DE2265147C3 - Hochschlagzähe thermoplastische Massen - Google Patents
Hochschlagzähe thermoplastische MassenInfo
- Publication number
- DE2265147C3 DE2265147C3 DE2265147A DE2265147A DE2265147C3 DE 2265147 C3 DE2265147 C3 DE 2265147C3 DE 2265147 A DE2265147 A DE 2265147A DE 2265147 A DE2265147 A DE 2265147A DE 2265147 C3 DE2265147 C3 DE 2265147C3
- Authority
- DE
- Germany
- Prior art keywords
- rubber
- polystyrene
- impact
- molecular weight
- weight
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 229920001169 thermoplastic Polymers 0.000 title claims description 15
- 239000004416 thermosoftening plastic Substances 0.000 title claims description 15
- 229920001971 elastomer Polymers 0.000 claims description 45
- 239000005060 rubber Substances 0.000 claims description 43
- 239000004793 Polystyrene Substances 0.000 claims description 39
- 229920002223 polystyrene Polymers 0.000 claims description 39
- 239000000203 mixture Substances 0.000 claims description 21
- 239000011159 matrix material Substances 0.000 claims description 13
- HEDRZPFGACZZDS-UHFFFAOYSA-N Chloroform Chemical compound ClC(Cl)Cl HEDRZPFGACZZDS-UHFFFAOYSA-N 0.000 claims description 12
- 229920003244 diene elastomer Polymers 0.000 claims description 5
- 239000012815 thermoplastic material Substances 0.000 claims 1
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 description 20
- 238000000034 method Methods 0.000 description 11
- KAKZBPTYRLMSJV-UHFFFAOYSA-N Butadiene Chemical compound C=CC=C KAKZBPTYRLMSJV-UHFFFAOYSA-N 0.000 description 10
- 238000002156 mixing Methods 0.000 description 10
- 229920005990 polystyrene resin Polymers 0.000 description 9
- 229920001577 copolymer Polymers 0.000 description 7
- 239000002904 solvent Substances 0.000 description 6
- 238000004519 manufacturing process Methods 0.000 description 5
- 239000000178 monomer Substances 0.000 description 5
- 239000002245 particle Substances 0.000 description 5
- 229920005989 resin Polymers 0.000 description 5
- 239000011347 resin Substances 0.000 description 5
- 229920002554 vinyl polymer Polymers 0.000 description 5
- RRHGJUQNOFWUDK-UHFFFAOYSA-N Isoprene Chemical compound CC(=C)C=C RRHGJUQNOFWUDK-UHFFFAOYSA-N 0.000 description 4
- 229920005669 high impact polystyrene Polymers 0.000 description 4
- 229920002857 polybutadiene Polymers 0.000 description 4
- ZWEHNKRNPOVVGH-UHFFFAOYSA-N 2-Butanone Chemical compound CCC(C)=O ZWEHNKRNPOVVGH-UHFFFAOYSA-N 0.000 description 3
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 3
- 150000001993 dienes Chemical class 0.000 description 3
- 239000004797 high-impact polystyrene Substances 0.000 description 3
- 229920001519 homopolymer Polymers 0.000 description 3
- 229920003051 synthetic elastomer Polymers 0.000 description 3
- 239000005061 synthetic rubber Substances 0.000 description 3
- 238000012360 testing method Methods 0.000 description 3
- MYRTYDVEIRVNKP-UHFFFAOYSA-N 1,2-Divinylbenzene Chemical compound C=CC1=CC=CC=C1C=C MYRTYDVEIRVNKP-UHFFFAOYSA-N 0.000 description 2
- ZGHFDIIVVIFNPS-UHFFFAOYSA-N 3-Methyl-3-buten-2-one Chemical compound CC(=C)C(C)=O ZGHFDIIVVIFNPS-UHFFFAOYSA-N 0.000 description 2
- CSCPPACGZOOCGX-UHFFFAOYSA-N Acetone Chemical compound CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 description 2
- NLHHRLWOUZZQLW-UHFFFAOYSA-N Acrylonitrile Chemical compound C=CC#N NLHHRLWOUZZQLW-UHFFFAOYSA-N 0.000 description 2
- 244000043261 Hevea brasiliensis Species 0.000 description 2
- 239000005062 Polybutadiene Substances 0.000 description 2
- 239000000654 additive Substances 0.000 description 2
- 238000005452 bending Methods 0.000 description 2
- 239000013065 commercial product Substances 0.000 description 2
- 239000000806 elastomer Substances 0.000 description 2
- 238000001125 extrusion Methods 0.000 description 2
- 229920000578 graft copolymer Polymers 0.000 description 2
