DE2209373C3 - Verfahren zur Herstellung eines mit Kupfer und/oder Silber überzogenen Glaskeramikgegenstandes mit zusammenhängender Überzugsschicht - Google Patents
Verfahren zur Herstellung eines mit Kupfer und/oder Silber überzogenen Glaskeramikgegenstandes mit zusammenhängender ÜberzugsschichtInfo
- Publication number
- DE2209373C3 DE2209373C3 DE2209373A DE2209373A DE2209373C3 DE 2209373 C3 DE2209373 C3 DE 2209373C3 DE 2209373 A DE2209373 A DE 2209373A DE 2209373 A DE2209373 A DE 2209373A DE 2209373 C3 DE2209373 C3 DE 2209373C3
- Authority
- DE
- Germany
- Prior art keywords
- glass
- metal
- heat treatment
- temperature
- copper
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 238000000034 method Methods 0.000 title claims description 23
- 239000002241 glass-ceramic Substances 0.000 title claims description 22
- 239000010949 copper Substances 0.000 title claims description 21
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 title claims description 18
- 229910052802 copper Inorganic materials 0.000 title claims description 18
- 230000008569 process Effects 0.000 title claims description 11
- 229910052709 silver Inorganic materials 0.000 title claims description 11
- 239000004332 silver Substances 0.000 title claims description 11
- 238000004519 manufacturing process Methods 0.000 title claims description 10
- 239000011247 coating layer Substances 0.000 title 1
- 238000010438 heat treatment Methods 0.000 claims description 62
- 239000011521 glass Substances 0.000 claims description 37
- 229910052751 metal Inorganic materials 0.000 claims description 33
- 239000002184 metal Substances 0.000 claims description 33
- 238000000576 coating method Methods 0.000 claims description 24
- 239000011248 coating agent Substances 0.000 claims description 21
- 239000002245 particle Substances 0.000 claims description 16
- 229910044991 metal oxide Inorganic materials 0.000 claims description 12
- 150000004706 metal oxides Chemical class 0.000 claims description 12
- BQCADISMDOOEFD-UHFFFAOYSA-N Silver Chemical compound [Ag] BQCADISMDOOEFD-UHFFFAOYSA-N 0.000 claims description 10
- 230000008018 melting Effects 0.000 claims description 9
- 238000002844 melting Methods 0.000 claims description 9
- 239000002667 nucleating agent Substances 0.000 claims description 9
- 230000001590 oxidative effect Effects 0.000 claims description 7
- 230000001427 coherent effect Effects 0.000 claims description 5
- 238000004031 devitrification Methods 0.000 claims description 5
- 229910021645 metal ion Inorganic materials 0.000 claims description 5
- 239000006066 glass batch Substances 0.000 claims description 4
- 239000011159 matrix material Substances 0.000 claims description 4
- 239000000155 melt Substances 0.000 claims description 4
- 239000013528 metallic particle Substances 0.000 claims description 4
- 239000002923 metal particle Substances 0.000 claims description 3
- 125000000325 methylidene group Chemical group [H]C([H])=* 0.000 claims 1
- 239000000203 mixture Substances 0.000 description 13
- 239000000047 product Substances 0.000 description 10
- 238000002474 experimental method Methods 0.000 description 9
- 150000002736 metal compounds Chemical class 0.000 description 8
- 229940100890 silver compound Drugs 0.000 description 7
- 150000003379 silver compounds Chemical class 0.000 description 7
- 238000013459 approach Methods 0.000 description 6
- 238000007496 glass forming Methods 0.000 description 6
- 150000002739 metals Chemical class 0.000 description 6
