DE2110450C3 - Organischer Festelektrolyt mit einem Elektrondonator-Akzeptor-Komplex, welcher 7,7,8,8-Tetracyanchinodimethan enthält, und Verfahren zu dessen Herstellung - Google Patents
Organischer Festelektrolyt mit einem Elektrondonator-Akzeptor-Komplex, welcher 7,7,8,8-Tetracyanchinodimethan enthält, und Verfahren zu dessen HerstellungInfo
- Publication number
- DE2110450C3 DE2110450C3 DE2110450A DE2110450A DE2110450C3 DE 2110450 C3 DE2110450 C3 DE 2110450C3 DE 2110450 A DE2110450 A DE 2110450A DE 2110450 A DE2110450 A DE 2110450A DE 2110450 C3 DE2110450 C3 DE 2110450C3
- Authority
- DE
- Germany
- Prior art keywords
- complex
- eda
- molecule
- tcnq
- crystals
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 238000000034 method Methods 0.000 title claims description 9
- 239000007784 solid electrolyte Substances 0.000 title claims 5
- PCCVSPMFGIFTHU-UHFFFAOYSA-N tetracyanoquinodimethane Chemical compound N#CC(C#N)=C1C=CC(=C(C#N)C#N)C=C1 PCCVSPMFGIFTHU-UHFFFAOYSA-N 0.000 title claims 5
- 238000002360 preparation method Methods 0.000 title claims 3
- 239000013078 crystal Substances 0.000 claims description 22
- NLZUEZXRPGMBCV-UHFFFAOYSA-N Butylhydroxytoluene Chemical compound CC1=CC(C(C)(C)C)=C(O)C(C(C)(C)C)=C1 NLZUEZXRPGMBCV-UHFFFAOYSA-N 0.000 claims description 12
- YMWUJEATGCHHMB-UHFFFAOYSA-N Dichloromethane Chemical compound ClCCl YMWUJEATGCHHMB-UHFFFAOYSA-N 0.000 claims description 12
- HEDRZPFGACZZDS-UHFFFAOYSA-N Chloroform Chemical compound ClC(Cl)Cl HEDRZPFGACZZDS-UHFFFAOYSA-N 0.000 claims description 10
- 239000003792 electrolyte Substances 0.000 claims description 10
- 239000002904 solvent Substances 0.000 claims description 9
- 239000000126 substance Substances 0.000 claims description 9
- CBCKQZAAMUWICA-UHFFFAOYSA-N 1,4-phenylenediamine Chemical compound NC1=CC=C(N)C=C1 CBCKQZAAMUWICA-UHFFFAOYSA-N 0.000 claims description 4
- 229910052751 metal Inorganic materials 0.000 claims description 4
- 239000002184 metal Substances 0.000 claims description 4
- 239000000463 material Substances 0.000 claims description 3
- 229910052782 aluminium Inorganic materials 0.000 claims description 2
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 claims description 2
- 239000003990 capacitor Substances 0.000 claims description 2
- 150000004984 aromatic diamines Chemical class 0.000 claims 7
- 150000002825 nitriles Chemical class 0.000 claims 4
- -1 dona amide Chemical class 0.000 claims 3
- 239000004215 Carbon black (E152) Substances 0.000 claims 2
- 150000001408 amides Chemical class 0.000 claims 2
- 125000003118 aryl group Chemical group 0.000 claims 2
- 150000004985 diamines Chemical class 0.000 claims 2
- 150000004820 halides Chemical class 0.000 claims 2
- 229930195733 hydrocarbon Natural products 0.000 claims 2
- 150000002430 hydrocarbons Chemical class 0.000 claims 2
- QGZKDVFQNNGYKY-UHFFFAOYSA-O Ammonium Chemical compound [NH4+] QGZKDVFQNNGYKY-UHFFFAOYSA-O 0.000 claims 1
- VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 claims 1
- 239000003513 alkali Substances 0.000 claims 1
- 229910001615 alkaline earth metal halide Inorganic materials 0.000 claims 1
- 150000001412 amines Chemical class 0.000 claims 1
- 208000007502 anemia Diseases 0.000 claims 1
- 150000004945 aromatic hydrocarbons Chemical class 0.000 claims 1
- 230000015572 biosynthetic process Effects 0.000 claims 1
- 239000007795 chemical reaction product Substances 0.000 claims 1
- 150000001875 compounds Chemical class 0.000 claims 1
- 239000011521 glass Substances 0.000 claims 1
- 150000002500 ions Chemical class 0.000 claims 1
- 238000004519 manufacturing process Methods 0.000 claims 1
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 claims 1
- 230000007935 neutral effect Effects 0.000 claims 1
- 229910052709 silver Inorganic materials 0.000 claims 1
- 239000004332 silver Substances 0.000 claims 1
- 239000007787 solid Substances 0.000 claims 1
- 229910052715 tantalum Inorganic materials 0.000 claims 1
- GUVRBAGPIYLISA-UHFFFAOYSA-N tantalum atom Chemical compound [Ta] GUVRBAGPIYLISA-UHFFFAOYSA-N 0.000 claims 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims 1
- ZMXDDKWLCZADIW-UHFFFAOYSA-N N,N-Dimethylformamide Chemical compound CN(C)C=O ZMXDDKWLCZADIW-UHFFFAOYSA-N 0.000 description 6
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 4
- WEVYAHXRMPXWCK-UHFFFAOYSA-N Acetonitrile Chemical compound CC#N WEVYAHXRMPXWCK-UHFFFAOYSA-N 0.000 description 3
- HFACYLZERDEVSX-UHFFFAOYSA-N benzidine Chemical compound C1=CC(N)=CC=C1C1=CC=C(N)C=C1 HFACYLZERDEVSX-UHFFFAOYSA-N 0.000 description 3
