DE2115737C3 - Verfahren zur Herstellung von 1 - Aminoalkan-1,1 -diphosphonsäuren - Google Patents
Verfahren zur Herstellung von 1 - Aminoalkan-1,1 -diphosphonsäurenInfo
- Publication number
- DE2115737C3 DE2115737C3 DE2115737A DE2115737A DE2115737C3 DE 2115737 C3 DE2115737 C3 DE 2115737C3 DE 2115737 A DE2115737 A DE 2115737A DE 2115737 A DE2115737 A DE 2115737A DE 2115737 C3 DE2115737 C3 DE 2115737C3
- Authority
- DE
- Germany
- Prior art keywords
- acid
- hydrogen
- aminoalkane
- diphosphonic
- acids
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 239000002253 acid Substances 0.000 title claims description 15
- 150000007513 acids Chemical class 0.000 title claims description 14
- 238000000034 method Methods 0.000 title claims description 11
- CPELXLSAUQHCOX-UHFFFAOYSA-N Hydrogen bromide Chemical compound Br CPELXLSAUQHCOX-UHFFFAOYSA-N 0.000 claims description 19
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 claims description 17
- ISIJQEHRDSCQIU-UHFFFAOYSA-N tert-butyl 2,7-diazaspiro[4.5]decane-7-carboxylate Chemical compound C1N(C(=O)OC(C)(C)C)CCCC11CNCC1 ISIJQEHRDSCQIU-UHFFFAOYSA-N 0.000 claims description 15
- IXCSERBJSXMMFS-UHFFFAOYSA-N hydrogen chloride Substances Cl.Cl IXCSERBJSXMMFS-UHFFFAOYSA-N 0.000 claims description 13
- 229910000041 hydrogen chloride Inorganic materials 0.000 claims description 13
- 239000011541 reaction mixture Substances 0.000 claims description 13
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 10
- 229910000042 hydrogen bromide Inorganic materials 0.000 claims description 9
- 150000003857 carboxamides Chemical class 0.000 claims description 7
- 125000004432 carbon atom Chemical group C* 0.000 claims description 6
- 239000004215 Carbon black (E152) Substances 0.000 claims description 4
- 229930195733 hydrocarbon Natural products 0.000 claims description 4
- 125000003277 amino group Chemical group 0.000 claims description 3
- -1 carboxylic acid hydrochlorides Chemical class 0.000 claims description 3
- 150000001875 compounds Chemical class 0.000 claims description 3
- 150000001732 carboxylic acid derivatives Chemical class 0.000 claims description 2
- ZMXDDKWLCZADIW-UHFFFAOYSA-N N,N-Dimethylformamide Chemical compound CN(C)C=O ZMXDDKWLCZADIW-UHFFFAOYSA-N 0.000 claims 3
- 125000004435 hydrogen atom Chemical group [H]* 0.000 claims 3
- 150000002148 esters Chemical class 0.000 claims 2
- ZETHHMPKDUSZQQ-UHFFFAOYSA-N Betulafolienepentol Natural products C1C=C(C)CCC(C(C)CCC=C(C)C)C2C(OC)OC(OC)C2=C1 ZETHHMPKDUSZQQ-UHFFFAOYSA-N 0.000 claims 1
- PHSPJQZRQAJPPF-UHFFFAOYSA-N N-alpha-Methylhistamine Chemical compound CNCCC1=CN=CN1 PHSPJQZRQAJPPF-UHFFFAOYSA-N 0.000 claims 1
- OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 claims 1
- PCSMJKASWLYICJ-UHFFFAOYSA-N Succinic aldehyde Chemical compound O=CCCC=O PCSMJKASWLYICJ-UHFFFAOYSA-N 0.000 claims 1
- 150000008064 anhydrides Chemical class 0.000 claims 1
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 claims 1