- 238000011282 treatment Methods 0.000 description 6
- 150000001875 compounds Chemical class 0.000 description 5
- 229910052760 oxygen Inorganic materials 0.000 description 5
- 230000007704 transition Effects 0.000 description 5
- 229910018068 Li 2 O Inorganic materials 0.000 description 4
- 239000007789 gas Substances 0.000 description 4
- XLOMVQKBTHCTTD-UHFFFAOYSA-N Zinc monoxide Chemical compound [Zn]=O XLOMVQKBTHCTTD-UHFFFAOYSA-N 0.000 description 3
- 238000002425 crystallisation Methods 0.000 description 3
- 230000008025 crystallization Effects 0.000 description 3
- 239000001257 hydrogen Substances 0.000 description 3
- 229910052739 hydrogen Inorganic materials 0.000 description 3
- 238000005498 polishing Methods 0.000 description 3
- 230000009467 reduction Effects 0.000 description 3
- 238000012360 testing method Methods 0.000 description 3
- 229910018072 Al 2 O 3 Inorganic materials 0.000 description 2
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 2
- 239000005749 Copper compound Substances 0.000 description 2
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 2
- ATUOYWHBWRKTHZ-UHFFFAOYSA-N Propane Chemical compound CCC ATUOYWHBWRKTHZ-UHFFFAOYSA-N 0.000 description 2
- 229910004298 SiO 2 Inorganic materials 0.000 description 2
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 2
- 239000000470 constituent Substances 0.000 description 2
- 239000013078 crystal Substances 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 239000012467 final product Substances 0.000 description 2
- 239000000463 material Substances 0.000 description 2
- VNWKTOKETHGBQD-UHFFFAOYSA-N methane Chemical compound C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 description 2
- 239000001301 oxygen Substances 0.000 description 2
- 238000007747 plating Methods 0.000 description 2
- -1 silver ions Chemical class 0.000 description 2
- SQGYOTSLMSWVJD-UHFFFAOYSA-N silver(1+) nitrate Chemical compound [Ag+].[O-]N(=O)=O SQGYOTSLMSWVJD-UHFFFAOYSA-N 0.000 description 2
- 229910004261 CaF 2 Inorganic materials 0.000 description 1
- UGFAIRIUMAVXCW-UHFFFAOYSA-N Carbon monoxide Chemical compound [O+]#[C-] UGFAIRIUMAVXCW-UHFFFAOYSA-N 0.000 description 1
- OTMSDBZUPAUEDD-UHFFFAOYSA-N Ethane Chemical compound CC OTMSDBZUPAUEDD-UHFFFAOYSA-N 0.000 description 1
- 229910019142 PO4 Inorganic materials 0.000 description 1
- 229910004283 SiO 4 Inorganic materials 0.000 description 1
- 229910021607 Silver chloride Inorganic materials 0.000 description 1
- LSNNMFCWUKXFEE-UHFFFAOYSA-N Sulfurous acid Chemical class OS(O)=O LSNNMFCWUKXFEE-UHFFFAOYSA-N 0.000 description 1
- 229910010413 TiO 2 Inorganic materials 0.000 description 1
- 238000002441 X-ray diffraction Methods 0.000 description 1
- 230000001464 adherent effect Effects 0.000 description 1
- 239000000853 adhesive Substances 0.000 description 1
- 230000001070 adhesive effect Effects 0.000 description 1
- 229910052653 anorthoclase Inorganic materials 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 239000001273 butane Substances 0.000 description 1
- NWXHSRDXUJENGJ-UHFFFAOYSA-N calcium;magnesium;dioxido(oxo)silane Chemical compound [Mg+2].[Ca+2].[O-][Si]([O-])=O.[O-][Si]([O-])=O NWXHSRDXUJENGJ-UHFFFAOYSA-N 0.000 description 1
- 239000003990 capacitor Substances 0.000 description 1
- 229910052799 carbon Inorganic materials 0.000 description 1
- 229910002091 carbon monoxide Inorganic materials 0.000 description 1
- 230000008859 change Effects 0.000 description 1
- 230000001276 controlling effect Effects 0.000 description 1
