DE2060606A1 - Verfahren zur Polymerisation von alpha-Olefinen - Google Patents
Verfahren zur Polymerisation von alpha-OlefinenInfo
- Publication number
- DE2060606A1 DE2060606A1 DE19702060606 DE2060606A DE2060606A1 DE 2060606 A1 DE2060606 A1 DE 2060606A1 DE 19702060606 DE19702060606 DE 19702060606 DE 2060606 A DE2060606 A DE 2060606A DE 2060606 A1 DE2060606 A1 DE 2060606A1
- Authority
- DE
- Germany
- Prior art keywords
- catalyst
- polymerization
- alkoxides
- silicon
- hexamethylbenzene
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 238000006116 polymerization reaction Methods 0.000 title claims description 13
- 238000000034 method Methods 0.000 title claims description 10
- 239000004711 α-olefin Substances 0.000 title 1
- 239000003054 catalyst Substances 0.000 claims description 30
- -1 aluminum halides Chemical class 0.000 claims description 23
- 238000002360 preparation method Methods 0.000 claims description 8
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 claims description 6
- 239000005977 Ethylene Substances 0.000 claims description 6
- 150000004703 alkoxides Chemical class 0.000 claims description 6
- 125000004435 hydrogen atom Chemical group [H]* 0.000 claims description 6
- YUWFEBAXEOLKSG-UHFFFAOYSA-N hexamethylbenzene Chemical compound CC1=C(C)C(C)=C(C)C(C)=C1C YUWFEBAXEOLKSG-UHFFFAOYSA-N 0.000 claims description 5
- 150000003377 silicon compounds Chemical class 0.000 claims description 5
- 230000000737 periodic effect Effects 0.000 claims description 4
- 229910052710 silicon Inorganic materials 0.000 claims description 4
- 239000010703 silicon Substances 0.000 claims description 4
- 229910052782 aluminium Inorganic materials 0.000 claims description 3
- 125000004432 carbon atom Chemical group C* 0.000 claims description 3
- 229910001507 metal halide Inorganic materials 0.000 claims description 3
- 150000005309 metal halides Chemical class 0.000 claims description 3
- 239000007858 starting material Substances 0.000 claims description 3
- 125000002947 alkylene group Chemical group 0.000 claims description 2
- 238000007334 copolymerization reaction Methods 0.000 claims description 2
- IMNFDUFMRHMDMM-UHFFFAOYSA-N N-Heptane Chemical compound CCCCCCC IMNFDUFMRHMDMM-UHFFFAOYSA-N 0.000 description 27
- 239000004698 Polyethylene Substances 0.000 description 10
- 229920000573 polyethylene Polymers 0.000 description 10
- 239000000725 suspension Substances 0.000 description 9
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 8
- 239000001257 hydrogen Substances 0.000 description 8
- 229910052739 hydrogen Inorganic materials 0.000 description 8
- 239000000843 powder Substances 0.000 description 8
- LXSMILGNHYBUCG-UHFFFAOYSA-N 1,2,3,4,5,6-hexaethylbenzene Chemical compound CCC1=C(CC)C(CC)=C(CC)C(CC)=C1CC LXSMILGNHYBUCG-UHFFFAOYSA-N 0.000 description 6
- KFZMGEQAYNKOFK-UHFFFAOYSA-N Isopropanol Chemical compound CC(C)O KFZMGEQAYNKOFK-UHFFFAOYSA-N 0.000 description 6
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 6
- VSCWAEJMTAWNJL-UHFFFAOYSA-K aluminium trichloride Chemical compound Cl[Al](Cl)Cl VSCWAEJMTAWNJL-UHFFFAOYSA-K 0.000 description 6
- 238000006243 chemical reaction Methods 0.000 description 6
- 239000007789 gas Substances 0.000 description 6
- 239000007788 liquid Substances 0.000 description 6
- 239000000155 melt Substances 0.000 description 5
- 239000000203 mixture Substances 0.000 description 5
- NHTMVDHEPJAVLT-UHFFFAOYSA-N Isooctane Chemical compound CC(C)CC(C)(C)C NHTMVDHEPJAVLT-UHFFFAOYSA-N 0.000 description 4
- OFBQJSOFQDEBGM-UHFFFAOYSA-N Pentane Chemical compound CCCCC OFBQJSOFQDEBGM-UHFFFAOYSA-N 0.000 description 4
- JVSWJIKNEAIKJW-UHFFFAOYSA-N dimethyl-hexane Natural products CCCCCC(C)C JVSWJIKNEAIKJW-UHFFFAOYSA-N 0.000 description 4
- 229910052757 nitrogen Inorganic materials 0.000 description 4
- 229920000098 polyolefin Polymers 0.000 description 4
- 229920001296 polysiloxane Polymers 0.000 description 4