- HEOKFDGOFROELJ-UHFFFAOYSA-N diacetal Natural products COc1ccc(C=C/c2cc(O)cc(OC3OC(COC(=O)c4cc(O)c(O)c(O)c4)C(O)C(O)C3O)c2)cc1O HEOKFDGOFROELJ-UHFFFAOYSA-N 0.000 claims 1
- LXCYSACZTOKNNS-UHFFFAOYSA-N diethoxy(oxo)phosphanium Chemical compound CCO[P+](=O)OCC LXCYSACZTOKNNS-UHFFFAOYSA-N 0.000 claims 1
- 150000002825 nitriles Chemical class 0.000 claims 1
- 150000007524 organic acids Chemical class 0.000 claims 1
- 235000005985 organic acids Nutrition 0.000 claims 1
- 229910052760 oxygen Inorganic materials 0.000 claims 1
- 239000001301 oxygen Substances 0.000 claims 1
- 229910052698 phosphorus Inorganic materials 0.000 claims 1
- 239000011574 phosphorus Substances 0.000 claims 1
- 239000000203 mixture Substances 0.000 description 16
- DLFVBJFMPXGRIB-UHFFFAOYSA-N Acetamide Chemical compound CC(N)=O DLFVBJFMPXGRIB-UHFFFAOYSA-N 0.000 description 6
- CSCPPACGZOOCGX-UHFFFAOYSA-N Acetone Chemical compound CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 description 6
- 239000007789 gas Substances 0.000 description 6
- 238000003756 stirring Methods 0.000 description 6
- 239000003960 organic solvent Substances 0.000 description 4
- XEKOWRVHYACXOJ-UHFFFAOYSA-N Ethyl acetate Chemical compound CCOC(C)=O XEKOWRVHYACXOJ-UHFFFAOYSA-N 0.000 description 3
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 3
- 239000007864 aqueous solution Substances 0.000 description 3
- 239000002585 base Substances 0.000 description 3
- 238000006243 chemical reaction Methods 0.000 description 3
- 239000008139 complexing agent Substances 0.000 description 3
- 150000003839 salts Chemical class 0.000 description 3
- ZRALSGWEFCBTJO-UHFFFAOYSA-N Guanidine Chemical compound NC(N)=N ZRALSGWEFCBTJO-UHFFFAOYSA-N 0.000 description 2
- JUJWROOIHBZHMG-UHFFFAOYSA-N Pyridine Chemical compound C1=CC=NC=C1 JUJWROOIHBZHMG-UHFFFAOYSA-N 0.000 description 2
- AXJDEHNQPMZKOS-UHFFFAOYSA-N acetylazanium;chloride Chemical compound [Cl-].CC([NH3+])=O AXJDEHNQPMZKOS-UHFFFAOYSA-N 0.000 description 2
- 230000002378 acidificating effect Effects 0.000 description 2
- 150000001408 amides Chemical class 0.000 description 2
- 150000001412 amines Chemical class 0.000 description 2
- 150000001768 cations Chemical class 0.000 description 2
- 238000004140 cleaning Methods 0.000 description 2
- ILRSCQWREDREME-UHFFFAOYSA-N dodecanamide Chemical compound CCCCCCCCCCCC(N)=O ILRSCQWREDREME-UHFFFAOYSA-N 0.000 description 2
- HSEMFIZWXHQJAE-UHFFFAOYSA-N hexadecanamide Chemical compound CCCCCCCCCCCCCCCC(N)=O HSEMFIZWXHQJAE-UHFFFAOYSA-N 0.000 description 2
- 229910000039 hydrogen halide Inorganic materials 0.000 description 2
- 239000012433 hydrogen halide Substances 0.000 description 2
- 239000012535 impurity Substances 0.000 description 2
- WFKAJVHLWXSISD-UHFFFAOYSA-N isobutyramide Chemical compound CC(C)C(N)=O WFKAJVHLWXSISD-UHFFFAOYSA-N 0.000 description 2
- ABLZXFCXXLZCGV-UHFFFAOYSA-N phosphonic acid group Chemical group P(O)(O)=O ABLZXFCXXLZCGV-UHFFFAOYSA-N 0.000 description 2
- 238000001556 precipitation Methods 0.000 description 2
- 239000000047 product Substances 0.000 description 2