- 150000001880 copper compounds Chemical class 0.000 description 1
- 229910000365 copper sulfate Inorganic materials 0.000 description 1
- ARUVKPQLZAKDPS-UHFFFAOYSA-L copper(II) sulfate Chemical compound [Cu+2].[O-][S+2]([O-])([O-])[O-] ARUVKPQLZAKDPS-UHFFFAOYSA-L 0.000 description 1
- 230000007423 decrease Effects 0.000 description 1
- 229910052637 diopside Inorganic materials 0.000 description 1
- 238000009826 distribution Methods 0.000 description 1
- 238000010410 dusting Methods 0.000 description 1
- 238000009713 electroplating Methods 0.000 description 1
- 229910000174 eucryptite Inorganic materials 0.000 description 1
- 230000008020 evaporation Effects 0.000 description 1
- 238000001704 evaporation Methods 0.000 description 1
- 150000002222 fluorine compounds Chemical class 0.000 description 1
- 150000004820 halides Chemical class 0.000 description 1
- 239000001307 helium Substances 0.000 description 1
- 229910052734 helium Inorganic materials 0.000 description 1
- SWQJXJOGLNCZEY-UHFFFAOYSA-N helium atom Chemical compound [He] SWQJXJOGLNCZEY-UHFFFAOYSA-N 0.000 description 1
- 150000002431 hydrogen Chemical class 0.000 description 1
- 150000004679 hydroxides Chemical class 0.000 description 1
- 239000011261 inert gas Substances 0.000 description 1
- 239000004615 ingredient Substances 0.000 description 1
- 238000009434 installation Methods 0.000 description 1
- 150000002500 ions Chemical class 0.000 description 1
- 238000002955 isolation Methods 0.000 description 1
- 230000007774 longterm Effects 0.000 description 1
- 239000002932 luster Substances 0.000 description 1
- 238000005259 measurement Methods 0.000 description 1
- 150000001455 metallic ions Chemical class 0.000 description 1
- 238000013508 migration Methods 0.000 description 1
- 230000005012 migration Effects 0.000 description 1
- 239000006060 molten glass Substances 0.000 description 1
- IJDNQMDRQITEOD-UHFFFAOYSA-N n-butane Chemical compound CCCC IJDNQMDRQITEOD-UHFFFAOYSA-N 0.000 description 1
- OFBQJSOFQDEBGM-UHFFFAOYSA-N n-pentane Natural products CCCCC OFBQJSOFQDEBGM-UHFFFAOYSA-N 0.000 description 1
- 150000002823 nitrates Chemical class 0.000 description 1
- 229910052757 nitrogen Inorganic materials 0.000 description 1
- 235000021317 phosphate Nutrition 0.000 description 1
- 150000003013 phosphoric acid derivatives Chemical class 0.000 description 1
- 229910052698 phosphorus Inorganic materials 0.000 description 1
- 238000002360 preparation method Methods 0.000 description 1
- 239000001294 propane Substances 0.000 description 1
- 230000001105 regulatory effect Effects 0.000 description 1
- HKZLPVFGJNLROG-UHFFFAOYSA-M silver monochloride Chemical compound [Cl-].[Ag+] HKZLPVFGJNLROG-UHFFFAOYSA-M 0.000 description 1
- 229910001961 silver nitrate Inorganic materials 0.000 description 1
- 229910052642 spodumene Inorganic materials 0.000 description 1
- 239000007858 starting material Substances 0.000 description 1
- 150000003467 sulfuric acid derivatives Chemical class 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C17/00—Surface treatment of glass, not in the form of fibres or filaments, by coating
- C03C17/06—Surface treatment of glass, not in the form of fibres or filaments, by coating with metals
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03B—MANUFACTURE, SHAPING, OR SUPPLEMENTARY PROCESSES
- C03B32/00—Thermal after-treatment of glass products not provided for in groups C03B19/00, C03B25/00 - C03B31/00 or C03B37/00, e.g. crystallisation, eliminating gas inclusions or other impurities; Hot-pressing vitrified, non-porous, shaped glass products
