DE2326667C3 - Verfahren zur Aktivierung von Katalysatoren für Elektroden in elektrochemischen Zellen - Google Patents
Verfahren zur Aktivierung von Katalysatoren für Elektroden in elektrochemischen ZellenInfo
- Publication number
- DE2326667C3 DE2326667C3 DE2326667A DE2326667A DE2326667C3 DE 2326667 C3 DE2326667 C3 DE 2326667C3 DE 2326667 A DE2326667 A DE 2326667A DE 2326667 A DE2326667 A DE 2326667A DE 2326667 C3 DE2326667 C3 DE 2326667C3
- Authority
- DE
- Germany
- Prior art keywords
- catalyst
- cobalt
- oxygen
- catalysts
- electrodes
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 239000003054 catalyst Substances 0.000 title claims description 37
- 238000000034 method Methods 0.000 title claims description 8
- 230000003213 activating effect Effects 0.000 title claims description 3
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 claims description 19
- 239000001301 oxygen Substances 0.000 claims description 19
- 229910052760 oxygen Inorganic materials 0.000 claims description 19
- 239000000446 fuel Substances 0.000 claims description 17
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 claims description 13
- 229910017052 cobalt Inorganic materials 0.000 claims description 9
- 239000010941 cobalt Substances 0.000 claims description 9
- GUTLYIVDDKVIGB-UHFFFAOYSA-N cobalt atom Chemical compound [Co] GUTLYIVDDKVIGB-UHFFFAOYSA-N 0.000 claims description 9
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 claims description 8
- 239000010949 copper Substances 0.000 claims description 6
- 239000011261 inert gas Substances 0.000 claims description 6
- 229910052742 iron Inorganic materials 0.000 claims description 6
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 claims description 5
- 239000013522 chelant Substances 0.000 claims description 5
- 229910052802 copper Inorganic materials 0.000 claims description 5
- 229910052757 nitrogen Inorganic materials 0.000 claims description 4
- 229910052751 metal Inorganic materials 0.000 claims description 2
- 239000002184 metal Substances 0.000 claims description 2
- 238000005496 tempering Methods 0.000 claims 2
- 150000001242 acetic acid derivatives Chemical class 0.000 claims 1
- 239000003245 coal Substances 0.000 claims 1
- IJNJLGFTSIAHEA-UHFFFAOYSA-N prop-2-ynal Chemical compound O=CC#C IJNJLGFTSIAHEA-UHFFFAOYSA-N 0.000 claims 1
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 12
- 230000000694 effects Effects 0.000 description 11
- BDAGIHXWWSANSR-UHFFFAOYSA-N methanoic acid Natural products OC=O BDAGIHXWWSANSR-UHFFFAOYSA-N 0.000 description 4
- WSFSSNUMVMOOMR-UHFFFAOYSA-N Formaldehyde Chemical compound O=C WSFSSNUMVMOOMR-UHFFFAOYSA-N 0.000 description 3
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 3
- MUBZPKHOEPUJKR-UHFFFAOYSA-N Oxalic acid Chemical compound OC(=O)C(O)=O MUBZPKHOEPUJKR-UHFFFAOYSA-N 0.000 description 3
- 238000001994 activation Methods 0.000 description 3
- 238000006243 chemical reaction Methods 0.000 description 3
- 230000003647 oxidation Effects 0.000 description 3
- 238000007254 oxidation reaction Methods 0.000 description 3
- 239000004810 polytetrafluoroethylene Substances 0.000 description 3
- 229920001343 polytetrafluoroethylene Polymers 0.000 description 3
- OSWFIVFLDKOXQC-UHFFFAOYSA-N 4-(3-methoxyphenyl)aniline Chemical compound COC1=CC=CC(C=2C=CC(N)=CC=2)=C1 OSWFIVFLDKOXQC-UHFFFAOYSA-N 0.000 description 2
- VVQNEPGJFQJSBK-UHFFFAOYSA-N Methyl methacrylate Chemical compound COC(=O)C(C)=C VVQNEPGJFQJSBK-UHFFFAOYSA-N 0.000 description 2
- 229920005372 Plexiglas® Polymers 0.000 description 2
- 239000006230 acetylene black Substances 0.000 description 2