- 239000012265 solid product Substances 0.000 description 2
- 239000007858 starting material Substances 0.000 description 2
- 238000001256 steam distillation Methods 0.000 description 2
- GPCTYPSWRBUGFH-UHFFFAOYSA-N (1-amino-1-phosphonoethyl)phosphonic acid Chemical compound OP(=O)(O)C(N)(C)P(O)(O)=O GPCTYPSWRBUGFH-UHFFFAOYSA-N 0.000 description 1
- VYIBCOSBNVFEIW-UHFFFAOYSA-N 3-phenylpropanamide Chemical compound NC(=O)CCC1=CC=CC=C1 VYIBCOSBNVFEIW-UHFFFAOYSA-N 0.000 description 1
- CHJJGSNFBQVOTG-UHFFFAOYSA-N N-methyl-guanidine Natural products CNC(N)=N CHJJGSNFBQVOTG-UHFFFAOYSA-N 0.000 description 1
- OHLUUHNLEMFGTQ-UHFFFAOYSA-N N-methylacetamide Chemical compound CNC(C)=O OHLUUHNLEMFGTQ-UHFFFAOYSA-N 0.000 description 1
- 229910019142 PO4 Inorganic materials 0.000 description 1
- QZXRHSUKCRFNQC-UHFFFAOYSA-N [NH4+].[NH4+].[O-]P(=O)OP([O-])=O Chemical class [NH4+].[NH4+].[O-]P(=O)OP([O-])=O QZXRHSUKCRFNQC-UHFFFAOYSA-N 0.000 description 1
- OJADDPKDAQXHHI-UHFFFAOYSA-N acetamide;hydron;bromide Chemical compound Br.CC(N)=O OJADDPKDAQXHHI-UHFFFAOYSA-N 0.000 description 1
- 239000000654 additive Substances 0.000 description 1
- 230000000996 additive effect Effects 0.000 description 1
- 150000001298 alcohols Chemical class 0.000 description 1
- 239000003513 alkali Substances 0.000 description 1
- 150000001447 alkali salts Chemical class 0.000 description 1
- 150000003863 ammonium salts Chemical class 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- DNSISZSEWVHGLH-UHFFFAOYSA-N butanamide Chemical compound CCCC(N)=O DNSISZSEWVHGLH-UHFFFAOYSA-N 0.000 description 1
- 125000006297 carbonyl amino group Chemical group [H]N([*:2])C([*:1])=O 0.000 description 1
- 150000001735 carboxylic acids Chemical class 0.000 description 1
- 238000005341 cation exchange Methods 0.000 description 1
- SWSQBOPZIKWTGO-UHFFFAOYSA-N dimethylaminoamidine Natural products CN(C)C(N)=N SWSQBOPZIKWTGO-UHFFFAOYSA-N 0.000 description 1
- 238000001914 filtration Methods 0.000 description 1
- 150000002430 hydrocarbons Chemical class 0.000 description 1
- 150000002431 hydrogen Chemical class 0.000 description 1
- 229910021645 metal ion Inorganic materials 0.000 description 1
- ABMDIECEEGFXNC-UHFFFAOYSA-N n-ethylpropanamide Chemical compound CCNC(=O)CC ABMDIECEEGFXNC-UHFFFAOYSA-N 0.000 description 1
- FUZZWVXGSFPDMH-UHFFFAOYSA-N n-hexanoic acid Natural products CCCCCC(O)=O FUZZWVXGSFPDMH-UHFFFAOYSA-N 0.000 description 1
- MGFYIUFZLHCRTH-UHFFFAOYSA-N nitrilotriacetic acid Chemical compound OC(=O)CN(CC(O)=O)CC(O)=O MGFYIUFZLHCRTH-UHFFFAOYSA-N 0.000 description 1
- LYRFLYHAGKPMFH-UHFFFAOYSA-N octadecanamide Chemical compound CCCCCCCCCCCCCCCCCC(N)=O LYRFLYHAGKPMFH-UHFFFAOYSA-N 0.000 description 1
- LTHCSWBWNVGEFE-UHFFFAOYSA-N octanamide Chemical compound CCCCCCCC(N)=O LTHCSWBWNVGEFE-UHFFFAOYSA-N 0.000 description 1
- IPWFJLQDVFKJDU-UHFFFAOYSA-N pentanamide Chemical compound CCCCC(N)=O IPWFJLQDVFKJDU-UHFFFAOYSA-N 0.000 description 1
- 235000021317 phosphate Nutrition 0.000 description 1
- 150000003009 phosphonic acids Chemical class 0.000 description 1
