DE19714122A1 - Bleichaktive Metall-Komplexe - Google Patents
Bleichaktive Metall-KomplexeInfo
- Publication number
- DE19714122A1 DE19714122A1 DE19714122A DE19714122A DE19714122A1 DE 19714122 A1 DE19714122 A1 DE 19714122A1 DE 19714122 A DE19714122 A DE 19714122A DE 19714122 A DE19714122 A DE 19714122A DE 19714122 A1 DE19714122 A1 DE 19714122A1
- Authority
- DE
- Germany
- Prior art keywords
- compounds
- formula
- integer
- iii
- oxidation state
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Withdrawn
Links
- 229910052751 metal Inorganic materials 0.000 title description 18
- 239000002184 metal Substances 0.000 title description 18
- 150000001875 compounds Chemical class 0.000 claims description 29
- 239000003599 detergent Substances 0.000 claims description 27
- 238000004061 bleaching Methods 0.000 claims description 26
- 239000003054 catalyst Substances 0.000 claims description 15
- 230000003647 oxidation Effects 0.000 claims description 14
- 238000007254 oxidation reaction Methods 0.000 claims description 14
- 239000011572 manganese Substances 0.000 claims description 11
- 239000007844 bleaching agent Substances 0.000 claims description 10
- 239000012459 cleaning agent Substances 0.000 claims description 10
- 229910052739 hydrogen Inorganic materials 0.000 claims description 10
- 239000001257 hydrogen Substances 0.000 claims description 10
- 239000004753 textile Substances 0.000 claims description 9
- 229910052748 manganese Inorganic materials 0.000 claims description 8
- 239000002253 acid Substances 0.000 claims description 7
- 150000002431 hydrogen Chemical class 0.000 claims description 7
- PWHULOQIROXLJO-UHFFFAOYSA-N Manganese Chemical compound [Mn] PWHULOQIROXLJO-UHFFFAOYSA-N 0.000 claims description 6
- 125000000753 cycloalkyl group Chemical group 0.000 claims description 6
- 239000003446 ligand Substances 0.000 claims description 6
- 229910017052 cobalt Inorganic materials 0.000 claims description 5
- 239000010941 cobalt Substances 0.000 claims description 5
- GUTLYIVDDKVIGB-UHFFFAOYSA-N cobalt atom Chemical compound [Co] GUTLYIVDDKVIGB-UHFFFAOYSA-N 0.000 claims description 5
- 150000003839 salts Chemical group 0.000 claims description 5
- QGZKDVFQNNGYKY-UHFFFAOYSA-O ammonium group Chemical group [NH4+] QGZKDVFQNNGYKY-UHFFFAOYSA-O 0.000 claims description 4
- 150000005840 aryl radicals Chemical class 0.000 claims description 4
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 claims description 3
- 125000003178 carboxy group Chemical group [H]OC(*)=O 0.000 claims description 3
- 125000000008 (C1-C10) alkyl group Chemical group 0.000 claims description 2
- 125000000229 (C1-C4)alkoxy group Chemical group 0.000 claims description 2
- 229910020366 ClO 4 Inorganic materials 0.000 claims description 2
- 150000004696 coordination complex Chemical class 0.000 claims description 2
- 125000005843 halogen group Chemical group 0.000 claims description 2
- 125000000020 sulfo group Chemical group O=S(=O)([*])O[H] 0.000 claims description 2
- GBXQPDCOMJJCMJ-UHFFFAOYSA-M trimethyl-[6-(trimethylazaniumyl)hexyl]azanium;bromide Chemical compound [Br-].C[N+](C)(C)CCCCCC[N+](C)(C)C GBXQPDCOMJJCMJ-UHFFFAOYSA-M 0.000 claims description 2
- 125000003277 amino group Chemical group 0.000 claims 1
- -1 Transition metal salts Chemical class 0.000 description 27
- 239000000203 mixture Substances 0.000 description 21
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 12
- 239000011734 sodium Substances 0.000 description 11
- 229910052708 sodium Inorganic materials 0.000 description 11
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 9
- 239000000126 substance Substances 0.000 description 9
- 239000000344 soap Substances 0.000 description 8
- 239000007788 liquid Substances 0.000 description 7
- 239000007795 chemical reaction product Substances 0.000 description 6
- 235000014113 dietary fatty acids Nutrition 0.000 description 6
- 239000000194 fatty acid Substances 0.000 description 6
- 229930195729 fatty acid Natural products 0.000 description 6
- 125000000864 peroxy group Chemical group O(O*)* 0.000 description 6
- IAYPIBMASNFSPL-UHFFFAOYSA-N Ethylene oxide Chemical compound C1CO1 IAYPIBMASNFSPL-UHFFFAOYSA-N 0.000 description 5
- 239000012190 activator Substances 0.000 description 5
- 125000000217 alkyl group Chemical group 0.000 description 5
- 150000004665 fatty acids Chemical class 0.000 description 5
- 150000002500 ions Chemical class 0.000 description 5
- 150000002978 peroxides Chemical class 0.000 description 5
- 239000007787 solid Substances 0.000 description 5
- MHAJPDPJQMAIIY-UHFFFAOYSA-N Hydrogen peroxide Chemical compound OO MHAJPDPJQMAIIY-UHFFFAOYSA-N 0.000 description 4
