DE2358409C2 - Verfahren zur Reinigung wässriger Natriumcitrat-Lösungen - Google Patents
Verfahren zur Reinigung wässriger Natriumcitrat-LösungenInfo
- Publication number
- DE2358409C2 DE2358409C2 DE2358409A DE2358409A DE2358409C2 DE 2358409 C2 DE2358409 C2 DE 2358409C2 DE 2358409 A DE2358409 A DE 2358409A DE 2358409 A DE2358409 A DE 2358409A DE 2358409 C2 DE2358409 C2 DE 2358409C2
- Authority
- DE
- Germany
- Prior art keywords
- solution
- citrate
- evaporation
- sodium citrate
- sodium
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 238000000034 method Methods 0.000 title claims description 41
- 239000001509 sodium citrate Substances 0.000 title claims description 34
- NLJMYIDDQXHKNR-UHFFFAOYSA-K sodium citrate Chemical compound O.O.[Na+].[Na+].[Na+].[O-]C(=O)CC(O)(CC([O-])=O)C([O-])=O NLJMYIDDQXHKNR-UHFFFAOYSA-K 0.000 title claims description 34
- RAHZWNYVWXNFOC-UHFFFAOYSA-N Sulphur dioxide Chemical compound O=S=O RAHZWNYVWXNFOC-UHFFFAOYSA-N 0.000 claims description 44
- 238000010521 absorption reaction Methods 0.000 claims description 31
- 238000000746 purification Methods 0.000 claims description 6
- 238000011081 inoculation Methods 0.000 claims description 4
- 239000012141 concentrate Substances 0.000 claims description 3
- 239000000243 solution Substances 0.000 description 76
- 239000011734 sodium Substances 0.000 description 40
- 238000001704 evaporation Methods 0.000 description 36
- 230000008020 evaporation Effects 0.000 description 36
- PMZURENOXWZQFD-UHFFFAOYSA-L Sodium Sulfate Chemical compound [Na+].[Na+].[O-]S([O-])(=O)=O PMZURENOXWZQFD-UHFFFAOYSA-L 0.000 description 32
- 239000013078 crystal Substances 0.000 description 32
- 235000011083 sodium citrates Nutrition 0.000 description 31
- 229910052938 sodium sulfate Inorganic materials 0.000 description 28
- 235000011152 sodium sulphate Nutrition 0.000 description 28
- KRKNYBCHXYNGOX-UHFFFAOYSA-K Citrate Chemical compound [O-]C(=O)CC(O)(CC([O-])=O)C([O-])=O KRKNYBCHXYNGOX-UHFFFAOYSA-K 0.000 description 22
- 238000001556 precipitation Methods 0.000 description 20
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 20
- QAOWNCQODCNURD-UHFFFAOYSA-L Sulfate Chemical compound [O-]S([O-])(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-L 0.000 description 19
- 239000007789 gas Substances 0.000 description 19
- 239000012452 mother liquor Substances 0.000 description 16
- 238000003756 stirring Methods 0.000 description 14
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 description 11
- 239000007788 liquid Substances 0.000 description 11
- 229910021653 sulphate ion Inorganic materials 0.000 description 10
- 239000000872 buffer Substances 0.000 description 9
- 238000005119 centrifugation Methods 0.000 description 8
- 238000002425 crystallisation Methods 0.000 description 8
- 238000001816 cooling Methods 0.000 description 7
- 230000008025 crystallization Effects 0.000 description 7
- 239000012535 impurity Substances 0.000 description 7
- 239000002244 precipitate Substances 0.000 description 7
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 6
- KRKNYBCHXYNGOX-UHFFFAOYSA-N citric acid Chemical compound OC(=O)CC(O)(C(O)=O)CC(O)=O KRKNYBCHXYNGOX-UHFFFAOYSA-N 0.000 description 6
- 238000011084 recovery Methods 0.000 description 6
- 238000005406 washing Methods 0.000 description 6
- 238000004140 cleaning Methods 0.000 description 5
- 239000000126 substance Substances 0.000 description 5
- -1 hydrogen ions Chemical class 0.000 description 4
- HWPKGOGLCKPRLZ-UHFFFAOYSA-M monosodium citrate Chemical compound [Na+].OC(=O)CC(O)(C([O-])=O)CC(O)=O HWPKGOGLCKPRLZ-UHFFFAOYSA-M 0.000 description 4
- 235000018342 monosodium citrate Nutrition 0.000 description 4
- 239000002524 monosodium citrate Substances 0.000 description 4