- XRBCRPZXSCBRTK-UHFFFAOYSA-N phosphonous acid Chemical compound OPO XRBCRPZXSCBRTK-UHFFFAOYSA-N 0.000 description 1
- 150000003013 phosphoric acid derivatives Chemical class 0.000 description 1
- 230000001376 precipitating effect Effects 0.000 description 1
- QLNJFJADRCOGBJ-UHFFFAOYSA-N propionamide Chemical compound CCC(N)=O QLNJFJADRCOGBJ-UHFFFAOYSA-N 0.000 description 1
- UMJSCPRVCHMLSP-UHFFFAOYSA-N pyridine Natural products COC1=CC=CN=C1 UMJSCPRVCHMLSP-UHFFFAOYSA-N 0.000 description 1
- 150000003254 radicals Chemical class 0.000 description 1
- 230000035484 reaction time Effects 0.000 description 1
- 239000002904 solvent Substances 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 239000004753 textile Substances 0.000 description 1
- 238000005406 washing Methods 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F9/00—Compounds containing elements of Groups 5 or 15 of the Periodic Table
- C07F9/02—Phosphorus compounds
- C07F9/28—Phosphorus compounds with one or more P—C bonds
- C07F9/38—Phosphonic acids [RP(=O)(OH)2]; Thiophosphonic acids ; [RP(=X1)(X2H)2(X1, X2 are each independently O, S or Se)]
- C07F9/3804—Phosphonic acids [RP(=O)(OH)2]; Thiophosphonic acids ; [RP(=X1)(X2H)2(X1, X2 are each independently O, S or Se)] not used, see subgroups
- C07F9/3839—Polyphosphonic acids
- C07F9/3873—Polyphosphonic acids containing nitrogen substituent, e.g. N.....H or N-hydrocarbon group which can be substituted by halogen or nitro(so), N.....O, N.....S, N.....C(=X)- (X =O, S), N.....N, N...C(=X)...N (X =O, S)
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Biochemistry (AREA)
- General Health & Medical Sciences (AREA)
- Molecular Biology (AREA)
Priority Applications (14)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DE2115737A DE2115737C3 (de) | 1971-03-31 | 1971-03-31 | Verfahren zur Herstellung von 1 - Aminoalkan-1,1 -diphosphonsäuren |
| NL7202859A NL7202859A (OSRAM) | 1971-03-31 | 1972-03-03 | |
| US05/235,838 US4006182A (en) | 1971-03-31 | 1972-03-16 | Process for the preparation of 1-aminoalkane-1,1-diphosphonic acids |
| YU799/72A YU35266B (en) | 1971-03-31 | 1972-03-27 | Process for obtaining 1-aminoalkane-1,1-diphosphonic acids |
| BR721823A BR7201823D0 (pt) | 1971-03-31 | 1972-03-28 | Processo para a preparacao de acidos l aminoalcano-1,1-difosfonicos |
| AT268372A AT308141B (de) | 1971-03-31 | 1972-03-28 | Verfahren zur Herstellung von 1-Aminoalkan-1,1-diphosphonsäuren |
| ES401300A ES401300A1 (es) | 1971-03-31 | 1972-03-29 | Procedimiento para la obtencion de acidos 1-aminoalcano-1,1-difosfonicos. |
| BE781462A BE781462A (fr) | 1971-03-31 | 1972-03-30 | Procede de preparation d'acides 1-aminoalcane-1,1-diphosphoniques |
| GB1495372A GB1381668A (en) | 1971-03-31 | 1972-03-30 | Process for manufacturing 1-aminoalkene 1,1-diphosphonic acids |
| ZA722181A ZA722181B (en) | 1971-03-31 | 1972-03-30 | Process for manufacturing 1-aminoalkane-1,1-diphosphonic acids |
| IT22590/72A IT954825B (it) | 1971-03-31 | 1972-03-30 | Procedimento per preparare acidi i amminoalcan i i difosfonici |
