DE19962910A1

DE19962910A1 - Chemische Verbindung, Verfahren zu deren Herstellung und deren Verwendung in Katalysatorsystemen zur Herstellung von Polyolefinen

Chemische Verbindung, Verfahren zu deren Herstellung und deren Verwendung in Katalysatorsystemen zur Herstellung von Polyolefinen

Info

Publication number: DE19962910A1
Authority: DE; Germany
Prior art keywords: methyl; borate; indenyl; zirconium dichloride; tetrakis
Prior art date: 1999-12-23
Legal status : Withdrawn

Application number

DE19962910A

Other languages

German (de)

English (en)

Inventor

Joerg Schottek

Iris Kuellmer

Heike Gregorius

David Fischer

Current Assignee

Basell Polyolefine GmbH

Original Assignee

Targor GmbH

Priority date

1999-12-23

Filing date

1999-12-23

Publication date

2001-07-05

1999-12-23 Application filed by Targor GmbH filed Critical Targor GmbH

1999-12-23 Priority to DE19962910A priority Critical patent/DE19962910A1/de

2000-12-21 Priority to DE50013407T priority patent/DE50013407D1/de

2000-12-21 Priority to US10/168,719 priority patent/US7101940B2/en

2000-12-21 Priority to AT00991248T priority patent/ATE338075T1/de

2000-12-21 Priority to EP00991248A priority patent/EP1250363B1/de

2000-12-21 Priority to PCT/EP2000/013096 priority patent/WO2001048035A2/de

2000-12-21 Priority to JP2001548573A priority patent/JP2003518516A/ja

2001-07-05 Publication of DE19962910A1 publication Critical patent/DE19962910A1/de

