DE2145800A1 - Verfahren zur Herstellung eines Zeolith mit hohem Kieselsäuregehalt - Google Patents
Verfahren zur Herstellung eines Zeolith mit hohem KieselsäuregehaltInfo
- Publication number
- DE2145800A1 DE2145800A1 DE19712145800 DE2145800A DE2145800A1 DE 2145800 A1 DE2145800 A1 DE 2145800A1 DE 19712145800 DE19712145800 DE 19712145800 DE 2145800 A DE2145800 A DE 2145800A DE 2145800 A1 DE2145800 A1 DE 2145800A1
- Authority
- DE
- Germany
- Prior art keywords
- sodium
- slurry
- solution
- zeolite
- reaction mixture
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 title claims description 58
- 239000000377 silicon dioxide Substances 0.000 title claims description 28
- 238000000034 method Methods 0.000 title claims description 25
- HNPSIPDUKPIQMN-UHFFFAOYSA-N dioxosilane;oxo(oxoalumanyloxy)alumane Chemical compound O=[Si]=O.O=[Al]O[Al]=O HNPSIPDUKPIQMN-UHFFFAOYSA-N 0.000 title claims description 22
- 239000010457 zeolite Substances 0.000 title description 26
- 229910021536 Zeolite Inorganic materials 0.000 title description 20
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 claims description 36
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 claims description 24
- 239000004115 Sodium Silicate Substances 0.000 claims description 23
- NTHWMYGWWRZVTN-UHFFFAOYSA-N sodium silicate Chemical compound [Na+].[Na+].[O-][Si]([O-])=O NTHWMYGWWRZVTN-UHFFFAOYSA-N 0.000 claims description 23
- 229910052911 sodium silicate Inorganic materials 0.000 claims description 23
- 239000000203 mixture Substances 0.000 claims description 21
- ANBBXQWFNXMHLD-UHFFFAOYSA-N aluminum;sodium;oxygen(2-) Chemical compound [O-2].[O-2].[Na+].[Al+3] ANBBXQWFNXMHLD-UHFFFAOYSA-N 0.000 claims description 15
- 229910001388 sodium aluminate Inorganic materials 0.000 claims description 15
- BPQQTUXANYXVAA-UHFFFAOYSA-N Orthosilicate Chemical compound [O-][Si]([O-])([O-])[O-] BPQQTUXANYXVAA-UHFFFAOYSA-N 0.000 claims description 13
- 239000011734 sodium Substances 0.000 claims description 12
- 238000004519 manufacturing process Methods 0.000 claims description 11
- 239000002253 acid Substances 0.000 claims description 10
- 239000011541 reaction mixture Substances 0.000 claims description 10
- 235000012239 silicon dioxide Nutrition 0.000 claims description 10
- 238000002156 mixing Methods 0.000 claims description 7
- 238000005216 hydrothermal crystallization Methods 0.000 claims description 4
- 239000007858 starting material Substances 0.000 claims description 4
- 229910000323 aluminium silicate Inorganic materials 0.000 claims description 2
- 239000002002 slurry Substances 0.000 description 27
- 239000002054 inoculum Substances 0.000 description 16
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 14
- 229910001868 water Inorganic materials 0.000 description 14
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 description 12
- 238000002425 crystallisation Methods 0.000 description 10
- 230000008025 crystallization Effects 0.000 description 10
- 239000000047 product Substances 0.000 description 9
- 239000002245 particle Substances 0.000 description 8
- 238000003756 stirring Methods 0.000 description 8
- 229910004298 SiO 2 Inorganic materials 0.000 description 7
- 239000000126 substance Substances 0.000 description 7
- TWNQGVIAIRXVLR-UHFFFAOYSA-N oxo(oxoalumanyloxy)alumane Chemical compound O=[Al]O[Al]=O TWNQGVIAIRXVLR-UHFFFAOYSA-N 0.000 description 6
- 210000001280 germinal center Anatomy 0.000 description 5
- 230000032683 aging Effects 0.000 description 4
- 150000004645 aluminates Chemical class 0.000 description 4
- BFNBIHQBYMNNAN-UHFFFAOYSA-N ammonium sulfate Chemical compound N.N.OS(O)(=O)=O BFNBIHQBYMNNAN-UHFFFAOYSA-N 0.000 description 4
- 229910052921 ammonium sulfate Inorganic materials 0.000 description 4
- 235000011130 ammonium sulphate Nutrition 0.000 description 4
- 230000015572 biosynthetic process Effects 0.000 description 4
- 239000013078 crystal Substances 0.000 description 4
