DE2136744C3 - Verfahren zur Herstellung von Cyclohexylhydroperoxid enthaltenden Oxidationsprodukten - Google Patents
Verfahren zur Herstellung von Cyclohexylhydroperoxid enthaltenden OxidationsproduktenInfo
- Publication number
- DE2136744C3 DE2136744C3 DE2136744A DE2136744A DE2136744C3 DE 2136744 C3 DE2136744 C3 DE 2136744C3 DE 2136744 A DE2136744 A DE 2136744A DE 2136744 A DE2136744 A DE 2136744A DE 2136744 C3 DE2136744 C3 DE 2136744C3
- Authority
- DE
- Germany
- Prior art keywords
- cyclohexane
- oxygen
- oxidation
- gas
- amount
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 230000003647 oxidation Effects 0.000 title claims description 43
- 238000007254 oxidation reaction Methods 0.000 title claims description 43
- FGGJBCRKSVGDPO-UHFFFAOYSA-N hydroperoxycyclohexane Chemical compound OOC1CCCCC1 FGGJBCRKSVGDPO-UHFFFAOYSA-N 0.000 title claims description 24
- 238000000034 method Methods 0.000 title claims description 11
- 238000002360 preparation method Methods 0.000 title claims description 3
- XDTMQSROBMDMFD-UHFFFAOYSA-N Cyclohexane Chemical compound C1CCCCC1 XDTMQSROBMDMFD-UHFFFAOYSA-N 0.000 claims description 46
- 239000007789 gas Substances 0.000 claims description 35
- 229910052760 oxygen Inorganic materials 0.000 claims description 30
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 claims description 29
- 239000001301 oxygen Substances 0.000 claims description 29
- JHIVVAPYMSGYDF-UHFFFAOYSA-N cyclohexanone Chemical compound O=C1CCCCC1 JHIVVAPYMSGYDF-UHFFFAOYSA-N 0.000 claims description 26
- HPXRVTGHNJAIIH-UHFFFAOYSA-N cyclohexanol Chemical compound OC1CCCCC1 HPXRVTGHNJAIIH-UHFFFAOYSA-N 0.000 claims description 13
- 239000003054 catalyst Substances 0.000 claims description 12
- 239000007788 liquid Substances 0.000 claims description 10
- 230000036284 oxygen consumption Effects 0.000 claims description 9
- 239000000203 mixture Substances 0.000 claims description 5
- 238000009833 condensation Methods 0.000 claims description 4
- 230000005494 condensation Effects 0.000 claims description 4
- 239000002360 explosive Substances 0.000 claims description 4
- 229910017052 cobalt Inorganic materials 0.000 claims description 3
- 239000010941 cobalt Substances 0.000 claims description 3
- GUTLYIVDDKVIGB-UHFFFAOYSA-N cobalt atom Chemical compound [Co] GUTLYIVDDKVIGB-UHFFFAOYSA-N 0.000 claims description 3
- 239000011261 inert gas Substances 0.000 claims description 2
- 239000007791 liquid phase Substances 0.000 claims description 2
- 230000015572 biosynthetic process Effects 0.000 claims 1
- 239000012071 phase Substances 0.000 claims 1
- 239000002689 soil Substances 0.000 description 9
- 238000006243 chemical reaction Methods 0.000 description 8
- 230000001590 oxidative effect Effects 0.000 description 4
- 150000001336 alkenes Chemical class 0.000 description 2
- 150000001868 cobalt Chemical class 0.000 description 2
- 150000001924 cycloalkanes Chemical class 0.000 description 2
- 239000007800 oxidant agent Substances 0.000 description 2
- BOKGTLAJQHTOKE-UHFFFAOYSA-N 1,5-dihydroxynaphthalene Chemical compound C1=CC=C2C(O)=CC=CC2=C1O BOKGTLAJQHTOKE-UHFFFAOYSA-N 0.000 description 1
- -1 Cycloalkane hydroperoxide Chemical class 0.000 description 1
- MHAJPDPJQMAIIY-UHFFFAOYSA-N Hydrogen peroxide Chemical compound OO MHAJPDPJQMAIIY-UHFFFAOYSA-N 0.000 description 1
- 239000003513 alkali Substances 0.000 description 1
- 238000013459 approach Methods 0.000 description 1
- 230000001174 ascending effect Effects 0.000 description 1
- 239000002585 base Substances 0.000 description 1
- 230000002996 emotional effect Effects 0.000 description 1
- 238000004880 explosion Methods 0.000 description 1
- 229930195733 hydrocarbon Natural products 0.000 description 1
- 150000002430 hydrocarbons Chemical class 0.000 description 1