Status Withdrawn legal-status Critical Current

Links

150000001875 compounds Chemical class 0.000 title claims abstract description 48
239000003054 catalyst Substances 0.000 title claims description 46
238000000034 method Methods 0.000 title claims description 13
238000004519 manufacturing process Methods 0.000 title claims description 8
229920000098 polyolefin Polymers 0.000 title claims description 8
230000008569 process Effects 0.000 title claims description 8
238000002360 preparation method Methods 0.000 title claims description 5
125000004122 cyclic group Chemical group 0.000 claims abstract description 25
229910052799 carbon Inorganic materials 0.000 claims abstract description 22
OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims abstract description 20
125000004435 hydrogen atom Chemical group [H]* 0.000 claims abstract description 14
230000000737 periodic effect Effects 0.000 claims abstract description 13
150000001768 cations Chemical class 0.000 claims abstract description 6
NFHFRUOZVGFOOS-UHFFFAOYSA-N palladium;triphenylphosphane Chemical compound [Pd].C1=CC=CC=C1P(C=1C=CC=CC=1)C1=CC=CC=C1.C1=CC=CC=C1P(C=1C=CC=CC=1)C1=CC=CC=C1.C1=CC=CC=C1P(C=1C=CC=CC=1)C1=CC=CC=C1.C1=CC=CC=C1P(C=1C=CC=CC=1)C1=CC=CC=C1 NFHFRUOZVGFOOS-UHFFFAOYSA-N 0.000 claims description 332
BTBUEUYNUDRHOZ-UHFFFAOYSA-N Borate Chemical compound [O-]B([O-])[O-] BTBUEUYNUDRHOZ-UHFFFAOYSA-N 0.000 claims description 116
125000000538 pentafluorophenyl group Chemical group FC1=C(F)C(F)=C(*)C(F)=C1F 0.000 claims description 106
LWNGJAHMBMVCJR-UHFFFAOYSA-N (2,3,4,5,6-pentafluorophenoxy)boronic acid Chemical compound OB(O)OC1=C(F)C(F)=C(F)C(F)=C1F LWNGJAHMBMVCJR-UHFFFAOYSA-N 0.000 claims description 67
229910052757 nitrogen Inorganic materials 0.000 claims description 61
CIXSDMKDSYXUMJ-UHFFFAOYSA-N n,n-diethylcyclohexanamine Chemical compound CCN(CC)C1CCCCC1 CIXSDMKDSYXUMJ-UHFFFAOYSA-N 0.000 claims description 37
238000006116 polymerization reaction Methods 0.000 claims description 25
150000001336 alkenes Chemical class 0.000 claims description 24
125000003710 aryl alkyl group Chemical group 0.000 claims description 23
SVYKKECYCPFKGB-UHFFFAOYSA-N N,N-dimethylcyclohexylamine Chemical compound CN(C)C1CCCCC1 SVYKKECYCPFKGB-UHFFFAOYSA-N 0.000 claims description 22
125000000217 alkyl group Chemical group 0.000 claims description 22
125000003106 haloaryl group Chemical group 0.000 claims description 19
125000000027 (C1-C10) alkoxy group Chemical group 0.000 claims description 14
GBXQPDCOMJJCMJ-UHFFFAOYSA-M trimethyl-[6-(trimethylazaniumyl)hexyl]azanium;bromide Chemical compound [Br-].C[N+](C)(C)CCCCCC[N+](C)(C)C GBXQPDCOMJJCMJ-UHFFFAOYSA-M 0.000 claims description 14
125000002877 alkyl aryl group Chemical group 0.000 claims description 13
125000001188 haloalkyl group Chemical group 0.000 claims description 13
125000004104 aryloxy group Chemical group 0.000 claims description 12
125000006492 halo alkyl aryl group Chemical group 0.000 claims description 11
125000000753 cycloalkyl group Chemical group 0.000 claims description 10
125000002034 haloarylalkyl group Chemical group 0.000 claims description 9
229920000642 polymer Polymers 0.000 claims description 9
125000004432 carbon atom Chemical group C* 0.000 claims description 8
OSCBARYHPZZEIS-UHFFFAOYSA-N phenoxyboronic acid Chemical compound OB(O)OC1=CC=CC=C1 OSCBARYHPZZEIS-UHFFFAOYSA-N 0.000 claims description 8
ZOXJGFHDIHLPTG-UHFFFAOYSA-N Boron Chemical compound [B] ZOXJGFHDIHLPTG-UHFFFAOYSA-N 0.000 claims description 6
229910052782 aluminium Inorganic materials 0.000 claims description 6
229910052796 boron Inorganic materials 0.000 claims description 6
230000007704 transition Effects 0.000 claims description 6
125000002524 organometallic group Chemical group 0.000 claims description 5
BAVYZALUXZFZLV-UHFFFAOYSA-N Methylamine Chemical compound NC BAVYZALUXZFZLV-UHFFFAOYSA-N 0.000 claims description 4
XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 claims description 4
125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 claims description 4
ATBNMWWDBWBAHM-UHFFFAOYSA-N n-decyl-n-methyldecan-1-amine Chemical compound CCCCCCCCCCN(C)CCCCCCCCCC ATBNMWWDBWBAHM-UHFFFAOYSA-N 0.000 claims description 4
150000003856 quaternary ammonium compounds Chemical class 0.000 claims description 4
239000002879 Lewis base Substances 0.000 claims description 3
150000007527 lewis bases Chemical class 0.000 claims description 3
UWHRNIXHZAWBMF-UHFFFAOYSA-N n-dodecyl-n-methyldodecan-1-amine Chemical compound CCCCCCCCCCCCN(C)CCCCCCCCCCCC UWHRNIXHZAWBMF-UHFFFAOYSA-N 0.000 claims description 3
KWVPRPSXBZNOHS-UHFFFAOYSA-N 2,4,6-Trimethylaniline Chemical compound CC1=CC(C)=C(N)C(C)=C1 KWVPRPSXBZNOHS-UHFFFAOYSA-N 0.000 claims description 2
JLTDJTHDQAWBAV-UHFFFAOYSA-N N,N-dimethylaniline Chemical compound CN(C)C1=CC=CC=C1 JLTDJTHDQAWBAV-UHFFFAOYSA-N 0.000 claims description 2
XBPCUCUWBYBCDP-UHFFFAOYSA-O dicyclohexylazanium Chemical compound C1CCCCC1[NH2+]C1CCCCC1 XBPCUCUWBYBCDP-UHFFFAOYSA-O 0.000 claims description 2
JLTDJTHDQAWBAV-UHFFFAOYSA-O dimethyl(phenyl)azanium Chemical compound C[NH+](C)C1=CC=CC=C1 JLTDJTHDQAWBAV-UHFFFAOYSA-O 0.000 claims description 2
OCZBPNBIXHLBFM-UHFFFAOYSA-N n,n-di(propan-2-yl)cyclohexanamine Chemical compound CC(C)N(C(C)C)C1CCCCC1 OCZBPNBIXHLBFM-UHFFFAOYSA-N 0.000 claims description 2
IQSLPSKHVSSQOH-UHFFFAOYSA-N n,n-dibutyldecan-1-amine Chemical compound CCCCCCCCCCN(CCCC)CCCC IQSLPSKHVSSQOH-UHFFFAOYSA-N 0.000 claims description 2
FPFTUTDQPYXFSM-UHFFFAOYSA-N n,n-didodecylcyclohexanamine Chemical compound CCCCCCCCCCCCN(CCCCCCCCCCCC)C1CCCCC1 FPFTUTDQPYXFSM-UHFFFAOYSA-N 0.000 claims description 2
YWWNNLPSZSEZNZ-UHFFFAOYSA-N n,n-dimethyldecan-1-amine Chemical compound CCCCCCCCCCN(C)C YWWNNLPSZSEZNZ-UHFFFAOYSA-N 0.000 claims description 2
NHLUVTZJQOJKCC-UHFFFAOYSA-N n,n-dimethylhexadecan-1-amine Chemical compound CCCCCCCCCCCCCCCCN(C)C NHLUVTZJQOJKCC-UHFFFAOYSA-N 0.000 claims description 2
CWAIAZCEPCBUON-UHFFFAOYSA-N n-icosyl-n-methylicosan-1-amine Chemical compound CCCCCCCCCCCCCCCCCCCCN(C)CCCCCCCCCCCCCCCCCCCC CWAIAZCEPCBUON-UHFFFAOYSA-N 0.000 claims description 2
VFLWKHBYVIUAMP-UHFFFAOYSA-N n-methyl-n-octadecyloctadecan-1-amine Chemical compound CCCCCCCCCCCCCCCCCCN(C)CCCCCCCCCCCCCCCCCC VFLWKHBYVIUAMP-UHFFFAOYSA-N 0.000 claims description 2
125000004079 stearyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 claims description 2
NAPSCFZYZVSQHF-UHFFFAOYSA-N dimantine Chemical compound CCCCCCCCCCCCCCCCCCN(C)C NAPSCFZYZVSQHF-UHFFFAOYSA-N 0.000 claims 1
WEHWNAOGRSTTBQ-UHFFFAOYSA-N dipropylamine Chemical compound CCCNCCC WEHWNAOGRSTTBQ-UHFFFAOYSA-N 0.000 claims 1
NNMCLUGKHHLNKX-UHFFFAOYSA-N n,n-didecyldodecan-1-amine Chemical compound CCCCCCCCCCCCN(CCCCCCCCCC)CCCCCCCCCC NNMCLUGKHHLNKX-UHFFFAOYSA-N 0.000 claims 1
XJIXQZHZNXTYRV-UHFFFAOYSA-N n,n-didecyloctadecan-1-amine Chemical compound CCCCCCCCCCCCCCCCCCN(CCCCCCCCCC)CCCCCCCCCC XJIXQZHZNXTYRV-UHFFFAOYSA-N 0.000 claims 1
YWFWDNVOPHGWMX-UHFFFAOYSA-N n,n-dimethyldodecan-1-amine Chemical compound CCCCCCCCCCCCN(C)C YWFWDNVOPHGWMX-UHFFFAOYSA-N 0.000 claims 1
GOTQULLXGZGQMK-UHFFFAOYSA-N n-benzyl-n-propan-2-ylpropan-2-amine Chemical compound CC(C)N(C(C)C)CC1=CC=CC=C1 GOTQULLXGZGQMK-UHFFFAOYSA-N 0.000 claims 1
KCMTVIZYKDBFFS-UHFFFAOYSA-N n-hexadecyl-n-methylhexadecan-1-amine Chemical compound CCCCCCCCCCCCCCCCN(C)CCCCCCCCCCCCCCCC KCMTVIZYKDBFFS-UHFFFAOYSA-N 0.000 claims 1
KUFYUMSBZMUWAN-UHFFFAOYSA-N n-methyl-n-tetradecyltetradecan-1-amine Chemical compound CCCCCCCCCCCCCCN(C)CCCCCCCCCCCCCC KUFYUMSBZMUWAN-UHFFFAOYSA-N 0.000 claims 1
-1 perfluorinated tetraphenylborates Chemical class 0.000 description 416
VPGLGRNSAYHXPY-UHFFFAOYSA-L zirconium(2+);dichloride Chemical compound Cl[Zr]Cl VPGLGRNSAYHXPY-UHFFFAOYSA-L 0.000 description 88
150000001412 amines Chemical class 0.000 description 63
IMNFDUFMRHMDMM-UHFFFAOYSA-N N-Heptane Chemical compound CCCCCCC IMNFDUFMRHMDMM-UHFFFAOYSA-N 0.000 description 34
YMWUJEATGCHHMB-UHFFFAOYSA-N Dichloromethane Chemical compound ClCCl YMWUJEATGCHHMB-UHFFFAOYSA-N 0.000 description 30
WHXSMMKQMYFTQS-UHFFFAOYSA-N Lithium Chemical compound [Li] WHXSMMKQMYFTQS-UHFFFAOYSA-N 0.000 description 21
229910052744 lithium Inorganic materials 0.000 description 21
239000007983 Tris buffer Substances 0.000 description 20
XXBDWLFCJWSEKW-UHFFFAOYSA-N dimethylbenzylamine Chemical compound CN(C)CC1=CC=CC=C1 XXBDWLFCJWSEKW-UHFFFAOYSA-N 0.000 description 19
DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 18
ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 description 18
YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 description 18
ZWRDBWDXRLPESY-UHFFFAOYSA-N n-benzyl-n-ethylethanamine Chemical compound CCN(CC)CC1=CC=CC=C1 ZWRDBWDXRLPESY-UHFFFAOYSA-N 0.000 description 18
229910052700 potassium Inorganic materials 0.000 description 18
239000011591 potassium Substances 0.000 description 18
229910052708 sodium Inorganic materials 0.000 description 18
239000011734 sodium Substances 0.000 description 18
229910052726 zirconium Inorganic materials 0.000 description 16
XKRFYHLGVUSROY-UHFFFAOYSA-N Argon Chemical compound [Ar] XKRFYHLGVUSROY-UHFFFAOYSA-N 0.000 description 14
239000002904 solvent Substances 0.000 description 14
239000012876 carrier material Substances 0.000 description 13
125000003118 aryl group Chemical group 0.000 description 12
238000006243 chemical reaction Methods 0.000 description 12
VLKZOEOYAKHREP-UHFFFAOYSA-N n-Hexane Chemical compound CCCCCC VLKZOEOYAKHREP-UHFFFAOYSA-N 0.000 description 12
YBYIRNPNPLQARY-UHFFFAOYSA-N 1H-indene Natural products C1=CC=C2CC=CC2=C1 YBYIRNPNPLQARY-UHFFFAOYSA-N 0.000 description 11
239000007789 gas Substances 0.000 description 11
229910052751 metal Inorganic materials 0.000 description 10
239000002184 metal Substances 0.000 description 10
RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 9
125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 description 9
238000003786 synthesis reaction Methods 0.000 description 9
DDXMXHFSQQUJFF-UHFFFAOYSA-N (2,3,4,6-tetrafluoro-5-methoxyphenoxy)boronic acid Chemical compound COC1=C(F)C(F)=C(F)C(OB(O)O)=C1F DDXMXHFSQQUJFF-UHFFFAOYSA-N 0.000 description 8
BWOONEDTGJUENF-UHFFFAOYSA-N (2,3,4,6-tetrafluoro-5-methylphenoxy)boronic acid Chemical compound CC1=C(F)C(F)=C(F)C(OB(O)O)=C1F BWOONEDTGJUENF-UHFFFAOYSA-N 0.000 description 8
PKNXWXIOHMVSPA-UHFFFAOYSA-N (2,4,6-trifluoro-3-methylphenoxy)boronic acid Chemical compound CC1=C(F)C=C(F)C(OB(O)O)=C1F PKNXWXIOHMVSPA-UHFFFAOYSA-N 0.000 description 8
MMWDAJAFHLFILV-UHFFFAOYSA-N (2,6-difluoro-3-methylphenoxy)boronic acid Chemical compound CC1=CC=C(F)C(OB(O)O)=C1F MMWDAJAFHLFILV-UHFFFAOYSA-N 0.000 description 8
IFKYPHHIFNSPNK-UHFFFAOYSA-N (3,4,6-trifluoro-2-methylphenoxy)boronic acid Chemical compound CC1=C(F)C(F)=CC(F)=C1OB(O)O IFKYPHHIFNSPNK-UHFFFAOYSA-N 0.000 description 8
SVTYWVXZGDAWDG-UHFFFAOYSA-N (3,5-difluoro-2-methylphenoxy)boronic acid Chemical compound CC1=C(F)C=C(F)C=C1OB(O)O SVTYWVXZGDAWDG-UHFFFAOYSA-N 0.000 description 8
YCKRFDGAMUMZLT-UHFFFAOYSA-N Fluorine atom Chemical compound [F] YCKRFDGAMUMZLT-UHFFFAOYSA-N 0.000 description 8
QCWXUUIWCKQGHC-UHFFFAOYSA-N Zirconium Chemical compound [Zr] QCWXUUIWCKQGHC-UHFFFAOYSA-N 0.000 description 8