- UOCIZHQMWNPGEN-UHFFFAOYSA-N dialuminum;oxygen(2-);trihydrate Chemical compound O.O.O.[O-2].[O-2].[O-2].[Al+3].[Al+3] UOCIZHQMWNPGEN-UHFFFAOYSA-N 0.000 description 4
- 230000035784 germination Effects 0.000 description 4
- KKCBUQHMOMHUOY-UHFFFAOYSA-N sodium oxide Chemical compound [O-2].[Na+].[Na+] KKCBUQHMOMHUOY-UHFFFAOYSA-N 0.000 description 4
- 229910001948 sodium oxide Inorganic materials 0.000 description 4
- 229910018072 Al 2 O 3 Inorganic materials 0.000 description 3
- 238000002441 X-ray diffraction Methods 0.000 description 3
- 238000006243 chemical reaction Methods 0.000 description 3
- 239000012013 faujasite Substances 0.000 description 3
- 238000010899 nucleation Methods 0.000 description 3
- 230000006911 nucleation Effects 0.000 description 3
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 2
- 229910000503 Na-aluminosilicate Inorganic materials 0.000 description 2
- PMZURENOXWZQFD-UHFFFAOYSA-L Sodium Sulfate Chemical compound [Na+].[Na+].[O-]S([O-])(=O)=O PMZURENOXWZQFD-UHFFFAOYSA-L 0.000 description 2
- 238000000605 extraction Methods 0.000 description 2
- 238000010438 heat treatment Methods 0.000 description 2
- 229910052500 inorganic mineral Inorganic materials 0.000 description 2
- 239000011707 mineral Substances 0.000 description 2
- 238000006386 neutralization reaction Methods 0.000 description 2
- 238000002360 preparation method Methods 0.000 description 2
- RMAQACBXLXPBSY-UHFFFAOYSA-N silicic acid Chemical compound O[Si](O)(O)O RMAQACBXLXPBSY-UHFFFAOYSA-N 0.000 description 2
- 229910052708 sodium Inorganic materials 0.000 description 2
- 239000000429 sodium aluminium silicate Substances 0.000 description 2
- 235000012217 sodium aluminium silicate Nutrition 0.000 description 2
- URGAHOPLAPQHLN-UHFFFAOYSA-N sodium aluminosilicate Chemical compound [Na+].[Al+3].[O-][Si]([O-])=O.[O-][Si]([O-])=O URGAHOPLAPQHLN-UHFFFAOYSA-N 0.000 description 2
- 229910052938 sodium sulfate Inorganic materials 0.000 description 2
- 235000011152 sodium sulphate Nutrition 0.000 description 2
- 238000003786 synthesis reaction Methods 0.000 description 2
- 229960005486 vaccine Drugs 0.000 description 2
- 241001460678 Napo <wasp> Species 0.000 description 1
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 description 1
- 150000008043 acidic salts Chemical class 0.000 description 1
- 238000013019 agitation Methods 0.000 description 1
- 238000009835 boiling Methods 0.000 description 1
- 239000003054 catalyst Substances 0.000 description 1
- 239000007795 chemical reaction product Substances 0.000 description 1
- 238000001816 cooling Methods 0.000 description 1
- 238000007865 diluting Methods 0.000 description 1
- 238000004090 dissolution Methods 0.000 description 1
- 238000001035 drying Methods 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 239000000499 gel Substances 0.000 description 1
- 230000009931 harmful effect Effects 0.000 description 1
- 239000004615 ingredient Substances 0.000 description 1
- 238000011081 inoculation Methods 0.000 description 1
- 230000008520 organization Effects 0.000 description 1
- 230000020477 pH reduction Effects 0.000 description 1
- 239000002243 precursor Substances 0.000 description 1
- 238000005086 pumping Methods 0.000 description 1
- 239000000376 reactant Substances 0.000 description 1
- 230000008929 regeneration Effects 0.000 description 1
- 238000011069 regeneration method Methods 0.000 description 1
- 229910002027 silica gel Inorganic materials 0.000 description 1
- 239000000741 silica gel Substances 0.000 description 1
- 229910052710 silicon Inorganic materials 0.000 description 1
- 239000010703 silicon Substances 0.000 description 1
- LIVNPJMFVYWSIS-UHFFFAOYSA-N silicon monoxide Chemical compound [Si-]#[O+] LIVNPJMFVYWSIS-UHFFFAOYSA-N 0.000 description 1
- 229910052814 silicon oxide Inorganic materials 0.000 description 1
- 238000001179 sorption measurement Methods 0.000 description 1
- 230000002194 synthesizing effect Effects 0.000 description 1