- KFZMGEQAYNKOFK-UHFFFAOYSA-N Isopropanol Chemical compound CC(C)O KFZMGEQAYNKOFK-UHFFFAOYSA-N 0.000 description 4
- 150000001298 alcohols Chemical class 0.000 description 4
- 125000000129 anionic group Chemical group 0.000 description 4
- 239000011575 calcium Substances 0.000 description 4
- 238000009472 formulation Methods 0.000 description 4
- 239000008187 granular material Substances 0.000 description 4
- 239000004615 ingredient Substances 0.000 description 4
- 239000002736 nonionic surfactant Substances 0.000 description 4
- 239000004094 surface-active agent Substances 0.000 description 4
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 4
- XSVSPKKXQGNHMD-UHFFFAOYSA-N 5-bromo-3-methyl-1,2-thiazole Chemical compound CC=1C=C(Br)SN=1 XSVSPKKXQGNHMD-UHFFFAOYSA-N 0.000 description 3
- OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 description 3
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 3
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 description 3
- ZMXDDKWLCZADIW-UHFFFAOYSA-N N,N-Dimethylformamide Chemical compound CN(C)C=O ZMXDDKWLCZADIW-UHFFFAOYSA-N 0.000 description 3
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 3
- 244000269722 Thea sinensis Species 0.000 description 3
- 229910052783 alkali metal Inorganic materials 0.000 description 3
- 125000003118 aryl group Chemical group 0.000 description 3
- 229910052791 calcium Inorganic materials 0.000 description 3
- 238000006243 chemical reaction Methods 0.000 description 3
- KRKNYBCHXYNGOX-UHFFFAOYSA-N citric acid Chemical compound OC(=O)CC(O)(C(O)=O)CC(O)=O KRKNYBCHXYNGOX-UHFFFAOYSA-N 0.000 description 3
- 230000000694 effects Effects 0.000 description 3
- 230000007062 hydrolysis Effects 0.000 description 3
- 238000006460 hydrolysis reaction Methods 0.000 description 3
- 238000000034 method Methods 0.000 description 3
- 239000000243 solution Substances 0.000 description 3
- 150000003871 sulfonates Chemical class 0.000 description 3
- 238000005406 washing Methods 0.000 description 3
- 235000013162 Cocos nucifera Nutrition 0.000 description 2
- 244000060011 Cocos nucifera Species 0.000 description 2
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 2
- KCXVZYZYPLLWCC-UHFFFAOYSA-N EDTA Chemical class OC(=O)CN(CC(O)=O)CCN(CC(O)=O)CC(O)=O KCXVZYZYPLLWCC-UHFFFAOYSA-N 0.000 description 2
- 102000004190 Enzymes Human genes 0.000 description 2
- 108090000790 Enzymes Proteins 0.000 description 2
- PMZURENOXWZQFD-UHFFFAOYSA-L Sodium Sulfate Chemical class [Na+].[Na+].[O-]S([O-])(=O)=O PMZURENOXWZQFD-UHFFFAOYSA-L 0.000 description 2
- 150000007513 acids Chemical class 0.000 description 2
- 230000003213 activating effect Effects 0.000 description 2
- 125000001931 aliphatic group Chemical group 0.000 description 2
- 150000003863 ammonium salts Chemical class 0.000 description 2
- 239000011230 binding agent Substances 0.000 description 2
- 229940088598 enzyme Drugs 0.000 description 2
- 150000002148 esters Chemical class 0.000 description 2
- 239000004744 fabric Substances 0.000 description 2
- SUMDYPCJJOFFON-UHFFFAOYSA-N isethionic acid Chemical compound OCCS(O)(=O)=O SUMDYPCJJOFFON-UHFFFAOYSA-N 0.000 description 2
- YDSWCNNOKPMOTP-UHFFFAOYSA-N mellitic acid Chemical class OC(=O)C1=C(C(O)=O)C(C(O)=O)=C(C(O)=O)C(C(O)=O)=C1C(O)=O YDSWCNNOKPMOTP-UHFFFAOYSA-N 0.000 description 2
- 239000000047 product Substances 0.000 description 2
- VHNQIURBCCNWDN-UHFFFAOYSA-N pyridine-2,6-diamine Chemical compound NC1=CC=CC(N)=N1 VHNQIURBCCNWDN-UHFFFAOYSA-N 0.000 description 2
- SMQUZDBALVYZAC-UHFFFAOYSA-N salicylaldehyde Chemical compound OC1=CC=CC=C1C=O SMQUZDBALVYZAC-UHFFFAOYSA-N 0.000 description 2
- CDBYLPFSWZWCQE-UHFFFAOYSA-L sodium carbonate Substances [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 description 2
- 229910052938 sodium sulfate Inorganic materials 0.000 description 2
- 235000011152 sodium sulphate Nutrition 0.000 description 2
- 239000007790 solid phase Substances 0.000 description 2
- 239000000758 substrate Substances 0.000 description 2
- 235000013616 tea Nutrition 0.000 description 2
- 229910052723 transition metal Inorganic materials 0.000 description 2
- 239000004711 α-olefin Substances 0.000 description 2
- CIOXZGOUEYHNBF-UHFFFAOYSA-N (carboxymethoxy)succinic acid Chemical class OC(=O)COC(C(O)=O)CC(O)=O CIOXZGOUEYHNBF-UHFFFAOYSA-N 0.000 description 1
- CFPOJWPDQWJEMO-UHFFFAOYSA-N 2-(1,2-dicarboxyethoxy)butanedioic acid Chemical class OC(=O)CC(C(O)=O)OC(C(O)=O)CC(O)=O CFPOJWPDQWJEMO-UHFFFAOYSA-N 0.000 description 1
- QBONJTWTMGVHQM-UHFFFAOYSA-N 2-[[6-[(2-hydroxyphenyl)methylideneamino]pyridin-2-yl]iminomethyl]phenol Chemical compound OC1=CC=CC=C1C=NC1=CC=CC(N=CC=2C(=CC=CC=2)O)=N1 QBONJTWTMGVHQM-UHFFFAOYSA-N 0.000 description 1