- XJDNKRIXUMDJCW-UHFFFAOYSA-J titanium tetrachloride Chemical compound Cl[Ti](Cl)(Cl)Cl XJDNKRIXUMDJCW-UHFFFAOYSA-J 0.000 description 4
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical group [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 description 3
- 238000001816 cooling Methods 0.000 description 3
- 238000002156 mixing Methods 0.000 description 3
- 229920000642 polymer Polymers 0.000 description 3
- 238000003756 stirring Methods 0.000 description 3
- VXNZUUAINFGPBY-UHFFFAOYSA-N 1-Butene Chemical compound CCC=C VXNZUUAINFGPBY-UHFFFAOYSA-N 0.000 description 2
- XDTMQSROBMDMFD-UHFFFAOYSA-N Cyclohexane Chemical compound C1CCCCC1 XDTMQSROBMDMFD-UHFFFAOYSA-N 0.000 description 2
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 2
- 230000000052 comparative effect Effects 0.000 description 2
- 238000000354 decomposition reaction Methods 0.000 description 2
- 238000004090 dissolution Methods 0.000 description 2
- 238000001035 drying Methods 0.000 description 2
- 230000007717 exclusion Effects 0.000 description 2
- 238000002474 experimental method Methods 0.000 description 2
- 239000011521 glass Substances 0.000 description 2
- VLKZOEOYAKHREP-UHFFFAOYSA-N hexane Substances CCCCCC VLKZOEOYAKHREP-UHFFFAOYSA-N 0.000 description 2
- QQONPFPTGQHPMA-UHFFFAOYSA-N propylene Natural products CC=C QQONPFPTGQHPMA-UHFFFAOYSA-N 0.000 description 2
- 125000004805 propylene group Chemical group [H]C([H])([H])C([H])([*:1])C([H])([H])[*:2] 0.000 description 2
- 239000012429 reaction media Substances 0.000 description 2
- 238000010992 reflux Methods 0.000 description 2
- WSSSPWUEQFSQQG-UHFFFAOYSA-N 4-methyl-1-pentene Chemical compound CC(C)CC=C WSSSPWUEQFSQQG-UHFFFAOYSA-N 0.000 description 1
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 1
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 1
- XLVKXZZJSTWDJY-UHFFFAOYSA-N [SiH4].[Si] Chemical group [SiH4].[Si] XLVKXZZJSTWDJY-UHFFFAOYSA-N 0.000 description 1
- 238000009825 accumulation Methods 0.000 description 1
- 150000001338 aliphatic hydrocarbons Chemical class 0.000 description 1
- 150000001336 alkenes Chemical class 0.000 description 1
- 125000000217 alkyl group Chemical group 0.000 description 1
- AZDRQVAHHNSJOQ-UHFFFAOYSA-N alumane Chemical class [AlH3] AZDRQVAHHNSJOQ-UHFFFAOYSA-N 0.000 description 1
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 1
- 229910052799 carbon Inorganic materials 0.000 description 1
- ZHXZNKNQUHUIGN-UHFFFAOYSA-N chloro hypochlorite;vanadium Chemical compound [V].ClOCl ZHXZNKNQUHUIGN-UHFFFAOYSA-N 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 239000000428 dust Substances 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 238000001914 filtration Methods 0.000 description 1
- 239000008187 granular material Substances 0.000 description 1
- 238000005469 granulation Methods 0.000 description 1
- 230000003179 granulation Effects 0.000 description 1
- 150000004820 halides Chemical class 0.000 description 1
- 150000002431 hydrogen Chemical class 0.000 description 1
- 239000011261 inert gas Substances 0.000 description 1
- 239000007791 liquid phase Substances 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 1
- 239000001301 oxygen Substances 0.000 description 1
- 229910052760 oxygen Inorganic materials 0.000 description 1
- RPESBQCJGHJMTK-UHFFFAOYSA-I pentachlorovanadium Chemical class [Cl-].[Cl-].[Cl-].[Cl-].[Cl-].[V+5] RPESBQCJGHJMTK-UHFFFAOYSA-I 0.000 description 1
- 239000012071 phase Substances 0.000 description 1
- 238000009700 powder processing Methods 0.000 description 1
- 239000011541 reaction mixture Substances 0.000 description 1
- 229920006395 saturated elastomer Polymers 0.000 description 1
- 229930195734 saturated hydrocarbon Natural products 0.000 description 1
- 230000003685 thermal hair damage Effects 0.000 description 1
- 238000012795 verification Methods 0.000 description 1
- 239000002912 waste gas Substances 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10S526/00—Synthetic resins or natural rubbers -- part of the class 520 series