230000015572 biosynthetic process Effects 0.000 description 8
229910052731 fluorine Inorganic materials 0.000 description 8
239000011737 fluorine Substances 0.000 description 8
239000000047 product Substances 0.000 description 8
239000000243 solution Substances 0.000 description 8
XBBVGTDZNACBIW-UHFFFAOYSA-N (2,3,5,6-tetrafluoro-4-methoxyphenoxy)boronic acid Chemical compound COC1=C(F)C(F)=C(OB(O)O)C(F)=C1F XBBVGTDZNACBIW-UHFFFAOYSA-N 0.000 description 7
XQSHNVWECPGIGB-UHFFFAOYSA-N (2,3,6-trifluoro-4-methylphenoxy)boronic acid Chemical compound CC1=CC(F)=C(OB(O)O)C(F)=C1F XQSHNVWECPGIGB-UHFFFAOYSA-N 0.000 description 7
XXMNSSKYPKSJOH-UHFFFAOYSA-L C[Si](=CC1=CC2=CC=NC2=C1)C.[Cl-].[Cl-].[Zr+2] Chemical compound C[Si](=CC1=CC2=CC=NC2=C1)C.[Cl-].[Cl-].[Zr+2] XXMNSSKYPKSJOH-UHFFFAOYSA-L 0.000 description 7
LJDLJFKCGOQWLH-UHFFFAOYSA-L C[Si](=CC1=CC2=CCSC2=C1)C.[Cl-].[Cl-].[Zr+2] Chemical compound C[Si](=CC1=CC2=CCSC2=C1)C.[Cl-].[Cl-].[Zr+2] LJDLJFKCGOQWLH-UHFFFAOYSA-L 0.000 description 7
QQONPFPTGQHPMA-UHFFFAOYSA-N Propene Chemical compound CC=C QQONPFPTGQHPMA-UHFFFAOYSA-N 0.000 description 7
229910052786 argon Inorganic materials 0.000 description 7
238000001035 drying Methods 0.000 description 7
125000003454 indenyl group Chemical group C1(C=CC2=CC=CC=C12)* 0.000 description 7
239000003446 ligand Substances 0.000 description 7
239000003921 oil Substances 0.000 description 7
150000003254 radicals Chemical class 0.000 description 7
239000011541 reaction mixture Substances 0.000 description 7
TZEQJYRYMIBGAM-UHFFFAOYSA-N (2,3,4,5-tetrafluoro-6-methoxyphenoxy)boronic acid Chemical compound COC1=C(F)C(F)=C(F)C(F)=C1OB(O)O TZEQJYRYMIBGAM-UHFFFAOYSA-N 0.000 description 6
JXTPPJGAAFJFMR-UHFFFAOYSA-N (2,3,5,6-tetrafluoro-4-methylphenoxy)boronic acid Chemical compound CC1=C(F)C(F)=C(OB(O)O)C(F)=C1F JXTPPJGAAFJFMR-UHFFFAOYSA-N 0.000 description 6
CZWAQIALFQKSKD-UHFFFAOYSA-N (2,3,5-trifluorophenoxy)boronic acid Chemical compound OB(O)OC1=CC(F)=CC(F)=C1F CZWAQIALFQKSKD-UHFFFAOYSA-N 0.000 description 6
HLVPGBSZESESKG-UHFFFAOYSA-N (2,4-difluoro-5-methylphenoxy)boronic acid Chemical compound CC1=CC(OB(O)O)=C(F)C=C1F HLVPGBSZESESKG-UHFFFAOYSA-N 0.000 description 6
QGZKDVFQNNGYKY-UHFFFAOYSA-O Ammonium Chemical compound [NH4+] QGZKDVFQNNGYKY-UHFFFAOYSA-O 0.000 description 6
GCPYSPSXOKVXOK-UHFFFAOYSA-L C[Si](=CC1C=C2C=C(C=C2O1)C)C.[Cl-].[Cl-].[Zr+2] Chemical compound C[Si](=CC1C=C2C=C(C=C2O1)C)C.[Cl-].[Cl-].[Zr+2] GCPYSPSXOKVXOK-UHFFFAOYSA-L 0.000 description 6
FLJDLWIESSEPCG-UHFFFAOYSA-L C[Si](=CC1C=C2C=C(C=C2S1)C)C.[Cl-].[Cl-].[Zr+2] Chemical compound C[Si](=CC1C=C2C=C(C=C2S1)C)C.[Cl-].[Cl-].[Zr+2] FLJDLWIESSEPCG-UHFFFAOYSA-L 0.000 description 6
KFZMGEQAYNKOFK-UHFFFAOYSA-N Isopropanol Chemical compound CC(C)O KFZMGEQAYNKOFK-UHFFFAOYSA-N 0.000 description 6
WYURNTSHIVDZCO-UHFFFAOYSA-N Tetrahydrofuran Chemical compound C1CCOC1 WYURNTSHIVDZCO-UHFFFAOYSA-N 0.000 description 6
230000004913 activation Effects 0.000 description 6
125000000058 cyclopentadienyl group Chemical group C1(=CC=CC1)* 0.000 description 6
238000006297 dehydration reaction Methods 0.000 description 6
KWGKDLIKAYFUFQ-UHFFFAOYSA-M lithium chloride Chemical compound [Li+].[Cl-] KWGKDLIKAYFUFQ-UHFFFAOYSA-M 0.000 description 6
239000000203 mixture Substances 0.000 description 6
150000003839 salts Chemical class 0.000 description 6
GKPQATDUBIVTSI-UHFFFAOYSA-L C[Si](=CC1=CC2=CSCC2=C1)C.[Cl-].[Cl-].[Zr+2] Chemical compound C[Si](=CC1=CC2=CSCC2=C1)C.[Cl-].[Cl-].[Zr+2] GKPQATDUBIVTSI-UHFFFAOYSA-L 0.000 description 5
MZQPVBRTTLTWGW-UHFFFAOYSA-L C[Si](=CC=1C=C2OCC=C2C1)C.[Cl-].[Cl-].[Zr+2] Chemical compound C[Si](=CC=1C=C2OCC=C2C1)C.[Cl-].[Cl-].[Zr+2] MZQPVBRTTLTWGW-UHFFFAOYSA-L 0.000 description 5
239000000969 carrier Substances 0.000 description 5
239000000463 material Substances 0.000 description 5
150000002736 metal compounds Chemical class 0.000 description 5
OFBQJSOFQDEBGM-UHFFFAOYSA-N n-pentane Natural products CCCCC OFBQJSOFQDEBGM-UHFFFAOYSA-N 0.000 description 5
230000035484 reaction time Effects 0.000 description 5
WFMWNJXHNPVTMO-UHFFFAOYSA-N (2,3,6-trifluorophenoxy)boronic acid Chemical compound OB(O)OC1=C(F)C=CC(F)=C1F WFMWNJXHNPVTMO-UHFFFAOYSA-N 0.000 description 4
DZETZMSAJDMAKS-UHFFFAOYSA-L Cl[Zr]Cl.[CH]1C(C)=CC2=C1C=CC=C2C1=CC=CC=C1 Chemical compound Cl[Zr]Cl.[CH]1C(C)=CC2=C1C=CC=C2C1=CC=CC=C1 DZETZMSAJDMAKS-UHFFFAOYSA-L 0.000 description 4
VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 description 4
JGFZNNIVVJXRND-UHFFFAOYSA-N N,N-Diisopropylethylamine (DIPEA) Chemical compound CCN(C(C)C)C(C)C JGFZNNIVVJXRND-UHFFFAOYSA-N 0.000 description 4
239000004743 Polypropylene Substances 0.000 description 4
125000001931 aliphatic group Chemical group 0.000 description 4
229910052784 alkaline earth metal Inorganic materials 0.000 description 4
239000002216 antistatic agent Substances 0.000 description 4
125000004429 atom Chemical group 0.000 description 4
CADWTSSKOVRVJC-UHFFFAOYSA-N benzyl(dimethyl)azanium;chloride Chemical compound [Cl-].C[NH+](C)CC1=CC=CC=C1 CADWTSSKOVRVJC-UHFFFAOYSA-N 0.000 description 4
150000001642 boronic acid derivatives Chemical class 0.000 description 4
230000018044 dehydration Effects 0.000 description 4
230000000694 effects Effects 0.000 description 4
125000002887 hydroxy group Chemical group [H]O* 0.000 description 4
JRZJOMJEPLMPRA-UHFFFAOYSA-N olefin Natural products CCCCCCCC=C JRZJOMJEPLMPRA-UHFFFAOYSA-N 0.000 description 4
229920001155 polypropylene Polymers 0.000 description 4
239000011148 porous material Substances 0.000 description 4
239000000843 powder Substances 0.000 description 4
230000004044 response Effects 0.000 description 4
239000000725 suspension Substances 0.000 description 4
VOITXYVAKOUIBA-UHFFFAOYSA-N triethylaluminium Chemical compound CC[Al](CC)CC VOITXYVAKOUIBA-UHFFFAOYSA-N 0.000 description 4
MCULRUJILOGHCJ-UHFFFAOYSA-N triisobutylaluminium Chemical compound CC(C)C[Al](CC(C)C)CC(C)C MCULRUJILOGHCJ-UHFFFAOYSA-N 0.000 description 4
RURFJXKOXIWFJX-UHFFFAOYSA-N (2,3,4,6-tetrafluorophenoxy)boronic acid Chemical compound OB(O)OC1=C(F)C=C(F)C(F)=C1F RURFJXKOXIWFJX-UHFFFAOYSA-N 0.000 description 3
LIKMAJRDDDTEIG-UHFFFAOYSA-N 1-hexene Chemical compound CCCCC=C LIKMAJRDDDTEIG-UHFFFAOYSA-N 0.000 description 3
238000004293 19F NMR spectroscopy Methods 0.000 description 3
SFJZQGYBQXBYDT-UHFFFAOYSA-L C[Si](=CC1=CC2=CN=CC2=C1)C.[Cl-].[Cl-].[Zr+2] Chemical compound C[Si](=CC1=CC2=CN=CC2=C1)C.[Cl-].[Cl-].[Zr+2] SFJZQGYBQXBYDT-UHFFFAOYSA-L 0.000 description 3
JIJRFIGFKMTHCB-UHFFFAOYSA-L C[Si](=CC1=CC2=COCC2=C1)C.[Cl-].[Cl-].[Zr+2] Chemical compound C[Si](=CC1=CC2=COCC2=C1)C.[Cl-].[Cl-].[Zr+2] JIJRFIGFKMTHCB-UHFFFAOYSA-L 0.000 description 3
238000005481 NMR spectroscopy Methods 0.000 description 3
VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 3
ZLVQLTSJKUTCNH-UHFFFAOYSA-L [Cl-].[Cl-].[Zr+2].C[Si](=CC1=NC2=CC(=CC2=C1)C)C Chemical compound [Cl-].[Cl-].[Zr+2].C[Si](=CC1=NC2=CC(=CC2=C1)C)C ZLVQLTSJKUTCNH-UHFFFAOYSA-L 0.000 description 3
239000003513 alkali Substances 0.000 description 3
239000003849 aromatic solvent Substances 0.000 description 3
125000001797 benzyl group Chemical group [H]C1=C([H])C([H])=C(C([H])=C1[H])C([H])([H])* 0.000 description 3
238000004140 cleaning Methods 0.000 description 3
229920001577 copolymer Polymers 0.000 description 3
239000000706 filtrate Substances 0.000 description 3
125000005843 halogen group Chemical group 0.000 description 3
150000002430 hydrocarbons Chemical group 0.000 description 3
239000001257 hydrogen Substances 0.000 description 3
229910052739 hydrogen Inorganic materials 0.000 description 3
229910052809 inorganic oxide Inorganic materials 0.000 description 3
ZEFLPHRHPMEVPM-UHFFFAOYSA-N n,n-dimethylcyclopentanamine Chemical compound CN(C)C1CCCC1 ZEFLPHRHPMEVPM-UHFFFAOYSA-N 0.000 description 3
ISRXMEYARGEVIU-UHFFFAOYSA-N n-methyl-n-propan-2-ylpropan-2-amine Chemical compound CC(C)N(C)C(C)C ISRXMEYARGEVIU-UHFFFAOYSA-N 0.000 description 3
239000002245 particle Substances 0.000 description 3
239000002244 precipitate Substances 0.000 description 3
125000002914 sec-butyl group Chemical group [H]C([H])([H])C([H])([H])C([H])(*)C([H])([H])[H] 0.000 description 3
YLQBMQCUIZJEEH-UHFFFAOYSA-N tetrahydrofuran Natural products C=1C=COC=1 YLQBMQCUIZJEEH-UHFFFAOYSA-N 0.000 description 3
229910052719 titanium Inorganic materials 0.000 description 3
239000010936 titanium Substances 0.000 description 3
ZWYDDDAMNQQZHD-UHFFFAOYSA-L titanium(ii) chloride Chemical compound [Cl-].[Cl-].[Ti+2] ZWYDDDAMNQQZHD-UHFFFAOYSA-L 0.000 description 3
229910052723 transition metal Inorganic materials 0.000 description 3
150000003624 transition metals Chemical group 0.000 description 3
JLTRXTDYQLMHGR-UHFFFAOYSA-N trimethylaluminium Chemical compound C[Al](C)C JLTRXTDYQLMHGR-UHFFFAOYSA-N 0.000 description 3
OUHOZBRDLAZZLQ-UHFFFAOYSA-N (2,3,5,6-tetrafluorophenoxy)boronic acid Chemical compound OB(O)OC1=C(F)C(F)=CC(F)=C1F OUHOZBRDLAZZLQ-UHFFFAOYSA-N 0.000 description 2
PRBHEGAFLDMLAL-GQCTYLIASA-N (4e)-hexa-1,4-diene Chemical compound C\C=C\CC=C PRBHEGAFLDMLAL-GQCTYLIASA-N 0.000 description 2
125000000008 (C1-C10) alkyl group Chemical group 0.000 description 2
125000004642 (C1-C12) alkoxy group Chemical group 0.000 description 2
125000006736 (C6-C20) aryl group Chemical group 0.000 description 2
RFFLAFLAYFXFSW-UHFFFAOYSA-N 1,2-dichlorobenzene Chemical compound ClC1=CC=CC=C1Cl RFFLAFLAYFXFSW-UHFFFAOYSA-N 0.000 description 2
VXNZUUAINFGPBY-UHFFFAOYSA-N 1-Butene Chemical compound CCC=C VXNZUUAINFGPBY-UHFFFAOYSA-N 0.000 description 2
AFFLGGQVNFXPEV-UHFFFAOYSA-N 1-decene Chemical compound CCCCCCCCC=C AFFLGGQVNFXPEV-UHFFFAOYSA-N 0.000 description 2
KWKAKUADMBZCLK-UHFFFAOYSA-N 1-octene Chemical compound CCCCCCC=C KWKAKUADMBZCLK-UHFFFAOYSA-N 0.000 description 2
INQYGHQWXMXAIN-UHFFFAOYSA-N 2-ethyl-n,n-dimethylbutan-1-amine Chemical compound CCC(CC)CN(C)C INQYGHQWXMXAIN-UHFFFAOYSA-N 0.000 description 2
OQADVBLQZQTGLL-UHFFFAOYSA-N 2-ethyl-n,n-dimethylhexan-1-amine Chemical compound CCCCC(CC)CN(C)C OQADVBLQZQTGLL-UHFFFAOYSA-N 0.000 description 2
JZHVQPOCGIHICO-UHFFFAOYSA-N 2-ethyl-n,n-dimethylpentan-1-amine Chemical compound CCCC(CC)CN(C)C JZHVQPOCGIHICO-UHFFFAOYSA-N 0.000 description 2
125000003229 2-methylhexyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])(C([H])([H])[H])C([H])([H])* 0.000 description 2
125000004337 3-ethylpentyl group Chemical group [H]C([H])([H])C([H])([H])C([H])(C([H])([H])C([H])([H])[H])C([H])([H])C([H])([H])* 0.000 description 2
125000003469 3-methylhexyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])(C([H])([H])[H])C([H])([H])C([H])([H])* 0.000 description 2
JLAUIBFZZUVOBB-UHFFFAOYSA-N 3-methylpentan-1-amine Chemical compound CCC(C)CCN JLAUIBFZZUVOBB-UHFFFAOYSA-N 0.000 description 2
WSSSPWUEQFSQQG-UHFFFAOYSA-N 4-methyl-1-pentene Chemical compound CC(C)CC=C WSSSPWUEQFSQQG-UHFFFAOYSA-N 0.000 description 2
IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 2
KAKZBPTYRLMSJV-UHFFFAOYSA-N Butadiene Chemical compound C=CC=C KAKZBPTYRLMSJV-UHFFFAOYSA-N 0.000 description 2
125000006374 C2-C10 alkenyl group Chemical group 0.000 description 2
YNQLUTRBYVCPMQ-UHFFFAOYSA-N Ethylbenzene Chemical compound CCC1=CC=CC=C1 YNQLUTRBYVCPMQ-UHFFFAOYSA-N 0.000 description 2
VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 description 2
UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 2
GSCCALZHGUWNJW-UHFFFAOYSA-N N-Cyclohexyl-N-methylcyclohexanamine Chemical compound C1CCCCC1N(C)C1CCCCC1 GSCCALZHGUWNJW-UHFFFAOYSA-N 0.000 description 2
PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 description 2
RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 description 2
KUNZSLJMPCDOGI-UHFFFAOYSA-L [Cl-].[Cl-].[Hf+2] Chemical compound [Cl-].[Cl-].[Hf+2] KUNZSLJMPCDOGI-UHFFFAOYSA-L 0.000 description 2
230000003213 activating effect Effects 0.000 description 2
150000001342 alkaline earth metals Chemical class 0.000 description 2
125000003342 alkenyl group Chemical group 0.000 description 2
RWZYAGGXGHYGMB-UHFFFAOYSA-N anthranilic acid Chemical compound NC1=CC=CC=C1C(O)=O RWZYAGGXGHYGMB-UHFFFAOYSA-N 0.000 description 2
150000004945 aromatic hydrocarbons Chemical class 0.000 description 2
125000005018 aryl alkenyl group Chemical group 0.000 description 2
230000000711 cancerogenic effect Effects 0.000 description 2
231100000315 carcinogenic Toxicity 0.000 description 2
IJOOHPMOJXWVHK-UHFFFAOYSA-N chlorotrimethylsilane Chemical compound C[Si](C)(C)Cl IJOOHPMOJXWVHK-UHFFFAOYSA-N 0.000 description 2
230000000536 complexating effect Effects 0.000 description 2
125000000582 cycloheptyl group Chemical group [H]C1([H])C([H])([H])C([H])([H])C([H])([H])C([H])(*)C([H])([H])C1([H])[H] 0.000 description 2
125000000113 cyclohexyl group Chemical group [H]C1([H])C([H])([H])C([H])([H])C([H])(*)C([H])([H])C1([H])[H] 0.000 description 2
KBXRGBYSPXRSOZ-UHFFFAOYSA-N cyclohexyl(dimethyl)azanium;chloride Chemical compound Cl.CN(C)C1CCCCC1 KBXRGBYSPXRSOZ-UHFFFAOYSA-N 0.000 description 2
125000000640 cyclooctyl group Chemical group [H]C1([H])C([H])([H])C([H])([H])C([H])([H])C([H])(*)C([H])([H])C([H])([H])C1([H])[H] 0.000 description 2
235000014113 dietary fatty acids Nutrition 0.000 description 2
CEDZUBPESYQRPL-UHFFFAOYSA-N dimethylazanide;zirconium(2+) Chemical compound [Zr+2].C[N-]C.C[N-]C CEDZUBPESYQRPL-UHFFFAOYSA-N 0.000 description 2
238000009826 distribution Methods 0.000 description 2
125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 description 2
239000000194 fatty acid Substances 0.000 description 2
229930195729 fatty acid Natural products 0.000 description 2
150000004665 fatty acids Chemical class 0.000 description 2
125000003709 fluoroalkyl group Chemical group 0.000 description 2
125000004407 fluoroaryl group Chemical group 0.000 description 2
229910052735 hafnium Inorganic materials 0.000 description 2
125000001072 heteroaryl group Chemical group 0.000 description 2
229930195733 hydrocarbon Natural products 0.000 description 2
239000011261 inert gas Substances 0.000 description 2
150000002500 ions Chemical class 0.000 description 2
125000000959 isobutyl group Chemical group [H]C([H])([H])C([H])(C([H])([H])[H])C([H])([H])* 0.000 description 2
125000004491 isohexyl group Chemical group C(CCC(C)C)* 0.000 description 2
239000011777 magnesium Substances 0.000 description 2
VNWKTOKETHGBQD-UHFFFAOYSA-N methane Chemical compound C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 description 2
UNSDWONDAUAWPV-UHFFFAOYSA-N methylaluminum;oxane Chemical compound [Al]C.C1CCOCC1 UNSDWONDAUAWPV-UHFFFAOYSA-N 0.000 description 2
231100000219 mutagenic Toxicity 0.000 description 2
230000003505 mutagenic effect Effects 0.000 description 2
DLAZAKAUHNPOJH-UHFFFAOYSA-N n,2-diethyl-n-methylbutan-1-amine Chemical compound CCC(CC)CN(C)CC DLAZAKAUHNPOJH-UHFFFAOYSA-N 0.000 description 2
GXDMXOLBLNHBQG-UHFFFAOYSA-N n,2-diethyl-n-methylhexan-1-amine Chemical compound CCCCC(CC)CN(C)CC GXDMXOLBLNHBQG-UHFFFAOYSA-N 0.000 description 2
BSAMKPOGCZWWEW-UHFFFAOYSA-N n,2-diethyl-n-methylpentan-1-amine Chemical compound CCCC(CC)CN(C)CC BSAMKPOGCZWWEW-UHFFFAOYSA-N 0.000 description 2
BQEDEIIIGXEIFG-UHFFFAOYSA-N n,n,2-triethylbutan-1-amine Chemical compound CCC(CC)CN(CC)CC BQEDEIIIGXEIFG-UHFFFAOYSA-N 0.000 description 2
TXQIZBKYTFVWRG-UHFFFAOYSA-N n,n,2-triethylhexan-1-amine Chemical compound CCCCC(CC)CN(CC)CC TXQIZBKYTFVWRG-UHFFFAOYSA-N 0.000 description 2
NLBQFOYRFDNSDU-UHFFFAOYSA-N n,n,2-triethylpentan-1-amine Chemical compound CCCC(CC)CN(CC)CC NLBQFOYRFDNSDU-UHFFFAOYSA-N 0.000 description 2
BHMZPPHMQJHCHQ-UHFFFAOYSA-N n,n,2-trimethylbutan-1-amine Chemical compound CCC(C)CN(C)C BHMZPPHMQJHCHQ-UHFFFAOYSA-N 0.000 description 2
VOSQGFKRKRRUOT-UHFFFAOYSA-N n,n,2-trimethylhexan-1-amine Chemical compound CCCCC(C)CN(C)C VOSQGFKRKRRUOT-UHFFFAOYSA-N 0.000 description 2
JRHGZGWIJIJJTE-UHFFFAOYSA-N n,n-diethyl-2-methylbutan-1-amine Chemical compound CCC(C)CN(CC)CC JRHGZGWIJIJJTE-UHFFFAOYSA-N 0.000 description 2
WOJNVNZNZOHVCY-UHFFFAOYSA-N n,n-diethyl-2-methylhexan-1-amine Chemical compound CCCCC(C)CN(CC)CC WOJNVNZNZOHVCY-UHFFFAOYSA-N 0.000 description 2
HXPXISSNEJVFRA-UHFFFAOYSA-N n,n-diethylbutan-2-amine Chemical compound CCC(C)N(CC)CC HXPXISSNEJVFRA-UHFFFAOYSA-N 0.000 description 2
ULWOJODHECIZAU-UHFFFAOYSA-N n,n-diethylpropan-2-amine Chemical compound CCN(CC)C(C)C ULWOJODHECIZAU-UHFFFAOYSA-N 0.000 description 2
USSPHSVODLAWSA-UHFFFAOYSA-N n,n-dimethylbutan-2-amine Chemical compound CCC(C)N(C)C USSPHSVODLAWSA-UHFFFAOYSA-N 0.000 description 2
QKMDVMAZORRHAL-UHFFFAOYSA-N n,n-dimethylcyclooctanamine Chemical compound CN(C)C1CCCCCCC1 QKMDVMAZORRHAL-UHFFFAOYSA-N 0.000 description 2
VMOWKUTXPNPTEN-UHFFFAOYSA-N n,n-dimethylpropan-2-amine Chemical compound CC(C)N(C)C VMOWKUTXPNPTEN-UHFFFAOYSA-N 0.000 description 2
XRKQMIFKHDXFNQ-UHFFFAOYSA-N n-cyclohexyl-n-ethylcyclohexanamine Chemical compound C1CCCCC1N(CC)C1CCCCC1 XRKQMIFKHDXFNQ-UHFFFAOYSA-N 0.000 description 2
FDVGAMJGVBLLES-UHFFFAOYSA-N n-ethyl-n,2-dimethylbutan-1-amine Chemical compound CCC(C)CN(C)CC FDVGAMJGVBLLES-UHFFFAOYSA-N 0.000 description 2
QQWXQKMVASVXCI-UHFFFAOYSA-N n-ethyl-n,2-dimethylpropan-1-amine Chemical compound CCN(C)CC(C)C QQWXQKMVASVXCI-UHFFFAOYSA-N 0.000 description 2
HAFZSBASGRZPLA-UHFFFAOYSA-N n-ethyl-n-methylbutan-2-amine Chemical compound CCC(C)N(C)CC HAFZSBASGRZPLA-UHFFFAOYSA-N 0.000 description 2
PSRABQSGTFZLOM-UHFFFAOYSA-N n-ethyl-n-methylcyclohexanamine Chemical compound CCN(C)C1CCCCC1 PSRABQSGTFZLOM-UHFFFAOYSA-N 0.000 description 2
UTLDDSNRFHWERZ-UHFFFAOYSA-N n-ethyl-n-methylpropan-2-amine Chemical compound CCN(C)C(C)C UTLDDSNRFHWERZ-UHFFFAOYSA-N 0.000 description 2
SJYNFBVQFBRSIB-UHFFFAOYSA-N norbornadiene Chemical compound C1=CC2C=CC1C2 SJYNFBVQFBRSIB-UHFFFAOYSA-N 0.000 description 2
125000002347 octyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 2
150000002902 organometallic compounds Chemical class 0.000 description 2
125000003538 pentan-3-yl group Chemical group [H]C([H])([H])C([H])([H])C([H])(*)C([H])([H])C([H])([H])[H] 0.000 description 2
YWAKXRMUMFPDSH-UHFFFAOYSA-N pentene Chemical compound CCCC=C YWAKXRMUMFPDSH-UHFFFAOYSA-N 0.000 description 2
239000002574 poison Substances 0.000 description 2
231100000614 poison Toxicity 0.000 description 2
229920000768 polyamine Polymers 0.000 description 2
229910052710 silicon Inorganic materials 0.000 description 2
239000010703 silicon Substances 0.000 description 2
239000000126 substance Substances 0.000 description 2
239000000375 suspending agent Substances 0.000 description 2
231100000331 toxic Toxicity 0.000 description 2
230000002588 toxic effect Effects 0.000 description 2
125000004178 (C1-C4) alkyl group Chemical group 0.000 description 1
125000004169 (C1-C6) alkyl group Chemical group 0.000 description 1
CYCRXMMOJQBQMU-UHFFFAOYSA-N 1,1-dimethyl-2-(4-methylphenyl)hydrazine Chemical compound CN(C)NC1=CC=C(C)C=C1 CYCRXMMOJQBQMU-UHFFFAOYSA-N 0.000 description 1
ABIPLJQFLRXYES-UHFFFAOYSA-N 1,2,3,3a-tetrahydropentalene Chemical class C1=CC=C2CCCC21 ABIPLJQFLRXYES-UHFFFAOYSA-N 0.000 description 1
BIEBZGCKLFWMCR-UHFFFAOYSA-N 2,3,3a,4-tetrahydro-1h-indene Chemical class C1C=CC=C2CCCC21 BIEBZGCKLFWMCR-UHFFFAOYSA-N 0.000 description 1
IUXHSTUILLNWRM-UHFFFAOYSA-J 2,4-dimethylphenolate zirconium(4+) Chemical compound [Zr+4].CC1=CC=C([O-])C(C)=C1.CC1=CC=C([O-])C(C)=C1.CC1=CC=C([O-])C(C)=C1.CC1=CC=C([O-])C(C)=C1 IUXHSTUILLNWRM-UHFFFAOYSA-J 0.000 description 1
BKQYOTCGNDVZCR-UHFFFAOYSA-N 2-(octadecylamino)benzoic acid Chemical class CCCCCCCCCCCCCCCCCCNC1=CC=CC=C1C(O)=O BKQYOTCGNDVZCR-UHFFFAOYSA-N 0.000 description 1
VPCAZZICACQNKZ-UHFFFAOYSA-N 2-Ethyl-N-(2-ethylhexyl)-N-methyl-1-hexanamine Chemical compound CCCCC(CC)CN(C)CC(CC)CCCC VPCAZZICACQNKZ-UHFFFAOYSA-N 0.000 description 1
DIOYAVUHUXAUPX-ZHACJKMWSA-N 2-[methyl-[(e)-octadec-9-enoyl]amino]acetic acid Chemical compound CCCCCCCC\C=C\CCCCCCCC(=O)N(C)CC(O)=O DIOYAVUHUXAUPX-ZHACJKMWSA-N 0.000 description 1
XHRCFGDFESIFRG-UHFFFAOYSA-N 2-chloro-n-ethyl-n-[(2-methylphenyl)methyl]ethanamine Chemical compound ClCCN(CC)CC1=CC=CC=C1C XHRCFGDFESIFRG-UHFFFAOYSA-N 0.000 description 1
WBIQQQGBSDOWNP-UHFFFAOYSA-N 2-dodecylbenzenesulfonic acid Chemical compound CCCCCCCCCCCCC1=CC=CC=C1S(O)(=O)=O WBIQQQGBSDOWNP-UHFFFAOYSA-N 0.000 description 1
ZHBQELPBAQWROB-UHFFFAOYSA-N 2-ethyl-n-(2-ethylbutyl)-n-methylbutan-1-amine Chemical compound CCC(CC)CN(C)CC(CC)CC ZHBQELPBAQWROB-UHFFFAOYSA-N 0.000 description 1
IAKXHGZNNCCOKN-UHFFFAOYSA-J 2-ethylphenolate zirconium(4+) Chemical compound C(C)C1=C([O-])C=CC=C1.[Zr+4].C(C)C1=C([O-])C=CC=C1.C(C)C1=C([O-])C=CC=C1.C(C)C1=C([O-])C=CC=C1 IAKXHGZNNCCOKN-UHFFFAOYSA-J 0.000 description 1
VSYZXASVWVQEMR-UHFFFAOYSA-N 2-methylbuta-1,3-dienylalumane Chemical compound CC(=C[AlH2])C=C VSYZXASVWVQEMR-UHFFFAOYSA-N 0.000 description 1
SDTMFDGELKWGFT-UHFFFAOYSA-N 2-methylpropan-2-olate Chemical compound CC(C)(C)[O-] SDTMFDGELKWGFT-UHFFFAOYSA-N 0.000 description 1
GTJOHISYCKPIMT-UHFFFAOYSA-N 2-methylundecane Chemical compound CCCCCCCCCC(C)C GTJOHISYCKPIMT-UHFFFAOYSA-N 0.000 description 1
NAOXXKNFQYQSNZ-UHFFFAOYSA-N 3-ethyl-n,n-dimethylhexan-1-amine Chemical compound CCCC(CC)CCN(C)C NAOXXKNFQYQSNZ-UHFFFAOYSA-N 0.000 description 1
BQRNQSBEUJWIAS-UHFFFAOYSA-N 3-ethyl-n,n-dimethylpentan-1-amine Chemical compound CCC(CC)CCN(C)C BQRNQSBEUJWIAS-UHFFFAOYSA-N 0.000 description 1
VXEGSRKPIUDPQT-UHFFFAOYSA-N 4-[4-(4-methoxyphenyl)piperazin-1-yl]aniline Chemical compound C1=CC(OC)=CC=C1N1CCN(C=2C=CC(N)=CC=2)CC1 VXEGSRKPIUDPQT-UHFFFAOYSA-N 0.000 description 1
ULHXWMDHZFEUJY-UHFFFAOYSA-N 4-ethyl-n,n-dimethylhexan-1-amine Chemical compound CCC(CC)CCCN(C)C ULHXWMDHZFEUJY-UHFFFAOYSA-N 0.000 description 1
RMDKEBZUCHXUER-UHFFFAOYSA-N 4-methylbicyclo[2.2.1]hept-2-ene Chemical compound C1CC2C=CC1(C)C2 RMDKEBZUCHXUER-UHFFFAOYSA-N 0.000 description 1
FJJOBPGZEJKTNK-UHFFFAOYSA-J 4-methylphenolate zirconium(4+) Chemical compound [Zr+4].Cc1ccc([O-])cc1.Cc1ccc([O-])cc1.Cc1ccc([O-])cc1.Cc1ccc([O-])cc1 FJJOBPGZEJKTNK-UHFFFAOYSA-J 0.000 description 1
INYHZQLKOKTDAI-UHFFFAOYSA-N 5-ethenylbicyclo[2.2.1]hept-2-ene Chemical compound C1C2C(C=C)CC1C=C2 INYHZQLKOKTDAI-UHFFFAOYSA-N 0.000 description 1
WUKFGBUJEPLCSN-UHFFFAOYSA-N 5-methyl-2h-cyclopenta[b]thiophene Chemical compound C1SC2=CC(C)=CC2=C1 WUKFGBUJEPLCSN-UHFFFAOYSA-N 0.000 description 1
RMNKHKYRLLFLPT-UHFFFAOYSA-N 5-methylcyclopenta[c]pyrrole Chemical compound N1=CC2=CC(C)=CC2=C1 RMNKHKYRLLFLPT-UHFFFAOYSA-N 0.000 description 1