- FRIBMENBGGCKPD-UHFFFAOYSA-N 3-(2,3-dimethoxyphenyl)prop-2-enal Chemical compound COC1=CC=CC(C=CC=O)=C1OC FRIBMENBGGCKPD-UHFFFAOYSA-N 0.000 description 1
- FAGGUIDTQQXDSJ-UHFFFAOYSA-N 3-benzoylazepan-2-one Chemical compound C=1C=CC=CC=1C(=O)C1CCCCNC1=O FAGGUIDTQQXDSJ-UHFFFAOYSA-N 0.000 description 1
- KJDPLFMXUGEZSU-UHFFFAOYSA-N 3-butyl-2-hydroxybenzaldehyde Chemical compound CCCCC1=CC=CC(C=O)=C1O KJDPLFMXUGEZSU-UHFFFAOYSA-N 0.000 description 1
- 102000013142 Amylases Human genes 0.000 description 1
- 108010065511 Amylases Proteins 0.000 description 1
- 102000005701 Calcium-Binding Proteins Human genes 0.000 description 1
- 108010045403 Calcium-Binding Proteins Proteins 0.000 description 1
- 102000005575 Cellulases Human genes 0.000 description 1
- 108010084185 Cellulases Proteins 0.000 description 1
- 229920000742 Cotton Polymers 0.000 description 1
- FBPFZTCFMRRESA-FSIIMWSLSA-N D-Glucitol Natural products OC[C@H](O)[C@H](O)[C@@H](O)[C@H](O)CO FBPFZTCFMRRESA-FSIIMWSLSA-N 0.000 description 1
- FBPFZTCFMRRESA-JGWLITMVSA-N D-glucitol Chemical compound OC[C@H](O)[C@@H](O)[C@H](O)[C@H](O)CO FBPFZTCFMRRESA-JGWLITMVSA-N 0.000 description 1
- PIICEJLVQHRZGT-UHFFFAOYSA-N Ethylenediamine Chemical compound NCCN PIICEJLVQHRZGT-UHFFFAOYSA-N 0.000 description 1
- SHBUUTHKGIVMJT-UHFFFAOYSA-N Hydroxystearate Chemical compound CCCCCCCCCCCCCCCCCC(=O)OO SHBUUTHKGIVMJT-UHFFFAOYSA-N 0.000 description 1
- 239000004367 Lipase Substances 0.000 description 1
- 102000004882 Lipase Human genes 0.000 description 1
- 108090001060 Lipase Proteins 0.000 description 1
- SUZRRICLUFMAQD-UHFFFAOYSA-N N-Methyltaurine Chemical compound CNCCS(O)(=O)=O SUZRRICLUFMAQD-UHFFFAOYSA-N 0.000 description 1
- 239000012425 OXONE® Substances 0.000 description 1
- 229910019142 PO4 Inorganic materials 0.000 description 1
- 102000035195 Peptidases Human genes 0.000 description 1
- 108091005804 Peptidases Proteins 0.000 description 1
- 229930182556 Polyacetal Natural products 0.000 description 1
- 229920000388 Polyphosphate Polymers 0.000 description 1
- GOOHAUXETOMSMM-UHFFFAOYSA-N Propylene oxide Chemical compound CC1CO1 GOOHAUXETOMSMM-UHFFFAOYSA-N 0.000 description 1
- 239000004365 Protease Substances 0.000 description 1
- DWAQJAXMDSEUJJ-UHFFFAOYSA-M Sodium bisulfite Chemical compound [Na+].OS([O-])=O DWAQJAXMDSEUJJ-UHFFFAOYSA-M 0.000 description 1
- KDYFGRWQOYBRFD-UHFFFAOYSA-N Succinic acid Natural products OC(=O)CCC(O)=O KDYFGRWQOYBRFD-UHFFFAOYSA-N 0.000 description 1
- ULUAUXLGCMPNKK-UHFFFAOYSA-N Sulfobutanedioic acid Chemical class OC(=O)CC(C(O)=O)S(O)(=O)=O ULUAUXLGCMPNKK-UHFFFAOYSA-N 0.000 description 1
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical class OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 description 1
- BGRWYDHXPHLNKA-UHFFFAOYSA-N Tetraacetylethylenediamine Chemical compound CC(=O)N(C(C)=O)CCN(C(C)=O)C(C)=O BGRWYDHXPHLNKA-UHFFFAOYSA-N 0.000 description 1
- 235000006468 Thea sinensis Nutrition 0.000 description 1
- ZMANZCXQSJIPKH-UHFFFAOYSA-N Triethylamine Chemical compound CCN(CC)CC ZMANZCXQSJIPKH-UHFFFAOYSA-N 0.000 description 1
- 239000001083 [(2R,3R,4S,5R)-1,2,4,5-tetraacetyloxy-6-oxohexan-3-yl] acetate Substances 0.000 description 1
- UAOKXEHOENRFMP-ZJIFWQFVSA-N [(2r,3r,4s,5r)-2,3,4,5-tetraacetyloxy-6-oxohexyl] acetate Chemical compound CC(=O)OC[C@@H](OC(C)=O)[C@@H](OC(C)=O)[C@H](OC(C)=O)[C@@H](OC(C)=O)C=O UAOKXEHOENRFMP-ZJIFWQFVSA-N 0.000 description 1
- WKBIBHADRQJGRP-UHFFFAOYSA-N [Co].OC1=C(C=NC2=CC=CC(=N2)N=CC2=C(C(=CC=C2)OC)O)C=CC=C1OC Chemical compound [Co].OC1=C(C=NC2=CC=CC(=N2)N=CC2=C(C(=CC=C2)OC)O)C=CC=C1OC WKBIBHADRQJGRP-UHFFFAOYSA-N 0.000 description 1
- DCAOGQVFHBDNNL-UHFFFAOYSA-N [Co].OC1=C(C=NC2=CC=CC(=N2)N=CC2=C(C=C(C=C2)N(CC)CC)O)C=CC(=C1)N(CC)CC Chemical compound [Co].OC1=C(C=NC2=CC=CC(=N2)N=CC2=C(C=C(C=C2)N(CC)CC)O)C=CC(=C1)N(CC)CC DCAOGQVFHBDNNL-UHFFFAOYSA-N 0.000 description 1
- RXBICMLMJRPKMM-UHFFFAOYSA-N [Co].OC1=C(C=NC2=CC=CC(=N2)N=CC2=C(C=C(C=C2)OC)O)C=CC(=C1)OC Chemical compound [Co].OC1=C(C=NC2=CC=CC(=N2)N=CC2=C(C=C(C=C2)OC)O)C=CC(=C1)OC RXBICMLMJRPKMM-UHFFFAOYSA-N 0.000 description 1
- COORTAXAPWLRRU-UHFFFAOYSA-N [Co].OC1=C(C=NC2=CC=CC(=N2)N=CC2=C(C=CC(=C2)[N+](=O)[O-])O)C=C(C=C1)[N+](=O)[O-] Chemical compound [Co].OC1=C(C=NC2=CC=CC(=N2)N=CC2=C(C=CC(=C2)[N+](=O)[O-])O)C=C(C=C1)[N+](=O)[O-] COORTAXAPWLRRU-UHFFFAOYSA-N 0.000 description 1
- NEDOZTBSLKZCHQ-UHFFFAOYSA-N [Co].OC1=C(C=NC2=CC=CC(=N2)N=CC2=C(C=CC=C2)O)C=CC=C1 Chemical compound [Co].OC1=C(C=NC2=CC=CC(=N2)N=CC2=C(C=CC=C2)O)C=CC=C1 NEDOZTBSLKZCHQ-UHFFFAOYSA-N 0.000 description 1
- DGJLCYKNLIILHF-UHFFFAOYSA-N [Mn].OC1=C(C=NC2=CC=CC(=N2)N=CC2=C(C(=CC=C2)OC)O)C=CC=C1OC Chemical compound [Mn].OC1=C(C=NC2=CC=CC(=N2)N=CC2=C(C(=CC=C2)OC)O)C=CC=C1OC DGJLCYKNLIILHF-UHFFFAOYSA-N 0.000 description 1