- Y10S526/903—Monomer polymerized in presence of transition metal containing catalyst and hydrocarbon additive affecting polymer properties of catalyst activity
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10S526/00—Synthetic resins or natural rubbers -- part of the class 520 series
- Y10S526/909—Polymerization characterized by particle size of product
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
Priority Applications (11)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DE19702060606 DE2060606A1 (de) | 1970-12-09 | 1970-12-09 | Verfahren zur Polymerisation von alpha-Olefinen |
| NL7116051A NL7116051A (enExample) | 1970-12-09 | 1971-11-22 | |
| US00203430A US3808188A (en) | 1970-12-09 | 1971-11-30 | Catalysts and process for alpha-olefin polymerization |
| CA129,265A CA989546A (en) | 1970-12-09 | 1971-12-03 | CATALYSTS FOR .alpha.-OLEFIN POLYMERIZATION AND THE POLYMERIZATION PROCESS |
| BE776290A BE776290A (fr) | 1970-12-09 | 1971-12-06 | Procede de polymerisation d'alpha-olefines |
| IT54590/71A IT945321B (it) | 1970-12-09 | 1971-12-07 | Procedimento per la polimerizza zione di alfa olefine |
| AT1050971A AT309812B (de) | 1970-12-09 | 1971-12-07 | Verfahren zur Polymerisation von α-Olefinen |
| FR7144024A FR2117525A5 (enExample) | 1970-12-09 | 1971-12-08 | |
| GB5707171A GB1372317A (en) | 1970-12-09 | 1971-12-08 | Olefin polymerisation catalyst |
| CH1795671A CH548423A (de) | 1970-12-09 | 1971-12-09 | Verfahren zur polymerisation von (alpha)-olefinen. |
| JP46099819A JPS497076B1 (enExample) | 1970-12-09 | 1971-12-09 |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DE19702060606 DE2060606A1 (de) | 1970-12-09 | 1970-12-09 | Verfahren zur Polymerisation von alpha-Olefinen |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| DE2060606A1 true DE2060606A1 (de) | 1972-06-15 |
Family
ID=5790459
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| DE19702060606 Pending DE2060606A1 (de) | 1970-12-09 | 1970-12-09 | Verfahren zur Polymerisation von alpha-Olefinen |
Country Status (11)
| Country | Link |
|---|---|
| US (1) | US3808188A (enExample) |
| JP (1) | JPS497076B1 (enExample) |
| AT (1) | AT309812B (enExample) |
| BE (1) | BE776290A (enExample) |
| CA (1) | CA989546A (enExample) |
| CH (1) | CH548423A (enExample) |
| DE (1) | DE2060606A1 (enExample) |
| FR (1) | FR2117525A5 (enExample) |
| GB (1) | GB1372317A (enExample) |
| IT (1) | IT945321B (enExample) |
| NL (1) | NL7116051A (enExample) |
Families Citing this family (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE69530907T2 (de) * | 1994-12-12 | 2003-12-04 | Ford Motor Co., Dearborn | Verfahren und Gerät zur Datenübertragung |
-
1970
- 1970-12-09 DE DE19702060606 patent/DE2060606A1/de active Pending
-
1971
- 1971-11-22 NL NL7116051A patent/NL7116051A/xx unknown
- 1971-11-30 US US00203430A patent/US3808188A/en not_active Expired - Lifetime
- 1971-12-03 CA CA129,265A patent/CA989546A/en not_active Expired
- 1971-12-06 BE BE776290A patent/BE776290A/xx unknown
- 1971-12-07 IT IT54590/71A patent/IT945321B/it active
- 1971-12-07 AT AT1050971A patent/AT309812B/de not_active IP Right Cessation
- 1971-12-08 FR FR7144024A patent/FR2117525A5/fr not_active Expired
- 1971-12-08 GB GB5707171A patent/GB1372317A/en not_active Expired
- 1971-12-09 CH CH1795671A patent/CH548423A/xx not_active IP Right Cessation
- 1971-12-09 JP JP46099819A patent/JPS497076B1/ja active Pending
Also Published As
| Publication number | Publication date |
|---|---|
| IT945321B (it) | 1973-05-10 |
| FR2117525A5 (enExample) | 1972-07-21 |
| CH548423A (de) | 1974-04-30 |
| BE776290A (fr) | 1972-06-06 |
| US3808188A (en) | 1974-04-30 |
| GB1372317A (en) | 1974-10-30 |
| AT309812B (de) | 1973-09-10 |
| NL7116051A (enExample) | 1972-06-13 |
| JPS497076B1 (enExample) | 1974-02-18 |
| CA989546A (en) | 1976-05-18 |
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