490A DE 2419490 A DE2419490 A DE 2419490A DE 2419490 C3 DE2419490 C3 DE 2419490C3
- Authority
- DE
- Germany
- Prior art keywords
- manganese
- halogens
- treatment
- manganese dioxide
- acid
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- NUJOXMJBOLGQSY-UHFFFAOYSA-N manganese dioxide Chemical compound O=[Mn]=O NUJOXMJBOLGQSY-UHFFFAOYSA-N 0.000 title claims description 32
- 238000000034 method Methods 0.000 title claims description 14
- 238000004519 manufacturing process Methods 0.000 title claims description 8
- 230000008569 process Effects 0.000 title claims description 6
- VLTRZXGMWDSKGL-UHFFFAOYSA-N perchloric acid Chemical compound OCl(=O)(=O)=O VLTRZXGMWDSKGL-UHFFFAOYSA-N 0.000 claims description 16
- 150000004965 peroxy acids Chemical class 0.000 claims description 15
- CBENFWSGALASAD-UHFFFAOYSA-N Ozone Chemical compound [O-][O+]=O CBENFWSGALASAD-UHFFFAOYSA-N 0.000 claims description 11
- 238000007323 disproportionation reaction Methods 0.000 claims description 11
- 229910052736 halogen Inorganic materials 0.000 claims description 10
- 239000011572 manganese Substances 0.000 claims description 10
- 150000002367 halogens Chemical class 0.000 claims description 9
- AMWRITDGCCNYAT-UHFFFAOYSA-L manganese oxide Inorganic materials [Mn].O[Mn]=O.O[Mn]=O AMWRITDGCCNYAT-UHFFFAOYSA-L 0.000 claims description 9
- PPNAOCWZXJOHFK-UHFFFAOYSA-N manganese(2+);oxygen(2-) Chemical class [O-2].[Mn+2] PPNAOCWZXJOHFK-UHFFFAOYSA-N 0.000 claims description 9
- -1 ammonium ions Chemical class 0.000 claims description 6
- PWHULOQIROXLJO-UHFFFAOYSA-N Manganese Chemical compound [Mn] PWHULOQIROXLJO-UHFFFAOYSA-N 0.000 claims description 4
- 150000002500 ions Chemical class 0.000 claims description 4
- 229910052748 manganese Inorganic materials 0.000 claims description 4
- BHPQYMZQTOCNFJ-UHFFFAOYSA-N Calcium cation Chemical compound [Ca+2] BHPQYMZQTOCNFJ-UHFFFAOYSA-N 0.000 claims description 2
- ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 claims description 2
- 230000008901 benefit Effects 0.000 claims description 2
- 229910001424 calcium ion Inorganic materials 0.000 claims description 2
- 229910052700 potassium Inorganic materials 0.000 claims description 2
- 239000011591 potassium Substances 0.000 claims description 2
- 150000001768 cations Chemical class 0.000 claims 1
- KQFUCKFHODLIAZ-UHFFFAOYSA-N manganese Chemical compound [Mn].[Mn] KQFUCKFHODLIAZ-UHFFFAOYSA-N 0.000 claims 1
- 239000000243 solution Substances 0.000 description 8
- 230000003647 oxidation Effects 0.000 description 6
- 238000007254 oxidation reaction Methods 0.000 description 6
- 239000000047 product Substances 0.000 description 6
- 230000000694 effects Effects 0.000 description 5
- 229910052739 hydrogen Inorganic materials 0.000 description 5
- 239000001257 hydrogen Substances 0.000 description 5
- QVRFMRZEAVHYMX-UHFFFAOYSA-L manganese(2+);diperchlorate Chemical compound [Mn+2].[O-]Cl(=O)(=O)=O.[O-]Cl(=O)(=O)=O QVRFMRZEAVHYMX-UHFFFAOYSA-L 0.000 description 5
- 239000000126 substance Substances 0.000 description 5
- 239000002253 acid Substances 0.000 description 4
- 239000012266 salt solution Substances 0.000 description 4
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 3
- 238000006243 chemical reaction Methods 0.000 description 3
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 2
- 230000006872 improvement Effects 0.000 description 2
- 150000002696 manganese Chemical class 0.000 description 2
- 229910052751 metal Inorganic materials 0.000 description 2
- 239000002184 metal Substances 0.000 description 2
- 150000002739 metals Chemical class 0.000 description 2
- 239000007800 oxidant agent Substances 0.000 description 2