NLXLAEXVIDQMFP-UHFFFAOYSA-N Ammonia chloride Chemical compound [NH4+].[Cl-] NLXLAEXVIDQMFP-UHFFFAOYSA-N 0.000 description 1
JIOQEGRWISYKGL-UHFFFAOYSA-N C(C)(C)(C)[NH-].[Zr+4].C(C)(C)(C)[NH-].C(C)(C)(C)[NH-].C(C)(C)(C)[NH-] Chemical compound C(C)(C)(C)[NH-].[Zr+4].C(C)(C)(C)[NH-].C(C)(C)(C)[NH-].C(C)(C)(C)[NH-] JIOQEGRWISYKGL-UHFFFAOYSA-N 0.000 description 1
HNRPUSUZWWREBP-UHFFFAOYSA-N C(C)N(C1CCC(CC1)(C)C)C1CCC(CC1)(C)C Chemical compound C(C)N(C1CCC(CC1)(C)C)C1CCC(CC1)(C)C HNRPUSUZWWREBP-UHFFFAOYSA-N 0.000 description 1
GAVPEITVUYUXAB-UHFFFAOYSA-J C1(=CC=CC=C1)C1=C([O-])C=CC=C1.[Zr+4].C1(=CC=CC=C1)C1=C([O-])C=CC=C1.C1(=CC=CC=C1)C1=C([O-])C=CC=C1.C1(=CC=CC=C1)C1=C([O-])C=CC=C1 Chemical compound C1(=CC=CC=C1)C1=C([O-])C=CC=C1.[Zr+4].C1(=CC=CC=C1)C1=C([O-])C=CC=C1.C1(=CC=CC=C1)C1=C([O-])C=CC=C1.C1(=CC=CC=C1)C1=C([O-])C=CC=C1 GAVPEITVUYUXAB-UHFFFAOYSA-J 0.000 description 1
ALIHCGVCSLWOAX-UHFFFAOYSA-J C1(C=CC2=CC=CC=C12)[Zr+3].C[Si](=CC1=CC2=COCC2=C1)C.[Cl-].[Cl-].C1(C=CC2=CC=CC=C12)[Zr+3].C[Si](=CC1=CC2=CCOC2=C1)C.[Cl-].[Cl-] Chemical compound C1(C=CC2=CC=CC=C12)[Zr+3].C[Si](=CC1=CC2=COCC2=C1)C.[Cl-].[Cl-].C1(C=CC2=CC=CC=C12)[Zr+3].C[Si](=CC1=CC2=CCOC2=C1)C.[Cl-].[Cl-] ALIHCGVCSLWOAX-UHFFFAOYSA-J 0.000 description 1
NWLATAZBCUUHBV-UHFFFAOYSA-N CC(C(C1=CC=C2)[Zr](C3C4=CC=CC(C5=CC=CC=C5)=C4C=C3C)=[Si](C)C)=CC1=C2C1=CC=CC=C1.CC(C(C1=CC=C2)[Zr](C3C4=CC=CC(C5=CC6=CC=CC=C6C=C5)=C4C=C3C)=[Si](C)C)=CC1=C2C1=CC2=CC=CC=C2C=C1.Cl.Cl.Cl.Cl Chemical compound CC(C(C1=CC=C2)[Zr](C3C4=CC=CC(C5=CC=CC=C5)=C4C=C3C)=[Si](C)C)=CC1=C2C1=CC=CC=C1.CC(C(C1=CC=C2)[Zr](C3C4=CC=CC(C5=CC6=CC=CC=C6C=C5)=C4C=C3C)=[Si](C)C)=CC1=C2C1=CC2=CC=CC=C2C=C1.Cl.Cl.Cl.Cl NWLATAZBCUUHBV-UHFFFAOYSA-N 0.000 description 1
HNLHIFWNMSJZTF-UHFFFAOYSA-N CC(C)C1=C(C=C(C)C2[Zr](C3C4=CC=CC(C(C)C)=C4C=C3C)=[Si](C)C)C2=CC=C1.CC(C)(C)C1=C(C=C(C)C2[Zr](C3C4=CC=CC(C(C)(C)C)=C4C=C3C)=[Si](C)C)C2=CC=C1.Cl.Cl.Cl.Cl Chemical compound CC(C)C1=C(C=C(C)C2[Zr](C3C4=CC=CC(C(C)C)=C4C=C3C)=[Si](C)C)C2=CC=C1.CC(C)(C)C1=C(C=C(C)C2[Zr](C3C4=CC=CC(C(C)(C)C)=C4C=C3C)=[Si](C)C)C2=CC=C1.Cl.Cl.Cl.Cl HNLHIFWNMSJZTF-UHFFFAOYSA-N 0.000 description 1
GEBHAPKJACULJB-UHFFFAOYSA-J CC(C)C1=CC(C(C)C)=C(C=C(C)C2[Zr](C3C4=CC(C(C)C)=CC(C(C)C)=C4C=C3C)=[Si](C)C)C2=C1.CC(C)C1=CC=C(C(C(C)=C2)[Zr](C3C4=CC=C(C(C)C)C(C(C)C)=C4C=C3C)=[Si](C)C)C2=C1C(C)C.[Cl-].[Cl-].[Cl-].[Cl-].Cl.Cl.[Zr+4] Chemical compound CC(C)C1=CC(C(C)C)=C(C=C(C)C2[Zr](C3C4=CC(C(C)C)=CC(C(C)C)=C4C=C3C)=[Si](C)C)C2=C1.CC(C)C1=CC=C(C(C(C)=C2)[Zr](C3C4=CC=C(C(C)C)C(C(C)C)=C4C=C3C)=[Si](C)C)C2=C1C(C)C.[Cl-].[Cl-].[Cl-].[Cl-].Cl.Cl.[Zr+4] GEBHAPKJACULJB-UHFFFAOYSA-J 0.000 description 1
WUUJIJLSJCGQKS-UHFFFAOYSA-N CC(C)CC1=CC=C(C(C(C)=C2)[Zr](C3C4=CC=C(CC(C)C)C=C4C=C3C)=[Si](C)C)C2=C1.CC(C)(C)C1=CC=C(C(C(C)=C2)[Zr](C3C4=CC=C(C(C)(C)C)C=C4C=C3C)=[Si](C)C)C2=C1.Cl.Cl.Cl.Cl.Cl.Cl Chemical compound CC(C)CC1=CC=C(C(C(C)=C2)[Zr](C3C4=CC=C(CC(C)C)C=C4C=C3C)=[Si](C)C)C2=C1.CC(C)(C)C1=CC=C(C(C(C)=C2)[Zr](C3C4=CC=C(C(C)(C)C)C=C4C=C3C)=[Si](C)C)C2=C1.Cl.Cl.Cl.Cl.Cl.Cl WUUJIJLSJCGQKS-UHFFFAOYSA-N 0.000 description 1
VWTVXOSCPQSDLG-UHFFFAOYSA-L CC(C)c1cccc2C(C(C)=Cc12)[Zr](Cl)(Cl)(C1C(C)=Cc2c1cccc2C(C)C)=[Si](C)c1ccccc1 Chemical compound CC(C)c1cccc2C(C(C)=Cc12)[Zr](Cl)(Cl)(C1C(C)=Cc2c1cccc2C(C)C)=[Si](C)c1ccccc1 VWTVXOSCPQSDLG-UHFFFAOYSA-L 0.000 description 1
UINHOCLEQOISNK-UHFFFAOYSA-J CC(CC1=C(C2=CC=CC3=CC=CC4=C23)C4=C2)=CC1=C2[Zr](C1=C(C=C(C)C2)C2=C(C2=CC=CC3=CC=CC4=C23)C4=C1)=[Si](C)C1=CC=CC=C1.CC1=CC2=CC=CC=C2C1[Zr](C1C2=CC=CC=C2C=C1C)=[Si](C)C1=CC=CC=C1.[Cl-].[Cl-].[Cl-].[Cl-].Cl.Cl.[Zr+4] Chemical compound CC(CC1=C(C2=CC=CC3=CC=CC4=C23)C4=C2)=CC1=C2[Zr](C1=C(C=C(C)C2)C2=C(C2=CC=CC3=CC=CC4=C23)C4=C1)=[Si](C)C1=CC=CC=C1.CC1=CC2=CC=CC=C2C1[Zr](C1C2=CC=CC=C2C=C1C)=[Si](C)C1=CC=CC=C1.[Cl-].[Cl-].[Cl-].[Cl-].Cl.Cl.[Zr+4] UINHOCLEQOISNK-UHFFFAOYSA-J 0.000 description 1
OXLXAPYJCPFBFT-UHFFFAOYSA-L CC1=CC(C)(C=C1)[Zr](Cl)(Cl)C1(C)C=CC(C)=C1 Chemical compound CC1=CC(C)(C=C1)[Zr](Cl)(Cl)C1(C)C=CC(C)=C1 OXLXAPYJCPFBFT-UHFFFAOYSA-L 0.000 description 1
INSFHIAEOGNTCK-UHFFFAOYSA-N CC1=CC2=CC(C)=C(C)C=C2C1[Zr](C1C2=CC(C)=C(C)C=C2C=C1C)=[Si](C)C.CC1=CC2=C(C)C=C(C)C=C2C1[Zr](C1C2=CC(C)=CC(C)=C2C=C1C)=[Si](C)C.CC1=CC2=C(C)C=CC(C)=C2C1[Zr](C1C2=C(C)C=CC(C)=C2C=C1C)=[Si](C)C.Cl.Cl.Cl.Cl Chemical compound CC1=CC2=CC(C)=C(C)C=C2C1[Zr](C1C2=CC(C)=C(C)C=C2C=C1C)=[Si](C)C.CC1=CC2=C(C)C=C(C)C=C2C1[Zr](C1C2=CC(C)=CC(C)=C2C=C1C)=[Si](C)C.CC1=CC2=C(C)C=CC(C)=C2C1[Zr](C1C2=C(C)C=CC(C)=C2C=C1C)=[Si](C)C.Cl.Cl.Cl.Cl INSFHIAEOGNTCK-UHFFFAOYSA-N 0.000 description 1
QJUAXGQDGMCGBZ-UHFFFAOYSA-N CC1=CC2=CC=C(C=CC=C3)C3=C2C1[Zr](C1C2=C(C=CC=C3)C3=CC=C2C=C1C)=[Si](C)C.C[Si](C)=[Zr](C1C2=CC=CC=C2C=C1)C1C2=CC=CC=C2C=C1.C[Si](C)=[Zr](C1C2=CC=CC(C3=CC=CC4=CC=CC=C34)=C2C=C1)C1C2=CC=CC(C3=CC=CC4=CC=CC=C34)=C2C=C1.Cl.Cl.Cl.Cl.Cl.Cl Chemical compound CC1=CC2=CC=C(C=CC=C3)C3=C2C1[Zr](C1C2=C(C=CC=C3)C3=CC=C2C=C1C)=[Si](C)C.C[Si](C)=[Zr](C1C2=CC=CC=C2C=C1)C1C2=CC=CC=C2C=C1.C[Si](C)=[Zr](C1C2=CC=CC(C3=CC=CC4=CC=CC=C34)=C2C=C1)C1C2=CC=CC(C3=CC=CC4=CC=CC=C34)=C2C=C1.Cl.Cl.Cl.Cl.Cl.Cl QJUAXGQDGMCGBZ-UHFFFAOYSA-N 0.000 description 1
IZYXSTPBQMPZGT-UHFFFAOYSA-N CC1=CC2=CC=CC=C2C1[Zr](C1C2=CC=CC=C2C=C1C)=[Si](C)C.CC(C(C1=CC=C2)[Zr](C3C4=CC=CC(C5=CC=CC6=CC=CC=C56)=C4C=C3C)=[Si](C)C)=CC1=C2C1=CC=CC2=CC=CC=C12.Cl.Cl.Cl.Cl Chemical compound CC1=CC2=CC=CC=C2C1[Zr](C1C2=CC=CC=C2C=C1C)=[Si](C)C.CC(C(C1=CC=C2)[Zr](C3C4=CC=CC(C5=CC=CC6=CC=CC=C56)=C4C=C3C)=[Si](C)C)=CC1=C2C1=CC=CC2=CC=CC=C12.Cl.Cl.Cl.Cl IZYXSTPBQMPZGT-UHFFFAOYSA-N 0.000 description 1
XZRIUDXXODHKDN-UHFFFAOYSA-J CC=1C=C(C=CC=1)O[Zr](OC1=CC(=CC=C1)C)(OC1=CC(=CC=C1)C)OC1=CC(=CC=C1)C Chemical compound CC=1C=C(C=CC=1)O[Zr](OC1=CC(=CC=C1)C)(OC1=CC(=CC=C1)C)OC1=CC(=CC=C1)C XZRIUDXXODHKDN-UHFFFAOYSA-J 0.000 description 1
MYUPRGBAFRDZFZ-UHFFFAOYSA-N CCC1=C(C=C(C)C2[Zr](C3C4=CC=CC(CC)=C4C=C3C)=[Si](C)C)C2=CC=C1.CC(CC1=C(C2=CC=CC3=CC=CC4=C23)C4=C2)=CC1=C2[Zr](C1=C(C=C(C)C2)C2=C(C2=CC=CC3=CC=CC4=C23)C4=C1)=[Si](C)C.Cl.Cl.Cl.Cl Chemical compound CCC1=C(C=C(C)C2[Zr](C3C4=CC=CC(CC)=C4C=C3C)=[Si](C)C)C2=CC=C1.CC(CC1=C(C2=CC=CC3=CC=CC4=C23)C4=C2)=CC1=C2[Zr](C1=C(C=C(C)C2)C2=C(C2=CC=CC3=CC=CC4=C23)C4=C1)=[Si](C)C.Cl.Cl.Cl.Cl MYUPRGBAFRDZFZ-UHFFFAOYSA-N 0.000 description 1
ZPIHXGSVXDIVHP-UHFFFAOYSA-N CCC1=CC2=CC=CC=C2C1[Zr](C1C2=CC=CC=C2C=C1CC)=[Si](C)C.CCC1=CC2=C(CC)C=CC=C2C1[Zr](C1C2=CC=CC(CC)=C2C=C1CC)=[Si](C)C.CC1=CC2=C(C)C=CC=C2C1[Zr](C1C2=CC=CC(C)=C2C=C1C)=[Si](C)C.Cl.Cl.Cl.Cl.Cl.Cl Chemical compound CCC1=CC2=CC=CC=C2C1[Zr](C1C2=CC=CC=C2C=C1CC)=[Si](C)C.CCC1=CC2=C(CC)C=CC=C2C1[Zr](C1C2=CC=CC(CC)=C2C=C1CC)=[Si](C)C.CC1=CC2=C(C)C=CC=C2C1[Zr](C1C2=CC=CC(C)=C2C=C1C)=[Si](C)C.Cl.Cl.Cl.Cl.Cl.Cl ZPIHXGSVXDIVHP-UHFFFAOYSA-N 0.000 description 1
ZQVDTPHKVJVFGG-UHFFFAOYSA-L CCC1=Cc2c(cccc2-c2ccccc2)C1[Zr](Cl)(Cl)(C1C(CC)=Cc2c1cccc2-c1ccccc1)=[Si](C)C Chemical compound CCC1=Cc2c(cccc2-c2ccccc2)C1[Zr](Cl)(Cl)(C1C(CC)=Cc2c1cccc2-c1ccccc1)=[Si](C)C ZQVDTPHKVJVFGG-UHFFFAOYSA-L 0.000 description 1
RNBFVXHRNOCMPO-UHFFFAOYSA-N CN(C)C(C)C.C(C1=CC=CC=C1)N1CCNCC1 Chemical compound CN(C)C(C)C.C(C1=CC=CC=C1)N1CCNCC1 RNBFVXHRNOCMPO-UHFFFAOYSA-N 0.000 description 1
DWFUSQKUSIHHOG-UHFFFAOYSA-N CN(C)C(CCC)CCCC.CN(C)C(CC)CCCCC Chemical compound CN(C)C(CCC)CCCC.CN(C)C(CC)CCCCC DWFUSQKUSIHHOG-UHFFFAOYSA-N 0.000 description 1
RYFQDXJVDRXHPI-UHFFFAOYSA-N CN(C)CC1=CC=CC=C1.C(C)N(NC1=CC=C(C=C1)C)CC Chemical compound CN(C)CC1=CC=CC=C1.C(C)N(NC1=CC=C(C=C1)C)CC RYFQDXJVDRXHPI-UHFFFAOYSA-N 0.000 description 1
RTSXHWVQEKMBEB-UHFFFAOYSA-N CN(C1CCC(CC1)(C)C)C1CCC(CC1)(C)C Chemical compound CN(C1CCC(CC1)(C)C)C1CCC(CC1)(C)C RTSXHWVQEKMBEB-UHFFFAOYSA-N 0.000 description 1
QGMHSTRDYFPFNT-UHFFFAOYSA-J C[Si](=CC1=CC2=CC(=CC2=N1)C)C.[Cl-].[Cl-].CC=1C(C2=CC=CC=C2C1)[Zr+3].C[Si](=CC1=NC2=CC(=CC2=C1)C)C.[Cl-].[Cl-].CC=1C(C2=CC=CC=C2C1)[Zr+3] Chemical compound C[Si](=CC1=CC2=CC(=CC2=N1)C)C.[Cl-].[Cl-].CC=1C(C2=CC=CC=C2C1)[Zr+3].C[Si](=CC1=NC2=CC(=CC2=C1)C)C.[Cl-].[Cl-].CC=1C(C2=CC=CC=C2C1)[Zr+3] QGMHSTRDYFPFNT-UHFFFAOYSA-J 0.000 description 1
MVMROCNZSAQJFO-UHFFFAOYSA-N C[Si](C)=CC1=CC2=CCSC2=C1.Cl.Cl Chemical compound C[Si](C)=CC1=CC2=CCSC2=C1.Cl.Cl MVMROCNZSAQJFO-UHFFFAOYSA-N 0.000 description 1
AFKFFMWEHJLZIG-UHFFFAOYSA-J C[Si](C=1C(=CC2=CCSC12)C)(C=1C(=CC2=CCSC12)C)C.[Cl-].[Cl-].[Zr+4].C[Si](C1=C(C=C2CSC=C12)C)(C1=C(C=C2CSC=C12)C)C.[Cl-].[Cl-].[Zr+4].C[Si](C1=C(C=C2SCC=C12)C)(C1=C(C=C2SCC=C12)C)C Chemical compound C[Si](C=1C(=CC2=CCSC12)C)(C=1C(=CC2=CCSC12)C)C.[Cl-].[Cl-].[Zr+4].C[Si](C1=C(C=C2CSC=C12)C)(C1=C(C=C2CSC=C12)C)C.[Cl-].[Cl-].[Zr+4].C[Si](C1=C(C=C2SCC=C12)C)(C1=C(C=C2SCC=C12)C)C AFKFFMWEHJLZIG-UHFFFAOYSA-J 0.000 description 1
239000004215 Carbon black (E152) Substances 0.000 description 1
AHJNKVQHFFADRI-UHFFFAOYSA-J Cc1ccccc1O[Zr](Oc1ccccc1C)(Oc1ccccc1C)Oc1ccccc1C Chemical compound Cc1ccccc1O[Zr](Oc1ccccc1C)(Oc1ccccc1C)Oc1ccccc1C AHJNKVQHFFADRI-UHFFFAOYSA-J 0.000 description 1
LYSPDWQBNFDNAH-UHFFFAOYSA-N Cl.Cl.C[Si](=CC1=CC2=CCOC2=C1)C Chemical compound Cl.Cl.C[Si](=CC1=CC2=CCOC2=C1)C LYSPDWQBNFDNAH-UHFFFAOYSA-N 0.000 description 1
229940126062 Compound A Drugs 0.000 description 1
MHZGKXUYDGKKIU-UHFFFAOYSA-N Decylamine Chemical compound CCCCCCCCCCN MHZGKXUYDGKKIU-UHFFFAOYSA-N 0.000 description 1
NLDMNSXOCDLTTB-UHFFFAOYSA-N Heterophylliin A Natural products O1C2COC(=O)C3=CC(O)=C(O)C(O)=C3C3=C(O)C(O)=C(O)C=C3C(=O)OC2C(OC(=O)C=2C=C(O)C(O)=C(O)C=2)C(O)C1OC(=O)C1=CC(O)=C(O)C(O)=C1 NLDMNSXOCDLTTB-UHFFFAOYSA-N 0.000 description 1
SGVYKUFIHHTIFL-UHFFFAOYSA-N Isobutylhexyl Natural products CCCCCCCC(C)C SGVYKUFIHHTIFL-UHFFFAOYSA-N 0.000 description 1
239000002841 Lewis acid Substances 0.000 description 1
FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 description 1
SGFLNXSZZZJNKA-UHFFFAOYSA-N N,N-diethyl-4,4-dimethylcyclohexan-1-amine Chemical compound C(C)N(CC)C1CCC(CC1)(C)C SGFLNXSZZZJNKA-UHFFFAOYSA-N 0.000 description 1
KSTAEHFRUXNFKQ-UHFFFAOYSA-N N-ethyl-N,4,4-trimethylcyclohexan-1-amine Chemical compound CN(CC)C1CCC(CC1)(C)C KSTAEHFRUXNFKQ-UHFFFAOYSA-N 0.000 description 1
CTQNGGLPUBDAKN-UHFFFAOYSA-N O-Xylene Chemical compound CC1=CC=CC=C1C CTQNGGLPUBDAKN-UHFFFAOYSA-N 0.000 description 1
229920003171 Poly (ethylene oxide) Polymers 0.000 description 1
239000004698 Polyethylene Substances 0.000 description 1
239000004793 Polystyrene Substances 0.000 description 1
XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 description 1
229910010413 TiO 2 Inorganic materials 0.000 description 1
ATJFFYVFTNAWJD-UHFFFAOYSA-N Tin Chemical compound [Sn] ATJFFYVFTNAWJD-UHFFFAOYSA-N 0.000 description 1
QLBSZWMIJXMMDQ-UHFFFAOYSA-L [Cl-].[Cl-].C1(C=CC2=CC=CC=C12)[Zr+2].C[Si](=CC1C=C2C=C(C=C2N1C1=CC=CC=C1)C)C Chemical compound [Cl-].[Cl-].C1(C=CC2=CC=CC=C12)[Zr+2].C[Si](=CC1C=C2C=C(C=C2N1C1=CC=CC=C1)C)C QLBSZWMIJXMMDQ-UHFFFAOYSA-L 0.000 description 1
DSZBIEVLOSJWLQ-UHFFFAOYSA-J [Cl-].[Cl-].C1(C=CC2=CC=CC=C12)[Zr+3].C[Si](=CC1=NC2=CC(=CC2=C1)C)C.[Cl-].[Cl-].C1(C=CC2=CC=CC=C12)[Zr+3].C[Si](=CC=1C=C2N(CC=C2C1)C1=CC=CC=C1)C Chemical compound [Cl-].[Cl-].C1(C=CC2=CC=CC=C12)[Zr+3].C[Si](=CC1=NC2=CC(=CC2=C1)C)C.[Cl-].[Cl-].C1(C=CC2=CC=CC=C12)[Zr+3].C[Si](=CC=1C=C2N(CC=C2C1)C1=CC=CC=C1)C DSZBIEVLOSJWLQ-UHFFFAOYSA-J 0.000 description 1