- 239000003513 alkali Substances 0.000 description 3
- 159000000009 barium salts Chemical class 0.000 description 3
- 230000015572 biosynthetic process Effects 0.000 description 3
- 239000000356 contaminant Substances 0.000 description 3
- 235000019262 disodium citrate Nutrition 0.000 description 3
- 239000002526 disodium citrate Substances 0.000 description 3
- CEYULKASIQJZGP-UHFFFAOYSA-L disodium;2-(carboxymethyl)-2-hydroxybutanedioate Chemical compound [Na+].[Na+].[O-]C(=O)CC(O)(C(=O)O)CC([O-])=O CEYULKASIQJZGP-UHFFFAOYSA-L 0.000 description 3
- 239000007791 liquid phase Substances 0.000 description 3
- MWUXSHHQAYIFBG-UHFFFAOYSA-N nitrogen oxide Inorganic materials O=[N] MWUXSHHQAYIFBG-UHFFFAOYSA-N 0.000 description 3
- 238000011069 regeneration method Methods 0.000 description 3
- 229910052708 sodium Inorganic materials 0.000 description 3
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 2
- 238000009825 accumulation Methods 0.000 description 2
- 239000007864 aqueous solution Substances 0.000 description 2
- 159000000007 calcium salts Chemical class 0.000 description 2
- 238000006243 chemical reaction Methods 0.000 description 2
- 239000000470 constituent Substances 0.000 description 2
- 238000000605 extraction Methods 0.000 description 2
- 239000000706 filtrate Substances 0.000 description 2
- 238000004519 manufacturing process Methods 0.000 description 2
- 239000002245 particle Substances 0.000 description 2
- 230000008929 regeneration Effects 0.000 description 2
- VWDWKYIASSYTQR-UHFFFAOYSA-N sodium nitrate Chemical compound [Na+].[O-][N+]([O-])=O VWDWKYIASSYTQR-UHFFFAOYSA-N 0.000 description 2
- GEHJYWRUCIMESM-UHFFFAOYSA-L sodium sulfite Chemical compound [Na+].[Na+].[O-]S([O-])=O GEHJYWRUCIMESM-UHFFFAOYSA-L 0.000 description 2
- LSNNMFCWUKXFEE-UHFFFAOYSA-M Bisulfite Chemical compound OS([O-])=O LSNNMFCWUKXFEE-UHFFFAOYSA-M 0.000 description 1
- BHPQYMZQTOCNFJ-UHFFFAOYSA-N Calcium cation Chemical compound [Ca+2] BHPQYMZQTOCNFJ-UHFFFAOYSA-N 0.000 description 1
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 1
- RWSOTUBLDIXVET-UHFFFAOYSA-N Dihydrogen sulfide Chemical compound S RWSOTUBLDIXVET-UHFFFAOYSA-N 0.000 description 1
- 102100034535 Histone H3.1 Human genes 0.000 description 1
- 101001067844 Homo sapiens Histone H3.1 Proteins 0.000 description 1
- CDBYLPFSWZWCQE-UHFFFAOYSA-L Sodium Carbonate Chemical compound [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 description 1
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 239000000654 additive Substances 0.000 description 1
- 150000001299 aldehydes Chemical class 0.000 description 1
- 229910001424 calcium ion Inorganic materials 0.000 description 1
- GBAOBIBJACZTNA-UHFFFAOYSA-L calcium sulfite Chemical compound [Ca+2].[O-]S([O-])=O GBAOBIBJACZTNA-UHFFFAOYSA-L 0.000 description 1
- 235000010261 calcium sulphite Nutrition 0.000 description 1
- 229940069078 citric acid / sodium citrate Drugs 0.000 description 1
- 239000003245 coal Substances 0.000 description 1
- 239000000567 combustion gas Substances 0.000 description 1
- 238000011109 contamination Methods 0.000 description 1
- 239000002826 coolant Substances 0.000 description 1
- 229910052802 copper Inorganic materials 0.000 description 1
- 239000010949 copper Substances 0.000 description 1
- 230000003247 decreasing effect Effects 0.000 description 1
- 230000001419 dependent effect Effects 0.000 description 1
- 238000004090 dissolution Methods 0.000 description 1
- 238000002474 experimental method Methods 0.000 description 1
- 238000011049 filling Methods 0.000 description 1
- 238000001914 filtration Methods 0.000 description 1
- 230000008014 freezing Effects 0.000 description 1