- 230000001590 oxidative effect Effects 0.000 description 2
- 239000007787 solid Substances 0.000 description 2
- 239000004575 stone Substances 0.000 description 2
- 230000007306 turnover Effects 0.000 description 2
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 1
- 229910003174 MnOOH Inorganic materials 0.000 description 1
- KVKRSMAXOZCCOG-UHFFFAOYSA-N O.[O-2].[Mn+4].[O-2] Chemical compound O.[O-2].[Mn+4].[O-2] KVKRSMAXOZCCOG-UHFFFAOYSA-N 0.000 description 1
- 238000001311 chemical methods and process Methods 0.000 description 1
- 230000000052 comparative effect Effects 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 230000007423 decrease Effects 0.000 description 1
- 238000011049 filling Methods 0.000 description 1
- 238000001914 filtration Methods 0.000 description 1
- 239000007789 gas Substances 0.000 description 1
- 229910002804 graphite Inorganic materials 0.000 description 1
- 239000010439 graphite Substances 0.000 description 1
- 238000011835 investigation Methods 0.000 description 1
- JJIJKNKBEFFVIK-UHFFFAOYSA-N manganese(2+);oxygen(2-);hydrate Chemical class O.[O-2].[Mn+2] JJIJKNKBEFFVIK-UHFFFAOYSA-N 0.000 description 1
- SQQMAOCOWKFBNP-UHFFFAOYSA-L manganese(II) sulfate Chemical compound [Mn+2].[O-]S([O-])(=O)=O SQQMAOCOWKFBNP-UHFFFAOYSA-L 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 239000010413 mother solution Substances 0.000 description 1
- 238000001556 precipitation Methods 0.000 description 1
- 238000002360 preparation method Methods 0.000 description 1
- 230000035484 reaction time Effects 0.000 description 1
- 150000003839 salts Chemical class 0.000 description 1
- 238000000926 separation method Methods 0.000 description 1
- 239000006228 supernatant Substances 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
Classifications
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M4/00—Electrodes
- H01M4/02—Electrodes composed of, or comprising, active material
- H01M4/36—Selection of substances as active materials, active masses, active liquids
- H01M4/48—Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides
- H01M4/50—Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides of manganese
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01G—COMPOUNDS CONTAINING METALS NOT COVERED BY SUBCLASSES C01D OR C01F
- C01G45/00—Compounds of manganese
- C01G45/02—Oxides
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
- Y02E60/10—Energy storage using batteries
Landscapes
- Chemical & Material Sciences (AREA)
- Inorganic Chemistry (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Electrochemistry (AREA)
- General Chemical & Material Sciences (AREA)
- Inorganic Compounds Of Heavy Metals (AREA)
- Electrolytic Production Of Non-Metals, Compounds, Apparatuses Therefor (AREA)
- Pharmaceuticals Containing Other Organic And Inorganic Compounds (AREA)
Priority Applications (9)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DE2419490A DE2419490C3 (de) | 1974-04-23 | 1974-04-23 | Verfahren zur Herstellung von Mangandioxid |
| JP50028118A JPS50158596A (oth) | 1974-04-23 | 1975-03-10 | |
| SU752121998A SU625597A3 (ru) | 1974-04-23 | 1975-04-11 | Способ получени двуокиси марганца |
| FR7512319A FR2268752B1 (oth) | 1974-04-23 | 1975-04-21 | |
| BE2054289A BE828201A (fr) | 1974-04-23 | 1975-04-22 | Procede de preparation de bioxyde de manganese |
| DK173675A DK173675A (da) | 1974-04-23 | 1975-04-22 | Fremgangsmade til fremstilling af mangandioxid |
| GB16694/75A GB1498649A (en) | 1974-04-23 | 1975-04-22 | Process for manufacturing manganese dioxide |
| US05/570,585 US4006217A (en) | 1974-04-23 | 1975-04-23 | Process for making manganese dioxide |