- C03B32/02—Thermal crystallisation, e.g. for crystallising glass bodies into glass-ceramic articles
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C1/00—Ingredients generally applicable to manufacture of glasses, glazes, or vitreous enamels
- C03C1/002—Use of waste materials, e.g. slags
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C10/00—Devitrified glass ceramics, i.e. glass ceramics having a crystalline phase dispersed in a glassy phase and constituting at least 50% by weight of the total composition
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C10/00—Devitrified glass ceramics, i.e. glass ceramics having a crystalline phase dispersed in a glassy phase and constituting at least 50% by weight of the total composition
- C03C10/0009—Devitrified glass ceramics, i.e. glass ceramics having a crystalline phase dispersed in a glassy phase and constituting at least 50% by weight of the total composition containing silica as main constituent
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01B—CABLES; CONDUCTORS; INSULATORS; SELECTION OF MATERIALS FOR THEIR CONDUCTIVE, INSULATING OR DIELECTRIC PROPERTIES
- H01B1/00—Conductors or conductive bodies characterised by the conductive materials; Selection of materials as conductors
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C2217/00—Coatings on glass
- C03C2217/20—Materials for coating a single layer on glass
- C03C2217/25—Metals
- C03C2217/251—Al, Cu, Mg or noble metals
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C2217/00—Coatings on glass
- C03C2217/20—Materials for coating a single layer on glass
- C03C2217/25—Metals
- C03C2217/251—Al, Cu, Mg or noble metals
- C03C2217/253—Cu
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C2217/00—Coatings on glass
- C03C2217/20—Materials for coating a single layer on glass
- C03C2217/25—Metals
- C03C2217/251—Al, Cu, Mg or noble metals
- C03C2217/254—Noble metals
- C03C2217/256—Ag
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C2218/00—Methods for coating glass
- C03C2218/10—Deposition methods
- C03C2218/17—Deposition methods from a solid phase
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C2218/00—Methods for coating glass
- C03C2218/30—Aspects of methods for coating glass not covered above
- C03C2218/35—Exuding
-
- H—ELECTRICITY
- H05—ELECTRIC TECHNIQUES NOT OTHERWISE PROVIDED FOR
- H05K—PRINTED CIRCUITS; CASINGS OR CONSTRUCTIONAL DETAILS OF ELECTRIC APPARATUS; MANUFACTURE OF ASSEMBLAGES OF ELECTRICAL COMPONENTS
- H05K1/00—Printed circuits
- H05K1/02—Details
- H05K1/03—Use of materials for the substrate
- H05K1/0306—Inorganic insulating substrates, e.g. ceramic, glass
-
- H—ELECTRICITY
- H05—ELECTRIC TECHNIQUES NOT OTHERWISE PROVIDED FOR
- H05K—PRINTED CIRCUITS; CASINGS OR CONSTRUCTIONAL DETAILS OF ELECTRIC APPARATUS; MANUFACTURE OF ASSEMBLAGES OF ELECTRICAL COMPONENTS
- H05K3/00—Apparatus or processes for manufacturing printed circuits
- H05K3/10—Apparatus or processes for manufacturing printed circuits in which conductive material is applied to the insulating support in such a manner as to form the desired conductive pattern
- H05K3/105—Apparatus or processes for manufacturing printed circuits in which conductive material is applied to the insulating support in such a manner as to form the desired conductive pattern by conversion of non-conductive material on or in the support into conductive material, e.g. by using an energy beam