- AYGSRPGJSFKYMU-UHFFFAOYSA-N [Mn].OC1=C(C=NC2=CC=CC(=N2)N=CC2=C(C=C(C=C2)N(CC)CC)O)C=CC(=C1)N(CC)CC Chemical compound [Mn].OC1=C(C=NC2=CC=CC(=N2)N=CC2=C(C=C(C=C2)N(CC)CC)O)C=CC(=C1)N(CC)CC AYGSRPGJSFKYMU-UHFFFAOYSA-N 0.000 description 1
- HQGPSQQHMWYXIN-UHFFFAOYSA-N [Mn].OC1=C(C=NC2=CC=CC(=N2)N=CC2=C(C=C(C=C2)OC)O)C=CC(=C1)OC Chemical compound [Mn].OC1=C(C=NC2=CC=CC(=N2)N=CC2=C(C=C(C=C2)OC)O)C=CC(=C1)OC HQGPSQQHMWYXIN-UHFFFAOYSA-N 0.000 description 1
- RMDSUGSUEUUXIV-UHFFFAOYSA-N [Mn].OC1=C(C=NC2=CC=CC(=N2)N=CC2=C(C=CC(=C2)[N+](=O)[O-])O)C=C(C=C1)[N+](=O)[O-] Chemical compound [Mn].OC1=C(C=NC2=CC=CC(=N2)N=CC2=C(C=CC(=C2)[N+](=O)[O-])O)C=C(C=C1)[N+](=O)[O-] RMDSUGSUEUUXIV-UHFFFAOYSA-N 0.000 description 1
- AKGBEUSVNPDFPV-UHFFFAOYSA-N [Mn].OC1=C(C=NC2=CC=CC(=N2)N=CC2=C(C=CC=C2)O)C=CC=C1 Chemical compound [Mn].OC1=C(C=NC2=CC=CC(=N2)N=CC2=C(C=CC=C2)O)C=CC=C1 AKGBEUSVNPDFPV-UHFFFAOYSA-N 0.000 description 1
- DPXJVFZANSGRMM-UHFFFAOYSA-N acetic acid;2,3,4,5,6-pentahydroxyhexanal;sodium Chemical compound [Na].CC(O)=O.OCC(O)C(O)C(O)C(O)C=O DPXJVFZANSGRMM-UHFFFAOYSA-N 0.000 description 1
- 230000009471 action Effects 0.000 description 1
- 239000013543 active substance Substances 0.000 description 1
- 239000000654 additive Substances 0.000 description 1
- 150000001335 aliphatic alkanes Chemical class 0.000 description 1
- 239000003513 alkali Substances 0.000 description 1
- 150000004973 alkali metal peroxides Chemical class 0.000 description 1
- 150000001340 alkali metals Chemical class 0.000 description 1
- 150000001336 alkenes Chemical class 0.000 description 1
- 229920013820 alkyl cellulose Polymers 0.000 description 1
- 229940045714 alkyl sulfonate alkylating agent Drugs 0.000 description 1
- 125000002947 alkylene group Chemical group 0.000 description 1
- 229910052782 aluminium Inorganic materials 0.000 description 1
- 239000002280 amphoteric surfactant Substances 0.000 description 1
- 235000019418 amylase Nutrition 0.000 description 1
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- 239000002518 antifoaming agent Substances 0.000 description 1
- 239000007864 aqueous solution Substances 0.000 description 1
- 230000008901 benefit Effects 0.000 description 1
- 235000020279 black tea Nutrition 0.000 description 1
- 125000004432 carbon atom Chemical group C* 0.000 description 1
- 239000001768 carboxy methyl cellulose Substances 0.000 description 1
- 150000007942 carboxylates Chemical class 0.000 description 1
- 230000003197 catalytic effect Effects 0.000 description 1
- 125000002091 cationic group Chemical group 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- 238000004140 cleaning Methods 0.000 description 1
- QAHREYKOYSIQPH-UHFFFAOYSA-L cobalt(II) acetate Chemical compound [Co+2].CC([O-])=O.CC([O-])=O QAHREYKOYSIQPH-UHFFFAOYSA-L 0.000 description 1
- 239000003240 coconut oil Substances 0.000 description 1
- 235000019864 coconut oil Nutrition 0.000 description 1
- 235000016213 coffee Nutrition 0.000 description 1
- 235000013353 coffee beverage Nutrition 0.000 description 1
- UNWDCFHEVIWFCW-UHFFFAOYSA-N decanediperoxoic acid Chemical compound OOC(=O)CCCCCCCCC(=O)OO UNWDCFHEVIWFCW-UHFFFAOYSA-N 0.000 description 1
- 239000000645 desinfectant Substances 0.000 description 1
- 150000004985 diamines Chemical class 0.000 description 1
- CICFLWYXGGPEOO-UHFFFAOYSA-M dimethyl-octyl-(11-oxo-11-phenoxyundecyl)azanium;chloride Chemical compound [Cl-].CCCCCCCC[N+](C)(C)CCCCCCCCCCC(=O)OC1=CC=CC=C1 CICFLWYXGGPEOO-UHFFFAOYSA-M 0.000 description 1
- VTIIJXUACCWYHX-UHFFFAOYSA-L disodium;carboxylatooxy carbonate Chemical compound [Na+].[Na+].[O-]C(=O)OOC([O-])=O VTIIJXUACCWYHX-UHFFFAOYSA-L 0.000 description 1
- BRDYCNFHFWUBCZ-UHFFFAOYSA-N dodecaneperoxoic acid Chemical compound CCCCCCCCCCCC(=O)OO BRDYCNFHFWUBCZ-UHFFFAOYSA-N 0.000 description 1
- 239000000975 dye Substances 0.000 description 1
- 230000007613 environmental effect Effects 0.000 description 1
- 230000032050 esterification Effects 0.000 description 1
- 238000005886 esterification reaction Methods 0.000 description 1
- 238000002474 experimental method Methods 0.000 description 1
- 150000002191 fatty alcohols Chemical class 0.000 description 1
- 239000000835 fiber Substances 0.000 description 1
- 239000006260 foam Substances 0.000 description 1
- 239000004088 foaming agent Substances 0.000 description 1
- 235000019990 fruit wine Nutrition 0.000 description 1
- 239000008233 hard water Substances 0.000 description 1
- 230000006872 improvement Effects 0.000 description 1
- 239000003112 inhibitor Substances 0.000 description 1
- 239000002563 ionic surfactant Substances 0.000 description 1
- 229940045996 isethionic acid Drugs 0.000 description 1
- 150000002576 ketones Chemical class 0.000 description 1
- 235000019421 lipase Nutrition 0.000 description 1