| IN1990/CAL/75A IN143851B (oth) | 1974-04-23 | 1975-10-15 |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DE2419490A DE2419490C3 (de) | 1974-04-23 | 1974-04-23 | Verfahren zur Herstellung von Mangandioxid |
Publications (3)
| Publication Number | Publication Date |
|---|---|
| DE2419490A1 DE2419490A1 (de) | 1975-10-30 |
| DE2419490B2 DE2419490B2 (de) | 1977-07-21 |
| DE2419490C3 true DE2419490C3 (de) | 1978-03-09 |
Family
ID=5913677
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| DE2419490A Expired DE2419490C3 (de) | 1974-04-23 | 1974-04-23 | Verfahren zur Herstellung von Mangandioxid |
Country Status (9)
| Country | Link |
|---|---|
| US (1) | US4006217A (oth) |
| JP (1) | JPS50158596A (oth) |
| BE (1) | BE828201A (oth) |
| DE (1) | DE2419490C3 (oth) |
| DK (1) | DK173675A (oth) |
| FR (1) | FR2268752B1 (oth) |
| GB (1) | GB1498649A (oth) |
| IN (1) | IN143851B (oth) |
| SU (1) | SU625597A3 (oth) |
Families Citing this family (33)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4450148A (en) * | 1982-09-30 | 1984-05-22 | Chemetals Incorporated | Preparation of manganite, MnOOH |
| US4448760A (en) * | 1982-09-30 | 1984-05-15 | Chemetals Incorporated | Continuous process for the preparation of manganite, MnOOH |
| US5078889A (en) * | 1989-02-28 | 1992-01-07 | Csa Division, Lake Industries, Inc. | Selective removal of contaminants from water sources using inorganic media |
| US5250374A (en) * | 1991-01-24 | 1993-10-05 | Rbc Universal | Method of preparing a rechargeable modified manganese-containing material by electrolytic deposition and related material |
| US5156934A (en) * | 1991-02-11 | 1992-10-20 | Rbc Universal Ltd. | Method of making a rechargable modified manganese dioxide material and related compound and electrode material |
| US5395534A (en) * | 1992-11-02 | 1995-03-07 | Sterling Air & Water Corporation | Water filtration medium and method of use |
| US5401477A (en) * | 1992-12-07 | 1995-03-28 | Olin Corporation | Process for producing solid manganese dioxide |
| US5419986A (en) * | 1993-10-15 | 1995-05-30 | Rechargeable Battery Corporation | Method of making a rechargeable manganese-oxide compound and related electrode material |
| US6200542B1 (en) | 1995-01-20 | 2001-03-13 | Engelhard Corporation | Method and apparatus for treating the atmosphere |
| DE69620740T2 (de) | 1995-01-20 | 2002-08-22 | Engelhard Corp., Iselin | Vorrichtung zur schadstoffentfernung aus umgebungsluft in der motorhaube eines fahrzeuges |
| US6517899B1 (en) | 1995-01-20 | 2003-02-11 | Engelhard Corporation | Catalyst and adsorption compositions having adhesion characteristics |
| US6863984B2 (en) | 1995-01-20 | 2005-03-08 | Engelhard Corporation | Catalyst and adsorption compositions having improved adhesion characteristics |
| US6818254B1 (en) | 1995-01-20 | 2004-11-16 | Engelhard Corporation | Stable slurries of catalytically active materials |
| US20020018742A1 (en) * | 1995-01-20 | 2002-02-14 | Engelhard Corporation | Method and apparatus for treating the atmosphere |
| US6214303B1 (en) | 1995-01-20 | 2001-04-10 | Engelhard Corporation | Method and apparatus for treating the atmosphere |
| US5997831A (en) * | 1996-07-12 | 1999-12-07 | Engelhard Corporation | Method of catalytically treating the atmosphere and heat exchange devices produced thereby |
| US5815235A (en) * | 1997-07-09 | 1998-09-29 | John L. Runckel Trust | Ski goggles with pivotal frame members for interchanging lenses |
| US6156283A (en) | 1998-03-23 | 2000-12-05 | Engelhard Corporation | Hydrophobic catalytic materials and method of forming the same |