| CH484572A CH571011A5 (OSRAM) | 1971-03-31 | 1972-03-30 | |
| FR7211450A FR2132312B1 (OSRAM) | 1971-03-31 | 1972-03-31 | |
| JP3254372A JPS5530000B1 (OSRAM) | 1971-03-31 | 1972-03-31 |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DE2115737A DE2115737C3 (de) | 1971-03-31 | 1971-03-31 | Verfahren zur Herstellung von 1 - Aminoalkan-1,1 -diphosphonsäuren |
Publications (3)
| Publication Number | Publication Date |
|---|---|
| DE2115737A1 DE2115737A1 (de) | 1972-10-12 |
| DE2115737B2 DE2115737B2 (de) | 1979-01-25 |
| DE2115737C3 true DE2115737C3 (de) | 1979-11-08 |
Family
ID=5803468
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| DE2115737A Expired DE2115737C3 (de) | 1971-03-31 | 1971-03-31 | Verfahren zur Herstellung von 1 - Aminoalkan-1,1 -diphosphonsäuren |
Country Status (14)
| Country | Link |
|---|---|
| US (1) | US4006182A (OSRAM) |
| JP (1) | JPS5530000B1 (OSRAM) |
| AT (1) | AT308141B (OSRAM) |
| BE (1) | BE781462A (OSRAM) |
| BR (1) | BR7201823D0 (OSRAM) |
| CH (1) | CH571011A5 (OSRAM) |
| DE (1) | DE2115737C3 (OSRAM) |
| ES (1) | ES401300A1 (OSRAM) |
| FR (1) | FR2132312B1 (OSRAM) |
| GB (1) | GB1381668A (OSRAM) |
| IT (1) | IT954825B (OSRAM) |
| NL (1) | NL7202859A (OSRAM) |
| YU (1) | YU35266B (OSRAM) |
| ZA (1) | ZA722181B (OSRAM) |
Families Citing this family (13)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| AT352142B (de) * | 1977-03-29 | 1979-09-10 | Benckiser Knapsack Gmbh | Verfahren zur herstellung von neuen n- sulfoalkan-aminoalkanphosphonsaeuren und deren alkalisalzen |
| DE2722539C3 (de) * | 1977-05-18 | 1981-11-19 | Joh. A. Benckiser Gmbh, 6700 Ludwigshafen | Verfahren zur Herstellung der N,N-Dimethylaminomethan-diphosphonsäure |
| DE2732777C2 (de) * | 1977-07-20 | 1979-09-13 | Benckiser-Knapsack Gmbh, 6802 Ladenburg | N-Carboxyalkan-aminoalkan-polyphosphonsäuren und deren Alkalisalze sowie Verfahren zu ihrer Herstellung |
| DE2758306C3 (de) * | 1977-12-27 | 1981-05-27 | Benckiser-Knapsack Gmbh, 6802 Ladenburg | Verfahren zur Herstellung von N- Sulfoalkanaminoalkanphosphonsäuren bzw. deren Alkalisalze |
| FR2558837B1 (fr) * | 1984-01-26 | 1986-06-27 | Sanofi Sa | Derives de l'acide methylenediphosphonique, procede d'obtention et medicaments antirhumatismaux les contenant |
| DE3611522A1 (de) * | 1986-04-05 | 1987-10-08 | Henkel Kgaa | Diphosphonylierte oxonitrille, verfahren zu ihrer herstellung und ihre verwendung in mikrobistatischen zusammensetzungen sowie mikrobistatisch wirksame, diphosphonylierte oxonitrile enthaltende zusammensetzungen |
| DE3700772A1 (de) * | 1987-01-13 | 1988-07-21 | Inst Khim Kinetiki I Gorenija | Verfahren zur herstellung von i-funktionellsubstituierten alkyliden-i,i-diphosphonsaeuren und deren gemischen |
| MY129053A (en) * | 2001-06-06 | 2007-03-30 | Thermphos Trading Gmbh | Composition for inhibiting calcium salt scale |
| MY138251A (en) * | 2001-06-06 | 2009-05-29 | Thermphos Trading Gmbh | Method for inhibiting calcium salt scale |