- 238000010992 reflux Methods 0.000 description 2
- OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 description 1
- FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 description 1
- OHLUUHNLEMFGTQ-UHFFFAOYSA-N N-methylacetamide Chemical compound CNC(C)=O OHLUUHNLEMFGTQ-UHFFFAOYSA-N 0.000 description 1
- 229910052791 calcium Inorganic materials 0.000 description 1
- 239000011575 calcium Substances 0.000 description 1
- 125000004177 diethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 description 1
- 229910052749 magnesium Inorganic materials 0.000 description 1
- 239000011777 magnesium Substances 0.000 description 1
- 239000000203 mixture Substances 0.000 description 1
- 230000003647 oxidation Effects 0.000 description 1
- 238000007254 oxidation reaction Methods 0.000 description 1
- 150000004986 phenylenediamines Chemical class 0.000 description 1
- 238000007711 solidification Methods 0.000 description 1
- 230000008023 solidification Effects 0.000 description 1
Classifications
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01G—CAPACITORS; CAPACITORS, RECTIFIERS, DETECTORS, SWITCHING DEVICES, LIGHT-SENSITIVE OR TEMPERATURE-SENSITIVE DEVICES OF THE ELECTROLYTIC TYPE
- H01G9/00—Electrolytic capacitors, rectifiers, detectors, switching devices, light-sensitive or temperature-sensitive devices; Processes of their manufacture
- H01G9/004—Details
- H01G9/022—Electrolytes; Absorbents
- H01G9/025—Solid electrolytes
- H01G9/028—Organic semiconducting electrolytes, e.g. TCNQ
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M6/00—Primary cells; Manufacture thereof
- H01M6/14—Cells with non-aqueous electrolyte
- H01M6/18—Cells with non-aqueous electrolyte with solid electrolyte
- H01M6/181—Cells with non-aqueous electrolyte with solid electrolyte with polymeric electrolytes
Landscapes
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Electrochemistry (AREA)
- Engineering & Computer Science (AREA)
- Power Engineering (AREA)
- Microelectronics & Electronic Packaging (AREA)
- Manufacturing & Machinery (AREA)
- General Chemical & Material Sciences (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Conductive Materials (AREA)
- Secondary Cells (AREA)
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP1889470 | 1970-03-04 | ||
| JP1914170 | 1970-03-05 |
Publications (3)
| Publication Number | Publication Date |
|---|---|
| DE2110450A1 DE2110450A1 (de) | 1971-09-16 |
| DE2110450B2 DE2110450B2 (de) | 1973-12-13 |
| DE2110450C3 true DE2110450C3 (de) | 1974-07-25 |
Family
ID=26355633
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| DE2110450A Expired DE2110450C3 (de) | 1970-03-04 | 1971-03-04 | Organischer Festelektrolyt mit einem Elektrondonator-Akzeptor-Komplex, welcher 7,7,8,8-Tetracyanchinodimethan enthält, und Verfahren zu dessen Herstellung |
Country Status (6)
| Country | Link |
|---|---|
| US (1) | US3709820A (enExample) |
| CA (1) | CA947817A (enExample) |
| DE (1) | DE2110450C3 (enExample) |
| FR (1) | FR2081682B1 (enExample) |
| GB (1) | GB1331712A (enExample) |
| NL (1) | NL7102885A (enExample) |
Families Citing this family (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS5610777B2 (enExample) * | 1972-06-13 | 1981-03-10 | ||
| JPS5042368A (enExample) * | 1973-08-16 | 1975-04-17 | ||
| JPH0610199B2 (ja) * | 1985-11-18 | 1994-02-09 | 日本カ−リツト株式会社 | 電荷移動錯体 |
| JP3361928B2 (ja) * | 1996-02-15 | 2003-01-07 | 株式会社東芝 | 電荷移動錯体 |
Family Cites Families (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3110630A (en) * | 1960-08-11 | 1963-11-12 | Du Pont | Electrolytic cell |
-
1971
- 1971-02-25 US US00119058A patent/US3709820A/en not_active Expired - Lifetime
- 1971-03-01 FR FR7106977A patent/FR2081682B1/fr not_active Expired
- 1971-03-03 CA CA106,837A patent/CA947817A/en not_active Expired
- 1971-03-04 DE DE2110450A patent/DE2110450C3/de not_active Expired
- 1971-03-04 NL NL7102885A patent/NL7102885A/xx unknown
- 1971-04-19 GB GB2256271A patent/GB1331712A/en not_active Expired
Also Published As
| Publication number | Publication date |
|---|---|
| NL7102885A (enExample) | 1971-09-07 |
| GB1331712A (en) | 1973-09-26 |
| FR2081682B1 (enExample) | 1975-01-17 |
| DE2110450A1 (de) | 1971-09-16 |
| DE2110450B2 (de) | 1973-12-13 |
| FR2081682A1 (enExample) | 1971-12-10 |
| US3709820A (en) | 1973-01-09 |
| CA947817A (en) | 1974-05-21 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C3 | Grant after two publication steps (3rd publication) | ||
| E77 | Valid patent as to the heymanns-index 1977 | ||
| EF | Willingness to grant licences |