| US6162561A (en) * | 1999-05-03 | 2000-12-19 | The Gillette Company | Akaline cell with improved cathode |
| US6391270B1 (en) | 1999-12-23 | 2002-05-21 | Noranda Inc. | Method for removing manganese from acidic sulfate solutions |
| US6610263B2 (en) | 2000-08-01 | 2003-08-26 | Enviroscrub Technologies Corporation | System and process for removal of pollutants from a gas stream |
| US7232782B2 (en) * | 2002-03-06 | 2007-06-19 | Enviroscrub Technologies Corp. | Regeneration, pretreatment and precipitation of oxides of manganese |
| US20030059460A1 (en) * | 2001-09-27 | 2003-03-27 | Yasuhiko Tabata | Hybrid material for regeneration of living body tissue |
| PL373791A1 (pl) * | 2001-12-21 | 2005-09-19 | Enviroscrub Technologies Corporation | Sposób obróbki wstępnej i regeneracji tlenków manganu, zespół do wstępnej obróbki tlenków manganu, cząstki tlenków manganu otrzymane tym sposobem i placek filtracyjny z tlenków manganu |
| US20040101457A1 (en) * | 2002-06-11 | 2004-05-27 | Pahlman John E. | Disassociation processing of metal oxides |
| EP1590082B1 (en) * | 2003-01-28 | 2008-12-31 | Enviroscrub Technologies Corporation | Oxides of manganese processed in continuous flow reactors |
| US7488464B2 (en) * | 2003-07-31 | 2009-02-10 | Enviroscrub Technologies Corporation | Metal oxide processing methods and systems |
| US7951354B2 (en) * | 2008-04-02 | 2011-05-31 | The Gillette Company | Ozonating manganese dioxide |
| CN101798118A (zh) * | 2010-03-11 | 2010-08-11 | 湘潭大学 | 一种二氧化锰一维纳米材料的制备方法 |
| US9422177B2 (en) | 2013-10-10 | 2016-08-23 | Tronox Llc | Removal of organic impurities from water |
| CN111039448B (zh) * | 2019-12-12 | 2022-09-20 | 佛山市德方纳米科技有限公司 | 臭氧去除酸性溶液中锰杂质的方法 |
| CN111018178B (zh) * | 2019-12-12 | 2022-09-30 | 佛山市德方纳米科技有限公司 | 含锰酸性溶液中锰的去除方法 |
| WO2024176382A1 (ja) * | 2023-02-22 | 2024-08-29 | 国立大学法人北海道大学 | 二酸化マンガン、及びそれを用いた多価金属イオン二次電池、並びそれらの製造方法 |
Family Cites Families (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US1330738A (en) * | 1916-09-26 | 1920-02-10 | Nat Carbon Co Inc | Process of making conducting hydrated black manganese dioxid |
| US1358626A (en) * | 1917-10-31 | 1920-11-09 | Nat Carbon Co Inc | Depolarizing agent for dry batteries and process of making same |
| DE1189960B (de) * | 1962-10-27 | 1965-04-01 | Varta Pertrix Union Ges Mit Be | Verfahren zur Herstellung von Ramsdellit |
| US3702889A (en) * | 1970-10-19 | 1972-11-14 | Pfizer | Process for making activated manganese dioxide |
-
1974
- 1974-04-23 DE DE2419490A patent/DE2419490C3/de not_active Expired
-
1975
- 1975-03-10 JP JP50028118A patent/JPS50158596A/ja active Pending
- 1975-04-11 SU SU752121998A patent/SU625597A3/ru active
- 1975-04-21 FR FR7512319A patent/FR2268752B1/fr not_active Expired
- 1975-04-22 BE BE2054289A patent/BE828201A/xx unknown
- 1975-04-22 GB GB16694/75A patent/GB1498649A/en not_active Expired
- 1975-04-22 DK DK173675A patent/DK173675A/da active IP Right Grant
- 1975-04-23 US US05/570,585 patent/US4006217A/en not_active Expired - Lifetime
- 1975-10-15 IN IN1990/CAL/75A patent/IN143851B/en unknown
Also Published As
| Publication number | Publication date |
|---|---|
| BE828201A (fr) | 1975-08-18 |
| JPS50158596A (oth) | 1975-12-22 |
| FR2268752B1 (oth) | 1981-06-19 |
| US4006217A (en) | 1977-02-01 |
| IN143851B (oth) | 1978-02-11 |
| GB1498649A (en) | 1978-01-25 |
| DK173675A (da) | 1975-10-24 |
| DE2419490B2 (de) | 1977-07-21 |
| DE2419490A1 (de) | 1975-10-30 |
| SU625597A3 (ru) | 1978-09-25 |
| FR2268752A1 (oth) | 1975-11-21 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C3 | Grant after two publication steps (3rd publication) | ||
| 8339 | Ceased/non-payment of the annual fee |