- 239000001257 hydrogen Substances 0.000 description 1
- 229910052739 hydrogen Inorganic materials 0.000 description 1
- 125000004435 hydrogen atom Chemical class [H]* 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- GEMHFKXPOCTAIP-UHFFFAOYSA-N n,n-dimethyl-n'-phenylcarbamimidoyl chloride Chemical compound CN(C)C(Cl)=NC1=CC=CC=C1 GEMHFKXPOCTAIP-UHFFFAOYSA-N 0.000 description 1
- 150000002978 peroxides Chemical class 0.000 description 1
- 238000011084 recovery Methods 0.000 description 1
- 230000000630 rising effect Effects 0.000 description 1
- 238000005070 sampling Methods 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C409/00—Peroxy compounds
- C07C409/02—Peroxy compounds the —O—O— group being bound between a carbon atom, not further substituted by oxygen atoms, and hydrogen, i.e. hydroperoxides
- C07C409/14—Peroxy compounds the —O—O— group being bound between a carbon atom, not further substituted by oxygen atoms, and hydrogen, i.e. hydroperoxides the carbon atom belonging to a ring other than a six-membered aromatic ring
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C407/00—Preparation of peroxy compounds
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C2601/00—Systems containing only non-condensed rings
- C07C2601/12—Systems containing only non-condensed rings with a six-membered ring
- C07C2601/14—The ring being saturated
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US5988870A | 1970-07-31 | 1970-07-31 |
Publications (3)
| Publication Number | Publication Date |
|---|---|
| DE2136744A1 DE2136744A1 (enExample) | 1972-02-03 |
| DE2136744B2 DE2136744B2 (de) | 1980-02-21 |
| DE2136744C3 true DE2136744C3 (de) | 1980-10-09 |
Family
ID=22025925
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| DE2136744A Expired DE2136744C3 (de) | 1970-07-31 | 1971-07-22 | Verfahren zur Herstellung von Cyclohexylhydroperoxid enthaltenden Oxidationsprodukten |
Country Status (5)
| Country | Link |
|---|---|
| JP (1) | JPS5529059B1 (enExample) |
| BE (1) | BE769798A (enExample) |
| CA (1) | CA935182A (enExample) |
| DE (1) | DE2136744C3 (enExample) |
| GB (1) | GB1353225A (enExample) |
Families Citing this family (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3987100A (en) * | 1974-04-11 | 1976-10-19 | E. I. Du Pont De Nemours And Company | Cyclohexane oxidation in the presence of binary catalysts |
| DE2951956A1 (de) * | 1979-12-22 | 1981-07-23 | Basf Ag, 6700 Ludwigshafen | Verfahren zur herstellung von gemischen aus cyclohexylhydroperoxid |
| JPH01117230A (ja) * | 1987-10-29 | 1989-05-10 | Izumi Seimitsu Kogyo Kk | 電流遮断装置 |
| DE19643154A1 (de) * | 1996-10-18 | 1998-04-23 | Basf Ag | Verfahren zur Herstellung von Oxidationsprodukten des Cyclohexans im Gegenstrom |
| CN104583163A (zh) * | 2012-07-19 | 2015-04-29 | 因温斯特技术公司 | 氧化环己烷的方法 |
Family Cites Families (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US2851496A (en) * | 1954-07-27 | 1958-09-09 | Du Pont | Preparation of oxidation products of cyclohexane |
-
1971
- 1971-06-23 CA CA116483A patent/CA935182A/en not_active Expired
- 1971-07-09 BE BE769798A patent/BE769798A/xx unknown
- 1971-07-22 DE DE2136744A patent/DE2136744C3/de not_active Expired
- 1971-07-29 GB GB3575071A patent/GB1353225A/en not_active Expired
- 1971-07-29 JP JP5646871A patent/JPS5529059B1/ja active Pending
Also Published As
| Publication number | Publication date |
|---|---|
| BE769798A (fr) | 1971-11-16 |
| JPS5529059B1 (enExample) | 1980-07-31 |
| DE2136744A1 (enExample) | 1972-02-03 |
| GB1353225A (en) | 1974-05-15 |
| DE2136744B2 (de) | 1980-02-21 |
| CA935182A (en) | 1973-10-09 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| OD | Request for examination | ||
| C3 | Grant after two publication steps (3rd publication) |