JEUHTJHFFRTRGF-UHFFFAOYSA-H [Cl-].[Cl-].C1(C=CC2=CC=CC=C12)[Zr+3].C[Si](=CC1C=C2C=C(C=C2S1)C)C.[Cl-].[Cl-].C1(C=CC2=CC=CC=C12)[Zr+3].C[Si](=CC1SC2=CC(=CC2=C1)C)C.[Cl-].[Cl-].C1(C=CC2=CC=CC=C12)[Zr+3] Chemical compound [Cl-].[Cl-].C1(C=CC2=CC=CC=C12)[Zr+3].C[Si](=CC1C=C2C=C(C=C2S1)C)C.[Cl-].[Cl-].C1(C=CC2=CC=CC=C12)[Zr+3].C[Si](=CC1SC2=CC(=CC2=C1)C)C.[Cl-].[Cl-].C1(C=CC2=CC=CC=C12)[Zr+3] JEUHTJHFFRTRGF-UHFFFAOYSA-H 0.000 description 1
IJWJAVHBOCRHSP-UHFFFAOYSA-L [Cl-].[Cl-].C1=CC=C2C([Zr+2])C(C)=CC2=C1 Chemical compound [Cl-].[Cl-].C1=CC=C2C([Zr+2])C(C)=CC2=C1 IJWJAVHBOCRHSP-UHFFFAOYSA-L 0.000 description 1
MBPTYPNFOAYZQY-UHFFFAOYSA-L [Cl-].[Cl-].CC=1C(C2=CC=CC(=C2C1)C1=CC=CC=C1)[Zr+2].C[Si](=CC=1C=C2SCC=C2C1)C Chemical compound [Cl-].[Cl-].CC=1C(C2=CC=CC(=C2C1)C1=CC=CC=C1)[Zr+2].C[Si](=CC=1C=C2SCC=C2C1)C MBPTYPNFOAYZQY-UHFFFAOYSA-L 0.000 description 1
GUMJSUONGRBFKU-UHFFFAOYSA-J [Cl-].[Cl-].CC=1C(C2=CC=CC(=C2C1)C1=CC=CC=C1)[Zr+3].C[Si](=CC1=CC2=CC=NC2=C1)C.[Cl-].[Cl-].C1(C=CC2=CC=CC=C12)[Zr+3].C[Si](=CC1C=C2C=C(C=C2O1)C)C Chemical compound [Cl-].[Cl-].CC=1C(C2=CC=CC(=C2C1)C1=CC=CC=C1)[Zr+3].C[Si](=CC1=CC2=CC=NC2=C1)C.[Cl-].[Cl-].C1(C=CC2=CC=CC=C12)[Zr+3].C[Si](=CC1C=C2C=C(C=C2O1)C)C GUMJSUONGRBFKU-UHFFFAOYSA-J 0.000 description 1
XPJACPUYFYCODD-UHFFFAOYSA-J [Cl-].[Cl-].CC=1C(C2=CC=CC(=C2C1)C1=CC=CC=C1)[Zr+3].C[Si](=CC1=CC2=CN=CC2=C1)C.[Cl-].[Cl-].CC=1C(C2=CC=CC(=C2C1)C1=CC=CC=C1)[Zr+3].C[Si](=CC1=CC2=CC=NC2=C1)C Chemical compound [Cl-].[Cl-].CC=1C(C2=CC=CC(=C2C1)C1=CC=CC=C1)[Zr+3].C[Si](=CC1=CC2=CN=CC2=C1)C.[Cl-].[Cl-].CC=1C(C2=CC=CC(=C2C1)C1=CC=CC=C1)[Zr+3].C[Si](=CC1=CC2=CC=NC2=C1)C XPJACPUYFYCODD-UHFFFAOYSA-J 0.000 description 1
OUOOPHAOVMFTKW-UHFFFAOYSA-J [Cl-].[Cl-].CC=1C(C2=CC=CC(=C2C1)C1=CC=CC=C1)[Zr+3].C[Si](=CC1=CC2=COCC2=C1)C.[Cl-].[Cl-].CC=1C(C2=CC=CC(=C2C1)C1=CC=CC=C1)[Zr+3].C[Si](=CC1=CC2=CCOC2=C1)C Chemical compound [Cl-].[Cl-].CC=1C(C2=CC=CC(=C2C1)C1=CC=CC=C1)[Zr+3].C[Si](=CC1=CC2=COCC2=C1)C.[Cl-].[Cl-].CC=1C(C2=CC=CC(=C2C1)C1=CC=CC=C1)[Zr+3].C[Si](=CC1=CC2=CCOC2=C1)C OUOOPHAOVMFTKW-UHFFFAOYSA-J 0.000 description 1
VGVVWSYEXCAHSR-UHFFFAOYSA-J [Cl-].[Cl-].CC=1C(C2=CC=CC(=C2C1)C1=CC=CC=C1)[Zr+3].C[Si](=CC1OC2=CC(=CC2=C1)C)C.[Cl-].[Cl-].CC=1C(C2=CC=CC(=C2C1)C1=CC=CC=C1)[Zr+3].C[Si](=CC=1C=C2OCC=C2C1)C Chemical compound [Cl-].[Cl-].CC=1C(C2=CC=CC(=C2C1)C1=CC=CC=C1)[Zr+3].C[Si](=CC1OC2=CC(=CC2=C1)C)C.[Cl-].[Cl-].CC=1C(C2=CC=CC(=C2C1)C1=CC=CC=C1)[Zr+3].C[Si](=CC=1C=C2OCC=C2C1)C VGVVWSYEXCAHSR-UHFFFAOYSA-J 0.000 description 1
FMZWQZKJPDXGQX-UHFFFAOYSA-J [Cl-].[Cl-].CC=1C(C2=CC=CC=C2C1)[Zr+3].C[Si](=CC1=CC2=CCN(C2=C1)C1=CC=CC=C1)C.[Cl-].[Cl-].CC=1C(C2=CC=CC=C2C1)[Zr+3].C[Si](=CC1=CC2=NC=CC2=C1)C Chemical compound [Cl-].[Cl-].CC=1C(C2=CC=CC=C2C1)[Zr+3].C[Si](=CC1=CC2=CCN(C2=C1)C1=CC=CC=C1)C.[Cl-].[Cl-].CC=1C(C2=CC=CC=C2C1)[Zr+3].C[Si](=CC1=CC2=NC=CC2=C1)C FMZWQZKJPDXGQX-UHFFFAOYSA-J 0.000 description 1
UJLVTAIGDGRDBG-UHFFFAOYSA-J [Cl-].[Cl-].CC=1C(C2=CC=CC=C2C1)[Zr+3].C[Si](=CC1=CC2=CCOC2=C1)C.[Cl-].[Cl-].CC=1C(C2=CC=CC=C2C1)[Zr+3].C[Si](=CC1C=C2C=C(C=C2S1)C)C Chemical compound [Cl-].[Cl-].CC=1C(C2=CC=CC=C2C1)[Zr+3].C[Si](=CC1=CC2=CCOC2=C1)C.[Cl-].[Cl-].CC=1C(C2=CC=CC=C2C1)[Zr+3].C[Si](=CC1C=C2C=C(C=C2S1)C)C UJLVTAIGDGRDBG-UHFFFAOYSA-J 0.000 description 1
ZDUXVTZISIANTF-UHFFFAOYSA-J [Cl-].[Cl-].CC=1C(C2=CC=CC=C2C1)[Zr+3].C[Si](=CC=1C=C2N(CC=C2C1)C1=CC=CC=C1)C.[Cl-].[Cl-].CC=1C(C2=CC=CC=C2C1)[Zr+3].C[Si](=CC1=CC2=CN(CC2=C1)C1=CC=CC=C1)C Chemical compound [Cl-].[Cl-].CC=1C(C2=CC=CC=C2C1)[Zr+3].C[Si](=CC=1C=C2N(CC=C2C1)C1=CC=CC=C1)C.[Cl-].[Cl-].CC=1C(C2=CC=CC=C2C1)[Zr+3].C[Si](=CC1=CC2=CN(CC2=C1)C1=CC=CC=C1)C ZDUXVTZISIANTF-UHFFFAOYSA-J 0.000 description 1
ODGKSAZUUWEIAB-UHFFFAOYSA-J [Cl-].[Cl-].CC=1C(C2=CC=CC=C2C1)[Zr+3].C[Si](=CC=1C=C2OCC=C2C1)C.[Cl-].[Cl-].CC=1C(C2=CC=CC=C2C1)[Zr+3].C[Si](=CC1=CC2=COCC2=C1)C Chemical compound [Cl-].[Cl-].CC=1C(C2=CC=CC=C2C1)[Zr+3].C[Si](=CC=1C=C2OCC=C2C1)C.[Cl-].[Cl-].CC=1C(C2=CC=CC=C2C1)[Zr+3].C[Si](=CC1=CC2=COCC2=C1)C ODGKSAZUUWEIAB-UHFFFAOYSA-J 0.000 description 1
NSIJSSUTTKOQTE-UHFFFAOYSA-J [Cl-].[Cl-].CC=1C(C2=CC=CC=C2C1)[Zr+3].C[Si](=CC=1C=C2SCC=C2C1)C.[Cl-].[Cl-].CC=1C(C2=CC=CC=C2C1)[Zr+3].C[Si](=CC1=CC2=CSCC2=C1)C Chemical compound [Cl-].[Cl-].CC=1C(C2=CC=CC=C2C1)[Zr+3].C[Si](=CC=1C=C2SCC=C2C1)C.[Cl-].[Cl-].CC=1C(C2=CC=CC=C2C1)[Zr+3].C[Si](=CC1=CC2=CSCC2=C1)C NSIJSSUTTKOQTE-UHFFFAOYSA-J 0.000 description 1
AZBVUMJQAKFEJA-UHFFFAOYSA-L [Cl-].[Cl-].C[Si](=[Zr+2](C1C(=CC2=CC(=CC=C12)CC(C)C)C)C1C(=CC2=CC(=CC=C12)CC(C)C)C)C1=CC=CC=C1 Chemical compound [Cl-].[Cl-].C[Si](=[Zr+2](C1C(=CC2=CC(=CC=C12)CC(C)C)C)C1C(=CC2=CC(=CC=C12)CC(C)C)C)C1=CC=CC=C1 AZBVUMJQAKFEJA-UHFFFAOYSA-L 0.000 description 1
JLULRTOCWRETOZ-UHFFFAOYSA-J [Cl-].[Cl-].[Zr+4].C[Si](C1=C(C=C2C=C(N=C12)C)C)(C1=C(C=C2C=C(N=C12)C)C)C.[Cl-].[Cl-].[Zr+4].C[Si](C1=C(C=C2N=C(C=C12)C)C)(C1=C(C=C2N=C(C=C12)C)C)C Chemical compound [Cl-].[Cl-].[Zr+4].C[Si](C1=C(C=C2C=C(N=C12)C)C)(C1=C(C=C2C=C(N=C12)C)C)C.[Cl-].[Cl-].[Zr+4].C[Si](C1=C(C=C2N=C(C=C12)C)C)(C1=C(C=C2N=C(C=C12)C)C)C JLULRTOCWRETOZ-UHFFFAOYSA-J 0.000 description 1
QGPWUMKHULFBOP-UHFFFAOYSA-H [Cl-].[Cl-].[Zr+4].C[Si](C1=C(C=C2C=NC=C12)C)(C1=C(C=C2C=NC=C12)C)C.[Cl-].[Cl-].[Zr+4].C[Si](C1=C(C=C2N=CC=C12)C)(C1=C(C=C2N=CC=C12)C)C.[Cl-].[Cl-].[Zr+4] Chemical compound [Cl-].[Cl-].[Zr+4].C[Si](C1=C(C=C2C=NC=C12)C)(C1=C(C=C2C=NC=C12)C)C.[Cl-].[Cl-].[Zr+4].C[Si](C1=C(C=C2N=CC=C12)C)(C1=C(C=C2N=CC=C12)C)C.[Cl-].[Cl-].[Zr+4] QGPWUMKHULFBOP-UHFFFAOYSA-H 0.000 description 1
DJGIQGMJWCRRIU-UHFFFAOYSA-J [Cl-].[Cl-].[Zr+4].C[Si](C1=C(C=C2N(CC=C12)C1=CC=CC=C1)C)(C1=C(C=C2N(CC=C12)C1=CC=CC=C1)C)C.[Cl-].[Cl-].[Zr+4].C[Si](C1=C(C=C2C=CN=C12)C)(C1=C(C=C2C=CN=C12)C)C Chemical compound [Cl-].[Cl-].[Zr+4].C[Si](C1=C(C=C2N(CC=C12)C1=CC=CC=C1)C)(C1=C(C=C2N(CC=C12)C1=CC=CC=C1)C)C.[Cl-].[Cl-].[Zr+4].C[Si](C1=C(C=C2C=CN=C12)C)(C1=C(C=C2C=CN=C12)C)C DJGIQGMJWCRRIU-UHFFFAOYSA-J 0.000 description 1
JMRHMOFUCQSAPC-UHFFFAOYSA-J [Cl-].[Cl-].[Zr+4].C[Si](C=1C(=CC2=CC(N(C12)C1=CC=CC=C1)C)C)(C=1C(=CC2=CC(N(C12)C1=CC=CC=C1)C)C)C.[Cl-].[Cl-].[Zr+4].C[Si](C1=C(C=C2N(C(C=C12)C)C1=CC=CC=C1)C)(C1=C(C=C2N(C(C=C12)C)C1=CC=CC=C1)C)C Chemical compound [Cl-].[Cl-].[Zr+4].C[Si](C=1C(=CC2=CC(N(C12)C1=CC=CC=C1)C)C)(C=1C(=CC2=CC(N(C12)C1=CC=CC=C1)C)C)C.[Cl-].[Cl-].[Zr+4].C[Si](C1=C(C=C2N(C(C=C12)C)C1=CC=CC=C1)C)(C1=C(C=C2N(C(C=C12)C)C1=CC=CC=C1)C)C JMRHMOFUCQSAPC-UHFFFAOYSA-J 0.000 description 1
KNTVYNIJAONSRI-UHFFFAOYSA-N [Hf++].C[N-]C.C[N-]C Chemical compound [Hf++].C[N-]C.C[N-]C KNTVYNIJAONSRI-UHFFFAOYSA-N 0.000 description 1
FKJYTKPFILYGAI-UHFFFAOYSA-J [Zr+4].C(C)(C)(C)C1=C(C(=CC(=C1)C)C(C)(C)C)[O-].C(C)(C)(C)C1=C(C(=CC(=C1)C)C(C)(C)C)[O-].C(C)(C)(C)C1=C(C(=CC(=C1)C)C(C)(C)C)[O-].C(C)(C)(C)C1=C(C(=CC(=C1)C)C(C)(C)C)[O-] Chemical compound [Zr+4].C(C)(C)(C)C1=C(C(=CC(=C1)C)C(C)(C)C)[O-].C(C)(C)(C)C1=C(C(=CC(=C1)C)C(C)(C)C)[O-].C(C)(C)(C)C1=C(C(=CC(=C1)C)C(C)(C)C)[O-].C(C)(C)(C)C1=C(C(=CC(=C1)C)C(C)(C)C)[O-] FKJYTKPFILYGAI-UHFFFAOYSA-J 0.000 description 1
QYSSQHGYJKMAPS-UHFFFAOYSA-J [Zr+4].C(C)(C)(C)C1=C([O-])C=CC=C1.C(C)(C)(C)C1=C([O-])C=CC=C1.C(C)(C)(C)C1=C([O-])C=CC=C1.C(C)(C)(C)C1=C([O-])C=CC=C1 Chemical compound [Zr+4].C(C)(C)(C)C1=C([O-])C=CC=C1.C(C)(C)(C)C1=C([O-])C=CC=C1.C(C)(C)(C)C1=C([O-])C=CC=C1.C(C)(C)(C)C1=C([O-])C=CC=C1 QYSSQHGYJKMAPS-UHFFFAOYSA-J 0.000 description 1
YFCIXLODLPGTEP-UHFFFAOYSA-J [Zr+4].C(C)(C)(C)C=1C=C(C=C(C1)C(C)(C)C)[O-].C(C)(C)(C)C=1C=C(C=C(C1)C(C)(C)C)[O-].C(C)(C)(C)C=1C=C(C=C(C1)C(C)(C)C)[O-].C(C)(C)(C)C=1C=C(C=C(C1)C(C)(C)C)[O-] Chemical compound [Zr+4].C(C)(C)(C)C=1C=C(C=C(C1)C(C)(C)C)[O-].C(C)(C)(C)C=1C=C(C=C(C1)C(C)(C)C)[O-].C(C)(C)(C)C=1C=C(C=C(C1)C(C)(C)C)[O-].C(C)(C)(C)C=1C=C(C=C(C1)C(C)(C)C)[O-] YFCIXLODLPGTEP-UHFFFAOYSA-J 0.000 description 1
FXROLTVYULHLSQ-UHFFFAOYSA-J [Zr+4].C(CCCCCCCC)C1=CC=C(C=C1)[O-].C(CCCCCCCC)C1=CC=C(C=C1)[O-].C(CCCCCCCC)C1=CC=C(C=C1)[O-].C(CCCCCCCC)C1=CC=C(C=C1)[O-] Chemical compound [Zr+4].C(CCCCCCCC)C1=CC=C(C=C1)[O-].C(CCCCCCCC)C1=CC=C(C=C1)[O-].C(CCCCCCCC)C1=CC=C(C=C1)[O-].C(CCCCCCCC)C1=CC=C(C=C1)[O-] FXROLTVYULHLSQ-UHFFFAOYSA-J 0.000 description 1
UEBQHUKEIXWCLT-UHFFFAOYSA-J [Zr+4].Cc1cccc([O-])c1C.Cc1cccc([O-])c1C.Cc1cccc([O-])c1C.Cc1cccc([O-])c1C Chemical compound [Zr+4].Cc1cccc([O-])c1C.Cc1cccc([O-])c1C.Cc1cccc([O-])c1C.Cc1cccc([O-])c1C UEBQHUKEIXWCLT-UHFFFAOYSA-J 0.000 description 1
239000002253 acid Substances 0.000 description 1
230000009471 action Effects 0.000 description 1
239000012190 activator Substances 0.000 description 1
239000000654 additive Substances 0.000 description 1
230000000996 additive effect Effects 0.000 description 1
150000001335 aliphatic alkanes Chemical class 0.000 description 1
150000005215 alkyl ethers Chemical class 0.000 description 1
125000005213 alkyl heteroaryl group Chemical group 0.000 description 1
150000003868 ammonium compounds Chemical class 0.000 description 1
150000003863 ammonium salts Chemical class 0.000 description 1
UPABQMWFWCMOFV-UHFFFAOYSA-N benethamine Chemical compound C=1C=CC=CC=1CNCCC1=CC=CC=C1 UPABQMWFWCMOFV-UHFFFAOYSA-N 0.000 description 1
238000009835 boiling Methods 0.000 description 1
VTYDSHHBXXPBBQ-UHFFFAOYSA-N boron germanium Chemical compound [B].[Ge] VTYDSHHBXXPBBQ-UHFFFAOYSA-N 0.000 description 1
239000001273 butane Substances 0.000 description 1
159000000007 calcium salts Chemical class 0.000 description 1
150000001721 carbon Chemical group 0.000 description 1
238000012512 characterization method Methods 0.000 description 1
239000003153 chemical reaction reagent Substances 0.000 description 1
239000003795 chemical substances by application Substances 0.000 description 1
150000001844 chromium Chemical class 0.000 description 1
238000003776 cleavage reaction Methods 0.000 description 1
239000003426 co-catalyst Substances 0.000 description 1
239000000356 contaminant Substances 0.000 description 1
150000004696 coordination complex Chemical class 0.000 description 1
238000007334 copolymerization reaction Methods 0.000 description 1
HCKMSHYCAFVSGW-UHFFFAOYSA-N cyclohexyl(trimethyl)azanium Chemical compound C[N+](C)(C)C1CCCCC1 HCKMSHYCAFVSGW-UHFFFAOYSA-N 0.000 description 1
ZPADAZTVSGCTNF-UHFFFAOYSA-N cyclohexyl-diethyl-methylazanium Chemical compound CC[N+](C)(CC)C1CCCCC1 ZPADAZTVSGCTNF-UHFFFAOYSA-N 0.000 description 1
XURMURYJWMFWER-UHFFFAOYSA-N cyclohexyl-ethyl-dimethylazanium Chemical compound CC[N+](C)(C)C1CCCCC1 XURMURYJWMFWER-UHFFFAOYSA-N 0.000 description 1
PBZHFLGIROVUPM-UHFFFAOYSA-N cyclopenta[c]pyrrol-5-ylmethylidene(dimethyl)silane Chemical compound C[Si](=CC1=CC2=CN=CC2=C1)C PBZHFLGIROVUPM-UHFFFAOYSA-N 0.000 description 1
239000002274 desiccant Substances 0.000 description 1
150000004985 diamines Chemical class 0.000 description 1
RAABOESOVLLHRU-UHFFFAOYSA-N diazene Chemical class N=N RAABOESOVLLHRU-UHFFFAOYSA-N 0.000 description 1
150000001993 dienes Chemical class 0.000 description 1
GGSUCNLOZRCGPQ-UHFFFAOYSA-O diethyl(phenyl)azanium Chemical compound CC[NH+](CC)C1=CC=CC=C1 GGSUCNLOZRCGPQ-UHFFFAOYSA-O 0.000 description 1
DGUIDBYKNGVRCS-UHFFFAOYSA-N dimethyl-[(5-methyl-2H-cyclopenta[b]furan-2-yl)methylidene]silane Chemical compound C[Si](=CC1OC2=CC(=CC2=C1)C)C DGUIDBYKNGVRCS-UHFFFAOYSA-N 0.000 description 1
RUHNOXVVNSBKSC-UHFFFAOYSA-N dimethylazanide;titanium(2+) Chemical compound [Ti+2].C[N-]C.C[N-]C RUHNOXVVNSBKSC-UHFFFAOYSA-N 0.000 description 1
238000004821 distillation Methods 0.000 description 1
229940060296 dodecylbenzenesulfonic acid Drugs 0.000 description 1