- 230000004913 activation Effects 0.000 description 2
- 229910052799 carbon Inorganic materials 0.000 description 2
- 239000003792 electrolyte Substances 0.000 description 2
- 235000019253 formic acid Nutrition 0.000 description 2
- 229910002804 graphite Inorganic materials 0.000 description 2
- 239000010439 graphite Substances 0.000 description 2
- 239000010970 precious metal Substances 0.000 description 2
- UGFAIRIUMAVXCW-UHFFFAOYSA-N Carbon monoxide Chemical compound [O+]#[C-] UGFAIRIUMAVXCW-UHFFFAOYSA-N 0.000 description 1
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 1
- 229910001252 Pd alloy Inorganic materials 0.000 description 1
- 239000011149 active material Substances 0.000 description 1
- 238000000137 annealing Methods 0.000 description 1
- 239000012298 atmosphere Substances 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 229910002091 carbon monoxide Inorganic materials 0.000 description 1
- 238000010349 cathodic reaction Methods 0.000 description 1
- 239000007795 chemical reaction product Substances 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 239000004020 conductor Substances 0.000 description 1
- 229940116318 copper carbonate Drugs 0.000 description 1
- GEZOTWYUIKXWOA-UHFFFAOYSA-L copper;carbonate Chemical compound [Cu+2].[O-]C([O-])=O GEZOTWYUIKXWOA-UHFFFAOYSA-L 0.000 description 1
- 239000003995 emulsifying agent Substances 0.000 description 1
- 239000000839 emulsion Substances 0.000 description 1
- 238000002474 experimental method Methods 0.000 description 1
- 230000002349 favourable effect Effects 0.000 description 1
- 230000008014 freezing Effects 0.000 description 1
- 238000007710 freezing Methods 0.000 description 1
- 239000011521 glass Substances 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- 239000001257 hydrogen Substances 0.000 description 1
- 229910052739 hydrogen Inorganic materials 0.000 description 1
- 230000002209 hydrophobic effect Effects 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 238000002156 mixing Methods 0.000 description 1
- 239000000203 mixture Substances 0.000 description 1
- 239000004570 mortar (masonry) Substances 0.000 description 1
- 239000012299 nitrogen atmosphere Substances 0.000 description 1
- 229910000510 noble metal Inorganic materials 0.000 description 1
- 235000006408 oxalic acid Nutrition 0.000 description 1
- 238000005245 sintering Methods 0.000 description 1
- 230000002459 sustained effect Effects 0.000 description 1
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
- B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
- B01J31/18—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes containing nitrogen, phosphorus, arsenic or antimony as complexing atoms, e.g. in pyridine ligands, or in resonance therewith, e.g. in isocyanide ligands C=N-R or as complexed central atoms
- B01J31/1805—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes containing nitrogen, phosphorus, arsenic or antimony as complexing atoms, e.g. in pyridine ligands, or in resonance therewith, e.g. in isocyanide ligands C=N-R or as complexed central atoms the ligands containing nitrogen
- B01J31/181—Cyclic ligands, including e.g. non-condensed polycyclic ligands, comprising at least one complexing nitrogen atom as ring member, e.g. pyridine
- B01J31/1825—Ligands comprising condensed ring systems, e.g. acridine, carbazole
- B01J31/183—Ligands comprising condensed ring systems, e.g. acridine, carbazole with more than one complexing nitrogen atom, e.g. phenanthroline
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
- B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