| US6890404B2 (en) | 2001-06-06 | 2005-05-10 | Solutia, Inc. | Composition for the production of improved pulp |
| US6846419B2 (en) * | 2002-08-30 | 2005-01-25 | Johnsondiversey, Inc. | Phosphonamide and phosphonamide blend compositions and method to treat water |
| US20050104031A1 (en) * | 2003-01-21 | 2005-05-19 | Lyle Steimel | Phosphonamide and phosphonamide blend compositions and method to treat water |
| EP2289900A1 (en) * | 2009-08-26 | 2011-03-02 | Humboldt Universität zu Berlin | Bisphosphonates as inhibitors of acid sphingomyelinase |
Family Cites Families (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE1002355C2 (de) * | 1954-05-03 | 1957-07-25 | Thomae Gmbh Dr K | Verfahren zur Herstellung von ª‡-prim.-Amino-diphosphonsaeuren und deren Estern |
| DE1171401B (de) * | 1962-01-27 | 1964-06-04 | Henkel & Cie Gmbh | Verwendung von Aminophosphonsaeuren oder ihrer Derivate als Komplexbildner fuer Metallionen |
| NL6407908A (OSRAM) * | 1963-07-12 | 1965-01-13 | ||
| FR91049E (fr) * | 1966-02-14 | 1968-03-29 | Kuhlmann Ets | Polyols phosphorés et azotés, procédé pour leur obtention et leurs applications |
| US3565949A (en) * | 1967-08-15 | 1971-02-23 | Fmc Corp | Diaminoalkanediylidenetetraphosphonic acids useful in cleaning compositions |
| US3668138A (en) * | 1970-11-27 | 1972-06-06 | Calgon Corp | Method of inhibiting corrosion with amino diphosphonates |
-
1971
- 1971-03-31 DE DE2115737A patent/DE2115737C3/de not_active Expired
-
1972
- 1972-03-03 NL NL7202859A patent/NL7202859A/xx not_active Application Discontinuation
- 1972-03-16 US US05/235,838 patent/US4006182A/en not_active Expired - Lifetime
- 1972-03-27 YU YU799/72A patent/YU35266B/xx unknown
- 1972-03-28 AT AT268372A patent/AT308141B/de not_active IP Right Cessation
- 1972-03-28 BR BR721823A patent/BR7201823D0/pt unknown
- 1972-03-29 ES ES401300A patent/ES401300A1/es not_active Expired
- 1972-03-30 BE BE781462A patent/BE781462A/xx not_active IP Right Cessation
- 1972-03-30 IT IT22590/72A patent/IT954825B/it active
- 1972-03-30 GB GB1495372A patent/GB1381668A/en not_active Expired
- 1972-03-30 CH CH484572A patent/CH571011A5/xx not_active IP Right Cessation
- 1972-03-30 ZA ZA722181A patent/ZA722181B/xx unknown
- 1972-03-31 JP JP3254372A patent/JPS5530000B1/ja active Pending
- 1972-03-31 FR FR7211450A patent/FR2132312B1/fr not_active Expired
Also Published As
| Publication number | Publication date |
|---|---|
| BR7201823D0 (pt) | 1973-06-14 |
| IT954825B (it) | 1973-09-15 |
| YU79972A (en) | 1980-04-30 |
| JPS5530000B1 (OSRAM) | 1980-08-07 |
| ZA722181B (en) | 1973-04-25 |
| BE781462A (fr) | 1972-10-02 |
| YU35266B (en) | 1980-10-31 |
| DE2115737B2 (de) | 1979-01-25 |
| FR2132312A1 (OSRAM) | 1972-11-17 |
| AT308141B (de) | 1973-06-25 |
| ES401300A1 (es) | 1975-02-16 |
| DE2115737A1 (de) | 1972-10-12 |
| CH571011A5 (OSRAM) | 1975-12-31 |
| US4006182A (en) | 1977-02-01 |
| GB1381668A (en) | 1975-01-22 |
| FR2132312B1 (OSRAM) | 1977-04-01 |
| NL7202859A (OSRAM) | 1972-10-03 |
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