- 239000012669 liquid formulation Substances 0.000 description 1
- 229940057995 liquid paraffin Drugs 0.000 description 1
- 150000004668 long chain fatty acids Chemical class 0.000 description 1
- CESXSDZNZGSWSP-UHFFFAOYSA-L manganese(2+);diacetate;tetrahydrate Chemical compound O.O.O.O.[Mn+2].CC([O-])=O.CC([O-])=O CESXSDZNZGSWSP-UHFFFAOYSA-L 0.000 description 1
- WPBNNNQJVZRUHP-UHFFFAOYSA-L manganese(2+);methyl n-[[2-(methoxycarbonylcarbamothioylamino)phenyl]carbamothioyl]carbamate;n-[2-(sulfidocarbothioylamino)ethyl]carbamodithioate Chemical compound [Mn+2].[S-]C(=S)NCCNC([S-])=S.COC(=O)NC(=S)NC1=CC=CC=C1NC(=S)NC(=O)OC WPBNNNQJVZRUHP-UHFFFAOYSA-L 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 238000002156 mixing Methods 0.000 description 1
- 229930014626 natural product Natural products 0.000 description 1
- 230000007935 neutral effect Effects 0.000 description 1
- 238000006386 neutralization reaction Methods 0.000 description 1
- 150000002825 nitriles Chemical class 0.000 description 1
- MGFYIUFZLHCRTH-UHFFFAOYSA-N nitrilotriacetic acid Chemical compound OC(=O)CN(CC(O)=O)CC(O)=O MGFYIUFZLHCRTH-UHFFFAOYSA-N 0.000 description 1
- JRZJOMJEPLMPRA-UHFFFAOYSA-N olefin Natural products CCCCCCCC=C JRZJOMJEPLMPRA-UHFFFAOYSA-N 0.000 description 1
- 150000001451 organic peroxides Chemical class 0.000 description 1
- MPQXHAGKBWFSNV-UHFFFAOYSA-N oxidophosphanium Chemical group [PH3]=O MPQXHAGKBWFSNV-UHFFFAOYSA-N 0.000 description 1
- 239000003346 palm kernel oil Substances 0.000 description 1
- 235000019865 palm kernel oil Nutrition 0.000 description 1
- 235000011837 pasties Nutrition 0.000 description 1
- HJKYXKSLRZKNSI-UHFFFAOYSA-I pentapotassium;hydrogen sulfate;oxido sulfate;sulfuric acid Chemical compound [K+].[K+].[K+].[K+].[K+].OS([O-])(=O)=O.[O-]S([O-])(=O)=O.OS(=O)(=O)O[O-].OS(=O)(=O)O[O-] HJKYXKSLRZKNSI-UHFFFAOYSA-I 0.000 description 1
- 239000002304 perfume Substances 0.000 description 1
- 125000005342 perphosphate group Chemical group 0.000 description 1
- 235000021317 phosphate Nutrition 0.000 description 1
- 239000004014 plasticizer Substances 0.000 description 1
- 239000002798 polar solvent Substances 0.000 description 1
- 229920000642 polymer Polymers 0.000 description 1
- 229920005862 polyol Polymers 0.000 description 1
- 150000003077 polyols Chemical class 0.000 description 1
- 229920006324 polyoxymethylene Polymers 0.000 description 1
- 239000001205 polyphosphate Substances 0.000 description 1
- 235000011176 polyphosphates Nutrition 0.000 description 1
- 229920001296 polysiloxane Polymers 0.000 description 1
- 230000008092 positive effect Effects 0.000 description 1
- 159000000001 potassium salts Chemical class 0.000 description 1
- 239000000843 powder Substances 0.000 description 1
- 230000001376 precipitating effect Effects 0.000 description 1
- 125000002924 primary amino group Chemical group [H]N([H])* 0.000 description 1
- 230000008569 process Effects 0.000 description 1
- JUJWROOIHBZHMG-UHFFFAOYSA-N pyridine Substances C1=CC=NC=C1 JUJWROOIHBZHMG-UHFFFAOYSA-N 0.000 description 1
- 125000001453 quaternary ammonium group Chemical group 0.000 description 1
- 150000003242 quaternary ammonium salts Chemical class 0.000 description 1
- 235000020095 red wine Nutrition 0.000 description 1
- 238000010992 reflux Methods 0.000 description 1
- 229920006395 saturated elastomer Polymers 0.000 description 1
- 229910000029 sodium carbonate Inorganic materials 0.000 description 1
- 235000019812 sodium carboxymethyl cellulose Nutrition 0.000 description 1
- 229920001027 sodium carboxymethylcellulose Polymers 0.000 description 1
- 235000010267 sodium hydrogen sulphite Nutrition 0.000 description 1
- QSKQNALVHFTOQX-UHFFFAOYSA-M sodium nonanoyloxybenzenesulfonate Chemical compound [Na+].CCCCCCCCC(=O)OC1=CC=CC=C1S([O-])(=O)=O QSKQNALVHFTOQX-UHFFFAOYSA-M 0.000 description 1
- 229960001922 sodium perborate Drugs 0.000 description 1
- 239000012418 sodium perborate tetrahydrate Substances 0.000 description 1
- 229940045872 sodium percarbonate Drugs 0.000 description 1
- 159000000000 sodium salts Chemical class 0.000 description 1
- 235000019832 sodium triphosphate Nutrition 0.000 description 1
- XVESOXRSUKAXRD-UHFFFAOYSA-M sodium;3-benzoyloxy-4-methylbenzoate Chemical compound [Na+].CC1=CC=C(C([O-])=O)C=C1OC(=O)C1=CC=CC=C1 XVESOXRSUKAXRD-UHFFFAOYSA-M 0.000 description 1
- IBDSNZLUHYKHQP-UHFFFAOYSA-N sodium;3-oxidodioxaborirane;tetrahydrate Chemical compound O.O.O.O.[Na+].[O-]B1OO1 IBDSNZLUHYKHQP-UHFFFAOYSA-N 0.000 description 1
- YKLJGMBLPUQQOI-UHFFFAOYSA-M sodium;oxidooxy(oxo)borane Chemical compound [Na+].[O-]OB=O YKLJGMBLPUQQOI-UHFFFAOYSA-M 0.000 description 1
- 239000002904 solvent Substances 0.000 description 1