- B01J31/22—Organic complexes
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
- B01J37/08—Heat treatment
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M4/00—Electrodes
- H01M4/86—Inert electrodes with catalytic activity, e.g. for fuel cells
- H01M4/90—Selection of catalytic material
- H01M4/9008—Organic or organo-metallic compounds
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J21/00—Catalysts comprising the elements, oxides, or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium, or hafnium
- B01J21/18—Carbon
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
- B01J2531/02—Compositional aspects of complexes used, e.g. polynuclearity
- B01J2531/0238—Complexes comprising multidentate ligands, i.e. more than 2 ionic or coordinative bonds from the central metal to the ligand, the latter having at least two donor atoms, e.g. N, O, S, P
- B01J2531/0241—Rigid ligands, e.g. extended sp2-carbon frameworks or geminal di- or trisubstitution
- B01J2531/025—Ligands with a porphyrin ring system or analogues thereof, e.g. phthalocyanines, corroles
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
- B01J2531/10—Complexes comprising metals of Group I (IA or IB) as the central metal
- B01J2531/16—Copper
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
- B01J2531/80—Complexes comprising metals of Group VIII as the central metal
- B01J2531/84—Metals of the iron group
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
- B01J2531/80—Complexes comprising metals of Group VIII as the central metal
- B01J2531/84—Metals of the iron group
- B01J2531/845—Cobalt
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
- Y02E60/30—Hydrogen technology
- Y02E60/50—Fuel cells
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Organic Chemistry (AREA)
- Inorganic Chemistry (AREA)
- Electrochemistry (AREA)
- General Chemical & Material Sciences (AREA)
- Physics & Mathematics (AREA)
- Thermal Sciences (AREA)
- Inert Electrodes (AREA)
- Catalysts (AREA)
Priority Applications (4)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DE2326667A DE2326667C3 (de) | 1973-05-25 | 1973-05-25 | Verfahren zur Aktivierung von Katalysatoren für Elektroden in elektrochemischen Zellen |
| FR7410969A FR2231120B1 (enExample) | 1973-05-25 | 1974-03-28 | |
| US05/467,911 US3930884A (en) | 1973-05-25 | 1974-05-08 | Activated stable oxygen electrode |
| GB2325474A GB1468610A (en) | 1973-05-25 | 1974-05-24 | Process for the activation of catalysts for electrodes in electrochemical cells |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DE2326667A DE2326667C3 (de) | 1973-05-25 | 1973-05-25 | Verfahren zur Aktivierung von Katalysatoren für Elektroden in elektrochemischen Zellen |
Publications (3)
| Publication Number | Publication Date |
|---|---|
| DE2326667A1 DE2326667A1 (de) | 1974-12-12 |
| DE2326667B2 DE2326667B2 (de) | 1980-11-27 |
| DE2326667C3 true DE2326667C3 (de) | 1982-01-14 |
Family
ID=5882118
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| DE2326667A Expired DE2326667C3 (de) | 1973-05-25 | 1973-05-25 | Verfahren zur Aktivierung von Katalysatoren für Elektroden in elektrochemischen Zellen |
Country Status (4)
| Country | Link |
|---|---|
| US (1) | US3930884A (enExample) |
| DE (1) | DE2326667C3 (enExample) |
| FR (1) | FR2231120B1 (enExample) |
| GB (1) | GB1468610A (enExample) |
Families Citing this family (12)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE2335403C3 (de) * | 1973-07-12 | 1982-01-07 | Robert Bosch Gmbh, 7000 Stuttgart | Verfahren zur Überwachung des Gehaltes an Stickoxiden in Abgasen, insbesondere in Kfz.-Abgasen, sowie Sensor zur Durchführung des Verfahrens |