238000010981 drying operation Methods 0.000 description 1
ZSWFCLXCOIISFI-UHFFFAOYSA-N endo-cyclopentadiene Natural products C1C=CC=C1 ZSWFCLXCOIISFI-UHFFFAOYSA-N 0.000 description 1
150000002148 esters Chemical class 0.000 description 1
HQQADJVZYDDRJT-UHFFFAOYSA-N ethene;prop-1-ene Chemical group C=C.CC=C HQQADJVZYDDRJT-UHFFFAOYSA-N 0.000 description 1
125000000219 ethylidene group Chemical group [H]C(=[*])C([H])([H])[H] 0.000 description 1
230000007717 exclusion Effects 0.000 description 1
239000000835 fiber Substances 0.000 description 1
238000001914 filtration Methods 0.000 description 1
239000010419 fine particle Substances 0.000 description 1
125000001207 fluorophenyl group Chemical group 0.000 description 1
239000011888 foil Substances 0.000 description 1
239000012634 fragment Substances 0.000 description 1
VBJZVLUMGGDVMO-UHFFFAOYSA-N hafnium atom Chemical compound [Hf] VBJZVLUMGGDVMO-UHFFFAOYSA-N 0.000 description 1
150000008282 halocarbons Chemical class 0.000 description 1
229910052736 halogen Inorganic materials 0.000 description 1
125000000623 heterocyclic group Chemical group 0.000 description 1
IXCSERBJSXMMFS-UHFFFAOYSA-N hydrogen chloride Substances Cl.Cl IXCSERBJSXMMFS-UHFFFAOYSA-N 0.000 description 1
229910000041 hydrogen chloride Inorganic materials 0.000 description 1
238000010348 incorporation Methods 0.000 description 1
239000012442 inert solvent Substances 0.000 description 1
238000002347 injection Methods 0.000 description 1
239000007924 injection Substances 0.000 description 1
230000003993 interaction Effects 0.000 description 1
VKPSKYDESGTTFR-UHFFFAOYSA-N isododecane Natural products CC(C)(C)CC(C)CC(C)(C)C VKPSKYDESGTTFR-UHFFFAOYSA-N 0.000 description 1
LYBKPDDZTNUNNM-UHFFFAOYSA-N isopropylbenzylamine Chemical compound CC(C)NCC1=CC=CC=C1 LYBKPDDZTNUNNM-UHFFFAOYSA-N 0.000 description 1
150000007517 lewis acids Chemical class 0.000 description 1
239000007788 liquid Substances 0.000 description 1
229920002521 macromolecule Polymers 0.000 description 1
229910052749 magnesium Inorganic materials 0.000 description 1
KJJBSBKRXUVBMX-UHFFFAOYSA-N magnesium;butane Chemical compound [Mg+2].CCC[CH2-].CCC[CH2-] KJJBSBKRXUVBMX-UHFFFAOYSA-N 0.000 description 1
238000002844 melting Methods 0.000 description 1
230000008018 melting Effects 0.000 description 1
239000012968 metallocene catalyst Substances 0.000 description 1
150000002739 metals Chemical class 0.000 description 1
125000002950 monocyclic group Chemical group 0.000 description 1
239000000178 monomer Substances 0.000 description 1
125000001421 myristyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
ACYBVNYNIZTUIL-UHFFFAOYSA-N n'-benzylethane-1,2-diamine Chemical compound NCCNCC1=CC=CC=C1 ACYBVNYNIZTUIL-UHFFFAOYSA-N 0.000 description 1
GQJYLXDEAQNWEK-UHFFFAOYSA-N n,1-dimethyl-n-(1-methylcyclohexyl)cyclohexan-1-amine Chemical compound C1CCCCC1(C)N(C)C1(C)CCCCC1 GQJYLXDEAQNWEK-UHFFFAOYSA-N 0.000 description 1
FOSIZMVVHVQEKE-UHFFFAOYSA-N n,2-diethyl-n-(2-ethylbutyl)butan-1-amine Chemical compound CCC(CC)CN(CC)CC(CC)CC FOSIZMVVHVQEKE-UHFFFAOYSA-N 0.000 description 1
VQAWUDQDLGGCEE-UHFFFAOYSA-N n,2-diethyl-n-(2-ethylhexyl)hexan-1-amine Chemical compound CCCCC(CC)CN(CC)CC(CC)CCCC VQAWUDQDLGGCEE-UHFFFAOYSA-N 0.000 description 1
GJGPRGBVRVFGJT-UHFFFAOYSA-N n,2-dimethyl-n-(2-methylhexyl)hexan-1-amine Chemical compound CCCCC(C)CN(C)CC(C)CCCC GJGPRGBVRVFGJT-UHFFFAOYSA-N 0.000 description 1
KEEXPDPBIQJVKK-UHFFFAOYSA-N n,2-dimethyl-n-(2-methylpropyl)propan-1-amine Chemical compound CC(C)CN(C)CC(C)C KEEXPDPBIQJVKK-UHFFFAOYSA-N 0.000 description 1
PTGOEOKOIYELNP-UHFFFAOYSA-N n,3-diethyl-n-methylhexan-1-amine Chemical compound CCCC(CC)CCN(C)CC PTGOEOKOIYELNP-UHFFFAOYSA-N 0.000 description 1
DQXYWMTZRQWTEK-UHFFFAOYSA-N n,3-diethyl-n-methylpentan-1-amine Chemical compound CCC(CC)CCN(C)CC DQXYWMTZRQWTEK-UHFFFAOYSA-N 0.000 description 1
OEJFYXWYEMZNML-UHFFFAOYSA-N n,4-diethyl-n-methylhexan-1-amine Chemical compound CCC(CC)CCCN(C)CC OEJFYXWYEMZNML-UHFFFAOYSA-N 0.000 description 1
GBVCMCDVQPHZGE-UHFFFAOYSA-N n,n,1-trimethylcyclohexan-1-amine Chemical compound CN(C)C1(C)CCCCC1 GBVCMCDVQPHZGE-UHFFFAOYSA-N 0.000 description 1
CIMGCZYKXIVELK-UHFFFAOYSA-N n,n,2-trimethylheptan-1-amine Chemical compound CCCCCC(C)CN(C)C CIMGCZYKXIVELK-UHFFFAOYSA-N 0.000 description 1
FYRHPVBMURAQJE-UHFFFAOYSA-N n,n,2-trimethylpentan-1-amine Chemical compound CCCC(C)CN(C)C FYRHPVBMURAQJE-UHFFFAOYSA-N 0.000 description 1
GDHRQDYGUDOEIZ-UHFFFAOYSA-N n,n,2-trimethylpropan-1-amine Chemical compound CC(C)CN(C)C GDHRQDYGUDOEIZ-UHFFFAOYSA-N 0.000 description 1
CLNKOMWYZXEJKF-UHFFFAOYSA-N n,n,3-triethylhexan-1-amine Chemical compound CCCC(CC)CCN(CC)CC CLNKOMWYZXEJKF-UHFFFAOYSA-N 0.000 description 1
OVHHQBMMXHXGCK-UHFFFAOYSA-N n,n,3-triethylpentan-1-amine Chemical compound CCC(CC)CCN(CC)CC OVHHQBMMXHXGCK-UHFFFAOYSA-N 0.000 description 1
KOOQJINBDNZUTB-UHFFFAOYSA-N n,n,3-trimethylbutan-1-amine Chemical compound CC(C)CCN(C)C KOOQJINBDNZUTB-UHFFFAOYSA-N 0.000 description 1
JDCVJEVYSCHZED-UHFFFAOYSA-N n,n,3-trimethylheptan-1-amine Chemical compound CCCCC(C)CCN(C)C JDCVJEVYSCHZED-UHFFFAOYSA-N 0.000 description 1
NVKAWKWPMINQKR-UHFFFAOYSA-N n,n,3-trimethylhexan-1-amine Chemical compound CCCC(C)CCN(C)C NVKAWKWPMINQKR-UHFFFAOYSA-N 0.000 description 1
FZGSAGJJUFQDML-UHFFFAOYSA-N n,n,3-trimethylpentan-1-amine Chemical compound CCC(C)CCN(C)C FZGSAGJJUFQDML-UHFFFAOYSA-N 0.000 description 1
VRVGWOSJKSLVGN-UHFFFAOYSA-N n,n,4,4-tetramethylcyclohexan-1-amine Chemical compound CN(C)C1CCC(C)(C)CC1 VRVGWOSJKSLVGN-UHFFFAOYSA-N 0.000 description 1
GLWHTJGTWGZOGS-UHFFFAOYSA-N n,n,4-triethylhexan-1-amine Chemical compound CCC(CC)CCCN(CC)CC GLWHTJGTWGZOGS-UHFFFAOYSA-N 0.000 description 1
XSQJXNRSPHKFNX-UHFFFAOYSA-N n,n,4-trimethylheptan-1-amine Chemical compound CCCC(C)CCCN(C)C XSQJXNRSPHKFNX-UHFFFAOYSA-N 0.000 description 1
QTHSJIBVANLIMT-UHFFFAOYSA-N n,n,4-trimethylhexan-1-amine Chemical compound CCC(C)CCCN(C)C QTHSJIBVANLIMT-UHFFFAOYSA-N 0.000 description 1
NQULBISGTHBUGM-UHFFFAOYSA-N n,n,4-trimethylpentan-1-amine Chemical compound CC(C)CCCN(C)C NQULBISGTHBUGM-UHFFFAOYSA-N 0.000 description 1
CBLJUTPROLICEC-UHFFFAOYSA-N n,n,5-trimethylheptan-1-amine Chemical compound CCC(C)CCCCN(C)C CBLJUTPROLICEC-UHFFFAOYSA-N 0.000 description 1
JYYUAKLPQLNPFA-UHFFFAOYSA-N n,n,5-trimethylhexan-1-amine Chemical compound CC(C)CCCCN(C)C JYYUAKLPQLNPFA-UHFFFAOYSA-N 0.000 description 1
AIVGHALKDNEHNX-UHFFFAOYSA-N n,n,6-trimethylheptan-1-amine Chemical compound CC(C)CCCCCN(C)C AIVGHALKDNEHNX-UHFFFAOYSA-N 0.000 description 1
WBGPDYJIPNTOIB-UHFFFAOYSA-N n,n-dibenzylethanamine Chemical compound C=1C=CC=CC=1CN(CC)CC1=CC=CC=C1 WBGPDYJIPNTOIB-UHFFFAOYSA-N 0.000 description 1
XJEPUDKDCKLTSL-UHFFFAOYSA-N n,n-didodecylaniline Chemical compound CCCCCCCCCCCCN(CCCCCCCCCCCC)C1=CC=CC=C1 XJEPUDKDCKLTSL-UHFFFAOYSA-N 0.000 description 1
TVCIMZVAAUYMMM-UHFFFAOYSA-N n,n-diethyl-1-methylcyclohexan-1-amine Chemical compound CCN(CC)C1(C)CCCCC1 TVCIMZVAAUYMMM-UHFFFAOYSA-N 0.000 description 1
APYORAMXFRDIQW-UHFFFAOYSA-N n,n-diethyl-2-methylheptan-1-amine Chemical compound CCCCCC(C)CN(CC)CC APYORAMXFRDIQW-UHFFFAOYSA-N 0.000 description 1
PTMPMFIGAZXBOH-UHFFFAOYSA-N n,n-diethyl-2-methylpentan-1-amine Chemical compound CCCC(C)CN(CC)CC PTMPMFIGAZXBOH-UHFFFAOYSA-N 0.000 description 1
SDJXWHZCYABKHD-UHFFFAOYSA-N n,n-diethyl-2-methylpropan-1-amine Chemical compound CCN(CC)CC(C)C SDJXWHZCYABKHD-UHFFFAOYSA-N 0.000 description 1
CRBJWJCZPYKQBF-UHFFFAOYSA-N n,n-diethyl-2-propylpentan-1-amine Chemical compound CCCC(CCC)CN(CC)CC CRBJWJCZPYKQBF-UHFFFAOYSA-N 0.000 description 1
FJPUTKPSUZLWMN-UHFFFAOYSA-N n,n-diethyl-3-methylbutan-1-amine Chemical compound CCN(CC)CCC(C)C FJPUTKPSUZLWMN-UHFFFAOYSA-N 0.000 description 1
SNFYDQJAVIDUJE-UHFFFAOYSA-N n,n-diethyl-3-methylheptan-1-amine Chemical compound CCCCC(C)CCN(CC)CC SNFYDQJAVIDUJE-UHFFFAOYSA-N 0.000 description 1
HYCDTFOFNMEJMK-UHFFFAOYSA-N n,n-diethyl-3-methylhexan-1-amine Chemical compound CCCC(C)CCN(CC)CC HYCDTFOFNMEJMK-UHFFFAOYSA-N 0.000 description 1
OMNOFJWUTPYULY-UHFFFAOYSA-N n,n-diethyl-3-methylpentan-1-amine Chemical compound CCC(C)CCN(CC)CC OMNOFJWUTPYULY-UHFFFAOYSA-N 0.000 description 1
FYLRBQZBNMTZFN-UHFFFAOYSA-N n,n-diethyl-4-methylheptan-1-amine Chemical compound CCCC(C)CCCN(CC)CC FYLRBQZBNMTZFN-UHFFFAOYSA-N 0.000 description 1
MOAHSYUYLYFMSJ-UHFFFAOYSA-N n,n-diethyl-4-methylhexan-1-amine Chemical compound CCC(C)CCCN(CC)CC MOAHSYUYLYFMSJ-UHFFFAOYSA-N 0.000 description 1
MIJPWIKBRMBPIZ-UHFFFAOYSA-N n,n-diethyl-4-methylpentan-1-amine Chemical compound CCN(CC)CCCC(C)C MIJPWIKBRMBPIZ-UHFFFAOYSA-N 0.000 description 1
PLKLAOOPYPOZCX-UHFFFAOYSA-N n,n-diethyl-5-methylheptan-1-amine Chemical compound CCC(C)CCCCN(CC)CC PLKLAOOPYPOZCX-UHFFFAOYSA-N 0.000 description 1
FPBIZWGPSPZTAV-UHFFFAOYSA-N n,n-diethyl-5-methylhexan-1-amine Chemical compound CCN(CC)CCCCC(C)C FPBIZWGPSPZTAV-UHFFFAOYSA-N 0.000 description 1
YNXNMMGZJFJYHB-UHFFFAOYSA-N n,n-diethyl-6-methylheptan-1-amine Chemical compound CCN(CC)CCCCCC(C)C YNXNMMGZJFJYHB-UHFFFAOYSA-N 0.000 description 1
ZEPRYRDSABELMO-UHFFFAOYSA-N n,n-diethylcycloheptanamine Chemical compound CCN(CC)C1CCCCCC1 ZEPRYRDSABELMO-UHFFFAOYSA-N 0.000 description 1
VIZUDTBASHRHCW-UHFFFAOYSA-N n,n-diethylcyclohepten-1-amine Chemical compound CCN(CC)C1=CCCCCC1 VIZUDTBASHRHCW-UHFFFAOYSA-N 0.000 description 1
SVCZQFNJMKAWAD-UHFFFAOYSA-N n,n-diethylcyclooctanamine Chemical compound CCN(CC)C1CCCCCCC1 SVCZQFNJMKAWAD-UHFFFAOYSA-N 0.000 description 1
ZURPXDWBEOCXSO-UHFFFAOYSA-N n,n-diethylcyclopentanamine Chemical compound CCN(CC)C1CCCC1 ZURPXDWBEOCXSO-UHFFFAOYSA-N 0.000 description 1
OJRWQFMJFFCMNV-UHFFFAOYSA-N n,n-diethylheptan-2-amine Chemical compound CCCCCC(C)N(CC)CC OJRWQFMJFFCMNV-UHFFFAOYSA-N 0.000 description 1
DIDHXPOHVNDCLA-UHFFFAOYSA-N n,n-diethylheptan-3-amine Chemical compound CCCCC(CC)N(CC)CC DIDHXPOHVNDCLA-UHFFFAOYSA-N 0.000 description 1
GVIBXZHTXVAROK-UHFFFAOYSA-N n,n-diethylhexan-2-amine Chemical compound CCCCC(C)N(CC)CC GVIBXZHTXVAROK-UHFFFAOYSA-N 0.000 description 1
PFOIVJKGNQWKSC-UHFFFAOYSA-N n,n-diethylhexan-3-amine Chemical compound CCCC(CC)N(CC)CC PFOIVJKGNQWKSC-UHFFFAOYSA-N 0.000 description 1
VYMLHBZXBXZDFY-UHFFFAOYSA-N n,n-diethylnonanamide Chemical compound CCCCCCCCC(=O)N(CC)CC VYMLHBZXBXZDFY-UHFFFAOYSA-N 0.000 description 1
OFYRDHNOICLKHY-UHFFFAOYSA-N n,n-diethyloctan-2-amine Chemical compound CCCCCCC(C)N(CC)CC OFYRDHNOICLKHY-UHFFFAOYSA-N 0.000 description 1
RPZFQIIXTXYUEN-UHFFFAOYSA-N n,n-diethyloctan-3-amine Chemical compound CCCCCC(CC)N(CC)CC RPZFQIIXTXYUEN-UHFFFAOYSA-N 0.000 description 1
CRXSRCPEKYQYDG-UHFFFAOYSA-N n,n-diethyloctan-4-amine Chemical compound CCCCC(CCC)N(CC)CC CRXSRCPEKYQYDG-UHFFFAOYSA-N 0.000 description 1
FGGGQKSGWAWKRC-UHFFFAOYSA-N n,n-diethylpentan-2-amine Chemical compound CCCC(C)N(CC)CC FGGGQKSGWAWKRC-UHFFFAOYSA-N 0.000 description 1
XQNPPJUYXDHJGI-UHFFFAOYSA-N n,n-diethylpentan-3-amine Chemical compound CCC(CC)N(CC)CC XQNPPJUYXDHJGI-UHFFFAOYSA-N 0.000 description 1
LBBQPHQCWMWSFL-UHFFFAOYSA-N n,n-dimethyl-2-propylpentan-1-amine Chemical compound CCCC(CCC)CN(C)C LBBQPHQCWMWSFL-UHFFFAOYSA-N 0.000 description 1
HAQDTCQCHJEYRE-UHFFFAOYSA-N n,n-dimethylcycloheptanamine Chemical compound CN(C)C1CCCCCC1 HAQDTCQCHJEYRE-UHFFFAOYSA-N 0.000 description 1