- 239000000600 sorbitol Substances 0.000 description 1
- 238000001694 spray drying Methods 0.000 description 1
- 239000003381 stabilizer Substances 0.000 description 1
- 238000003756 stirring Methods 0.000 description 1
- 125000000547 substituted alkyl group Chemical group 0.000 description 1
- 230000001180 sulfating effect Effects 0.000 description 1
- BDHFUVZGWQCTTF-UHFFFAOYSA-M sulfonate Chemical compound [O-]S(=O)=O BDHFUVZGWQCTTF-UHFFFAOYSA-M 0.000 description 1
- 150000003462 sulfoxides Chemical class 0.000 description 1
- 150000003467 sulfuric acid derivatives Chemical class 0.000 description 1
- 239000003760 tallow Substances 0.000 description 1
- 150000003512 tertiary amines Chemical class 0.000 description 1
- CIHOLLKRGTVIJN-UHFFFAOYSA-N tert‐butyl hydroperoxide Chemical compound CC(C)(C)OO CIHOLLKRGTVIJN-UHFFFAOYSA-N 0.000 description 1
- 150000004685 tetrahydrates Chemical class 0.000 description 1
- 150000003624 transition metals Chemical class 0.000 description 1
- RYFMWSXOAZQYPI-UHFFFAOYSA-K trisodium phosphate Chemical compound [Na+].[Na+].[Na+].[O-]P([O-])([O-])=O RYFMWSXOAZQYPI-UHFFFAOYSA-K 0.000 description 1
- AQLJVWUFPCUVLO-UHFFFAOYSA-N urea hydrogen peroxide Chemical class OO.NC(N)=O AQLJVWUFPCUVLO-UHFFFAOYSA-N 0.000 description 1
- 239000010457 zeolite Substances 0.000 description 1
- 239000002888 zwitterionic surfactant Substances 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/168—Organometallic compounds or orgometallic complexes
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/39—Organic or inorganic per-compounds
- C11D3/3902—Organic or inorganic per-compounds combined with specific additives
- C11D3/3905—Bleach activators or bleach catalysts
- C11D3/3932—Inorganic compounds or complexes
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06L—DRY-CLEANING, WASHING OR BLEACHING FIBRES, FILAMENTS, THREADS, YARNS, FABRICS, FEATHERS OR MADE-UP FIBROUS GOODS; BLEACHING LEATHER OR FURS
- D06L4/00—Bleaching fibres, filaments, threads, yarns, fabrics, feathers or made-up fibrous goods; Bleaching leather or furs
- D06L4/10—Bleaching fibres, filaments, threads, yarns, fabrics, feathers or made-up fibrous goods; Bleaching leather or furs using agents which develop oxygen
- D06L4/13—Bleaching fibres, filaments, threads, yarns, fabrics, feathers or made-up fibrous goods; Bleaching leather or furs using agents which develop oxygen using inorganic agents
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21C—PRODUCTION OF CELLULOSE BY REMOVING NON-CELLULOSE SUBSTANCES FROM CELLULOSE-CONTAINING MATERIALS; REGENERATION OF PULPING LIQUORS; APPARATUS THEREFOR
- D21C9/00—After-treatment of cellulose pulp, e.g. of wood pulp, or cotton linters ; Treatment of dilute or dewatered pulp or process improvement taking place after obtaining the raw cellulosic material and not provided for elsewhere
- D21C9/10—Bleaching ; Apparatus therefor
- D21C9/1026—Other features in bleaching processes
- D21C9/1036—Use of compounds accelerating or improving the efficiency of the processes
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21C—PRODUCTION OF CELLULOSE BY REMOVING NON-CELLULOSE SUBSTANCES FROM CELLULOSE-CONTAINING MATERIALS; REGENERATION OF PULPING LIQUORS; APPARATUS THEREFOR
- D21C9/00—After-treatment of cellulose pulp, e.g. of wood pulp, or cotton linters ; Treatment of dilute or dewatered pulp or process improvement taking place after obtaining the raw cellulosic material and not provided for elsewhere
- D21C9/10—Bleaching ; Apparatus therefor
- D21C9/16—Bleaching ; Apparatus therefor with per compounds
- D21C9/163—Bleaching ; Apparatus therefor with per compounds with peroxides
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Life Sciences & Earth Sciences (AREA)
- Wood Science & Technology (AREA)
- Inorganic Chemistry (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Textile Engineering (AREA)
- Detergent Compositions (AREA)
- Pyridine Compounds (AREA)
- Paper (AREA)
Priority Applications (8)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DE19714122A DE19714122A1 (de) | 1997-04-05 | 1997-04-05 | Bleichaktive Metall-Komplexe |
| EP98105257A EP0869171B1 (de) | 1997-04-05 | 1998-03-24 | Bleichaktive Metall-Komplexe |
| DE59812192T DE59812192D1 (de) | 1997-04-05 | 1998-03-24 | Bleichaktive Metall-Komplexe |
| ES98105257T ES2231913T3 (es) | 1997-04-05 | 1998-03-24 | Complejos con metales, activos para el blanqueo. |
| US09/054,204 US6139769A (en) | 1997-04-05 | 1998-04-02 | Bleaching-active metal complexes |
| JP09204098A JP4049881B2 (ja) | 1997-04-05 | 1998-04-03 | 漂白活性金属錯体 |
| BR9801148-0A BR9801148A (pt) | 1997-04-05 | 1998-04-03 | Complexos de metal ativos para branqueamento. |