| NL7714575A (nl) * | 1977-12-30 | 1979-07-03 | Shell Int Research | Werkwijze voor het activeren van een katalysator voor brandstofcelelektroden. |
| CA1185149A (en) * | 1980-02-25 | 1985-04-09 | Jurgen F. Gauger | Process for manufacturing a polychelate coating |
| US4510214A (en) * | 1980-10-03 | 1985-04-09 | Tracer Technologies, Inc. | Electrode with electron transfer catalyst |
| US4490464A (en) * | 1981-04-08 | 1984-12-25 | Gorton Lo G | Electrode for the electrochemical regeneration of coenzyme, a method of making said electrode, and the use thereof |
| ATE18601T1 (de) * | 1981-05-14 | 1986-03-15 | Kopo Konepohja Oy | Foerdervorrichtung zum zufuehren von festem brennstoff aus einem lagerbehaelter oder dergleichen in einen heizkessel fuer festen brennstoff. |
| US4722905A (en) * | 1981-12-01 | 1988-02-02 | National Research Development Corporation | Semiconductors |
| US4469763A (en) * | 1983-10-21 | 1984-09-04 | Tracer Technologies, Inc. | Lithium oxyhalide battery with cathode catalyst |
| US4584251A (en) * | 1983-12-23 | 1986-04-22 | Ciba-Geigy Corporation | Solid electrolyte cell and iodine-doped metal complexes as the cathode material |
| US4652647A (en) * | 1984-12-26 | 1987-03-24 | Exxon Research And Engineering Company | Aromatic-metal chelate compositions |
| US4911803A (en) * | 1988-07-19 | 1990-03-27 | Kunz Harold R | Composite hydrogen purification membrane and method for purifying hydrogen |
| US20110076598A1 (en) * | 2009-09-30 | 2011-03-31 | Academia Sinica | Corrin compound fuel cell catalysts |
Family Cites Families (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3617388A (en) * | 1966-07-25 | 1971-11-02 | Monsanto Res Corp | Method of activating fuel cell anodes |
| CH506892A (de) * | 1966-10-25 | 1971-04-30 | Bosch Gmbh Robert | Verfahren zur Herstellung von Sauerstoffelektroden für Brennstoffzellen |
| SE346422B (enExample) * | 1967-07-07 | 1972-07-03 | Bosch Gmbh Robert | |
| DE1671907A1 (de) * | 1967-11-16 | 1972-03-09 | Siemens Ag | Elektroden fuer Brennstoffelemente und Verfahren zu ihrer Herstellung |
| US3649365A (en) * | 1968-05-29 | 1972-03-14 | Gen Electric | Method of forming a catalyst catalyst coated powder and electrode |
| US3658721A (en) * | 1969-02-06 | 1972-04-25 | Univ Tokyo | Ammonia synthesis catalyst |
| DE2046354C3 (de) * | 1970-09-19 | 1979-11-08 | Robert Bosch Gmbh, 7000 Stuttgart | Elektrokatalysator für die Sauerstoffkathode in elektrochemischen Zellen |
| DE2128842C3 (de) * | 1971-06-11 | 1980-12-18 | Robert Bosch Gmbh, 7000 Stuttgart | Brennstoffelektrode für elektrochemische Brennstoffelemente |
-
1973
- 1973-05-25 DE DE2326667A patent/DE2326667C3/de not_active Expired
-
1974
- 1974-03-28 FR FR7410969A patent/FR2231120B1/fr not_active Expired
- 1974-05-08 US US05/467,911 patent/US3930884A/en not_active Expired - Lifetime
- 1974-05-24 GB GB2325474A patent/GB1468610A/en not_active Expired
Also Published As
| Publication number | Publication date |
|---|---|
| DE2326667A1 (de) | 1974-12-12 |
| FR2231120B1 (enExample) | 1979-09-28 |
| FR2231120A1 (enExample) | 1974-12-20 |
| GB1468610A (en) | 1977-03-30 |
| DE2326667B2 (de) | 1980-11-27 |
| US3930884A (en) | 1976-01-06 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| OF | Willingness to grant licences before publication of examined application | ||
| OF | Willingness to grant licences before publication of examined application | ||
| OD | Request for examination | ||
| C3 | Grant after two publication steps (3rd publication) | ||
| 8339 | Ceased/non-payment of the annual fee |