- 238000005406 washing Methods 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B33/00—Silicon; Compounds thereof
- C01B33/20—Silicates
- C01B33/26—Aluminium-containing silicates, i.e. silico-aluminates
- C01B33/28—Base exchange silicates, e.g. zeolites
- C01B33/2807—Zeolitic silicoaluminates with a tridimensional crystalline structure possessing molecular sieve properties; Isomorphous compounds wherein a part of the aluminium ore of the silicon present may be replaced by other elements such as gallium, germanium, phosphorus; Preparation of zeolitic molecular sieves from molecular sieves of another type or from preformed reacting mixtures
- C01B33/2838—Zeolitic silicoaluminates with a tridimensional crystalline structure possessing molecular sieve properties; Isomorphous compounds wherein a part of the aluminium ore of the silicon present may be replaced by other elements such as gallium, germanium, phosphorus; Preparation of zeolitic molecular sieves from molecular sieves of another type or from preformed reacting mixtures of faujasite type, or type X or Y (UNION CARBIDE trade names; correspond to GRACE's types Z-14 and Z-14HS, respectively)
- C01B33/2853—Zeolitic silicoaluminates with a tridimensional crystalline structure possessing molecular sieve properties; Isomorphous compounds wherein a part of the aluminium ore of the silicon present may be replaced by other elements such as gallium, germanium, phosphorus; Preparation of zeolitic molecular sieves from molecular sieves of another type or from preformed reacting mixtures of faujasite type, or type X or Y (UNION CARBIDE trade names; correspond to GRACE's types Z-14 and Z-14HS, respectively) of type Y
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10S423/00—Chemistry of inorganic compounds
- Y10S423/21—Faujasite, e.g. X, Y, CZS-3, ECR-4, Z-14HS, VHP-R
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Life Sciences & Earth Sciences (AREA)
- General Life Sciences & Earth Sciences (AREA)
- Geology (AREA)
- Inorganic Chemistry (AREA)
- Silicates, Zeolites, And Molecular Sieves (AREA)
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US7287270A | 1970-09-16 | 1970-09-16 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| DE2145800A1 true DE2145800A1 (de) | 1972-03-23 |
Family
ID=22110251
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| DE19712145800 Pending DE2145800A1 (de) | 1970-09-16 | 1971-09-14 | Verfahren zur Herstellung eines Zeolith mit hohem Kieselsäuregehalt |
Country Status (5)
| Country | Link |
|---|---|
| US (1) | US3671191A (enExample) |
| CA (1) | CA990264A (enExample) |
| DE (1) | DE2145800A1 (enExample) |
| FR (1) | FR2107769A5 (enExample) |
| GB (1) | GB1348527A (enExample) |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE3311339A1 (de) * | 1983-03-29 | 1984-10-11 | Degussa Ag, 6000 Frankfurt | Verfahren zur herstellung einer impfmischung fuer die faujasit-synthese |
| DE3538416A1 (de) * | 1985-10-29 | 1987-05-07 | Degussa | Verfahren zur herstellung einer impfmischung fuer die faujasit-synthese |
Families Citing this family (28)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3886094A (en) * | 1972-12-22 | 1975-05-27 | Grace W R & Co | Preparation of hydrocarbon conversion catalysts |
| US5102644A (en) * | 1973-12-13 | 1992-04-07 | Mobil Oil Corporation | Method for producing zeolites |
| US4199556A (en) * | 1973-12-13 | 1980-04-22 | Mobil Oil Corporation | Method for producing zeolites |
| US4175114A (en) * | 1973-12-13 | 1979-11-20 | Mobil Oil Corporation | Method for producing zeolites |
| US4166099A (en) * | 1974-04-20 | 1979-08-28 | W. R. Grace & Co. | Preparation of zeolites |
| DE2533614C2 (de) * | 1975-07-26 | 1985-10-31 | Degussa Ag, 6000 Frankfurt | Verfahren zur Herstellung von zeolithischen Alkalialuminiumsilikaten |
| US4178352A (en) * | 1976-01-30 | 1979-12-11 | W. R. Grace & Co. | Synthesis of type Y zeolite |
| US4340573A (en) * | 1979-01-03 | 1982-07-20 | W. R. Grace & Co. | Preparation of zeolites |