| US09/613,211 US6602441B1 (en) | 1997-04-05 | 2000-07-10 | Bleaching-active metal complexes |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DE19714122A DE19714122A1 (de) | 1997-04-05 | 1997-04-05 | Bleichaktive Metall-Komplexe |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| DE19714122A1 true DE19714122A1 (de) | 1998-10-08 |
Family
ID=7825561
Family Applications (2)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| DE19714122A Withdrawn DE19714122A1 (de) | 1997-04-05 | 1997-04-05 | Bleichaktive Metall-Komplexe |
| DE59812192T Expired - Fee Related DE59812192D1 (de) | 1997-04-05 | 1998-03-24 | Bleichaktive Metall-Komplexe |
Family Applications After (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| DE59812192T Expired - Fee Related DE59812192D1 (de) | 1997-04-05 | 1998-03-24 | Bleichaktive Metall-Komplexe |
Country Status (6)
| Country | Link |
|---|---|
| US (2) | US6139769A (enExample) |
| EP (1) | EP0869171B1 (enExample) |
| JP (1) | JP4049881B2 (enExample) |
| BR (1) | BR9801148A (enExample) |
| DE (2) | DE19714122A1 (enExample) |
| ES (1) | ES2231913T3 (enExample) |
Cited By (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2000012808A1 (en) * | 1998-09-01 | 2000-03-09 | Unilever Plc | Method of treating a textile |
| WO2000060043A1 (en) * | 1999-04-01 | 2000-10-12 | Unilever Plc | Composition and method for bleaching a substrate |
| WO2000060044A1 (en) * | 1999-04-01 | 2000-10-12 | Unilever Plc | Composition and method for bleaching a substrate |
| US6302921B1 (en) | 1999-09-01 | 2001-10-16 | Unilever Home & Personal Care Usa, Division Of Conopco, Inc. | Method of bleaching stained fabrics |
| US6432900B1 (en) | 1999-09-01 | 2002-08-13 | Unilever Home & Personal Care Usa, Division Of Conopco, Inc. | Ligand and complex for catalytically bleaching a substrate |
| US6451752B1 (en) | 1999-09-01 | 2002-09-17 | Unilever Home & Personal Care Usa, Division Of Conopco, Inc. | Method of pretreating and bleaching stained fabrics |
| US6610641B2 (en) | 2000-02-29 | 2003-08-26 | Unilever Home & Personal Care Usa, Division Of Conopco, Inc. | Composition and method for bleaching a substrate |
| US6653271B2 (en) | 1999-09-01 | 2003-11-25 | Unilever Home & Personal Care Usa, Division Of Conopco, Inc. | Composition and method for bleaching a substrate |
Families Citing this family (18)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| KR20000005710A (ko) | 1998-06-05 | 2000-01-25 | 성재갑 | 표백활성화제 |
| GB2366575A (en) * | 2000-09-11 | 2002-03-13 | Unilever Plc | Bleaching composition |
| DE10304131A1 (de) * | 2003-02-03 | 2004-08-05 | Clariant Gmbh | Verwendung von Übergangsmetallkomplexen als Bleichkatalysatoren |
| US7794607B2 (en) * | 2005-06-22 | 2010-09-14 | Truox, Inc. | Composition and method for enhanced sanitation and oxidation of aqueous systems |
| US7572390B2 (en) * | 2005-06-22 | 2009-08-11 | Truox, Inc. | Composition and method for reducing chemical oxygen demand in water |
| US7695631B2 (en) * | 2005-06-22 | 2010-04-13 | Truox, Inc. | Composition and method for reducing chemical oxygen demand in water |
| US7476333B2 (en) * | 2005-06-22 | 2009-01-13 | Truox, Inc. | Composition and method for reducing chemical oxygen demand in water |
| JP2007126776A (ja) * | 2005-11-02 | 2007-05-24 | Nisshin Kagaku Kenkyusho:Kk | 古紙パルプの処理方法および脱墨助剤 |
| JP5352099B2 (ja) * | 2007-03-09 | 2013-11-27 | 住友化学株式会社 | 変性金属錯体を用いたレッドックス触媒 |
| TR201905689T4 (tr) | 2008-04-09 | 2019-05-21 | Basf Se | Hidrazit bileşiklerinin oksidasyon katalizörleri olarak kullanımı. |
| MX2012015285A (es) | 2010-06-28 | 2013-02-07 | Basf Se | Composicion blanqueadora libre de metal. |
| RU2014120925A (ru) | 2011-10-25 | 2015-12-10 | Басф Се | Применение гребенчатых или блок-сополимеров в качестве средств против повторного осаждения загрязнения и грязеотталкивающих средств в процессах стирки |
| CN104145012A (zh) | 2011-10-25 | 2014-11-12 | 巴斯夫欧洲公司 | 丙烯酸酯共聚物作为抗污垢再沉积剂和去污剂在洗衣过程中的用途 |
| CN110105480A (zh) | 2013-03-15 | 2019-08-09 | 路博润先进材料公司 | 衣康酸聚合物 |
| US9790452B2 (en) | 2013-03-27 | 2017-10-17 | Basf Se | Block copolymers as soil release agents in laundry processes |
| KR20160105790A (ko) | 2013-11-27 | 2016-09-07 | 바스프 에스이 | 세탁 방법에서 오염물 방출제로서의 랜덤 공중합체 |
| KR102350475B1 (ko) | 2014-03-14 | 2022-01-11 | 루브리졸 어드밴스드 머티어리얼스, 인코포레이티드 | 이타콘산 폴리머 및 코폴리머 |
| WO2017186480A1 (en) | 2016-04-26 | 2017-11-02 | Basf Se | Metal free bleaching composition |
Family Cites Families (20)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3928328A (en) * | 1972-12-08 | 1975-12-23 | Du Pont | Schiff base and metal bisazomethine metal chelate |
| GB1439048A (en) * | 1973-09-11 | 1976-06-09 | Ciba Geigy Ag | Metal complexes of bis-azomethines and processes for their manufacture |