- 125000004435 hydrogen atom Chemical group [H]* 0.000 description 2
- 239000000463 material Substances 0.000 description 2
- 229920003052 natural elastomer Polymers 0.000 description 2
- 229920001194 natural rubber Polymers 0.000 description 2
- 230000000704 physical effect Effects 0.000 description 2
- 229920002285 poly(styrene-co-acrylonitrile) Polymers 0.000 description 2
- 229920000642 polymer Polymers 0.000 description 2
- 238000006116 polymerization reaction Methods 0.000 description 2
- 125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 description 2
- KGIGUEBEKRSTEW-UHFFFAOYSA-N 2-vinylpyridine Chemical compound C=CC1=CC=CC=N1 KGIGUEBEKRSTEW-UHFFFAOYSA-N 0.000 description 1
- 229920001368 Crepe rubber Polymers 0.000 description 1
- VVQNEPGJFQJSBK-UHFFFAOYSA-N Methyl methacrylate Chemical compound COC(=O)C(C)=C VVQNEPGJFQJSBK-UHFFFAOYSA-N 0.000 description 1
- 229920007962 Styrene Methyl Methacrylate Polymers 0.000 description 1
- 229920006328 Styrofoam Polymers 0.000 description 1
- 125000000217 alkyl group Chemical group 0.000 description 1
- XYLMUPLGERFSHI-UHFFFAOYSA-N alpha-Methylstyrene Chemical compound CC(=C)C1=CC=CC=C1 XYLMUPLGERFSHI-UHFFFAOYSA-N 0.000 description 1
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 1
- 229910052782 aluminium Inorganic materials 0.000 description 1
- MPMBRWOOISTHJV-UHFFFAOYSA-N but-1-enylbenzene Chemical compound CCC=CC1=CC=CC=C1 MPMBRWOOISTHJV-UHFFFAOYSA-N 0.000 description 1
- MTAZNLWOLGHBHU-UHFFFAOYSA-N butadiene-styrene rubber Chemical compound C=CC=C.C=CC1=CC=CC=C1 MTAZNLWOLGHBHU-UHFFFAOYSA-N 0.000 description 1
- 125000004432 carbon atom Chemical group C* 0.000 description 1
- 125000003178 carboxy group Chemical group [H]OC(*)=O 0.000 description 1
- 239000003054 catalyst Substances 0.000 description 1
- 238000005119 centrifugation Methods 0.000 description 1
- 239000012986 chain transfer agent Substances 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 238000000748 compression moulding Methods 0.000 description 1
- 230000006866 deterioration Effects 0.000 description 1
- 239000012895 dilution Substances 0.000 description 1
- 238000010790 dilution Methods 0.000 description 1
- 238000001035 drying Methods 0.000 description 1
- 238000007720 emulsion polymerization reaction Methods 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 239000000835 fiber Substances 0.000 description 1
- 239000010419 fine particle Substances 0.000 description 1
- 239000003063 flame retardant Substances 0.000 description 1
- 238000005227 gel permeation chromatography Methods 0.000 description 1
- 239000011521 glass Substances 0.000 description 1
- 239000008187 granular material Substances 0.000 description 1
- 229910052736 halogen Inorganic materials 0.000 description 1
- 125000005843 halogen group Chemical group 0.000 description 1
- 150000002367 halogens Chemical class 0.000 description 1
- 239000002638 heterogeneous catalyst Substances 0.000 description 1
- 229910052739 hydrogen Inorganic materials 0.000 description 1
- 239000001257 hydrogen Substances 0.000 description 1
- 125000002887 hydroxy group Chemical group [H]O* 0.000 description 1
- 230000001771 impaired effect Effects 0.000 description 1
- 238000001746 injection moulding Methods 0.000 description 1
- 150000002576 ketones Chemical class 0.000 description 1
- ADFPJHOAARPYLP-UHFFFAOYSA-N methyl 2-methylprop-2-enoate;styrene Chemical compound COC(=O)C(C)=C.C=CC1=CC=CC=C1 ADFPJHOAARPYLP-UHFFFAOYSA-N 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 239000000049 pigment Substances 0.000 description 1
- 239000004014 plasticizer Substances 0.000 description 1
- 229920001596 poly (chlorostyrenes) Polymers 0.000 description 1
- 229920001084 poly(chloroprene) Polymers 0.000 description 1
- 229920001195 polyisoprene Polymers 0.000 description 1