FCWALRHYXFGQFZ-UHFFFAOYSA-N n,n-dimethylcyclohepten-1-amine Chemical compound CN(C)C1=CCCCCC1 FCWALRHYXFGQFZ-UHFFFAOYSA-N 0.000 description 1
BSKOUVXDGUXGAZ-UHFFFAOYSA-N n,n-dimethylheptan-2-amine Chemical compound CCCCCC(C)N(C)C BSKOUVXDGUXGAZ-UHFFFAOYSA-N 0.000 description 1
KDZRDXMJTGTWNE-UHFFFAOYSA-N n,n-dimethylheptan-3-amine Chemical compound CCCCC(CC)N(C)C KDZRDXMJTGTWNE-UHFFFAOYSA-N 0.000 description 1
OFTGYFQPRTVGCW-UHFFFAOYSA-N n,n-dimethylheptan-4-amine Chemical compound CCCC(N(C)C)CCC OFTGYFQPRTVGCW-UHFFFAOYSA-N 0.000 description 1
QMQRPFWKJWNKCJ-UHFFFAOYSA-N n,n-dimethylhexan-2-amine Chemical compound CCCCC(C)N(C)C QMQRPFWKJWNKCJ-UHFFFAOYSA-N 0.000 description 1
BXAQFTLBYMGEIQ-UHFFFAOYSA-N n,n-dimethylhexan-3-amine Chemical compound CCCC(CC)N(C)C BXAQFTLBYMGEIQ-UHFFFAOYSA-N 0.000 description 1
DMLHJLWUADABON-UHFFFAOYSA-N n,n-dimethylnonanamide Chemical compound CCCCCCCCC(=O)N(C)C DMLHJLWUADABON-UHFFFAOYSA-N 0.000 description 1
JXXZVUDFXQNPRZ-UHFFFAOYSA-N n,n-dimethyloctan-2-amine Chemical compound CCCCCCC(C)N(C)C JXXZVUDFXQNPRZ-UHFFFAOYSA-N 0.000 description 1
LSTZYJQJHGEVKH-UHFFFAOYSA-N n,n-dimethylpentan-2-amine Chemical compound CCCC(C)N(C)C LSTZYJQJHGEVKH-UHFFFAOYSA-N 0.000 description 1
SUEKSPIQGIMSQM-UHFFFAOYSA-N n,n-dimethylpentan-3-amine Chemical compound CCC(CC)N(C)C SUEKSPIQGIMSQM-UHFFFAOYSA-N 0.000 description 1
TVMXDCGIABBOFY-UHFFFAOYSA-N n-Octanol Natural products CCCCCCCC TVMXDCGIABBOFY-UHFFFAOYSA-N 0.000 description 1
ZYZHMSJNPCYUTB-UHFFFAOYSA-N n-benzyl-1-phenylethanamine Chemical compound C=1C=CC=CC=1C(C)NCC1=CC=CC=C1 ZYZHMSJNPCYUTB-UHFFFAOYSA-N 0.000 description 1
DLSOILHAKCBARI-UHFFFAOYSA-N n-benzyl-2-methylpropan-2-amine Chemical compound CC(C)(C)NCC1=CC=CC=C1 DLSOILHAKCBARI-UHFFFAOYSA-N 0.000 description 1
LLSJAFHDYCTFCM-UHFFFAOYSA-N n-benzyl-n',n'-dimethylethane-1,2-diamine Chemical compound CN(C)CCNCC1=CC=CC=C1 LLSJAFHDYCTFCM-UHFFFAOYSA-N 0.000 description 1
WYZDCUGWXKHESN-UHFFFAOYSA-N n-benzyl-n-methyl-1-phenylmethanamine Chemical compound C=1C=CC=CC=1CN(C)CC1=CC=CC=C1 WYZDCUGWXKHESN-UHFFFAOYSA-N 0.000 description 1
ABRGFZIXRKAUJS-UHFFFAOYSA-N n-benzyl-n-methylethanamine Chemical compound CCN(C)CC1=CC=CC=C1 ABRGFZIXRKAUJS-UHFFFAOYSA-N 0.000 description 1
HIPXPABRMMYVQD-UHFFFAOYSA-N n-benzylbutan-1-amine Chemical compound CCCCNCC1=CC=CC=C1 HIPXPABRMMYVQD-UHFFFAOYSA-N 0.000 description 1
HVAAHUDGWQAAOJ-UHFFFAOYSA-N n-benzylethanamine Chemical compound CCNCC1=CC=CC=C1 HVAAHUDGWQAAOJ-UHFFFAOYSA-N 0.000 description 1
CTSROGJAZGEKAW-UHFFFAOYSA-N n-butan-2-yl-n-ethylbutan-2-amine Chemical compound CCC(C)N(CC)C(C)CC CTSROGJAZGEKAW-UHFFFAOYSA-N 0.000 description 1
IJDNQMDRQITEOD-UHFFFAOYSA-N n-butane Chemical compound CCCC IJDNQMDRQITEOD-UHFFFAOYSA-N 0.000 description 1
CRYMTEHEKQNKEB-UHFFFAOYSA-N n-cyclopentyl-n-ethylcyclopentanamine Chemical compound C1CCCC1N(CC)C1CCCC1 CRYMTEHEKQNKEB-UHFFFAOYSA-N 0.000 description 1
JNMBQGIZTCTCRT-UHFFFAOYSA-N n-cyclopentyl-n-methylcyclopentanamine Chemical compound C1CCCC1N(C)C1CCCC1 JNMBQGIZTCTCRT-UHFFFAOYSA-N 0.000 description 1
GOJIVVWJAXAPGS-UHFFFAOYSA-N n-dodecyl-n-methylaniline Chemical compound CCCCCCCCCCCCN(C)C1=CC=CC=C1 GOJIVVWJAXAPGS-UHFFFAOYSA-N 0.000 description 1
LMCCGZLCQAODRW-UHFFFAOYSA-N n-ethyl-1-methyl-n-(1-methylcyclohexyl)cyclohexan-1-amine Chemical compound C1CCCCC1(C)N(CC)C1(C)CCCCC1 LMCCGZLCQAODRW-UHFFFAOYSA-N 0.000 description 1
BGLQMIYKKIZSEI-UHFFFAOYSA-N n-ethyl-2-methyl-n-(2-methylbutyl)butan-1-amine Chemical compound CCC(C)CN(CC)CC(C)CC BGLQMIYKKIZSEI-UHFFFAOYSA-N 0.000 description 1
IJJSELJKVOJWPQ-UHFFFAOYSA-N n-ethyl-2-methyl-n-(2-methylhexyl)hexan-1-amine Chemical compound CCCCC(C)CN(CC)CC(C)CCCC IJJSELJKVOJWPQ-UHFFFAOYSA-N 0.000 description 1
XQQLJWFNDMEBHP-UHFFFAOYSA-N n-ethyl-2-methyl-n-(2-methylpropyl)propan-1-amine Chemical compound CC(C)CN(CC)CC(C)C XQQLJWFNDMEBHP-UHFFFAOYSA-N 0.000 description 1
MBGBSRHLYRSUND-UHFFFAOYSA-N n-ethyl-n,1-dimethylcyclohexan-1-amine Chemical compound CCN(C)C1(C)CCCCC1 MBGBSRHLYRSUND-UHFFFAOYSA-N 0.000 description 1
BQIGDAHNLAJYIZ-UHFFFAOYSA-N n-ethyl-n,2-dimethylheptan-1-amine Chemical compound CCCCCC(C)CN(C)CC BQIGDAHNLAJYIZ-UHFFFAOYSA-N 0.000 description 1
HFIYHZVPPBQWLM-UHFFFAOYSA-N n-ethyl-n,2-dimethylhexan-1-amine;n-ethyl-n,3-dimethylhexan-1-amine Chemical compound CCCCC(C)CN(C)CC.CCCC(C)CCN(C)CC HFIYHZVPPBQWLM-UHFFFAOYSA-N 0.000 description 1
XHEKGDVTYCPZLB-UHFFFAOYSA-N n-ethyl-n,2-dimethylpentan-1-amine Chemical compound CCCC(C)CN(C)CC XHEKGDVTYCPZLB-UHFFFAOYSA-N 0.000 description 1
KTJILDWKDVCFOT-UHFFFAOYSA-N n-ethyl-n,3-dimethylbutan-1-amine Chemical compound CCN(C)CCC(C)C KTJILDWKDVCFOT-UHFFFAOYSA-N 0.000 description 1
LCCFSHXSQZHDBT-UHFFFAOYSA-N n-ethyl-n,3-dimethylheptan-1-amine Chemical compound CCCCC(C)CCN(C)CC LCCFSHXSQZHDBT-UHFFFAOYSA-N 0.000 description 1
VOZWXDWNTANOST-UHFFFAOYSA-N n-ethyl-n,3-dimethylpentan-1-amine Chemical compound CCC(C)CCN(C)CC VOZWXDWNTANOST-UHFFFAOYSA-N 0.000 description 1
CUYFEVDEMNGHGP-UHFFFAOYSA-N n-ethyl-n,4-dimethylheptan-1-amine Chemical compound CCCC(C)CCCN(C)CC CUYFEVDEMNGHGP-UHFFFAOYSA-N 0.000 description 1
IBIZMOJVQCIOHO-UHFFFAOYSA-N n-ethyl-n,4-dimethylpentan-1-amine Chemical compound CCN(C)CCCC(C)C IBIZMOJVQCIOHO-UHFFFAOYSA-N 0.000 description 1
FLFIINJUKRMSJZ-UHFFFAOYSA-N n-ethyl-n,5-dimethylheptan-1-amine Chemical compound CCC(C)CCCCN(C)CC FLFIINJUKRMSJZ-UHFFFAOYSA-N 0.000 description 1
MPHQTBVOQNDZFS-UHFFFAOYSA-N n-ethyl-n,5-dimethylhexan-1-amine Chemical compound CCN(C)CCCCC(C)C MPHQTBVOQNDZFS-UHFFFAOYSA-N 0.000 description 1
UXSMMLMMHVFBTH-UHFFFAOYSA-N n-ethyl-n,6-dimethylheptan-1-amine Chemical compound CCN(C)CCCCCC(C)C UXSMMLMMHVFBTH-UHFFFAOYSA-N 0.000 description 1
HVBWKZITQBALFG-UHFFFAOYSA-N n-ethyl-n-methyl-2-propylpentan-1-amine Chemical compound CCCC(CCC)CN(C)CC HVBWKZITQBALFG-UHFFFAOYSA-N 0.000 description 1
QEVWCCUYXFIPNX-UHFFFAOYSA-N n-ethyl-n-methylcyclooctanamine Chemical compound CCN(C)C1CCCCCCC1 QEVWCCUYXFIPNX-UHFFFAOYSA-N 0.000 description 1
HGKWLWUBVWRXSK-UHFFFAOYSA-N n-ethyl-n-methylcyclopentanamine Chemical compound CCN(C)C1CCCC1 HGKWLWUBVWRXSK-UHFFFAOYSA-N 0.000 description 1
GKERNLYSUCIOIN-UHFFFAOYSA-N n-ethyl-n-methylheptan-2-amine Chemical compound CCCCCC(C)N(C)CC GKERNLYSUCIOIN-UHFFFAOYSA-N 0.000 description 1
JAUOWDIUOTXYPP-UHFFFAOYSA-N n-ethyl-n-methylheptan-3-amine;n-ethyl-n-methylheptan-4-amine Chemical compound CCCCC(CC)N(C)CC.CCCC(CCC)N(C)CC JAUOWDIUOTXYPP-UHFFFAOYSA-N 0.000 description 1
QLPOBUIRFXAKEO-UHFFFAOYSA-N n-ethyl-n-methylhexan-2-amine Chemical compound CCCCC(C)N(C)CC QLPOBUIRFXAKEO-UHFFFAOYSA-N 0.000 description 1
NQHPTUWPOLUNIT-UHFFFAOYSA-N n-ethyl-n-methylhexan-3-amine Chemical compound CCCC(CC)N(C)CC NQHPTUWPOLUNIT-UHFFFAOYSA-N 0.000 description 1
DOPGITBHCKHUSV-UHFFFAOYSA-N n-ethyl-n-methyloctan-2-amine Chemical compound CCCCCCC(C)N(C)CC DOPGITBHCKHUSV-UHFFFAOYSA-N 0.000 description 1
YGMZIBKZGRMQPB-UHFFFAOYSA-N n-ethyl-n-methyloctan-3-amine Chemical compound CCCCCC(CC)N(C)CC YGMZIBKZGRMQPB-UHFFFAOYSA-N 0.000 description 1
KUZKQXAPSKMONG-UHFFFAOYSA-N n-ethyl-n-methyloctan-4-amine Chemical compound CCCCC(CCC)N(C)CC KUZKQXAPSKMONG-UHFFFAOYSA-N 0.000 description 1
CVROJDQHTFJRIE-UHFFFAOYSA-N n-ethyl-n-methylpentan-2-amine Chemical compound CCCC(C)N(C)CC CVROJDQHTFJRIE-UHFFFAOYSA-N 0.000 description 1
OKGGHIDPQJWJTI-UHFFFAOYSA-N n-ethyl-n-methylpentan-3-amine Chemical compound CCC(CC)N(C)CC OKGGHIDPQJWJTI-UHFFFAOYSA-N 0.000 description 1
RIWRFSMVIUAEBX-UHFFFAOYSA-N n-methyl-1-phenylmethanamine Chemical compound CNCC1=CC=CC=C1 RIWRFSMVIUAEBX-UHFFFAOYSA-N 0.000 description 1
NEMUVWSQFWIZKP-UHFFFAOYSA-N n-methyl-n-trichlorosilylmethanamine Chemical compound CN(C)[Si](Cl)(Cl)Cl NEMUVWSQFWIZKP-UHFFFAOYSA-N 0.000 description 1
230000007935 neutral effect Effects 0.000 description 1
125000005151 nonafluorobutanesulfonyl group Chemical group FC(C(C(S(=O)(=O)*)(F)F)(F)F)(C(F)(F)F)F 0.000 description 1
JFNLZVQOOSMTJK-KNVOCYPGSA-N norbornene Chemical compound C1[C@@H]2CC[C@H]1C=C2 JFNLZVQOOSMTJK-KNVOCYPGSA-N 0.000 description 1
150000002894 organic compounds Chemical class 0.000 description 1
239000003960 organic solvent Substances 0.000 description 1
TWNQGVIAIRXVLR-UHFFFAOYSA-N oxo(oxoalumanyloxy)alumane Chemical compound O=[Al]O[Al]=O TWNQGVIAIRXVLR-UHFFFAOYSA-N 0.000 description 1
229920000573 polyethylene Polymers 0.000 description 1
229920001223 polyethylene glycol Polymers 0.000 description 1
239000002685 polymerization catalyst Substances 0.000 description 1
230000000379 polymerizing effect Effects 0.000 description 1
229920002223 polystyrene Polymers 0.000 description 1
125000004805 propylene group Chemical group [H]C([H])([H])C([H])([*:1])C([H])([H])[*:2] 0.000 description 1
239000002994 raw material Substances 0.000 description 1
239000013557 residual solvent Substances 0.000 description 1
239000011833 salt mixture Substances 0.000 description 1
230000007017 scission Effects 0.000 description 1
230000035945 sensitivity Effects 0.000 description 1
150000004756 silanes Chemical class 0.000 description 1
239000000741 silica gel Substances 0.000 description 1
229910002027 silica gel Inorganic materials 0.000 description 1
239000000377 silicon dioxide Substances 0.000 description 1
235000012239 silicon dioxide Nutrition 0.000 description 1
239000005049 silicon tetrachloride Substances 0.000 description 1
239000000344 soap Substances 0.000 description 1
239000007787 solid Substances 0.000 description 1
230000003068 static effect Effects 0.000 description 1
238000003756 stirring Methods 0.000 description 1
125000001424 substituent group Chemical group 0.000 description 1
150000003459 sulfonic acid esters Chemical class 0.000 description 1
239000000454 talc Substances 0.000 description 1
229910052623 talc Inorganic materials 0.000 description 1
229920001897 terpolymer Polymers 0.000 description 1
125000005147 toluenesulfonyl group Chemical group C=1(C(=CC=CC1)S(=O)(=O)*)C 0.000 description 1
150000003623 transition metal compounds Chemical class 0.000 description 1
LALRXNPLTWZJIJ-UHFFFAOYSA-N triethylborane Chemical compound CCB(CC)CC LALRXNPLTWZJIJ-UHFFFAOYSA-N 0.000 description 1
125000004044 trifluoroacetyl group Chemical group FC(C(=O)*)(F)F 0.000 description 1
125000001889 triflyl group Chemical group FC(F)(F)S(*)(=O)=O 0.000 description 1
125000000026 trimethylsilyl group Chemical group [H]C([H])([H])[Si]([*])(C([H])([H])[H])C([H])([H])[H] 0.000 description 1
LFXVBWRMVZPLFK-UHFFFAOYSA-N trioctylalumane Chemical compound CCCCCCCC[Al](CCCCCCCC)CCCCCCCC LFXVBWRMVZPLFK-UHFFFAOYSA-N 0.000 description 1
ANEFWEBMQHRDLH-UHFFFAOYSA-N tris(2,3,4,5,6-pentafluorophenyl) borate Chemical compound FC1=C(F)C(F)=C(F)C(F)=C1OB(OC=1C(=C(F)C(F)=C(F)C=1F)F)OC1=C(F)C(F)=C(F)C(F)=C1F ANEFWEBMQHRDLH-UHFFFAOYSA-N 0.000 description 1
ORUFTXBRVJTAFU-UHFFFAOYSA-N tris(4-fluorophenyl) borate Chemical compound C1=CC(F)=CC=C1OB(OC=1C=CC(F)=CC=1)OC1=CC=C(F)C=C1 ORUFTXBRVJTAFU-UHFFFAOYSA-N 0.000 description 1
238000005406 washing Methods 0.000 description 1
XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
239000008096 xylene Substances 0.000 description 1
239000004711 α-olefin Substances 0.000 description 1