- 238000007710 freezing Methods 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- 239000001257 hydrogen Substances 0.000 description 1
- 229910052739 hydrogen Inorganic materials 0.000 description 1
- 229910000037 hydrogen sulfide Inorganic materials 0.000 description 1
- 230000002427 irreversible effect Effects 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 230000008018 melting Effects 0.000 description 1
- 238000002844 melting Methods 0.000 description 1
- 229910052751 metal Inorganic materials 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- 239000010446 mirabilite Substances 0.000 description 1
- 239000000203 mixture Substances 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 230000003647 oxidation Effects 0.000 description 1
- 238000007254 oxidation reaction Methods 0.000 description 1
- 230000001376 precipitating effect Effects 0.000 description 1
- 230000003134 recirculating effect Effects 0.000 description 1
- 230000001172 regenerating effect Effects 0.000 description 1
- 150000003839 salts Chemical class 0.000 description 1
- 238000005201 scrubbing Methods 0.000 description 1
- 238000000926 separation method Methods 0.000 description 1
- 235000010267 sodium hydrogen sulphite Nutrition 0.000 description 1
- 235000010344 sodium nitrate Nutrition 0.000 description 1
- 239000004317 sodium nitrate Substances 0.000 description 1
- RSIJVJUOQBWMIM-UHFFFAOYSA-L sodium sulfate decahydrate Chemical compound O.O.O.O.O.O.O.O.O.O.[Na+].[Na+].[O-]S([O-])(=O)=O RSIJVJUOQBWMIM-UHFFFAOYSA-L 0.000 description 1
- 235000010265 sodium sulphite Nutrition 0.000 description 1
- OESFSXYRSCBAQJ-UHFFFAOYSA-M sodium;3-carboxy-3,5-dihydroxy-5-oxopentanoate;2-hydroxypropane-1,2,3-tricarboxylic acid Chemical compound [Na+].OC(=O)CC(O)(C(O)=O)CC(O)=O.OC(=O)CC(O)(C(O)=O)CC([O-])=O OESFSXYRSCBAQJ-UHFFFAOYSA-M 0.000 description 1
- 239000002904 solvent Substances 0.000 description 1
- 159000000008 strontium salts Chemical class 0.000 description 1
- VTBSJEPGLHXIIS-UHFFFAOYSA-L strontium;sulfite Chemical compound [Sr+2].[O-]S([O-])=O VTBSJEPGLHXIIS-UHFFFAOYSA-L 0.000 description 1
- LSNNMFCWUKXFEE-UHFFFAOYSA-L sulfite Chemical compound [O-]S([O-])=O LSNNMFCWUKXFEE-UHFFFAOYSA-L 0.000 description 1
- 229910052717 sulfur Inorganic materials 0.000 description 1
- HRXKRNGNAMMEHJ-UHFFFAOYSA-K trisodium citrate Chemical class [Na+].[Na+].[Na+].[O-]C(=O)CC(O)(CC([O-])=O)C([O-])=O HRXKRNGNAMMEHJ-UHFFFAOYSA-K 0.000 description 1
- 230000008016 vaporization Effects 0.000 description 1
- 239000006200 vaporizer Substances 0.000 description 1
- 239000013585 weight reducing agent Substances 0.000 description 1
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
- B01D53/34—Chemical or biological purification of waste gases
- B01D53/46—Removing components of defined structure
- B01D53/48—Sulfur compounds
- B01D53/50—Sulfur oxides
- B01D53/501—Sulfur oxides by treating the gases with a solution or a suspension of an alkali or earth-alkali or ammonium compound
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C51/00—Preparation of carboxylic acids or their salts, halides or anhydrides
- C07C51/42—Separation; Purification; Stabilisation; Use of additives
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Organic Chemistry (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Environmental & Geological Engineering (AREA)
- Analytical Chemistry (AREA)
- General Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Biomedical Technology (AREA)
- Treating Waste Gases (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Gas Separation By Absorption (AREA)
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| NO4331/72A NO133546C (US20080094685A1-20080424-C00004.png) | 1972-11-24 | 1972-11-24 |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| DE2358409A1 DE2358409A1 (de) | 1974-06-06 |
