DE2229542A1 - Verfahren zur katalytischen polymerisation und kopolymerisation von olefinen - Google Patents
Verfahren zur katalytischen polymerisation und kopolymerisation von olefinenInfo
- Publication number
- DE2229542A1 DE2229542A1 DE19722229542 DE2229542A DE2229542A1 DE 2229542 A1 DE2229542 A1 DE 2229542A1 DE 19722229542 DE19722229542 DE 19722229542 DE 2229542 A DE2229542 A DE 2229542A DE 2229542 A1 DE2229542 A1 DE 2229542A1
- Authority
- DE
- Germany
- Prior art keywords
- vcl
- polymerization
- sicl
- copolymerization
- olefins
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 238000006116 polymerization reaction Methods 0.000 title claims description 25
- 230000003197 catalytic effect Effects 0.000 title claims description 16
- 238000000034 method Methods 0.000 title claims description 14
- 238000007334 copolymerization reaction Methods 0.000 title claims description 9
- 150000001336 alkenes Chemical class 0.000 title claims description 8
- 239000002904 solvent Substances 0.000 claims description 13
- 239000000460 chlorine Substances 0.000 claims description 9
- 230000008569 process Effects 0.000 claims description 9
- 229930195733 hydrocarbon Natural products 0.000 claims description 7
- 239000004215 Carbon black (E152) Substances 0.000 claims description 6
- 150000002430 hydrocarbons Chemical class 0.000 claims description 6
- ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 claims description 5
- 229910052801 chlorine Inorganic materials 0.000 claims description 5
- 150000002736 metal compounds Chemical class 0.000 claims description 3
- 229920000642 polymer Polymers 0.000 description 21
- 239000003054 catalyst Substances 0.000 description 12
- 239000000243 solution Substances 0.000 description 8
- IMNFDUFMRHMDMM-UHFFFAOYSA-N N-Heptane Chemical compound CCCCCCC IMNFDUFMRHMDMM-UHFFFAOYSA-N 0.000 description 7
- 239000000178 monomer Substances 0.000 description 7
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 description 6
- 239000005977 Ethylene Substances 0.000 description 6
- KFZMGEQAYNKOFK-UHFFFAOYSA-N Isopropanol Chemical compound CC(C)O KFZMGEQAYNKOFK-UHFFFAOYSA-N 0.000 description 6
- 238000006243 chemical reaction Methods 0.000 description 6
- 238000004519 manufacturing process Methods 0.000 description 6
- VLKZOEOYAKHREP-UHFFFAOYSA-N n-Hexane Chemical compound CCCCCC VLKZOEOYAKHREP-UHFFFAOYSA-N 0.000 description 6
- 229920001577 copolymer Polymers 0.000 description 5
- -1 Polyethylene Polymers 0.000 description 4
- 150000001875 compounds Chemical class 0.000 description 4
- 239000000945 filler Substances 0.000 description 4
- UHOVQNZJYSORNB-UHFFFAOYSA-N Benzene Chemical compound C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 description 3
- 239000004698 Polyethylene Substances 0.000 description 3
- 230000015572 biosynthetic process Effects 0.000 description 3
- 150000001805 chlorine compounds Chemical class 0.000 description 3
- 238000000354 decomposition reaction Methods 0.000 description 3
- 150000001993 dienes Chemical class 0.000 description 3
- 229920000573 polyethylene Polymers 0.000 description 3
- AZDRQVAHHNSJOQ-UHFFFAOYSA-N alumane Chemical class [AlH3] AZDRQVAHHNSJOQ-UHFFFAOYSA-N 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 239000012535 impurity Substances 0.000 description 2
- 229910052751 metal Inorganic materials 0.000 description 2
- 239000002184 metal Substances 0.000 description 2
- 239000003607 modifier Substances 0.000 description 2
- 239000000047 product Substances 0.000 description 2
- QQONPFPTGQHPMA-UHFFFAOYSA-N propylene Natural products CC=C QQONPFPTGQHPMA-UHFFFAOYSA-N 0.000 description 2
- 125000004805 propylene group Chemical group [H]C([H])([H])C([H])([*:1])C([H])([H])[*:2] 0.000 description 2
- 229920006395 saturated elastomer Polymers 0.000 description 2
- 230000035945 sensitivity Effects 0.000 description 2
- 238000005406 washing Methods 0.000 description 2
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 2
- VYZAMTAEIAYCRO-UHFFFAOYSA-N Chromium Chemical compound [Cr] VYZAMTAEIAYCRO-UHFFFAOYSA-N 0.000 description 1
- 229910003902 SiCl 4 Inorganic materials 0.000 description 1
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 description 1
- 229910021552 Vanadium(IV) chloride Inorganic materials 0.000 description 1
- QCWXUUIWCKQGHC-UHFFFAOYSA-N Zirconium Chemical compound [Zr] QCWXUUIWCKQGHC-UHFFFAOYSA-N 0.000 description 1
- 125000005595 acetylacetonate group Chemical group 0.000 description 1
- 238000007792 addition Methods 0.000 description 1
- 239000000654 additive Substances 0.000 description 1
- 125000000217 alkyl group Chemical group 0.000 description 1
- 229910052782 aluminium Inorganic materials 0.000 description 1
- 229910002056 binary alloy Inorganic materials 0.000 description 1
- 230000033558 biomineral tissue development Effects 0.000 description 1
- 239000006227 byproduct Substances 0.000 description 1
- 230000008859 change Effects 0.000 description 1