- 238000001556 precipitation Methods 0.000 description 1
- 239000012763 reinforcing filler Substances 0.000 description 1
- 239000000243 solution Substances 0.000 description 1
- 239000003381 stabilizer Substances 0.000 description 1
- 238000010561 standard procedure Methods 0.000 description 1
- 239000008261 styrofoam Substances 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 239000000725 suspension Substances 0.000 description 1
- 238000010557 suspension polymerization reaction Methods 0.000 description 1
- 229920001897 terpolymer Polymers 0.000 description 1
- 229910052719 titanium Inorganic materials 0.000 description 1
- 239000010936 titanium Substances 0.000 description 1
- -1 titanium halides Chemical class 0.000 description 1
- 125000004417 unsaturated alkyl group Chemical group 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L51/00—Compositions of graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers
- C08L51/003—Compositions of graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers grafted on to macromolecular compounds obtained by reactions only involving unsaturated carbon-to-carbon bonds
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L25/00—Compositions of, homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an aromatic carbocyclic ring; Compositions of derivatives of such polymers
- C08L25/02—Homopolymers or copolymers of hydrocarbons
- C08L25/04—Homopolymers or copolymers of styrene
- C08L25/06—Polystyrene
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L51/00—Compositions of graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers
- C08L51/04—Compositions of graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers grafted on to rubbers
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L71/00—Compositions of polyethers obtained by reactions forming an ether link in the main chain; Compositions of derivatives of such polymers
- C08L71/08—Polyethers derived from hydroxy compounds or from their metallic derivatives
- C08L71/10—Polyethers derived from hydroxy compounds or from their metallic derivatives from phenols
- C08L71/12—Polyphenylene oxides
- C08L71/123—Polyphenylene oxides not modified by chemical after-treatment
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L21/00—Compositions of unspecified rubbers
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L71/00—Compositions of polyethers obtained by reactions forming an ether link in the main chain; Compositions of derivatives of such polymers
- C08L71/08—Polyethers derived from hydroxy compounds or from their metallic derivatives
- C08L71/10—Polyethers derived from hydroxy compounds or from their metallic derivatives from phenols
- C08L71/12—Polyphenylene oxides
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10S525/00—Synthetic resins or natural rubbers -- part of the class 520 series
- Y10S525/905—Polyphenylene oxide
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10S525/00—Synthetic resins or natural rubbers -- part of the class 520 series
- Y10S525/912—Polymer from nonethylenic monomers only, having pendant unsaturated group
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Compositions Of Macromolecular Compounds (AREA)
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US00183630A US3819761A (en) | 1971-09-24 | 1971-09-24 | High impact strength thermoplastic compositions |
Publications (3)
| Publication Number | Publication Date |
|---|---|
| DE2265147A1 DE2265147A1 (de) | 1976-06-16 |
| DE2265147B2 DE2265147B2 (de) | 1979-03-08 |
| DE2265147C3 true DE2265147C3 (de) | 1979-11-15 |
Family
ID=22673653
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| DE2265147A Expired DE2265147C3 (de) | 1971-09-24 | 1972-09-22 | Hochschlagzähe thermoplastische Massen |
Country Status (8)
| Country | Link |