| DE2358409C2 true DE2358409C2 (de) | 1982-12-02 |
Family
ID=19880213
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| DE2358409A Expired DE2358409C2 (de) | 1972-11-24 | 1973-11-23 | Verfahren zur Reinigung wässriger Natriumcitrat-Lösungen |
Country Status (13)
Families Citing this family (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| SE429200B (sv) * | 1978-10-31 | 1983-08-22 | Flaekt Ab | Forfarande for atervinning av natriumcitrat fran vattenlosningar som anvents i ett absorptions/avdrivningsforfarande for so?712-atervinning |
| JPS597324A (ja) * | 1982-07-05 | 1984-01-14 | Nippon Telegr & Teleph Corp <Ntt> | 光フアイバ用結合器 |
| JPS5934507A (ja) * | 1982-08-21 | 1984-02-24 | Nippon Sheet Glass Co Ltd | 戻り光干渉を防止した光フアイバ−端末 |
| US5653917A (en) * | 1994-06-29 | 1997-08-05 | Singerman; Gary M. | Rust-removing alkali metal hydrogen citrate composition |
| US5785888A (en) * | 1995-03-24 | 1998-07-28 | Milmac Operating Company | Method for removal of sulfur dioxide |
| ES2821501T3 (es) | 2012-05-02 | 2021-04-26 | Mecs Inc | Recuperación regenerativa de contaminantes de gases efluentes |
| KR102180252B1 (ko) | 2013-03-15 | 2020-11-18 | 엠이씨에스, 인코포레이티드 | 배출 가스로부터의 오염물질의 재생식 회수 |
| CN106831402A (zh) * | 2016-12-24 | 2017-06-13 | 句容亿格纳米材料厂 | 一种柠檬酸钠的精制方法 |
Family Cites Families (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US2031802A (en) * | 1932-05-06 | 1936-02-25 | Ici Ltd | Recovery of sulphur dioxide from gas mixtures |
| US2086379A (en) * | 1933-05-03 | 1937-07-06 | Ici Ltd | Gas absorption process |
| US3420881A (en) * | 1966-03-03 | 1969-01-07 | Gen Dynamics Corp | Reclamation process |
-
1972
- 1972-11-24 NO NO4331/72A patent/NO133546C/no unknown
-
1973
- 1973-11-19 US US416767A patent/US3886069A/en not_active Expired - Lifetime
- 1973-11-20 AU AU62689/73A patent/AU471806B2/en not_active Expired
- 1973-11-22 DK DK632673AA patent/DK133865B/da not_active IP Right Cessation
- 1973-11-22 JP JP48131595A patent/JPS5745608B2/ja not_active Expired
- 1973-11-23 ES ES420775A patent/ES420775A1/es not_active Expired
- 1973-11-23 DE DE2358409A patent/DE2358409C2/de not_active Expired
- 1973-11-23 BE BE138146A patent/BE807774A/xx unknown
- 1973-11-23 GB GB5453273A patent/GB1434061A/en not_active Expired
- 1973-11-23 IT IT53866/73A patent/IT1000152B/it active
- 1973-11-23 NL NL7316047A patent/NL7316047A/xx not_active Application Discontinuation
- 1973-11-23 CA CA186,572A patent/CA1012124A/en not_active Expired
- 1973-11-23 FR FR7341778A patent/FR2213265B1/fr not_active Expired
Non-Patent Citations (1)
| Title |
|---|
| NICHTS-ERMITTELT |
Also Published As
| Publication number | Publication date |
|---|---|
| GB1434061A (en) | 1976-04-28 |
| ES420775A1 (es) | 1976-11-16 |
| DK133865C (US20080094685A1-20080424-C00004.png) | 1977-01-03 |
| JPS4982625A (US20080094685A1-20080424-C00004.png) | 1974-08-08 |
| CA1012124A (en) | 1977-06-14 |
| US3886069A (en) | 1975-05-27 |
| NO133546C (US20080094685A1-20080424-C00004.png) | 1976-05-19 |
| FR2213265B1 (US20080094685A1-20080424-C00004.png) | 1977-08-12 |
| DE2358409A1 (de) | 1974-06-06 |
| NO133546B (US20080094685A1-20080424-C00004.png) | 1976-02-09 |
| IT1000152B (it) | 1976-03-30 |
| AU471806B2 (en) | 1976-05-06 |
| NL7316047A (US20080094685A1-20080424-C00004.png) | 1974-05-28 |
| FR2213265A1 (US20080094685A1-20080424-C00004.png) | 1974-08-02 |
| AU6268973A (en) | 1975-05-22 |
| BE807774A (fr) | 1974-03-15 |
| JPS5745608B2 (US20080094685A1-20080424-C00004.png) | 1982-09-29 |
| DK133865B (da) | 1976-08-02 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| OD | Request for examination | ||
| D2 | Grant after examination | ||
| 8339 | Ceased/non-payment of the annual fee |