| US4235753A (en) * | 1979-03-16 | 1980-11-25 | Engelhard Minerals & Chemicals Corporation | Zeolitized composite bodies and manufacture thereof |
| US4877514A (en) * | 1981-12-07 | 1989-10-31 | Ashland Oil, Inc. | Carbo-metallic oil conversion process and catalysts |
| US4612298A (en) * | 1981-12-07 | 1986-09-16 | Ashland Oil, Inc. | Carbo-metallic oil conversion catalysts |
| USH282H (en) | 1982-12-27 | 1987-06-02 | W. R. Grace & Co. | High silica/alumina ratio faujasite type NaY |
| US4965059A (en) * | 1984-05-04 | 1990-10-23 | Exxon Research & Engineering Company | High silica faujasite aluminosilicate, ECR-4, and a process for making it |
| US4931267A (en) * | 1987-11-19 | 1990-06-05 | Exxon Research And Engineering Company | Process for preparing a high silica zeolite having the faujasite topology, ECR-32 |
| DE3806932A1 (de) * | 1988-03-03 | 1989-09-14 | Vaw Ver Aluminium Werke Ag | Verfahren zur modifizierung eines zeoliths |
| US6284218B1 (en) * | 1998-09-23 | 2001-09-04 | Indian Oil Corporation Limited | Process for preparing an hydrothermally stable, large crystallite sized, highly crystallite sized, highly crystalline synthetic faujasite zeolite |
| US6843977B2 (en) | 2000-05-25 | 2005-01-18 | Board Of Trustees Of Michigan State University | Ultrastable porous aluminosilicate structures and compositions derived therefrom |
| US6585952B1 (en) | 2000-05-25 | 2003-07-01 | Board Of Trustees Operating Michigan State University | Ultrastable hexagonal, cubic and wormhole aluminosilicate mesostructures |
| US6746659B2 (en) | 2000-05-25 | 2004-06-08 | Board Of Trustees Of Michigan State University | Ultrastable porous aluminosilicate structures |
| CN1275855C (zh) * | 2003-03-28 | 2006-09-20 | 中国石油化工股份有限公司 | 用高岭土合成的纳米级y型沸石及其制备方法 |
| US20070059238A1 (en) * | 2004-01-16 | 2007-03-15 | Thakur Ram M | Process for enhancing yield of sodium aluminosilicate molecular sieves during synthesis |
| US20050158237A1 (en) * | 2004-01-16 | 2005-07-21 | Indian Oil Corporation Limited | Process for enhancing yield of sodium aluminosilicate molecular sieves during synthesis |
| CN101863494A (zh) * | 2010-06-23 | 2010-10-20 | 深圳市海川实业股份有限公司 | 一种以石英砂为原料制备y型沸石的方法 |
| FR3012125A1 (enExample) | 2013-10-22 | 2015-04-24 | China Petroleum & Chemical | |
| WO2016044615A1 (en) | 2014-09-17 | 2016-03-24 | University Of Houston System | A one-step method for the synthesis of high silica content zeolites in organic-free media |
| US10265687B2 (en) | 2014-12-01 | 2019-04-23 | China Petroleum & Chemical Corporation | Na—Y molecular sieve, H—Y molecular sieve, and preparation methods thereof, hydrocracking catalyst, and hydrocracking method |
| CN109502603B (zh) * | 2017-09-14 | 2021-02-19 | 北京化工大学 | 一种磁性分子筛的制备方法及得到的磁性分子筛 |
| CN110871104B (zh) * | 2018-08-29 | 2022-10-21 | 中国石油化工股份有限公司 | 一种多孔催化材料及其制备方法 |
-
1970
- 1970-09-16 US US72872A patent/US3671191A/en not_active Expired - Lifetime
-
1971
- 1971-05-12 CA CA112,793A patent/CA990264A/en not_active Expired
- 1971-09-13 GB GB1697371*[A patent/GB1348527A/en not_active Expired
- 1971-09-14 DE DE19712145800 patent/DE2145800A1/de active Pending
- 1971-09-16 FR FR7133455A patent/FR2107769A5/fr not_active Expired
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE3311339A1 (de) * | 1983-03-29 | 1984-10-11 | Degussa Ag, 6000 Frankfurt | Verfahren zur herstellung einer impfmischung fuer die faujasit-synthese |
| DE3538416A1 (de) * | 1985-10-29 | 1987-05-07 | Degussa | Verfahren zur herstellung einer impfmischung fuer die faujasit-synthese |
| US5154904A (en) * | 1985-10-29 | 1992-10-13 | Degussa Aktiengesellschaft | Process for the production of a seed mixture for the synthesis of faujasite |
Also Published As
| Publication number | Publication date |
|---|---|
| CA990264A (en) | 1976-06-01 |
| FR2107769A5 (enExample) | 1972-05-05 |
| US3671191A (en) | 1972-06-20 |
| GB1348527A (en) | 1974-03-20 |
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