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Geochemistry & Mineralogy (AREA)
- General Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Ceramic Engineering (AREA)
- Crystallography & Structural Chemistry (AREA)
- Dispersion Chemistry (AREA)
- Physics & Mathematics (AREA)
- Thermal Sciences (AREA)
- Glass Compositions (AREA)
Priority Applications (4)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US00228757A US3790360A (en) | 1972-02-23 | 1972-02-23 | Process for producing metal coated glass-ceramic articles |
| GB836672A GB1341533A (US07714131-20100511-C00038.png) | 1972-02-23 | 1972-02-23 | |
| FR7206441A FR2172880B1 (US07714131-20100511-C00038.png) | 1972-02-23 | 1972-02-25 | |
| DE2209373A DE2209373C3 (de) | 1972-02-23 | 1972-02-28 | Verfahren zur Herstellung eines mit Kupfer und/oder Silber überzogenen Glaskeramikgegenstandes mit zusammenhängender Überzugsschicht |
Applications Claiming Priority (4)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US22875772A | 1972-02-23 | 1972-02-23 | |
| GB836672 | 1972-02-23 | ||
| FR7206441A FR2172880B1 (US07714131-20100511-C00038.png) | 1972-02-23 | 1972-02-25 | |
| DE2209373A DE2209373C3 (de) | 1972-02-23 | 1972-02-28 | Verfahren zur Herstellung eines mit Kupfer und/oder Silber überzogenen Glaskeramikgegenstandes mit zusammenhängender Überzugsschicht |
Publications (3)
| Publication Number | Publication Date |
|---|---|
| DE2209373A1 DE2209373A1 (de) | 1973-09-20 |
| DE2209373B2 DE2209373B2 (de) | 1974-04-04 |
| DE2209373C3 true DE2209373C3 (de) | 1974-11-21 |
Family
ID=27431435
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| DE2209373A Expired DE2209373C3 (de) | 1972-02-23 | 1972-02-28 | Verfahren zur Herstellung eines mit Kupfer und/oder Silber überzogenen Glaskeramikgegenstandes mit zusammenhängender Überzugsschicht |
Country Status (4)
| Country | Link |
|---|---|
| US (1) | US3790360A (US07714131-20100511-C00038.png) |
| DE (1) | DE2209373C3 (US07714131-20100511-C00038.png) |
| FR (1) | FR2172880B1 (US07714131-20100511-C00038.png) |
| GB (1) | GB1341533A (US07714131-20100511-C00038.png) |
Families Citing this family (25)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3914517A (en) * | 1971-02-23 | 1975-10-21 | Owens Illinois Inc | Method of forming a conductively coated crystalline glass article and product produced thereby |
| US3854919A (en) * | 1971-07-23 | 1974-12-17 | Owens Illinois Inc | Method of forming transparent glass ceramic with compression layer |
| US4001476A (en) * | 1971-09-17 | 1977-01-04 | Pilkington Brothers Limited | Manufacture of float glass |
| JPS5324966B2 (US07714131-20100511-C00038.png) * | 1972-12-25 | 1978-07-24 | ||
| FR2234239B1 (US07714131-20100511-C00038.png) * | 1973-06-25 | 1977-02-18 | Ishizuka Glass | |
| US4030903A (en) * | 1974-01-01 | 1977-06-21 | Corning Glass Works | Exuded transition metal films on glass-ceramic articles |
| JPS5912624B2 (ja) * | 1975-05-24 | 1984-03-24 | 石塚硝子 （株） | 高温用断熱材とその製造方法 |
| US4084972A (en) * | 1977-01-07 | 1978-04-18 | Corning Glass Works | Glass-ceramics with metallic iron surfaces |
| US4084973A (en) * | 1977-01-07 | 1978-04-18 | Corning Glass Works | Glass articles with hematite and/or magnetite and/or metallic iron surfaces |
| US4083727A (en) * | 1977-01-07 | 1978-04-11 | Corning Glass Works | Glass-ceramics with magnetic surface films |
| US4413061A (en) * | 1978-02-06 | 1983-11-01 | International Business Machines Corporation | Glass-ceramic structures and sintered multilayer substrates thereof with circuit patterns of gold, silver or copper |