|---|---|
| US (1) | US3819761A (enExample) |
| JP (2) | JPS5741499B2 (enExample) |
| AU (1) | AU471653B2 (enExample) |
| DE (1) | DE2265147C3 (enExample) |
| FR (1) | FR2153409B1 (enExample) |
| GB (1) | GB1391974A (enExample) |
| IT (1) | IT967758B (enExample) |
| NL (1) | NL175310C (enExample) |
Families Citing this family (15)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4203931A (en) * | 1976-03-29 | 1980-05-20 | General Electric Company | Flame retardant thermoplastic polyphenylene ether resin compositions |
| US4101503A (en) * | 1977-04-13 | 1978-07-18 | General Electric Company | Compositions of a polyphenylene ether resin and high molecular weight alkenyl aromatic resins modified with EPDM rubber |
| JPS5812304B2 (ja) * | 1980-09-16 | 1983-03-07 | 旭化成株式会社 | 芳香族ポリエ−テル樹脂組成物 |
| JPS6084356A (ja) * | 1983-10-13 | 1985-05-13 | Mitsubishi Gas Chem Co Inc | 高耐衝撃性ポリフエニレンエ−テル系樹脂組成物 |
| JPS60181416U (ja) * | 1984-05-09 | 1985-12-02 | ヤンマー農機株式会社 | 除雪機 |
| CA1300784C (en) * | 1986-11-07 | 1992-05-12 | Ge Chemicals, Inc. | Phenylene ether resin based thermoplastic compositions |
| US4833223A (en) * | 1987-12-14 | 1989-05-23 | Borg-Warner Chemicals, Inc. | High molecular weight polystyrene and method |
| US4804712A (en) * | 1987-11-23 | 1989-02-14 | The Dow Chemical Company | Polyphenylene ether/polystyrene blends |
| US4900786A (en) * | 1988-06-23 | 1990-02-13 | General Electric Company | Polyphenylene ether/rubber modified polystyrene composition suitable for blow molding large parts |
| US5008314A (en) * | 1989-12-21 | 1991-04-16 | General Electric Co. | Polyphenylene ether compositions resistant to environmental stress cracking |
| JPH05501121A (ja) * | 1991-01-23 | 1993-03-04 | ゼネラル・エレクトリック・カンパニイ | 環境応力亀裂に対して抵抗性のポリフェニレンエーテル組成物 |
| US5235001A (en) * | 1991-08-26 | 1993-08-10 | Eastman Kodak Company | Polyester/polyphenylene ether blends |
| JPH09157488A (ja) * | 1995-12-12 | 1997-06-17 | Nippon G Ii Plast Kk | 自動車部品用熱可塑性樹脂組成物 |
| US6096821A (en) * | 1999-04-02 | 2000-08-01 | General Electric Company | Polyphenylene ether resin concentrates |
| US10882940B2 (en) * | 2016-04-29 | 2021-01-05 | Sabic Global Technologies B.V. | Process for the production of copolymers |
-
1971
- 1971-09-24 US US00183630A patent/US3819761A/en not_active Expired - Lifetime
-
1972
- 1972-09-07 AU AU46436/72A patent/AU471653B2/en not_active Expired
- 1972-09-20 GB GB4364472A patent/GB1391974A/en not_active Expired
- 1972-09-21 NL NLAANVRAGE7212764,A patent/NL175310C/xx not_active IP Right Cessation
- 1972-09-22 DE DE2265147A patent/DE2265147C3/de not_active Expired
- 1972-09-22 IT IT29546/72A patent/IT967758B/it active
- 1972-09-22 FR FR7233636A patent/FR2153409B1/fr not_active Expired
- 1972-09-25 JP JP47095240A patent/JPS5741499B2/ja not_active Expired
-
1981
- 1981-10-30 JP JP56173185A patent/JPS595618B2/ja not_active Expired
Also Published As
| Publication number | Publication date |
|---|---|
| DE2265147B2 (de) | 1979-03-08 |
| AU4643672A (en) | 1974-03-14 |
| JPS5741499B2 (enExample) | 1982-09-03 |
| JPS595618B2 (ja) | 1984-02-06 |
| GB1391974A (en) | 1975-04-23 |
| FR2153409A1 (enExample) | 1973-05-04 |
| NL175310B (nl) | 1984-05-16 |
| JPS57108148A (en) | 1982-07-06 |
| NL175310C (nl) | 1984-10-16 |
| US3819761A (en) | 1974-06-25 |
| JPS4842047A (enExample) | 1973-06-19 |
| DE2246713A1 (de) | 1973-03-29 |
| DE2265147A1 (de) | 1976-06-16 |
| FR2153409B1 (enExample) | 1978-08-18 |
| DE2246713B2 (de) | 1976-08-26 |
| IT967758B (it) | 1974-03-11 |
| AU471653B2 (en) | 1976-04-29 |
| NL7212764A (enExample) | 1973-03-27 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C3 | Grant after two publication steps (3rd publication) | ||
| 8328 | Change in the person/name/address of the agent |
Free format text: SCHUELER, H., DIPL.-CHEM. DR.RER.NAT., PAT.-ANW., 6000 FRANKFURT |