| CH596276A5 (enExample) * | 1974-07-31 | 1978-03-15 | Ciba Geigy Ag | |
| US4728455A (en) * | 1986-03-07 | 1988-03-01 | Lever Brothers Company | Detergent bleach compositions, bleaching agents and bleach activators |
| US4861904A (en) * | 1986-04-17 | 1989-08-29 | Agency Of Industrial Science And Technology | Schiff base metal complex compounds, and organometallic ultrathin film composed thereof and oxygen separation films composed thereof |
| GB8908416D0 (en) * | 1989-04-13 | 1989-06-01 | Unilever Plc | Bleach activation |
| GB9003741D0 (en) * | 1990-02-19 | 1990-04-18 | Unilever Plc | Bleach activation |
| US5266283A (en) * | 1990-05-11 | 1993-11-30 | Bend Research, Inc. | Sterically hindered, regenerable Schiff base complexes, solutions thereof and process using the same |
| DE69125310T2 (de) * | 1990-05-21 | 1997-07-03 | Unilever Nv | Bleichmittelaktivierung |
| GB9108136D0 (en) * | 1991-04-17 | 1991-06-05 | Unilever Plc | Concentrated detergent powder compositions |
| GB9124581D0 (en) * | 1991-11-20 | 1992-01-08 | Unilever Plc | Bleach catalyst composition,manufacture and use thereof in detergent and/or bleach compositions |
| EP0544490A1 (en) * | 1991-11-26 | 1993-06-02 | Unilever Plc | Detergent bleach compositions |
| US5194416A (en) * | 1991-11-26 | 1993-03-16 | Lever Brothers Company, Division Of Conopco, Inc. | Manganese catalyst for activating hydrogen peroxide bleaching |
| GB9127060D0 (en) * | 1991-12-20 | 1992-02-19 | Unilever Plc | Bleach activation |
| CA2085642A1 (en) * | 1991-12-20 | 1993-06-21 | Ronald Hage | Bleach activation |
| DE69412188T2 (de) * | 1993-06-19 | 1999-03-11 | Ciba Specialty Chemicals Holding Inc., Basel | Inhibierung der Wiederabsorption von migrierenden Farbstoffen in der Waschlösung |
| WO1996015136A1 (en) * | 1994-11-14 | 1996-05-23 | Dublin Institute Of Technology | Novel mn(ii) carboxylate complexes, processes for their preparation and their use as disproportionation catalysts |
| GB9425296D0 (en) * | 1994-12-15 | 1995-02-15 | Ciba Geigy Ag | Inhibition of dye migration |
| GB9523654D0 (en) * | 1995-11-18 | 1996-01-17 | Ciba Geigy Ag | Fabric bleaching composition |
| DE19719397A1 (de) * | 1997-05-07 | 1998-11-12 | Clariant Gmbh | Bleichaktive Metall-Komplexe |
-
1997
- 1997-04-05 DE DE19714122A patent/DE19714122A1/de not_active Withdrawn
-
1998
- 1998-03-24 DE DE59812192T patent/DE59812192D1/de not_active Expired - Fee Related
- 1998-03-24 ES ES98105257T patent/ES2231913T3/es not_active Expired - Lifetime
- 1998-03-24 EP EP98105257A patent/EP0869171B1/de not_active Expired - Lifetime
- 1998-04-02 US US09/054,204 patent/US6139769A/en not_active Expired - Fee Related
- 1998-04-03 JP JP09204098A patent/JP4049881B2/ja not_active Expired - Fee Related
- 1998-04-03 BR BR9801148-0A patent/BR9801148A/pt not_active Application Discontinuation
-
2000
- 2000-07-10 US US09/613,211 patent/US6602441B1/en not_active Expired - Fee Related
Cited By (9)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2000012808A1 (en) * | 1998-09-01 | 2000-03-09 | Unilever Plc | Method of treating a textile |
| US6245115B1 (en) | 1998-09-01 | 2001-06-12 | Unilever Home & Personal Care Usa, Division Of Conopco, Inc. | Method of treating a textile |
| WO2000060043A1 (en) * | 1999-04-01 | 2000-10-12 | Unilever Plc | Composition and method for bleaching a substrate |
| WO2000060044A1 (en) * | 1999-04-01 | 2000-10-12 | Unilever Plc | Composition and method for bleaching a substrate |
| US6302921B1 (en) | 1999-09-01 | 2001-10-16 | Unilever Home & Personal Care Usa, Division Of Conopco, Inc. | Method of bleaching stained fabrics |
| US6432900B1 (en) | 1999-09-01 | 2002-08-13 | Unilever Home & Personal Care Usa, Division Of Conopco, Inc. | Ligand and complex for catalytically bleaching a substrate |
| US6451752B1 (en) | 1999-09-01 | 2002-09-17 | Unilever Home & Personal Care Usa, Division Of Conopco, Inc. | Method of pretreating and bleaching stained fabrics |
| US6653271B2 (en) | 1999-09-01 | 2003-11-25 | Unilever Home & Personal Care Usa, Division Of Conopco, Inc. | Composition and method for bleaching a substrate |
| US6610641B2 (en) | 2000-02-29 | 2003-08-26 | Unilever Home & Personal Care Usa, Division Of Conopco, Inc. | Composition and method for bleaching a substrate |
Also Published As
| Publication number | Publication date |
|---|---|
| US6602441B1 (en) | 2003-08-05 |
| EP0869171B1 (de) | 2004-11-03 |
| JP4049881B2 (ja) | 2008-02-20 |
| ES2231913T3 (es) | 2005-05-16 |
| EP0869171A3 (de) | 1999-04-07 |
| US6139769A (en) | 2000-10-31 |
| BR9801148A (pt) | 2000-02-08 |
| DE59812192D1 (de) | 2004-12-09 |
| EP0869171A2 (de) | 1998-10-07 |
| JPH115993A (ja) | 1999-01-12 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| 8130 | Withdrawal |