| US4472185A (en) * | 1983-01-27 | 1984-09-18 | Corning Glass Works | Method of producing a cellular ceramic body |
| US4442175A (en) * | 1983-01-27 | 1984-04-10 | Corning Glass Works | Cellular ceramic bodies and method making same |
| US4441905A (en) * | 1983-01-27 | 1984-04-10 | Corning Glass Works | Method of forming ceramic bodies |
| US4836837A (en) * | 1987-11-16 | 1989-06-06 | Owens-Corning Fiberglas Corporation | Metal coated glass fibers |
| US4971738A (en) * | 1988-07-18 | 1990-11-20 | International Business Machines Corporation | Enhanced removal of carbon from ceramic substrate laminates |
| US5053361A (en) * | 1988-07-18 | 1991-10-01 | International Business Machines Corporation | Setter tile for use in sintering of ceramic substrate laminates |
| US5718046A (en) * | 1995-12-11 | 1998-02-17 | General Motors Corporation | Method of making a ceramic coated exhaust manifold and method |
| US6030681A (en) * | 1997-07-10 | 2000-02-29 | Raychem Corporation | Magnetic disk comprising a substrate with a cermet layer on a porcelain |
| WO2007121052A2 (en) * | 2006-04-13 | 2007-10-25 | 3M Innovative Properties Company | Metal-coated superabrasive material and methods of making the same |
| US8181483B2 (en) * | 2007-06-01 | 2012-05-22 | Schott Ag | Processes for preparing electrically-conductive glass-ceramics |
| US8241395B2 (en) * | 2007-06-11 | 2012-08-14 | Schott Corporation | Glass-ceramic membranes |
| US9139465B2 (en) | 2009-08-04 | 2015-09-22 | Lehigh University | Conductive doped metal-glass compositions and methods |
| JP7025405B2 (ja) | 2016-08-02 | 2022-02-24 | コーニング インコーポレイテッド | 反応性ガラス及びガラスセラミックの溶融方法並びにその溶融装置 |
| CN110885189B (zh) * | 2019-11-13 | 2021-12-03 | 蒙娜丽莎集团股份有限公司 | 无锆羊脂釉及使用无锆羊脂釉制得的定位晶花陶瓷砖 |
Family Cites Families (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| NL121002C (US07714131-20100511-C00038.png) * | 1960-02-29 | |||
| DE1496540B1 (de) * | 1963-02-27 | 1970-08-06 | Ishizuka Glass | Verfahren zur Erzeugung von UEberzuegen aus metallischem Kupfer und/oder Silber auf entglasten keramischen Formkoerpern |
| DE1490706A1 (de) * | 1964-11-18 | 1969-09-04 | Siemens Ag | Verfahren zum Herstellen eines elektrischen Widerstandskoerpers |
| US3490887A (en) * | 1966-03-30 | 1970-01-20 | Corning Glass Works | Ferroelectric glass-ceramics |
| US3639113A (en) * | 1969-01-31 | 1972-02-01 | Margarita Semenovna Aslanova | Method of manufacturing tape possessing semiconducting properties |
| US3704110A (en) * | 1971-05-13 | 1972-11-28 | John B Finn | Electrically conductive surface |
-
1972
- 1972-02-23 GB GB836672A patent/GB1341533A/en not_active Expired
- 1972-02-23 US US00228757A patent/US3790360A/en not_active Expired - Lifetime
- 1972-02-25 FR FR7206441A patent/FR2172880B1/fr not_active Expired
- 1972-02-28 DE DE2209373A patent/DE2209373C3/de not_active Expired
Also Published As
| Publication number | Publication date |
|---|---|
| FR2172880A1 (US07714131-20100511-C00038.png) | 1973-10-05 |
| DE2209373A1 (de) | 1973-09-20 |
| US3790360A (en) | 1974-02-05 |
| FR2172880B1 (US07714131-20100511-C00038.png) | 1977-06-17 |
| GB1341533A (US07714131-20100511-C00038.png) | 1973-12-25 |
| DE2209373B2 (de) | 1974-04-04 |
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| Date | Code | Title | Description |
|---|---|---|---|
| C3 | Grant after two publication steps (3rd publication) | ||
| E77 | Valid patent as to the heymanns-index 1977 | ||
| EHJ | Ceased/non-payment of the annual fee |