- 150000001804 chlorine Chemical class 0.000 description 1
- 229910052804 chromium Inorganic materials 0.000 description 1
- 239000011651 chromium Substances 0.000 description 1
- 239000000571 coke Substances 0.000 description 1
- 239000000539 dimer Substances 0.000 description 1
- 239000012153 distilled water Substances 0.000 description 1
- 239000000835 fiber Substances 0.000 description 1
- 238000011049 filling Methods 0.000 description 1
- 238000005429 filling process Methods 0.000 description 1
- 239000011521 glass Substances 0.000 description 1
- 150000004820 halides Chemical class 0.000 description 1
- 239000008240 homogeneous mixture Substances 0.000 description 1
- 238000000265 homogenisation Methods 0.000 description 1
- 230000007062 hydrolysis Effects 0.000 description 1
- 238000006460 hydrolysis reaction Methods 0.000 description 1
- 238000001746 injection moulding Methods 0.000 description 1
- 238000002156 mixing Methods 0.000 description 1
- 239000000203 mixture Substances 0.000 description 1
- 239000004745 nonwoven fabric Substances 0.000 description 1
- 230000000269 nucleophilic effect Effects 0.000 description 1
- 150000002902 organometallic compounds Chemical class 0.000 description 1
- 230000000737 periodic effect Effects 0.000 description 1
- 239000004033 plastic Substances 0.000 description 1
- 229920003023 plastic Polymers 0.000 description 1
- 230000037048 polymerization activity Effects 0.000 description 1
- 229920000098 polyolefin Polymers 0.000 description 1
- 230000001681 protective effect Effects 0.000 description 1
- 238000000746 purification Methods 0.000 description 1
- 239000012429 reaction media Substances 0.000 description 1
- 230000009467 reduction Effects 0.000 description 1
- 238000011946 reduction process Methods 0.000 description 1
- 238000005096 rolling process Methods 0.000 description 1
- 238000007086 side reaction Methods 0.000 description 1
- 239000004071 soot Substances 0.000 description 1
- 230000002269 spontaneous effect Effects 0.000 description 1
- 238000003860 storage Methods 0.000 description 1
- 238000006467 substitution reaction Methods 0.000 description 1
- 229910052719 titanium Inorganic materials 0.000 description 1
- 239000010936 titanium Substances 0.000 description 1
- 229910052720 vanadium Inorganic materials 0.000 description 1
- GPPXJZIENCGNKB-UHFFFAOYSA-N vanadium Chemical compound [V]#[V] GPPXJZIENCGNKB-UHFFFAOYSA-N 0.000 description 1
- JTJFQBNJBPPZRI-UHFFFAOYSA-J vanadium tetrachloride Chemical compound Cl[V](Cl)(Cl)Cl JTJFQBNJBPPZRI-UHFFFAOYSA-J 0.000 description 1
- 125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 description 1
- 229920002554 vinyl polymer Polymers 0.000 description 1
- 229910052726 zirconium Inorganic materials 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
- Polymerisation Methods In General (AREA)
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| SU1666661A SU390105A1 (ru) | 1971-06-18 | 1971-06-18 | Способ получения карбоцепных полимеров |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| DE2229542A1 true DE2229542A1 (de) | 1973-02-22 |
Family
ID=20478262
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| DE19722229542 Pending DE2229542A1 (de) | 1971-06-18 | 1972-06-16 | Verfahren zur katalytischen polymerisation und kopolymerisation von olefinen |
Country Status (11)
| Country | Link |
|---|---|
| JP (1) | JPS4923887A (enExample) |
| BE (1) | BE785040A (enExample) |
| CS (1) | CS162154B1 (enExample) |
| DD (1) | DD97217A1 (enExample) |
| DE (1) | DE2229542A1 (enExample) |
| EG (1) | EG10552A (enExample) |
| FR (1) | FR2141989B1 (enExample) |
| GB (1) | GB1358661A (enExample) |
| IT (1) | IT961230B (enExample) |
| PL (1) | PL75676B1 (enExample) |
| SU (1) | SU390105A1 (enExample) |
-
1971
- 1971-06-18 SU SU1666661A patent/SU390105A1/ru active
-
1972
- 1972-06-13 EG EG25072A patent/EG10552A/xx active
- 1972-06-16 PL PL15607772A patent/PL75676B1/xx unknown
- 1972-06-16 DD DD16378472A patent/DD97217A1/xx unknown
- 1972-06-16 DE DE19722229542 patent/DE2229542A1/de active Pending
- 1972-06-16 BE BE785040A patent/BE785040A/xx unknown
- 1972-06-16 FR FR7221706A patent/FR2141989B1/fr not_active Expired
- 1972-06-16 CS CS423472A patent/CS162154B1/cs unknown
- 1972-06-17 IT IT2584372A patent/IT961230B/it active
- 1972-06-19 GB GB2868572A patent/GB1358661A/en not_active Expired
- 1972-06-19 JP JP6127072A patent/JPS4923887A/ja active Pending
Also Published As
| Publication number | Publication date |
|---|---|
| BE785040A (fr) | 1972-12-18 |
| JPS4923887A (enExample) | 1974-03-02 |
| PL75676B1 (enExample) | 1974-12-31 |
| EG10552A (en) | 1976-02-29 |
| GB1358661A (en) | 1974-07-03 |
| FR2141989B1 (enExample) | 1977-12-23 |
| SU390105A1 (ru) | 1973-07-11 |
| FR2141989A1 (enExample) | 1973-01-26 |
| DD97217A1 (enExample) | 1973-04-23 |
| IT961230B (it) | 1973-12-10 |
| CS162154B1 (enExample) | 1975-07-15 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| OHJ | Non-payment of the annual fee |